CN107721387A - A kind of high-performance environment-friendly complex building ceramic material and preparation method thereof - Google Patents
A kind of high-performance environment-friendly complex building ceramic material and preparation method thereof Download PDFInfo
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- CN107721387A CN107721387A CN201711029794.4A CN201711029794A CN107721387A CN 107721387 A CN107721387 A CN 107721387A CN 201711029794 A CN201711029794 A CN 201711029794A CN 107721387 A CN107721387 A CN 107721387A
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- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000000919 ceramic Substances 0.000 claims abstract description 35
- 239000000843 powder Substances 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 17
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011521 glass Substances 0.000 claims abstract description 17
- 239000004579 marble Substances 0.000 claims abstract description 17
- 239000008188 pellet Substances 0.000 claims abstract description 17
- 239000012783 reinforcing fiber Substances 0.000 claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 17
- 239000010703 silicon Substances 0.000 claims abstract description 17
- 238000005245 sintering Methods 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 17
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 16
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 15
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 14
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 14
- 239000004088 foaming agent Substances 0.000 claims description 14
- 239000003349 gelling agent Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000000498 ball milling Methods 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 3
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 3
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000012774 insulation material Substances 0.000 abstract description 12
- 239000002699 waste material Substances 0.000 abstract description 12
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 230000002265 prevention Effects 0.000 abstract description 6
- 238000009435 building construction Methods 0.000 abstract description 5
- 239000002689 soil Substances 0.000 abstract description 4
- 239000004035 construction material Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- -1 glair Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 238000011031 large-scale manufacturing process Methods 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 208000002925 dental caries Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
- C04B33/1322—Red mud
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/36—Glass starting materials for making ceramics, e.g. silica glass
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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- Materials Engineering (AREA)
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- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Finishing Walls (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
It is prepared the invention discloses a kind of high-performance environment-friendly complex building ceramic material and preparation method thereof, including by the raw material of following parts by weight：20 35 parts of shraff fine aggregate, 20 30 parts of marble powder, 15 30 parts of devitrified glass pellet, 10 20 parts of glair, 8 15 parts of silicon ash, 20 35 parts of red mud, 10 12 parts of oyster shell whiting, 11 22 parts of sodium humate, 7 15 parts of magnesium hydroxide, 8 18 parts of acrylate, 5 10 parts of sintering aid, 5 10 parts of reinforcing fiber.Entirety of the invention is made up of ceramic material, and temperature in use is up to 900 DEG C, completely fire prevention, and the high service life length of intensity, alternative existing materials for wall and inflammable insulation material, substantially increases the security of building construction；Ceramic discarded object greatly reduces the production cost of heat-insulating construction material as raw materials for production；Ceramic discarded object takes a large amount of soils, causes environmental pollution, and the present invention realizes the comprehensive utilization to trade waste, energy-conserving and environment-protective, reduce pollution using it as a kind of raw material of industry.
Description
Technical field
The present invention relates to technical field of ceramic preparation, and in particular to a kind of high-performance environment-friendly complex building ceramic material and its
Preparation method.
Background technology
With increasing for the fire disaster accident associated with wall heat insulation material, building field is proposed in external wall outer insulation
Using fire prevention isolation and without ways such as cavitys in system, can so solve organic insulation material combustion characteristics Flame and easily pass
The defects of broadcasting, easily spreading, so as to avoid the fire incident caused by inflammable insulation material triggers flame spread, propagated.But
It is that temperature tolerance of the organic insulation material on wall body structure, flame resistance, and organic guarantor are not researched and solved in fireproof construction
It is molten caused by itself in combustion that adiabator discharges the thermoplasticity such as cigarette poison gas, EPS, XPS organic insulation material in a fire
The problems such as melting, dripping.This means that low fire-protection rating existing for organic insulation material technology, stability and poor durability
Inherent shortcoming has not adapted to requirement of the society to building thermal insulation material.
