CN107787984A - A kind of prothioconazoles Tebuconazole micro-capsule suspension and preparation method thereof - Google Patents
A kind of prothioconazoles Tebuconazole micro-capsule suspension and preparation method thereof Download PDFInfo
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- CN107787984A CN107787984A CN201610757495.1A CN201610757495A CN107787984A CN 107787984 A CN107787984 A CN 107787984A CN 201610757495 A CN201610757495 A CN 201610757495A CN 107787984 A CN107787984 A CN 107787984A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
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Abstract
The invention provides a kind of prothioconazoles Tebuconazole micro-capsule suspension and preparation method thereof.The prothioconazoles Tebuconazole micro-capsule suspension includes following each component by mass percentage：Prothioconazoles：1%~20%, Tebuconazole：1%~40%；Cyst material：6%~10%；Capsule-core solvent：15%~20%；Emulsifying agent：1%~5%；Thickener：0.1%~1%；Dispersant：3%~5%；Antifreezing agent：1%~5%；Preservative：0.1%~0.5%；PH adjusting agent：1%~3%；Surplus is water.The preparation method, prothioconazoles microcapsules oil phase is obtained to coagulate legal system again, is sanded with wet method and tebuconazole suspension concentrates aqueous phase is made, final products are then prepared in the presence of shear-mixed；The micro-capsule suspension has the function that slowly release, improves the lasting period, so as to improve quick-acting and lasting effect, reduces frequency of usage, reduces the usage amount of agricultural chemicals；Technique is simple, can effectively realize volume production, thus has very high application value.
Description
Technical field
The invention belongs to bactericide field, and in particular to a kind of prothioconazoles-Tebuconazole micro-capsule suspension and its preparation
Method.
Background technology
It is well known that growth of the disease to crops has very big harm, and agricultural chemicals rises in preventing and treating plant disease pest, disease
Main function.In recent years, the average annual Pesticide use amount in China is excessive, and wherein majority is chemical pesticide, thus caused by environment it is dirty
Dye and food-safety problem are increasingly serious, endanger the health of the mankind, it is seen that less toxic, efficient, the environment-friendly novel agrochemical of exploitation
It is the main outlet for realizing agricultural product security.
Prothioconazoles are a kind of New-type wide-spectrum triazolinthione series bactericidal agents that Beyer Co., Ltd develops, and its mechanism of action is suppression
The demethylation effect of precursor-lanosterol of sterol, i.e. demethylation inhibitors (DMIs) in fungi processed.Prothioconazoles are not only
With good systemic activity, excellent protection, treat and root out activity, and the lasting period is grown.Tried by substantial amounts of field efficacy
Test, the results showed that prothioconazoles not only have good security to crop, and preventing disease theraping effect is good, and increase production substantially, together
Triazole bactericidal agent is compared, and prothioconazoles have broader spectrum of bactericidal activity；It is mainly used in preventing and treating cereal crop such as wheat, big
Numerous diseases such as wheat, rape, peanut, rice and legume crop.Moreover, prothioconazoles almost have very well to all wheat class diseases
Prevention effect, such as the powdery mildew of wheat and barley, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire
Disease etc..Prothioconazoles can also prevent and treat the soil-borne disease of oily Lay and peanut, such as sclerotiniose, and main foliage disease, as gray mold,
Black spot, brown spot, balck shank, sclerotiniose and rust etc..
Tebuconazole is a kind of efficient, wide spectrum, absorbability triazole type sterilization pesticide, has and protects, treats, rooting out three big work(
Can, wide sterilization spectrum, lasting period length.As all triazole bactericidal agents, Tebuconazole can suppress the ergosterol of fungi
Biosynthesis so that germ can not form cell membrane, so as to kill germ.Tebuconazole is used as seed treatment in worldwide
Agent and foliar spray, wide sterilization spectrum, not only activity is high, and the lasting period is grown；It is mainly used in preventing and treating wheat, rice, peanut, vegetable
A variety of fungal diseases on the crops such as dish, banana, apple, pears and corn and Chinese sorghum, its kind more than 60 in more than 50 countries in the whole world
Obtained on crop and register and obtain extensive use.Tebuconazole is used to prevent and treat sclerotinia sclerotiorum, and not only preventive effect is good, and with anti-fall
Volt, the features such as production-increasing function is obvious.
