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CN107546312A - A kind of light source module group and the lighting device including the light source module group - Google Patents

A kind of light source module group and the lighting device including the light source module group Download PDF

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CN107546312A
CN107546312A CN201710736445.XA CN201710736445A CN107546312A CN 107546312 A CN107546312 A CN 107546312A CN 201710736445 A CN201710736445 A CN 201710736445A CN 107546312 A CN107546312 A CN 107546312A
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light
phosphor
source module
light source
peak
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周志贤
强洁
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Opple Lighting Co Ltd
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Opple Lighting Co Ltd
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Abstract

A kind of light source module group and the lighting device using the light source module group, matched by specific fluorescent material, realization is specific photochromic, with high-color rendering while with LED specular removals, it sends photochromic and similar to candle light, and colour rendering and colour gamut index are close with Halogen lamp LED.

Description

一种光源模组及包括该光源模组的照明装置A light source module and a lighting device including the light source module

技术领域technical field

本发明涉及一种光源模组及包括该光源模组的照明装置。The invention relates to a light source module and a lighting device including the light source module.

背景技术Background technique

随着第三次照明技术革命的到来和发展,白炽灯、卤素灯等由于光效低、不节能已经逐渐被世界各国禁止生产和销售,LED照明器具取而代之已被广泛的使用。目前照明市场上替代白炽灯的LED灯,常见的色温以2700K和3000K为主,光色呈暖白色。这一类的产品虽然能实现人们的照明需求,但是随着生活水平的提高,人们对光的各种需求也出现了多样化的要求,烛光一直给人以温暖舒适的感觉,可以营造一种私密温馨的氛围,因此也有很多用户希望LED灯具也可以产生类似烛光的效果。With the advent and development of the third lighting technology revolution, the production and sale of incandescent lamps and halogen lamps have been gradually banned by countries all over the world due to their low light efficiency and lack of energy saving. LED lighting appliances have been widely used instead. At present, the LED lamps that replace incandescent lamps in the lighting market, the common color temperature is mainly 2700K and 3000K, and the light color is warm white. Although this type of product can meet people's lighting needs, with the improvement of living standards, people's various needs for light also have diversified requirements. Candlelight has always given people a warm and comfortable feeling, which can create a kind of living space. Intimate and warm atmosphere, so many users hope that LED lamps can also produce candlelight-like effects.

发明内容Contents of the invention

本发明的目的是为了解决上述问题,寻找一种光色接近烛光,显色性和色域指数与卤素灯相近,同时具有高光效的LED光源。The object of the present invention is to solve the above problems and find an LED light source with light color close to candlelight, color rendering and color gamut index similar to halogen lamps, and high light efficiency.

本发明为实现上述功能,所采用的技术方案是提供一种光源模组,光源模组包括:In order to realize the above functions, the technical solution adopted by the present invention is to provide a light source module, the light source module includes:

第一发光元件,所述第一发光元件发出峰值波长为435~465nm的第一颜色光;a first light-emitting element, the first light-emitting element emits light of a first color with a peak wavelength of 435-465nm;

附加发光体,所述附加发光体被配置为接收所述第一发光元件所发射的部分光线,并将其转换为不同于第一颜色的第二颜色光;an additional illuminant configured to receive part of the light emitted by the first light emitting element and convert it into light of a second color different from the first color;

所述第一颜色和第二颜色光混合形成白光,the first color and the second color light are mixed to form white light,

所述附加发光体包括:The additional illuminants include:

发射光的峰值波长在600~670nm,发射光的光谱半宽度为80~120nm的红色或橙色荧光粉;The peak wavelength of emitted light is 600~670nm, and the red or orange phosphor with spectral half width of emitted light is 80~120nm;

发射光的峰值波长在520~560nm,发射光谱的半宽度为60~115nm的绿色荧光粉。The peak wavelength of the emitted light is 520~560nm, and the green phosphor with the half width of the emission spectrum is 60~115nm.

优选的,所述第一发光元件为蓝光LED芯片,所述附加发光体还包括封装体,所述封装体和荧光粉混合后涂覆在所述第一发光元件之上。Preferably, the first light-emitting element is a blue LED chip, and the additional light-emitting body further includes an encapsulation body, and the encapsulation body and phosphor powder are mixed and coated on the first light-emitting element.

优选的,所述封装体为树脂或硅胶。Preferably, the package is resin or silicone.

优选的,所述封装体中包括光扩散剂。Preferably, the package includes a light diffusing agent.

优选的,所述红色或橙色荧光粉发射光的光谱半宽度为80~100nm。Preferably, the spectral half-width of the light emitted by the red or orange phosphor is 80-100 nm.

优选的,所述红色或橙色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:Preferably, the red or orange phosphor is any one or a mixture of two or more of the following phosphors:

(a)具有1113晶体结构的氮化物红粉,Eu2+为激活剂(a) Nitride red powder with 1113 crystal structure, Eu 2+ as activator

化学组成通式:(M1)1-xAlSiN3:Eux General formula of chemical composition: (M1) 1-x AlSiN 3 :Eu x

其中M1为Ca、Sr、Ba中至少一种元素,x=0.005~0.300;Where M1 is at least one element among Ca, Sr and Ba, x=0.005~0.300;

(b)具有258晶体结构的氮化物红粉,Eu2+为激活剂(b) Nitride red powder with 258 crystal structure, Eu 2+ as activator

化学组成通式:(M2)2-xSi5N8:Eux General formula of chemical composition: (M2) 2-x Si 5 N 8 : Eu x

其中M2为Ca、Sr、Ba、Mg中至少一种元素,x=0.005~0.300;Where M2 is at least one element among Ca, Sr, Ba, Mg, x=0.005~0.300;

(c)氮氧化物荧光粉(塞隆体α-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon α-SiAlON), Eu 2+ is the activator

化学组成通式:((M3)1-a)xSibAlcOdNe:EuaGeneral formula of chemical composition: ((M3) 1-a ) x Si b Al c O d Ne : Eua

其中M3为Li、Na、K、Rb、Cs、Sr、Ba、Sc、Y、La、Gd之中至少一种元素,x=0.15~1.5,a=0.005~0.300, b+c=12,d+e=16;Where M3 is at least one element among Li, Na, K, Rb, Cs, Sr, Ba, Sc, Y, La, Gd, x=0.15~1.5, a=0.005~0.300, b+c=12, d +e=16;

(d)硅酸盐荧光粉,Eu2+为激活剂(d) Silicate phosphor, Eu2+ as activator

化学组成通式:(Sr,Ba)3-xSi5O5:Eux General formula of chemical composition: (Sr,Ba) 3-x Si 5 O 5 :Eu x

其中x=0.005~0.300。where x=0.005~0.300.

优选的,所述红色或橙色荧光粉的重量占混入荧光粉后的封装体的总重量的10.0~26.0%。Preferably, the weight of the red or orange phosphor accounts for 10.0-26.0% of the total weight of the package after the phosphor is mixed.

优选的,所述绿色荧光粉发射光的光谱半宽度为90~115nm。Preferably, the spectral half-width of the light emitted by the green phosphor is 90-115 nm.

优选的,所述绿色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:Preferably, the green phosphor is any one or a mixture of two or more of the following phosphors:

(a)石榴石结构的绿色荧光粉,Ce3+为激活剂(a) Green phosphor with garnet structure, Ce 3+ as activator

化学组成通式:(M4)3-x(M5)5O12:Cex General formula of chemical composition: (M4) 3-x (M5) 5 O 12 : Cex

其中M4为Y、Lu、Gd及La中至少一种元素,M5为Al、Ga中至少一种元素,x=0.005~0.200;Wherein M4 is at least one element among Y, Lu, Gd and La, M5 is at least one element among Al and Ga, x=0.005~0.200;

(b)硅酸盐体系的绿色荧光粉,Eu2+为激活剂(b) Green phosphor in silicate system, Eu 2+ as activator

化学组成通式:(M6)2-xSiO4:Eux General formula of chemical composition: (M6) 2-x SiO 4 : Eu x

或 (Ba,Ca,Sr)2-x(Mg,Zn)Si2O7:Eux or (Ba,Ca,Sr) 2-x (Mg,Zn)Si 2 O 7 :Eu x

其中M6为Mg、Sr、Ca、Ba中至少一种元素,x=0.01~0.20;Where M6 is at least one element of Mg, Sr, Ca, Ba, x=0.01~0.20;

(c)氮氧化物荧光粉 (塞隆体β-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon β-SiAlON), Eu 2+ is the activator

化学组成通式:SibAlcOdNe:Eux General formula of chemical composition: Si b Al c O d Ne : Eu x

其中x=0.005~0.400,b+c=12,d+e=16;Where x=0.005~0.400, b+c=12, d+e=16;

(d)铝酸盐体系荧光粉,Eu2+为激活剂(d) Aluminate system phosphor, Eu 2+ is the activator

化学组成通式:(Sr,Ba)2-xAl2O4:Eux General formula of chemical composition: (Sr,Ba) 2-x Al 2 O 4 :Eu x

或 (Sr,Ba)4-xAl14O25:Eux Or (Sr,Ba) 4-x Al 14 O 25 : Eu x

其中x=0.01~0.15。where x=0.01~0.15.

优选的,所述绿色荧光粉的重量占混入荧光粉后的封装体的总重量的55.0~88.0%。Preferably, the weight of the green phosphor accounts for 55.0-88.0% of the total weight of the package after the phosphor is mixed.

优选的,所述附加发光体还包括发射光的峰值波长在560~600nm,发射光的光谱半宽度为60~125nm的黄色荧光粉。Preferably, the additional illuminant further includes a yellow phosphor with a peak wavelength of emitted light at 560-600 nm and a spectral half-width of emitted light at 60-125 nm.

优选的,所述黄色荧光粉发射光的光谱半宽度为100~125nm。Preferably, the spectral half-width of the light emitted by the yellow fluorescent powder is 100-125 nm.

