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CN107488791A - Copper smelting apparatus - Google Patents

Copper smelting apparatus Download PDF

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Publication number
CN107488791A
CN107488791A CN201710842877.9A CN201710842877A CN107488791A CN 107488791 A CN107488791 A CN 107488791A CN 201710842877 A CN201710842877 A CN 201710842877A CN 107488791 A CN107488791 A CN 107488791A
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CN
China
Prior art keywords
smelting
copper
zone
stripping section
matte regulus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710842877.9A
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Chinese (zh)
Inventor
李锋
张振民
尉克俭
李海春
周钢
陆金忠
蒋继穆
梁帅表
冯双杰
李兵
许欣
黎敏
曹珂菲
李东波
郝小红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China ENFI Engineering Corp
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China ENFI Engineering Corp
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Filing date
Publication date
Application filed by China ENFI Engineering Corp filed Critical China ENFI Engineering Corp
Priority to CN201710842877.9A priority Critical patent/CN107488791A/en
Publication of CN107488791A publication Critical patent/CN107488791A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00Obtaining copper
    • C22B15/0026Pyrometallurgy
    • C22B15/0028Smelting or converting
    • C22B15/0052Reduction smelting or converting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention provides a kind of copper smelting apparatus.The device is provided with inner chamber, and inner chamber includes smelting zone, stripping section and decanting zone, and smelting zone to copper concentrate carrying out melting to generate the first copper matte regulus and smelting slag;Stripping section is separated with smelting zone by the first partition wall, is connected between stripping section and smelting zone by smelting slag passage, and stripping section is used to carry out smelting slag dilution processing to generate the second copper matte regulus and poor slugging;Decanting zone is separated with stripping section by the second partition wall, and decanting zone is located at the side of the remote smelting zone of stripping section, is connected between decanting zone and stripping section by poor slugging passage, and decanting zone is used to carry out sedimentation separation to the second copper matte regulus and poor slugging.Above-mentioned copper smelting apparatus is the integration apparatus of a stove multicell, melting, dilution and sedimentation separation directly can be concentrated on into a stove, be effectively saved technological process, and occupation area of equipment is smaller, and equipment investment, operating cost decline to a great extent.

Description

Copper smelting apparatus
Technical field
The present invention relates to nonferrous metallurgy field, in particular to a kind of copper smelting apparatus.
Background technology
Existing copper metallurgy technique, the Copper in Slag amount of the direct output of smelting furnace are higher (1~4wt%), it is impossible to directly as abandoning Slag, it is required to reprocessing and reclaims the valuable metals such as copper therein.Currently used method is as follows:By the smelting slag of smelting furnace output Blend melt swinging dilution stove or sedimentation electric furnace in handled, through slag and copper matte regulus separation after can output copper content be 0.6~1.0wt% waste.Some factories add at slag ore dressing again in order to further reclaim the valuable metal in waste Science and engineering sequence.The shortcomings that this processing mode, is that technological process is long, occupation area of equipment is big, and equipment investment and operating cost are high. In addition, there is a kind of handling process of more main flow for smelting slag, i.e.,:The smelting slag that smelting furnace output is come directly is subjected to slag Ore dressing is handled, the copper content of obtained slag mine tailing<0.3wt%.However, this method is there is also numerous shortcomings, such as:Slag slow cooling Time is grown, and steamed stuffed bun quantity is more, and slag beneficiating process technological process length, floor space is big, and investment is big, and operating cost is high.
Based on above reason, it is necessary to new technique and equipment are further researched and developed, overcomes the shortcomings of process above, Shorten production procedure, reduce production cost, cost of investment, realize efficiently production.
The content of the invention
It is a primary object of the present invention to provide a kind of copper smelting apparatus, with solve in the prior art after copper weld pool for The problem of processing technological flow of smelting slag is long, occupation area of equipment is big, cost is high.
