CN107619197A - A kind of compound caesium tungsten nanometer thermal insulation coating glass and its manufacture method - Google Patents
A kind of compound caesium tungsten nanometer thermal insulation coating glass and its manufacture method Download PDFInfo
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- CN107619197A CN107619197A CN201710966141.2A CN201710966141A CN107619197A CN 107619197 A CN107619197 A CN 107619197A CN 201710966141 A CN201710966141 A CN 201710966141A CN 107619197 A CN107619197 A CN 107619197A
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Abstract
Following components is included the invention discloses a kind of compound caesium tungsten nanometer thermal insulation coating glass, including glass, and coated on the compound caesium tungsten film layer on the glass, the compound caesium tungsten film layer：Compound caesium tungsten solution 5% 15%, resin compound 50 60%, solvent 30%, other additives 3 5%.Using compound caesium tungsten film layer as heat-barrier material, there is high selectivity to solar spectrum, i.e. to 780nm~2500nm near-infrared absorption more than 90%, by absorption of the mixture to ultraviolet such as the resins that is added in film layer up to more than 99%, above-mentioned compound caesium tungsten nanometer thermal insulation coating glass has high-barrier effect to infrared ray and ultraviolet, visible transmission is influenceed smaller, light pollution can be greatly decreased, reduce shading coefficient, improve photo-thermal ratio, effectively improve summer heat insulation and heat control efficiency, improve comfortableness, reduce air conditioning energy consumption, reach good effects of energy conservation and environmental protection.
Description
Technical field
The present invention relates to coated glass field, more particularly to a kind of compound caesium tungsten nanometer thermal insulation coating glass and its manufacture
Method.
Background technology
Summer heat, the strong irradiation for obstructing the sun are particularly important for in-car, the indoor comfortable environment of offer,
Solar irradiation heat is got in or in-car refrigerating capacity, the consumption of automobile for increasing air-conditioning about per square meter 800w through glass
Oil and the dynamic property for reducing automobile, strong ultraviolet also can produce injury to the skin of people, or even can trigger cutaneum carcinoma, be
This can use heat-protecting glass, or solar film is pasted on vehicle window, and heat-insulated film layer glass of the prior art is more using such as：Oxidation
Tin, tin-antiomony oxide (ATO) or tin indium oxide (ITO), titanium dioxide (TiO2) etc., or the nano modified material of identical element, every
Thermal effect is difficult to meet the needs of people, and solar film is pasted on vehicle window and also brings along a series of problem, such as driving safety etc.,
As society is to energy-saving and environmental protection, the continuous attention of comfortableness requirement, the glass with higher heat-proof quality can be in vehicle glass city
Preferentially applied field.
The content of the invention
For overcome the deficiencies in the prior art, an object of the present invention is to provide a kind of compound caesium tungsten nano heat-insulating
Coated glass, to the heat-proof quality of further lifting heat-protecting glass.
The second object of the present invention is to provide a kind of manufacture method of above-mentioned compound caesium tungsten nanometer thermal insulation coating glass,
It has that technique is simple, easy to operate, the characteristics of being adapted to industrialized production.
An object of the present invention adopts the following technical scheme that realization：
A kind of compound caesium tungsten nanometer thermal insulation coating glass, including glass, and coated on the compound caesium on the glass
Change tungsten film layer, the compound caesium tungsten film layer includes following components：Compound caesium tungsten solution 10%-15%, resin compound 50-
60%, solvent 30%, other additives 3-5%.
Further, the compound caesium tungsten solution includes following components：Compound caesium tungsten CsxWO3Ay30-35%, its
In 0<x<0.5,0<y<0.5, ethyl acetate 55-60%, propylene glycol methyl ether acetate 5-10%.
Further, the resin compound includes following components：Modified acrylic silicic acid resin 40-50%, nanometer two
Silica dispersion liquid 20-25%, butyl glycol ether 25-30%, ethyl acetate 5%.
Further, the solvent is butyl glycol ether 80%, isopropanol 20%.
Further, other described additives are defoamer 20-40%, levelling agent 20-40%, ultra-violet absorber 20-
40%.
Further, the glass is thickness 2-8mm normal transparent plate glass or hot bending arc glass, described compound
The thickness of dry film of caesium tungsten film layer is 10-25 μm.