优选的,所述黄色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:Preferably, the yellow phosphor is any one or a mixture of two or more of the following phosphors:

(a)石榴石结构的黄色荧光粉,Ce3+为激活剂(a) Yellow phosphor with garnet structure, Ce 3+ as activator

化学组成通式:(Y,Gd)3-xAl5O12:Cex General formula of chemical composition: (Y,Gd) 3-x Al 5 O 12 :Cex

其中x=0.005~0.100;where x=0.005~0.100;

(b)硅酸盐体系的黄色荧光粉,Eu2+为激活剂(b) Yellow phosphor in silicate system, Eu 2+ is the activator

化学组成通式:(M7)2-xSiO4:Eux General formula of chemical composition: (M7) 2-x SiO 4 :Eu x

或 (Ba,Ca,Sr)2-x(Mg,Zn)Si2O7:Eux or (Ba,Ca,Sr) 2-x (Mg,Zn)Si 2 O 7 :Eu x

其中M7为Sr、Ca、Ba中至少一种元素,x=0.01~0.20;Where M7 is at least one element among Sr, Ca and Ba, x=0.01~0.20;

(c)氮氧化物荧光粉 (塞隆体β-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon β-SiAlON), Eu 2+ is the activator

化学组成通式:SibAlcOdNe:Eux General formula of chemical composition: Si b Al c O d Ne : Eu x

其中x=0.005~0.400,b+c=12,d+e=16Where x=0.005~0.400, b+c=12, d+e=16

优选的,所述黄色荧光粉的重量在混入荧光粉后的封装体的总重量中的占比小于30.0%。Preferably, the weight of the yellow phosphor accounts for less than 30.0% of the total weight of the package after the phosphor is mixed.

优选的,所述附加发光体还包括发射光的峰值波长在485~520nm,发射光的光谱半宽度为25~65nm的蓝绿色荧光粉。Preferably, the additional illuminant further includes a blue-green phosphor with a peak wavelength of emitted light at 485-520 nm and a spectral half width of emitted light of 25-65 nm.

优选的,所述蓝绿色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:Preferably, the blue-green phosphor is any one or a mixture of two or more of the following phosphors:

(a)氮氧化物,Eu2+为激活剂(a) Nitrogen oxides, Eu 2+ as activator

化学组成通式:(Ba,Ca)Si2N2O2:Eu;General formula of chemical composition: (Ba,Ca)Si 2 N 2 O 2 :Eu;

(b)掺Ga石榴石荧光粉,Eu2+为激活剂(b) Ga-doped garnet phosphor with Eu 2+ as the activator

化学组成通式:Ga-LuAG:Eu;General formula of chemical composition: Ga-LuAG:Eu;

(c)硅酸盐荧光粉,Eu2+为激活剂(c) Silicate phosphor, Eu 2+ as activator

化学组成通式:Ba2SiO4:Eu。General formula of chemical composition: Ba 2 SiO 4 :Eu.

优选的,所述蓝绿色荧光粉的重量在混入荧光粉后的封装体的总重量中的占比小于30.0%。Preferably, the weight of the blue-green phosphor accounts for less than 30.0% of the total weight of the package after the phosphor is mixed.

本发明还提供一种照明装置,包括:The present invention also provides a lighting device, comprising:

如上所述的光源模组;The above-mentioned light source module;

电源模组,连接所述光源模组,为所述光源模组提供工作所需电力。The power supply module is connected to the light source module to provide the power required for the light source module to work.

优选的,所述照明装置还包括控制器,所述控制器连接所述光源模组,用于调整所述光源模组所发出照射光。Preferably, the lighting device further includes a controller, the controller is connected to the light source module, and is used to adjust the illumination light emitted by the light source module.

本发明所提供的光源模组在具有LED高光效同时,其发出的光色和与烛光相似,显色性和色域指数与卤素灯相近。While the light source module provided by the present invention has high LED light efficiency, the light color emitted by it is similar to candlelight, and the color rendering and color gamut index are similar to those of halogen lamps.

附图说明Description of drawings

图1是符合本发明优选实施例的照明装置的结构示意图;Fig. 1 is a schematic structural diagram of a lighting device according to a preferred embodiment of the present invention;

图2是符合本发明优选实施例的光源模组的结构示意图;Fig. 2 is a schematic structural diagram of a light source module according to a preferred embodiment of the present invention;

图3是符合本发明优选实施例1~11的CIE1931色坐标图;Fig. 3 is the CIE1931 chromatic coordinate figure that meets preferred embodiment 1~11 of the present invention;

图4是本发明中优选实施例1的发光光谱与其参考光谱的比对图;Fig. 4 is the comparative figure of the luminescent spectrum of preferred embodiment 1 and its reference spectrum in the present invention;

图5是本发明中优选实施例1的光谱强度与其参考光谱强度差的分布图;Fig. 5 is the distribution diagram of the spectrum intensity of preferred embodiment 1 and its reference spectrum intensity difference in the present invention;

图6是本发明中优选实施例2的发光光谱与其参考光谱的比对图;Fig. 6 is a comparison chart of the luminescence spectrum of the preferred embodiment 2 and its reference spectrum in the present invention;

图7是本发明中优选实施例2的光谱强度与其参考光谱强度差的分布图;Fig. 7 is the distribution diagram of the spectrum intensity of preferred embodiment 2 and its reference spectrum intensity difference in the present invention;

图8是本发明中优选实施例3的发光光谱与其参考光谱的比对图;Fig. 8 is a comparison chart of the luminescent spectrum of the preferred embodiment 3 and its reference spectrum in the present invention;

图9是本发明中优选实施例3的光谱强度与其参考光谱强度差的分布图;Fig. 9 is a distribution diagram of the spectral intensity and its reference spectral intensity difference of preferred embodiment 3 in the present invention;

图10是本发明中优选实施例4的发光光谱与其参考光谱的比对图;Fig. 10 is a comparison chart of the luminescence spectrum of preferred embodiment 4 and its reference spectrum in the present invention;

图11是本发明中优选实施例4的光谱强度与其参考光谱强度差的分布图;Fig. 11 is the distribution diagram of the spectrum intensity and its reference spectrum intensity difference of preferred embodiment 4 in the present invention;

图12是本发明中优选实施例5的发光光谱与其参考光谱的比对图;Fig. 12 is a comparison diagram of the luminescence spectrum of the preferred embodiment 5 and its reference spectrum in the present invention;

图13是本发明中优选实施例5的光谱强度与其参考光谱强度差的分布图;Fig. 13 is a distribution diagram of the spectral intensity of preferred embodiment 5 and its reference spectral intensity difference in the present invention;

图14是本发明中优选实施例6的发光光谱与其参考光谱的比对图;Fig. 14 is a comparison chart of the luminescence spectrum of the preferred embodiment 6 and its reference spectrum in the present invention;

图15是本发明中优选实施例6的光谱强度与其参考光谱强度差的分布图;Fig. 15 is a distribution diagram of the difference between the spectral intensity of preferred embodiment 6 and its reference spectral intensity in the present invention;

图16是本发明中优选实施例7的发光光谱与其参考光谱的比对图;Fig. 16 is a comparison chart of the luminescence spectrum of the preferred embodiment 7 and its reference spectrum in the present invention;

图17是本发明中优选实施例7的光谱强度与其参考光谱强度差的分布图;Fig. 17 is a distribution diagram of the difference between the spectral intensity of preferred embodiment 7 and its reference spectral intensity in the present invention;

图18是本发明中优选实施例8的发光光谱与其参考光谱的比对图;Fig. 18 is a comparison chart of the luminescence spectrum of preferred embodiment 8 and its reference spectrum in the present invention;

图19是本发明中优选实施例8的光谱强度与其参考光谱强度差的分布图;Fig. 19 is a distribution diagram of the difference between the spectral intensity of preferred embodiment 8 and its reference spectral intensity in the present invention;

图20是本发明中优选实施例9的的相对光谱能量分布图;Fig. 20 is the relative spectral energy distribution figure of preferred embodiment 9 in the present invention;

图21是本发明中优选实施例9的光谱强度与其参考光谱强度差的分布图;Fig. 21 is a distribution diagram of the difference between the spectral intensity of the preferred embodiment 9 and its reference spectral intensity in the present invention;

图22是本发明中优选实施例10的发光光谱与其参考光谱的比对图;Fig. 22 is a comparison chart of the luminescence spectrum of the preferred embodiment 10 of the present invention and its reference spectrum;

图23是本发明中优选实施例10的光谱强度与其参考光谱强度差的分布图;Fig. 23 is a distribution diagram of the difference between the spectral intensity of the preferred embodiment 10 and its reference spectral intensity in the present invention;

图24是本发明中优选实施例11的发光光谱与其参考光谱的比对图;Fig. 24 is a comparison chart of the luminescence spectrum of the preferred embodiment 11 of the present invention and its reference spectrum;

图25是本发明中优选实施例11的光谱强度与其参考光谱强度差的分布图。Fig. 25 is a distribution diagram of the difference between the spectral intensity of the preferred embodiment 11 and its reference spectral intensity in the present invention.

具体实施方式detailed description

以下结合附图和一些符合本发明的优选实施例对本发明提出的一种光源模组及照明装置作进一步详细的说明。A light source module and lighting device proposed by the present invention will be further described in detail below with reference to the accompanying drawings and some preferred embodiments in accordance with the present invention.