To achieve these goals, according to an aspect of the invention, there is provided a kind of copper smelting apparatus, it is provided with interior Chamber, inner chamber include:Smelting zone, smelting zone to copper concentrate carrying out melting to generate the first copper matte regulus and smelting slag;Stripping section, it is poor Change area to separate by the first partition wall with smelting zone, connected between stripping section and smelting zone by smelting slag passage, and stripping section is used Handled in carrying out dilution to smelting slag to generate the second copper matte regulus and poor slugging;And decanting zone, decanting zone and stripping section pass through the Two partition walls separate, and decanting zone is located at the side of the remote smelting zone of stripping section, passes through poor slugging between decanting zone and stripping section Passage connects, and decanting zone is used to carry out sedimentation separation to the second copper matte regulus and poor slugging.
Further, in inner chamber, smelting zone and stripping section are separately positioned on the both sides of the first partition wall, sedimentation in the horizontal direction Area and stripping section are separately positioned on the both sides of the second partition wall in the horizontal direction.
Further, the bottom wall below the second partition wall of inner chamber is inclined plane, and along stripping section to away from stripping section Direction, inclined plane is inclined upwardly.
Further, ledge structure is formed between the bottom wall of smelting zone and the bottom wall of stripping section, and the depth of smelting zone is big In the depth of stripping section;The bottom of smelting zone is provided with copper matte regulus outlet.
Further, it is additionally provided with bulge-structure on the bottom wall below the first partition wall of inner chamber, bulge-structure and the Smelting slag passage is formed between one partition wall;The bottom of smelting zone is provided with the outlet of the first copper matte regulus, and the bottom of stripping section is provided with Second copper matte regulus exports;Or the bottom of smelting zone is provided with copper matte regulus outlet.
Further, the first partition wall, the second partition wall have interval, copper weld pool dress between the roof of copper smelting apparatus respectively The top put is additionally provided with exhanst gas outlet.
Further, smelting zone is provided with the first charge door and the first blast orifice, and smelting zone is additionally provided with the first spray gun, the Bottom of the injection direction of one spray gun towards smelting zone.
Further, stripping section is provided with the second charge door and the second blast orifice, and stripping section is additionally provided with the second spray gun, the The injection direction of two spray guns is towards the bottom of stripping section.
Further, decanting zone is additionally provided with heating unit, and heating unit to decanting zone being heated or be incubated.
Further, heating unit is heating electrode and/or burner.
Further, decanting zone is additionally provided with slag-drip opening.
Further, copper smelting apparatus is additionally provided with cooling element.
Apply the technical scheme of the present invention, there is provided a kind of copper smelting apparatus, it is provided with inner chamber, and inner chamber includes melting Area, stripping section and decanting zone, smelting zone to copper concentrate carrying out melting to generate the first copper matte regulus and smelting slag;Stripping section with Smelting zone is separated by the first partition wall, is connected between stripping section and smelting zone by smelting slag passage, and stripping section is used for molten Refining slag carries out dilution processing to generate the second copper matte regulus and poor slugging;Decanting zone is separated with stripping section by the second partition wall, and is settled Area is located at the side of the remote smelting zone of stripping section, is connected between decanting zone and stripping section by poor slugging passage, and decanting zone is used In to the second copper matte regulus and poor slugging progress sedimentation separation.
Above-mentioned copper smelting apparatus is the integration apparatus of a stove multicell, at copper weld pool process and smelting slag dilution, sedimentation Reason process is concentrated in a stove and carried out.In actual application, copper concentrate can carry out melting, output first in smelting zone Copper matte regulus (high-grade copper matte regulus) and smelting slag, smelting slag pass through the first partition wall through stove, and smelting slag passage flow to stripping section.Smelting slag After dilution is handled can the copper matte regulus of output second (low-grade copper matte regulus) and poor slugging, decanting zone is further entered by poor slugging passage Sedimentation separation is carried out, the second copper matte regulus and poor slugging are more fully separated, makes copper content in the slag that finally gives lower, Can be directly as waste.Copper weld pool is carried out using said apparatus provided by the invention, can be directly by melting, dilution and sedimentation separation A stove is concentrated on, is effectively saved technological process, and occupation area of equipment is smaller, equipment investment, operating cost decline to a great extent.