Further, be additionally provided with stiffened film layer on the compound caesium tungsten film layer, the protective layer be through UV solidifications or
The nano-organosilicon modified resin of heat cure.
The second object of the present invention adopts the following technical scheme that realization：
A kind of manufacture method of above-mentioned compound caesium tungsten nanometer thermal insulation coating glass, comprises the following steps：
(1) compound caesium tungsten membrane layer pulp is prepared：By compound caesium tungsten solution, resin mixture liquor, solvent and other add
Add agent, in proportion, half an hour is filtered, mixed, stirred and then stood under ten thousand grades of clean environments, produce compound caesium tungsten
Membrane layer pulp；
(2) pretreatment of glass：Carried out under ten thousand grades of cleanings, first using the cleaning of common round brush and then ultrasonic pure water
Cleaning, the drying of ordinary hot air knife, remove moisture film in the drying of 60-80 DEG C of tunnel oven, destatic；
(3) sprayed protection：Blocked in region beyond will be to be sprayed；
(4) film layer adhesive agent is sprayed：Film layer adhesive agent is sprayed in area to be sprayed；
(5) compound caesium tungsten slurry is sprayed：3D sprayings are carried out simultaneously using more spray guns, the sensor installed on spray gun can
To ensure that shower nozzle is vertical with direction with the distance of glass surface；
(6) levelling conjunctiva is completed through 1-3 minutes；
(7) heating, drying：The glass that above-mentioned steps (6) are completed to levelling conjunctiva is inputted to tunnel type baking oven, through 8-10 points
Clock is warming up to 160 DEG C, continues heating 15 minutes, is cooled to room temperature and produces above-mentioned compound caesium tungsten nanometer thermal insulation coating glass.
Further, in addition to spraying stiffened film layer step：(1) above-mentioned compound caesium tungsten nanometer thermal insulation coating glass is entered
Row pretreatment, make film layer contact angle be less than 30 degree, then using spray gun carry out 3D sprayings, the spray gun be provided with make holding spray gun with
The vertical sensor of glass surface；(2) solidify：After the spraying of stiffened film layer being completed by above-mentioned steps (1), progress UV solidifications, or
Heat cure is carried out at a temperature of 100 DEG C；
Further, the film layer adhesive agent is：Isopropanol 96-98%, siloxanes 2-4%.
Compared with prior art, the beneficial effects of the present invention are：Compound caesium tungsten nanometer thermal insulation coating provided by the invention
Glass, using compound caesium tungsten as heat-barrier material, there is high selectivity to solar spectrum, i.e., to 780nm~2500nm
Near-infrared heat absorption more than 90%, to ultraviolet radiation absorption up to more than 99%, there is high-barrier work to infrared ray and ultraviolet
With, while it is smaller on visible transmission influence, light pollution can be greatly decreased, reduce shading coefficient, improve photo-thermal ratio, effectively lifting
Summer heat insulation and heat control efficiency, improve comfortableness, reduce air conditioning energy consumption, reaching good effects of energy conservation and environmental protection.
Brief description of the drawings
Fig. 1 is the structural representation of the compound caesium tungsten nanometer thermal insulation coating glass of the present invention；
Fig. 2 is the flow chart of the compound caesium tungsten nanometer thermal insulation coating glass preparation of the present invention；
In figure：1st, glass；2nd, compound caesium tungsten film layer.
Embodiment
Below, with reference to accompanying drawing and embodiment, the present invention is described further, it is necessary to which explanation is, not
Under the premise of afoul, new implementation can be formed between various embodiments described below or between each technical characteristic in any combination
Example.
In the present invention, if not refering in particular to, all percentages are unit of weight, and used equipment and raw material etc. can be from
Market is bought or commonly used in the art, the method in following embodiments, is the conventional method of this area unless otherwise instructed.