However, in actual applications, there are some defects in prothioconazoles, the independent dispenser of Tebuconazole or compounding use,
For example, agricultural chemicals quick-acting is not good enough, overall usage amount is excessive, and the lasting period falls short of, the technical problems such as spraying times are excessive.
Pesticide micro capsule suspending agent refers to form the small appearance of nucleocapsid structure using natural or synthesis high polymer material
Device, by agricultural chemicals cladding wherein, and it is suspended in the formulations of pesticide in water.It includes cyst wall and capsule-core two parts, and capsule-core is that agricultural chemicals has
It is the high polymer material of film forming to imitate composition and solvent, cyst wall.This formulation is divided into continuous phase and discontinuous phase, continuous phase be water and
Auxiliary agent, discontinuous phase are the agricultural chemicals tiny capsules being wrapped by.Microcapsule method is an important application in prepared by the formulations of pesticide
Technology, compared with conventional pesticide technology, microcapsules have protection core material material exempt from it is influenced by environmental conditions, make pesticide activity
The decomposition rate of composition slows down, reduces pesticide activity component volatilization loss, so as to obtain the utilization rate for improving active component, extends
Its lasting period, the advantages that reducing the number and frequency of dispenser.
The content of the invention
In order to overcome shortcomings and deficiencies present in above-mentioned prior art, inventor is answered prothioconazoles and Tebuconazole
Match somebody with somebody, using prothioconazoles-Tebuconazole after compounding as the active ingredient of the micro-capsule suspension, also, inventor intends fully profit
With this one dosage type low temperature of micro-capsule suspension, a kind of significant prothioconazoles of synergistic effect-Tebuconazole micro-capsule suspension is prepared, and
Obtain excellent prevention effect.
Pesticide micro capsule suspending agent mainly has following four advantages in itself：First, introduce sustained release and control release skill
Art, the agricultural chemicals lasting period is extended, reduce dispenser quantity and frequency, improved the utilization rate of agricultural chemicals, save pesticide dosage；The
Two, be prepared into the stability that agricultural chemicals can be improved after microcapsule formulations, avoid caused by environmental factor and other chemical substances effectively into
Point decomposition, oxidation, loss etc.；3rd, oil phase is separated from the water, to the agricultural chemicals of some water unstables, then can be processed into
Microcapsule formulations, expand the use range of agricultural chemicals, improve the compounding capacity with other agricultural chemicals；4th, microcapsule formulations can suppress agriculture
The volatility of medicine, shelters offending smell, reduces poisoning of the agricultural chemicals to the toxicity of people, animal and other animals and to crop, subtracts
Gently to the pressure of environment.
Therefore, the first aspect of the present invention provides a kind of prothioconazoles-Tebuconazole micro-capsule suspension, the rosickyite bacterium
Azoles-Tebuconazole micro-capsule suspension includes following each component by mass percentage：Prothioconazoles：1%~20%, Tebuconazole：
1%~40%；Cyst material：6%~10%；Capsule-core solvent：15%~20%；Emulsifying agent：1%~5%；Thickener：0.1%
~1%；Dispersant：3%~5%；Antifreezing agent：1%~5%；Preservative：0.1%~0.5%；PH adjusting agent：1%~3%；
Surplus is water.Wherein, the water is preferably deionization soft water.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the cyst material is selected from following any
It is or a variety of：Arabic gelatin, gum arabic, Lauxite, isocyanates, polyamine.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the capsule-core solvent is rosin-based plant
Oil.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the emulsifying agent is that plant source anacardol gathers
Oxygen ethene-oxypropylene block type polyethers.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the thickener is selected from following any：
Xanthans, white carbon, Magnesiumaluminumsilicate.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the dispersant is selected from following any：
Carboxylate, plant source cardanol polyoxyethylene ether phosphate, naphthalene sulfonate, alkylsulfonate, sodium alkyl benzene sulfonate, alkylnaphthalene sulphur
Hydrochlorate, alkylphenol-polyethenoxy base sodium sulphate.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the antifreezing agent is ethylene glycol or the third three
Alcohol.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the preservative is sodium benzoate or different thiophene
Oxazoline ketone.
Preferably, in above-mentioned prothioconazoles-Tebuconazole micro-capsule suspension, the pH adjusting agent is selected from following any
It is or a variety of：Hydrochloric acid, sodium hydroxide, glacial acetic acid, triethanolamine.
