CN107746586A - A kind of toner and carbon fibre composite, composite article and manufacturing process - Google Patents
A kind of toner and carbon fibre composite, composite article and manufacturing process Download PDFInfo
- Publication number
- CN107746586A CN107746586A CN201711047281.6A CN201711047281A CN107746586A CN 107746586 A CN107746586 A CN 107746586A CN 201711047281 A CN201711047281 A CN 201711047281A CN 107746586 A CN107746586 A CN 107746586A
- Authority
- CN
- China
- Prior art keywords
- powder
- toner
- parts
- carbon
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/16—Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/02—Polythioethers; Polythioether-ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of toner and carbon fibre composite, composite article and manufacturing process.Toner and carbon fibre composite, including 100 parts of carbon cloth, 30~300 parts of thermoplastic macromolecule resin's powder.Toner is formed with carbon fiber composite article by toner and carbon fibre composite molding.In the application in technical scheme, toner and carbon fiber energy complete wetting, and the shortcomings that overcome prior art air is not easy discharge between layers；Its lighter weight of the composite article of formation, tensile strength is high, and production cost is low.
Description
Technical field
The invention belongs to composite and engineering field, is related to the application of powdex based composites, particularly relates to
And a kind of toner and carbon fibre composite, composite article and manufacturing process.
Background technology
Constantly increase with the continuous development and energy resource consumption of industry, save the energy and reduce pollution to environment into
The key issue for being badly in need of solving for automobile industry development and social sustainable development.
The fuel consumption of automobile and the discharge capacity of CO 2 waste gas depend primarily on the weight of body of a motor car, existing vapour
Car body part and parts are made of metal material mostly, and automobile body part intensity made from metal material is big, performance is good, but
The density of metal is big, and the automobile being assembled into is heavy, therefore the fuel consumption of automobile is big, wastes the energy, and CO 2 waste gas
Discharge capacity it is also once big, the pollution to environment aggravates.
At present, new-energy automobile substitutes traditional fuel-engined vehicle to have become a kind of trend.But with New energy electric
The development of automobile, the anxiety of new-energy automobile distance travelled, the requirement more and more higher to automotive light weight technology.With carbon fiber and high score
Subtree fat is compound to turn into the focus material for preparing lightweight car product.
The content of the invention
Goal of the invention：The present invention has made improvements in view of the above-mentioned problems of the prior art, i.e. first mesh of the invention
Be disclose a kind of toner and carbon fibre composite.Second object of the present invention is to disclose a kind of resin-oatmeal
End and carbon fiber composite article.Third object of the present invention is the system for disclosing a kind of toner and carbon fiber composite article
Make technique.
A kind of toner disclosed by the invention and carbon fibre composite, composite article and manufacturing process, meet very well
The light-weighted requirement of electric automobile, it is using thermoplastic macromolecule resin's powder compound with carbon cloth, consolidate with thermosetting resin
Change is compared, and has physical solidification and shaping beat short (3~5 clock), recyclable, physical and chemical performance is good, good toughness is flexible etc.
Advantage；Compared with thermoplastic extrusion coated carbon fibers cloth or extrudate piece, process for making disclosed by the invention is not required to secondary add
Heat, shaping only is carried out to carbon fiber cloth, leftover pieces are few, save the energy, and molecular resin amount can be higher, can reach more than 1,500,000 (ratios
Such as ultra-high molecular weight polyethylene), its product combination property is higher (because molecular resin amount is high).So the present invention solves very well
The deficiency of other combination process, its physical and chemical performance is more preferable, is more suitable for electric automobile to light-weighted requirement.The present invention
Available for military and national defense industry.
Technical scheme：A kind of toner and carbon fibre composite, by weight, including 100 parts of carbon cloth, thermoplastic
30~300 parts of property macromolecule resin powder.
Further, in addition to 0.5~6 part of auxiliary material, wherein：
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 0.2~2
The parts by weight of lubricant 0.2~2
The parts by weight of colouring agent 0.3~2.
