CN107744635A - A kind of water-based extinguishing agent - Google Patents
A kind of water-based extinguishing agent Download PDFInfo
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- CN107744635A CN107744635A CN201711018045.1A CN201711018045A CN107744635A CN 107744635 A CN107744635 A CN 107744635A CN 201711018045 A CN201711018045 A CN 201711018045A CN 107744635 A CN107744635 A CN 107744635A
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- water
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- extinguishing agent
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 60
- 239000004094 surface-active agent Substances 0.000 claims abstract description 35
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- 230000002528 anti-freeze Effects 0.000 claims abstract description 15
- 239000003063 flame retardant Substances 0.000 claims abstract description 13
- 230000000740 bleeding effect Effects 0.000 claims abstract description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 11
- 239000008104 plant cellulose Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 49
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 20
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 20
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- 239000005696 Diammonium phosphate Substances 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 14
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 230000002950 deficient Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 230000001988 toxicity Effects 0.000 claims description 5
- 231100000419 toxicity Toxicity 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- -1 APG-0810 Chemical compound 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 108010053481 Antifreeze Proteins Proteins 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 3
- 238000007710 freezing Methods 0.000 claims description 3
- 230000008014 freezing Effects 0.000 claims description 3
- 238000001764 infiltration Methods 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 230000005415 magnetization Effects 0.000 claims description 3
- 238000010008 shearing Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 238000009795 derivation Methods 0.000 claims 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 14
- 239000000126 substance Substances 0.000 description 12
- 239000003643 water by type Substances 0.000 description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 description 8
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 8
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 8
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 8
- 235000011130 ammonium sulphate Nutrition 0.000 description 8
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 235000011147 magnesium chloride Nutrition 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 206010003497 Asphyxia Diseases 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- CAMWVBRDIKKGII-UHFFFAOYSA-M n,n-dimethyl-4-(1-methylpyridin-1-ium-4-yl)aniline;iodide Chemical compound [I-].C1=CC(N(C)C)=CC=C1C1=CC=[N+](C)C=C1 CAMWVBRDIKKGII-UHFFFAOYSA-M 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229920000447 polyanionic polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0035—Aqueous solutions
- A62D1/0042—"Wet" water, i.e. containing surfactant
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
- A62D1/0085—Foams containing perfluoroalkyl-terminated surfactant
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
A kind of water-based extinguishing agent, it is included：46 fc-surfactants of environment-friendly type of (1) 0.89 parts by weight；The plant cellulose of (2) 0.02 parts by weight；The inorganic salts of (3) 1.6 parts by weight；The antifreeze of (4) 0.5 parts by weight；The bleeding agent of (5) 0.18 parts by weight；The xanthans of (6) 0.5 parts by weight；The environment friendly flame retardant of (7) 20 parts by weight；The deionized water of (8) 76.31 parts by weight.
Description
Technical field
The present invention relates to a kind of extinguishing chemical, a kind of especially water-based extinguishing agent.
Background technology
Burning condition can be effectively destroyed, the material of fire end is referred to as extinguishing chemical.The extinguishing mechanism master of extinguishing chemical
If cooling, asphyxia, isolation and Chemical Inhibition.The product of the extinguishing chemical manufacturer production produced at present in China market is mostly
BC, ABC dry powder, aerosol, ultra-fine dry powder, aqueous film forming foam, albumen and the common extinguishing chemical of fluorine albumen.Above product extinguishing property
It is small, fire extinguishing object is single, anti-resume combustion performance is weak, and can not go out several special fire simultaneously again, and be limited by temperature in use.
BC, ABC powder extinguishing agent have obvious limitation, and it is not suitable for fire extinguishing system, can only fill all size and do
Powder fire extinguisher, going out, A, B class fire ability are weak, and fire-fighting area is small, and do not possess anti-resume combustion ability.Make in crowded place
With harmful, a large amount of uses can damage the health of people, can make one to suffocate when serious.