It can be seen that prothioconazoles provided by the present invention-Tebuconazole micro-capsule suspension, be using prothioconazoles and Tebuconazole as
Active ingredient, be equipped with cyst material, capsule-core solvent, emulsifying agent, thickener, dispersant, antifreezing agent, preservative, water and formed
Micro-capsule suspension.Wherein, the plant source anacardol PULLRONIC F68 block type polyethers as emulsifying agent, as capsule
The turpentine-based vegetable oil of core solvent, it is not only cheap and easy to get, and there is no toxic action to environment, obtained microcapsules is suspended
Agent aids in improving the prevention effect of prothioconazoles and Tebuconazole, and reduces the production cost of agricultural chemicals.
The second aspect of the present invention, there is provided a kind of prothioconazoles described in first aspect present invention-Tebuconazole microcapsules hang
The preparation method of floating agent, comprises the following steps：
(1) prothioconazoles, capsule-core solvent are weighed by proportioning, added in container, temperature control heating, is sufficiently stirred, with completely molten
Solve prothioconazoles；Add emulsifying agent and cyst material, stirring and dissolving, and using pH adjusting agent regulation system pH value to 5~
7, prothioconazoles microcapsules oil phase is made；
(2) Tebuconazole, dispersant, thickener, preservative, antifreezing agent and water are weighed by proportioning, added in another container,
After being sufficiently stirred, carry out homogeneous shearing and be sanded, tebuconazole suspension concentrates aqueous phase is made；
(3) in the presence of homogeneous shearing, by the prothioconazoles microcapsules oil phase and the tebuconazole suspension concentrates aqueous phase
Mixing, the prothioconazoles-Tebuconazole micro-capsule suspension is made.
In summary, the preparation method of prothioconazoles provided by the invention-Tebuconazole micro-capsule suspension, to coagulate legal system again
Prothioconazoles microcapsules oil phase is obtained, is sanded with wet method and tebuconazole suspension concentrates aqueous phase is made, then made in the presence of shear-mixed
Standby final products；The micro-capsule suspension has slowly release, improves the effect of lasting period, which not only improves prothioconazoles-
The quick-acting of Tebuconazole, meets the use demand of peasant, while also improves the lasting effect of preparation, reduces the Pesticide use frequency,
Reduce the usage amount of agricultural chemicals.In addition, the technique of the preparation method is simple, volume production can be effectively realized, thus should with very high
With value.
In addition, prothioconazoles of the present invention-Tebuconazole micro-capsule suspension is compared with prior art, can also at least produce
Raw following beneficial effect：
(1) the successful compounding of prothioconazoles and Tebuconazole, there is obvious synergy synergy, it is seen that prevention effect is obvious
Improve, reduce Pesticide use amount, effectively reduce environmental pollution and residues of pesticides, reduce the harm to beneficial organism；(2) it is quick-acting
Property good and lasting effect grow, so as to save spraying times, reduce labour cost；(3) preparation method and obtained pesticide agent
Type is green, has good market potential.
Brief description of the drawings
Fig. 1 is the process chart of the preparation method of prothioconazoles of the present invention-Tebuconazole micro-capsule suspension.
Embodiment
With reference to embodiment, the present invention is further elaborated, but the present invention is not limited to following embodiment party
Formula.
Embodiment 1
The matter of prothioconazoles-Tebuconazole micro-capsule suspension, wherein each component is prepared using technological process as shown in Figure 1
Measuring percentage is：
Wherein, cyst material is Arabic gelatin, and capsule-core solvent is turpentine-based vegetable oil, and emulsifying agent is plant source anacardol
PULLRONIC F68 block type polyethers, thickener are xanthans, and dispersant is naphthalene sulfonate, and antifreezing agent is glycerine, are prevented
Rotten agent is sodium benzoate, and pH adjusting agent is glacial acetic acid and triethanolamine.
10g prothioconazoles, 10g turpentine-based vegetable oils are weighed, is added in container, temperature control heating, is sufficiently stirred, with completely molten
Solve prothioconazoles；3g plant source anacardol PULLRONIC F68 block type polyethers and 10g Arab gelatin are added, is stirred
Dissolving is mixed, and using the pH value of glacial acetic acid and triethanolamine regulation system to 5~7, prothioconazoles microcapsules oil phase is made；Weigh
30g Tebuconazoles, 3g naphthalene sulfonates, 0.2g xanthans, 0.1g sodium benzoates, 4g glycerine and 27.7g water, add another container
In, after being sufficiently stirred, it is added in sand mill, carries out homogeneous shearing and be sanded, tebuconazole suspension concentrates aqueous phase is made；Sheared in homogeneous
In the presence of, the prothioconazoles microcapsules oil phase is mixed with the tebuconazole suspension concentrates aqueous phase, (40% active ingredient is made
Content) prothioconazoles-Tebuconazole micro-capsule suspension.
