CN107641813A - A kind of environmental protection and safety type copper material cleaning and protective agent and preparation method thereof - Google Patents
A kind of environmental protection and safety type copper material cleaning and protective agent and preparation method thereof Download PDFInfo
- Publication number
- CN107641813A CN107641813A CN201610578985.5A CN201610578985A CN107641813A CN 107641813 A CN107641813 A CN 107641813A CN 201610578985 A CN201610578985 A CN 201610578985A CN 107641813 A CN107641813 A CN 107641813A
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- Prior art keywords
- solution
- cleaning
- copper material
- protective agent
- environmental protection
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- 238000004140 cleaning Methods 0.000 title claims abstract description 42
- 239000000463 material Substances 0.000 title claims abstract description 30
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 29
- 239000010949 copper Substances 0.000 title claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000003223 protective agent Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 230000007613 environmental effect Effects 0.000 title claims abstract description 7
- 239000012459 cleaning agent Substances 0.000 title abstract description 11
- 230000003641 microbiacidal effect Effects 0.000 claims abstract description 6
- 229940124561 microbicide Drugs 0.000 claims abstract description 6
- 239000002855 microbicide agent Substances 0.000 claims abstract description 6
- 235000015393 sodium molybdate Nutrition 0.000 claims abstract description 6
- 239000011684 sodium molybdate Substances 0.000 claims abstract description 6
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000003918 triazines Chemical class 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000005259 measurement Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 206010013786 Dry skin Diseases 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 238000012552 review Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 9
- 238000012545 processing Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000004094 surface-active agent Substances 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 239000003899 bactericide agent Substances 0.000 abstract description 3
- 150000007524 organic acids Chemical class 0.000 abstract description 3
- 229940093430 polyethylene glycol 1500 Drugs 0.000 abstract description 3
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 abstract description 2
- 235000012207 sodium gluconate Nutrition 0.000 abstract description 2
- 239000000176 sodium gluconate Substances 0.000 abstract description 2
- 229940005574 sodium gluconate Drugs 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 229920002125 Sokalan® Polymers 0.000 abstract 1
- 150000001879 copper Chemical class 0.000 abstract 1
- 239000004584 polyacrylic acid Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000003921 oil Substances 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000013556 antirust agent Substances 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of environmental protection and safety type copper material cleaning and protective agent in chemical field and preparation method thereof, its component, which is formed, is respectively：Polyacrylic acid solution 1~2%, sodium gluconate solution 1~2%, the solution 1~3% of copper material protective agent CU 1806; polyethylene glycol 1500 solution 8~10%, sodium molybdate solution 1~2%, triazines microbicide solution 1~2%; APG (APG) solution 1~2%, remaining adds water to 100%.This copper material cleaning protective agent is to use organic acid and surfactant, copper material protective agent and bactericide to be prepared for primary raw material through science processing technology; it is not required to rinse after cleaning; wash rear piece surface and can reach the copper material requirement of shelter of overlength as new without hickie, light.This product is in alkalescent, and cleaning and protection settle at one go, solves cleaning and protects numerous and diverse process problem, the cleaning rust-proof especially suitable for various copper materials.
Description
Technical field
The present invention relates to chemical field, particularly a kind of cleaning protective agent for being combined into one cleaning-protection and
Its preparation method.
Background technology
With the fast development of machinery manufacturing industry, copper material material widely using and popularizing, all trades and professions production and
Various operating modes can be run among the process used, such as：The parts or raw material of copper material are contaminated, workpiece surface
There are various greasy dirts etc., in face of it is such the problem of generally require and cleaned, not only the requirement to cleaning agent is tighter
Lattice, there can not be corrosion to copper material, and require that cleaning agent is extremely strong, the workpiece after cleaning is exposed in an atmosphere can be by air
Oxidation, causes copper material surface discolouration, a series of problem occurs, the quality of workpiece and attractive in appearance can be directly affected, in face of such
Problem, all trades and professions are typically all taken and first cleaned, and the solution pattern of rear protecting is located respectively, it is necessary to prepare different processes
Reason, while the copper material protective agent quality of in the market is uneven, it is impossible to meet the requirement that the long-time of client is protected to copper material.
In processing or use inevitably by oil pollution, the metal parts after pollution must use some metal parts made of copper
Cleaning agent cleans.Using the cleaning of existing cleaning agent, there are the following problems：1. cleaning after metal parts remained on surface have some because
White dot caused by cleaning agent；Got rusty 2. can be oxidized again within a short period of time after cleaning again.Produce the original of above mentioned problem
Because being because existing metal cleaner is the aqueous cleaning agent using surfactant as main component, the cleaning agent only has clear
Wash function and (former without rust-preventing characteristic：Rustless property), and foam is more and can not use high-tension apparatus when causing cleaning, makes scavenger
It is low to make efficiency.In addition existing cleaning method processing step is complicated, typically needs to clean, rinses, three processes of antirust, cleaning zero
The part time is longer.
