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CN107721780A - Powdery explosive density regulator for explosive cladding and preparation method thereof - Google Patents

Powdery explosive density regulator for explosive cladding and preparation method thereof Download PDF

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Publication number
CN107721780A
CN107721780A CN201711142286.7A CN201711142286A CN107721780A CN 107721780 A CN107721780 A CN 107721780A CN 201711142286 A CN201711142286 A CN 201711142286A CN 107721780 A CN107721780 A CN 107721780A
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powder
parts
explosives
perlite
explosive
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Inventor
王乐
邹见宾
李琼
朱荣强
李松元
牛少伟
晁万新
王梅
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Shaanxi Hongqi Industrial Explosive Group Co ltd
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Shaanxi Hongqi Industrial Explosive Group Co ltd
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    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B23/00Compositions characterised by non-explosive or non-thermic constituents
    • C06B23/002Sensitisers or density reducing agents, foam stabilisers, crystal habit modifiers
    • C06B23/003Porous or hollow inert particles
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B23/00Compositions characterised by non-explosive or non-thermic constituents
    • C06B23/002Sensitisers or density reducing agents, foam stabilisers, crystal habit modifiers
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B31/00Compositions containing an inorganic nitrogen-oxygen salt
    • C06B31/28Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种爆炸复合用粉状炸药密度调节剂,所述密度调节剂由以下重量份的一种或多种互配物组成,珍珠岩500~950份、碳粉10~400份、铝粉50~300份、滑石粉30~200份。该密度调节剂选用的原料均为憎水性物质,可有效提高炸药流散性,极大的提高了炸药防潮性能。本发明还公开了一种爆炸复合用粉状炸药密度调节剂的制备方法,将珍珠岩、碳粉、铝粉、滑石粉中一种或多种按重量份投入混料机中,开机混合30~60Min后装入袋中即可。其工艺方法简单,通过该方法制备的密度调节剂质量稳定,可用于改性铵油炸药、多孔粒铵油炸药密度、爆速及流散性调节。The present invention discloses a density regulator for powdered explosives for explosive compounding, which is composed of one or more of the following mutually matching materials in parts by weight: 500-950 parts of perlite, 10-400 parts of carbon powder, 50-300 parts of aluminum powder, and 30-200 parts of talcum powder. The raw materials selected for the density regulator are all hydrophobic substances, which can effectively improve the flowability of explosives and greatly improve the moisture-proof performance of explosives. The present invention also discloses a preparation method for the density regulator for powdered explosives for explosive compounding, wherein one or more of perlite, carbon powder, aluminum powder, and talcum powder are put into a mixer by weight, and the mixture is mixed for 30-60 minutes before being packed into a bag. The process is simple, and the density regulator prepared by the method has stable quality, and can be used for adjusting the density, detonation velocity, and flowability of modified ammonium nitrate oil explosives and porous granular ammonium nitrate oil explosives.

Description

一种爆炸复合用粉状炸药密度调节剂以及制备方法A powdery explosive density regulator for explosive compounding and its preparation method

技术领域technical field

本发明属于金属复合材料生产工艺领域,涉及爆炸复合法用粉状炸药,具体涉及一种爆炸复合用粉状炸药密度调节剂,还涉及一种爆炸复合用粉状炸药密度调节剂的制备方法。The invention belongs to the field of metal composite material production technology, and relates to a powdery explosive for explosive compounding, in particular to a powdery explosive density regulator for explosive compounding, and to a preparation method for the powdery explosive density regulator for explosive compounding.

