CN107675229A - A kind of high temperature is without nickel hole sealing agent - Google Patents
A kind of high temperature is without nickel hole sealing agent Download PDFInfo
- Publication number
- CN107675229A CN107675229A CN201710903628.6A CN201710903628A CN107675229A CN 107675229 A CN107675229 A CN 107675229A CN 201710903628 A CN201710903628 A CN 201710903628A CN 107675229 A CN107675229 A CN 107675229A
- Authority
- CN
- China
- Prior art keywords
- high temperature
- sealing agent
- hole sealing
- acid
- nickel hole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 238000007789 sealing Methods 0.000 title claims abstract description 55
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 43
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 36
- -1 alcohol compound Chemical class 0.000 claims abstract description 86
- 239000002253 acid Substances 0.000 claims abstract description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 235000019441 ethanol Nutrition 0.000 claims description 27
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 24
- 239000000194 fatty acid Substances 0.000 claims description 24
- 229930195729 fatty acid Natural products 0.000 claims description 24
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000004115 Sodium Silicate Substances 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 11
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 11
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 11
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 5
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical class CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 claims description 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims description 3
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 claims description 3
- UKFQWAVMIMCNEH-UHFFFAOYSA-N 2-ethylpentan-1-ol Chemical class CCCC(CC)CO UKFQWAVMIMCNEH-UHFFFAOYSA-N 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004111 Potassium silicate Substances 0.000 claims description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- 125000003158 alcohol group Chemical group 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229950011392 sorbitan stearate Drugs 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims 1
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229920001281 polyalkylene Polymers 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
- 239000011799 hole material Substances 0.000 description 37
- 239000007769 metal material Substances 0.000 description 13
- YMQSVZAVQMDOHH-UHFFFAOYSA-L S(=O)(=O)([O-])[O-].[Na+].C(CCCCC(C)C)O.[Na+] Chemical compound S(=O)(=O)([O-])[O-].[Na+].C(CCCCC(C)C)O.[Na+] YMQSVZAVQMDOHH-UHFFFAOYSA-L 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 239000002585 base Substances 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 235000002639 sodium chloride Nutrition 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- JYTNGEWJAZCVAN-UHFFFAOYSA-N 2-hexadecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O JYTNGEWJAZCVAN-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 238000012644 addition polymerization Methods 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001868 cobalt Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical group CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 1
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
- 229910001094 6061 aluminium alloy Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 101000598921 Homo sapiens Orexin Proteins 0.000 description 1
- 101001123245 Homo sapiens Protoporphyrinogen oxidase Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 102100029028 Protoporphyrinogen oxidase Human genes 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- CZEYPXHFPYFNTP-UHFFFAOYSA-N [Na].C(CCCCCCCCCCCCCC)C1=C(C=CC=C1)S(=O)(=O)O Chemical compound [Na].C(CCCCCCCCCCCCCC)C1=C(C=CC=C1)S(=O)(=O)O CZEYPXHFPYFNTP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical group [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical group CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical group CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- HSJXWMZKBLUOLQ-UHFFFAOYSA-M potassium;2-dodecylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HSJXWMZKBLUOLQ-UHFFFAOYSA-M 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229960002668 sodium chloride Drugs 0.000 description 1
- URLJMZWTXZTZRR-UHFFFAOYSA-N sodium myristyl sulfate Chemical compound CCCCCCCCCCCCCCOS(O)(=O)=O URLJMZWTXZTZRR-UHFFFAOYSA-N 0.000 description 1
- 229950005425 sodium myristyl sulfate Drugs 0.000 description 1
- ZIGVUIYVPLQEAL-UHFFFAOYSA-M sodium;2-tetradecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O ZIGVUIYVPLQEAL-UHFFFAOYSA-M 0.000 description 1
- RUTSRVMUIGMTHJ-UHFFFAOYSA-M sodium;tetradec-1-ene-1-sulfonate Chemical group [Na+].CCCCCCCCCCCCC=CS([O-])(=O)=O RUTSRVMUIGMTHJ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- KRTNITDCKAVIFI-UHFFFAOYSA-N tridecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KRTNITDCKAVIFI-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/24—Chemical after-treatment
- C25D11/246—Chemical after-treatment for sealing layers
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of high temperature without nickel hole sealing agent, the high temperature is the aqueous solution without nickel hole sealing agent, the high temperature includes 20 50g/L silicate, 10 30g/L surfactant, 10 40g/L hydroxide without nickel hole sealing agent, and 3 15g/L carbon number is 6 10 alcohol compound and 0.1 3g/L sulfydryl aliphatic acid acid ethylhexyl.The high temperature of the present invention has good sealing of hole effect without nickel hole sealing agent.
