CN107699149A - A kind of traffic mark sticker - Google Patents
A kind of traffic mark sticker Download PDFInfo
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- CN107699149A CN107699149A CN201710972584.2A CN201710972584A CN107699149A CN 107699149 A CN107699149 A CN 107699149A CN 201710972584 A CN201710972584 A CN 201710972584A CN 107699149 A CN107699149 A CN 107699149A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
- C09J179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09J179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
- E01F9/524—Reflecting elements specially adapted for incorporation in or application to road surface markings
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/576—Traffic lines
- E01F9/578—Traffic lines consisting of preformed elements, e.g. tapes, block-type elements specially designed or arranged to make up a traffic line
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/16—Solid spheres
- C08K7/18—Solid spheres inorganic
- C08K7/20—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2409/00—Presence of diene rubber
- C09J2409/006—Presence of diene rubber in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2479/00—Presence of polyamine or polyimide
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Abstract
The present invention provides a kind of traffic mark sticker, is related to traffic marking field.The traffic mark sticker includes from top to bottom：Reflective skid resistant course, rubber substrate, adhesive-layer and viscose glue protective layer；The viscose glue of the adhesive-layer is made up of following parts by weight：20~30 parts of polyimide resin, 30~50 parts of tackifier, 1~3 part of zinc oxide, 20~30 parts of silicone oil, 0.5~1 part of vulcanization accelerator, 5~10 parts of snake glue.Wherein tackifier are epoxy resin, siloxane oligomer, terpene resin according to according to mass parts 3:2:4 mixture.It can just be affixed to after solving the traffic mark sticker of prior art and needing high-temperature fusion on road, complex operation, cost of manufacture is higher.Obtained traffic mark sticker only needs to throw off viscose glue protective layer when in use, you can affixes to traffic mark sticker on road, easy to operate simple, cost of manufacture is cheap.
Description
Technical field
The present invention relates to traffic marking field, and in particular to a kind of traffic mark sticker and preparation method thereof.
Background technology
Widely used different kinds of roads are handed on the road surface that the public such as highway, town road, public square and parking lot pass through
It is logical to mark (will) line to indicate and guide pedestrian and vehicle to pass through in order.Empty or real pavement marker including different colours and shape
The pavement marker such as lines and different road surface lines, figure, pattern, word, symbol, raised road sign, delineator.These road traffics
In graticule, there is the reflecting road traffic marking of reflex reflection (reflective) performance, due to night under car light irradiation it is more eye-catching, more
Easily by driver it is clear that being thus increasingly taken seriously and being widely used.
In the making of reflecting road traffic marking, reflecting coating and reflective adhesive tape are answered with the most use.Reflective glue
Adhesive tape has easy construction and safety and environmental protection, service life long and the obvious advantages such as using effect is good compared with reflecting coating.Cause
This, in the construction of road traffic marking, the use for progressively increasing pavement reflecting adhesive tape is technology development and social progress
Inevitable outcome.
But the traffic mark sticker of prior art is after high-temperature fusion, it is necessary to can just affix on road, complex operation,
Cost of manufacture is higher.
The content of the invention
(1) technical problem solved
In view of the shortcomings of the prior art, the invention provides a kind of traffic mark sticker and preparation method thereof, solve
The traffic mark sticker of prior art can be just affixed on road after needing high-temperature fusion, complex operation, and cost of manufacture is higher.
(2) technical scheme
To realize object above, the present invention is achieved by the following technical programs：
The present invention provides a kind of traffic mark sticker, and above-mentioned traffic mark sticker includes from top to bottom：It is reflective anti-skidding
Layer, rubber substrate, adhesive-layer and viscose glue protective layer；
The viscose glue of above-mentioned adhesive-layer is made up of following parts by weight：20~30 parts of polyimide resin, tackifier 30~
50 parts, 1~3 part of zinc oxide, 20~30 parts of silicone oil, 0.5~1 part of vulcanization accelerator, 5~10 parts of snake glue；
Above-mentioned tackifier are epoxy resin, siloxane oligomer, terpene resin according to according to mass parts 3:2:4 mixture.
Preferably, above-mentioned reflective overcoat is made up of following parts by weight：1~2 part of fluorescent material, 25~35 parts of glass microballoon,
5~10 parts of antiskid particles, 2~5 parts of pigment, 20~30 parts of polyurethane resin.
