CN107629452A - A kind of New Electric Polymer - Google Patents
A kind of New Electric Polymer Download PDFInfo
- Publication number
- CN107629452A CN107629452A CN201710814857.0A CN201710814857A CN107629452A CN 107629452 A CN107629452 A CN 107629452A CN 201710814857 A CN201710814857 A CN 201710814857A CN 107629452 A CN107629452 A CN 107629452A
- Authority
- CN
- China
- Prior art keywords
- parts
- new electric
- electric polymer
- acrylamide
- glass fibre
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 23
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 32
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 32
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims abstract description 24
- -1 benzene alkene Chemical class 0.000 claims abstract description 17
- 239000006229 carbon black Substances 0.000 claims abstract description 16
- 239000003365 glass fiber Substances 0.000 claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 16
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 15
- 125000005234 alkyl aluminium group Chemical group 0.000 claims abstract description 15
- 239000004917 carbon fiber Substances 0.000 claims abstract description 15
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 13
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 13
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 13
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 13
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims abstract description 12
- 235000019838 diammonium phosphate Nutrition 0.000 claims abstract description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000001488 sodium phosphate Substances 0.000 claims 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims 2
- 238000005829 trimerization reaction Methods 0.000 claims 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 2
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 6
- 239000002861 polymer material Substances 0.000 description 5
- 239000004020 conductor Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of New Electric Polymer, in parts by weight, including following component：26 parts of 20 30 parts of pyrrole monomer, 20 30 parts of acrylamide, 15 20 parts of benzene alkene, 26 parts of glass fibre, 5 10 parts of carbon fiber, 12 parts of carbon black, 12 parts of sodium tripolyphosphate, 12 parts of alkyl aluminum, 20 40 parts of diammonium hydrogen phosphate, 26 parts of calcium nitrate, 13 parts of polyvinyl alcohol and ammonium molybdate.Big New Electric Polymer is made by adding glass fibre, carbon fiber, carbon black, sodium tripolyphosphate, alkyl aluminum in pyrrole monomer, acrylamide, benzene alkene and diammonium hydrogen phosphate group mixture in the present invention, it is strong to provide New Electric Polymer heat endurance, and it is easy to process, suitable for industrial mass production.
Description
Technical field
The invention belongs to chemical technology field, and in particular to a kind of New Electric Polymer.
Background technology
With the rapid development of modern industry, the utilization of high polymer material is more and more extensive, and major colleges and universities, research institute all set
High polymer material research center is put.High polymer material is also referred to as polymeric material, is using high molecular polymer as matrix, is furnished with
The material that other auxiliary agents are formed, high polymer material are divided into rubber, fiber, plastics, polymer binder, macromolecule by characteristic and applied
Material and polymer-based composite etc..High polymer material is in electric and electronic industry, aerospace industry, construction industry, medicine equipment, medical treatment bag
Suffer from being widely applied in the every profession and trades such as dress, transportation, home electric, agricultural.
New Electric Polymer is with conducting function（Including semiconduction, metallic conductivity and superconductivity）、
Polymeric material of the electrical conductivity in more than 10S/m.Macromolecule conducting material have small density, easy processing, it is corrosion-resistant, can big face
The features such as product film forming and electrical conductivity can be adjusted in the range of the individual order of magnitude more than ten, can be used as various metals material
With the substitute of inorganic conductive material, and turn into the indispensable one kind of many advanced industrial departments and sophisticated technology field
Material.The one kind of polyaniline as macromolecule conducting material, in addition to its electrical characteristics, also having can be compared by cheap aniline
Easily synthesis and the excellent stability to oxygen etc. is shown in the state of showing electric conductivity the advantages of and characteristic.But its
Caused by processability is bad and stability is not high, the application of conductive polymer material industrially is seriously hindered.Especially in electrical equipment
Otherwise application in element, even if other performance is good again, can not be also applied, it is necessary to conductive material has good heat endurance.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of New Electric Polymer.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of New Electric Polymer, it is created
New point is：In parts by weight, including following component：Pyrrole monomer 20-30 parts, acrylamide 20-30 parts, benzene alkene 15-20 parts,
Glass fibre 2-6 parts, carbon fiber 5-10 parts, carbon black 1-2 parts, sodium tripolyphosphate 1-2 parts, alkyl aluminum 1-2 parts, diammonium hydrogen phosphate
20-40 parts, calcium nitrate 2-6 parts, polyvinyl alcohol 1-3 parts and ammonium molybdate 2-6 parts.
Including following component further, in parts by weight,：20 parts of pyrrole monomer, 20 parts of acrylamide, 15 parts of benzene alkene,
2 parts of glass fibre, 5 parts of carbon fiber, 1 part of carbon black, 1 part of sodium tripolyphosphate, 1 part of alkyl aluminum, 20 parts of diammonium hydrogen phosphate, calcium nitrate 2
2 parts of part, 1 part of polyvinyl alcohol and ammonium molybdate.