Albumen, fluorine albumen and aqueous film forming foam extinguishing chemical are to develop success, albumen and fluorine protein product in the eighties
Color is black stink, puts out a fire single, it is impossible to which go out A, C, E, F class fire, and corrosivity is big, and the shelf-life is short (only 2 years).
Chinese patent once disclosed a kind of extinguishing chemical (200710120280.X), and it is included：Fluorine-containing surfactant, emulsifying agent
Or fatty alcohol, fire retardant, anion surfactant, thickener, urea and water, and optional, antifreezing agent.
Chinese patent once disclosed a kind of environmentally friendly water-based extinguishing agent (201610866037.1), by the main of following weight proportioning
Raw material is prepared：Foaming agent：APG 4-8 parts, interfacial agent：Neopelex 3-6.5 parts, sprawl anti-burning
Agent：Polyethylene glycol 1-3 parts, tackifier：Carboxylic propyl methocel 0.5-1.5 parts, antifreeze：Dimethyl ether 8-16
Part, cosolvent：Urea 3-6.5 parts, wetting agent：Two (2- ethylhexyls) Disodium sulfosuccinate 0.5-1.5 parts, water 43-87 parts.
Chinese patent once disclosed a kind of water-based extinguishing agent (201510770682.9), and it includes inorganic salts 0.5-5%, surface
Activating agent 0.1-1%, foaming agent 0.5-2%, fire retardant 1-20%, antifreeze 10-20%, bleeding agent 0.1-1%, emulsifying agent 1-
2%, water 65-85%.
The content of the invention
It is an object of the invention to provide a kind of environmental protection, efficient, energy-conservation, free of contamination water-based extinguishing agent.
To reach above-mentioned purpose, the solution that the present invention takes is：A kind of water-based extinguishing agent, it is included：
4-6 fc-surfactant of environment-friendly type of (1) 0.89 parts by weight；
The plant cellulose of (2) 0.02 parts by weight；
The inorganic salts of (3) 1.6 parts by weight；
The antifreeze of (4) 0.5 parts by weight；
The bleeding agent of (5) 0.18 parts by weight；
The xanthans of (6) 0.5 parts by weight；
The environment friendly flame retardant of (7) 20 parts by weight；
The deionized water of (8) 76.31 parts by weight.
Described 4-6 fc-surfactant of environment-friendly type belongs to botanical derivative, selected from by 1440,1470,1460,
1157 or their mixtures composition group.
Described plant cellulose belongs to botanical derivative, selected from by lauryl sodium sulfate, CAB, APG-0810, BS-
12nd, the group of KL-30, SLS810 or their mixture composition.
Described inorganic salts are selected from and are made up of ammonium chloride, ammonium sulfate, Diammonium phosphate (DAP), diammonium hydrogen phosphate or their mixture
Group.
Described antifreeze is selected from the group being made up of medical glycerine, medical propane diols, ethylene glycol or their mixture.
Described bleeding agent is selected to be made up of sodium acid carbonate, edible sodium chloride, sodium sulphate, magnesium chloride or their mixtures
Group.
Described xanthans is food-grade, selected from by BP9270, the special TW of fire-fighting, emulsifying agent, APG or they
The group of mixture composition.
Described environment friendly flame retardant is selected from by low-polymerization-dammonium ammonium polyphosphate, APP8123, APP8124 or their mixing
The group of thing composition.
Described deionized water be selected from made of counter-infiltration is equipped pH value be 7.2-7.8, electrical conductivity be≤20 μ S/cm it is pure
Water purification.