本发明提供的光源模组是发出光源,其可应用于如图1所示的照明装置101中用以日常照明。照明装置101包括向光源模组提供工作所需电力的电源模组(未图示)和控制器102、散热装置103、照明模组104和灯罩105等。控制器102可用于调整光源模组104所发出照射光如光色、光强等,而灯罩105在其他实施例中可以根据照明装置101的设计替换成为其他光学元件,如透镜、扩散元件、光导等,其中也可以不包括散热器。The light source module provided by the present invention is an emitting light source, which can be applied to the lighting device 101 shown in FIG. 1 for daily lighting. The lighting device 101 includes a power supply module (not shown) and a controller 102 , a heat sink 103 , a lighting module 104 , a lampshade 105 , etc., which provide power required for the light source module to work. The controller 102 can be used to adjust the illumination light emitted by the light source module 104, such as light color, light intensity, etc., and the lampshade 105 can be replaced with other optical elements according to the design of the lighting device 101 in other embodiments, such as lenses, diffusion elements, light guides, etc. etc., which may not include the radiator.

本发明的光源模组104的一个具体实施方式为一个混光的白光LED封装芯片,如图2所示,光源模组104至少包括一个第一发光元件1041和附加发光体。在本实施方式中第一发光元件1041为蓝光LED芯片,由半导体材料直接激发发光,其发光的峰值波长位置在430~470nm,光色呈蓝色,这里我们称第一发光元件1041发出的光为第一颜色光。在另一优选实施方式中也可采用峰值波长位置在435~465nm的蓝光LED芯片。LED芯片(LED Chip),包括正装或倒装,单颗LED Chip或者多颗LED Chip按串联、并联或串并联方式连接在一起。在其他实施方式中第一发光元件1041也可以采用LED芯片配合荧光粉的模式,即包含半导体发光元件(LED芯片)及吸收半导体发光元件(LED芯片)所发出的光并通过波长转换而发出蓝光的蓝光荧光粉,这里的半导体发光元件可以为发出紫外光的单色LED芯片。附加发光体在光源模组104中的作用是接收所述第一发光元件所发射的部分光线,并将其转换为不同于第一颜色的第二颜色光,在本实施方式中附加发光体至少包含两种不同光色的荧光粉,附加发光体发出的光,其峰值波长在大于等于620nm,更为优选的峰值波长位于630~660nm区域。第一颜色光和第二颜色光混合后即形成光源模组104的发射光,光源模组104的发射光为白光。A specific embodiment of the light source module 104 of the present invention is a light-mixing white LED package chip. As shown in FIG. 2 , the light source module 104 includes at least a first light-emitting element 1041 and an additional light-emitting body. In this embodiment, the first light-emitting element 1041 is a blue LED chip, which is directly excited by semiconductor materials to emit light. The peak wavelength of the light is at 430-470nm, and the light color is blue. Here we call the light emitted by the first light-emitting element 1041 is the first color light. In another preferred embodiment, a blue LED chip with a peak wavelength position of 435-465 nm may also be used. LED chip (LED Chip), including front-mounted or flip-chip, a single LED Chip or multiple LED Chips are connected together in series, parallel or series-parallel. In other implementations, the first light-emitting element 1041 can also adopt the mode of LED chips and phosphor powder, that is, it includes semiconductor light-emitting elements (LED chips) and absorbs the light emitted by semiconductor light-emitting elements (LED chips) and emits blue light through wavelength conversion. The blue-light phosphor powder, the semiconductor light-emitting element here can be a monochromatic LED chip that emits ultraviolet light. The role of the additional illuminant in the light source module 104 is to receive part of the light emitted by the first light-emitting element and convert it into light of a second color different from the first color. In this embodiment, the additional illuminant at least It contains two phosphors with different light colors, and the light emitted by the additional luminous body has a peak wavelength greater than or equal to 620nm, and a more preferable peak wavelength is in the region of 630-660nm. The light emitted by the light source module 104 is formed after the light of the first color and the light of the second color are mixed, and the emitted light of the light source module 104 is white light.

由于光源模组104中是由第一发光元件1041蓝光LED芯片作为激发光源,虽然蓝光LED芯片发出的光有很大一部分发射光经过附加发光体进行了波长转换,但是仍有一部分能量未经转换,这些能量在430~470nm波长区域内形成了第一峰,这个峰的能量的主要来源为第一发光元件1041,而附加发光体转换后的光在该波长段也会有部分能量,两者混合后,此第一峰并不一定和原第一发光元件1041蓝光LED芯片的峰值波长位置完全重合,可能稍有漂移。光源模组104的发射光,在波长630~660nm区域内具有第二峰,这个峰的能量主要由附加发光体提供。为了可以产生烛光色,第一峰的光谱强度和第二峰的光谱强度的比值需小于等于20%。Since the first light-emitting element 1041 blue LED chip is used as the excitation light source in the light source module 104, although a large part of the light emitted by the blue LED chip has undergone wavelength conversion through an additional luminous body, there is still a part of energy that has not been converted. , these energies form the first peak in the wavelength range of 430~470nm, the main source of energy of this peak is the first light-emitting element 1041, and the light converted by the additional luminous body will also have part of the energy in this wavelength range, the two After mixing, the first peak may not completely coincide with the peak wavelength position of the original first light-emitting element 1041 blue LED chip, and there may be a slight shift. The light emitted by the light source module 104 has a second peak in the wavelength range of 630-660 nm, and the energy of this peak is mainly provided by the additional luminous body. In order to produce candlelight color, the ratio of the spectral intensity of the first peak to the spectral intensity of the second peak must be less than or equal to 20%.

以和所述光源模组发射光相同色温、相同Y(光通量)的黑体辐射光谱作为参考光谱,黑体辐射公式如下:Taking the blackbody radiation spectrum with the same color temperature and the same Y (luminous flux) as the light emitted by the light source module as the reference spectrum, the blackbody radiation formula is as follows:

其中, in, ,

λ辐射波长(μm);c 光速(2.998×10^8m/s );h 普朗克常数6.626×10^-34 J·S;K 玻尔兹曼常数(Boltzmann) 1.3806505*10^-23J/K;CCT相关色温。λ radiation wavelength (μm); c speed of light (2.998×10^8m/s ); h Planck constant 6.626×10^-34 J·S; K Boltzmann constant (Boltzmann) 1.3806505*10^-23J/ K; CCT correlated color temperature.

光源模组104的发射光谱具有如下特征,在380nm至所述第二峰的峰值波长之间的区域内,光源模组发射光的光谱强度和同波长所述参考波长的光谱强度的差值A(λ)满足如下条件-2.0≤A(λ)≤2.0之间,在一些更佳的实施方式中-1.0≤A(λ)≤1.0。A(λ)的计算公式如下:The emission spectrum of the light source module 104 has the following characteristics. In the region between 380nm and the peak wavelength of the second peak, the difference A between the spectral intensity of the light emitted by the light source module and the spectral intensity of the reference wavelength at the same wavelength (λ) satisfies the following condition -2.0≤A(λ)≤2.0, and in some better embodiments -1.0≤A(λ)≤1.0. The calculation formula of A(λ) is as follows:

;

其中:P(λ)为所述光源模组的发光光谱,R(λ)为和所述光源模组具有相同色温、相同光通量的参考光谱,V(λ)是明视觉光谱光视效率函数。Wherein: P(λ) is the luminescence spectrum of the light source module, R(λ) is a reference spectrum having the same color temperature and the same luminous flux as the light source module, and V(λ) is the photopic spectrum luminous efficiency function.

光源模组发射光光谱的另一个特征是,在380~780nm可见光范围内光谱是连续分布的,即380~780nm区域内,任意两个相邻波长(间隔宽度为5nm)的光谱强度的差值的绝对值和第二峰的光谱强度的比值均小于等于8.0%。当然这个比值数值越小光谱的连续性就越好,在另外的较佳实施例中,可实现任意两个相邻波长(间隔宽度为5nm)的光谱强度的差值的绝对值和第二峰的光谱强度的比值均小于等于6.5%Another feature of the light spectrum emitted by the light source module is that the spectrum is continuously distributed in the visible light range of 380~780nm, that is, the difference between the spectral intensities of any two adjacent wavelengths (the interval width is 5nm) in the 380~780nm region The ratio of the absolute value of and the spectral intensity of the second peak is less than or equal to 8.0%. Certainly the continuity of the smaller spectrum of this ratio value is better, in another preferred embodiment, can realize the absolute value of the difference of the spectral intensity of any two adjacent wavelengths (the interval width is 5nm) and the second peak The ratios of spectral intensities are all less than or equal to 6.5%

具有上述光谱特性的光源模组104发射光的光色在CIE1931色空间上,位于相关色温1850~2150K与黑体轨迹的距离在-0.005~0.005之间的点围成的区间内,即duv∈[-0.005,0.005],如图3所示的区域1。更为优选的是,位于中心点x0=0.5267,y0=0.4133,长轴a=0.00233,短轴b=0.00132,倾角θ=47.9°,SDCM=5.0的椭圆范围内,如图3所示的区域2。这种光谱的显色性参数CRI不小于90,R9不小于50,色域指数Rg不小于90。The light color of the light emitted by the light source module 104 with the above spectral characteristics is in the CIE1931 color space, located in the interval surrounded by points with a correlated color temperature of 1850~2150K and a distance between -0.005~0.005 from the black body locus, that is, duv∈[ -0.005,0.005], area 1 shown in Figure 3. More preferably, it is located within the ellipse range of the center point x0=0.5267, y0=0.4133, long axis a=0.00233, short axis b=0.00132, inclination θ=47.9°, SDCM=5.0, as shown in Figure 3 2. The color rendering parameter CRI of this spectrum is not less than 90, R9 is not less than 50, and the color gamut index Rg is not less than 90.