The content of the invention
There is provided it is an object of the invention to overcome the deficiencies in the prior art a kind of safe environment protection type cleaning protective agent and its
Preparation method, there is cleaning and safeguard function simultaneously by the cleaning protective agent prepared by this method, and need not be floated after cleaning
Parts after can reach cleaning are washed to remain without white and adsorbed one layer of hydrophobic rust-preventing film in metal surface to realize that inter process is prevented
Shield.
Realize the technical scheme is that：
A kind of safe environment protection type copper material cleaning protection, it is characterised in that：
Its constituent and weight proportion are respectively：
Moreover, the solution concentration of described each constituent is respectively：
A kind of preparation method of environmental protection and safety type copper material cleaning protective agent is as follows：
(1) reviews and validate reactor equipment Qing Jie ﹑ dryings, and starts reactor equipment and confirm that equipment runs well, standby
With；
(2) meterings add copper material protective agent CU-1806 Rong Ye ﹑ polyethylene glycol 1500s solution and sodium molybdate according to measurement criteria
Solution, it is about 30 minutes to continue mixing time, and it is light yellow transparent liquid to observe solution colour；
(3) finally sequentially adds triazines microbicide solution and APG (APG) solution according to measurement criteria, during stirring
Between about 20 minutes, confirm product stir completely.
Advantages of the present invention and beneficial effect are：
1. a cleaning simple science of the protective agent mechanism of action, a kind of clear using organic acid and sodium gluconate reaction generation first
Cosolvent is washed, the quick dissolving of copper material protective agent and cleaning-type surfactant can be achieved and dissolve each other, the alkyl added in it
Glucosides (APG) solution amine plays fine cleaning action.The cleaning cosolvent generated also needs to add copper material protective agent CU-1806
Solution, polyethylene glycol 1500 solution and triazines microbicide solution, sodium molybdate solution with formed the present invention cleaning protective agent,
The polyethylene glycol 1500 solution wherein added can provide a stable pH value for cleaning process, and the bactericide added can press down
Bacterium generation processed, the copper material protective agent CU-1806 solution added, which can play a part of helping, washes and protects copper material.Thus, this is clear
It is to clean greasy dirt, disperse, emulsifying first that the mechanism of action of lotion, which is, will be surplus using very strong suction-operated between antirust agent and metal
Remaining dirty displacement departs from metal surface, and now one layer of hydrophobic rust-preventing film has been adsorbed in metal surface, and this film has repulsion to make to water, greasy dirt
With.Therefore after cleaning, metal surface is very clean, without the residual of greasy dirt.
2. a cleaning protective agent is obvious using simple effects, operating efficiency is improved, need not rinse can be complete for part after cleaning
U.S.A reaches the effect of rinsing, and part need not rinse antirust to realize the effect of rust prevention during manufacture through antirust agent after cleaning.Cause
Instant invention overcomes cleaning agent the drawbacks of exhibiting high surface activating agent causes workpiece surface to remain for this, makes the anti-nurse of numerous and diverse cleaning
Skill is simplified.
3. a cleaning protective agent is to use organic acid and surfactant, bactericide are primary raw material through science processing technology
It is prepared, is not required to rinse after cleaning, without hickie, light can reach inter process protection and want as new on zero (portion) part surface after washing
Ask.This product is in alkalescent, raw materials used wide material sources, and it is easy to obtain, and usage amount is few, to antirust oil, oil emulsion, cutting fluid,
The processing oils such as compacting oil, lubricating oil, transformer oil have strong washing power, and the cleaning especially suitable for various copper materials is protected.
Embodiment
Below by specific embodiment, the invention will be further described, and following examples are descriptive, is not limit
Qualitatively, it is impossible to which protection scope of the present invention is limited with this.
What it is firstly the need of explanation is：The various components that the embodiment of the present invention uses are commercially available prod.
Embodiment 1：
Each component and its content, weight proportion are respectively：
Preparation method is as follows：
(1) reviews and validate reactor equipment Qing Jie ﹑ dryings, and starts reactor equipment and confirm that equipment runs well, standby
With；
(2) meterings add copper material protective agent CU-1806 Rong Ye ﹑ polyethylene glycol 1500s solution and sodium molybdate according to measurement criteria
Solution, it is about 30 minutes to continue mixing time, and it is light yellow transparent liquid to observe solution colour；
(3) finally sequentially adds triazines microbicide solution and APG (APG) solution according to measurement criteria, during stirring
Between about 20 minutes, confirm product stir completely.