背景技术Background technique

近年来,随着我国航空航天、船舶重工及汽车等领域的飞速发展,在实际应用中对材料性能的需求也越来越高,层状金属复合材料是将两种或两种以上的金属材料,以一定的排列方式组合,采用一定的加工工艺复合而成,同时具有多种材料的优异性能。层状金属复合材料加工方法主要有爆炸复合法、轧制法、扩散焊接法、爆炸+轧制复合法等,爆炸复合法以其简单的操作工艺、低廉的设备投入、良好的复合效果获得了广大专家学者及市场客户的认可。爆炸复合法制备层状金属复合材料对炸药的性能要求较为特属,一般选用密度、爆速较低的低爆速炸药。在实际应用中,一般采用添加木粉、NaCl来降低炸药密度、爆速,但是该方法会使炸药防潮性能大大降低。In recent years, with the rapid development of my country's aerospace, shipbuilding heavy industry and automobiles, the demand for material performance in practical applications is also increasing. Layered metal composite materials are two or more metal materials , combined in a certain arrangement and compounded by a certain processing technology, and has excellent properties of various materials. The processing methods of layered metal composite materials mainly include explosive cladding method, rolling method, diffusion welding method, explosion + rolling cladding method, etc. Explosive cladding method has gained a lot of attention due to its simple operation process, low equipment investment and good composite effect. Recognized by experts, scholars and market customers. The preparation of layered metal composites by explosive compounding has special requirements on the performance of explosives, and low-detonation-velocity explosives with low density and low detonation velocity are generally used. In practical applications, adding wood flour and NaCl is generally used to reduce the density and detonation velocity of explosives, but this method will greatly reduce the moisture-proof performance of explosives.

发明内容Contents of the invention

本发明解决了现有技术的不足,提供一种爆炸复合用粉状炸药密度调节剂,解决了现有爆炸复合法制备金属复合材料用粉状炸药存在防潮性能低的问题,该密度调节剂选用的原料均为憎水性物质,可有效提高炸药流散性,极大的提高了炸药防潮性能。The present invention solves the deficiencies of the prior art, provides a powdery explosive density regulator for explosive compounding, and solves the problem of low moisture-proof performance of powdery explosives for metal composite materials prepared by the existing explosive compounding method. The density regulator is selected from The raw materials are all hydrophobic substances, which can effectively improve the fluidity of explosives and greatly improve the moisture-proof performance of explosives.

本发明还提供一种爆炸复合用粉状炸药密度调节剂的制备方法,其工艺方法简单,通过该方法制备的密度调节剂质量稳定,可用于改性铵油炸药、多孔粒铵油炸药密度、爆速及流散性调节。The present invention also provides a preparation method of a powdery explosive density regulator for explosive compounding. The process method is simple, and the quality of the density regulator prepared by the method is stable, and can be used for modifying the density of ammonium oil explosives, porous granular ammonium oil explosives, Detonation velocity and fluidity adjustment.

本发明所采用的技术方案是:一种爆炸复合用粉状炸药密度调节剂,所述密度调节剂由珍珠岩、碳粉、铝粉、滑石粉中的一种或多种互配物组成。The technical solution adopted in the present invention is: a powdery explosive density regulator for explosive compounding, the density regulator is composed of one or more intercombinations of perlite, carbon powder, aluminum powder and talcum powder.

优选的,所述密度调节剂由以下重量份的一种或多种互配物组成,珍珠岩500~950份、碳粉10~400份、铝粉50~300份、滑石粉30~200份。Preferably, the density modifier is composed of one or more of the following intercomplexes in parts by weight: 500-950 parts of perlite, 10-400 parts of carbon powder, 50-300 parts of aluminum powder, and 30-200 parts of talc powder .

优选的,所述珍珠岩为憎水性多孔珍珠岩,其颗粒大小为4~100目。Preferably, the perlite is hydrophobic porous perlite with a particle size of 4-100 mesh.

优选的,所述碳粉为工业无烟煤碳破碎而成,其颗粒大小为4~200目。Preferably, the carbon powder is crushed from industrial anthracite coal, and its particle size is 4-200 mesh.

优选的,所述铝粉颗粒大小为20~200目。Preferably, the particle size of the aluminum powder is 20-200 mesh.

进一步优选的,所述滑石粉的颗粒大小为4~200目Further preferably, the particle size of the talc powder is 4-200 mesh

本发明另一种技术方案,一种爆炸复合用粉状炸药密度调节剂的制备方法,将珍珠岩、碳粉、铝粉、滑石粉中一种或多种按重量份投入混料机中,开机混合30~60Min后装入袋中即可。Another technical scheme of the present invention is a preparation method of a powdery explosive density regulator for explosive compounding, in which one or more of perlite, carbon powder, aluminum powder, and talcum powder are put into a mixer by weight, Turn on the machine and mix for 30-60 minutes, then put it into a bag.