为了实现上述光色及光谱,本实施方式中的附加发光体是混合有荧光粉的封装体1042,封装体1042的材料可以为树脂或硅胶,而透明树脂可以是环氧树脂或尿素树脂。封装体1042和荧光粉混合均匀后涂覆在第一发光元件1041之上,如图15所示。在本实施方式中我们通过采用荧光粉来实现波长转换,而为了实现本发明要求的光谱连续,如果仅采用一种荧光粉,其半宽度有限,无法实现在380~780nm如此大的范围内的连续分布,因此附加发光体至少包括两种光色不同的荧光粉。在本实施方式中附加发光体包括第一荧光粉1043,其为发射光的峰值波长在600~670nm,发射光的光谱半宽度为80~120nm,优选的为80~100nm的红色或橙色荧光粉;第二荧光粉1044,其为发射光的峰值波长在520~560nm,发射光谱的半宽度为60~115nm,优选的为90~115nm的绿色荧光粉。In order to realize the above-mentioned light color and spectrum, the additional illuminant in this embodiment is a package 1042 mixed with phosphor powder. The material of the package 1042 can be resin or silica gel, and the transparent resin can be epoxy resin or urea resin. The encapsulation body 1042 and phosphor powder are evenly mixed and coated on the first light emitting element 1041 , as shown in FIG. 15 . In this embodiment, we use fluorescent powder to achieve wavelength conversion, but in order to achieve the spectral continuity required by the present invention, if only one kind of fluorescent powder is used, its half width is limited, and it is impossible to realize wavelength conversion in such a large range of 380~780nm. The distribution is continuous, so the additional illuminants include at least two phosphors with different light colors. In this embodiment, the additional luminous body includes the first phosphor 1043, which is a red or orange phosphor with a peak wavelength of emitted light at 600-670 nm and a spectral half-width of emitted light of 80-120 nm, preferably 80-100 nm. ; The second phosphor 1044 is a green phosphor with a peak wavelength of emitted light at 520-560nm and a half-width of the emission spectrum of 60-115nm, preferably 90-115nm.

红色或橙色荧光粉可以选择下述荧光粉中的任意一种,或者从下述荧光粉中选择两种或以上混合而成。具体的荧光粉种类如下(在本发明中以x来表示摩尔比):The red or orange phosphor can be selected from any one of the following phosphors, or two or more of the following phosphors can be selected and mixed. Concrete fluorescent powder kind is as follows (express molar ratio with x in the present invention):

(a)具有1113晶体结构的氮化物红粉,Eu2+为激活剂(a) Nitride red powder with 1113 crystal structure, Eu 2+ as activator

化学组成通式:(M1)1-xAlSiN3:Eux General formula of chemical composition: (M1) 1-x AlSiN 3 :Eu x

其中M1为Ca、Sr、Ba中至少一种元素,x=0.005~0.300;Where M1 is at least one element among Ca, Sr and Ba, x=0.005~0.300;

(b)具有258晶体结构的氮化物红粉,Eu2+为激活剂(b) Nitride red powder with 258 crystal structure, Eu 2+ as activator

化学组成通式:(M2)2-xSi5N8:Eux General formula of chemical composition: (M2) 2-x Si 5 N 8 : Eu x

其中M2为Ca、Sr、Ba、Mg中至少一种元素,x=0.005~0.300;Where M2 is at least one element among Ca, Sr, Ba, Mg, x=0.005~0.300;

(c)氮氧化物荧光粉(塞隆体α-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon α-SiAlON), Eu 2+ is the activator

化学组成通式:((M3)1-a)xSibAlcOdNe:EuaGeneral formula of chemical composition: ((M3) 1-a ) x Si b Al c O d Ne : Eua

其中M3为Li、Na、K、Rb、Cs、Sr、Ba、Sc、Y、La、Gd之中至少一种元素,x=0.15~1.5,a=0.005~0.300, b+c=12,d+e=16;Where M3 is at least one element among Li, Na, K, Rb, Cs, Sr, Ba, Sc, Y, La, Gd, x=0.15~1.5, a=0.005~0.300, b+c=12, d +e=16;

(d)硅酸盐荧光粉,Eu2+为激活剂(d) Silicate phosphor, Eu2+ as activator

化学组成通式:(Sr,Ba)3-xSi5O5:Eux General formula of chemical composition: (Sr,Ba) 3-x Si 5 O 5 :Eu x

其中x=0.005~0.300。where x=0.005~0.300.

绿色荧光粉可以选择下述荧光粉中的任意一种,或者从下述荧光粉中选择两种或以上混合而成。具体的荧光粉种类如下:The green phosphor can be any one of the following phosphors, or two or more of the following phosphors can be selected and mixed. The specific phosphor types are as follows:

(a)石榴石结构的绿色荧光粉,Ce3+为激活剂(a) Green phosphor with garnet structure, Ce 3+ as activator

化学组成通式:(M4)3-x(M5)5O12:Cex General formula of chemical composition: (M4) 3-x (M5) 5 O 12 : Cex

其中M4为Y、Lu、Gd及La中至少一种元素,M5为Al、Ga中至少一种元素,x=0.005~0.200;Wherein M4 is at least one element among Y, Lu, Gd and La, M5 is at least one element among Al and Ga, x=0.005~0.200;

(b)硅酸盐体系的绿色荧光粉,Eu2+为激活剂(b) Green phosphor in silicate system, Eu 2+ as activator

化学组成通式:(M6)2-xSiO4:Eux General formula of chemical composition: (M6) 2-x SiO 4 : Eu x

或 (Ba,Ca,Sr)2-x(Mg,Zn)Si2O7:Eux or (Ba,Ca,Sr) 2-x (Mg,Zn)Si 2 O 7 :Eu x

其中M6为Mg、Sr、Ca、Ba中至少一种元素,x=0.01~0.20;Where M6 is at least one element of Mg, Sr, Ca, Ba, x=0.01~0.20;

(c)氮氧化物荧光粉 (塞隆体β-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon β-SiAlON), Eu 2+ is the activator

化学组成通式:SibAlcOdNe:Eux General formula of chemical composition: Si b Al c O d Ne : Eu x

其中x=0.005~0.400,b+c=12,d+e=16;Where x=0.005~0.400, b+c=12, d+e=16;

(d)铝酸盐体系荧光粉,Eu2+为激活剂(d) Aluminate system phosphor, Eu 2+ is the activator

化学组成通式:(Sr,Ba)2-xAl2O4:Eux General formula of chemical composition: (Sr,Ba) 2-x Al 2 O 4 :Eu x

或 (Sr,Ba)4-xAl14O25:Eux Or (Sr,Ba) 4-x Al 14 O 25 : Eu x

其中x=0.01~0.15。where x=0.01~0.15.

通过红光荧光粉和绿光荧光粉的共同作用,本实施方式中光源模组104的发射光谱在380~780nm范围内可以基本实现连续分布。为了使光谱曲线更为平滑,可在红光荧光粉和绿光荧光粉的基础上再加入其他种类的荧光粉,如在一个较佳实施方式中可加入发射光的峰值波长在560~600nm,光谱半宽度为60~125nm,优选的为100~125nm的黄色荧光粉。黄色荧光粉可以选择下述荧光粉中的任意一种,或者从下述荧光粉中选择两种或以上混合而成。具体的荧光粉种类如下:Through the joint action of the red phosphor and the green phosphor, the emission spectrum of the light source module 104 in this embodiment can basically achieve a continuous distribution within the range of 380-780 nm. In order to make the spectrum curve smoother, other types of phosphors can be added on the basis of red phosphors and green phosphors. For example, in a preferred embodiment, the peak wavelength of emitted light can be added at 560~600nm. The spectral half-width is 60-125nm, preferably 100-125nm yellow phosphor. The yellow phosphor can be any one of the following phosphors, or two or more of the following phosphors can be selected and mixed. The specific phosphor types are as follows:

(a)石榴石结构的黄色荧光粉,Ce3+为激活剂(a) Yellow phosphor with garnet structure, Ce 3+ as activator

化学组成通式:(Y,Gd)3-xAl5O12:Cex General formula of chemical composition: (Y,Gd) 3-x Al 5 O 12 :Cex

其中x=0.005~0.100;where x=0.005~0.100;

(b)硅酸盐体系的黄色荧光粉,Eu2+为激活剂(b) Yellow phosphor in silicate system, Eu 2+ is the activator

化学组成通式:(M7)2-xSiO4:Eux General formula of chemical composition: (M7) 2-x SiO 4 :Eu x

或 (Ba,Ca,Sr)2-x(Mg,Zn)Si2O7:Eux or (Ba,Ca,Sr) 2-x (Mg,Zn)Si 2 O 7 :Eu x

其中M7为Sr、Ca、Ba中至少一种元素,x=0.01~0.20;Where M7 is at least one element among Sr, Ca and Ba, x=0.01~0.20;

(c)氮氧化物荧光粉 (塞隆体β-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon β-SiAlON), Eu 2+ is the activator

化学组成通式:SibAlcOdNe:Eux General formula of chemical composition: Si b Al c O d Ne : Eu x

其中x=0.005~0.400,b+c=12,d+e=16。Where x=0.005~0.400, b+c=12, d+e=16.

在另一较佳的实施方式中增加了发射光的峰值波长在485~520nm,发射光的光谱半宽度为25~65nm的蓝绿色荧光粉。蓝绿色荧光粉可以选择下述荧光粉中的任意一种,或者从下述荧光粉中选择两种或以上混合而成。具体的荧光粉种类如下:In another preferred embodiment, a blue-green phosphor with a peak wavelength of emitted light at 485-520 nm and a spectral half-width of emitted light at 25-65 nm is added. The blue-green phosphor can be selected from any one of the following phosphors, or two or more of the following phosphors can be selected and mixed. The specific phosphor types are as follows:

(a)氮氧化物,Eu2+为激活剂(a) Nitrogen oxides, Eu 2+ as activator

化学组成通式:(Ba,Ca)Si2N2O2:Eu;General formula of chemical composition: (Ba,Ca)Si 2 N 2 O 2 :Eu;

(b)掺Ga石榴石荧光粉,Eu2+为激活剂(b) Ga-doped garnet phosphor with Eu 2+ as the activator

化学组成通式:Ga-LuAG:Eu;General formula of chemical composition: Ga-LuAG:Eu;

(c)硅酸盐荧光粉,Eu2+为激活剂(c) Silicate phosphor, Eu 2+ as activator

化学组成通式:Ba2SiO4:Eu。General formula of chemical composition: Ba 2 SiO 4 :Eu.