Brief description of the drawings
The Figure of description for forming the part of the application is used for providing a further understanding of the present invention, and of the invention shows Meaning property embodiment and its illustrate be used for explain the present invention, do not form inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 shows copper smelting apparatus schematic diagram according to an embodiment of the present;
Fig. 2 shows the copper smelting apparatus schematic diagram of another embodiment according to the present invention;
Fig. 3 shows the top view of copper smelting apparatus in Fig. 1;And
Fig. 4 shows the diagrammatic cross-section in the A-A directions of copper smelting apparatus in Fig. 1.
Wherein, above-mentioned accompanying drawing marks including the following drawings:
10th, smelting zone;20th, stripping section;30th, decanting zone;11st, the first partition wall;12nd, the second partition wall;13rd, the first spray gun;21、 Second spray gun;31st, heating unit;101st, exhanst gas outlet;102nd, the first charge door;103rd, the first blast orifice;201st, the second charging Mouthful;202nd, the second blast orifice;301st, slag-drip opening;311st, electrode is heated;312nd, burner.
Embodiment
It should be noted that in the case where not conflicting, the feature in embodiment and embodiment in the application can phase Mutually combination.Describe the present invention in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
The application is described in further detail below in conjunction with specific embodiment, these embodiments are it is not intended that limit this Apply for scope claimed.
As described by background section, in the prior art for the processing technological flow of smelting slag after copper weld pool Length, occupation area of equipment is big, cost is high.
In order to solve this problem, the invention provides a kind of copper smelting apparatus, as shown in figure 1, copper smelting apparatus is set There is inner chamber, inner chamber includes smelting zone 10, stripping section 20 and decanting zone 30;Smelting zone 10 to copper concentrate carry out melting with life Into the first copper matte regulus and smelting slag;Stripping section 20 is separated with smelting zone 10 by the first partition wall 11, stripping section 20 and smelting zone 10 it Between connected by smelting slag passage, and stripping section 20 is used to carry out smelting slag dilution processing to generate the second copper matte regulus and dilution Slag;Decanting zone 30 is separated with stripping section 20 by the second partition wall 12, and decanting zone 30 is located at the remote smelting zone 10 of stripping section 20 Side, connected between decanting zone 30 and stripping section 20 by poor slugging passage, decanting zone 30 be used for the second copper matte regulus and dilution Slag carries out sedimentation separation.
Above-mentioned copper smelting apparatus is the integration apparatus of a stove multicell, at copper weld pool process and smelting slag dilution, sedimentation Reason process is concentrated in a stove and carried out.In actual application, copper concentrate can carry out melting, output in smelting zone 10 One copper matte regulus (high-grade copper matte regulus) and smelting slag, smelting slag pass through the first partition wall 11 through stove, and smelting slag passage flow to stripping section 20. Smelting slag after dilution is handled can the copper matte regulus of output second (low-grade copper matte regulus) and poor slugging, further pass through poor slugging passage enter Decanting zone 30 carries out sedimentation separation, and the second copper matte regulus and poor slugging are more fully separated, and makes copper in the slag that finally gives Content is lower, can be directly as waste.
Copper weld pool is carried out using said apparatus provided by the invention, directly can be concentrated on melting, dilution and sedimentation separation One stove, it can realize in the case of output high-grade copper matte regulus while obtain the very low waste of copper content.And use a stove multi zone furnace Body structure type, process is few, and technological process greatly shortens, and floor space is few, reduced investment, cancels slag slow cooling and slag beneficiating process, Reduce material to have bad luck, save a large amount of human and material resources, labour cost is low, improves production efficiency, high financial profit.Therefore, this hair Bright device is ingenious in design, reasonable, energy-saving and environmental protection, green, has good value for applications.
Herein it should be noted that during dilution, the second copper matte regulus and poor slugging are generated, poor slugging can carry part Second copper matte regulus enters sedimentation separation from poor slugging passage.So-called sedimentation separation is actually the part by poor slugging and its carrying Second copper matte regulus carries out sedimentation separation.In addition, in actual application, copper concentrate is carried out to the process of melting in smelting zone 10 In, some Gold Concentrate under Normal Pressure can also be added, during copper weld pool by gold and silver melting into the first copper matte regulus, follow-up need to be by ability The usual electrolysis mode in domain separates gold and silver with copper.Gold Concentrate under Normal Pressure is added from smelting zone rather than added from stripping section, so The gold and silver loss taken away from decanting zone waste can be reduced, improves the rate of recovery of gold and silver.