Including following component further, in parts by weight,：30 parts of pyrrole monomer, 30 parts of acrylamide, 20 parts of benzene alkene,
6 parts of glass fibre, 10 parts of carbon fiber, 2 parts of carbon black, 2 parts of sodium tripolyphosphate, 2 parts of alkyl aluminum, 40 parts of diammonium hydrogen phosphate, calcium nitrate 6
6 parts of part, 3 parts of polyvinyl alcohol and ammonium molybdate.
Including following component further, in parts by weight,：25 parts of pyrrole monomer, 25 parts of acrylamide, 17 parts of benzene alkene,
4 parts of glass fibre, 7 parts of carbon fiber, 1.5 parts of carbon black, 1.5 parts of sodium tripolyphosphate, 1.5 parts of alkyl aluminum, 30 parts of diammonium hydrogen phosphate, nitre
3 parts of sour 4 parts of calcium, 2 parts of polyvinyl alcohol and ammonium molybdate.
Beneficial effects of the present invention are as follows：The present invention is mixed by pyrrole monomer, acrylamide, benzene alkene and diammonium hydrogen phosphate group
Glass fibre, carbon fiber, carbon black, sodium tripolyphosphate, alkyl aluminum are added in compound big New Electric Polymer is made, carried
Supply New Electric Polymer heat endurance strong and easy to process, suitable for industrial mass production.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
A kind of New Electric Polymer, in parts by weight, including following component：Pyrrole monomer 20-30 parts, acryloyl
Amine 20-30 parts, benzene alkene 15-20 parts, glass fibre 2-6 parts, carbon fiber 5-10 parts, carbon black 1-2 parts, sodium tripolyphosphate 1-2 parts, alkane
Base aluminium 1-2 parts, diammonium hydrogen phosphate 20-40 parts, calcium nitrate 2-6 parts, polyvinyl alcohol 1-3 parts and ammonium molybdate 2-6 parts.
Embodiment 1
A kind of New Electric Polymer, in parts by weight, including following component：20 parts of pyrrole monomer, 20 parts of acrylamide,
15 parts of benzene alkene, 2 parts of glass fibre, 5 parts of carbon fiber, 1 part of carbon black, 1 part of sodium tripolyphosphate, 1 part of alkyl aluminum, diammonium hydrogen phosphate 20
Part, 2 parts of calcium nitrate, 1 part of polyvinyl alcohol and 2 parts of ammonium molybdate.
Embodiment 2
A kind of New Electric Polymer, in parts by weight, including following component：30 parts of pyrrole monomer, 30 parts of acrylamide,
20 parts of benzene alkene, 6 parts of glass fibre, 10 parts of carbon fiber, 2 parts of carbon black, 2 parts of sodium tripolyphosphate, 2 parts of alkyl aluminum, diammonium hydrogen phosphate 40
Part, 6 parts of calcium nitrate, 3 parts of polyvinyl alcohol and 6 parts of ammonium molybdate.
Embodiment 3
A kind of New Electric Polymer, in parts by weight, including following component：25 parts of pyrrole monomer, 25 parts of acrylamide,
17 parts of benzene alkene, 4 parts of glass fibre, 7 parts of carbon fiber, 1.5 parts of carbon black, 1.5 parts of sodium tripolyphosphate, 1.5 parts of alkyl aluminum, phosphoric acid hydrogen two
3 parts of 30 parts of ammonium, 4 parts of calcium nitrate, 2 parts of polyvinyl alcohol and ammonium molybdate.
The present invention is by adding glass fibre, carbon in pyrrole monomer, acrylamide, benzene alkene and diammonium hydrogen phosphate group mixture
Big New Electric Polymer is made in fiber, carbon black, sodium tripolyphosphate, alkyl aluminum, there is provided New Electric Polymer
Heat endurance is strong, and easy to process, suitable for industrial mass production.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as
The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention
Rights protection scope in.
Claims (4)
- A kind of 1. New Electric Polymer, it is characterised in that：In parts by weight, including following component：Pyrrole monomer 20-30 Part, acrylamide 20-30 parts, benzene alkene 15-20 parts, glass fibre 2-6 parts, carbon fiber 5-10 parts, carbon black 1-2 parts, tripolyphosphate Sodium 1-2 parts, alkyl aluminum 1-2 parts, diammonium hydrogen phosphate 20-40 parts, calcium nitrate 2-6 parts, polyvinyl alcohol 1-3 parts and ammonium molybdate 2-6 parts.