在另一较佳实施方式中可同时增加上述黄色荧光粉和蓝绿色荧光粉。在其他可选的实施方式中,还可以加入其他光色的荧光粉,但是不管加入何种荧光粉,如前所述的红色或橙色荧光粉、绿色荧光粉这两种荧光粉都是必须的。In another preferred embodiment, the above-mentioned yellow phosphor and blue-green phosphor can be added at the same time. In other optional embodiments, phosphors of other light colors can also be added, but no matter what kind of phosphors are added, the red or orange phosphors and green phosphors as mentioned above are necessary .

本实施方式中的光源模组104为具有一般贴片封装结构或COB封装结构LED芯片,荧光粉均匀分布在透明硅胶中,覆盖在蓝光LED Chip上方。在每一种方案中,各色荧光粉占混入全部种类荧光粉后的封装体的总重量的比例是有一定规律的。其中,红色或橙色荧光粉的重量在混入荧光粉后的封装体的总重量中的占比为10.0~26.0%。绿色荧光粉的重量在混入荧光粉后的封装体的总重量中的占比为55.0~88.0%。如有黄色荧光粉,黄色荧光粉的重量在混入荧光粉后的封装体的总重量中的占比不能太高,应小于30.0%。蓝绿色荧光粉的重量在混入荧光粉后的封装透明体的总重量中的占比不能太高,应小于30.0%。The light source module 104 in this embodiment is an LED chip with a general patch package structure or a COB package structure, and the phosphor is evenly distributed in transparent silica gel, covering the top of the blue LED Chip. In each solution, there is a certain rule in the ratio of phosphor powders of various colors to the total weight of the package after mixing all kinds of phosphor powders. Wherein, the weight of the red or orange phosphor accounts for 10.0-26.0% of the total weight of the package after the phosphor is mixed. The weight of the green phosphor accounts for 55.0-88.0% of the total weight of the package after the phosphor is mixed. If there is yellow phosphor powder, the proportion of the weight of the yellow phosphor powder to the total weight of the package after the phosphor powder is mixed should not be too high, and should be less than 30.0%. The proportion of the weight of the blue-green phosphor powder to the total weight of the encapsulated transparent body mixed with the phosphor powder should not be too high, and should be less than 30.0%.

虽然各色荧光粉已经在上述实施方式中说明了可选的种类,但是在实际应用中,荧光粉的组合方式还是很多,在下表中示出了光源模组104的几个优选的实施例的荧光粉种类及粉重。在每一实施例中,封装透明体1042都是透明硅胶,重量为6.00g,在透明硅胶中还含有光扩散剂,光扩散剂可以是纳米级氧化钛、氧化铝或氧化硅中的一种。Although the optional types of fluorescent powders of various colors have been described in the above embodiments, in practical applications, there are still many combinations of fluorescent powders. The fluorescent powders of several preferred embodiments of the light source module 104 are shown in the following table. Flour type and powder weight. In each embodiment, the encapsulating transparent body 1042 is transparent silica gel with a weight of 6.00 g, and the transparent silica gel also contains a light diffusing agent, and the light diffusing agent can be one of nanoscale titanium oxide, aluminum oxide or silicon oxide .

根据上表荧光粉配比制成的芯片,其各项光色参数的测试数据如下表所示The test data of various light and color parameters of the chip made according to the phosphor powder ratio in the above table are shown in the table below

从表中我们可以看到,这些优选实施例的色温在1850~2150K之间,即我们所说的烛光色,光色和相关色温的黑体轨迹的距离duv的绝对值均小于0.005。所有实施例在CIE1931色坐标图中均落入图3所示的区域1中,而实施例1、2、3、8、9、10、11落入本发明的优选光色区域(图3中的区域2)之中,其中实施例1最接近椭圆的中心是本发明的最佳方案。各实施例的显色性参数CRI均大于90,R9不小于50,色域指数Rg大于90。We can see from the table that the color temperature of these preferred embodiments is between 1850K and 2150K, which is what we call candlelight color, and the absolute value of the distance duv of the blackbody locus of light color and correlated color temperature is less than 0.005. All embodiments all fall in area 1 shown in Figure 3 in the CIE1931 color coordinate diagram, and embodiment 1,2,3,8,9,10,11 falls into the preferred light color area of the present invention (in Figure 3 Among the region 2), the center of the ellipse in which embodiment 1 is closest is the best solution of the present invention. The color rendering parameter CRI of each embodiment is greater than 90, R9 is not less than 50, and the color gamut index Rg is greater than 90.

下面我们具体介绍上表所列的各优选实施例。Below we specifically introduce each preferred embodiment listed in the table above.

实施例1,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉CaAlSiN3:Eu,Peak=648nm,Hw=86.6nm)0.72g;绿色荧光粉(Ga-YAG绿粉,Y3(Ga,Al)5O12:Ce,Peak=522nm,Hw=107.95nm)2.50g;黄色荧光粉(YAG,Peak=561nm,Hw=121.7nm)1.20g;蓝绿色荧光粉(BaSi2N2O2:Eu,Peak=494nm,Hw=32.6nm)0.30g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图4为实施例1和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的11.0%。从380nm到红光区峰值波长640nm之间实施例1光谱与参考光谱的强度差值A(λ)的范围是[-0.51,0.71],如图5所示。实施1的色坐标为x=0.5274,y=0.4138,色温1998K,duv=0.0002,显色指数CRI是91.1,R9是64.6,Rf是87.9,色域指数Rg是101.9。Embodiment 1, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 0.72g of red phosphor (nitride red powder CaAlSiN 3 :Eu, Peak=648nm, Hw=86.6nm); green phosphor (Ga-YAG green powder, Y 3 (Ga,Al) 5 O 12 : Ce, Peak=522nm, Hw=107.95nm) 2.50g; yellow phosphor (YAG, Peak=561nm, Hw=121.7nm) 1.20g; blue-green phosphor (BaSi 2 N 2 O 2 :Eu, Peak=494nm, Hw=32.6nm) 0.30g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 4 is the relative spectral energy distribution diagram of Example 1 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 11.0% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 1 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red light region is [-0.51, 0.71], as shown in FIG. 5 . The color coordinates of implementation 1 are x=0.5274, y=0.4138, color temperature 1998K, duv=0.0002, color rendering index CRI is 91.1, R9 is 64.6, Rf is 87.9, color gamut index Rg is 101.9.

实施例2,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉(Ca,Sr)AlSiN3:Eu,Peak=651nm,Hw=88.9nm)0.80g;绿色荧光粉((Y,Gd)3(Ga,Al)5O12:Ce,Peak=553nm,Hw=121.0nm)4.31g;蓝绿色荧光粉(Ba2SiO4:Eu,Peak=509nm,Hw=56.2nm)0.60g;光扩散剂纳米氧化钛0.06g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图6为实施例2和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的9.0%。从380nm到红光区峰值波长640nm之间实施例2光谱与参考光谱的强度差值A(λ)的范围是[-0.43,0.97],如图7所示。实施2的色坐标为x=0.5326,y=0.4137,色温1957K,duv=0.0004,显色指数CRI是95.4,R9是68.6,Rf是92.9,色域指数Rg是100.5。Embodiment 2, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 0.80 g of red phosphor (nitride red powder (Ca, Sr) AlSiN 3 :Eu, Peak=651nm, Hw=88.9nm); green phosphor ((Y,Gd) 3 (Ga,Al) 5 O 12 : Ce, Peak=553nm, Hw=121.0nm) 4.31g; blue-green phosphor (Ba 2 SiO 4 :Eu, Peak=509nm, Hw=56.2nm) 0.60g; light diffusing agent nano-titanium oxide 0.06g; Transparent silicone 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 6 is the relative spectral energy distribution diagram of Example 2 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 9.0% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 2 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red light region is [-0.43, 0.97], as shown in FIG. 7 . The color coordinates of implementation 2 are x=0.5326, y=0.4137, color temperature 1957K, duv=0.0004, color rendering index CRI is 95.4, R9 is 68.6, Rf is 92.9, color gamut index Rg is 100.5.

实施例3,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉(Ca,Sr)AlSiN3:Eu,Peak=651nm,Hw=88.9nm)0.78g;绿色荧光粉((Y,Gd)3(Ga,Al)5O12:Ce,Peak=553nm,Hw=121.0nm)4.29g;黄色荧光粉(硅酸盐黄色荧光粉(Ca,Sr,Ba)2SiO4:Eu,Peak=584nm,Hw=69.1nm)0.50g;蓝绿色荧光粉(BaSi2N2O2:Eu,Peak=494nm,Hw=32.6nm)0.50g;光扩散剂纳米氧化钛0.12g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图8为实施例3和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的9.4%。从380nm到红光区峰值波长640nm之间实施例3光谱与参考光谱的强度差值A(λ)的范围是[-0.51,0.70],如图9所示。实施3的色坐标为x=0.5310,y=0.4166,色温1988K,duv=0.0012,显色指数CRI是92.1,R9是61.0,Rf是91.1,色域指数Rg是98.9。Embodiment 3, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 0.78g of red phosphor (nitride red powder (Ca,Sr)AlSiN 3 :Eu, Peak=651nm, Hw=88.9nm); green phosphor ((Y,Gd) 3 (Ga,Al) 5 O 12 : Ce, Peak=553nm, Hw=121.0nm) 4.29g; yellow phosphor (silicate yellow phosphor (Ca, Sr, Ba) 2 SiO 4 : Eu, Peak=584nm, Hw=69.1nm) 0.50 g; blue-green phosphor (BaSi 2 N 2 O 2 :Eu, Peak=494nm, Hw=32.6nm) 0.50g; light diffusing agent nano-titanium oxide 0.12g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 8 is the relative spectral energy distribution diagram of Example 3 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 9.4% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 3 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red region is [-0.51, 0.70], as shown in FIG. 9 . The color coordinates of implementation 3 are x=0.5310, y=0.4166, color temperature 1988K, duv=0.0012, color rendering index CRI is 92.1, R9 is 61.0, Rf is 91.1, color gamut index Rg is 98.9.