In a preferred embodiment, in above-mentioned inner chamber, smelting zone 10 and stripping section 20 are set respectively in the horizontal direction Put in the both sides of the first partition wall 11, decanting zone 30 and stripping section 20 are separately positioned on the both sides of the second partition wall 12 in the horizontal direction. So, smelting zone 10, stripping section 20, the chamber of decanting zone 30 3 are horizontal arrangement, with continuous charging melting, are produced after smelting Raw smelting slag directly can be from flowing into stripping section 20, and poor slugging caused by dilution processing can also be from inflow decanting zone 30 Complete the separation of copper matte regulus and slag.
In a preferred embodiment, the bottom wall positioned at the lower section of the second partition wall 12 of inner chamber is inclined plane, and along poor Change area 20 to the direction away from stripping section 20, inclined plane to be inclined upwardly.In this way, poor slugging and the second copper matte regulus are in decanting zone 30 After middle completion sedimentation separation, the second copper matte regulus conveniently can be concentrated the second copper matte regulus along inclined plane from flowing back in stripping section 20 Discharge.
First copper matte regulus of the above-mentioned output of smelting zone 10 is high-grade copper matte regulus, and the second copper matte regulus of the output of stripping section 20 is low-grade Copper matte regulus, the two can be discharged respectively, can also concentrate discharge.Specifically:
As shown in figure 1, in a preferred embodiment, shape between the bottom wall of smelting zone 10 and the bottom wall of stripping section 20 Into ledge structure, and the depth of smelting zone 10 is more than the depth of stripping section 20;The bottom of smelting zone 10 is provided with copper matte regulus outlet.This Sample, the second copper matte regulus can mix by ledge structure from flowing into smelting zone 10 equivalent to by high-grade copper matte regulus and low-grade copper matte regulus Concentrated after conjunction from the copper matte regulus of the bottom of smelting zone 10 and export perforating or siphon discharge.
Preferably, in said apparatus, the height of ledge structure is 500~1200mm, so in continuous running, The thickness of first copper matte regulus layer of the bottom of smelting zone 10 can reach 500~1200mm, and the second of stripping section 20 and the bottom of decanting zone 30 The very thin thickness of copper matte regulus layer, is 0~300mm, 100~1200mm of thickness of slag layer in region.Made using the gravity flow of the second copper matte regulus With reaching the purpose of the stable discharging of copper matte regulus.
As shown in Fig. 2 in another preferred embodiment, inner chamber is gone back on the bottom wall of the lower section of the first partition wall 11 Bulge-structure is provided with, smelting slag passage is formed between bulge-structure and the first partition wall 11;The bottom of smelting zone 10 is provided with One copper matte regulus exports, and the bottom of stripping section 20 is provided with the outlet of the second copper matte regulus.So, can be respectively by the first copper matte regulus and the second bronze medal Sulfonium is discharged from copper smelting apparatus.It is convex or being located on the bottom wall of the lower section of the first partition wall 11 for inner chamber is additionally provided with bulge-structure Rise and smelting slag passage is formed between structure and the first partition wall 11;The bottom of smelting zone 10 is provided with copper matte regulus outlet.So, with dressing The continuous production put, the second copper matte regulus is cumulative in the bottom of stripping section 20, may finally enter across raised overflow in smelting zone 10, Concentrated after being mixed with the first copper matte regulus from the copper matte regulus of the bottom of smelting zone 10 and export discharge.