Preferably, the auxiliary material also includes calcium carbonate, and calcium carbonate described in every part of auxiliary material is no more than 3 parts by weight.
Preferably, the auxiliary material also includes nucleator, and nucleator described in every part of auxiliary material is no more than 0.2 parts by weight.
It is further preferable that the plasticizer is ESO or dibutyl phthalate.
It is further preferable that the lubricant is oxidic polyethylene or stearate.
It is highly preferred that the stearate is selected from one or both of zinc stearate and calcium stearate.
It is highly preferred that the stabilizer is organic tin stabilizer.
It is highly preferred that the nucleator is zinc oxide.
A kind of toner and carbon fiber composite article, by above-mentioned toner and carbon fibre composite molding
Into.
It is further preferable that the toner and carbon fiber composite article can serve as vehicle body, wheel hub, collision prevention girders, bumper,
Seat battery bag.
The manufacturing process of a kind of toner and carbon fiber composite article, comprises the following steps:
(1) carbon cloth is cut into the shape of needs according to the size of prefabricated compound car product, baking oven is placed on or can connect
It is heated in the drying tunnel of continuous heating in the melt temperature scope of thermoplastic macromolecule resin's powder used；
(2) one layer of thermoplastic macromolecule resin's powder is applied on carbon cloth after the heating, and it is high in thermoplasticity used
Continue heating under the melting temperature of molecule resin 3~5 minutes, wherein：
The mass ratio of carbon cloth and thermoplastic macromolecule resin's powder is 100：(30~300)；
(3) carbon cloth after the completion of step (2) is heated according to the Thickness Strength of prefabricated composite body product is folded
Layer；
(4) carbon cloth after step (3) lamination is placed in the mould of required shape, is molded in forcing press,
Wherein：
0.1~100MPa of molding pressure；
Clamp time 1~5 minute；
20~120 DEG C of molding temperature；
(5) pickup is molded, arranges corner, you can obtain toner and carbon fiber composite article.
Further, auxiliary material has uniformly been mixed in thermoplastic macromolecule resin's powder of step (2), wherein：
The mass ratio of carbon cloth, thermoplastic macromolecule resin's powder and auxiliary material is 100：(30~300)：(0.5~6)；
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 0.2~2
The parts by weight of lubricant 0.2~2
The parts by weight of colouring agent 0.3~2.
Preferably, the auxiliary material also includes calcium carbonate, and calcium carbonate described in every part of auxiliary material is no more than 3 parts by weight.
Preferably, the auxiliary material also includes nucleator, and nucleator described in every part of auxiliary material is no more than 0.2 parts by weight.
It is further preferable that the plasticizer is ESO or dibutyl phthalate.
It is further preferable that the lubricant is oxidic polyethylene or stearate.
It is highly preferred that the stearate is selected from one or both of zinc stearate and calcium stearate.
It is highly preferred that the stabilizer is organic tin stabilizer.
It is highly preferred that the nucleator is zinc oxide.
Further, the particle diameter of thermoplastic macromolecule resin's powder in step (2) is 20~400 mesh.
Further, step (2) thermoplastic macromolecule resin's powder is ultra-high molecular weight polyethylene powder, polypropylene
Powder, polyvinyl chloride powder, ABS resin powder, Polystyrene powder, polycarbonate powder, polyamide resin powders, polyphenylene sulfide
One kind in ether resin powder, polyether-ether-ketone resin powder.
It is further preferable that the number-average molecular weight of the ultra-high molecular weight polyethylene powder is more than 150W.
Further, carbon cloth described in step (1) is plain cloth or twills or satin fabric or unidirectionally knitted
Thing or multilayer multiaxial fabric.
Preferably, when the carbon cloth is multilayer multiaxial fabric, the multilayer multiaxial fabric is knitted for Multi-axial stitch knitting
Thing or knitted fabric or direct oriented structure fabric.