Description
Technical field
The present invention relates to a kind of high temperature without nickel hole sealing agent.
Background technology
Light metal material, such as aluminium, magnesium, zinc, titanium, aluminium alloy, magnesium alloy, kirsite and titanium alloy etc., there is density
Small, conductive and heat-conductive ability is strong, excellent in mechanical performance and can secondary operation the advantages that, therefore obtained in national economy extensive
Using., generally need to be to light gold but light metal material is typically easily corroded, therefore in order to better profit from light metal material
Category material be surface-treated to avoid light metal material from being corroded, at present using it is more be to light metal material progress anode
Oxidation.
Traditional anode oxidation process flow is：Removing oil-removing wax → chemical polishing → anodic oxidation → sealing of hole → drying is (every
Step all need sufficiently to be washed), when the color to light metal material requires, can before sealing of hole to anodic oxidation after
Light metal material dyed.
The anode oxidation membrane of light metal material is fine and close porous layer, has higher adsorption capacity, is easily adsorbed with
Evil material so as to cause light metal material contaminated or premature corrosion, therefore in order to avoid being contaminated because of absorption harmful substance or
Premature corrosion, sealing pores need to be carried out to the light metal material after anodic oxidation.The closing of aluminium and its alloy anodized film, it is
The nanoscale hole hole on its surface is blocked using method physically or chemically, so as to reduce the porosity of anode oxide film and suction
Attached performance, improve the hardness and decay resistance of anode oxide film.
The aluminium and its method for sealing of alloy anodized film being used both at home and abroad at present mainly have boiling water or high temperature to steam
Vapour hole sealing technology, nickel salt or cobalt salt hole sealing technology and calcium and magnesium salt hole sealing technology.The principle of boiling water or high-temperature steam hole sealing technology
Simply, the closed process of film is exactly the hydro-combination process of aluminum oxide, and operation temperature is the major control factors of speed in a closed circuit, water quality
The outward appearance and speed in a closed circuit of meeting significant impact close membrane, excessive calcium ions and magnesium ions, pore membrane can be made spot occur and close ash, and mistake
More silicate or phosphate can draw up the hydrolysis of film.The shortcomings that this technology is that energy consumption is big and very high to water quality requirement.
Nickel salt or cobalt salt sealing technique usually contain the heavy metal ion such as nickel or cobalt, natural, ecological are endangered serious.It is existing
In technology, main problem is that, hole sealing agent is relatively difficult in more than 20 microns thicker anode oxide films of closing.Seal simultaneously
Stream color is serious when closing organic dye film, and film is easy to change, and product surface has washmarking generation after drying.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of high temperature without nickel hole sealing agent, the high temperature is without nickel sealing of hole
Agent is the aqueous solution, and the high temperature includes 20-50g/L silicate, 10-30g/L surfactant, 10- without nickel hole sealing agent
40g/L hydroxide, 3-15g/L carbon number is 6-10 alcohol compound and 0.1-3g/L sulfydryl aliphatic acid acid
Ethylhexyl.
As a kind of perferred technical scheme, the sulfydryl aliphatic acid acid ethylhexyl is selected from 3- mercaptopropionic acid -2- ethyls
One or more in own ester, thioglycollic acid-2-ethyl hexyl ester, sulfydryl formic acid -2- ethylhexyls.