The outlet of first copper matte regulus and the outlet of the second copper matte regulus are set at the same time, the first copper matte regulus and the second copper matte regulus are discharged respectively In mode, the depth of smelting zone 10 and stripping section 20 is deeper than the depth of decanting zone 30.Preferably, the bottom of decanting zone 30 with it is poor 500~900mm steps are formed on the bottom for changing area 20, and the second copper matte regulus layer of decanting zone 30 is relatively thin, 0~300mm of copper matte regulus thickness.This portion The gravity flow of the second copper matte regulus is divided to export stable discharge as the second copper matte regulus after stripping section 20, can be passed through.In addition, the height of bulge-structure is 500~1200mm, so in continuous running, the thickness of the first copper matte regulus layer of the bottom of smelting zone 10 can reach 500~ 1200mm, the first copper matte regulus can export stable discharge by the first copper matte regulus.100~1200mm of thickness of slag layer in each region.
In a preferred embodiment, as shown in Figure 1, Figure 2 and Figure 3, the first partition wall 11, the second partition wall 12 respectively with There is interval between the roof of copper smelting apparatus, exhanst gas outlet 101 is additionally provided with the top of copper smelting apparatus.So, in reality In production process, flue gas caused by each chamber can be pooled together by the interval, then be discharged by exhanst gas outlet 101. It is highly preferred that said apparatus also includes fume treatment unit, to carry out purified treatment to flue gas.The process is except can be by cigarette Gas carries out harmless discharge, can also reclaim some volatilization points in flue gas than relatively low heavy metal such as metallic zinc, metallic antimony etc. Return.
In a preferred embodiment, smelting zone 10 is provided with the first charge door 102 and the first blast orifice 103, melts Refining area 10 is additionally provided with the first spray gun 13, the bottom of the injection direction of the first spray gun 13 towards smelting zone 10.Pass through the first charging The 102, first blast orifice 103 of mouth and the first spray gun 13 can add melting raw material into smelting zone 10, and specific each raw material adds Entering form can be selected according to its form and character.For example oxygen-enriched air needed for melting can pass through the first blast orifice 103 And/or first spray gun 13 add, copper concentrate, optional Gold Concentrate under Normal Pressure, flux, returning charge etc. can be added by the first charge door 102. This is that those skilled in the art can carry out selection, be will not be repeated here.Preferably, the first blast orifice 103 is located at smelting zone 10 sidepiece, this is equivalent to side-blown smelting zone;The injection direction of first spray gun 13 towards smelting zone 10 bottom, equivalent to top blast Smelting zone.Side-blown and top blow smelting can also be combined during actual production.First spray gun 13 can be immersion spray gun, also may be used To be non-immersion spray gun.
In a preferred embodiment, stripping section 20 is provided with the second charge door 201 and the second blast orifice 202, poor Change area 20 and be additionally provided with the second spray gun 21, the injection direction of the second spray gun 21 is towards the bottom of stripping section 20.Similarly, second is passed through Charge door 201, the second blast orifice 202 and the second spray gun 21 can add original required during dilution processing into stripping section 20 Material, such as, powdery reducing agent, alternatively oxygen-enriched air can be added by the second blast orifice 202 and the second spray gun 21.It is logical Block reducing agent and optional copper concentrate can be added by crossing the second charge door 201.Second spray gun 21 can be immersion spray gun, It can be non-immersion spray gun.
In decanting zone 30, poor slugging and the second copper matte regulus carry out the separation of slag, sulfonium by standing sedimentation, in order to ensure the second bronze medal The mobility of sulfonium and slag, the effect of slag sulfonium separation is improved, in a preferred embodiment, decanting zone 30 is additionally provided with heating Unit 31, heating unit 31 is being heated or be incubated to decanting zone 30.Specific heating unit 31 includes but is not limited to add Thermode 311 and/or burner 312, electrode insert melt heating in slag blanket.
Preferably, as illustrated in fig. 1 and 2, decanting zone 30 is additionally provided with slag-drip opening 301.Decanting zone 30 can so be separated Waste discharge out.
Preferably, as shown in figure 4, the bottom wall of smelting zone 10 can be curved-surface structure, and curved-surface structure is towards smelting zone 10 Inside bending, this aspect is advantageous to the stability of device, on the one hand also collected using copper matte regulus.Similarly, the bottom of stripping section 20 Wall is also curved-surface structure, and curved-surface structure is bent towards the inside of stripping section 20.