A kind of method for preparing above-mentioned water-based extinguishing agent, this method comprise the following steps：
A) 2/3 (8) deionized water adds agitator tank, is warming up to 35 DEG C；
B) dispensing：
1. solid raw material：
(3) inorganic salts+(5) bleeding agent+(6) food-grade xanthan gum+(7) environment friendly flame retardant=mixture A；
2. liquid charging stock：
(2) plant cellulose+(4) antifreeze=mixture B；
(1) 4-6 fc-surfactant+1/3 of environment-friendly type (8) deionized water=mixture C；
C) shearing+emulsification+magnetization+stirring：
Unlatching has added 2/3 (8) deionized water and had warmed up to 35 DEG C of agitator tank, mixing speed and controlled at 50~85 revs/min
Clock, it is slowly added to mixture A, mixture B successively respectively, shears 30 minutes, emulsify 50 minutes, magnetize 1.5 hours, it is last slow
After adding mixture C, it is stirred for 4.5 hours, closes agitator tank；
D) examine：
The product in agitator tank is taken, according to water-based extinguishing agent product standard, detection is according to national standard GB17835-2008《Water system is put out a fire
Agent》, inspection project is：Freezing point, anti-freeze, melt performance, pH value, surface tension, rate of corrosion, toxicity, extinguishing property, the above
Project must be all qualified, is otherwise defective work, to be performed according to defective work processing routine.
Product of the present invention is that S-6-AB (F500) water-based extinguishing agent is a kind of multifunctional water extinguishing chemical, with existing like product
Compare, have the positive effect that：Can be outer with aqueous film forming foam, synthesis and non-fusibility, compatibility is stronger, is not only suitable for various
The fixed of specification, semi-fixed type and portable low-expansion foam fire extinguishing system, can also fill various fire-fighting equipments and various rule
In lattice water base fire extinguishing device；Device is on minipumper and various miniature standby upper, for forest fire, urban architecture tunnel
And ancient building, all reachable prevention fireproof purpose, fire can be put out a fire and eliminate in time when happening suddenly fire by being equipped with the extinguishing chemical
Calamity hidden danger.
Product of the present invention be it is a kind of it is new, efficient, environmentally friendly, multi-functional resist molten cold resisting type water-based extinguishing agent, be in rose by
Deionized water, bleeding agent, antifreeze, environment friendly flame retardant, 4-6 carbon surface active agent of both sexes and other additives composition,
Typically by drop or the liquid extinguisher put out a fire in the form of drop and foams mix.Put out A, B, C, E, F class fire and environmental protection,
Efficiently, take it is convenient substantially harmless to human body and object, it is environmentally safe to biology without overt toxicity liquid extinguisher.Have
Following characteristics：
1. extinguishing property is good, fire extinguishing is quick, big with respect to fire-fighting area.
2. fire-extinguishing function concurrently is complete, complementary performance is good, A, B, C, F class of going out fire (culinary art class vegetable oil fire) and E classes fire (electrically fire
Calamity) from the beginning of fire.
3. extinguishing chemical is without pollution ozone layer material, nontoxic, biodegradable with 100%.
4. suitable for large-scale fixed fire extinguishing system and fire fighting truck, movable type, fixed, fire extinguishing system, can be filled in again various
The water base fire extinguishing device of model.
5. non-secondary pollution after fire extinguishing, easy to clean, leaves no trace.
6. the environment-friendly type antifreeze agent that premixed liquid prepares different ratios can directly use under 0 DEG C~-40 DEG C cold environmental conditions,
Anti- resume combustion performance is superpower after fire extinguishing terminates, and foam is sustainable to be preserved more than 10 hours.
7. environmental protection
1. small toxicity；
2. with biodegradable (to the earth)；
(to air) 3. pollution-free to air.
Embodiment
Specifically, the present invention provides a kind of water-based extinguishing agent, and it is included：4-6 carbon of environment-friendly type of (1) 0.89 parts by weight
Fluorine surfactant；The plant cellulose of (2) 0.02 parts by weight；The inorganic salts of (3) 1.6 parts by weight；(4) 0.5 parts by weight resist
Freeze agent；The bleeding agent of (5) 0.18 parts by weight；The xanthans of (6) 0.5 parts by weight；The environment friendly flame retardant of (7) 20 parts by weight；(8)
76.31 the deionized water of parts by weight.