As a kind of perferred technical scheme, the silicate is selected from one or both of sodium metasilicate, potassium silicate.
As a kind of perferred technical scheme, the hydroxide selection potassium hydroxide, one kind in sodium hydroxide or two
Kind.
As a kind of perferred technical scheme, the carbon number be 6-10 alcohol compound be selected from 2- ethyl butanols,
One or more in 2- ethylpentanols, 2-Ethylhexyl Alcohol, 2- ethyls octanol, 2- ethyl nonyl alcohols.
As a kind of perferred technical scheme, the surfactant is selected from anion surfactant, non-ionic surface
One or both of activating agent.
As a kind of perferred technical scheme, the anion surfactant be selected from polyoxyethylene alkyl ether sulfate salt,
Linear alkylbenzene sulfonate (LAS), alkyl sulfate, alcohol sulfate, secondary paraffin sulfonate, alpha-alkene sulfonate, α-sulfofatty acid esters
One or more in salt, aliphatic acid polyethenoxy ether sulfate, polyoxyethylene alkyl ether carboxylate.
As a kind of perferred technical scheme, the nonionic surfactant be selected from higher alcohol ethylene oxide adduct,
Alkyl phenol ethylene oxide addition product, fatty acid oxidation Addition on ethylene thing, polyol fatty acid ester ethylene oxide adduct, advanced alkane
Base amine ethylene oxide adduct, fatty acid alkanol amides ethylene oxide adduct, Oxidation of Fat and Oils Addition on ethylene thing, polyoxyalkylene are embedding
It is section copolymer, fatty acid glyceride, pentaerythritol fatty ester, sorbitan fatty ester, sucrose fatty ester, polynary
One or more in alcohol alkyl ether, ethyl alcohol amine fatty acid amide.
As a kind of perferred technical scheme, the surfactant is selected from alcohol sulfate and sorbitan fatty acid
The mixture of ester.
The surfactant is selected from the mixture of isooctanol sodium sulphate and sorbitan stearate.
Anode oxide film of the metal material surface thickness higher than 10 microns uses hole sealing agent high temperature hole sealing provided by the invention
Afterwards, metal material also has good surface effect after the salt spray test of the time of 2500 hours, it can be seen that the present invention
High temperature there is good sealing of hole effect without nickel hole sealing agent.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to described further below.
Embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention
The identical implication that art personnel are generally understood that.When contradiction be present, the definition in this specification is defined.
A kind of high temperature is without nickel hole sealing agent, it is characterised in that the high temperature is the aqueous solution without nickel hole sealing agent, and the high temperature is without nickel
Hole sealing agent includes 20-50g/L silicate, 10-30g/L surfactant, 10-40g/L hydroxide, 3-15g/L's
Carbon number is 6-10 alcohol compound and 0.1-3g/L sulfydryl aliphatic acid acid ethylhexyl.
As a preferred embodiment, the sulfydryl aliphatic acid acid ethylhexyl is selected from 3- mercaptopropionic acid -2- ethyls
One or more in own ester, thioglycollic acid-2-ethyl hexyl ester, sulfydryl formic acid -2- ethylhexyls.
As a preferred embodiment, the silicate is selected from one or both of sodium metasilicate, potassium silicate.
As a preferred embodiment, the hydroxide selection potassium hydroxide, one kind in sodium hydroxide or two
Kind.
As a preferred embodiment, the carbon number be 6-10 alcohol compound be selected from 2- ethyl butanols,
One or more in 2- ethylpentanols, 2-Ethylhexyl Alcohol, 2- ethyls octanol, 2- ethyl nonyl alcohols.
As a preferred embodiment, the surfactant is selected from anion surfactant, non-ionic surface
One or both of activating agent.
