CN107603078A - Luminous antibiotic plastic and preparation method thereof - Google Patents
Luminous antibiotic plastic and preparation method thereof Download PDFInfo
- Publication number
- CN107603078A CN107603078A CN201711039579.2A CN201711039579A CN107603078A CN 107603078 A CN107603078 A CN 107603078A CN 201711039579 A CN201711039579 A CN 201711039579A CN 107603078 A CN107603078 A CN 107603078A
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- CN
- China
- Prior art keywords
- luminous
- parts
- antibiotic plastic
- silver nitrate
- pvc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920003023 plastic Polymers 0.000 title claims abstract description 37
- 239000004033 plastic Substances 0.000 title claims abstract description 37
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 10
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 20
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 18
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 15
- UDHHXYYEUWKHMF-UHFFFAOYSA-N 6-butoxy-6-oxohexanoic acid Chemical class CCCCOC(=O)CCCCC(O)=O UDHHXYYEUWKHMF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005084 Strontium aluminate Substances 0.000 claims abstract description 13
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 13
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 10
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 10
- 239000008187 granular material Substances 0.000 claims description 10
- 238000004898 kneading Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of luminous antibiotic plastic, belong to plastic products technology field.The luminous antibiotic plastic of the present invention, is made up of the component of following parts by weight：100~102 parts of PVC, 1~3 part of chlorinated butyl adipate, 1~3 part of nano titanium oxide, 0.7~1 part of magnesium hydroxide, 0.5~0.8 part of talcum powder, 0.3~0.5 part of copper sulphate, SrAl2O4：Eu2+1~5 part, 0.5~0.8 part of silver nitrate.Luminous antibiotic plastic produced by the present invention, good anti-bacterial effect, cost are low；"dead" pollution, the light of green can be sent at night；Plastics produced by the present invention can resist cold, and cold tolerance is notable.
Description
Technical field
The present invention relates to a kind of luminous antibiotic plastic, belong to plastic products technology field.
Background technology
With industrial expansion, plastic product has obtained more and more extensive use.And the usual work(of current plastic products
Can be single, the demand of multi-functional composite plastic also increased.
The content of the invention
The invention solves first technical problem be to provide a kind of luminous antibiotic plastic.
Luminous antibiotic plastic, is made up of the component of following parts by weight：100~102 parts of PVC, chlorinated butyl adipate
1~3 part, 1~3 part of nano titanium oxide, 0.7~1 part of magnesium hydroxide, 0.5~0.8 part of talcum powder, 0.3~0.5 part of copper sulphate,
SrAl2O4：Eu2+1~5 part, 0.5~0.8 part of silver nitrate.
Preferably, it is made up of the component of following parts by weight：100~101 parts of PVC, chlorinated butyl adipate 2~3
Part, 2~3 parts of nano titanium oxide, 0.7~0.9 part of magnesium hydroxide, 0.7~0.8 part of talcum powder, 0.4~0.5 part of copper sulphate,
SrAl2O4：Eu2+1~3 part, 0.6~0.8 part of silver nitrate.
It is further preferred that it is made up of the component of following parts by weight：100 parts of PVC, 2 parts of chlorinated butyl adipate,
3 parts of nano titanium oxide, 0.7 part of magnesium hydroxide, 0.8 part of talcum powder, 0.4 part of copper sulphate, SrAl2O4：Eu2+2 parts, silver nitrate
0.8 part.
The invention solves second technical problem be to provide a kind of preparation method of luminous antibiotic plastic.
The preparation method of luminous antibiotic plastic, is prepared according to the following steps：
A, nano titanium oxide, talcum powder and silver nitrate solution are mixed, 2~3h of ultrasound at 40~55 DEG C, then stood
More than 24h, then dried at 70~85 DEG C, crush, antibacterial granule is made；
B, PVC is added in kneading machine and is preheated to 150~160 DEG C, add chlorinated butyl adipate, hydroxide
Magnesium, copper sulphate, SrAl2O4：Eu2+With step A made from antibacterial granule mix, be warming up to 190~200 DEG C and be kneaded, extrude
Shaping.
Preferably, in step A, nano titanium oxide, talcum powder and silver nitrate solution are mixed, the ultrasonic 3h at 45 DEG C,
24h is stood again, then is dried at 85 DEG C.
Preferably, in step B, PVC is added in kneading machine and is preheated to 155 DEG C.
Preferably, in step B, it is warming up at 200 DEG C and is kneaded.
Beneficial effects of the present invention：
1st, luminous antibiotic plastic produced by the present invention, good anti-bacterial effect, cost are low.
