CN107586234A - A kind of clean complex solid gas generator propellant and preparation method thereof - Google Patents
A kind of clean complex solid gas generator propellant and preparation method thereof Download PDFInfo
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- CN107586234A CN107586234A CN201610954640.5A CN201610954640A CN107586234A CN 107586234 A CN107586234 A CN 107586234A CN 201610954640 A CN201610954640 A CN 201610954640A CN 107586234 A CN107586234 A CN 107586234A
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- gas generator
- solid gas
- generator propellant
- complex solid
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- 239000003380 propellant Substances 0.000 title claims abstract description 37
- 239000007787 solid Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000000853 adhesive Substances 0.000 claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000007800 oxidant agent Substances 0.000 claims abstract description 13
- 230000001590 oxidative effect Effects 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 7
- 230000000996 additive effect Effects 0.000 claims abstract description 7
- 239000002826 coolant Substances 0.000 claims abstract description 7
- 239000004014 plasticizer Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 10
- 125000003431 oxalo group Chemical group 0.000 claims description 8
- -1 glycidol azide Chemical class 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical class [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- HXXHWKZFQGPFJX-UHFFFAOYSA-N hydrazine;nitric acid Chemical compound NN.O[N+]([O-])=O.O[N+]([O-])=O HXXHWKZFQGPFJX-UHFFFAOYSA-N 0.000 claims description 3
- 238000010348 incorporation Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- DRQFBCMQBWNTNV-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;trifluoroborane Chemical compound FB(F)F.OCCN(CCO)CCO DRQFBCMQBWNTNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 2
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 2
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical group [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 239000007767 bonding agent Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 2
- YCOWFDCCOFCZPM-UHFFFAOYSA-N n,n'-dihydroxyoxamide Chemical compound ONC(=O)C(=O)NO YCOWFDCCOFCZPM-UHFFFAOYSA-N 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- ZHXAZZQXWJJBHA-UHFFFAOYSA-N triphenylbismuthane Chemical compound C1=CC=CC=C1[Bi](C=1C=CC=CC=1)C1=CC=CC=C1 ZHXAZZQXWJJBHA-UHFFFAOYSA-N 0.000 claims description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 2
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical group CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 229920000305 Nylon 6,10 Polymers 0.000 claims 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 claims 1
- PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 32
- 239000000567 combustion gas Substances 0.000 abstract description 10
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000007246 mechanism Effects 0.000 abstract description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 4
- 239000002737 fuel gas Substances 0.000 description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- RAESLDWEUUSRLO-UHFFFAOYSA-O aminoazanium;nitrate Chemical compound [NH3+]N.[O-][N+]([O-])=O RAESLDWEUUSRLO-UHFFFAOYSA-O 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- AFEBXVJYLNMAJB-UHFFFAOYSA-N hydrazine;nitric acid Chemical compound NN.O[N+]([O-])=O AFEBXVJYLNMAJB-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 125000000466 oxiranyl group Chemical group 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000004449 solid propellant Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical group FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- XYVVCFFJQVMSNN-UHFFFAOYSA-N cyclopenta-1,3-diene iron(2+) 5-octylcyclopenta-1,3-diene Chemical compound [Fe++].c1cc[cH-]c1.CCCCCCCC[c-]1cccc1 XYVVCFFJQVMSNN-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Air Bags (AREA)
Abstract
The present invention discloses a kind of clean complex solid gas generator propellant, includes the component of following masses percentage：Adhesive 10%~20%；Curing agent：1%~5%；Oxidant：50%~80%；Cooling agent：0%~15%；Plasticizer：5%~15%；Combustionregulator：0%~5%；Additive：0%~2%.The present invention has the advantages that low exhaust residue content, clean anacidity, main raw material(s) is convieniently synthesized, cost is cheap, can provide combustion gas for fine gas steering wheel or full gas servo control mechanism.
Description
Technical field
It is particularly clean multiple the present invention relates to a kind of for gas generator and the gas generator propellant of other gas generators
Close solid gas propellant.
