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CN107503195A - A kind of dyeing waste water dyeing inorganic agent and preparation method thereof - Google Patents

A kind of dyeing waste water dyeing inorganic agent and preparation method thereof Download PDF

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Publication number
CN107503195A
CN107503195A CN201710572576.9A CN201710572576A CN107503195A CN 107503195 A CN107503195 A CN 107503195A CN 201710572576 A CN201710572576 A CN 201710572576A CN 107503195 A CN107503195 A CN 107503195A
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CN
China
Prior art keywords
dyeing
agent
waste water
raw material
inorganic agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710572576.9A
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Chinese (zh)
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CN107503195B (en
Inventor
李接代
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHISHI WANFENGSHENG DYEING WEAVING CO Ltd
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SHISHI WANFENGSHENG DYEING WEAVING CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by SHISHI WANFENGSHENG DYEING WEAVING CO Ltd filed Critical SHISHI WANFENGSHENG DYEING WEAVING CO Ltd
Priority to CN201710572576.9A priority Critical patent/CN107503195B/en
Publication of CN107503195A publication Critical patent/CN107503195A/en
Application granted granted Critical
Publication of CN107503195B publication Critical patent/CN107503195B/en
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/30Nature of the water, waste water, sewage or sludge to be treated from the textile industry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/04Surfactants, used as part of a formulation or alone

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The present invention discloses a kind of dyeing waste water dyeing inorganic agent, includes the raw material of following percentage by weight:5 10% cleaning agent, 10 20% borax, 5 10% surfactant, 3 5% buffer, 5 10% anti-flocculating agent, 3 5% dispersing agent MF, 0.5 1% defoamer, 10 20% odium stearate;Surplus is water.Its preparation method is:First odium stearate is diluted with water, the aqueous solution that mass concentration is 10~20% is prepared into, then the aqueous solution is transferred in reactor, adds surfactant, it is heated to 65~75 DEG C, cleaning agent and borax are sequentially added, is thoroughly mixed, is cooled to 35~45 DEG C, sequentially add defoamer, dispersing agent MF, buffer and anti-flocculating agent, after foam eliminates naturally, after finally adding water to be thoroughly mixed, that is, the dyeing waste water dyeing inorganic agent is made.A kind of dyeing waste water dyeing inorganic agent of the present invention, it is possible to increase the reappearance of dyeing, it is ensured that dyeing quality and cloth cover effect.