It is further preferable that in carbon fibre fabric in fibre bundle monofilament quantity be 3K or 6K or 12K or 24K or 48K or
64K。
Beneficial effect：Compared with prior art, a kind of toner disclosed by the invention and carbon fibre composite, compound
Product and manufacturing process have the advantages that：
1st, higher comprehensive physical chemical property, toner and carbon fiber energy complete wetting, and overcome prior art
Air is not easy the shortcomings that discharge between layers；
2nd, production process is not required to reheating, and production is simple, and cost is low；
3rd, it is high without leftover pieces processing, production efficiency；
4th, composite article its lighter weight formed using technical scheme in the application, the about a quarter of Steel material,
Density is 1.3~1.8g/cm3；Its modulus of elasticity is 200000MPa, and intensity is high；Tensile strength is 1500MPa, tensile strength
It is high；
5th, it has suffered in production process that leftover pieces are few, cost is low.
Brief description of the drawings
Fig. 1 is a kind of toner disclosed by the invention and the schematic flow sheet of the manufacturing process of carbon fiber composite article；
Component label instructions in Fig. 1
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
Before the specific embodiment of the invention is further described, it should be appreciated that protection scope of the present invention is not limited to down
State specific specific embodiment；It is also understood that the term used in the embodiment of the present invention is specific specific in order to describe
Embodiment, the protection domain being not intended to be limiting of the invention.The test method of unreceipted actual conditions in the following example,
Generally according to normal condition, or the condition proposed by according to each manufacturer.
When embodiment provides number range, it should be appreciated that except non-invention is otherwise noted, two ends of each number range
Any one numerical value can be selected between point and two end points.Unless otherwise defined, in the present invention all technologies for using and
Scientific terminology is identical with the meaning that those skilled in the art of the present technique are generally understood that.Except used in embodiment specific method, equipment,
Outside material, according to grasp of the those skilled in the art to prior art and the record of the present invention, it can also use and this
Any method, equipment and the material of the similar or equivalent prior art of method, equipment described in inventive embodiments, material come real
The existing present invention.
Specific embodiment 1
A kind of toner and carbon fibre composite, by weight, including 100 parts of carbon cloth, thermal plastic high polymer
30 parts of toner.
Further, in addition to 0.5 part of auxiliary material, wherein：
Every part of auxiliary material includes following raw material components and parts by weight, and (weight that the parts by weight of full text represent with part above is simultaneously
Differ)：
The parts by weight of plasticizer 0.2
The parts by weight of lubricant 0.2
The parts by weight of colouring agent 0.3.
Preferably, auxiliary material also includes calcium carbonate, and calcium carbonate is 0.1 parts by weight in every part of auxiliary material.
Preferably, auxiliary material also includes nucleator, and nucleator is 0.05 parts by weight in every part of auxiliary material.
It is further preferable that plasticizer is ESO.
It is further preferable that lubricant is oxidic polyethylene.
It is highly preferred that stabilizer is organic tin stabilizer.
It is highly preferred that nucleator is zinc oxide.
A kind of toner and carbon fiber composite article, by above-mentioned toner and carbon fibre composite molding
Into.
It is further preferable that toner can serve as vehicle body, wheel hub, collision prevention girders, bumper, seat with carbon fiber composite article
Battery bag.
Specific embodiment 2
A kind of toner and carbon fibre composite, by weight, including 100 parts of carbon cloth, thermal plastic high polymer
300 parts of toner.
Further, in addition to 6 parts of auxiliary material, wherein：
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 2
The parts by weight of lubricant 2
The parts by weight of colouring agent 2.
Preferably, auxiliary material also includes calcium carbonate, and calcium carbonate is 3 parts by weight in every part of auxiliary material.
Preferably, auxiliary material also includes nucleator, and nucleator is 0.2 parts by weight in every part of auxiliary material.
It is further preferable that plasticizer phthalic acid dibutyl ester.
It is further preferable that lubricant is stearate.
It is highly preferred that stearate is zinc stearate.
It is highly preferred that stabilizer is organic tin stabilizer.
It is highly preferred that nucleator is zinc oxide.
A kind of toner and carbon fiber composite article, by above-mentioned toner and carbon fibre composite molding
Into.
