CN107652822A - A kind of aqueous colorful art coatings and preparation method thereof - Google Patents
A kind of aqueous colorful art coatings and preparation method thereof Download PDFInfo
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- CN107652822A CN107652822A CN201710942433.2A CN201710942433A CN107652822A CN 107652822 A CN107652822 A CN 107652822A CN 201710942433 A CN201710942433 A CN 201710942433A CN 107652822 A CN107652822 A CN 107652822A
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- 238000000576 coating method Methods 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 75
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000008367 deionised water Substances 0.000 claims abstract description 62
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 62
- 239000000843 powder Substances 0.000 claims abstract description 42
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 35
- 239000000839 emulsion Substances 0.000 claims abstract description 33
- 239000002105 nanoparticle Substances 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000013530 defoamer Substances 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 27
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 25
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 15
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 15
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 15
- -1 Lauryl Alcohol ester Chemical class 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 15
- 239000003086 colorant Substances 0.000 claims abstract description 15
- 239000003063 flame retardant Substances 0.000 claims abstract description 15
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 15
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 238000005406 washing Methods 0.000 claims description 22
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 12
- 229910021536 Zeolite Inorganic materials 0.000 claims description 11
- 239000010457 zeolite Substances 0.000 claims description 11
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 235000007164 Oryza sativa Nutrition 0.000 claims description 6
- 235000009566 rice Nutrition 0.000 claims description 6
- 238000004062 sedimentation Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 230000000505 pernicious effect Effects 0.000 abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 18
- 239000012752 auxiliary agent Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 241000209094 Oryza Species 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/324—Alkali metal phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to technical field of coatings, specifically a kind of aqueous colorful art coatings and preparation method thereof, including component A, component B, component C, its mass ratio are 2：1.5：1；The component A includes following raw material：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin carried titanium dioxide nano-particle, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, the multifunctional assistants of AMP 95, colorant, ethylene glycol ethyl ether, alkide resin emulsion, deionized water；The component B includes following raw material：Defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, the multifunctional assistants of AMP 95, ethylene glycol ethyl ether, silicone acrylic emulsion, deionized water；The component C includes following raw material：Protect rubber powder, deionized water.The colorful art coatings of the present invention are on the basis of with good water-fast, weatherability, adhesion property, additionally it is possible to adsorb the pernicious gas and peculiar smell in air, purify air.
Description
Technical field
The invention belongs to technical field of coatings, specifically a kind of aqueous colorful art coatings and preparation method thereof.
Background technology
Art coatings are a kind of new wall decoration art paints, and it is also climing by Europe originating from Europe, advanced technique
Prolong and come, it is welcomed by the people again with its novel decorated style, unusual decorative effect into after domestic market
And high praise.Art coatings not only overcome that emulsion paint color is single, and no stereovision and wallpaper are easy to change, alice, foaming, connect
Seam, the shortcomings that short life；And again there is emulsion paint easily to construct, the advantages of long lifespan and wallpaper design is exquisite, good decorating effect
The advantages of, it is high-tech product the advantages of integrating emulsion paint and wallpaper, therefore be widely used in interior decoration.
With the continuous improvement of living standards of the people, indoor environment is particularly important to the health of people, especially public
The environment in place enjoys people to pay close attention to altogether, as the movements of population such as hospital, school, hotel and intensive place are it is necessary to regular
Interior is carried out disinfection, reduces bacteria breed, so as to ensure that the air of people is that health is pure and fresh.But at present on the market
The function of art coatings is relatively simple, uses it for house ornamentation, for the pernicious gas such as formaldehyde, benzene caused by finishing without net
Change acts on.Therefore, developing a kind of art coatings that can effectively purify the air of a room has the wide market demand capacity.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide a kind of aqueous colorful art coatings and its preparation side
Method, it can effectively purify air.
