CN107629570A - A kind of ceramic sanitary appliance self-cleaning composition - Google Patents
A kind of ceramic sanitary appliance self-cleaning composition Download PDFInfo
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- CN107629570A CN107629570A CN201710871552.3A CN201710871552A CN107629570A CN 107629570 A CN107629570 A CN 107629570A CN 201710871552 A CN201710871552 A CN 201710871552A CN 107629570 A CN107629570 A CN 107629570A
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- sanitary appliance
- ceramic sanitary
- cleaning composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 239000000919 ceramic Substances 0.000 title claims abstract description 29
- 238000004140 cleaning Methods 0.000 title claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001709 polysilazane Polymers 0.000 claims abstract description 6
- 239000007822 coupling agent Substances 0.000 claims abstract description 3
- 239000003085 diluting agent Substances 0.000 claims abstract description 3
- 239000012948 isocyanate Substances 0.000 claims abstract description 3
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 3
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 3
- 239000010703 silicon Substances 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 230000000844 anti-bacterial effect Effects 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 239000003899 bactericide agent Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 2
- YXRKNIZYMIXSAD-UHFFFAOYSA-N 1,6-diisocyanatohexane Chemical compound O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O YXRKNIZYMIXSAD-UHFFFAOYSA-N 0.000 claims description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical group CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000645 desinfectant Substances 0.000 claims description 2
- 239000002283 diesel fuel Substances 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 2
- ZDWQSEWVPQWLFV-UHFFFAOYSA-N C(CC)[Si](OC)(OC)OC.[O] Chemical compound C(CC)[Si](OC)(OC)OC.[O] ZDWQSEWVPQWLFV-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 239000004210 ether based solvent Substances 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- -1 triethoxy methyl silicane Chemical compound 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 235000012424 soybean oil Nutrition 0.000 abstract description 2
- 239000003549 soybean oil Substances 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000003075 superhydrophobic effect Effects 0.000 description 3
- 240000002853 Nelumbo nucifera Species 0.000 description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 1
- 230000001046 anti-mould Effects 0.000 description 1
- 239000002546 antimould Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004452 microanalysis Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of ceramic sanitary appliance self-cleaning composition, it is made up of tri- kinds of components of A, B, C, wherein A has been the fluorocarbon resin and related auxiliaries of filming function, B is the polysilazane with hardening crosslinked action, organo-silicon coupling agent and its diluent, and C is the isocyanate curing agent for solidifying fluorocarbon resin.After composition is fully cured on ceramic sanitary appliance surface, the contact angle of the composition film and water is more than 150 °, it is more than 120 ° with the contact angle of soybean oil, therefore it is easy to be taken away by water droplet when spot stays in film coated surface, reach automatically cleaning effect, the film has wide spectrum, efficient sterilizing effect simultaneously, and Durability of antimicrobial effect was up to more than 5 years.
Description
Technical field
The present invention relates to a kind of ceramic sanitary appliance self-cleaning composition, belong to the technical field of surface of ceramic sanitary appliance.
Technical background
In nature, lotus leaf surface has unique self-cleaning function, larger contact angle can be formed with water surface, is referred to as
Lotus leaf effect or super-hydrophobic effect.Because the contact area of super hydrophobic surface and water droplet is very small, and water droplet easily rolls from table
Fall, therefore, super hydrophobic surface not only has a self-cleaning function, but also with it is anti-electric spread lead, it is anticorrosion, waterproof, antifog, anti-
Mould, snow defence, frost protection, it is anti-the function such as stick, be anti-pollution, thus in building, textile clothing, liquid conveys, is biomedical, daily
The fields such as product and packaging, transport facility and micro-analysis are all with a wide range of applications.
Chinese patent 201310043491.3 discloses a kind of super-hydrophilic self-cleaning coating formula and its film-forming products, and the formula includes pressing
The following component calculated according to percentage by weight：Water nano resin 10%~20%；Nano-scale alumina slurry 30%~50%；
BYK023 is 0.1%~0.5%；Ethanol 10%~50%；Deionized water is as surplus；The invention nano-resin is as film forming agent
Use；Hydrophilic coating is used as using nano-scale alumina slurry；Defoamer and levelling agent are used as using BYK023；Cosolvent is used as using ethanol.