It is further preferable that toner can serve as vehicle body, wheel hub, collision prevention girders, bumper, seat with carbon fiber composite article
Battery bag.
Specific embodiment 3
It is roughly the same with specific embodiment 2, differ only in：Stearate is calcium stearate.
Specific embodiment 4
A kind of toner and carbon fibre composite, by weight, including 100 parts of carbon cloth, thermal plastic high polymer
150 parts of toner.
Further, in addition to 3 parts of auxiliary material, wherein：
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 0.9
The parts by weight of lubricant 0.9
The parts by weight of colouring agent 0.95.
Preferably, auxiliary material also includes calcium carbonate, and calcium carbonate is 1.5 parts by weight in every part of auxiliary material.
Preferably, auxiliary material also includes nucleator, and nucleator is 0.1 parts by weight in every part of auxiliary material.
It is further preferable that plasticizer is ESO.
It is further preferable that lubricant is stearate.
It is highly preferred that stearate for etc. quality zinc stearate and calcium stearate.
It is highly preferred that stabilizer is organic tin stabilizer.
It is highly preferred that nucleator is zinc oxide.
A kind of toner and carbon fiber composite article, by above-mentioned toner and carbon fibre composite molding
Into.
It is further preferable that toner can serve as vehicle body, wheel hub, collision prevention girders, bumper, seat with carbon fiber composite article
Battery bag.
Specific embodiment 5
As shown in figure 1, the manufacturing process of a kind of toner and carbon fiber composite article, comprises the following steps:
(1) carbon cloth is cut into the shape of needs according to the size of prefabricated compound car product, is placed in baking oven and heats
To the melt temperature scope of thermoplastic macromolecule resin's powder used；
(2) one layer of thermoplastic macromolecule resin's powder is applied on carbon cloth after the heating, and it is high in thermoplasticity used
Continue heating 3 minutes under the melting temperature of molecule resin, wherein：
The mass ratio of carbon cloth and thermoplastic macromolecule resin's powder is 100：30；
(3) carbon cloth after the completion of step (2) is heated according to the Thickness Strength of prefabricated composite body product is folded
Layer；
(4) carbon cloth after step (3) lamination is placed in the mould of required shape, is molded in forcing press,
Wherein：
Molding pressure 0.1MPa；
Clamp time 5 minutes；
120 DEG C of molding temperature；
(5) pickup is molded, arranges corner, you can obtain toner and carbon fiber composite article.
Further, auxiliary material has uniformly been mixed in thermoplastic macromolecule resin's powder of step (2), wherein：
The mass ratio of carbon cloth, thermoplastic macromolecule resin's powder and auxiliary material is 100：30：0.5；
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 0.2
The parts by weight of lubricant 0.2
The parts by weight of colouring agent 0.3.
Preferably, auxiliary material also includes calcium carbonate, and calcium carbonate is 0.1 parts by weight in every part of auxiliary material.
Preferably, auxiliary material also includes nucleator, and nucleator is 0.05 parts by weight in every part of auxiliary material.
It is further preferable that plasticizer is ESO.
It is further preferable that lubricant is oxidic polyethylene.
It is highly preferred that stabilizer is organic tin stabilizer.
It is highly preferred that nucleator is zinc oxide.
Further, the particle diameter of thermoplastic macromolecule resin's powder in step (2) is 20.
Further, step (2) thermoplastic macromolecule resin's powder is ultra-high molecular weight polyethylene powder.
It is further preferable that the number-average molecular weight of ultra-high molecular weight polyethylene powder is more than 150W.
Further, carbon cloth is plain cloth in step (1).
It is further preferable that monofilament quantity is 3K in fibre bundle in carbon fibre fabric.