Description

A kind of dyeing waste water dyeing inorganic agent and preparation method thereof
Technical field
The present invention relates to techniques of Dyeing Wastewater Treatment field, and in particular to be a kind of dyeing waste water dyeing inorganic agent and Its preparation method.
Background technology
Dyeing waste water circulating dyeing process is the dyeing of one of innovation, is entirely as treating directly using dyeing waste water The dyeing water of dyeing and weaving thing, waste water treating agent, surfactant, dyeing used additives and dyestuff are added in dyeing, so as to complete Treat the dyeing of dyeing and weaving thing and realize the recycling of dyeing waste water, kill two birds with one stone., it is necessary to open in the dyeing course of this technique Send out dyeing waste water a kind of and dye special inorganic agent, improve the reappearance of dyeing, it is ensured that dyeing quality and cloth cover effect, this case by This is produced.
The content of the invention
It is an object of the invention to provide a kind of dyeing waste water dyeing inorganic agent, it is possible to increase the reappearance of dyeing, really Protect dyeing quality and cloth cover effect.
In order to reach above-mentioned purpose, solution of the invention is:
A kind of dyeing waste water dyeing inorganic agent, include the raw material of following percentage by weight:
A kind of dyeing waste water dyeing inorganic agent, include the raw material of following percentage by weight:
The cleaning agent is the cleaning agent WFS288 that Shishi Wanfengsheng Bleaching and Dyeing Knitting Co., Ltd. provides.
The surfactant is the surfactant that Shishi Wanfengsheng Bleaching and Dyeing Knitting Co., Ltd. provides.
The buffer is disodium hydrogen phosphate.
The anti-flocculating agent is the anti-flocculating agent DN that Guangdong Demei Fine Chemical Co., Ltd. provides.
The defoamer is the defoamer that Zhejiang development of evil in febrile disease fine chemistry industry limited company provides.
The preparation method of the dyeing waste water dyeing inorganic agent, comprises the following steps:Raw material gross weight 10-20% will first be accounted for Odium stearate be diluted with water, be prepared into mass concentration be 10~20% the aqueous solution, the aqueous solution is then transferred to reactor In, 65~75 DEG C are heated to, then example sequentially adds the cleaning agent and 10- for accounting for raw material gross weight 5-10% by weight percentage 20% borax, is thoroughly mixed, and is cooled to 35~45 DEG C, then example by weight percentage sequentially adds and accounts for raw material gross weight 0.5-1% defoamer, 3-5% dispersing agent MF, 3-5% buffer and 5-10% anti-flocculating agent, treat foam nature After elimination, after finally adding water to be thoroughly mixed, that is, the dyeing waste water dyeing inorganic agent is made.
After adopting the above technical scheme, a kind of dyeing waste water dyeing inorganic agent of the present invention, each raw material are act as:
1st, cleaning agent:Clean cloth cover greasy dirt;
2nd, borax:With softened water and pH value cushioning effect, cloth cover dirt can also be removed;
3rd, surfactant:Prevent the dyestuff in dyeing waste water or impurity to be attached on fabric, improve dyeing quality;
4th, buffer:PH value in adjustable dye bath so that dye bath keeps weak basic condition, in favor of dyeing;
5th, anti-flocculating agent:Oil emulsion, colourity, heavy metal ion and the other pollutants gone in water removal;
6th, dispersing agent MF:It may be such that dye shade is bright-coloured, uniform coloring, improve fabric dye uptake;
7th, defoamer:Quickly defoam;
8th, stearic acid sodium:With emulsification, infiltration, decontamination.
A kind of dyeing waste water dyeing inorganic agent of the present invention, has following distinguishing feature:(1) waste water can effectively be prevented Impurity, residual dye are attached on fabric again, and reduce the colourity in dyeing waste water;(2) there is certain cushioning effect, make PH value in dye bath keeps stability;(3) reappearance of dyeing is improved, it is ensured that dyeing quality and cloth cover effect.Therefore, it is of the invention There is wide application value in dyeing waste water dyeing.
Embodiment
In order to which technical scheme is explained further, the present invention is explained in detail below by specific embodiment State.
1st, prepare:
It is the cleaning agent that Shishi Wanfengsheng Bleaching and Dyeing Knitting Co., Ltd. provides to be related to cleaning agent in following examples WFS288, surfactant are the surfactant that Shishi Wanfengsheng Bleaching and Dyeing Knitting Co., Ltd. provides, and buffer is phosphoric acid Disodium hydrogen, anti-flocculating agent are the anti-flocculating agent DN that Guangdong Demei Fine Chemical Co., Ltd. provides, and defoamer passes for Zhejiang Change the defoamer that fine chemistry industry limited company provides.
Embodiment 1
A kind of dyeing waste water dyeing inorganic agent, its preparation comprise the following steps:To first the hard of raw material gross weight 15% be accounted for Resin acid sodium is diluted with water, and is prepared into the aqueous solution that mass concentration is 10%, then the aqueous solution is transferred in reactor, addition accounts for The surfactant of raw material gross weight 10%, is heated to 70 DEG C, then example by weight percentage sequentially adds and accounts for raw material gross weight 10% cleaning agent and 20% borax, are thoroughly mixed, and are cooled to 40 DEG C, then example by weight percentage is sequentially added and accounted for The defoamer of raw material gross weight 1%, 4% dispersing agent MF, 5% buffer and 8% anti-flocculating agent, treat that foam disappears naturally After removing, after finally adding water to be thoroughly mixed, that is, the dyeing waste water dyeing inorganic agent is made.In above-mentioned preparation method, initially The total amount of water used in dilution stearic acid sodium and the water used in being finally stirred accounts for the 27% of raw material gross weight.
Embodiment 2
A kind of dyeing waste water dyeing inorganic agent, its preparation comprise the following steps:To first the hard of raw material gross weight 10% be accounted for Resin acid sodium is diluted with water, and is prepared into the aqueous solution that mass concentration is 10%, then the aqueous solution is transferred in reactor, addition accounts for The surfactant of raw material gross weight 5%, is heated to 70 DEG C, then example by weight percentage sequentially adds and accounts for raw material gross weight 5% Cleaning agent and 10% borax, be thoroughly mixed, be cooled to 40 DEG C, then example by weight percentage sequentially adds and accounts for raw material The defoamer of gross weight 0.5%, 5% dispersing agent MF, 3% buffer and 10% anti-flocculating agent, treat that foam disappears naturally After removing, after finally adding water to be thoroughly mixed, that is, the dyeing waste water dyeing inorganic agent is made.In above-mentioned preparation method, initially The total amount of water used in dilution stearic acid sodium and the water used in being finally stirred accounts for the 51.5% of raw material gross weight.
Embodiment 3
A kind of dyeing waste water dyeing inorganic agent, its preparation comprise the following steps:To first the hard of raw material gross weight 20% be accounted for Resin acid sodium is diluted with water, and is prepared into the aqueous solution that mass concentration is 10%, then the aqueous solution is transferred in reactor, addition accounts for The surfactant of raw material gross weight 8%, is heated to 70 DEG C, then example by weight percentage sequentially adds and accounts for raw material gross weight 8% Cleaning agent and 15% borax, be thoroughly mixed, be cooled to 40 DEG C, then example by weight percentage sequentially adds and accounts for raw material The defoamer of gross weight 0.8%, 3% dispersing agent MF, 4% buffer and 5% anti-flocculating agent, treat that foam eliminates naturally Afterwards, after finally adding water to be thoroughly mixed, that is, the dyeing waste water dyeing inorganic agent is made.It is initially dilute in above-mentioned preparation method The total amount released the water used in stearic acid sodium and be finally stirred water used accounts for the 36.2% of raw material gross weight.
2nd, application method:
According to technique bath raio=1: 8 are put into dacron to be dyed into overflow dyeing machine, dyeing waste water are added, then to dye Dyeing waste water dyeing inorganic agent, surfactant, dyeing used additives are added in dyeing waste water in color machine, according to dyeing needs Dyestuff is added, after being warming up to 110 DEG C with 1.5 DEG C/min speed, overflow dyeing machine insulation operating 15 minutes, reusable heat exchanger is with 2 DEG C/min speed is cooled to 70 DEG C, to the direct cloth outputting that do not washed cloth after good color, dehydration, complete the dyeing of dacron.
3rd, compared with the Color of traditional dyeing process
Table 1 uses the dyeing of the present invention and the dyeing quality contrast table of traditional handicraft
From table 1 it follows that the dyeing waste water dyeing of the present invention is applied to the dyer of dyeing waste water with inorganic agent Helpful to the stability of dyeing in skill, the reappearance of dyeing is high, and dyeing quality and cloth cover effect are good.
Above-described embodiment and non-limiting product form of the invention and style, the ordinary skill people of any art The appropriate change or modification that member is done to it, it all should be regarded as not departing from the patent category of the present invention.