The invention provides a kind of aqueous colorful art coatings, including component A, component B, component C, its mass ratio is 2：
1.5：1；
The component A includes following raw material：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin load two
Titanium oxide nanoparticles, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-
95 multifunctional assistants, colorant, ethylene glycol ethyl ether, alkide resin emulsion, deionized water；
The component B includes following raw material：Defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 are multi-functional
Auxiliary agent, ethylene glycol ethyl ether, silicone acrylic emulsion, deionized water；
The component C includes following raw material：Protect rubber powder, deionized water.
Preferably, the component A includes the raw material of following parts by weight：Sodium tripolyphosphate 0.5-0.8 parts, defoamer 0.2-
0.4 part, fire retardant 0.1-0.3 parts, pH adjusting agent 0.2-0.3 parts, cyclodextrin carried titanium dioxide nano-particle 1-3 parts, change
Property zeolite powder 3-5 parts, calcined kaolin 5-8 parts, inorganic water-proof impervious agent 0.4-0.8 parts, hydroxyethyl cellulose 0.5-0.8 parts,
Propane diols 1-2 parts, AMP-95 multifunctional assistant 0.3-0.5 parts, colorant 1-5 parts, ethylene glycol ethyl ether 1-2 parts, alkide resin emulsion
25-30 parts, deionized water 25-30 parts.
Preferably, the preparation method of the cyclodextrin carried titanium dioxide nano-particle is as follows：By titanium dioxide nano granule
Son is added in 10% sodium hydroxide solution, then adds beta-schardinger dextrin thereto, is stirred, ultrasonic disperse, centrifugation
Sedimentation, deionized water washing, gained solid matter is dried in vacuo, produced.
Preferably, the mass volume ratio of the titanium dioxide nano-particle and sodium hydroxide solution is 1g：10-15mL, it is excellent
Selection of land, the mass ratio of the titanium dioxide nano-particle and beta-schardinger dextrin is 1：7-10.
Preferably, the ultrasonic power is 600-800W, ultrasonic time 10-20min.
Preferably, the preparation method of the modified zeolite powder is as follows：Zeolite is crushed, microwave heating, is then added to salt
Soak, filter in acid solution, washing, be added into sodium chloride solution and soak, filter, washing, produce.
Preferably, the preparation method of the modified zeolite powder is as follows：Zeolite is crushed, microwave heating, the work(of microwave heating
Rate is 1000-1200W, heat time 1-3min, is then added in 10% hydrochloric acid solution and soaks 1-2h, filter, go from
Sub- water washing, it is added into 10% sodium chloride solution and soaks 40-60min, filter, deionized water washing, produces.
Preferably, the component B includes the raw material of following parts by weight：Defoamer 0.1-0.3 parts, inorganic water-proof impervious agent
0.3-0.5 parts, Lauryl Alcohol ester 2-3 parts, AMP-95 multifunctional assistant 0.3-0.5 parts, ethylene glycol ethyl ether 1-2 parts, silicone acrylic emulsion
68-75 parts, deionized water 20-25 parts.
Preferably, the component C includes the raw material of following parts by weight：Protect rubber powder 6-8 parts, deionized water 92-94 parts.
The invention also discloses the preparation method of above-mentioned aqueous colorful art coatings, comprise the following steps：
1) prepared by component A：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin carried titanium dioxide are received
Rice corpuscles, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-95 are multi-functional
Auxiliary agent, colorant, ethylene glycol ethyl ether, alkide resin emulsion are added sequentially in deionized water, are stirred with 1300-1500r/min rotating speeds
Mix 20-30min；
2) prepared by component B：By defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 multifunctional assistants, second two
Alcohol ether, silicone acrylic emulsion are added in deionized water, and 15-25min is stirred with 800-1000r/min rotating speed；
3) prepared by component C：Protection rubber powder is added in deionized water, 10- is stirred with 600-800r/min rotating speed
20min；
4) coating preparation：Component A, component B and component C are mixed in proportion, 20-30min is stirred, produces.