2nd, luminous antibiotic plastic "dead" pollution produced by the present invention, the light of green can be sent at night.
3rd, plastics produced by the present invention can resist cold, and cold tolerance is notable.
Embodiment
The invention solves first technical problem be to provide a kind of luminous antibiotic plastic.
Luminous antibiotic plastic, is made up of the component of following parts by weight：100~102 parts of PVC, chlorinated butyl adipate
1~3 part, 1~3 part of nano titanium oxide, 0.7~1 part of magnesium hydroxide, 0.5~0.8 part of talcum powder, 0.3~0.5 part of copper sulphate,
SrAl2O4：Eu2+1~5 part, 0.5~0.8 part of silver nitrate.
It is to increase the cold resistance of plastics to add chlorinated butyl adipate, makes plastics of the invention in lower temperature
Under can also use.
The addition of copper sulphate can improve the mildew resistance of plastics.
Preferably, it is made up of the component of following parts by weight：100~101 parts of PVC, chlorinated butyl adipate 2~3
Part, 2~3 parts of nano titanium oxide, 0.7~0.9 part of magnesium hydroxide, 0.7~0.8 part of talcum powder, 0.4~0.5 part of copper sulphate,
SrAl2O4：Eu2+1~3 part, 0.6~0.8 part of silver nitrate.
It is further preferred that it is made up of the component of following parts by weight：100 parts of PVC, 2 parts of chlorinated butyl adipate,
3 parts of nano titanium oxide, 0.7 part of magnesium hydroxide, 0.8 part of talcum powder, 0.4 part of copper sulphate, SrAl2O4：Eu2+2 parts, silver nitrate
0.8 part.
The invention solves second technical problem be to provide a kind of preparation method of luminous antibiotic plastic.
The preparation method of luminous antibiotic plastic, is prepared according to the following steps：
A, nano titanium oxide, talcum powder and silver nitrate solution are mixed, 2~3h of ultrasound at 40~55 DEG C, then stood
More than 24h, then dried at 70~85 DEG C, crush, antibacterial granule is made；
Using nano titanium oxide and talcum powder while the carrier as silver ion, the loss of silver ion is reduced, improves it
Utilization rate.
B, PVC is added in kneading machine and is preheated to 150~160 DEG C, add chlorinated butyl adipate, hydroxide
Magnesium, copper sulphate, SrAl2O4：Eu2+With step A made from antibacterial granule mix, be warming up to 190~200 DEG C and be kneaded, extrude
Shaping.
Preferably, in step A, nano titanium oxide, talcum powder and silver nitrate solution are mixed, the ultrasonic 3h at 45 DEG C,
24h is stood again, then is dried at 85 DEG C.
Preferably, in step B, PVC is added in kneading machine and is preheated to 155 DEG C.
Preferably, in step B, it is warming up at 200 DEG C and is kneaded.
The embodiment of the present invention is further described with reference to embodiment, therefore not limited the present invention
System is among described scope of embodiments.
Embodiment 1
A, nano titanium oxide 30g, talcum powder 8g and silver nitrate solution (silver nitrate 8g, concentration 50%) are mixed,
Ultrasonic 3h at 45 DEG C, then 24h is stood, then dried at 85 DEG C, crush, antibacterial granule is made；
B, 1000gPVC is added in kneading machine and is preheated to 150 DEG C, add 20g chlorinated butyls adipate, 7g hydrogen
Magnesia, 4g copper sulphate, 20gSrAl2O4：Eu2+With step A made from antibacterial granule mix, be warming up to 200 DEG C and be kneaded,
Extrusion forming.
Embodiment 2
A, nano titanium oxide 20g, talcum powder 7g and silver nitrate solution (silver nitrate 6g, concentration 50%) are mixed,
Ultrasonic 2h at 55 DEG C, then 24h is stood, then dried at 75 DEG C, crush, antibacterial granule is made；
B, 1020gPVC is added in kneading machine and is preheated to 160 DEG C, add 28g chlorinated butyls adipate, 9g hydrogen
Magnesia, 5g copper sulphate, 30gSrAl2O4：Eu2+With step A made from antibacterial granule mix, be warming up to 190 DEG C and be kneaded,
Extrusion forming.
Claims (7)
1. luminous antibiotic plastic, it is characterised in that the luminous antibiotic plastic is made up of the component of following parts by weight：PVC 100
~102 parts, 1~3 part of chlorinated butyl adipate, 1~3 part of nano titanium oxide, 0.7~1 part of magnesium hydroxide, talcum powder
0.5~0.8 part, 0.3~0.5 part of copper sulphate, SrAl2O4：Eu2+1~5 part, 0.5~0.8 part of silver nitrate.