Preferably, above-mentioned rubber substrate is made up of following parts by weight：25~35 parts of natural rubber, cis 1-4- polybutadiene
55~65 parts, 1~2 part of antiaging agent, 2~3 parts of vulcanization accelerator, 0.1~0.5 part of stearic acid, 1~2 part of antioxidant.
Preferably, the viscose glue of above-mentioned adhesive-layer is made up of following parts by weight：25 parts of polyimide resin, tackifier
40 parts, 2 parts of zinc oxide, 25 parts of silicone oil, 0.8 part of vulcanization accelerator, 8 parts of snake glue.
Preferably, a diameter of 0.1~0.5mm of above-mentioned microglass bead.
Preferably, above-mentioned anti-skidding grain be diamond dust, quartz sand, cullet sand it is any one or more.
Present invention also offers the preparation method of above-mentioned traffic mark sticker, comprise the following steps：
S1：Rubber substrate is prepared, natural rubber and cis 1-4- polybutadiene are plasticated；Mould to practice in glue after plasticating and add
Enter antiaging agent, vulcanization accelerator, stearic acid, antioxidant to be kneaded；Mixture is transferred in calender, is pressed into surface
Compounded rubber base material with uneven decorative pattern；
S2：Rubber substrate coated thereon fluorescent material, pigment, polyurethane resin composition dope layer, then by glass microballoon
With cunning is evengranular is dispersed in coating surface, reflective skid resistant course is made after baking oven for drying solidification；
S3：Below rubber substrate, carry out gluing using automatic glue spreaders and prepare adhesive-layer；
S4：Traffic mark sticker is made in compound viscose glue protective layer below adhesive-layer.
Preferably, the time of plasticating in above-mentioned steps S1 be 2min, plasticating temperature be 90~100 DEG C.
Preferably, the mixing time in above-mentioned steps S1 be 5min, melting temperature be 100~120 DEG C.
(3) beneficial effect
The invention provides traffic mark sticker and preparation method thereof.Compared with prior art, possess following beneficial to effect
Fruit：
1st, traffic mark sticker of the invention includes from top to bottom：Reflective skid resistant course, rubber substrate, adhesive-layer and viscose glue
Protective layer, wherein adhesive-layer by 20~30 parts of polyimide resin, 30~50 parts of tackifier, 1~3 part of zinc oxide, silicone oil 20~
30 parts, 0.5~1 part of vulcanization accelerator, 5~10 parts of snake glue composition, wherein tackifier are epoxy resin, siloxane oligomer, terpenes
Resin is according to according to mass parts 3:2:4 mixture, obtained traffic mark sticker only need to throw off viscose glue guarantor when in use
Sheath, you can affix to traffic mark sticker on road, easy to operate simple, cost is cheap.
2nd, using rubber as base material arbitrarily bending fold cracking and breakage, and rubber can will not also occur for the present invention
Base material has fine wearability and mechanical strength, avoid because vehicle rolls and caused by damage easy to crack the shortcomings that.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, to the technology in the embodiment of the present invention
Scheme is clearly and completely described, it is clear that and described embodiment is part of the embodiment of the present invention, rather than whole
Embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art are obtained under the premise of creative work is not made
The every other embodiment obtained, belongs to the scope of protection of the invention.
The present invention provides a kind of traffic mark sticker, and above-mentioned traffic mark sticker includes from top to bottom：It is reflective anti-skidding
Layer, rubber substrate, adhesive-layer and viscose glue protective layer；
The viscose glue of above-mentioned adhesive-layer is made up of following parts by weight：20~30 parts of polyimide resin, tackifier 30~
50 parts, 1~3 part of zinc oxide, 20~30 parts of silicone oil, 0.5~1 part of vulcanization accelerator, 5~10 parts of snake glue；
Above-mentioned tackifier are epoxy resin, siloxane oligomer, terpene resin according to according to mass parts 3:2:4 mixture.
The preparation method of above-mentioned adhesive-layer is：
It is put into mill and is kneaded after above-mentioned material is mixed so that mutual scattering and permeating between various materials.Its
Middle mixing time is 20~25 DEG C, and mixing time is 30~120min.