相较于现有技术,本发明具有的有益效果:取材方便、工艺简单、质量稳定、成本低廉,可用于改性铵油炸药、多孔粒铵油炸药密度、爆速及流散性调节。通过该密度调节剂可有效降低炸药密度及爆速,提高粉状炸药流散性。Compared with the prior art, the present invention has the beneficial effects of convenient material collection, simple process, stable quality and low cost, and can be used for density, detonation velocity and fluidity adjustment of modified ammonium oil explosives and porous granular ammonium oil explosives. The density regulator can effectively reduce the density and detonation velocity of explosives, and improve the fluidity of powdered explosives.

具体实施方式detailed description

下面结合具体实施方式对本发明进行详细说明。The present invention will be described in detail below in combination with specific embodiments.

一种爆炸复合用粉状炸药密度调节剂,所述密度调节剂由珍珠岩、碳粉、铝粉、滑石粉中的一种或多种互配物组成。A powdered explosive density regulator for explosive compounding, the density regulator is composed of one or more intercombinants of perlite, carbon powder, aluminum powder and talcum powder.

进一步的,所述密度调节剂由以下重量份的一种或多种互配物组成,珍珠岩500~950份、碳粉10~400份、铝粉50~300份、滑石粉30~200份。Further, the density modifier is composed of one or more of the following intercomplexes in parts by weight: 500-950 parts of perlite, 10-400 parts of carbon powder, 50-300 parts of aluminum powder, and 30-200 parts of talc powder .

更进一步的,所述密度调节剂由以下重量份的一种或多种互配物组成,珍珠岩600~850份、碳粉120~300份、铝粉100~200份、滑石粉60~150份。Further, the density regulator is composed of one or more of the following intercomplexes in parts by weight, 600-850 parts of perlite, 120-300 parts of carbon powder, 100-200 parts of aluminum powder, 60-150 parts of talc powder share.

其中,珍珠岩为憎水性多孔珍珠岩,优选其颗粒大小为4~100目。碳粉为工业无烟煤碳破碎而成,优选其颗粒大小为4~200目。铝粉颗粒大小为20~200目。滑石粉优选颗粒大小为4~200目。Among them, the perlite is hydrophobic porous perlite, preferably with a particle size of 4-100 mesh. The carbon powder is produced by crushing industrial anthracite coal, preferably with a particle size of 4-200 mesh. The particle size of the aluminum powder is 20-200 mesh. Talc powder preferably has a particle size of 4-200 mesh.

一种爆炸复合用粉状炸药密度调节剂的制备方法,将珍珠岩、碳粉、铝粉、滑石粉中一种或多种按重量份投入混料机中,开机混合30~60Min后装入袋中即可。A method for preparing a powdery explosive density regulator for explosive compounding. One or more of perlite, carbon powder, aluminum powder, and talc powder are put into a mixer by weight, and mixed for 30 to 60 minutes after starting the machine. Just in the bag.

实施例1Example 1

称取20目的珍珠岩40Kg、50目碳粉5Kg、100目铝粉2Kg、80目滑石粉3Kg,投入混合机中搅拌混合45Min,将混合好的密度调节剂接出。制备470Kg改性铵油炸药,在混料过程中外加30Kg上述密度调节剂,充分混合后接取炸药,测得炸药堆积密度为0.53g/cm3,平均爆速为1997m/s,猛度为9.5mm。Weigh 40Kg of 20-mesh perlite, 5Kg of 50-mesh carbon powder, 2Kg of 100-mesh aluminum powder, and 3Kg of 80-mesh talc powder, put them into a mixer and mix them for 45 minutes, and take out the mixed density regulator. Prepare 470Kg modified ammonium oil explosives, add 30Kg of the above-mentioned density regulator in the mixing process, take the explosives after fully mixing, the bulk density of the explosives is 0.53g/cm3, the average detonation velocity is 1997m/s, and the intensity is 9.5mm .

实施例2Example 2

称取50目的珍珠岩40Kg、80目碳粉5Kg、120目铝粉2Kg、100目滑石粉3Kg,投入混合机中搅拌混合50Min,将混合好的密度调节剂接出。制备480Kg改性铵油炸药,在混料过程中外加20Kg上述密度调节剂,充分混合后接取炸药,测得炸药堆积密度为0.61g/cm3,平均爆速为2352m/s,猛度为11.2mm。Weigh 40Kg of 50-mesh perlite, 5Kg of 80-mesh carbon powder, 2Kg of 120-mesh aluminum powder, and 3Kg of 100-mesh talc powder, put them into the mixer and mix them for 50 minutes, and take out the mixed density regulator. Prepare 480Kg modified ammonium oil explosives, add 20Kg of the above-mentioned density regulator in the mixing process, take the explosives after fully mixing, the bulk density of the explosives is 0.61g/cm3, the average detonation velocity is 2352m/s, and the intensity is 11.2mm .