Background technology
Gas generator propellant is the power source of Aeronautics and Astronautics and missilery auxiliary control power set.It is most widely used at present
The oxidant of general gas generator propellant is ammonium perchlorate（AP）, with hygroscopicity is small, energy is high, high/low temperature ignition performance is good, steady
The advantages such as the minimum pressure that burns surely is low, but a large amount of smoke particles can be produced in its combustion gas and contain HCl corrosive gas.One side
Face, turbo blade or gas generator pipeline can be produced and wash away and corrode strongly or even block.Therefore for the combustion gas of precision
Steering wheel, small-bore jet pipe and work long hours, nonexpondable part, it is desirable to using residue content is low, gas smokeless, anacidity
The clean fuel gas propellant of gas generator propellant-i.e..
The main path of clean fuel gas propellant formula development is to substitute AP to reach combustion gas anacidity using without oxychloride agent
Effect.Current the most frequently used no oxychloride agent be ammonium nitrate, and ammonium nitrate is because of combustion gas cleaning after its combustion decomposition, no residue, and
It is cheap and easy to get, turn into a kind of highly important oxidant in complex solid gas generator propellant.AN types gas generator propellant is formulated not only
Low with combustion flame temperature, combustion gas does not contain the corrosion products such as chlorine or chlorine compound, and solid content is low etc. in combustion gas
Feature, and it is insensitive to temperature and impact, there is good mechanical property in wide temperature range, be a kind of important combustion gas
Propellant.But have that energy is low, burn rate is slow, hygroscopicity is strong, the form under room temperature condition using AN as oxidant（Crystal formation, phase）
The deficiencies of transformation easily causes Volume Changes part.Another kind of relatively tool application prospect is triaminoguanidinium nitrate without oxychloride agent
（TAGN）, TAGN type gas generator propellants have low burn temperature, high yield tolerance, combustion gas cleaning, nonhygroscopic remarkable advantage, external existing
Successful application, it is disadvantageous in that, and raw material building-up process is complicated, cost is higher.
The hydrazine mononitrate of oxalyl two（OHN）And the hydrazine dinitrate of oxalyl two（OHDN）Synthesis and property by Germany
Dennis Fischer et al. reported that they make ODH protonation generations by nitric acid in 2013 first.Its synthesize cost it is extremely low,
Can expanding production and also yield it is very high.OHN and OHDN sensitivity is relatively low and contained element in it is not chloride, can be applied to clean fuel gas hair
Raw agent field., will at present both at home and abroad still without the open report for carrying out applications of the OHN and OHDN in composite solidpropellant
The shortcomings that energy is relatively low be present in applications of the OHN and OHDN in composite solidpropellant.
The content of the invention
The purpose of the present invention is to be directed to the easy moisture absorption of oxidant in existing clean fuel gas propellant, synthesize the deficiencies of cost is high,
Provide a kind of clean complex solid gas generator propellant non-hygroscopic, cost is low, combustion gas is clean.
The present invention also aims to provide the preparation method of above-mentioned clean complex solid gas generator propellant.
The technical solution of the present invention：Include following component and content（Mass percent）：
Adhesive 10%~20%；
Curing agent：1%~5%；
Oxidant：50%~80%；
Cooling agent：0%~15%
Plasticizer：5%~15%
Combustionregulator：0%~5%,
Additive：0%~2%.
Component and its mass content optimum ratio of the present invention is as follows：
Adhesive 10%~20%；
Curing agent：1%~5%；
Oxidant：50%~80%；
Cooling agent：0%~15%；
Plasticizer：5%~10%；
Combustionregulator：0.4%~5.0%；
Additive：0.2%~1.0%.
The combination of one or both of described adhesive adhesive containing polyethers or nitrine class adhesive.Wherein polyethers
Adhesive is oxirane（EO）, expoxy propane（PO）With tetrahydrofuran（THF）Homopolymer or block copolymer, nitrine class glues
Mixture is glycidol azide polymer（GAP）.
Described adhesive is oxirane（EO）, expoxy propane（PO）With tetrahydrofuran（THF）Homopolymer or block be total to
Polymers, glycidol azide polymer（GAP）In one kind or combination.
The curing agent is toluene di-isocyanate(TDI), IPDI, the isocyanic acid of polyfunctionality aliphatic two
One or more kinds of combinations in ester.