2. luminous antibiotic plastic according to claim 1, it is characterised in that the luminous antibiotic plastic is by following parts by weight
Component composition：100~101 parts of PVC, 2~3 parts of chlorinated butyl adipate, 2~3 parts of nano titanium oxide, hydroxide
0.7~0.9 part of magnesium, 0.7~0.8 part of talcum powder, 0.4~0.5 part of copper sulphate, SrAl2O4：Eu2+1~3 part, silver nitrate 0.6~
0.8 part.
3. the luminous antibiotic plastic according to any one of claim 1~2, it is characterised in that the luminous antibiotic plastic by
The component composition of following parts by weight：100 parts of PVC, 2 parts of chlorinated butyl adipate, 3 parts of nano titanium oxide, magnesium hydroxide
0.7 part, 0.8 part of talcum powder, 0.4 part of copper sulphate, SrAl2O4：Eu2+2 parts, 0.8 part of silver nitrate.
4. the preparation method of the luminous antibiotic plastic described in any one of claims 1 to 3, it is characterised in that the luminous antibacterial
Plastics are prepared according to the following steps：
A, by nano titanium oxide, talcum powder and silver nitrate solution mix, 2~3h of ultrasound at 40~55 DEG C, then stand 24h with
On, then dried at 70~85 DEG C, crush, antibacterial granule is made；
B, PVC is added in kneading machine and is preheated to 150~160 DEG C, add chlorinated butyl adipate, magnesium hydroxide, sulphur
Sour copper, SrAl2O4：Eu2+With step A made from antibacterial granule mix, be warming up to 190~200 DEG C and be kneaded, extrusion forming.
5. the preparation method of luminous antibiotic plastic according to claim 4, it is characterised in that in step A, by nano-silica
Change titanium, talcum powder and silver nitrate solution to mix, the ultrasonic 3h at 45 DEG C, then stand 24h, then dried at 85 DEG C.
6. the preparation method of the luminous antibiotic plastic according to claim 4 or 5, it is characterised in that in step B, PVC is added
155 DEG C are preheated in kneading machine.
7. the preparation method of luminous antibiotic plastic according to claim 4, it is characterised in that in step B, be warming up to 200
It is kneaded at DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711039579.2A CN107603078A (en) | 2017-10-30 | 2017-10-30 | Luminous antibiotic plastic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711039579.2A CN107603078A (en) | 2017-10-30 | 2017-10-30 | Luminous antibiotic plastic and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107603078A true CN107603078A (en) | 2018-01-19 |
Family
ID=61083785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711039579.2A Pending CN107603078A (en) | 2017-10-30 | 2017-10-30 | Luminous antibiotic plastic and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107603078A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301792A (en) * | 1999-12-30 | 2001-07-04 | 大连路明科技集团有限公司 | Luminous plastic masterbatch and its preparation method |
| CN1769366A (en) * | 2004-10-27 | 2006-05-10 | 中国石油化工股份有限公司 | A long afterglow luminescent thermoplastic composition and its preparation method |
| CN1900153A (en) * | 2006-07-05 | 2007-01-24 | 大连实德集团有限公司 | Coextruded light storage type self luminous plastic irregular profile and its production method |
| CN103148438A (en) * | 2013-01-16 | 2013-06-12 | 张海峰 | Light-emitting/transmitting plastic lampshade and manufacture method thereof |
| CN104531131A (en) * | 2014-12-22 | 2015-04-22 | 常熟市环虹化工颜料厂 | Method for preparing luminous pigment with surface coating film |
-
2017
- 2017-10-30 CN CN201711039579.2A patent/CN107603078A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301792A (en) * | 1999-12-30 | 2001-07-04 | 大连路明科技集团有限公司 | Luminous plastic masterbatch and its preparation method |
| CN1769366A (en) * | 2004-10-27 | 2006-05-10 | 中国石油化工股份有限公司 | A long afterglow luminescent thermoplastic composition and its preparation method |
| CN1900153A (en) * | 2006-07-05 | 2007-01-24 | 大连实德集团有限公司 | Coextruded light storage type self luminous plastic irregular profile and its production method |
| CN103148438A (en) * | 2013-01-16 | 2013-06-12 | 张海峰 | Light-emitting/transmitting plastic lampshade and manufacture method thereof |
| CN104531131A (en) * | 2014-12-22 | 2015-04-22 | 常熟市环虹化工颜料厂 | Method for preparing luminous pigment with surface coating film |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180119 |
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