With social economy and the fast development of ceramic industry, ceramic industry waste material is increasing, and handling these waste materials needs
Substantial amounts of social resources are expended, the sustainable development of development and the ceramic industry of urban economy is limited on partial extent.Mesh
Before, with producing level than relatively low, substantial amounts of waste residue ties up public resource for the processing of China's ceramic industry waste material, make environment by
Pollution.With the increase of ceramics production capacity, the quantity of waste material is more and more, and substantial amounts of shraff fine aggregate has not been letter
Single to fill soluble problem, the accumulation of shraff fine aggregate ties up soil, and fine dust influences the matter of local air
Amount, and the landfill of shraff fine aggregate expends substantial amounts of manpower and materials, goes back polluted underground water matter, how to turn waste into wealth, will make pottery
Porcelain waste material fine aggregate carries out recycling and rationally utilized, and has become the task of top priority of science and technology and environmental administration.
Ceramic material has many advantages, such as, such as elegant in appearance, acid and alkali-resistance, high temperature resistant, adds in commodity, building materials, machinery
The various fields such as work have extensive use.Aluminum oxide and zirconium oxide are two kinds of components common in ceramic material, and aluminum oxide has
The excellent properties such as proportion is low, high temperature resistant, there is extensive use in ceramic material field, but its rupture strength and fracture toughness are relatively low
；Zirconium oxide has good rupture strength, is described as " Ceramo-steel ", but its proportion is larger, it will usually increases the weight of finished product.Oxygen
Change the combination of both zirconium and aluminum oxide, prepare composite ceramic material technology and receive increasing attention.Nickel oxide leads to
It is commonly used for the pigment of ceramic material.
The content of the invention
To solve the above problems, high the invention provides a kind of building waste utilization rate, product water absorption rate is low, antifouling property
High-performance environment-friendly complex building ceramic material good, intensity is high and preparation method thereof.
To achieve the above object, the technical scheme taken of the present invention is：
A kind of high-performance environment-friendly complex building ceramic material and preparation method thereof, including by following parts by weight raw material prepare and
Into：Shraff fine aggregate 20-35 parts, marble powder 20-30 parts, devitrified glass pellet 15-30 parts, glair 10-20 parts, silicon ash
8-15 parts, red mud 20-35 parts, oyster shell whiting 10-12 parts, sodium humate 11-22 parts, magnesium hydroxide 7-15 parts, acrylate 8-18
Part, sintering aid 5-10 parts, reinforcing fiber 5-10 parts, foaming agent 4-8 parts, additional gelling agent 5-9 parts.
Further, a kind of high-performance environment-friendly complex building ceramic material, including by following parts by weight raw material prepare and
Into：Shraff fine aggregate 21-34 parts, marble powder 21-28 parts, devitrified glass pellet 16-27 parts, glair 11-19 parts, silicon ash
9-14 parts, red mud 22-33 parts, oyster shell whiting 11-12 parts, sodium humate 15-20 parts, magnesium hydroxide 8-14 parts, acrylate 9-17
Part, sintering aid 6-8 parts, reinforcing fiber 6-9 parts, foaming agent 5-7 parts, additional gelling agent 6-8 parts.
Further, the glair is the one or more in silica, aluminum oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
Further, a kind of preparation method of high-performance environment-friendly complex building ceramic material, comprises the following steps：
S1, by shraff fine aggregate 21-34 parts, marble powder 21-28 parts, devitrified glass pellet 16-27 parts, silicon ash 8-15
After part, red mud 20-35 parts, the mixing of oyster shell whiting 11-12 parts, after addition pulverizer is crushed, 100-130 mesh screens are crossed, are obtained
To material；
S2, step S1 is obtained to material add water to carry out ball milling, then add glair 11-19 parts, sodium humate 15-20 parts, hydrogen-oxygen
Change magnesium 8-14 parts, acrylate 9-17 parts, sintering aid 6-8 parts, reinforcing fiber 6-9 parts progress wet ball mill 10-20min, repeatedly
Ball milling 2-3 times, obtain ceramic slurry；
S3, add water to stir foaming agent 5-7 parts, additional gelling agent 6-8 parts, be heated up to 30-40 DEG C, stir；It is modified
Solution；
S4, the ceramic slurry obtained by step S2 and step S3 are obtained into modified solution are well mixed, the powder after pressed compact, heat treatment
Mill, 100 mesh sieves are crossed, the compound crossed after shining, which is placed in fireproof die after firing, to be obtained building composite ceramics.