Wherein described environment-friendly type 4-6 fc-surfactants belong to botanical derivative, selected from by 1440,1470,1460,1157
Or the group of their mixtures composition.1440th, 1470,1460,1157 be amphoteric ion type fc-surfactant, is four respectively
The fc-surfactant of the individual trade mark.
Wherein described plant cellulose belongs to botanical derivative, selected from by lauryl sodium sulfate, CAB, APG-0810, BS-
12nd, the group of KL-30, SLS810 or their mixture composition.
A. wherein described CAB is acetylbutyrylcellulose (Cellulose Acetate Butyrate), is coconut oleoyl amine third
Base glycine betaine.
B. the abbreviation for the Alkyl Polyglycoside that wherein described APG is, APG-0810 are a kind of non-ionic surface actives
Agent, raw material used is the glucose and fatty alcohol being derived by reproducible natural resources, so APG has been
Complete biodegradable, this kind of surfactant has its nontoxic, non-stimulated and outstanding surface-active.
C. wherein described BS-12 is dodecyl-dimethyl amine second lactone, as zwitterionic surfactant, can with it is various
Type dye, surfactant and cosmetic material compatibility, excellent stability, compatibility are respectively provided with acid and alkalescence condition
Property is good.Low to skin irritation, biological degradability is good, has excellent stain removal bactericidal, flexibility, antistatic behaviour, resistance to hard water
Property and rust-preventing characteristic.
D. wherein described KL-30 is a kind of cellulose ether, and be that natural fiber is obtained after chemical modification is a kind of water-soluble
Property good polyanion cellulose compound, be a kind of modified natural polymer, have thickening, it is scattered, suspend, bonding, into
The premium properties such as film, protecting colloid and protection moisture, can be used as thickener, water-loss reducer, adhesive, lubricant, emulsifying agent, suspending
Floating agent, tablet bases, bio-matrix and biological products carrier etc..
D. wherein described SLS810 is anion surfactant, i.e. dialkyl sulfonates.
Wherein described inorganic salts are selected from and are made up of ammonium chloride, ammonium sulfate, Diammonium phosphate (DAP), diammonium hydrogen phosphate or their mixture
Group.
Wherein described antifreeze is selected from the group being made up of medical glycerine, medical propane diols, ethylene glycol or their mixture.
Wherein described bleeding agent is selected to be made up of sodium acid carbonate, edible sodium chloride, sodium sulphate, magnesium chloride or their mixtures
Group.
Wherein described xanthans is food-grade, selected from by BP9270, the special TW of fire-fighting, emulsifying agent, APG or they
The group of mixture composition.
A. wherein described BP9270 is the food-grade xanthan gum of a trade mark.
B. wherein described TW (tween) is polysorbate, is nonionic surface active agent.
Wherein described environment friendly flame retardant is selected from by low-polymerization-dammonium ammonium polyphosphate, APP8123, APP8124 or their mixing
The group of thing composition.Wherein described APP8123 and APP8124 is the random polypropylene of two kinds of trades mark respectively.
Described deionized water be selected from made of counter-infiltration is equipped pH value be 7.2-7.8, electrical conductivity be≤20 μ S/cm it is pure
Water.