实施例3Example 3

称取70目的珍珠岩40Kg、100目碳粉3Kg、150目铝粉2Kg、200目滑石粉5Kg,投入混合机中搅拌混合60Min,将混合好的密度调节剂接出。制备470Kg改性铵油炸药,在混料过程中外加30Kg上述密度调节剂,充分混合后接取炸药,测得炸药堆积密度为0.55g/cm3,爆速为1914m/s,猛度为9.3mm。Weigh 40Kg of 70-mesh perlite, 3Kg of 100-mesh carbon powder, 2Kg of 150-mesh aluminum powder, and 5Kg of 200-mesh talc powder, put them into a mixer and mix them for 60 minutes, and take out the mixed density regulator. Prepare 470Kg of modified ammonium oil explosives, add 30Kg of the above-mentioned density regulator in the mixing process, take the explosives after fully mixing, record the bulk density of explosives as 0.55g/cm3, the detonation velocity is 1914m/s, and the intensity is 9.3mm.

上述实施例,只是本发明的较佳实施例,并非用来限制本发明的实施范围,故凡以本发明权利要求所述内容所做的等同变化,均应包括在本发明权利要求范围之内。The above-described embodiments are only preferred embodiments of the present invention, and are not intended to limit the scope of the present invention, so all equivalent changes made with the contents of the claims of the present invention should be included within the scope of the claims of the present invention .

Claims (7)

1. a kind of Explosion composite powder type explosive density adjuster, it is characterised in that the density adjuster is by perlite, carbon One or more interworking things composition in powder, aluminium powder, talcum powder.
2. a kind of Explosion composite powder type explosive density adjuster as claimed in claim 1, it is characterised in that the density is adjusted Section agent is made up of one or more interworking things of following parts by weight, 500~950 parts of perlite, 10~400 parts of carbon dust, aluminium powder 50 ~300 parts, 30~200 parts of talcum powder.
A kind of 3. Explosion composite powder type explosive density adjuster as claimed in claim 2, it is characterised in that the perlite For hydrophobicity expanded perlite, its granular size is 4~100 mesh.
4. a kind of Explosion composite powder type explosive density adjuster as claimed in claim 3, it is characterised in that the carbon dust is Industrial anthracitic coal is broken to be formed, and its granular size is 4~200 mesh.
A kind of 5. Explosion composite powder type explosive density adjuster as claimed in claim 4, it is characterised in that the aluminium powder Grain size is 20~200 mesh.
A kind of 6. Explosion composite powder type explosive density adjuster as claimed in claim 5, it is characterised in that the talcum powder Granular size be 4~200 mesh.
7. a kind of preparation method of the powder type explosive density adjuster of the Explosion composite as described in claim 1 to 6, its feature exist In, put into one or more in perlite, carbon dust, aluminium powder, talcum powder by weight in batch mixer, start mixing 30~ It is fitted into after 60Min in bag.
CN201711142286.7A 2017-11-17 2017-11-17 Powdery explosive density regulator for explosive cladding and preparation method thereof Pending CN107721780A (en)

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CN110343024A (en) * 2019-07-27 2019-10-18 陕西红旗民爆集团股份有限公司 A kind of outdoor type low density modified ammonium nitrate fuel explosive and preparation method
CN115197035A (en) * 2022-07-14 2022-10-18 攀枝花学院 Explosive composite explosive and preparation method thereof
CN116354780A (en) * 2022-12-16 2023-06-30 湖北东神楚天化工有限公司 Powdery explosive for explosion welding and production method thereof

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Publication number Priority date Publication date Assignee Title
CN110343024A (en) * 2019-07-27 2019-10-18 陕西红旗民爆集团股份有限公司 A kind of outdoor type low density modified ammonium nitrate fuel explosive and preparation method
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CN116354780A (en) * 2022-12-16 2023-06-30 湖北东神楚天化工有限公司 Powdery explosive for explosion welding and production method thereof

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Application publication date: 20180223