Anion surfactant:
In the present invention, the anion surfactant does not have other special limitations.For example, can be polyoxyethylene alkyl ether
Sulfate, linear alkylbenzene sulfonate (LAS), alkyl sulfate, alcohol sulfate, secondary paraffin sulfonate, alpha-alkene sulfonate, α-thio
Fatty acid ester salt, aliphatic acid polyethenoxy ether sulfate, polyoxyethylene alkyl ether carboxylate etc..
For example, described linear alkylbenzene sulfonate (LAS) is with the benzene sulfonate that carbon number is 8~16 alkyl or is
Carbon number is 12~16 p alkylphenylaceticacid, it is preferable that has the benzene sulfonic acid that carbon number is 12~16 alkyl
Salt, for example, neopelex, Potassium dodecylbenzenesulfonate, tridecyl benzene sulfonate, myristyl benzene sulfonic acid sodium salt,
Pentadecylbenzene sulfonic acid sodium, cetyl benzenesulfonic acid sodium, hexadecyl diphenyloxide disulfonic acid sodium etc..
In one embodiment, the anion surfactant is cetyl benzenesulfonic acid sodium.
In a kind of preferable implementation, the anion surfactant is hexadecyl diphenyloxide disulfonic acid sodium.
Wherein, p alkylphenylaceticacid has the characteristics that low-temperature water-soluble is excellent, foaminess is moderate, its foam stabilization
Class is poor, is easy to rinse, and washability is far above sodium alkyl benzene sulfonate in wider concentration range.
For example, described alkyl sulfate is with the alkyl sulfate that carbon number is 8~20 alkyl, for example, 12
Alkylsurfuric acid acid sodium, myristyl sulfate acid sodium, hexadecyl hydrosulfate acid sodium etc..
In one embodiment, the anion surfactant is dodecyl sulphate acid sodium.
For example, the alpha-alkene sulfonate for the alkyl that it is 8~20 with carbon number that described alpha-alkene sulfonate, which is, example
Such as, α-benzene sodium sulfonate, α-hexadecylene hydrocarbon sulfonate sodium, α-octadecylene hydrocarbon sulfonate sodium, α-icosa alkene hydrocarbon sulfonate sodium.
In one embodiment, the anion surfactant is sodium tetradecene sulfonate.
For example, the alkyl that it is 8~20 with carbon number that described polyoxyethylene alkyl ether sulfate salt, which is, oxirane
The polyoxyethylene alkyl ether sulfate salt that average addition molal quantity is 1~10.
As a preferred embodiment, described polyoxyethylene alkyl ether carboxylate be with carbon number be 8~
20 alkyl, the polyoxyethylene alkyl ether carboxylate that the average addition molal quantity of oxirane is 1~10.
Make as a preferred embodiment, above anion surfactant one or more kinds of can mix
With.
Nonionic surfactant:
In the present invention, the nonionic surfactant does not have other special limitations, primarily to improving cleaning agent
The material of conformality, is solid can at room temperature, and preferably fusing point is more than 45 DEG C of material.As non-ionic surface active
The example of agent, it can enumerate：Higher alcohol ethylene oxide adduct, alkyl phenol ethylene oxide addition product, fatty acid oxidation ethene add
Into thing, polyol fatty acid ester ethylene oxide adduct, senior alkylamines ethylene oxide adduct, fatty acid alkanol amides oxidation
Addition on ethylene thing, the ethylene oxide adduct of grease, the block copolymer (block of polyoxyethylene polyoxypropylene of polyoxyalkylene
Copolymer, the block copolymer of polyoxyethylene polybutylene, the block copolymer of polyoxyethylene polyoxypropylene polybutylene
Deng), the fatty acid ester of glycerine, the fatty acid ester of pentaerythrite, the fatty acid ester of D-sorbite, sorbitan fatty acid ester,
The fatty acid ester of sucrose, the alkyl ether of polyalcohol, the fatty acid amide of ethyl alcohol amine；And in higher alcohol, alkyl phenol, fat
It is embedding in the compounds containing reactive hydrogen such as acid, polyalcohol, senior alkylamines, fatty acid amide, grease or fatty acid alkanol amides
Section addition polymerization butylene oxide and/or propylene oxide, then copolymer of addition polymerization ethylene oxide generation etc., but be not limited to this
A bit.These may be used alone, can also be two or more kinds in combination.