A kind of compound caesium tungsten nanometer thermal insulation coating glass, including glass, and the compound caesium on the glass
Tungsten film layer, as shown in figure 1, wherein glass be thickness 2-8mm normal transparent plate glass or hot bending arc glass, compound caesium
The thickness of tungsten film layer is 10 μm -25 μm, and the slurry of above-mentioned compound caesium tungsten film layer is prepared from the following components：Compound caesium tungsten
Solution：5%-15%, the compound caesium tungsten solution include following components：Compound caesium tungsten CsxWO3Ay30-35%, wherein 0<x<
0.5,0<y<0.5, ethyl acetate 55-60%, propylene glycol methyl ether acetate 5-10%；Resin compound：50-60%, the resin
Mixture includes following components：Modified acrylic silicic acid resin 40-50%, nano silicon dioxide dispersion 20-25%, ethylene glycol
Butyl ether 25-30%, ethyl acetate 5%；Solvent：30%, specially butyl glycol ether, isopropanol, dosage are butyl glycol ether
(BCS) 80%, isopropanol (IPA) 20%.；Other additives：5%, wherein other additives are defoamer 20-40%, levelling
Agent 20-40%, ultra-violet absorber 20-40%.
A kind of manufacturing process of above-mentioned compound caesium tungsten nanometer thermal insulation coating glass is illustrated in figure 2, is specifically included as follows
Step：
(1) compound caesium tungsten membrane layer pulp is prepared：By compound caesium tungsten solution, resin mixture liquor, solvent and other add
Add agent, in proportion, half an hour is filtered, mixed, stirred and then stood under ten thousand grades of clean environments, produce compound caesium tungsten
Membrane layer pulp；
(2) pretreatment of glass：Carried out under ten thousand grades of cleanings, first using the cleaning of common round brush and then ultrasonic pure water
Cleaning, the drying of ordinary hot air knife, remove moisture film in the drying of 60-80 DEG C of tunnel oven, destatic；
(3) sprayed protection：Blocked in region beyond will be to be sprayed；
(4) film layer adhesive agent is sprayed：Film layer adhesive agent is sprayed in area to be sprayed, the film layer adhesive agent is：Isopropanol
96-98%, siloxanes 2-4%；
(5) compound caesium tungsten slurry is sprayed：3D sprayings are carried out simultaneously using more spray guns, the sensor installed on spray gun can
To ensure that shower nozzle is vertical with direction with the distance of glass surface；
(6) levelling conjunctiva is completed through 1-3 minutes；
(7) heating, drying：The glass that above-mentioned steps (6) are completed to levelling conjunctiva is inputted to tunnel type baking oven, through 8-10 points
Clock is warming up to 160 DEG C, continues heating 15 minutes, is cooled to room temperature and produces above-mentioned compound caesium tungsten nanometer thermal insulation coating glass.
Can also be as follows in above-mentioned compound caesium tungsten nanometer thermal insulation coating glass-coating stiffened film layer, step：(1) will be above-mentioned multiple
Close caesium tungsten nanometer thermal insulation coating glass to be pre-processed, film layer contact angle is less than 30 degree, then 3D sprayings are carried out using spray gun,
The spray gun, which is provided with, makes holding spray gun and the vertical sensor of glass surface spacing；(2) solidify：Completed by above-mentioned steps (1)
After the spraying of stiffened film layer, UV solidifications are carried out, or heat cure is carried out at a temperature of 100 DEG C；
By using compound caesium tungsten as heat-barrier material, have to solar spectrum it is high to selectivity, i.e., to 780nm~
2500nm near-infrared heat absorption more than 90%, to ultraviolet radiation absorption up to more than 99%, there is height to infrared ray and ultraviolet
Iris action, visible transmission is had substantially no effect on, shading coefficient can be effectively reduced, improve photo-thermal ratio, therefore improve summer
Heat insulation and heat control efficiency, improve comfortableness, reduce air conditioning energy consumption, reaching good effects of energy conservation and environmental protection.The coated glass is inhaled for light
Receipts type, it is seen that light reflectivity is less than 8%, and light pollution, particularly reduction vehicle glass reflection solar glare can be greatly decreased and cause
It is dazzling, so as to increase traffic safety, while coated glass provided by the invention is unshielded to wireless signal, including mobile phone signal
With GPS etc., contribute to application of the electronic product on automobile, by spraying stiffened film layer, further increase its hardness, can be extensive
Applied on automobile, and various buildings.