Specific embodiment 6
As shown in figure 1, the manufacturing process of a kind of toner and carbon fiber composite article, comprises the following steps:
(1) carbon cloth is cut into the shape of needs according to the size of prefabricated compound car product, is placed on laser heating
It is heated in drying tunnel in the melt temperature scope of thermoplastic macromolecule resin's powder used；
(2) one layer of thermoplastic macromolecule resin's powder is applied on carbon cloth after the heating, and it is high in thermoplasticity used
Continue heating 5 minutes under the melting temperature of molecule resin, wherein：
The mass ratio of carbon cloth and thermoplastic macromolecule resin's powder is 100：300；
(3) carbon cloth after the completion of step (2) is heated according to the Thickness Strength of prefabricated composite body product is folded
Layer；
(4) carbon cloth after step (3) lamination is placed in the mould of required shape, is molded in forcing press,
Wherein：
Molding pressure 100MPa；
Clamp time 1 minute；
20 DEG C of molding temperature；
(5) pickup is molded, arranges corner, you can obtain toner and carbon fiber composite article.
Further, auxiliary material has uniformly been mixed in thermoplastic macromolecule resin's powder of step (2), wherein：
The mass ratio of carbon cloth, thermoplastic macromolecule resin's powder and auxiliary material is 100：300：6；
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 2
The parts by weight of lubricant 2
The parts by weight of colouring agent 2.
Preferably, auxiliary material also includes calcium carbonate, and calcium carbonate is 3 parts by weight in every part of auxiliary material.
Preferably, auxiliary material also includes nucleator, and nucleator is 0.2 parts by weight in every part of auxiliary material.
It is further preferable that plasticizer is dibutyl phthalate.
It is further preferable that lubricant is stearate.
It is highly preferred that stearate is zinc stearate.
It is highly preferred that stabilizer is organic tin stabilizer.
It is highly preferred that nucleator is zinc oxide.
Further, the particle diameter of thermoplastic macromolecule resin's powder in step (2) is 400 mesh.
Further, step (2) thermoplastic macromolecule resin's powder is polypropylene powder.
Further, carbon cloth is twills in step (1).
It is further preferable that monofilament quantity is 6K in fibre bundle in carbon fibre fabric.
Specific embodiment 7
It is roughly the same with specific embodiment 6, differ only in：Stearate is calcium stearate.
Specific embodiment 8
As shown in figure 1, the manufacturing process of a kind of toner and carbon fiber composite article, comprises the following steps:
(1) carbon cloth is cut into the shape of needs according to the size of prefabricated compound car product, is placed in baking oven and heats
To the melt temperature scope of thermoplastic macromolecule resin's powder used；
(2) one layer of thermoplastic macromolecule resin's powder is applied on carbon cloth after the heating, and it is high in thermoplasticity used
Continue heating 4 minutes under the melting temperature of molecule resin, wherein：
The mass ratio of carbon cloth and thermoplastic macromolecule resin's powder is 100：160；
(3) carbon cloth after the completion of step (2) is heated according to the Thickness Strength of prefabricated composite body product is folded
Layer；
(4) carbon cloth after step (3) lamination is placed in the mould of required shape, is molded in forcing press,
Wherein：
Molding pressure 50MPa；
Clamp time 3 minutes；
60 DEG C of molding temperature；
(5) pickup is molded, arranges corner, you can obtain toner and carbon fiber composite article.
Further, auxiliary material has uniformly been mixed in thermoplastic macromolecule resin's powder of step (2), wherein：
The mass ratio of carbon cloth, thermoplastic macromolecule resin's powder and auxiliary material is 100：160：3；
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 0.9
The parts by weight of lubricant 0.9
The parts by weight of colouring agent 0.95.
Preferably, auxiliary material also includes calcium carbonate, and calcium carbonate is 1.5 parts by weight in every part of auxiliary material.
Preferably, auxiliary material also includes nucleator, and nucleator is 0.1 parts by weight in every part of auxiliary material.
It is further preferable that plasticizer is dibutyl phthalate.
It is further preferable that lubricant is stearate.
It is highly preferred that stearate for etc. the zinc stearate of quality and the mixture of calcium stearate.
It is highly preferred that stabilizer is organic tin stabilizer.
It is highly preferred that nucleator is zinc oxide.
Further, the particle diameter of thermoplastic macromolecule resin's powder in step (2) is 200 mesh.