In in use, by the super-hydrophilic self-cleaning coating matched spraying, showering or brush on the surface of product, dry at normal temperatures
Film forming or the film forming after 60~70 DEG C of bakings, the coating surface formed can be spontaneously wet out by water completely, and contact angle is less than 5 degree.
Due to too small with water contact angle, the self-cleaning coating described in the invention is not suitable in the pottery that spot easily stops, bacterium easily grows
Porcelain field of sanitary.
The content of the invention
The shortcomings that to overcome prior art and deficiency, primary and foremost purpose of the invention are to provide a kind of ceramic sanitary appliance automatically cleaning
Composition.
A kind of ceramic sanitary appliance self-cleaning composition of the present invention is made up of tri- kinds of components of A, B, C, and concrete composition is as follows
Table：
Described fluorocarbon resin 20~80mg of hydroxyl value KOH/g.
Described levelling agent is organosilicon levelling agent, preferably TEGO450, TEGO4100, BYK450, BYK415, BYK333,
At least one of BYK358, BYK306.
Described bactericide is that solvent-borne type is complexed silver ion disinfectant, concentration 2000ppm.
Described diluent is in petroleum ether solvent, ethyl acetate, butyl acetate, kerosene, diesel oil, ethanol, n-butyl ether, butanol
It is at least one.
Described organo-silicon coupling agent is that tetraethyl orthosilicate, methyl silicate, gamma-aminopropyl-triethoxy-silane, γ-shrink are sweet
Oily ether oxygen propyl trimethoxy silicane, γ-methacryloxypropyl trimethoxy silane, trimethoxymethylsila,e, three
At least one of (ethoxymethyl) base silane.
The polysilazane be Perhydropolysilazane, organopolysilazane, boron hydridization organopolysilazane, boron hydridization perhydro gather
At least one of silazane.
The isocyanate curing agent is low-free TDI tripolymer, low free MDI tripolymer, low free HDI trimer, low trip
From at least one of IPDI tripolymers.
The described anti-skidding Wax composition of water-based ceramic tile imposes on ceramics after using preceding be sufficiently mixed A, B, C uniformly, by spraying
Sanitary equipment surface, after surface drying, it is fully cured after 60~80 DEG C of freeze-day with constant temperature 12h.
Relative to prior art, ceramic sanitary appliance self-cleaning composition of the present invention has advantages below or benefit：(1) use
Fluorocarbon resin does film forming basic resin, the composition have than excellent acidproof, alkaline-resisting, weatherability, water and oil repellence, it is anti-stick,
Resistant to pollution excellent properties；(2) most hard synthetic resin polysilazane resin makees hardening agent, the composition film known to selecting
Afterwards, polysilazane resin self-crosslinking in the presence of Karsted catalyst, simultaneously participate in and fluorocarbon resin crosslinking and isocyanic acid
The cross-linking reaction of ester curing agent, composition film densification is hard, adhesive force is good；(3) after being fully cured on ceramic sanitary appliance surface, institute
The contact angle for stating composition film and water is more than 150 °, is more than 120 ° with the contact angle of soybean oil, therefore when spot stays in film
It is easy to be taken away by water droplet during surface, reaches automatically cleaning effect；(4) in the composition containing wide spectrum, efficiently, safety silver from
Sub- bactericide, antibacterial effect was up to more than 5 years.
Embodiment
A kind of ceramic sanitary appliance self-cleaning composition of the present invention is further described with reference to embodiment.It is appreciated that
It is that specific embodiment described herein is used only for explaining related invention, rather than the restriction to the invention.
Embodiment 1
A kind of ceramic sanitary appliance self-cleaning composition of the present invention is made up of tri- kinds of components of A, B, C, concrete composition such as following table：
Embodiment 2
A kind of ceramic sanitary appliance self-cleaning composition of the present invention is made up of tri- kinds of components of A, B, C, concrete composition such as following table：
Embodiment 3
A kind of ceramic sanitary appliance self-cleaning composition of the present invention is made up of tri- kinds of components of A, B, C, concrete composition such as following table：
By the anti-skidding Wax composition of water-based ceramic tile described in embodiment using it is preceding A, B, C are sufficiently mixed after, by spraying apply
In ceramic sanitary appliance surface, after surface drying, 60 ± 5 DEG C of constant temperature are done
It is fully cured after dry 12h, performance test such as following table：
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Pencil hardness | 5H | 5H | 5H |
| Adhesive force | 0 grade | 0 grade | 0 grade |
| Water, film contact angle | 156 | 152 | 151 |
Embodiment 1, embodiment 2, the antibacterial effect of composition in embodiment 3 detect according to building standard JC/T 897-2002
It is as follows：
Claims (9)
1. a kind of ceramic sanitary appliance self-cleaning composition, it is characterised in that be made up of tri- kinds of components of A, B, C, concrete composition such as following table：
A kind of 2. ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that described fluorocarbon resin hydroxyl
20~80mg of value KOH/g.