实施例4,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉CaAlSiN3:Eu,Peak=648nm,Hw=86.6nm)1.06g,硅酸盐红粉((Sr,Ba)3Si5O5:Eu,Peak=612nm,Hw=117.0nm)0.23g;硅酸盐绿色荧光粉(Ca,Sr,Mg)SiO4:Eu,Peak=556nm,Hw=121.0nm)4.33g;光扩散剂纳米氧化硅0.18g;透明硅胶6.00g。在本实施例中采用了两种红光荧光粉,将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图10为实施例4和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的2.1%。从380nm到红光区峰值波长640nm之间实施例4光谱与参考光谱的强度差值A(λ)的范围是[-0.52,0.88],如图11所示。实施4的色坐标为x=0.5450,y=0.4204,色温1904K,duv=0.0030,显色指数CRI是92.5,R9是67.7,Rf是86.9,色域指数Rg是90.3。Embodiment 4, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 1.06g of red phosphor (nitride red powder CaAlSiN 3 :Eu, Peak=648nm, Hw=86.6nm), silicate red powder ((Sr,Ba) 3 Si 5 O 5 :Eu, Peak=612nm , Hw=117.0nm) 0.23g; silicate green phosphor (Ca, Sr, Mg) SiO 4 :Eu, Peak=556nm, Hw=121.0nm) 4.33g; light diffusing agent nano silicon oxide 0.18g; transparent silica gel 6.00g. In this embodiment, two kinds of red light phosphors are used. Put the above phosphors into transparent silica gel, mix well and evenly with a mixer, coat the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 10 is the relative spectral energy distribution diagram of Example 4 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 2.1% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 4 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red light region is [-0.52, 0.88], as shown in FIG. 11 . The color coordinates of implementation 4 are x=0.5450, y=0.4204, color temperature 1904K, duv=0.0030, color rendering index CRI is 92.5, R9 is 67.7, Rf is 86.9, color gamut index Rg is 90.3.

实施例5,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉Sr2Si5N8:Eu,Peak=635nm,Hw=92.2nm)1.21g;绿色荧光粉(LuAG, Lu3Al5O12:Ce,Peak=545nm,Hw=116.8nm)3.97g;蓝绿色荧光粉(BaSi2N2O2:Eu,Peak=494nm,Hw=32.6nm)0.52g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图12为实施例5和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于630nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的12.8%。从380nm到红光区峰值波长630nm之间实施例5光谱与参考光谱的强度差值A(λ)的范围是[-0.34,1.41],如图13所示。实施5的色坐标为x=0.5311,y=0.4007,色温1886K,duv=-0.0034,显色指数CRI是90.5,R9是50.7,Rf是84.8,色域指数Rg是104.2。Embodiment 5, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional illuminant 1042 includes 1.21 g of red phosphor (nitride red powder Sr 2 Si 5 N 8 :Eu, Peak=635nm, Hw=92.2nm); green phosphor (LuAG, Lu 3 Al 5 O 12 :Ce, Peak= 545nm, Hw=116.8nm) 3.97g; blue-green phosphor (BaSi 2 N 2 O 2 :Eu, Peak=494nm, Hw=32.6nm) 0.52g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 12 is the relative spectral energy distribution diagram of Example 5 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 630nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 12.8% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 5 and the reference spectrum from 380nm to the peak wavelength of 630nm in the red light region is [-0.34, 1.41], as shown in FIG. 13 . The color coordinates of implementation 5 are x=0.5311, y=0.4007, color temperature 1886K, duv=-0.0034, color rendering index CRI is 90.5, R9 is 50.7, Rf is 84.8, color gamut index Rg is 104.2.

实施例6,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉Sr2Si5N8:Eu,Peak=635nm,Hw=92.2nm)0.81g;绿色荧光粉(Ga-YAG,Y(Ga,Al)5O12:Ce,Peak=522nm,Hw=107.9nm)5.50g;黄色荧光粉(YAG,Peak=561nm,Hw=121.7nm)0.79g;蓝绿色荧光粉(BaSi2N2O2:Eu,Peak=494nm,Hw=32.6nm)0.49g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图14为实施例6和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于630nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的17.8%。从380nm到红光区峰值波长630nm之间实施例6光谱与参考光谱的强度差值A(λ)的范围是[-0.27,1.21],如图15所示。实施6的色坐标为x=0.5135,y=0.4023,色温2041K,duv=-0.0038,显色指数CRI是91.3,R9是55.0,Rf是86.6,色域指数Rg是104.4。Embodiment 6, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional illuminant 1042 includes 0.81g of red phosphor (nitride red powder Sr 2 Si 5 N 8 :Eu, Peak=635nm, Hw=92.2nm); green phosphor (Ga-YAG, Y(Ga,Al) 5 O 12 : Ce, Peak=522nm, Hw=107.9nm) 5.50g; Yellow phosphor (YAG, Peak=561nm, Hw=121.7nm) 0.79g; Blue-green phosphor (BaSi 2 N 2 O 2 :Eu, Peak=494nm , Hw=32.6nm) 0.49g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 14 is the relative spectral energy distribution diagram of Example 6 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 630nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 17.8% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 6 and the reference spectrum from 380nm to the peak wavelength of 630nm in the red light region is [-0.27, 1.21], as shown in FIG. 15 . The color coordinates of implementation 6 are x=0.5135, y=0.4023, color temperature 2041K, duv=-0.0038, color rendering index CRI is 91.3, R9 is 55.0, Rf is 86.6, color gamut index Rg is 104.4.

实施例7,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉CaAlSiN3:Eu,Peak=645nm,Hw=89.6nm)0.64g;绿色荧光粉((Y,Gd)3(Ga,Al)5O12:Ce,Peak=553nm,Hw=121.0nm)4.38g;黄色荧光粉(硅酸盐黄色荧光粉(Ca,Sr,Ba)2SiO4:Eu,Peak=584nm,Hw=69.1nm)0.53g;光扩散剂纳米氧化硅0.06g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图16为实施例7和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的9.2%。从380nm到红光区峰值波长640nm之间实施例7光谱与参考光谱的强度差值A(λ)的范围是[-0.61,0.79],如图17所示。实施7的色坐标为x=0.5223,y=0.4243,色温2109K,duv=0.0031,显色指数CRI是92.2,R9是64.4,Rf是92.2,色域指数Rg是96.5。Embodiment 7, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 0.64g of red phosphor (nitride red powder CaAlSiN 3 :Eu, Peak=645nm, Hw=89.6nm); green phosphor ((Y,Gd) 3 (Ga,Al) 5 O 12 :Ce, Peak=553nm, Hw=121.0nm) 4.38g; yellow phosphor (silicate yellow phosphor (Ca, Sr, Ba) 2 SiO 4 :Eu, Peak=584nm, Hw=69.1nm) 0.53g; light diffusing agent Nano silicon oxide 0.06g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 16 is the relative spectral energy distribution diagram of Example 7 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 9.2% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 7 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red region is [-0.61, 0.79], as shown in FIG. 17 . The color coordinates of Implementation 7 are x=0.5223, y=0.4243, color temperature 2109K, duv=0.0031, color rendering index CRI is 92.2, R9 is 64.4, Rf is 92.2, color gamut index Rg is 96.5.

实施例8,在光源模组104中第一发光元件1041为Peak=465nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉(Ca,Sr,Ba)AlSiN3:Eu,Peak=647nm,Hw=95.2nm)1.02g;绿色荧光粉((Y,Gd)3(Ga,Al)5O12:Ce,Peak=551nm,Hw=120.1nm)4.25g;黄色荧光粉(硅酸盐黄色荧光粉(Ca,Sr,Ba)2SiO4:Eu,Peak=584nm,Hw=69.1nm)0.55g;光扩散剂纳米氧化铝0.06g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图18为实施例8和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在465nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的10.3%。从380nm到红光区峰值波长640nm之间实施例8光谱与参考光谱的强度差值A(λ)的范围是[-0.35,0.78],如图19所示。实施9的色坐标为x=0.5301,y=0.4186,色温2007K,duv=0.0017,显色指数CRI是94.2,R9是73.1,Rf是89.2,色域指数Rg是94.6。Embodiment 8, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=465nm. The additional luminous body 1042 includes red phosphor (nitride red powder (Ca, Sr, Ba) AlSiN 3 :Eu, Peak=647nm, Hw=95.2nm) 1.02g; green phosphor ((Y, Gd) 3 (Ga, Al ) 5 O 12 : Ce, Peak=551nm, Hw=120.1nm) 4.25g; yellow phosphor (silicate yellow phosphor (Ca, Sr, Ba) 2 SiO 4 : Eu, Peak=584nm, Hw=69.1nm ) 0.55g; light diffusing agent nano-alumina 0.06g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 18 is the relative spectral energy distribution diagram of Example 8 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 465nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 10.3% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 8 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red light region is [-0.35, 0.78], as shown in FIG. 19 . The color coordinates of Implementation 9 are x=0.5301, y=0.4186, color temperature 2007K, duv=0.0017, color rendering index CRI is 94.2, R9 is 73.1, Rf is 89.2, color gamut index Rg is 94.6.