Specifically, the present invention provides a kind of preparation method of water-based extinguishing agent, and this method comprises the following steps：a)
The deionized water of 38.95 parts by weight adds agitator tank, is warming up to 35 DEG C；B) dispensing：1. solid raw material：The nothing of 1.6 parts by weight
Environment friendly flame retardant=mixture of the parts by weight of food-grade xanthan gum+35 of the parts by weight of bleeding agent+2.0 of the parts by weight of machine salt+0.3
A；2. liquid charging stock：The antifreeze of the parts by weight of plant cellulose+1.0 of 0.08 parts by weight=mixture B；The ring of 1.6 parts by weight
Deionized water=the mixture C of 4-6 parts by weight of fc-surfactant+19.47 of guarantor's type；C) shearing+emulsification+magnetization+stirring：
Open the deionized water for having added 38.95 parts by weight and have warmed up to 35 DEG C of agitator tank, mixing speed and control 50~85
Rev/min, it is slowly added to mixture A, mixture B successively respectively, shears 30 minutes, emulsifies 50 minutes, magnetizes 1.5 hours, most
After be slowly added to mixture C after, be stirred for 4.5 hours, close agitator tank；D) examine：The product in agitator tank is taken, according to water system
Extinguishing chemical product standard, detection is according to national standard GB17835-2008《Water-based extinguishing agent》, inspection project is：Freezing point, anti-freeze,
Melt performance, pH value, surface tension, rate of corrosion, toxicity, extinguishing property, it is necessary all qualified to begin a project, otherwise to be unqualified
Product, to be performed according to defective work processing routine.
Embodiment 1：
A kind of water-based extinguishing agent, it is included：(1) 0.89Kg fc-surfactants 1440；(2) 0.02Kg dodecyl sulphates
Sodium；(3) 1.6Kg ammonium chlorides；(4) 0.5Kg medical glycerines；(5) 0.18Kg sodium acid carbonates；(6)0.5Kg BP9270；(7)20Kg
Low-polymerization-dammonium ammonium polyphosphate；(8) 76.31Kg deionized waters.
Embodiment 2：
A kind of water-based extinguishing agent, it is included：(1) 0.89Kg fc-surfactants 1470；(2)0.02Kg CAB；(3)1.6Kg
Ammonium sulfate；(4) the medical propane diols of 0.5Kg；(5) 0.18Kg eats sodium chloride；(6) the special TW of 0.5Kg fire-fightings；(7)
20KgAPP8123；(8) 76.31Kg deionized waters.
Embodiment 3：
A kind of water-based extinguishing agent, it is included：(1) 0.89Kg fc-surfactants 1460；(2)0.02Kg APG-0810；(3)
1.6Kg Diammonium phosphate (DAP)；(4) 0.5Kg ethylene glycol；(5) 0.18Kg sodium sulphate；(6) 0.5Kg emulsifying agents；(7)20Kg APP8124；
(8) 76.31Kg deionized waters.
Embodiment 4：
A kind of water-based extinguishing agent, it is included：(1) 0.89Kg fc-surfactants 1157；(2)0.02Kg BS-12；(3)
1.6Kg diammonium hydrogen phosphate；(4) the medical propane diols of 0.3Kg medical glycerines+0.2Kg；(5) 0.18Kg magnesium chlorides；(6) 0.5Kg alkyl
More glucosides；(7) 10Kg low-polymerization-dammonium ammonium polyphosphates+10Kg APP8123；(8) 76.31Kg deionized waters.
Embodiment 5：
A kind of water-based extinguishing agent, it is included：(1) 0.49Kg fc-surfactants 1440+0.40Kg fc-surfactants
1470；(2)0.02Kg SLS810；(3) 1.0Kg ammonium chlorides+0.6Kg ammonium sulfate；(4) the medical propane diols+0.2Kg second two of 0.3Kg
Alcohol；(5) 0.10Kg sodium acid carbonates+0.08Kg eats sodium chloride；(6) the special TW of 0.3Kg BP9270+0.2Kg fire-fightings；(7)10Kg
APP8123+10Kg APP8124；(8) 76.31Kg deionized waters.
Embodiment 6：
A kind of water-based extinguishing agent, it is included：(1) 0.49Kg fc-surfactants 1470+0.40Kg fc-surfactants
1460；(2)0.02Kg KL-30；(3) 1.0Kg ammonium sulfate+0.6Kg Diammonium phosphate (DAP)；(4) 0.2Kg medical glycerines+0.2Kg is medical
Propane diols+0.1Kg ethylene glycol；(5) 0.10Kg eats sodium chloride+0.08Kg sodium sulphate；(6) the special TW+0.2Kg of 0.3Kg fire-fightings
APG；(7) 10Kg low-polymerization-dammonium ammonium polyphosphates+5Kg APP8123+5Kg APP8124；(8) 76.31Kg is without ion
Water.