In the embodiment of some, the nonionic surfactant is the block of polyethylene glycol oxide PPOX
Copolymer, there is following structure：
R-O[(EO)a/(PO)b]-H
Wherein, R represent carbon number be 10~18, the alkyl that preferably carbon number is 12~14；A represents 0~20 number；B tables
Show 0~20 number；Except both a and b are 0 situation.A is preferably 6~15, it is more preferred to which 7~12, b are preferably 0
~10, it is more preferred to 1~5, particularly preferably 1~3.
In the present invention, " EO " refers to oxyethylene group；" PO " refers to oxypropylene group.
As a preferred embodiment, the surfactant is selected from alcohol sulfate and sorbitan fatty acid
The mixture of ester.
As a preferred embodiment, the surfactant is selected from isooctanol sodium sulphate and anhydrosorbitol is hard
The mixture of resin acid ester, the mass ratio of the isooctanol sodium sulphate and sorbitan stearate is 1：1-6.
Hereinafter, the present invention is explained in more detail by embodiment, it should be appreciated that these embodiments are only
It is illustrating and nonrestrictive.If without other explanations, raw materials used is all commercially available.In following each embodiments, unless
Specified otherwise, the solvent of solution used is water.The thickness of film layer is measured with Britain's production TMGII calibrators in embodiment.Implement
The electrostatic coating equipment paint sprayer NDL-Q2 produced in example with the municipal Zhi Jie Electronics Co., Ltd.s in Wuhan carries out spraying colored paint
And finish paint.
The present invention is described in detail referring to several examples.
Metal surface treatment process：
Removing oil-removing wax
The alloy degreasing powder that the aluminum alloy base material of model 6061 is immersed in 40 g/l, temperature is 60 DEG C (is purchased from Shenzhen
The LD-208 alloys degreasing powder of De Sheng Chemical Co., Ltd.s of city) taken out after 5 minutes in solution, clean substrate surface with water
Alloy degreasing powder.
Chemical polishing
It is 200 that metal material after above-mentioned carry out removing oil-removing wax, which is impregnated in by the phosphoric acid and concentration that concentration is 650 g/l,
G/l sulfuric acid composition solution in after chemical polishing 3 seconds, be impregnated in immediately in water to clean the residual of substrate surface
Acid, then base material is impregnated in 10 g/l of sodium hydroxide solution after 8 minutes, is impregnated in cleaning base material table in water immediately
The alkali of the residual in face.
Anodic oxidation
Immersed the base material after above-mentioned carry out pre-treatment as anode in electrolyte, while using stainless steel as negative electrode, make negative electrode
Electrically connected respectively with the positive pole and negative pole of power supply with anode.Using the sulfuric acid by 180 g/l, 8 g/l of aluminum sulfate group
Into solution as electrolyte, regulation DC voltage is 13 volts, carries out anodic oxidation 35 minutes.Substrate surface is measured to be formed
Thickness is the anode oxide film of 25-30 microns.Base material after anodic oxidation is toasted 0.5 hour in 100 DEG C of baking oven.
Sealing of hole
Anodic oxidation film thickness is randomly choosed 5 pieces for the polylith metal base of 25-30 microns, immerses following embodiments and contrast
The hole sealing agent of example（30 times of dilution）, sealing of hole is carried out within lower 10 minutes at 90 degrees Celsius.
Spraying
With spray gun the water that Huzhou Ji Fu new materials Co., Ltd produces is sprayed in the above-mentioned substrate surface carried out after anodic oxidation
Property the UV colored varnishes, then in UV solidification cases with 1000 MJs/square centimeter, wavelength be 360 nanometers ultraviolet away from
Place of 25 centimetres from base material is irradiated from the one side for being coated with the anti-UV colored varnishes completes UV solidifications for 1 minute, measures what is formed
The thickness of top coat layer is 15-20 microns.