Further, step (2) thermoplastic macromolecule resin's powder is polyvinyl chloride powder.
Further, carbon cloth is satin fabric in step (1).
It is further preferable that monofilament quantity is 12K in fibre bundle in carbon fibre fabric.
Specific embodiment 9
It is roughly the same with specific embodiment 6, differ only in：
Step (2) thermoplastic macromolecule resin's powder is ABS resin powder.
Carbon cloth is one-way fabric in step (1).
Monofilament quantity is 48K in fibre bundle in carbon fibre fabric.
Specific embodiment 10
It is roughly the same with specific embodiment 7, differ only in：
Step (2) thermoplastic macromolecule resin's powder is Polystyrene powder.
Carbon cloth is multilayer multiaxial fabric in step (1).
When carbon cloth is multilayer multiaxial fabric, the multilayer multiaxial fabric is Multi-axial stitch knitting fabric.
Monofilament quantity is 64K in fibre bundle in carbon fibre fabric.
Specific embodiment 11
It is roughly the same with specific embodiment 10 to differ only in：When carbon cloth is multilayer multiaxial fabric, the multilayer
Multi-axial fabric is knitted fabric.
Specific embodiment 12
It is roughly the same with specific embodiment 10 to differ only in：When carbon cloth is multilayer multiaxial fabric, the multilayer
Multi-axial fabric is direct oriented structure fabric.
Specific embodiment 13
It is roughly the same with specific embodiment 8, differ only in：
Step (2) thermoplastic macromolecule resin's powder is polycarbonate powder.
Specific embodiment 14
It is roughly the same with specific embodiment 6, differ only in：
Step (2) thermoplastic macromolecule resin's powder is polycarbonate powder.
Specific embodiment 15
It is roughly the same with specific embodiment 7, differ only in：
Step (2) thermoplastic macromolecule resin's powder is polyamide resin powders.
Specific embodiment 16
It is roughly the same with specific embodiment 8, differ only in：
Step (2) thermoplastic macromolecule resin's powder is polyphenylene sulfide powder.
Specific embodiment 17
It is roughly the same with specific embodiment 7, differ only in：
Step (2) thermoplastic macromolecule resin's powder is polyether-ether-ketone resin powder.
The composite article toner formed using the method in above-described embodiment in the application can be soaked completely with carbon fiber
Profit, the shortcomings that overcoming prior art air is not easy discharge between layers so that the flaw of product is less to produce stress collection
Middle place and influence quality and the use of composite article；Production process is not required to reheating, and production is simple, and cost is low；There is no corner
Material processing, production efficiency are high；It has suffered that leftover pieces in production process are few, and cost is low.Composite article in embodiment 5~17 after tested
Density is between for 1.3~1.8g/cm3Between；Modulus of elasticity is more than 200000MPa；Tensile strength is more than 1500MPa.
The above-described embodiments merely illustrate the principles and effects of the present invention, not for the limitation present invention.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and scope without prejudice to the present invention to above-described embodiment.Cause
This, those of ordinary skill in the art is complete without departing from disclosed spirit and institute under technological thought such as
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (10)
1. a kind of toner and carbon fibre composite, it is characterised in that by weight, including 100 parts of carbon cloth, thermoplastic
30~300 parts of property macromolecule resin powder.
2. a kind of toner according to claim 1 and carbon fibre composite, it is characterised in that also including auxiliary material
0.5~6 part, wherein：
Every part of auxiliary material includes following raw material components and parts by weight：
The parts by weight of plasticizer 0.2~2
The parts by weight of lubricant 0.2~2
The parts by weight of colouring agent 0.3~2.
3. a kind of toner according to claim 2 and carbon fibre composite, it is characterised in that the auxiliary material also wraps
Include the one or more in following characteristics：
The auxiliary material also includes calcium carbonate；Calcium carbonate described in every part of auxiliary material is no more than 3 parts by weight.