Further, a kind of high-performance environment-friendly complex building ceramic material, including by following parts by weight raw material prepare and
Into：28 parts of shraff fine aggregate, 25 parts of marble powder, 19 parts of devitrified glass pellet, 17 parts of glair, 11 parts of silicon ash, red mud 27
Part, 11 parts of oyster shell whiting, 18 parts of sodium humate, 11 parts of magnesium hydroxide, 15 parts of acrylate, 7 parts of sintering aid, 8 parts of reinforcing fiber,
6 parts of foaming agent, 7 parts of additional gelling agent.
The present invention using shraff fine aggregate, marble powder, devitrified glass pellet, glair, silicon ash, red mud, oyster shell whiting,
Sodium humate, magnesium hydroxide, acrylate, sintering aid, reinforcing fiber effectively match, and obtain building ceramics, use temperature
The high service life length of up to 900 DEG C of degree, completely fire prevention, and intensity, alternative existing materials for wall and inflammable insulation material,
The security enhancing ceramics strength that substantially increases building construction is high, compactness is good, toughness significantly improves, and high temperature resistant and wear-resisting
It is excellent, it can be widely used for the various fields high to strength of materials requirement and use mineral and industrial chemicals.
Entirety of the invention is made up of ceramic material, and temperature in use is up to 900 DEG C, fire prevention, and the high service life of intensity completely
Length, alternative existing materials for wall and inflammable insulation material, substantially increase the security of building construction；Ceramic discarded object
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced；Ceramic discarded object takes a large amount of soils, causes ring
Border is polluted, and the present invention realizes the comprehensive utilization to trade waste, energy-conserving and environment-protective, reduced dirty using it as a kind of raw material of industry
Dye；Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources；Cheap, production
Technique is simple, is adapted to large-scale production.
Embodiment
In order that objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further detailed
Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being prepared by the raw material of following parts by weight：Shraff fine aggregate 20-35 parts, marble powder
20-30 parts, devitrified glass pellet 15-30 parts, glair 10-20 parts, silicon ash 8-15 parts, red mud 20-35 parts, oyster shell whiting 10-12 parts,
Sodium humate 11-22 parts, magnesium hydroxide 7-15 parts, acrylate 8-18 parts, sintering aid 5-10 parts, reinforcing fiber 5-10 parts,
Foaming agent 4-8 parts, additional gelling agent 5-9 parts.
A kind of high-performance environment-friendly complex building ceramic material, including be prepared by the raw material of following parts by weight：Waste ceramic
Expect fine aggregate 21-34 parts, marble powder 21-28 parts, devitrified glass pellet 16-27 parts, glair 11-19 parts, silicon ash 9-14 parts, red
Mud 22-33 parts, oyster shell whiting 11-12 parts, sodium humate 15-20 parts, magnesium hydroxide 8-14 parts, acrylate 9-17 parts, sintering help
Agent 6-8 parts, reinforcing fiber 6-9 parts, foaming agent 5-7 parts, additional gelling agent 6-8 parts.
The glair is the one or more in silica, aluminum oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
A kind of preparation method of high-performance environment-friendly complex building ceramic material, comprises the following steps：
S1, by shraff fine aggregate 21-34 parts, marble powder 21-28 parts, devitrified glass pellet 16-27 parts, silicon ash 8-15
After part, red mud 20-35 parts, the mixing of oyster shell whiting 11-12 parts, after addition pulverizer is crushed, 100-130 mesh screens are crossed, are obtained
To material；
S2, step S1 is obtained to material add water to carry out ball milling, then add glair 11-19 parts, sodium humate 15-20 parts, hydrogen-oxygen
Change magnesium 8-14 parts, acrylate 9-17 parts, sintering aid 6-8 parts, reinforcing fiber 6-9 parts progress wet ball mill 10-20min, repeatedly
Ball milling 2-3 times, obtain ceramic slurry；
S3, add water to stir foaming agent 5-7 parts, additional gelling agent 6-8 parts, be heated up to 30-40 DEG C, stir；It is modified
Solution；
S4, the ceramic slurry obtained by step S2 and step S3 are obtained into modified solution are well mixed, the powder after pressed compact, heat treatment
Mill, 100 mesh sieves are crossed, the compound crossed after shining, which is placed in fireproof die after firing, to be obtained building composite ceramics.