实施例9,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉CaAlSiN3:Eu,Peak=648±5nm,Hw=86.6nm)0.75g;绿色荧光粉(Ga-YAG,Y(Ga,Al)5O12:Ce,Peak=536±5nm,Hw=111.6nm)5.60g;黄色荧光粉(YAG,Peak=561nm,Hw=121.7nm)0.40g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图20为实施例9和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的13.8%。从380nm到红光区峰值波长640nm之间实施例9光谱与参考光谱的强度差值A(λ)的范围是[-0.48,0.95],如图20所示。实施9的色坐标为x=0.5220,y=0.4080,色温2006K,duv=-0.0018,显色指数CRI是94.9,R9是73.3,Rf是87.9,色域指数Rg是105.8。In Embodiment 9, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 0.75g of red phosphor (nitride red powder CaAlSiN 3 :Eu, Peak=648±5nm, Hw=86.6nm); green phosphor (Ga-YAG, Y(Ga,Al) 5 O 12 :Ce , Peak=536±5nm, Hw=111.6nm) 5.60g; yellow phosphor (YAG, Peak=561nm, Hw=121.7nm) 0.40g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 20 is the relative spectral energy distribution diagram of Example 9 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 13.8% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 9 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red light region is [-0.48, 0.95], as shown in FIG. 20 . The color coordinates of Implementation 9 are x=0.5220, y=0.4080, color temperature 2006K, duv=-0.0018, color rendering index CRI is 94.9, R9 is 73.3, Rf is 87.9, color gamut index Rg is 105.8.

实施例10,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉CaAlSiN3:Eu,Peak=648nm,Hw=86.6nm)1.07g;绿色荧光粉(Ga-YAG,Y(Ga,Al)5O12:Ce,Peak=536nm,Hw=111.6nm)5.37g;黄色荧光粉(YAG,Peak=561nm,Hw=121.7nm)0.60g;蓝绿色荧光粉(BaSi2N2O2:Eu,Peak=494nm,Hw=32.6nm)0.30g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图22为实施例10和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的11.2%。从380nm到红光区峰值波长640nm之间实施例10光谱与参考光谱的强度差值A(λ)的范围是[-0.46,0.73],如图23所示。实施10的色坐标为x=0.5314,y=0.4099,色温1943K,duv=-0.0007,显色指数CRI是91.8,R9是62.8,Rf是86.8,色域指数Rg是103.6。In Embodiment 10, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 1.07g of red phosphor (nitride red powder CaAlSiN 3 :Eu, Peak=648nm, Hw=86.6nm); green phosphor (Ga-YAG, Y(Ga,Al) 5 O 12 :Ce, Peak =536nm, Hw=111.6nm) 5.37g; yellow phosphor (YAG, Peak=561nm, Hw=121.7nm) 0.60g; blue-green phosphor (BaSi 2 N 2 O 2 :Eu, Peak=494nm, Hw=32.6 nm) 0.30g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 22 is the relative spectral energy distribution diagram of Example 10 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 11.2% of that of the second peak. The range of intensity difference A(λ) between the spectrum of Example 10 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red light region is [-0.46, 0.73], as shown in FIG. 23 . The color coordinates of Implementation 10 are x=0.5314, y=0.4099, color temperature 1943K, duv=-0.0007, color rendering index CRI is 91.8, R9 is 62.8, Rf is 86.8, color gamut index Rg is 103.6.

实施例11,在光源模组104中第一发光元件1041为Peak=450nm的蓝光LED芯片。附加发光体1042包括红色荧光粉(氮化物红粉CaAlSiN3:Eu,Peak=648nm,Hw=86.6nm)0.85g;绿色荧光粉(Ga-YAG,Y(Ga,Al)5O12:Ce,Peak=536nm,Hw=111.6nm)6.45g;黄色荧光粉(硅酸盐黄色荧光粉(Ca,Sr,Ba)2SiO4:Eu,Peak=584nm,Hw=69.1nm)0.45g;光扩散剂纳米氧化铝0.12g;透明硅胶6.00g。将上述荧光粉放入透明硅胶,再搅拌机充分混合均匀,涂覆在蓝光LED芯片上,烘干除气泡后得到一种烛光色LED芯片。Peak表示峰值波长,Hw表示半宽度,以上数值都是本实施例中的实际数值,并不是对本发明的限定,因为在实际生产中即使型号完全相同,由于LED芯片的批次不同,或者由于荧光粉纯度、颗粒大小的不同其峰值波长和半宽度都有可能会和以上数据稍有偏差,这个偏差值一般在±5nm之间,应该认为在这个范围内的其他方案是等同于本实施例的。图24为实施例11和其参考光谱(Y=100)的相对光谱能量分布图,蓝光LED芯片发出的蓝光能量在450nm处形成第一峰,第二峰位于640nm是整个光谱中能量最高的点,第一峰的峰值强度为第二峰的11.3%。从380nm到红光区峰值波长640nm之间实施例11光谱与参考光谱的强度差值A(λ)的范围是[-0.52,0.56],如图25所示。实施11的色坐标为x=0.5225,y=0.4171,色温2061K,duv=0.0009,显色指数CRI是92.5,R9是65.0,Rf是91.2,色域指数Rg是99.9。Embodiment 11, the first light emitting element 1041 in the light source module 104 is a blue LED chip with Peak=450nm. The additional luminous body 1042 includes 0.85 g of red phosphor (nitride red powder CaAlSiN 3 :Eu, Peak=648nm, Hw=86.6nm); green phosphor (Ga-YAG, Y(Ga,Al) 5 O 12 :Ce, Peak =536nm, Hw=111.6nm) 6.45g; yellow phosphor (silicate yellow phosphor (Ca, Sr, Ba) 2 SiO 4 :Eu, Peak=584nm, Hw=69.1nm) 0.45g; light diffusing agent nano Aluminum oxide 0.12g; transparent silica gel 6.00g. Put the above-mentioned fluorescent powder into transparent silica gel, and then fully mix it evenly with a mixer, coat it on the blue LED chip, dry and remove air bubbles to obtain a candle light color LED chip. Peak represents the peak wavelength, and Hw represents the half-width. The above values are all actual values in this embodiment, and are not limitations of the present invention, because in actual production, even if the models are exactly the same, due to different batches of LED chips, or due to fluorescence Depending on the powder purity and particle size, the peak wavelength and half-width may have a slight deviation from the above data. This deviation is generally between ±5nm. It should be considered that other solutions within this range are equivalent to this embodiment. . Figure 24 is the relative spectral energy distribution diagram of Example 11 and its reference spectrum (Y=100). The blue light energy emitted by the blue LED chip forms the first peak at 450nm, and the second peak at 640nm is the highest energy point in the entire spectrum. , the peak intensity of the first peak is 11.3% of that of the second peak. The range of the intensity difference A(λ) between the spectrum of Example 11 and the reference spectrum from 380nm to the peak wavelength of 640nm in the red light region is [-0.52, 0.56], as shown in FIG. 25 . The color coordinates of Implementation 11 are x=0.5225, y=0.4171, color temperature 2061K, duv=0.0009, color rendering index CRI is 92.5, R9 is 65.0, Rf is 91.2, color gamut index Rg is 99.9.

上文对本发明优选实施例的描述是为了说明和描述,并非想要把本发明穷尽或局限于所公开的具体形式,显然,可能做出许多修改和变化,这些修改和变化可能对于本领域技术人员来说是显然的,应当包括在由所附权利要求书定义的本发明的范围之内。The foregoing description of the preferred embodiments of the present invention is for purposes of illustration and description, and is not intended to be exhaustive or to limit the invention to the specific forms disclosed. Obviously, many modifications and changes may be made, and these modifications and changes may be necessary for those skilled in the art. It is obvious to the person that it is intended to be included within the scope of the present invention as defined by the appended claims.

Claims (19)