Embodiment 2：
Each component and its content, weight proportion are respectively：
Preparation method is as follows：
(1) reviews and validate reactor equipment Qing Jie ﹑ dryings, and starts reactor equipment and confirm that equipment runs well, standby
With；
(2) meterings add copper material protective agent CU-1806 Rong Ye ﹑ polyethylene glycol 1500s solution and sodium molybdate according to measurement criteria
Solution, it is about 30 minutes to continue mixing time, and it is light yellow transparent liquid to observe solution colour；
(3) finally sequentially adds triazines microbicide solution and APG (APG) solution according to measurement criteria, during stirring
Between about 20 minutes, confirm product stir completely.
The application example of the present invention：
Part containing cutting greasy dirt thing is existed with the cleaning protective agent of embodiment 1 and embodiment 2,55 DEG C of temperature, work
Immersion or cleaning showers 3 minutes, then use hot blast drying under conditions of liquid concentration 3%.Workpiece is bright as new after cleaning, without white
Color residue.The part that this was cleaned is placed in storehouse, can play protection more than 1 year, is not in corrosion, spot corrosion, nothing is in vain
Color residue separates out.
Quality standard：
Outward appearance：It is colourless to light yellow transparent liquid
Density： 1.038-1.042
PH： 8.9-9.2
Antirust：December
Workpiece：Without white dot after washing
Concentration：3%
Cleaning pressure：0.1-2MPa (can soak or ultrasonic wave)
Cleaning temperature:Or 40-70 DEG C of normal temperature.
Claims (3)
1. a kind of environmental protection and safety type copper material cleans protective agent, it is characterised in that：
Its constituent and weight proportion are respectively：
Remaining adds water to 100%.
2. environmental protection and safety type copper material according to claim 1 cleans protective agent, it is characterised in that：
The solution concentration of described each constituent is respectively：
A kind of 3. preparation method of environmental protection and safety type copper material cleaning protective agent as claimed in claim 1, it is characterised in that：
Its preparation method is as follows：
(1) reviews and validate reactor equipment Qing Jie ﹑ dryings, and starts reactor equipment and confirm that equipment runs well, standby；
(2) meterings add copper material protective agent CU-1806 Rong Ye ﹑ polyethylene glycol 1500s solution according to measurement criteria and sodium molybdate is molten
Liquid, it is about 30 minutes to continue mixing time, and it is light yellow transparent liquid to observe solution colour；
(3) finally sequentially adds triazines microbicide solution and APG (APG) solution according to measurement criteria, and mixing time is big
About 20 minutes, confirm that product stirs completely.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610578985.5A CN107641813A (en) | 2016-07-21 | 2016-07-21 | A kind of environmental protection and safety type copper material cleaning and protective agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610578985.5A CN107641813A (en) | 2016-07-21 | 2016-07-21 | A kind of environmental protection and safety type copper material cleaning and protective agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107641813A true CN107641813A (en) | 2018-01-30 |
Family
ID=61108806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610578985.5A Pending CN107641813A (en) | 2016-07-21 | 2016-07-21 | A kind of environmental protection and safety type copper material cleaning and protective agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107641813A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666943A (en) * | 2017-10-16 | 2019-04-23 | 麦达可尔(天津)科技有限公司 | A kind of environmental protection and safety type copper material cleaning protective agent and preparation method thereof |
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| CN101113524A (en) * | 2007-09-04 | 2008-01-30 | 天津市华阳新兴科技有限公司 | Cleaning antirust agent and preparation method thereof |
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| US20180251712A1 (en) * | 2014-01-29 | 2018-09-06 | Entegris, Inc. | Post chemical mechanical polishing formulations and method of use |
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2016
- 2016-07-21 CN CN201610578985.5A patent/CN107641813A/en active Pending
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| CN101130877A (en) * | 2006-08-25 | 2008-02-27 | 安集微电子（上海）有限公司 | Metal anti-corrosion protection liquid used for semiconductor manufacture process |
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| CN101660148A (en) * | 2009-09-07 | 2010-03-03 | 天津市华阳新兴科技有限公司 | Water-base metal antirusting agent and preparation method thereof |
| US20180251712A1 (en) * | 2014-01-29 | 2018-09-06 | Entegris, Inc. | Post chemical mechanical polishing formulations and method of use |
| CN105483730A (en) * | 2015-12-14 | 2016-04-13 | 华南理工大学 | Neutral environment-friendly metal oil removal and scale removal cleaning fluid and preparation method thereof |
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Non-Patent Citations (1)
| Title |
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| 上传者PKS1981136PHS: "铜保护剂CU-1806", 《百度文库》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666943A (en) * | 2017-10-16 | 2019-04-23 | 麦达可尔(天津)科技有限公司 | A kind of environmental protection and safety type copper material cleaning protective agent and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20180130 |