The oxidant combines for one or both of the hydrazine mononitrate of oxalyl two or the hydrazine dinitrate of oxalyl two.
The cooling agent is ammonium oxalate, oxamides, one kind in dihydroxy glyoxime or combination.
The plasticizer is one kind in di-n-octyl sebacate, acetyl citrate glyceride, glycerine thricarbonate triethyl
Or combination.
The combustionregulator is one kind in octyl ferrocene, tert-butyl group ferrocene, di-iron trioxide, copper chromite
Or combination.
The additive is process auxiliaries methyl stearate, bonding agent boron trifluoride-triethanolamine complex compound, solidification promotion
One kind or combination in agent ferric acetyl acetonade, triphenyl bismuth, dibutyl tin laurate.
The preparation technology of the present invention includes：
（1）Above-mentioned component is weighed according to selected formula rate；
（2）Above-mentioned raw material are put into vertical mixer and mixed, 50 DEG C~70 DEG C of mixing temperature, incorporation time 60min
~100min.
（3）Slime vacuum spray is poured into mould or is poured into engine, is then placed on 50 DEG C~70 DEG C of oil bath
Solidify 7 days in baking oven.
The present invention performance be：Combustion temperature：1000~1500 DEG C；Pressure Exponent: 0.3~0.6；Burn rate（7MPa）:2.5~
8.0mm/s；Residue content：2.5~3.5%.
Beneficial effects of the present invention：
1. complex solid gas generator propellant of the present invention using being developed without oxychloride agent, have exhaust residue content it is low,
The advantages of clean anacidity, it can be applied to fine gas steering wheel or full gas servo control mechanism.
2. the hydrazine nitrate hygroscopicity of oxidant oxalyl two is low used in gas generator propellant provided by the present invention, effectively overcome existing
The shortcomings that Situation of Ammonium Nitrate Gas Generator Propellant easy moisture absorption.
3. the hydrazine nitrate of oxidant oxalyl two used in the present invention has advantage convieniently synthesized, that cost is cheap, suitable for criticizing
Amount production.
Embodiment
With reference to embodiment, the present invention is described in detail, but protection scope of the present invention is not limited in
The following example, the full content in claims should be included.
Embodiment 1
（1）Gas generator propellant forms
(2) gas generator propellant performance
The preparation technology of embodiment 1 is：Each component in formula is weighed in proportion, after liquid composition premixes with small component, with consolidating
Body component and curing agent, which are sequentially added in vertical mixer, to be mixed, 50 DEG C~70 DEG C of mixing temperature, and incorporation time 60min~
100min.Slime vacuum spray is poured into mould or is poured into engine, is then placed on 50 DEG C~70 DEG C of oil bath baking oven
Middle solidification 7 days.
Embodiment 2
(1) gas generator propellant forms
The preparation technology of embodiment 2 is the same as embodiment 1.
(2) gas generator propellant performance
Embodiment 3
（1）Gas generator propellant forms
The preparation technology of embodiment 3 is the same as embodiment 1.
(2) gas generator propellant performance
Embodiment 4
（1）Gas generator propellant forms
The preparation technology of embodiment 4 is the same as embodiment 1.
(2) gas generator propellant performance
It is described above, it is only the optimal embodiment of the present invention, but protection scope of the present invention is not limited thereto, and it is any
Those familiar with the art the invention discloses technical scope in, the change or replacement that can readily occur in, all should
It is included within the scope of the present invention.
The content not being described in detail in description of the invention belongs to the common knowledge of professional and technical personnel in the field.
Claims (10)
1. a kind of clean complex solid gas generator propellant, it is characterised in that include the component of following masses percentage：
Adhesive 10%~20%；
Curing agent：1%~5%；
Oxidant：50%~80%；
Cooling agent：0%~15%；
Plasticizer：5%~15%；
Combustionregulator：0%~5%；
Additive：0%~2%；
Described adhesive is the combination of one or both of polyethers adhesive or nitrine class adhesive.
2. clean complex solid gas generator propellant described in claim 1, it is characterised in that component and its mass content proportioning
It is as follows：
Adhesive 10%~20%；
Curing agent：1%~5%；
Oxidant：50%~80%；
Cooling agent：0%~15%；
Plasticizer：5%~10%；
Combustionregulator：0.4%~5.0%；
Additive：0.2%~1.0%.