Embodiment 1
(1) 1kg compound caesium tungsten membrane layer pulps to be sprayed are prepared：By compound caesium tungsten 42g, ethyl acetate 72g, the third two
Alcohol methyl ether acetate 6g, modified acrylic silicic acid resin 220g, nano silicon dioxide dispersion 137.5g, butyl glycol ether
165g, ethyl acetate 27.5, defoamer 10g, levelling agent 10g, ultra-violet absorber 10g, butyl glycol ether 240g, isopropanol
60g is filtered under ten thousand grades of clean environments, mixed, being stirred, standing half an hour, is completed membrane layer pulp and is prepared；
(2) it is that 300mm*300mm*5mm normal transparents plate glass carries out prerinse by specification to be processed, adds cleaning
Liquid carries out mechanical cleaning using round brush, then carries out multiple depth cleaning in pure water using ultrasonic wave, it is ensured that glass surface connects
Feeler is less than 20 degree；
(3) glass cleaned is delivered to preheating tunnel oven, temperature control dries moisture film at 60 DEG C；
(4) electrostatic of glass surface to be sprayed is eliminated via static removal equipment；
(5) glass to be sprayed is positioned, while the region beyond spraying is blocked, prevent spraying to be splashed to it
His position；
(6) adhesive agent is sprayed in glass surface using spray gun, the composition of the adhesive agent is：Isopropanol 96g, siloxanes
4g；
(7) the compound caesium tungsten membrane layer pulp for taking appropriate step (1) to prepare, using the more spray guns on robotic arm
3D is sprayed, and is connected with sensor on spray gun, guiding spray gun and the distance between glass keep it is constant with it is vertical；Wet-film thickness
40um, stand levelling conjunctiva within 3 minutes after spraying；
(8) glass that above-mentioned steps (7) are completed to levelling conjunctiva is delivered to tunnel type baking oven, and 160 were warming up to through 9 minutes
DEG C, continue heating 15 minutes, be cooled to room temperature both above-mentioned compound caesium tungsten nanometer thermal insulation coating glass.
Embodiment 2
(1) 1kg compound caesium tungsten membrane layer pulps to be sprayed are prepared:By compound caesium tungsten 30g, ethyl acetate 60g, the third two
Alcohol methyl ether acetate 10g, modified acrylic silicic acid resin 252g, nano silicon dioxide dispersion 112g, butyl glycol ether 168g,
Ethyl acetate 28g, defoamer 16g, levelling agent 16g, ultra-violet absorber 8g, butyl glycol ether 240g, isopropanol 80g are at ten thousand grades
Filtered, mixed under clean environment, being stirred, standing half an hour, completed membrane layer pulp and prepare；
(2) the normal transparent hot bending arc glass that specification to be processed is 300mm*300mm*5mm is subjected to prerinse, added
Enter cleaning fluid and carry out mechanical cleaning using round brush, then carry out multiple depth cleaning in pure water using ultrasonic wave, it is ensured that glass
Surface contact angle is less than 20 degree, and when particularly cleaning, glass bending radian is consistent with direct of travel, the transmitting mechanical of cleaning machine
Device will work good " the wave traveling " of arc glass；
(3) glass will be cleaned and be delivered to tunnel oven, temperature control dries moisture film at 60 DEG C；
(4) electrostatic of glass surface to be sprayed is eliminated via static removal equipment；
(5) glass to be sprayed is positioned, while the region beyond spraying is blocked, prevent spraying to be splashed to it
His position；
(6) adhesive agent is sprayed in glass surface using spray gun, the composition of the adhesive agent is：Isopropanol 97g, siloxanes
4g；
(7) the compound caesium tungsten membrane layer pulp for taking appropriate step (1) to prepare, using the more spray guns on robotic arm
3D is sprayed, and is connected with sensor on spray gun, guiding spray gun and the distance between glass keep it is constant with it is vertical；Spray wet-film thickness
30um, stand levelling conjunctiva within latter 3 minutes；
(8) glass that above-mentioned steps (7) are completed to levelling conjunctiva is delivered to tunnel type baking oven, and 160 were warming up to through 9 minutes
DEG C, continue heating 15 minutes, be cooled to room temperature both above-mentioned compound caesium tungsten nanometer thermal insulation coating glass.