Claims (3)

  1. A kind of 1. dyeing waste water dyeing inorganic agent, it is characterised in that:Include the raw material of following percentage by weight:
  2. A kind of 2. dyeing waste water dyeing inorganic agent according to claim 1, it is characterised in that:Including following weight percent The raw material of ratio:
  3. 3. prepare a kind of dyeing waste water dyeing inorganic agent as claimed in claim 1, it is characterised in that:Its preparation method includes Following steps:First the odium stearate for accounting for raw material gross weight 10-20% is diluted with water, it is 10~20% to be prepared into mass concentration The aqueous solution, then the aqueous solution is transferred in reactor, example adds the surface for accounting for raw material gross weight 5-10% by weight percentage Activating agent, is heated to 65~75 DEG C, then by weight percentage example sequentially add the cleaning agent that accounts for raw material gross weight 5-10% and 10-20% borax, is thoroughly mixed, and is cooled to 35~45 DEG C, then example by weight percentage sequentially adds and accounts for raw material gross weight 0.5-1% defoamer, 3-5% dispersing agent MF, 3-5% buffer and 5-10% anti-flocculating agent are measured, treats foam certainly After so eliminating, after finally adding water to be thoroughly mixed, that is, the dyeing waste water dyeing inorganic agent is made.
CN201710572576.9A 2017-07-12 2017-07-12 A kind of dyeing waste water dyeing inorganic agent and preparation method thereof Active CN107503195B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113047069A (en) * 2021-03-24 2021-06-29 广东溢达纺织有限公司 Cleaning method for fabric mercerizing after-treatment

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709554A (en) * 2009-08-18 2010-05-19 石狮市万峰盛漂染织造有限公司 Surfactant for woven fabric dye-bath retreat process and preparation method thereof
CN102250493A (en) * 2011-06-09 2011-11-23 天津德凯化工股份有限公司 Blue alkali resistant active dye
CN103243588A (en) * 2013-06-08 2013-08-14 武汉纺织大学 Method for dyeing terylene textile at high temperature and under high pressure
CN104233856A (en) * 2014-08-20 2014-12-24 张家港市大新毛纺有限公司 Dyeing composition for wool and polyester blended fabric

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709554A (en) * 2009-08-18 2010-05-19 石狮市万峰盛漂染织造有限公司 Surfactant for woven fabric dye-bath retreat process and preparation method thereof
CN102250493A (en) * 2011-06-09 2011-11-23 天津德凯化工股份有限公司 Blue alkali resistant active dye
CN103243588A (en) * 2013-06-08 2013-08-14 武汉纺织大学 Method for dyeing terylene textile at high temperature and under high pressure
CN104233856A (en) * 2014-08-20 2014-12-24 张家港市大新毛纺有限公司 Dyeing composition for wool and polyester blended fabric

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113047069A (en) * 2021-03-24 2021-06-29 广东溢达纺织有限公司 Cleaning method for fabric mercerizing after-treatment

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