Titanium dioxide has photocatalysis characteristic in the present invention, and nontoxic, therefore is widely used in the side such as gas purification, antibacterial
Face, but because titanium dioxide nano-particle particle diameter is smaller, be directly appended in coating, its photocatalysis effect is unstable
And it is poor, using cyclodextrin carried titanium dioxide nano-particle, its stability is effectively improved, in the presence of ordinary light source,
Catalytic organism is decomposed into water and carbon dioxide by cyclodextrin carried titanium dioxide nano-particle can, can effectively be removed smelly
Taste, formaldehyde and ammonia, and increase the pollution resistance of material surface；Using modified zeolite powder as aggregates, its opening structure can
Pernicious gas in air etc. is adsorbed well, and by zeolite powder after microwave irradiation, then after acidleach, salt leaching, its hole leads to
Road is opened, and further improves its adsorption capacity；Other compositions in the present invention mutually act synergistically so that the colorful art
Coating has good water resistance, weatherability, tack, pollution resistance, and it is ornamental strong.
Compared with prior art, beneficial effects of the present invention are：Colorful art coatings are made with good in the present invention
On the basis of the finishing performance such as water-fast, weatherability, adhesion property, additionally it is possible to adsorb the pernicious gas and peculiar smell in air, only
Change air, improve indoor environment, improve the life living quality of people, and the coating is nonpoisonous and tasteless, there are good popularization and application
Value.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only part of the embodiment of the present invention to apply example, rather than whole embodiments.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under the premise of creative work is not made, belongs to guarantor of the present invention
The scope of shield.
Embodiment 1
The invention provides a kind of aqueous colorful art coatings, including component A, component B, component C, its mass ratio is 2：
1.5：1；
The component A includes the raw material of following parts by weight：0.5 part of sodium tripolyphosphate, 0.4 part of defoamer, fire retardant 0.1
Part, 0.3 part of pH adjusting agent, 1 part of cyclodextrin carried titanium dioxide nano-particle, 5 parts of modified zeolite powder, 5 parts of calcined kaolin,
0.8 part of inorganic water-proof impervious agent, 0.5 part of hydroxyethyl cellulose, 2 parts of propane diols, 0.3 part of AMP-95 multifunctional assistants, colorant 5
Part, 1 part of ethylene glycol ethyl ether, 30 parts of alkide resin emulsion, 25 parts of deionized water；
Wherein, the preparation method of the cyclodextrin carried titanium dioxide nano-particle is as follows：By titanium dioxide nano-particle
It is added in 10% sodium hydroxide solution, its mass volume ratio is 1g：10mL, then adds beta-schardinger dextrin thereto, and two
The mass ratio of titanium oxide nanoparticles and beta-schardinger dextrin is 1：7, stir, ultrasonic disperse, ultrasonic power 600W, ultrasound
Time is 10min, centrifugal sedimentation, deionized water washing, gained solid matter is dried in vacuo, produced.
The preparation method of the modified zeolite powder is as follows：Zeolite is crushed, microwave heating, the power of microwave heating is
1000W, heat time 1min, it is then added in 10% hydrochloric acid solution and soaks 1h, filters, deionized water washing, by it
Add in 10% sodium chloride solution and soak 40min, filter, deionized water washing, produce.
The component B includes the raw material of following parts by weight：0.1 part of defoamer, 0.5 part of inorganic water-proof impervious agent, 12 carbon
2 parts of alcohol ester, 0.5 part of AMP-95 multifunctional assistants, 1 part of ethylene glycol ethyl ether, 75 parts of silicone acrylic emulsion, 20 parts of deionized water.
The component C includes the raw material of following parts by weight：Protect 8 parts of rubber powder, 92 parts of deionized water.
The invention also discloses the preparation method of above-mentioned aqueous colorful art coatings, comprise the following steps：
1) prepared by component A：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin carried titanium dioxide are received
Rice corpuscles, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-95 are multi-functional
Auxiliary agent, colorant, ethylene glycol ethyl ether, alkide resin emulsion are added sequentially in deionized water, are stirred with 1300r/min rotating speeds
20min；
2) prepared by component B：By defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 multifunctional assistants, second two
Alcohol ether, silicone acrylic emulsion are added in deionized water, and 15min is stirred with 800r/min rotating speed；
3) prepared by component C：Protection rubber powder is added in deionized water, 10min is stirred with 600r/min rotating speed；
4) coating preparation：Component A, component B and component C are mixed in proportion, 20min is stirred, produces.