Embodiment 2
The matter of prothioconazoles-Tebuconazole micro-capsule suspension, wherein each component is prepared using technological process as shown in Figure 1
Measuring percentage is：
Wherein, cyst material is isocyanates, and capsule-core solvent is turpentine-based vegetable oil, and emulsifying agent is that plant source anacardol gathers
Oxygen ethene-oxypropylene block type polyethers, thickener are xanthans, and dispersant is carboxylate, and antifreezing agent is glycerine, preservative
For sodium benzoate, pH adjusting agent is glacial acetic acid and triethanolamine.
15g prothioconazoles, 15g turpentine-based vegetable oils are weighed, is added in container, temperature control heating, is sufficiently stirred, with completely molten
Solve prothioconazoles；4g plant source anacardol PULLRONIC F68 block type polyethers and 7g isocyanates are added, stirring is molten
Solution, and using the pH value of glacial acetic acid and triethanolamine regulation system to 5~7, prothioconazoles microcapsules oil phase is made；Weigh 25g
Tebuconazole, 2.5g carboxylates, 0.1g xanthans, 0.1g sodium benzoates, 4g glycerine and 28.3g water, are added in another container,
After being sufficiently stirred, it is added in sand mill, carries out homogeneous shearing and be sanded, tebuconazole suspension concentrates aqueous phase is made；In homogeneous shearing
Under effect, the prothioconazoles microcapsules oil phase is mixed with the tebuconazole suspension concentrates aqueous phase, obtained (40% active ingredient contains
Amount) prothioconazoles-Tebuconazole micro-capsule suspension.
Embodiment 3
The matter of prothioconazoles-Tebuconazole micro-capsule suspension, wherein each component is prepared using technological process as shown in Figure 1
Measuring percentage is：
Wherein, cyst material is Lauxite, and capsule-core solvent is turpentine-based vegetable oil, and emulsifying agent is that plant source anacardol gathers
Oxygen ethene-oxypropylene block type polyethers, thickener are xanthans, and dispersant is plant source cardanol polyoxyethylene ether phosphoric acid
Ester, antifreezing agent are glycerine, and preservative is sodium benzoate, and pH adjusting agent is glacial acetic acid.
5g prothioconazoles, 10g turpentine-based vegetable oils are weighed, is added in container, temperature control heating, is sufficiently stirred, with completely molten
Solve prothioconazoles；3g plant source anacardol PULLRONIC F68 block type polyethers and 6g Lauxites are added, stirring is molten
Solution, and use the pH value of glacial acetic acid regulation system that prothioconazoles microcapsules oil phase is made to 5~7；Weigh 30g Tebuconazoles, 3g plants
Material resource cardanol polyoxyethylene ether phosphate, 0.1g xanthans, 0.1g sodium benzoates, 4g glycerine and 36.7g water, add another
In individual container, after being sufficiently stirred, it is added in sand mill, carries out homogeneous shearing and be sanded, tebuconazole suspension concentrates aqueous phase is made；Equal
In the presence of matter shearing, the prothioconazoles microcapsules oil phase is mixed with the tebuconazole suspension concentrates aqueous phase, obtained (35% has
Effective component content) prothioconazoles-Tebuconazole micro-capsule suspension.
Embodiment 4
The matter of prothioconazoles-Tebuconazole micro-capsule suspension, wherein each component is prepared using technological process as shown in Figure 1
Measuring percentage is：
Wherein, cyst material is Arabic gelatin and gum arabic, and capsule-core solvent is turpentine-based vegetable oil, and emulsifying agent is
Plant source anacardol PULLRONIC F68 block type polyethers, thickener is xanthans, and dispersant is naphthalene sulfonate, antifreeze
Agent is ethylene glycol, and preservative is OIT, and pH adjusting agent is glacial acetic acid and sodium hydroxide.