In a preferred embodiment, copper smelting apparatus is additionally provided with cooling element.Can be more using cooling element The life-span of furnace lining and body of heater is protected well, so that can be in high oxygen-enriched air and higher temperatures during fusion process and dilution Under the conditions of carry out, improve smelting efficiency and matte grade.Preferably, cooling element can be cooling jacket, can be arranged on copper In the side wall of smelting apparatus, on the first partition wall 11 and the second partition wall 12.Such as the side wall of copper smelting apparatus, the first partition wall 11 and Second partition wall 12 uses Copper Water Jacket form.
Preferably, the body of heater of copper smelting apparatus is steel construction, and refractory material is provided with the wall of inner chamber.
According to another aspect of the present invention, additionally provide a kind of copper weld pool method, copper weld pool method in copper smelting apparatus (such as Shown in Fig. 1) in carry out, copper smelting apparatus is provided with inner chamber, and inner chamber includes smelting zone 10, stripping section 20 and decanting zone 30;Dilution Area 20 is separated with smelting zone 10 by the first partition wall 11, and is connected between stripping section 20 and smelting zone 10 by smelting slag passage; Decanting zone 30 is separated with stripping section 20 by the second partition wall 12, and decanting zone 30 is located at the one of the remote smelting zone 10 of stripping section 20 Side, and connected between decanting zone 30 and stripping section 20 by poor slugging passage;
Copper weld pool method comprises the following steps:Copper concentrate is subjected to melting in smelting zone 10, the first copper matte regulus is obtained and melts Refine slag;Smelting slag is subjected to dilution processing in stripping section 20, obtains the second copper matte regulus and poor slugging;And by the second copper matte regulus and poor Slugging carries out sedimentation separation in decanting zone 30.
Each section length, each area's charge door quantity, copper matte regulus export volume, slag-drip opening quantity, outlet flue number in copper smelting apparatus Amount, blast orifice and spray gun diameter and quantity can will not be repeated here depending on concentrate treatment scale.
Above-mentioned copper weld pool method provided by the invention, the copper smelting apparatus used, will for the integration apparatus of a stove multicell Copper weld pool process and smelting slag dilution, settlement treatment process are concentrated in a stove and carried out.In actual application, copper concentrate exists Melting, the copper matte regulus of output first (high-grade copper matte regulus) and smelting slag are carried out in smelting zone 10, smelting slag passes through the first partition wall 11, through molten Refining slag passage flow to stripping section 20.Smelting slag after dilution is handled can the copper matte regulus of output second (low-grade copper matte regulus) and poor slugging, enter One step enters decanting zone 30 by poor slugging passage and carries out sedimentation separation, and the second copper matte regulus and poor slugging are more fully separated Come, make copper content in the slag that finally gives lower, can be directly as waste.The above method is directly by copper weld pool, dilution and sedimentation Separation concentrates on a stove, realizes in the case of output high-grade copper matte regulus while obtains the very low waste of copper content.And use One stove multi-region body of heater structure type, process is few, and technological process greatly shortens, and floor space is few, reduced investment, cancels slag slow cooling and slag Beneficiating process, reduce material and have bad luck, save a large amount of human and material resources, labour cost is low, improves production efficiency, high financial profit. Therefore, device of the invention is ingenious in design, reasonable, energy-saving and environmental protection, green, has good value for applications.
In a preferred embodiment, in above-mentioned inner chamber, smelting zone 10 and stripping section 20 are set respectively in the horizontal direction Put in the both sides of the first partition wall 11, decanting zone 30 and stripping section 20 are separately positioned on the both sides of the second partition wall 12 in the horizontal direction. So, smelting zone 10, stripping section 20, the chamber of decanting zone 30 3 are horizontal arrangement, with continuous charging melting, are produced after smelting Raw smelting slag directly can be from flowing into stripping section 20, and poor slugging caused by dilution processing can also be from inflow decanting zone 30 Complete the separation of slag sulfonium.