Embodiment 1：
A kind of preparation method of high-performance environment-friendly complex building ceramic material, comprises the following steps：
S1, by 26 parts of shraff fine aggregate, 26 parts of marble powder, 19 parts of devitrified glass pellet, 12 parts of silicon ash, 28 parts of red mud,
After 11 parts of mixing of oyster shell whiting, after addition pulverizer is crushed, 120 mesh screens are crossed, obtain material；
S2, step S1 is obtained to material add water to carry out ball milling, then add 17 parts of glair, 17 parts of sodium humate, magnesium hydroxide 11
7 parts of part, 15 parts of acrylate, 7 parts of sintering aid, reinforcing fiber progress wet ball mill 16min, ball milling 2-3 times repeatedly, obtain ceramics
Slurry；
S3, by 6 parts of foaming agent, 7 parts of additional gelling agent plus water stirring, be heated up to 36 DEG C, stir；Obtain modified solution；
S4, the ceramic slurry obtained by step S2 and step S3 are obtained into modified solution are well mixed, the powder after pressed compact, heat treatment
Mill, 100 mesh sieves are crossed, the compound crossed after shining, which is placed in fireproof die after firing, to be obtained building composite ceramics.
Embodiment 2：
A kind of preparation method of high-performance environment-friendly complex building ceramic material, comprises the following steps：
S1, by 34 parts of shraff fine aggregate, 28 parts of marble powder, 27 parts of devitrified glass pellet, 15 parts of silicon ash, 35 parts of red mud,
After 12 parts of mixing of oyster shell whiting, after addition pulverizer is crushed, 130 mesh screens are crossed, obtain material；
S2, step S1 is obtained to material add water to carry out ball milling, then add 19 parts of glair, 20 parts of sodium humate, magnesium hydroxide 14
9 parts of part, 17 parts of acrylate, 8 parts of sintering aid, reinforcing fiber progress wet ball mill 20min, ball milling 3 times, obtain ceramic slurry repeatedly
Material；
S3, by 7 parts of foaming agent, 8 parts of additional gelling agent plus water stirring, be heated up to 40 DEG C, stir；Obtain modified solution；
S4, the ceramic slurry obtained by step S2 and step S3 are obtained into modified solution are well mixed, the powder after pressed compact, heat treatment
Mill, 100 mesh sieves are crossed, the compound crossed after shining, which is placed in fireproof die after firing, to be obtained building composite ceramics.
Embodiment 3：
A kind of preparation method of high-performance environment-friendly complex building ceramic material, comprises the following steps：
S1, by 21 parts of shraff fine aggregate, 21 parts of marble powder, 16 parts of devitrified glass pellet, 8 parts of silicon ash, 20 parts of red mud, shellfish
After the 11 parts of mixing of shell powder, after addition pulverizer is crushed, 100 mesh screens are crossed, obtain material；
S2, step S1 is obtained to material add water to carry out ball milling, then add 11 parts of glair, 15 parts of sodium humate, magnesium hydroxide 8
6 parts of part, 9 parts of acrylate, 6 parts of sintering aid, reinforcing fiber progress wet ball mill 10min, ball milling 2 times, obtain ceramic slurry repeatedly
Material；
S3, by 5 parts of foaming agent, 6 parts of additional gelling agent plus water stirring, be heated up to 30 DEG C, stir；Obtain modified solution；
S4, the ceramic slurry obtained by step S2 and step S3 are obtained into modified solution are well mixed, the powder after pressed compact, heat treatment
Mill, 100 mesh sieves are crossed, the compound crossed after shining, which is placed in fireproof die after firing, to be obtained building composite ceramics.
The present invention using shraff fine aggregate, marble powder, devitrified glass pellet, glair, silicon ash, red mud, oyster shell whiting,
Sodium humate, magnesium hydroxide, acrylate, sintering aid, reinforcing fiber effectively match, and obtain building ceramics, use temperature
The high service life length of up to 900 DEG C of degree, completely fire prevention, and intensity, alternative existing materials for wall and inflammable insulation material,
The security enhancing ceramics strength that substantially increases building construction is high, compactness is good, toughness significantly improves, and high temperature resistant and wear-resisting
It is excellent, it can be widely used for the various fields high to strength of materials requirement and use mineral and industrial chemicals.