10g prothioconazoles, 20g turpentine-based vegetable oils are weighed, is added in container, temperature control heating, is sufficiently stirred, with completely molten
Solve prothioconazoles；Add 5g plant source anacardol PULLRONIC F68 block type polyethers and 6g Arab gelatin+I
Uncle's natural gum, stirring and dissolving, and using the pH value of glacial acetic acid and sodium hydroxide regulation system to 5~7, prothioconazoles microcapsules are made
Oil phase；10g Tebuconazoles, 2.5g naphthalene sulfonates, 0.2g xanthans, 0.1g OITs, 4g ethylene glycol and 41.2g water are weighed,
Add in another container, after being sufficiently stirred, be added in sand mill, carry out homogeneous shearing and be sanded, tebuconazole suspension concentrates are made
Aqueous phase；In the presence of homogeneous shearing, the prothioconazoles microcapsules oil phase is mixed with the tebuconazole suspension concentrates aqueous phase, made
Obtain (20% active constituent content) prothioconazoles-Tebuconazole micro-capsule suspension.
In order to prove that there is significant preventive effect containing prothioconazoles of the present invention-Tebuconazole micro-capsule suspension, application
People has carried out following crop field effect experiment：
A. wheat powdery mildew is entered in field using prothioconazoles-Tebuconazole micro-capsule suspension made from embodiment 1~4
The row test of pesticide effectiveness, wherein using 25% prothioconazoles missible oil and 430g/L tebuconazole suspension concentrates as comparison medicament, experimental result is shown in Table
1：
The field efficacy of 1 prothioconazoles of table-Tebuconazole micro-capsule suspension preventing and treating wheat powdery mildew
Data result in table 1 shows, prothioconazoles-Tebuconazole micro-capsule suspension in 1-7 days to wheat powdery mildew
Prevention effect be above 90%, hence it is evident that better than comparison medicament；In terms of holding effect sex expression, prothioconazoles-Tebuconazole microcapsules
Suspending agent is in the prevention effect of 28 days up to more than 70%, and the prevention effect at 42 days is also higher than 64%, generally better than control
Medicament；Show that the sustained release performance of the formulation is excellent.
B. wheat sharp eyespot is entered in field using prothioconazoles-Tebuconazole micro-capsule suspension made from embodiment 1~4
The row test of pesticide effectiveness, wherein using 25% prothioconazoles missible oil and 430g/L tebuconazole suspension concentrates as comparison medicament, experimental result is shown in Table
2：
The field efficacy of 2 prothioconazoles of table-Tebuconazole micro-capsule suspension preventing and treating wheat sharp eyespot
Data result in table 2 shows, prothioconazoles-Tebuconazole micro-capsule suspension in 1-7 days to wheat sharp eyespot
Prevention effect be above 90%, hence it is evident that better than comparison medicament；In terms of holding effect sex expression, prothioconazoles-Tebuconazole microcapsules
Suspending agent is in the prevention effect of 28 days up to more than 75%, and the prevention effect at 42 days is also higher than 65%, generally better than control
Medicament；Show that the sustained release performance of the formulation is excellent.
C. sclerotinia sclerotiorum is entered in field using prothioconazoles-Tebuconazole micro-capsule suspension made from embodiment 1~4
The row test of pesticide effectiveness, wherein using 25% prothioconazoles missible oil and 430g/L tebuconazole suspension concentrates as comparison medicament, experimental result is shown in Table
3：
The field efficacy of 3 prothioconazoles of table-Tebuconazole micro-capsule suspension preventing and treating sclerotinia sclerotiorum
Data result in table 3 shows, prothioconazoles-Tebuconazole micro-capsule suspension in 1-14 days to sclerotinia sclerotiorum
Prevention effect be above 90%, hence it is evident that better than comparison medicament；In terms of holding effect sex expression, prothioconazoles-Tebuconazole microcapsules
Suspending agent is in the prevention effect of 28 days up to more than 70%, and the prevention effect at 42 days is also higher than 65%, generally better than control
Medicament；Show that the sustained release performance of the formulation is excellent.
The specific embodiment of the present invention is described in detail above, but it is intended only as example, it is of the invention and unlimited
It is formed on particular embodiments described above.To those skilled in the art, it is any to the equivalent modifications that carry out of the present invention and
Substitute also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Modification, all should be contained within the scope of the invention.