The traffic mark sticker of the embodiment of the present invention includes from top to bottom：Reflective skid resistant course, rubber substrate, adhesive-layer and
Viscose glue protective layer, wherein adhesive-layer are by 20~30 parts of polyimide resin, 30~50 parts of tackifier, 1~3 part of zinc oxide, silicone oil
20~30 parts, 0.5~1 part of vulcanization accelerator, 5~10 parts of snake glue composition, wherein tackifier be epoxy resin, siloxane oligomer,
Terpene resin is according to according to mass parts 3:2:4 mixture, obtained traffic mark sticker only need to throw off when in use viscous
Compound protective layer, you can affix to traffic mark sticker on road, easy to operate simple, cost of manufacture is cheap.
The embodiment of the present invention using rubber be used as base material, can arbitrarily bending fold will not also occur ftracture and breakage, and
Rubber substrate has fine wearability and mechanical strength, avoid because vehicle rolls and caused by damage easy to crack the shortcomings that.
As a preferred mode, above-mentioned reflective overcoat is made up of following parts by weight：1~2 part of fluorescent material, glass
25~35 parts of microballon, 5~10 parts of antiskid particles, 2~5 parts of pigment, 20~30 parts of polyurethane resin.
As a preferred mode, above-mentioned rubber substrate is made up of following parts by weight：It is 25~35 parts of natural rubber, suitable
55~65 parts of formula 1-4- polybutadiene, 1~2 part of antiaging agent, 2~3 parts of vulcanization accelerator, 0.1~0.5 part of stearic acid, antioxygen
1~2 part of agent.
The base material of traffic mark sticker prepared by the embodiment of the present invention employs natural rubber and cis 1-4- polybutadienes
Alkene, it is base material through prolonging the good composite material rubber of strength high toughness made of pressure technique so that traffic mark sticker tool is tough
Property and intensity all there is good performance, cracking and damaged will not also occur even if bending fold.
As a preferred mode, the viscose glue of above-mentioned adhesive-layer is made up of following parts by weight：Polyimide resin
25 parts, 40 parts of tackifier, 2 parts of zinc oxide, 25 parts of silicone oil, 0.8 part of vulcanization accelerator, 8 parts of snake glue.
As a preferred mode, a diameter of 0.1~0.5mm of above-mentioned microglass bead.
As a preferred mode, above-mentioned anti-skidding grain be diamond dust, quartz sand, cullet sand it is any one or more.
The preparation method that the embodiment of the present invention additionally provides above-mentioned traffic mark sticker, comprises the following steps：
S1：Rubber substrate is prepared, natural rubber and cis 1-4- polybutadiene are plasticated；Mould to practice in glue after plasticating and add
Enter antiaging agent, vulcanization accelerator, stearic acid, antioxidant to be kneaded；Mixture is transferred in calender, is pressed into surface
Compounded rubber base material with uneven decorative pattern；
S2：Rubber substrate coated thereon fluorescent material, pigment, polyurethane resin composition dope layer, then by glass microballoon
With cunning is evengranular is dispersed in coating surface, reflective skid resistant course is made after baking oven for drying solidification；
S3：Below rubber substrate, carry out gluing using automatic glue spreaders and prepare adhesive-layer；
S4：Traffic mark sticker is made in compound viscose glue protective layer below adhesive-layer.
As a preferred mode, the time of plasticating in above-mentioned steps S1 be 2min, plasticating temperature be 90~100 DEG C.
As a preferred mode, the mixing time in above-mentioned steps S1 be 5min, melting temperature be 100~120 DEG C.
It is described in detail below by specific embodiment.
Embodiment 1：
S1：Rubber substrate is prepared, 25 parts of natural rubber and cis 55 parts of 1-4- polybutadiene are plasticated, plasticated the time
It it is 90 DEG C for 2min, plasticating temperature；
Mould to practice after plasticating and 1 part of antiaging agent, 2 parts of vulcanization accelerator, 0.1 part of stearic acid, 1 part of antioxidant are added in glue
It is kneaded；Mixture is transferred in calender, is pressed into the compounded rubber base material that surface carries uneven decorative pattern；During mixing
Between be 5min, melting temperature be 100 DEG C.