Embodiment 1
High temperature is without nickel hole sealing agent：
Sodium metasilicate 30g/L, isooctanol sodium sulphate 8g/L, sorbitan fatty ester 12g/L, sodium hydroxide 25g/L, it is different
Octanol 10g/L, 3- mercaptopropionic acid -2- ethylhexyls 1.5g/L.
Embodiment 2
High temperature is without nickel hole sealing agent：
Sodium metasilicate 35g/L, isooctanol sodium sulphate 8g/L, sorbitan fatty ester 16g/L, sodium hydroxide 25g/L, it is different
Octanol 10g/L, 3- mercaptopropionic acid -2- ethylhexyls 1.2g/L.
Embodiment 3
High temperature is without nickel hole sealing agent：
Sodium metasilicate 40g/L, isooctanol sodium sulphate 4g/L, sorbitan fatty ester 18g/L, sodium hydroxide 25g/L, it is different pungent
Alcohol 10g/L, 3- mercaptopropionic acid -2- ethylhexyls 1g/L.
Embodiment 4
High temperature is without nickel hole sealing agent：
Sodium metasilicate 20g/L, isooctanol sodium sulphate 20g/L, sorbitan fatty ester 10g/L, sodium hydroxide 25g/L, it is different
Octanol 10g/L, 3- mercaptopropionic acid -2- ethylhexyls 3g/L.
Embodiment 5
High temperature is without nickel hole sealing agent：
Sodium metasilicate 50g/L, isooctanol sodium sulphate 1g/L, sorbitan fatty ester 7g/L, sodium hydroxide 25g/L, it is different pungent
Alcohol 10g/L, 3- mercaptopropionic acid -2- ethylhexyls 0.1g/L.
Comparative example 1
High temperature is without nickel hole sealing agent：
Sodium metasilicate 30g/L, isooctanol sodium sulphate 8g/L, sorbitan fatty ester 12g/L, sodium hydroxide 25g/L, it is different
Octanol 10g/L.
Comparative example 2
High temperature is without nickel hole sealing agent：
Sodium metasilicate 30g/L, isooctanol sodium sulphate 8g/L, sorbitan fatty ester 12g/L, sodium hydroxide 25g/L, it is different
Octanol 10g/L, phosphoric acid -2- ethylhexyls 1.5g/L.
Comparative example 3
High temperature is without nickel hole sealing agent：
Nano silicon 30g/L, isooctanol sodium sulphate 8g/L, sorbitan fatty ester 12g/L, sodium hydroxide 25g/
L, isooctanol 10g/L, 3- mercaptopropionic acid -2- ethylhexyls 1.5g/L.
Comparative example 4
High temperature is without nickel hole sealing agent：
Sodium metasilicate 30g/L, isooctanol sodium sulphate 8g/L, sorbitan fatty ester 12g/L, sodium hydroxide 25g/L, second
Alcohol 10g/L, 3- mercaptopropionic acid -2- ethylhexyls 1.5g/L.
Salt spray test：
Corrosion resistance is weighed by salt spray test, and salt spray test method is by 5 piece of 6061 aluminium alloy base of same hole sealing agent sealing of hole
Material is placed in the WY-60D type salt-mist corrosion testers of Dongguan City pairing Electronic Science and Technology Co., Ltd. production, and concentration is used at 35 DEG C
After 5 weight % sodium-chloride water solution splash 16 hours, it is 40 DEG C, phase that base material is placed in into another temperature again after taking-up
In the climatic chamber for being 80% to humidity, base material is observed, is recorded in how long exception occurs in rear substrate surface, the time gets over
It is long, the maximum data and minimum data are removed, and calculate the average of time.
As can be seen that the high temperature hole sealing agent of the present invention has good sealing of hole effect.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.It is every
The equivalent changes and modifications done according to present invention, it is encompassed by the scope of the claims of the present invention.