Embodiment 2
The invention provides a kind of aqueous colorful art coatings, including component A, component B, component C, its mass ratio is 2：
1.5：1；
The component A includes the raw material of following parts by weight：0.6 part of sodium tripolyphosphate, 0.2 part of defoamer, fire retardant 0.2
Part, 0.2 part of pH adjusting agent, 1.5 parts of cyclodextrin carried titanium dioxide nano-particle, 4.5 parts of modified zeolite powder, calcined kaolin 6
Part, 0.5 part of inorganic water-proof impervious agent, 0.6 part of hydroxyethyl cellulose, 1.4 parts of propane diols, 0.3 part of AMP-95 multifunctional assistants,
3 parts of colorant, 1.5 parts of ethylene glycol ethyl ether, 27 parts of alkide resin emulsion, 26 parts of deionized water；
Wherein, the preparation method of the cyclodextrin carried titanium dioxide nano-particle is as follows：By titanium dioxide nano-particle
It is added in 10% sodium hydroxide solution, its mass volume ratio is 1g：12mL, then adds beta-schardinger dextrin thereto, and two
The mass ratio of titanium oxide nanoparticles and beta-schardinger dextrin is 1：8, stir, ultrasonic disperse, ultrasonic power 700W, ultrasound
Time is 15min, centrifugal sedimentation, deionized water washing, gained solid matter is dried in vacuo, produced.
The preparation method of the modified zeolite powder is as follows：Zeolite is crushed, microwave heating, the power of microwave heating is
1100W, heat time 2min, it is then added in 10% hydrochloric acid solution and soaks 1.5h, filter, deionized water washing will
It, which is added in 10% sodium chloride solution, soaks 50min, filters, and deionized water washing, produces.
The component B includes the raw material of following parts by weight：0.1 part of defoamer, 0.3 part of inorganic water-proof impervious agent, 12 carbon
2.5 parts of alcohol ester, 0.4 part of AMP-95 multifunctional assistants, 1.4 parts of ethylene glycol ethyl ether, 70 parts of silicone acrylic emulsion, 22 parts of deionized water.
The component C includes the raw material of following parts by weight：Protect 7 parts of rubber powder, 93 parts of deionized water.
The invention also discloses the preparation method of above-mentioned aqueous colorful art coatings, comprise the following steps：
1) prepared by component A：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin carried titanium dioxide are received
Rice corpuscles, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-95 are multi-functional
Auxiliary agent, colorant, ethylene glycol ethyl ether, alkide resin emulsion are added sequentially in deionized water, are stirred with 1400r/min rotating speeds
25min；
2) prepared by component B：By defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 multifunctional assistants, second two
Alcohol ether, silicone acrylic emulsion are added in deionized water, and 20min is stirred with 900r/min rotating speed；
3) prepared by component C：Protection rubber powder is added in deionized water, 15min is stirred with 700r/min rotating speed；
4) coating preparation：Component A, component B and component C are mixed in proportion, 25min is stirred, produces.