Embodiment 3
(1) compound caesium tungsten membrane layer pulp to be sprayed is prepared:By compound caesium tungsten 49.5g, ethyl acetate 85.5g, third
Glycol methyl ether acetate 15g, modified acrylic silicic acid resin 250g, nano silicon dioxide dispersion 100g, butyl glycol ether
125g, ethyl acetate 25g, defoamer 20g, levelling agent 10g, ultra-violet absorber 20g, butyl glycol ether 240g, isopropanol 80g
Filtered, mixed under ten thousand grades of clean environments, being stirred, standing half an hour, completed membrane layer pulp and prepare；
(2) the normal transparent hot bending arc glass that specification to be processed is 300mm*300mm*5mm is subjected to prerinse, it is general
Penetrating bright hot bending arc glass carries out prerinse, adds cleaning fluid and carries out mechanical cleaning using round brush, is then existed using ultrasonic wave
Multiple depth cleaning is carried out in pure water, it is ensured that glass surface contact angle is less than 20 degree, when particularly cleaning, and glass bending radian will
Consistent with direct of travel, the transfer mechanism of cleaning machine will work good " the wave traveling " of arc glass；
(3) glass will be cleaned and be delivered to tunnel oven, temperature control dries moisture film at 80 DEG C；
(4) electrostatic of glass surface to be sprayed is eliminated via static removal equipment；
(5) glass to be sprayed is positioned, while the region beyond spraying is blocked, prevent spraying to be splashed to it
His position；
(6) film layer adhesive agent is sprayed in glass surface using spray gun, the composition of the adhesive agent is：Isopropanol 96g, silica
Alkane 4g；
(7) the compound caesium tungsten membrane layer pulp for taking appropriate step (1) to prepare, using the more spray guns on robotic arm
3D is sprayed, and is connected with sensor on spray gun, guiding spray gun and the distance between glass keep it is constant with it is vertical；Wet-film thickness
40um, stand levelling conjunctiva within 3 minutes after spraying；
(8) glass that above-mentioned steps (7) are completed to levelling conjunctiva is delivered to tunnel type baking oven, and 160 were warming up to through 9 minutes
DEG C, continue heating 15 minutes, be cooled to room temperature both above-mentioned compound caesium tungsten nanometer thermal insulation coating glass.
Embodiment 4
(1) the compound caesium tungsten nanometer thermal insulation coating glass for obtaining embodiment 2 is pre-processed, and makes film layer contact angle small
In 25 °, then one of stiffened film using UV solidifications or the heat cure less than 100 DEG C is sprayed, it is hard after the stiffened film slurry curing of outsourcing
Degree need to reach 5H pencil hardness, need to require adjustment UV solidification energies or heat curing temperature according to stiffened film slurry during solidification, both
Compound caesium tungsten nanometer thermal insulation coating glass with stiffened film layer.
Comparative example 1：Commercially available solar-control glazing.
Comparative example 2：Commercially available online low emissivity glass (low-E).
According to ISO9050:2003《Building glass visible transmission ratio, the direct transmittance of sunshine, solar energy total transmission
Than, measure of the ultraviolet (uv) transmission when about glass pane parameter》, environmental condition is Chinese winter, summer criterion calculation condition.Adopt
Instrument and equipment is S-45Lambda950 ultraviolet-uisible spectrophotometers, S-47Spectrum100 fourier-transform infrared light
Spectrometer, environment temperature are 19 DEG C, and environment relative temperature is 45%RH, detect embodiment 1 to 4, comparative example 1-2 ultraviolet respectively
Transmittance, it is seen that transmittance, total solar energy transmittance, near-infrared transmission ratio are as a result as shown in the table：
Table 1
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 | Comparative example 2 |
| Ultraviolet (uv) transmission ratio (%) | 0.0 | 0.0 | 0.0 | 0.0 | 45.0 | 25.0 |
| Visible transmission ratio (%) | 71.8 | 71.0 | 71.0 | 70.0 | 66.0 | 78.6 |
| Total solar energy transmittance (%) | 50.7 | 50.1 | 50.0 | 48.0 | 68.0 | 69.7 |
| Near-infrared transmission ratio (%) | 5.5 | 5.4 | 5.4 | 4.5 | 30 | 20.1 |
It is can be seen that from upper table when visible transmission is 70%, coated glass total solar energy transmittance of the present invention, purple
Outside line transmittance, near infrared ray are all far below comparative example, represent that its is heat-insulated, is all significantly carried every ultraviolet, energy-conservation and other effects
Rise.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (10)
1. a kind of compound caesium tungsten nanometer thermal insulation coating glass, it is characterised in that including glass, and coated on the glass
Compound caesium tungsten film layer, the compound caesium tungsten film layer includes following components：Compound caesium tungsten solution 10%-15%, resin
Mixture 50-60%, solvent 30%, other additives 3-5%.