Claims (10)
1. a kind of high temperature is without nickel hole sealing agent, it is characterised in that the high temperature is the aqueous solution without nickel hole sealing agent, and the high temperature seals without nickel
Hole agent includes 20-50g/L silicate, 10-30g/L surfactant, 10-40g/L hydroxide, 3-15g/L carbon
Atomicity is 6-10 alcohol compound and 0.1-3g/L sulfydryl aliphatic acid acid ethylhexyl.
2. a kind of high temperature according to claim 1 is without nickel hole sealing agent, it is characterised in that the sulfydryl aliphatic acid acid ethyl hexyl
One kind in 3- mercaptopropionic acid -2- ethylhexyls, thioglycollic acid-2-ethyl hexyl ester, sulfydryl formic acid -2- ethylhexyls of ester or
It is several.
3. a kind of high temperature according to claim 2 is without nickel hole sealing agent, it is characterised in that the silicate be selected from sodium metasilicate,
One or both of potassium silicate.
4. a kind of high temperature according to claim 3 is without nickel hole sealing agent, it is characterised in that the hydroxide selects hydroxide
One or both of potassium, sodium hydroxide.
5. a kind of high temperature according to claim 4 is without nickel hole sealing agent, it is characterised in that the carbon number is 6-10 alcohol
One kind in 2- ethyl butanols, 2- ethylpentanols, 2-Ethylhexyl Alcohol, 2- ethyls octanol, 2- ethyl nonyl alcohols of class compound or
It is several.
6. a kind of high temperature according to claim 5 is without nickel hole sealing agent, it is characterised in that the surfactant be selected from it is cloudy from
One or both of sub- surfactant, nonionic surfactant.
7. a kind of high temperature according to claim 6 is without nickel hole sealing agent, it is characterised in that the anion surfactant choosing
Selfpolyoxyethylene alkyl ether sulfate, linear alkylbenzene sulfonate (LAS), alkyl sulfate, alcohol sulfate, secondary paraffin sulfonate, α-alkene
One kind in sulfonated hydrocarbon, α-sulfofatty acid esters salt, aliphatic acid polyethenoxy ether sulfate, polyoxyethylene alkyl ether carboxylate
It is or several.
8. a kind of high temperature according to claim 7 is without nickel hole sealing agent, it is characterised in that the nonionic surfactant choosing
From higher alcohol ethylene oxide adduct, alkyl phenol ethylene oxide addition product, fatty acid oxidation Addition on ethylene thing, polyol fatty acid
Ester ethylene oxide adduct, senior alkylamines ethylene oxide adduct, fatty acid alkanol amides ethylene oxide adduct, grease oxygen
Change Addition on ethylene thing, polyalkylene block copolymers, fatty acid glyceride, pentaerythritol fatty ester, Sorbitan alcohol ester
One or more in fat acid esters, sucrose fatty ester, polyol alkyl ether, ethyl alcohol amine fatty acid amide.
9. a kind of high temperature according to claim 8 is without nickel hole sealing agent, it is characterised in that the surfactant is selected from alcohol sulphur
The mixture of hydrochlorate and sorbitan fatty ester.