Embodiment 3
The invention provides a kind of aqueous colorful art coatings, including component A, component B, component C, its mass ratio is 2：
1.5：1；
The component A includes the raw material of following parts by weight：0.7 part of sodium tripolyphosphate, 0.3 part of defoamer, fire retardant 0.3
Part, 0.2 part of pH adjusting agent, 2 parts of cyclodextrin carried titanium dioxide nano-particle, 4 parts of modified zeolite powder, 7 parts of calcined kaolin,
0.6 part of inorganic water-proof impervious agent, 0.7 part of hydroxyethyl cellulose, 1.7 parts of propane diols, 0.4 part of AMP-95 multifunctional assistants, colorant
4 parts, 1.8 parts of ethylene glycol ethyl ether, 28 parts of alkide resin emulsion, 29 parts of deionized water；
Wherein, the preparation method of the cyclodextrin carried titanium dioxide nano-particle is as follows：By titanium dioxide nano-particle
It is added in 10% sodium hydroxide solution, its mass volume ratio is 1g：14mL, then adds beta-schardinger dextrin thereto, and two
The mass ratio of titanium oxide nanoparticles and beta-schardinger dextrin is 1：9, stir, ultrasonic disperse, ultrasonic power 800W, ultrasound
Time is 10min, centrifugal sedimentation, deionized water washing, gained solid matter is dried in vacuo, produced.
The preparation method of the modified zeolite powder is as follows：Zeolite is crushed, microwave heating, the power of microwave heating is
1000W, heat time 3min, it is then added in 10% hydrochloric acid solution and soaks 1.5h, filter, deionized water washing will
It, which is added in 10% sodium chloride solution, soaks 60min, filters, and deionized water washing, produces.
The component B includes the raw material of following parts by weight：0.2 part of defoamer, 0.4 part of inorganic water-proof impervious agent, 12 carbon
2.2 parts of alcohol ester, 0.3 part of AMP-95 multifunctional assistants, 1.7 parts of ethylene glycol ethyl ether, 72 parts of silicone acrylic emulsion, 24 parts of deionized water.
The component C includes the raw material of following parts by weight：Protect 6.5 parts of rubber powder, 93.5 parts of deionized water.
The invention also discloses the preparation method of above-mentioned aqueous colorful art coatings, comprise the following steps：
1) prepared by component A：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin carried titanium dioxide are received
Rice corpuscles, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-95 are multi-functional
Auxiliary agent, colorant, ethylene glycol ethyl ether, alkide resin emulsion are added sequentially in deionized water, are stirred with 1500r/min rotating speeds
20min；
2) prepared by component B：By defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 multifunctional assistants, second two
Alcohol ether, silicone acrylic emulsion are added in deionized water, and 15min is stirred with 1000r/min rotating speed；
3) prepared by component C：Protection rubber powder is added in deionized water, 20min is stirred with 600r/min rotating speed；
4) coating preparation：Component A, component B and component C are mixed in proportion, 30min is stirred, produces.
Embodiment 4
The invention provides a kind of aqueous colorful art coatings, including component A, component B, component C, its mass ratio is 2：
1.5：1；
The component A includes the raw material of following parts by weight：0.8 part of sodium tripolyphosphate, 0.2 part of defoamer, fire retardant 0.3
Part, 0.2 part of pH adjusting agent, 3 parts of cyclodextrin carried titanium dioxide nano-particle, 3 parts of modified zeolite powder, 8 parts of calcined kaolin,
0.4 part of inorganic water-proof impervious agent, 0.8 part of hydroxyethyl cellulose, 1 part of propane diols, 0.5 part of AMP-95 multifunctional assistants, colorant 1
Part, 2 parts of ethylene glycol ethyl ether, 25 parts of alkide resin emulsion, 30 parts of deionized water；
Wherein, the preparation method of the cyclodextrin carried titanium dioxide nano-particle is as follows：By titanium dioxide nano-particle
It is added in 10% sodium hydroxide solution, its mass volume ratio is 1g：15mL, then adds beta-schardinger dextrin thereto, and two
The mass ratio of titanium oxide nanoparticles and beta-schardinger dextrin is 1：10, stir, ultrasonic disperse, ultrasonic power 800W, ultrasound
Time is 20min, centrifugal sedimentation, deionized water washing, gained solid matter is dried in vacuo, produced.
The preparation method of the modified zeolite powder is as follows：Zeolite is crushed, microwave heating, the power of microwave heating is
1200W, heat time 3min, it is then added in 10% hydrochloric acid solution and soaks 2h, filters, deionized water washing, by it
Add in 10% sodium chloride solution and soak 60min, filter, deionized water washing, produce.