4. a kind of toner according to claim 2 and carbon fibre composite, it is characterised in that the auxiliary material also wraps
Include the one or more in following characteristics：
The auxiliary material also includes nucleator；
Nucleator described in every part of auxiliary material is no more than 0.2 parts by weight；
The nucleator is zinc oxide.
5. a kind of toner according to claim 1 and carbon fibre composite, it is characterised in that the composite
Also include the one or more in following characteristics：
The plasticizer is ESO or dibutyl phthalate；
The lubricant is oxidic polyethylene or stearate；
The stearate is selected from one or both of zinc stearate and calcium stearate；
The stabilizer is organic tin stabilizer.
6. a kind of toner according to claim 1 and carbon fibre composite, it is characterised in that the composite
Also include the one or more in following characteristics：
The particle diameter of thermoplastic macromolecule resin's powder is 20~400 mesh；
Thermoplastic macromolecule resin's powder be ultra-high molecular weight polyethylene powder, polypropylene powder, polyvinyl chloride powder,
ABS resin powder, Polystyrene powder, polycarbonate powder, polyamide resin powders, polyphenylene sulfide powder and polyethers ether
One or more in ketone resin powder；
The number-average molecular weight of the ultra-high molecular weight polyethylene powder is more than 150W.
7. a kind of toner according to claim 1 and carbon fibre composite, it is characterised in that the composite
Also include the one or more in following characteristics：
The carbon cloth is plain cloth or twills or satin fabric or one-way fabric or multilayer multiaxial fabric；
Monofilament quantity is 3K or 6K or 12K or 24K or 48K or 64K in fibre bundle in carbon fibre fabric.
8. a kind of toner and carbon fiber composite article, it is characterised in that by above-mentioned toner and carbon fiber composite
Material molding forms.
9. a kind of toner as claimed in claim 5 and carbon fiber composite article, in vehicle body, wheel hub, collision prevention girders, bumper
With the purposes in seat battery bag.
10. the manufacture method of a kind of toner and carbon fiber composite article, it is characterised in that comprise the following steps:
(1) carbon cloth is cut into the shape of needs according to the size of prefabricated compound car product, baking oven is placed on or can continuously add
It is heated in the drying tunnel of heat in the melt temperature scope of thermoplastic macromolecule resin's powder used；
(2) one layer of thermoplastic macromolecule resin's powder is applied on carbon cloth after the heating, and in thermal plastic high polymer used
Continue heating under the melting temperature of resin 3~5 minutes, wherein：
The mass ratio of carbon cloth and thermoplastic macromolecule resin's powder is 100：(30~300)；
(3) carbon cloth after the completion of step (2) is heated according to the Thickness Strength of prefabricated composite body product carries out lamination；
(4) carbon cloth after step (3) lamination is placed in the mould of required shape, be molded in forcing press, wherein：
0.1~100MPa of molding pressure；
Clamp time 1~5 minute；
20~120 DEG C of molding temperature；
(5) pickup is molded, arranges corner, you can obtain toner and carbon fiber composite article.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711047281.6A CN107746586A (en) | 2017-10-31 | 2017-10-31 | A kind of toner and carbon fibre composite, composite article and manufacturing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711047281.6A CN107746586A (en) | 2017-10-31 | 2017-10-31 | A kind of toner and carbon fibre composite, composite article and manufacturing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107746586A true CN107746586A (en) | 2018-03-02 |
Family
ID=61253636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711047281.6A Pending CN107746586A (en) | 2017-10-31 | 2017-10-31 | A kind of toner and carbon fibre composite, composite article and manufacturing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107746586A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359216A (en) * | 2018-03-21 | 2018-08-03 | 吉林省中研高分子材料股份有限公司 | A kind of continuous lod polyether-ether-ketone resin and its forming method |