Embodiment 7：
A kind of water-based extinguishing agent, it is included：(1) 0.49Kg fc-surfactants 1460+0.40Kg fc-surfactants
1157；(2) 0.01Kg lauryl sodium sulfate+0.01Kg CAB；(3) 0.6Kg amine-oxides+0.5Kg ammonium sulfate+0.5Kg phosphoric acid
Two ammoniums；(4) the medical propane diols+0.1Kg ethylene glycol of 0.2Kg medical glycerines+0.2Kg；(5) 0.10Kg sodium sulphate+0.08Kg chlorinations
Magnesium；(6) 0.3Kg emulsifying agents+0.2Kgg APGs；(7) 10Kg low-polymerization-dammonium ammonium polyphosphates+5Kg APP8123+5Kg
APP8124；(8) 76.31Kg deionized waters.
Embodiment 8：
A kind of water-based extinguishing agent, it is included：(1) 0.49Kg fc-surfactants 1440+0.40Kg fc-surfactants
1157；(2) 0.01Kg lauryl sodium sulfate+0.01Kg SLS810；(3) 0.6Kg amine-oxides 1.0Kg diammonium hydrogen phosphates；(4)
0.3Kg medical glycerine+0.2Kg ethylene glycol；(5) 0.10Kg sodium acid carbonates+0.08Kg magnesium chlorides；(6)0.3Kg BP9270+
0.2Kg APGs；(7) 10Kg low-polymerization-dammonium ammonium polyphosphates+10Kg APP81234；(8) 76.31Kg deionized waters.
Embodiment 9：
A kind of water-based extinguishing agent, it is included：(1) 0.30Kg fc-surfactants 1440+0.30Kg fc-surfactants
1470+0.29Kg fc-surfactant 1460；(2) 0.005Kg lauryl sodium sulfate+0.005Kg CAB+0.005Kg
APG-0810+0.005Kg BS-12；(3) 0.3Kg amine-oxides+0.5Kg ammonium sulfate+0.5Kg Diammonium phosphate (DAP)+0.3Kg phosphoric acid hydrogen two
Ammonium；(4) the medical propane diols+0.1Kg ethylene glycol of 0.2Kg medical glycerines+0.2Kg；(5) 0.045Kg sodium acid carbonates+0.045Kg is eaten
With sodium chloride+0.045Kg sodium sulphate+0.045Kg magnesium chlorides；(6) the special TW+0.1Kg emulsifications of 0.2KgBP9270+0.2Kg fire-fightings
Agent；(7) 10Kg low-polymerization-dammonium ammonium polyphosphates+5Kg APP8123+5Kg APP8124；(8) 76.31Kg deionized waters.
Embodiment 10：
A kind of water-based extinguishing agent, it is included：(1) 0.23Kg fc-surfactants 1440+0.23Kg fc-surfactants
1470+0.21Kg fc-surfactant 1460+0.21Kg fc-surfactants 1157；(2) 0.004Kg dodecyl sulphates
Sodium+0.004Kg CAB+0.004Kg APG-0810+0.004Kg BS-12+0.002Kg KL-30+0.002Kg SLS810；
(3) 0.5Kg amine-oxides+0.3Kg ammonium sulfate+0.3Kg Diammonium phosphate (DAP)+0.5Kg diammonium hydrogen phosphates；(4) 0.2Kg medical glycerines+
Medical propane diols+0.1Kg the ethylene glycol of 0.2Kg；(5) 0.045Kg sodium acid carbonates+0.045Kg eats sodium chloride+0.045Kg sulfuric acid
Sodium+0.045Kg magnesium chlorides；(6) the special TW+0.1Kg emulsifying agents of 0.2Kg BP9270+0.2Kg fire-fightings；(7) 10Kg low polymerization degrees
APP+5Kg APP8123+5Kg APP8124；(8) 76.31Kg deionized waters.