The component B includes the raw material of following parts by weight：0.3 part of defoamer, 0.3 part of inorganic water-proof impervious agent, 12 carbon
3 parts of alcohol ester, 0.3 part of AMP-95 multifunctional assistants, 2 parts of ethylene glycol ethyl ether, 68 parts of silicone acrylic emulsion, 25 parts of deionized water.
The component C includes the raw material of following parts by weight：Protect 6 parts of rubber powder, 94 parts of deionized water.
The invention also discloses the preparation method of above-mentioned aqueous colorful art coatings, comprise the following steps：
1) prepared by component A：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin carried titanium dioxide are received
Rice corpuscles, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-95 are multi-functional
Auxiliary agent, colorant, ethylene glycol ethyl ether, alkide resin emulsion are added sequentially in deionized water, are stirred with 1500r/min rotating speeds
30min；
2) prepared by component B：By defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 multifunctional assistants, second two
Alcohol ether, silicone acrylic emulsion are added in deionized water, and 25min is stirred with 1000r/min rotating speed；
3) prepared by component C：Protection rubber powder is added in deionized water, 20min is stirred with 800r/min rotating speed；
4) coating preparation：Component A, component B and component C are mixed in proportion, 30min is stirred, produces.
Comparative example 1
The embodiment is distinguished as with the unique of embodiment 2：Cyclodextrin carried titanium dioxide nanoparticle is not contained in component A
Son, remaining material composition content and preparation method are the same as embodiment 2.
Comparative example 2
The embodiment is distinguished as with the unique of embodiment 2：Modified zeolite powder is not contained, remaining material composition content and preparation
Method is the same as embodiment 2.
Comparative example 3
The embodiment is distinguished as with the unique of embodiment 2：Cyclodextrin carried titanium dioxide nano-particle and zeolite are not contained
Powder, remaining material composition content and preparation method are the same as embodiment 2.
The coating prepared to the embodiment of the present invention and comparative example carries out performance detection.
Coating prepared by embodiment 1-4 and comparative example 1-3 is attached to indoor wall for fitting up painting respectively, application terminates
0h, 24h and 72h detect content of formaldehyde respectively afterwards, calculate formaldehyde clearance.
The coating of table 1 goes formaldehyde performance detection
From table 1 it follows that coating prepared by 1-4 of the embodiment of the present invention can adsorb the pernicious gas in air, only
Change air, after fitting up application 24h, formaldehyde clearance can reach more than 55%, and the formaldehyde clearance in comparative example 1-3 will
Significantly lower than embodiment 2, illustrate that coating prepared by the present invention can effectively purify air.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, nothing
By from the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by institute
Attached claim rather than described above limit, it is intended that will fall in the implication and scope of the equivalency of claim
All changes include in the present invention.
Claims (10)
1. a kind of aqueous colorful art coatings, it is characterised in that including component A, component B, component C, its mass ratio is 2：1.5：
1；
The component A includes following raw material：Sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin load titanium dioxide
Titanium nano-particle, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-95 are more
Function additive, colorant, ethylene glycol ethyl ether, alkide resin emulsion, deionized water；
The component B includes following raw material：Defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 multifunctional assistants,
Ethylene glycol ethyl ether, silicone acrylic emulsion, deionized water；
The component C includes following raw material：Protect rubber powder, deionized water.
2. aqueous colorful art coatings according to claim 1, it is characterised in that the component A includes following parts by weight
Raw material：Sodium tripolyphosphate 0.5-0.8 parts, defoamer 0.2-0.4 parts, fire retardant 0.1-0.3 parts, pH adjusting agent 0.2-0.3 parts,
Cyclodextrin carried titanium dioxide nano-particle 1-3 parts, modified zeolite powder 3-5 parts, calcined kaolin 5-8 parts, inorganic water-proof are impervious
Agent 0.4-0.8 parts, hydroxyethyl cellulose 0.5-0.8 parts, propane diols 1-2 parts, AMP-95 multifunctional assistant 0.3-0.5 parts, colorant
1-5 parts, ethylene glycol ethyl ether 1-2 parts, alkide resin emulsion 25-30 parts, deionized water 25-30 parts.