Claims (10)
1. a kind of prothioconazoles-Tebuconazole micro-capsule suspension, it is characterised in that the prothioconazoles-Tebuconazole microcapsules hang
Floating agent includes following each component by mass percentage：Prothioconazoles：1%~20%, Tebuconazole：1%~40%；Cyst material：6%
~10%；Capsule-core solvent：15%~20%；Emulsifying agent：1%~5%；Thickener：0.1%~1%；Dispersant：3%~5%；Antifreezing agent：1%
~5%；Preservative：0.1%~0.5%；PH adjusting agent：1%~3%；Surplus is water.
2. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the cyst material
Selected from following any one or more：Arabic gelatin, gum arabic, Lauxite, isocyanates, polyamine.
3. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the capsule-core solvent
For turpentine-based vegetable oil.
4. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the emulsifying agent is
Plant source anacardol PULLRONIC F68 block type polyethers.
5. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the thickener choosing
From following any：Xanthans, white carbon, Magnesiumaluminumsilicate.
6. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the dispersant choosing
From following any：Carboxylate, plant source cardanol polyoxyethylene ether phosphate, naphthalene sulfonate, alkylsulfonate, benzene sulfonamide
Sour sodium, alkylnaphthalene sulfonate, alkylphenol-polyethenoxy base sodium sulphate.
7. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the antifreezing agent is
Ethylene glycol or glycerine.
8. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the preservative is
Sodium benzoate or OIT.
9. prothioconazoles according to claim 1-Tebuconazole micro-capsule suspension, it is characterised in that the pH adjusting agent
Selected from following any one or more：Hydrochloric acid, sodium hydroxide, glacial acetic acid, triethanolamine.
A kind of 10. preparation side of prothioconazoles-Tebuconazole micro-capsule suspension according to any one of claim 1 ~ 9
Method, it is characterised in that comprise the following steps：
（1）Prothioconazoles, capsule-core solvent are weighed by proportioning, is added in container, temperature control heating, is sufficiently stirred, to be completely dissolved third
Sulphur bacterium azoles；Emulsifying agent and cyst material, stirring and dissolving are added, and uses the pH value of pH adjusting agent regulation system to be made to 5 ~ 7
Prothioconazoles microcapsules oil phase；
（2）Tebuconazole, dispersant, thickener, preservative, antifreezing agent and water are weighed by proportioning, is added in another container, fully
After stirring, carry out homogeneous shearing and be sanded, tebuconazole suspension concentrates aqueous phase is made；
（3）In the presence of homogeneous shearing, the prothioconazoles microcapsules oil phase is mixed with the tebuconazole suspension concentrates aqueous phase,
The prothioconazoles-Tebuconazole micro-capsule suspension is made.
Priority Applications (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111887244A (en) * | 2020-07-15 | 2020-11-06 | 中国农业科学院植物保护研究所 | Method for preparing prothioconazole sustained-release gel particles by carboxymethyl chitosan-metal ion crosslinking method |
| CN114586795A (en) * | 2022-03-29 | 2022-06-07 | 宁夏苏融达化工有限公司 | Prothioconazole microcapsule suspending agent and preparation method and application thereof |
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| CN101416631A (en) * | 2008-09-24 | 2009-04-29 | 中国农业科学院植物保护研究所 | Functional slow-release suspension seed-coating agents |
| CN103583564A (en) * | 2012-08-17 | 2014-02-19 | 陕西美邦农药有限公司 | High-efficiency bactericidal composition containing simeconazole and triazoles |
| CN104642331A (en) * | 2013-11-15 | 2015-05-27 | 南京华洲药业有限公司 | Bactericidal composition containing prothioconazole and tebuconazole and application thereof |
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| CN101416631A (en) * | 2008-09-24 | 2009-04-29 | 中国农业科学院植物保护研究所 | Functional slow-release suspension seed-coating agents |
| CN103583564A (en) * | 2012-08-17 | 2014-02-19 | 陕西美邦农药有限公司 | High-efficiency bactericidal composition containing simeconazole and triazoles |
| CN104642331A (en) * | 2013-11-15 | 2015-05-27 | 南京华洲药业有限公司 | Bactericidal composition containing prothioconazole and tebuconazole and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111887244A (en) * | 2020-07-15 | 2020-11-06 | 中国农业科学院植物保护研究所 | Method for preparing prothioconazole sustained-release gel particles by carboxymethyl chitosan-metal ion crosslinking method |
| CN114586795A (en) * | 2022-03-29 | 2022-06-07 | 宁夏苏融达化工有限公司 | Prothioconazole microcapsule suspending agent and preparation method and application thereof |
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