10. a kind of high temperature according to claim 9 is without nickel hole sealing agent, it is characterised in that the surfactant is selected from different
The mixture of octanol sodium sulphate and sorbitan stearate.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114717630A (en) * | 2022-03-18 | 2022-07-08 | 江门市优博科技有限公司 | Novel environment-friendly sealing agent for aluminum and aluminum alloy anodic oxide film and preparation method thereof |
| CN115354379A (en) * | 2022-08-16 | 2022-11-18 | 安徽韩铝环保新材料有限公司 | High-temperature nickel-free hole sealing agent and hole sealing process |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3961111A (en) * | 1975-03-18 | 1976-06-01 | Pennwalt Corporation | Method of increasing corrosion resistance of anodized aluminum |
| CN101597784A (en) * | 2008-06-04 | 2009-12-09 | 比亚迪股份有限公司 | A kind of method for sealing of anode oxide film of light metal material |
| CN103215630A (en) * | 2013-04-23 | 2013-07-24 | 沈阳理工大学 | Method for sealing aluminum alloy anode oxide film pore by adopting organic-inorganic composite silica sol |
| CN103590086A (en) * | 2013-11-14 | 2014-02-19 | 佛山市三水雄鹰铝表面技术创新中心有限公司 | Nickel-free hole sealing agent for aluminum alloy and hole sealing treatment process of agent |
| CN104862762A (en) * | 2015-04-27 | 2015-08-26 | 武汉菲尼克化学有限公司 | Aluminum or aluminum alloy anode oxide film hole sealing treatment method |
| CN105088311A (en) * | 2015-08-06 | 2015-11-25 | 深圳前海艾丽优科技有限公司 | Aluminum alloy nickel-free environment-friendly hole sealing agent |
| US20160152839A1 (en) * | 2014-11-28 | 2016-06-02 | Catcher Technology Co., Ltd. | Antimicrobial complex surface and method for forming the same |
| CN106400085A (en) * | 2016-06-21 | 2017-02-15 | 武汉风帆电化科技股份有限公司 | Hole sealing agent and method for aluminum and aluminum alloy anode oxide film aftertreatment |
| CN106637338A (en) * | 2016-12-06 | 2017-05-10 | 上海英汇科技发展有限公司 | Anodic oxidation process for automobile aluminum alloy baggage holders |
-
2017
- 2017-09-29 CN CN201710903628.6A patent/CN107675229B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3961111A (en) * | 1975-03-18 | 1976-06-01 | Pennwalt Corporation | Method of increasing corrosion resistance of anodized aluminum |
| CN101597784A (en) * | 2008-06-04 | 2009-12-09 | 比亚迪股份有限公司 | A kind of method for sealing of anode oxide film of light metal material |
| CN103215630A (en) * | 2013-04-23 | 2013-07-24 | 沈阳理工大学 | Method for sealing aluminum alloy anode oxide film pore by adopting organic-inorganic composite silica sol |
| CN103590086A (en) * | 2013-11-14 | 2014-02-19 | 佛山市三水雄鹰铝表面技术创新中心有限公司 | Nickel-free hole sealing agent for aluminum alloy and hole sealing treatment process of agent |
| US20160152839A1 (en) * | 2014-11-28 | 2016-06-02 | Catcher Technology Co., Ltd. | Antimicrobial complex surface and method for forming the same |
| CN104862762A (en) * | 2015-04-27 | 2015-08-26 | 武汉菲尼克化学有限公司 | Aluminum or aluminum alloy anode oxide film hole sealing treatment method |
| CN105088311A (en) * | 2015-08-06 | 2015-11-25 | 深圳前海艾丽优科技有限公司 | Aluminum alloy nickel-free environment-friendly hole sealing agent |
| CN106400085A (en) * | 2016-06-21 | 2017-02-15 | 武汉风帆电化科技股份有限公司 | Hole sealing agent and method for aluminum and aluminum alloy anode oxide film aftertreatment |
| CN106637338A (en) * | 2016-12-06 | 2017-05-10 | 上海英汇科技发展有限公司 | Anodic oxidation process for automobile aluminum alloy baggage holders |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114717630A (en) * | 2022-03-18 | 2022-07-08 | 江门市优博科技有限公司 | Novel environment-friendly sealing agent for aluminum and aluminum alloy anodic oxide film and preparation method thereof |
| CN114717630B (en) * | 2022-03-18 | 2024-05-10 | 江门市优博科技有限公司 | Environment-friendly sealing agent for aluminum and aluminum alloy anodic oxide film and preparation method thereof |
| CN115354379A (en) * | 2022-08-16 | 2022-11-18 | 安徽韩铝环保新材料有限公司 | High-temperature nickel-free hole sealing agent and hole sealing process |
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|---|---|
| CN107675229B (en) | 2020-02-14 |
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