3. a kind of ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that described levelling agent is to have
Machine silicon levelling agent, preferably in TEGO450, TEGO4100, BYK450, BYK415, BYK333, BYK358, BYK306 at least
It is a kind of.
4. a kind of ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that described bactericide is molten
Formulation is complexed silver ion disinfectant, concentration 2000ppm.
5. a kind of ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that described diluent is stone
At least one of oily ether solvents, ethyl acetate, butyl acetate, kerosene, diesel oil, ethanol, n-butyl ether, butanol.
A kind of 6. ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that described organosilicon coupling
Agent is tetraethyl orthosilicate, methyl silicate, gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl trimethoxy silicon
In alkane, γ-methacryloxypropyl trimethoxy silane, trimethoxymethylsila,e, triethoxy methyl silicane extremely
Few one kind.
7. a kind of ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that the polysilazane is complete
Hydrogen polysilazane, organopolysilazane, boron hydridization organopolysilazane, at least one of boron hydridization Perhydropolysilazane.
A kind of 8. ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that the cured with isocyanates
Agent be low-free TDI tripolymer, low free MDI tripolymer, low free HDI trimer, in low free IPDI tripolymers at least
It is a kind of.
9. a kind of ceramic sanitary appliance self-cleaning composition according to claim 1, it is characterised in that described water-based ceramic tile is prevented
Sliding Wax composition using it is preceding A, B, C are sufficiently mixed uniformly after, ceramic sanitary appliance surface is imposed on by spraying, after surface drying, 60~
It is fully cured after 80 DEG C of freeze-day with constant temperature 12h.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710871552.3A CN107629570A (en) | 2017-09-24 | 2017-09-24 | A kind of ceramic sanitary appliance self-cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710871552.3A CN107629570A (en) | 2017-09-24 | 2017-09-24 | A kind of ceramic sanitary appliance self-cleaning composition |
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| Publication Number | Publication Date |
|---|---|
| CN107629570A true CN107629570A (en) | 2018-01-26 |
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|---|---|---|---|
| CN201710871552.3A Pending CN107629570A (en) | 2017-09-24 | 2017-09-24 | A kind of ceramic sanitary appliance self-cleaning composition |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109385150A (en) * | 2018-10-09 | 2019-02-26 | 刘鹏 | A kind of water-proof climate resisting bi-component exterior wall latex paint |
| CN109575708A (en) * | 2018-12-01 | 2019-04-05 | 韶关市合众化工有限公司 | A kind of simple water-proof climate resisting two-component exterior wall latex paint of construction technology |
| CN110373099A (en) * | 2019-07-30 | 2019-10-25 | 广州弘海化工科技有限公司 | Modified Polyaspartic Polyurea coating and its preparation method and application |
| CN113773706A (en) * | 2021-10-09 | 2021-12-10 | 宁波星禾新材料集团有限公司 | Film-forming surface treating agent capable of prolonging self-cleaning property, weather resistance and acid and alkali resistance and preparation method thereof |
| WO2023109364A1 (en) * | 2021-12-17 | 2023-06-22 | 广东美的白色家电技术创新中心有限公司 | Non-stick coating additive, non-stick coating, and preparation method therefor and use thereof |
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| CN113773706A (en) * | 2021-10-09 | 2021-12-10 | 宁波星禾新材料集团有限公司 | Film-forming surface treating agent capable of prolonging self-cleaning property, weather resistance and acid and alkali resistance and preparation method thereof |
| WO2023109364A1 (en) * | 2021-12-17 | 2023-06-22 | 广东美的白色家电技术创新中心有限公司 | Non-stick coating additive, non-stick coating, and preparation method therefor and use thereof |
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