S2：In 20 parts of 1 part of rubber substrate coated thereon fluorescent material, 2 parts of pigment, polyurethane resin dope layers formed, then
25 parts of 0.1mm glass microballoon and 5 parts of diamond dust are uniformly dispersed in coating surface, are made after baking oven for drying solidification reflective anti-
Slip layer；
S3：Below rubber substrate, carry out gluing using automatic glue spreaders and prepare adhesive-layer；
Viscose glue is made up of following parts by weight：20 parts of polyimide resin, 30~part of tackifier, 1 part of zinc oxide, silicone oil
20 parts, 0.5 part of vulcanization accelerator, 5 parts of snake glue.Wherein tackifier be epoxy resin, siloxane oligomer, terpene resin according to according to
Mass parts 3:2:4 mixture；
S4：Traffic mark sticker is made in compound viscose glue protective layer below adhesive-layer.
Traffic mark sticker is made.The main performance of the traffic mark sticker is tested as shown in table 1.
Embodiment 2：
S1：Rubber substrate is prepared, 35 parts of natural rubber and cis 1-4- polybutadiene 65 are plasticated, the time of plasticating is
2min, plasticating temperature are 100 DEG C；
After plasticating mould practice glue in add 2 parts of antiaging agent, 3 parts of vulcanization accelerator, 0.5 part of stearic acid, 2 parts of antioxidant,
It is kneaded；Mixture is transferred in calender, is pressed into the compounded rubber base material that surface carries uneven decorative pattern；During mixing
Between be 5min, melting temperature be 120 DEG C；
S2：In 30 parts of 2 parts of rubber substrate coated thereon fluorescent material, 5 parts of pigment, polyurethane resin dope layers formed, then
35 parts of 0.2m glass microballoon and 10 parts of diamond dust are uniformly dispersed in coating surface, are made after baking oven for drying solidification reflective anti-
Slip layer；
S3：Below rubber substrate, carry out gluing using automatic glue spreaders and prepare adhesive-layer；
Viscose glue is made up of following parts by weight：3 parts of polyimide resin, 3 parts of 50 zinc oxide of tackifier, 30 parts of silicone oil,
1 part of vulcanization accelerator, 10 parts of snake glue wherein tackifier are epoxy resin, siloxane oligomer, terpene resin according to according to mass parts
3:2:4 mixture；
S4：Traffic mark sticker is made in compound viscose glue protective layer below adhesive-layer.
Traffic mark sticker is made.The main performance of the traffic mark sticker is tested as shown in table 1.
Embodiment 3
S1：Rubber substrate is prepared, 30 parts of natural rubber and cis 60 parts of 1-4- polybutadiene are plasticated, plasticated the time
For 2min, plasticating temperature 95；
Mould to practice after plasticating and 1.5 parts of antiaging agent, 2.5 parts of vulcanization accelerator, 0.3 part of stearic acid, antioxidant are added in glue
Part 1.5 is kneaded；Mixture is transferred in calender, is pressed into the compounded rubber base material that surface carries uneven decorative pattern；
Mixing time is 5min, melting temperature 110.
S2：1.5 parts of rubber substrate coated thereon fluorescent material, 3 parts of pigment, 25 parts of polyurethane resin composition dope layers,
30 parts of 0.2m glass microballoon and 8 parts of diamond dust are uniformly dispersed in coating surface again, are made after baking oven for drying solidification reflective
Skid resistant course；
S3：Below rubber substrate, carry out gluing using automatic glue spreaders and prepare adhesive-layer；
Viscose glue is made up of following parts by weight：3 parts of polyimide resin, 50 parts of tackifier, 2 parts of zinc oxide, silicone oil 25
Part, 0.8 part of vulcanization accelerator, 8 parts of snake glue wherein tackifier are epoxy resin, siloxane oligomer, terpene resin is according to according to matter
Measure part 3:2:4 mixture；
S4：Traffic mark sticker is made in compound viscose glue protective layer below adhesive-layer.
Traffic mark sticker is made.The main performance of the traffic mark sticker is tested as shown in table 1.