3. aqueous colorful art coatings according to claim 2, it is characterised in that the cyclodextrin carried titanium dioxide is received
The preparation method of rice corpuscles is as follows：Titanium dioxide nano-particle is added in 10% sodium hydroxide solution, then thereto
Beta-schardinger dextrin is added, is stirred, ultrasonic disperse, centrifugal sedimentation, deionized water washing, gained solid matter is dried in vacuo,
Produce.
4. aqueous colorful art coatings according to claim 3, it is characterised in that the titanium dioxide nano-particle and hydrogen
The mass volume ratio of sodium hydroxide solution is 1g：10-15mL, it is preferable that the matter of the titanium dioxide nano-particle and beta-schardinger dextrin
Amount is than being 1：7-10.
5. aqueous colorful art coatings according to claim 3, it is characterised in that the ultrasonic power is 600-
800W, ultrasonic time 10-20min.
6. aqueous colorful art coatings according to claim 2, it is characterised in that the preparation method of the modified zeolite powder
It is as follows：Zeolite is crushed, microwave heating, is then added in hydrochloric acid solution and soaks, filter, washing, it is molten to be added into sodium chloride
Soak, filter in liquid, washing, produce.
7. aqueous colorful art coatings according to claim 6, it is characterised in that the preparation method of the modified zeolite powder
It is as follows：Zeolite is crushed, microwave heating, the power of microwave heating is 1000-1200W, heat time 1-3min, is then added
1-2h is soaked into 10% hydrochloric acid solution, is filtered, deionized water washing, is added into 10% sodium chloride solution and soaks 40-
60min, filter, deionized water washing, produce.
8. aqueous colorful art coatings according to claim 1, it is characterised in that the component B includes following parts by weight
Raw material：Defoamer 0.1-0.3 parts, inorganic water-proof impervious agent 0.3-0.5 parts, Lauryl Alcohol ester 2-3 parts, AMP-95 multifunctional assistants
Agent 0.3-0.5 parts, ethylene glycol ethyl ether 1-2 parts, silicone acrylic emulsion 68-75 parts, deionized water 20-25 parts.
9. aqueous colorful art coatings according to claim 1, it is characterised in that the component C includes following parts by weight
Raw material：Protect rubber powder 6-8 parts, deionized water 92-94 parts.
10. the preparation method based on the aqueous colorful art coatings described in claim 1-9 any one, it is characterised in that bag
Include following steps：
1) prepared by component A：By sodium tripolyphosphate, defoamer, fire retardant, pH adjusting agent, cyclodextrin carried titanium dioxide nanoparticle
Son, modified zeolite powder, calcined kaolin, inorganic water-proof impervious agent, hydroxyethyl cellulose, propane diols, AMP-95 multifunctional assistants,
Colorant, ethylene glycol ethyl ether, alkide resin emulsion are added sequentially in deionized water, and 20- is stirred with 1300-1500r/min rotating speeds
30min；
2) prepared by component B：By defoamer, inorganic water-proof impervious agent, Lauryl Alcohol ester, AMP-95 multifunctional assistants, ethylene glycol ethyl ethers
Ether, silicone acrylic emulsion are added in deionized water, and 15-25min is stirred with 800-1000r/min rotating speed；
3) prepared by component C：Protection rubber powder is added in deionized water, 10-20min is stirred with 600-800r/min rotating speed；
4) coating preparation：Component A, component B and component C are mixed in proportion, 20-30min is stirred, produces.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321074A (en) * | 2018-11-22 | 2019-02-12 | 遵义市世和建材有限公司 | A kind of water-fast building materials coating |
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| CN105038363A (en) * | 2015-07-30 | 2015-11-11 | 广西梧州龙鱼漆业有限公司 | Anti-bacteria mouldproof putty powder |
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