- A kind of 2. New Electric Polymer according to claim 1, it is characterised in that：In parts by weight, including such as Lower component：20 parts of pyrrole monomer, 20 parts of acrylamide, 15 parts of benzene alkene, 2 parts of glass fibre, 5 parts of carbon fiber, 1 part of carbon black, trimerization 2 parts of 1 part of sodium phosphate, 1 part of alkyl aluminum, 20 parts of diammonium hydrogen phosphate, 2 parts of calcium nitrate, 1 part of polyvinyl alcohol and ammonium molybdate.
- A kind of 3. New Electric Polymer according to claim 1, it is characterised in that：In parts by weight, including such as Lower component：30 parts of pyrrole monomer, 30 parts of acrylamide, 20 parts of benzene alkene, 6 parts of glass fibre, 10 parts of carbon fiber, 2 parts of carbon black, trimerization 6 parts of 2 parts of sodium phosphate, 2 parts of alkyl aluminum, 40 parts of diammonium hydrogen phosphate, 6 parts of calcium nitrate, 3 parts of polyvinyl alcohol and ammonium molybdate.
- A kind of 4. New Electric Polymer according to claim 1, it is characterised in that：In parts by weight, including such as Lower component：25 parts of pyrrole monomer, 25 parts of acrylamide, 17 parts of benzene alkene, 4 parts of glass fibre, 7 parts of carbon fiber, 1.5 parts of carbon black, three 3 parts of 1.5 parts of polyphosphate sodium, 1.5 parts of alkyl aluminum, 30 parts of diammonium hydrogen phosphate, 4 parts of calcium nitrate, 2 parts of polyvinyl alcohol and ammonium molybdate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710814857.0A CN107629452A (en) | 2017-09-12 | 2017-09-12 | A kind of New Electric Polymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710814857.0A CN107629452A (en) | 2017-09-12 | 2017-09-12 | A kind of New Electric Polymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107629452A true CN107629452A (en) | 2018-01-26 |
Family
ID=61101895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710814857.0A Pending CN107629452A (en) | 2017-09-12 | 2017-09-12 | A kind of New Electric Polymer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107629452A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102924919A (en) * | 2012-10-25 | 2013-02-13 | 无锡市三力胶带厂 | Conductive polymer material |
| CN106589939A (en) * | 2015-10-15 | 2017-04-26 | 徐文智 | Conductive high polymer material |
-
2017
- 2017-09-12 CN CN201710814857.0A patent/CN107629452A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102924919A (en) * | 2012-10-25 | 2013-02-13 | 无锡市三力胶带厂 | Conductive polymer material |
| CN106589939A (en) * | 2015-10-15 | 2017-04-26 | 徐文智 | Conductive high polymer material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104629187B (en) | A kind of multi-functional PP composite material and preparation method thereof | |
| CN105368043A (en) | Graphene thermal conductive plastic, and preparation method thereof | |
| CN105199304A (en) | Polymer composite high in heat-conducting property | |
| CN107501606A (en) | A kind of phosphorous, nitrogen Fire Retardant of The Expoxy Resin and preparation method thereof | |
| CN105111687B (en) | A kind of halogen-free ethoxyline resin antiflaming agent and preparation method thereof | |
| CN102295740A (en) | Polyamideimide cured epoxy resin composite material and preparation method thereof | |
| CN106589939A (en) | Conductive high polymer material | |
| CN103382378A (en) | Weather-resistant epoxy adhesive | |
| CN107629452A (en) | A kind of New Electric Polymer | |
| CN106751762A (en) | Corrosion-resistant macromolecular material | |
| CN105111434B (en) | A kind of composite of aniline and graphene, preparation method and applications | |
| CN107573631A (en) | A kind of conducting polymer composite | |
| CN107418112A (en) | A kind of conductivity type high polymer material | |
| CN102924919A (en) | Conductive polymer material | |
| CN116574430B (en) | Water-based environment-friendly wear-resistant epoxy floor paint and preparation method thereof | |
| CN107353558A (en) | A kind of conducting polymer composite | |
| CN110194924A (en) | A kind of anti-corrosive powder paint and preparation method thereof | |
| CN107236127A (en) | A kind of preparation method of compound monomer denatured conductive material | |
| CN108864894A (en) | A kind of computer high efficiency and heat radiation coating and preparation method thereof | |
| CN107417972A (en) | A kind of preparation method of quaternary ammonium salt-modified polythiophene intercalated graphite alkene | |
| CN107286328A (en) | A kind of preparation method for the polythiophene electromagnetic material that methylates | |
| CN104292395A (en) | Macromolecular polymerized phenol modified polydicyclopentadiene material and preparation method thereof | |
| CN107501528A (en) | The preparation of poly- (the 5 aldehyde radical indoles) nano composite material of graphene | |
| CN107383340A (en) | A kind of DOPO modified anhydrides ethoxyline resin antiflaming curing agent and preparation method thereof | |
| Zhu et al. | In situ synthesis of graphene/poly (aniline‐Co‐5‐aminosalicylic acid) nanocomposites toward improved electroactivity |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180126 |