Entirety of the invention is made up of ceramic material, and temperature in use is up to 900 DEG C, fire prevention, and the high service life of intensity completely
Length, alternative existing materials for wall and inflammable insulation material, substantially increase the security of building construction；Ceramic discarded object
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced；Ceramic discarded object takes a large amount of soils, causes ring
Border is polluted, and the present invention realizes the comprehensive utilization to trade waste, energy-conserving and environment-protective, reduced dirty using it as a kind of raw material of industry
Dye；Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources；Cheap, production
Technique is simple, is adapted to large-scale production.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of high-performance environment-friendly complex building ceramic material, it is characterised in that including the raw material preparation by following parts by weight
Into：Shraff fine aggregate 20-35 parts, marble powder 20-30 parts, devitrified glass pellet 15-30 parts, glair 10-20 parts, silicon ash
8-15 parts, red mud 20-35 parts, oyster shell whiting 10-12 parts, sodium humate 11-22 parts, magnesium hydroxide 7-15 parts, acrylate 8-18
Part, sintering aid 5-10 parts, reinforcing fiber 5-10 parts, foaming agent 4-8 parts, additional gelling agent 5-9 parts.
2. a kind of high-performance environment-friendly complex building ceramic material according to claim 1, it is characterised in that including by following
The raw material of parts by weight is prepared：Shraff fine aggregate 21-34 parts, marble powder 21-28 parts, devitrified glass pellet 16-27
Part, glair 11-19 parts, silicon ash 9-14 parts, red mud 22-33 parts, oyster shell whiting 11-12 parts, sodium humate 15-20 parts, magnesium hydroxide
8-14 parts, acrylate 9-17 parts, sintering aid 6-8 parts, reinforcing fiber 6-9 parts, foaming agent 5-7 parts, additional gelling agent 6-8
Part.
3. a kind of high-performance environment-friendly complex building ceramic material according to claim 1, it is characterised in that the glair is
One or more in silica, aluminum oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
A kind of 4. preparation method of high-performance environment-friendly complex building ceramic material according to claim 1, it is characterised in that
Comprise the following steps：
S1, by shraff fine aggregate 21-34 parts, marble powder 21-28 parts, devitrified glass pellet 16-27 parts, silicon ash 8-15
After part, red mud 20-35 parts, the mixing of oyster shell whiting 11-12 parts, after addition pulverizer is crushed, 100-130 mesh screens are crossed, are obtained
To material；
S2, step S1 is obtained to material add water to carry out ball milling, then add glair 11-19 parts, sodium humate 15-20 parts, hydrogen-oxygen
Change magnesium 8-14 parts, acrylate 9-17 parts, sintering aid 6-8 parts, reinforcing fiber 6-9 parts progress wet ball mill 10-20min, repeatedly
Ball milling 2-3 times, obtain ceramic slurry；
S3, add water to stir foaming agent 5-7 parts, additional gelling agent 6-8 parts, be heated up to 30-40 DEG C, stir；It is modified
Solution；
S4, the ceramic slurry obtained by step S2 and step S3 are obtained into modified solution are well mixed, the powder after pressed compact, heat treatment
Mill, 100 mesh sieves are crossed, the compound crossed after shining, which is placed in fireproof die after firing, to be obtained building composite ceramics.
5. a kind of high-performance environment-friendly complex building ceramic material according to claim 1, it is characterised in that including by following
The raw material of parts by weight is prepared：28 parts of shraff fine aggregate, 25 parts of marble powder, 19 parts of devitrified glass pellet, glair 17
Part, 11 parts of silicon ash, 27 parts of red mud, 11 parts of oyster shell whiting, 18 parts of sodium humate, 11 parts of magnesium hydroxide, 15 parts of acrylate, sintering help
7 parts of agent, 8 parts of reinforcing fiber, 6 parts of foaming agent, 7 parts of additional gelling agent.
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| CN111548123A (en) * | 2020-05-15 | 2020-08-18 | 西安工业大学 | a building ceramic material |
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