1.一种光源模组,其特征在于,包括:1. A light source module, characterized in that it comprises: 第一发光元件,所述第一发光元件发出峰值波长为435~465nm的第一颜色光;a first light-emitting element, the first light-emitting element emits light of a first color with a peak wavelength of 435-465nm; 附加发光体,所述附加发光体被配置为接收所述第一发光元件所发射的部分光线,并将其转换为不同于第一颜色的第二颜色光;an additional illuminant configured to receive part of the light emitted by the first light emitting element and convert it into light of a second color different from the first color; 所述第一颜色和第二颜色光混合形成白光,the first color and the second color light are mixed to form white light, 所述附加发光体包括:The additional illuminants include: 发射光的峰值波长在600~670nm,发射光的光谱半宽度为80~120nm的红色或橙色荧光粉;The peak wavelength of emitted light is 600~670nm, and the red or orange phosphor with spectral half width of emitted light is 80~120nm; 发射光的峰值波长在520~560nm, 发射光谱的半宽度为60~115nm的绿色荧光粉。The peak wavelength of the emitted light is 520~560nm, and the green phosphor with the half width of the emission spectrum is 60~115nm. 2.如权利要求1所述的光源模组,其特征在于,所述第一发光元件为蓝光LED芯片,所述附加发光体还包括封装体,所述封装体和荧光粉混合后涂覆在所述第一发光元件之上。2. The light source module according to claim 1, wherein the first light-emitting element is a blue LED chip, and the additional light-emitting body further includes a package body, and the package body and phosphor powder are mixed and coated on above the first light-emitting element. 3.如权利要求2所述的光源模组,其特征在于,所述封装体为树脂或硅胶。3. The light source module according to claim 2, wherein the package is made of resin or silicone. 4.如权利要求2所述的光源模组,其特征在于,所述封装体中包括光扩散剂。4. The light source module according to claim 2, wherein the package includes a light diffusing agent. 5.如权利要求1所述的光源模组,其特征在于,所述红色或橙色荧光粉发射光的光谱半宽度为80~100nm。5 . The light source module according to claim 1 , wherein the spectral half-width of the light emitted by the red or orange phosphor is 80-100 nm. 6.如权利要求2所述的光源模组,其特征在于,所述红色或橙色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:6. The light source module according to claim 2, wherein the red or orange phosphor is any one or a mixture of two or more of the following phosphors: (a) 具有1113晶体结构的氮化物红粉,Eu2+为激活剂(a) Nitride red powder with 1113 crystal structure, Eu 2+ as activator 化学组成通式:(M1)1-xAlSiN3:Eux General formula of chemical composition: (M1) 1-x AlSiN 3 :Eu x 其中M1为Ca、Sr、Ba中至少一种元素,x=0.005~0.300;Where M1 is at least one element among Ca, Sr and Ba, x=0.005~0.300; (b) 具有258晶体结构的氮化物红粉,Eu2+为激活剂(b) Nitride red powder with 258 crystal structure, Eu 2+ as activator 化学组成通式:(M2)2-xSi5N8:Eux General formula of chemical composition: (M2) 2 -xSi 5 N 8 : Eu x 其中M2为Ca、Sr、Ba、Mg中至少一种元素,x=0.005~0.300;Where M2 is at least one element among Ca, Sr, Ba, Mg, x=0.005~0.300; (c) 氮氧化物荧光粉(塞隆体α-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon α-SiAlON), Eu 2+ is the activator 化学组成通式:((M3)1-a)xSibAlcOdNe:EuaGeneral formula of chemical composition: ((M3) 1-a ) x Si b Al c O d Ne : Eua 其中M3为Li、Na、K、Rb、Cs、Sr、Ba、Sc、Y、La、Gd之中至少一种元素,x=0.15~1.5,a=0.005~0.300, b+c=12,d+e=16;Where M3 is at least one element among Li, Na, K, Rb, Cs, Sr, Ba, Sc, Y, La, Gd, x=0.15~1.5, a=0.005~0.300, b+c=12, d +e=16; (d) 硅酸盐荧光粉,Eu2+为激活剂(d) Silicate phosphor, Eu2+ as activator 化学组成通式:(Sr,Ba)3-xSi5O5:Eux General formula of chemical composition: (Sr,Ba) 3-x Si 5 O 5 :Eu x 其中x=0.005~0.300。where x=0.005~0.300. 7.如权利要求6所述的光源模组,其特征在于,所述红色或橙色荧光粉的重量占混入荧光粉后的封装体的总重量的10.0~26.0%。7. The light source module according to claim 6, wherein the weight of the red or orange phosphor accounts for 10.0-26.0% of the total weight of the package after the phosphor is mixed. 8.如权利要求2所述的光源模组,其特征在于,所述绿色荧光粉发射光的光谱半宽度为90~115nm。8. The light source module according to claim 2, wherein the spectral half-width of the light emitted by the green phosphor is 90-115 nm. 9.如权利要求2所述的光源模组,其特征在于,所述绿色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:9. The light source module according to claim 2, wherein the green phosphor is any one or a mixture of two or more of the following phosphors: (a) 石榴石结构的绿色荧光粉,Ce3+为激活剂(a) Green phosphor with garnet structure, Ce 3+ as activator 化学组成通式:(M4)3-x(M5)5O12:Cex General formula of chemical composition: (M4) 3-x (M5) 5 O 12 : Cex 其中M4为Y、Lu、Gd及La中至少一种元素,M5为Al、Ga中至少一种元素,x=0.005~0.200;Wherein M4 is at least one element among Y, Lu, Gd and La, M5 is at least one element among Al and Ga, x=0.005~0.200; (b) 硅酸盐体系的绿色荧光粉,Eu2+为激活剂(b) Green phosphor in silicate system, Eu 2+ as activator 化学组成通式:(M6)2-xSiO4:Eux General formula of chemical composition: (M6) 2-x SiO 4 : Eu x 或 (Ba,Ca,Sr)2-x(Mg,Zn)Si2O7:Eux or (Ba,Ca,Sr) 2-x (Mg,Zn)Si 2 O 7 :Eu x 其中M6为Mg、Sr、Ca、Ba中至少一种元素,x=0.01~0.20;Where M6 is at least one element of Mg, Sr, Ca, Ba, x=0.01~0.20; (c) 氮氧化物荧光粉 (塞隆体β-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon β-SiAlON), Eu 2+ as activator 化学组成通式:SibAlcOdNe:Eux General formula of chemical composition: Si b Al c O d Ne : Eu x 其中x=0.005~0.400,b+c=12,d+e=16;Where x=0.005~0.400, b+c=12, d+e=16; (d) 铝酸盐体系荧光粉,Eu2+为激活剂(d) Aluminate system phosphor, Eu 2+ as activator 化学组成通式:(Sr,Ba)2-xAl2O4:Eux General formula of chemical composition: (Sr,Ba) 2-x Al 2 O 4 :Eu x 或 (Sr,Ba)4-xAl14O25:Eux Or (Sr,Ba) 4-x Al 14 O 25 : Eu x 其中x=0.01~0.15。where x=0.01~0.15. 10.如权利要求9所述的光源模组,其特征在于,所述绿色荧光粉的重量占混入荧光粉后的封装体的总重量的55.0~88.0%。10. The light source module according to claim 9, wherein the weight of the green phosphor accounts for 55.0-88.0% of the total weight of the package after the phosphor is mixed. 11.如权利要求2所述的光源模组,其特征在于,所述附加发光体还包括发射光的峰值波长在560~600nm,发射光的光谱半宽度为60~125nm的黄色荧光粉。11. The light source module according to claim 2, wherein the additional illuminant further comprises a yellow phosphor with a peak wavelength of emitted light at 560-600 nm and a spectral half-width of emitted light at 60-125 nm. 12.如权利要求11所述的光源模组,其特征在于,所述黄色荧光粉发射光的光谱半宽度为100~125nm。12. The light source module according to claim 11, wherein the spectral half-width of the light emitted by the yellow phosphor is 100-125 nm. 13.如权利要求11所述的光源模组,其特征在于,所述黄色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:13. The light source module according to claim 11, wherein the yellow phosphor is any one or a mixture of two or more of the following phosphors: (a) 石榴石结构的黄色荧光粉,Ce3+为激活剂(a) Yellow phosphor with garnet structure, Ce 3+ as activator 化学组成通式:(Y,Gd)3-xAl5O12:Cex General formula of chemical composition: (Y,Gd) 3-x Al 5 O 12 :Cex 其中x=0.005~0.100;where x=0.005~0.100; (b) 硅酸盐体系的黄色荧光粉,Eu2+为激活剂(b) Yellow phosphor in silicate system, Eu 2+ as activator 化学组成通式:(M7)2-xSiO4:Eux General formula of chemical composition: (M7) 2-x SiO 4 :Eu x 或 (Ba,Ca,Sr)2-x(Mg,Zn)Si2O7:Eux or (Ba,Ca,Sr) 2-x (Mg,Zn)Si 2 O 7 :Eu x 其中M7为Sr、Ca、Ba中至少一种元素,x=0.01~0.20;Where M7 is at least one element among Sr, Ca and Ba, x=0.01~0.20; (c) 氮氧化物荧光粉 (塞隆体β-SiAlON),Eu2+为激活剂(c) Oxynitride phosphor (Sialon β-SiAlON), Eu 2+ as activator 化学组成通式:SibAlcOdNe:Eux General formula of chemical composition: Si b Al c O d Ne : Eu x 其中x=0.005~0.400,b+c=12,d+e=16。Where x=0.005~0.400, b+c=12, d+e=16. 14.如权利要求13所述的光源模组,其特征在于,所述黄色荧光粉的重量在混入荧光粉后的封装体的总重量中的占比小于30.0%。14. The light source module according to claim 13, wherein the weight of the yellow phosphor accounts for less than 30.0% of the total weight of the package after the phosphor is mixed. 15.如权利要求2所述的光源模组,其特征在于,所述附加发光体还包括发射光的峰值波长在485~520nm,发射光的光谱半宽度为25~65nm的蓝绿色荧光粉。15 . The light source module according to claim 2 , wherein the additional illuminant further comprises a blue-green phosphor with a peak wavelength of emitted light at 485-520 nm and a spectral half-width of emitted light at 25-65 nm. 16.如权利要求15所述的光源模组,其特征在于,所述蓝绿色荧光粉为下述荧光粉中的任意一种或两种以上混合而成:16. The light source module according to claim 15, wherein the blue-green phosphor is any one or a mixture of two or more of the following phosphors: (a)氮氧化物,Eu2+为激活剂(a) Nitrogen oxides, Eu 2+ as activator 化学组成通式:(Ba,Ca)Si2N2O2:Eu;General formula of chemical composition: (Ba,Ca)Si 2 N 2 O 2 :Eu; (b) 掺Ga石榴石荧光粉,Eu2+为激活剂(b) Ga-doped garnet phosphor with Eu 2+ as the activator 化学组成通式:Ga-LuAG:Eu;General formula of chemical composition: Ga-LuAG:Eu; (c) 硅酸盐荧光粉,Eu2+为激活剂(c) Silicate phosphor with Eu 2+ as activator 化学组成通式:Ba2SiO4:Eu。General formula of chemical composition: Ba 2 SiO 4 :Eu. 17.如权利要求16所述的光源模组,其特征在于,所述蓝绿色荧光粉的重量在混入荧光粉后的封装体的总重量中的占比小于30.0%。17. The light source module according to claim 16, wherein the weight of the blue-green phosphor accounts for less than 30.0% of the total weight of the package after the phosphor is mixed. 18.一种照明装置,其特征在于,包括:18. A lighting device, characterized in that it comprises: 如权利要求1至17中任意一项所述的光源模组;The light source module according to any one of claims 1 to 17; 电源模组,连接所述光源模组,为所述光源模组提供工作所需电力。The power supply module is connected to the light source module to provide the power required for the light source module to work. 19.如权利要求18所述的照明装置,其特征在于,所述照明装置还包括控制器,所述控制器连接所述光源模组,用于调整所述光源模组所发出照射光。19. The lighting device according to claim 18, further comprising a controller connected to the light source module for adjusting the illumination light emitted by the light source module.
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