3. clean complex solid gas generator propellant described in claim 1, it is characterised in that：Described adhesive is oxirane, ring
The homopolymer or block copolymer of Ethylene Oxide and tetrahydrofuran, one kind in glycidol azide polymer combine.
4. clean complex solid gas generator propellant described in claim 1, it is characterised in that：Curing agent be toluene di-isocyanate(TDI),
IPDI, one kind in polyfunctionality aliphatic diisocyanate or combination.
5. clean complex solid gas generator propellant described in claim 1, it is characterised in that the oxidant is the nitre of two hydrazine of oxalyl one
Hydrochlorate, one kind in the hydrazine dinitrate of oxalyl two or combination.
6. clean complex solid gas generator propellant described in claim 1, it is characterised in that described cooling agent is ammonium oxalate, oxalyl
Amine, one kind in dihydroxy glyoxime or combination.
7. clean complex solid gas generator propellant described in claim 1, it is characterised in that described plasticizer is that decanedioic acid two is pungent
Ester, acetyl citrate glyceride, one kind in glycerine thricarbonate triethyl or combination.
8. clean complex solid gas generator propellant described in claim 1, it is characterised in that described combustionregulator is n-octyl
Ferrocene, tert-butyl group ferrocene, di-iron trioxide, one kind in copper chromite or combination.
9. clean complex solid gas generator propellant described in claim 1, it is characterised in that：Described additive is that process auxiliaries are hard
Resin acid methyl esters, bonding agent boron trifluoride-triethanolamine complex compound, curing accelerator ferric acetyl acetonade, triphenyl bismuth, tin dilaurate
One kind or combination in dibutyl tin.
A kind of 10. preparation method of clean complex solid gas generator propellant described in claim 1, it is characterised in that：（1）Will be above-mentioned
Component weighs according to selected formula rate；
（2）Above-mentioned raw material are put into vertical mixer and mixed, 50 DEG C~70 DEG C of mixing temperature, incorporation time 60min
~100min；（3）Slime vacuum spray is poured into mould or is poured into engine, is then placed on 50 DEG C~70 DEG C of oil bath
Solidify in baking oven.
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| CN201610954640.5A CN107586234B (en) | 2016-11-03 | 2016-11-03 | A kind of cleaning complex solid gas generator propellant and preparation method thereof |
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| CN107586234B CN107586234B (en) | 2018-10-30 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627133A (en) * | 2018-12-05 | 2019-04-16 | 湖北航天化学技术研究所 | A kind of thermoplastic composite solid propellant and preparation method thereof |
| CN114133340A (en) * | 2021-12-03 | 2022-03-04 | 湖北航天化学技术研究所 | Oxalyl dihydrazide nitrate metal complex suitable for solid propellant and preparation method thereof |
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| CN103204753A (en) * | 2012-10-16 | 2013-07-17 | 湖北航天化学技术研究所 | Solid gas generator and preparation method thereof |
| CN105294487A (en) * | 2014-05-30 | 2016-02-03 | 湖北航天化学技术研究所 | Method for synthesizing oxalyl dihydrazide nitrate salt |
-
2016
- 2016-11-03 CN CN201610954640.5A patent/CN107586234B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627133A (en) * | 2018-12-05 | 2019-04-16 | 湖北航天化学技术研究所 | A kind of thermoplastic composite solid propellant and preparation method thereof |
| CN109627133B (en) * | 2018-12-05 | 2021-07-09 | 湖北航天化学技术研究所 | Thermoplastic composite solid propellant and preparation method thereof |
| CN114133340A (en) * | 2021-12-03 | 2022-03-04 | 湖北航天化学技术研究所 | Oxalyl dihydrazide nitrate metal complex suitable for solid propellant and preparation method thereof |
| CN114133340B (en) * | 2021-12-03 | 2024-03-15 | 湖北航天化学技术研究所 | Oxalyl dihydrazide nitrate metal complex suitable for solid propellant and preparation method thereof |
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| CN107586234B (en) | 2018-10-30 |
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