In a preferred embodiment, the bottom wall positioned at the lower section of the second partition wall 12 of inner chamber is inclined plane, and edge is leaned on Nearly stripping section 20 to the direction away from stripping section 20, inclined plane is inclined upwardly;The second copper matte regulus is separated in the step of sedimentation separation Out, and the second copper matte regulus flows into stripping section 20 certainly along inclined plane.So, poor slugging and the second copper matte regulus complete slag in decanting zone 30 After sulfonium separation, the second copper matte regulus is conveniently carried out concentration discharge by the second copper matte regulus along inclined plane from flowing back in stripping section 20.
In the above method, the first copper matte regulus of the output of smelting zone 10 is high-grade copper matte regulus, the second copper matte regulus of the output of stripping section 20 For low-grade copper matte regulus, the two can be discharged respectively, discharge can also be concentrated.Specifically:
As shown in figure 1, in a preferred embodiment, shape between the bottom wall of smelting zone 10 and the bottom wall of stripping section 20 Depth into ledge structure, and smelting zone 10 is deeper than the depth of stripping section 20;The bottom of smelting zone 10 is provided with copper matte regulus outlet; During second copper matte regulus flows into stripping section 20 certainly, the second copper matte regulus flows into smelting zone 10, copper weld pool method certainly by ledge structure Also include the mixture of the second copper matte regulus and the first copper matte regulus exporting the step of discharging from copper matte regulus.During being somebody's turn to do, high-grade first Copper matte regulus and low-grade second copper matte regulus concentrate discharge after mixing.
Herein it should be noted that above-mentioned ledge structure refer to smelting zone 10 bottom wall and stripping section 20 bottom wall on the whole Ledge structure is presented, the height of the bottom wall of smelting zone 10 is highly lower than the bottom wall of stripping section 20, namely the depth of smelting zone 10 It is deeper than the depth of stripping section 20.The bottom wall of stripping section 20 can be plane, itself can also have deeper region and shallower Region.
As shown in Fig. 2 in another preferred embodiment, inner chamber is gone back on the bottom wall of the lower section of the first partition wall 11 Bulge-structure is provided with, smelting slag passage is formed between bulge-structure and the first partition wall 11;The bottom of smelting zone 10 is provided with One copper matte regulus exports, and the bottom of stripping section 20 is provided with the outlet of the second copper matte regulus;Copper weld pool method is included the first copper matte regulus from first Copper matte regulus outlet discharge, and the second copper matte regulus is exported into the step of discharging from the second copper matte regulus.So, high-grade first copper matte regulus and low product Second copper matte regulus of position is discharged from different regions respectively.Or being located on the bottom wall of the lower section of the first partition wall 11 for inner chamber also sets up There is bulge-structure, smelting slag passage is formed between bulge-structure and the first partition wall 11;The bottom of smelting zone 10 is provided with the first bronze medal Sulfonium exports, and the bottom of stripping section 20 is provided with the outlet of the second copper matte regulus;The bottom of smelting zone 10 is provided with copper matte regulus outlet;Second bronze medal Sulfonium is overflowed into smelting zone 10 by bulge-structure;Copper weld pool method is included the mixture of the first copper matte regulus and the second copper matte regulus from copper matte regulus The step of outlet discharge.Which is also by high-grade first copper matte regulus and low-grade second copper matte regulus row of concentration after mixing Go out.
In a preferred embodiment, the first partition wall 11, the second partition wall 12 respectively with the roof of copper smelting apparatus it Between there is interval, be additionally provided with exhanst gas outlet 101 at the top of copper smelting apparatus;Cigarette is produced during fusion process and dilution Gas, copper weld pool method also include by flue gas from exhanst gas outlet 101 discharge the step of.It is highly preferred that the above method also includes to cigarette Gas carries out the step of purified treatment.The process can also wave except that flue gas can be carried out into harmless discharge by some in flue gas Hair point is returned than such as recovery such as metallic zinc, metallic antimony of relatively low heavy metal.