A kind of 2. compound caesium tungsten nanometer thermal insulation coating glass according to claim 1, it is characterised in that the compound caesium
Tungsten solution includes following components：Compound caesium tungsten CsxWO3Ay30-35%, wherein 0<x<0.5,0<y<0.5, ethyl acetate 55-
60%, propylene glycol methyl ether acetate 5-10%.
A kind of 3. compound caesium tungsten nanometer thermal insulation coating glass according to claim 1, it is characterised in that the resin mixing
Thing includes following components：Modified acrylic silicic acid resin 40-50%, nano silicon dioxide dispersion 20-25%, butyl glycol ether
25-30%, ethyl acetate 5%.
4. a kind of compound caesium tungsten nanometer thermal insulation coating glass according to claim 1, it is characterised in that the solvent is second
Glycol butyl ether 80%, isopropanol 20%.
A kind of 5. compound caesium tungsten nanometer thermal insulation coating glass according to claim 1, it is characterised in that other described additions
Agent is defoamer 20-40%, levelling agent 20-40%, ultra-violet absorber 20-40%.
6. a kind of compound caesium tungsten nanometer thermal insulation coating glass according to claim 1, it is characterised in that the glass is thickness
2-8mm normal transparent plate glass or hot bending arc glass is spent, the thickness of dry film of the compound caesium tungsten film layer is 10-25 μ
m。
7. a kind of compound caesium tungsten nanometer thermal insulation coating glass according to claim 1, it is characterised in that in the compound caesium
Change and stiffened film layer is additionally provided with tungsten film layer, the protective layer is the nano-organosilicon modified resin through UV solidifications or heat cure.
A kind of 8. manufacture method of compound caesium tungsten nanometer thermal insulation coating glass as claimed in claim 1, it is characterised in that bag
Include following steps：
(1) compound caesium tungsten membrane layer pulp is prepared：By compound caesium tungsten solution, resin mixture liquor, solvent and other additives,
In proportion, half an hour is filtered, is mixed, stirred and then stood under ten thousand grades of clean environments, produces compound caesium tungsten film layer slurry
Material；
(2) pretreatment of glass：Carried out under ten thousand grades of cleanings, cleaned first using the cleaning of common round brush and then ultrasonic pure water,
The drying of ordinary hot air knife, remove moisture film in the drying of 60-80 DEG C of tunnel oven, destatic；
(3) sprayed protection：Blocked in region beyond will be to be sprayed；
(4) film layer adhesive agent is sprayed：Film layer adhesive agent is sprayed in area to be sprayed；
(5) compound caesium tungsten slurry is sprayed：3D sprayings are carried out simultaneously using more spray guns, the sensor installed on spray gun can be true
It is vertical with direction with the distance of glass surface to protect shower nozzle；
(6) levelling conjunctiva is completed through 1-3 minutes；
(7) heating, drying：The glass that above-mentioned steps (6) are completed to levelling conjunctiva is inputted to tunnel type baking oven, is risen through 8-10 minutes
Temperature continues heating 15 minutes, is cooled to room temperature and produces above-mentioned compound caesium tungsten nanometer thermal insulation coating glass to 160 DEG C.
9. the manufacture method of compound caesium tungsten nanometer thermal insulation coating glass according to claim 8, it is characterised in that also wrap
Include spraying stiffened film layer step：(1) above-mentioned compound caesium tungsten nanometer thermal insulation coating glass is pre-processed, makes film layer contact angle
3D sprayings are carried out less than 30 degree, then using spray gun, the spray gun, which is provided with, makes holding spray gun and the vertical sensor of glass surface；
(2) solidify：After completing the spraying of stiffened film layer by above-mentioned steps (1), UV solidifications are carried out, or heat cure is carried out at a temperature of 100 DEG C.
A kind of 10. manufacture method of compound caesium tungsten nanometer thermal insulation coating glass according to claim 8, it is characterised in that
The film layer adhesive agent is：Isopropanol 96-98%, siloxanes 2-4%.
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| CN112961587A (en) * | 2021-02-07 | 2021-06-15 | 三棵树(上海)新材料研究有限公司 | High-stain-resistance glass heat-insulating coating based on cesium tungsten bronze and preparation method thereof |
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