Claims (10)
1. a kind of water-based extinguishing agent, it is characterized in that：It is included：
4-6 fc-surfactant of environment-friendly type of (1) 0.89 parts by weight；
The plant cellulose of (2) 0.02 parts by weight；
The inorganic salts of (3) 1.6 parts by weight；
The antifreeze of (4) 0.5 parts by weight；
The bleeding agent of (5) 0.18 parts by weight；
The xanthans of (6) 0.5 parts by weight；
The environment friendly flame retardant of (7) 20 parts by weight；
The deionized water of (8) 76.31 parts by weight.
2. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Live on described 4-6 carbon fluorine surface of environment-friendly type
Property agent belongs to botanical derivative, selected from the group being made up of 1440,1470,1460,1157 or their mixtures.
3. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Described plant cellulose belongs to plant derivation
Thing, selected from what is be made up of lauryl sodium sulfate, CAB, APG-0810, BS-12, KL-30, SLS810 or their mixture
Group.
4. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Described inorganic salts are selected from by ammonium chloride, sulphur
The group that sour ammonium, Diammonium phosphate (DAP), diammonium hydrogen phosphate or their mixture form.
5. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Described antifreeze be selected from by medical glycerine,
The group of medical propane diols, ethylene glycol or their mixture composition.
6. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Described bleeding agent be selected from by sodium acid carbonate,
The group that edible sodium chloride, sodium sulphate, magnesium chloride or their mixtures form.
7. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Described xanthans is food-grade, selected from by
The group that BP9270, the special TW of fire-fighting, emulsifying agent, APG or their mixtures form.
8. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Described environment friendly flame retardant is selected from by oligomeric
The group of right APP, APP8123, APP8124 or their mixture composition.
9. a kind of water-based extinguishing agent according to claim 1, it is characterized in that：Described deionized water is selected from and filled by counter-infiltration
Standby manufactured pH value is 7.2-7.8, electrical conductivity is≤20 μ S/cm pure water.
10. a kind of method for preparing water-based extinguishing agent according to claim 1, it is characterized in that：This method includes following step
Suddenly：
A) 2/3 (8) deionized water adds agitator tank, is warming up to 35 DEG C；
B) dispensing：
1. solid raw material：
(3) inorganic salts+(5) bleeding agent+(6) food-grade xanthan gum+(7) environment friendly flame retardant=mixture A；
2. liquid charging stock：
(2) plant cellulose+(4) antifreeze=mixture B；
(1) 4-6 fc-surfactant+1/3 of environment-friendly type (8) deionized water=mixture C；
C) shearing+emulsification+magnetization+stirring：
Unlatching has added 2/3 (8) deionized water and had warmed up to 35 DEG C of agitator tank, mixing speed and controlled at 50~85 revs/min
Clock, it is slowly added to mixture A, mixture B successively respectively, shears 30 minutes, emulsify 50 minutes, magnetize 1.5 hours, it is last slow
After adding mixture C, it is stirred for 4.5 hours, closes agitator tank；
D) examine：
The product in agitator tank is taken, according to water-based extinguishing agent product standard, detection is according to national standard GB17835-2008《Water system is put out a fire
Agent》, inspection project is：Freezing point, anti-freeze, melt performance, pH value, surface tension, rate of corrosion, toxicity, extinguishing property, the above
Project must be all qualified, is otherwise defective work, to be performed according to defective work processing routine.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110711339A (en) * | 2019-11-13 | 2020-01-21 | 徐州金港起重机制造有限公司 | Water-based fire extinguishing agent capable of extinguishing gasoline fire |
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