The main performance of the traffic mark sticker of table 1
Above-mentioned main performance test, wherein thickness and longitudinal tensile strength detect according to chinese national standard, reflex reflection system
The method for the professional standard that number is worked out according to Chinese transportation portion detects, with FB-94 type reflex reflection performance test (test conditions：See
1.05 ° of measuring angle, 86.5 ° of incidence angle)；And the traffic mark sticker for preparing above-described embodiment carries out alternating bending and folding
It is folded, obvious cracking and breakage is not observed.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic；And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (9)
1. a kind of traffic mark sticker, it is characterised in that the traffic mark sticker includes from top to bottom：It is reflective anti-skidding
Layer, rubber substrate, adhesive-layer and viscose glue protective layer；
The viscose glue of the adhesive-layer is made up of following parts by weight：20~30 parts of polyimide resin, 30~50 parts of tackifier,
1~3 part of zinc oxide, 20~30 parts of silicone oil, 0.5~1 part of vulcanization accelerator, 5~10 parts of snake glue；
The tackifier are epoxy resin, siloxane oligomer, terpene resin according to according to mass parts 3:2:4 mixture.
2. a kind of traffic mark sticker as claimed in claim 1, it is characterised in that the reflective overcoat is by following weight
Part composition：1~2 part of fluorescent material, 25~35 parts of glass microballoon, 5~10 parts of antiskid particles, 2~5 parts of pigment, polyurethane resin 20
~30 parts.
3. a kind of traffic mark sticker as claimed in claim 1, it is characterised in that the rubber substrate is by following parts by weight
Composition：25~35 parts of natural rubber, cis 1-4- polybutadiene 55~65,1~2 part of antiaging agent, 2~3 parts of vulcanization accelerator,
0.1~0.5 part of stearic acid, 1~2 part of antioxidant.
A kind of 4. traffic mark sticker as claimed in claim 1, it is characterised in that the viscose glue of the adhesive-layer by below with
Lower parts by weight composition：25 parts of polyimide resin, 40 parts of tackifier, 2 parts of zinc oxide, 25 parts of silicone oil, 0.8 part of vulcanization accelerator,
8 parts of snake glue.
A kind of 5. traffic mark sticker as claimed in claim 1, it is characterised in that a diameter of the 0.1 of the microglass bead
~0.5mm.
6. a kind of traffic mark sticker as claimed in claim 1, it is characterised in that the anti-skidding grain is diamond dust, quartz
Sand, cullet sand it is any one or more.
A kind of 7. preparation method of traffic mark sticker as described in any one of claim 1~6, it is characterised in that including
Following steps：
S1：Rubber substrate is prepared, natural rubber and cis 1-4- polybutadiene are plasticated；Mould to practice to add in glue after plasticating and prevent
Aging agent, vulcanization accelerator, stearic acid, antioxidant are kneaded；Mixture is transferred in calender, surface is pressed into and carries
The compounded rubber base material of uneven decorative pattern；
S2：Rubber substrate coated thereon fluorescent material, pigment, polyurethane resin composition dope layer, then by glass microballoon and cunning
It is evengranular to be dispersed in coating surface, reflective skid resistant course is made after baking oven for drying solidification；
S3：Below rubber substrate, carry out gluing using automatic glue spreaders and prepare adhesive-layer；
S4：Traffic mark sticker is made in compound viscose glue protective layer below adhesive-layer.
8. the preparation method of traffic mark sticker as claimed in claim 1, it is characterised in that plasticating in the step S1
Time is 2min, plasticating temperature is 90~100 DEG C.
9. the preparation method of traffic mark sticker as claimed in claim 1, it is characterised in that the mixing in the step S1
Time is 5min, melting temperature is 100~120 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710972584.2A CN107699149A (en) | 2017-10-18 | 2017-10-18 | A kind of traffic mark sticker |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710972584.2A CN107699149A (en) | 2017-10-18 | 2017-10-18 | A kind of traffic mark sticker |
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|---|---|
| CN107699149A true CN107699149A (en) | 2018-02-16 |
Family
ID=61181574
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| CN201710972584.2A Pending CN107699149A (en) | 2017-10-18 | 2017-10-18 | A kind of traffic mark sticker |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116144269A (en) * | 2022-12-29 | 2023-05-23 | 浙江兄弟路标涂料有限公司 | Road marking paint with high skid resistance and preparation process thereof |
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