| CN108948538A (en) * | 2018-06-22 | 2018-12-07 | 苏州上车新材料科技有限公司 | High-strength light-weight automotive wheels cover plate material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906251A (en) * | 2009-06-04 | 2010-12-08 | 上海杰事杰新材料股份有限公司 | Composite material for wind power generator blade and preparation method thereof |
| CN102059768A (en) * | 2009-11-16 | 2011-05-18 | 合肥杰事杰新材料有限公司 | Method for manufacturing all-plastic bicycle frame |
| CN102775622A (en) * | 2012-08-28 | 2012-11-14 | 株洲时代工程塑料制品有限责任公司 | Preparation method and application of fiber-reinforced thermoplastic composite material |
| CN104859158A (en) * | 2015-04-30 | 2015-08-26 | 山东大学 | Preparation method of thermoplastic carbon fiber composite material plate |
-
2017
- 2017-10-31 CN CN201711047281.6A patent/CN107746586A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906251A (en) * | 2009-06-04 | 2010-12-08 | 上海杰事杰新材料股份有限公司 | Composite material for wind power generator blade and preparation method thereof |
| CN102059768A (en) * | 2009-11-16 | 2011-05-18 | 合肥杰事杰新材料有限公司 | Method for manufacturing all-plastic bicycle frame |
| CN102775622A (en) * | 2012-08-28 | 2012-11-14 | 株洲时代工程塑料制品有限责任公司 | Preparation method and application of fiber-reinforced thermoplastic composite material |
| CN104859158A (en) * | 2015-04-30 | 2015-08-26 | 山东大学 | Preparation method of thermoplastic carbon fiber composite material plate |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359216A (en) * | 2018-03-21 | 2018-08-03 | 吉林省中研高分子材料股份有限公司 | A kind of continuous lod polyether-ether-ketone resin and its forming method |
| CN108948538A (en) * | 2018-06-22 | 2018-12-07 | 苏州上车新材料科技有限公司 | High-strength light-weight automotive wheels cover plate material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3395530B1 (en) | Methods for producing structure | |
| CN110435180A (en) | A kind of thermoplastic composite structure and its forming method | |
| JP2015048571A (en) | Molding including carbon fiber and natural fiber, and manufacturing method and use of the same | |
| CN107053703A (en) | Manufacture the method and vehicle component and vehicle of vehicle component | |
| CN101134368A (en) | Thermoplastic composite material sheet produced by wrapping composite fibers and preparation method thereof | |
| CN107746586A (en) | A kind of toner and carbon fibre composite, composite article and manufacturing process | |
| JP2017190439A (en) | Fiber reinforced resin intermediate material and method for producing the same | |
| US11504922B2 (en) | Multi-layered composite structures and methods for the preparation thereof | |
| CN107351469A (en) | Carbon fiber reinforced polymer-based composite board and preparation method thereof | |
| CN207207293U (en) | Carbon fiber reinforced polymer-based composite board | |
| CN106687271A (en) | Method for producing multi-shell composite-material components having an integrated reinforcement structure and multi-shell composite-material components obtained therefrom | |
| CN101733889B (en) | Preparation method of thermoplastic polyimide-based composite material structural member-opening cover | |
| JP2017537005A (en) | Manufacturing method of finished parts | |
| CA3007195C (en) | Hybrid non-woven composite part | |
| Ouali et al. | New biocomposites for lightweight structures and their processes | |
| Mubashir et al. | Carbon fibre composites: Outlook for the automobile sector | |
| Rajak et al. | Manufacturing Technologies of Carbon/Glass Fiber-Reinforced Polymer Composites and Their Properties: A Review. Polymers 2021, 13, 3721 | |
| CN108948538A (en) | High-strength light-weight automotive wheels cover plate material and preparation method thereof | |
| García-Arrieta et al. | Use case 2: thermal recycling of long fibers | |
| Rehkopf | Automotive carbon fiber composites | |
| CN114603878A (en) | Forming method of composite material part with hollow structure | |
| CN102765229A (en) | Compound plastic cloth as well as application and application method thereof | |
| Gorgojo | Recovery and re-use of carbon fibres from recycled end-of-life epoxy based composites | |
| Amar et al. | Experimental Investigation and Weibull Statistical Analysis on Tensile Behaviour of Carbon/Epoxy Composites | |
| Ziegmann et al. | Recent trends in “conventional” manufacturing of composites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180302 |