In a preferred embodiment, fusion process includes:By all or part of copper concentrate, optional aurin Ore deposit, flux carry out melting under conditions of the first oxygen-enriched air, obtain the first copper matte regulus and smelting slag.During being somebody's turn to do, it can add Gold Concentrate under Normal Pressure, it can also be added without.The purpose for adding Gold Concentrate under Normal Pressure is to melt out Jin Hetong in the lump to come, and gold can be present in the first copper matte regulus In, the two can subsequently be separated by the existing electrolysis process in this area.Preferably, during melting, while to molten Returning charge is added in refining area 10, returning charge includes black copper that blowing slag, refining slag, flue dust, the cold burden of copper matte regulus chute and electrolysis return etc.. This aspect can further reclaim the copper in these returning charges, on the other hand can also maintain the thermal balance of fusion process, prevent Only superheating phenomenon, so as to improve Smelting Effect.
Preferably, the oxygen concentration in the first oxygen-enriched air is 70~95vol%, and pressure is 0.1~0.3MPa.This is oxygen-enriched Under the conditions of, the first copper matte regulus has higher grade.It is highly preferred that the matte grade of the first copper matte regulus is 65~78wt%.
Preferably, part or complete is added into smelting zone 10 by being arranged on first charge door 102 at the top of smelting zone 10 The copper concentrate in portion, optional Gold Concentrate under Normal Pressure, flux, optional returning charge;It is highly preferred that by being arranged on the first of the sidepiece of smelting zone 10 Blast orifice 103 blasts oxygen-enriched air to smelting zone 10, and/or by being arranged on the injection direction of smelting zone 10 straight down One spray gun 13 sprays into oxygen-enriched air.Can so side-blown melting and/or top blow smelting be carried out to copper concentrate.Specific flux type Type commonly used in the art, such as quartz, lime stone etc. can be used.
In a preferred embodiment, the process of dilution processing includes:By smelting slag and reducing agent in stripping section 20 Middle progress dilution processing, obtains the second copper matte regulus and poor slugging.The Armco magnetic iron in smelting slag can be reduced using reducing agent, with drop The viscosity of low smelting slag, its mobility is improved, so as to improve follow-up sedimentation separation effect.
Preferably, when adding part copper concentrate in fusion process, in the step of dilution is handled, while to stripping section 20 plus Enter remaining copper concentrate and the second oxygen-enriched air.So, remaining copper concentrate is added in stripping section 20, can be oxygen-enriched second Low-grade copper matte regulus is generated in the presence of air, further to reduce the copper content in poor slugging.
Preferably, the concentration of oxygen is 60~95vol% in the second oxygen-enriched air, and pressure is 0.1~0.3MPa.This is oxygen-enriched Under the conditions of can make stable low-grade copper matte regulus.It is highly preferred that the matte grade of the second copper matte regulus is 30~50wt%.By the second bronze medal After sulfonium mixes from inflow smelting zone 10 with the first copper matte regulus, 60~70% can be reached by mixing the grade of copper matte regulus.
Preferably, remaining copper concentrate is added by being arranged on second charge door 201 at the top of stripping section 20;Pass through second Charge door 201, and/or it is arranged on the injection direction of stripping section 20 the second spray gun 21 straight down, and/or is arranged on stripping section Second blast orifice 202 of 20 sidepieces adds reducing agent;It is oxygen-enriched that second is blasted by the second spray gun 21 and/or the second blast orifice 202 Air.Specific feed way can add according to the form of raw material, such as, for powdered or gaseous reducing agent, such as coal Powder, natural gas etc., it can be added by the second spray gun 21 and/or the second blast orifice 202.For bulk reducing agent such as lump coal, Char particle etc., then it can be added by the second charge door 201.And when adding powdery reducing agent, compressed air, nitrogen can also be utilized Gas, oxygen-enriched air and natural gas etc. are used as carrier gas, are blasted stripping section 20.
In a preferred embodiment, during above-mentioned settlement treatment, using heating unit 31 to decanting zone 30 Heated or be incubated.This may further ensure that the mobility of the second copper matte regulus, improve the effect of slag sulfonium separation.Preferably, add Hot cell 31 includes but is not limited to heat electrode 311 and/or burner 312.
In a preferred embodiment, the process of settlement treatment also include will the poor slugging that separate from slag-drip opening The step of 301 discharge.By above-mentioned melting, dilution and sedimentation separation, the copper content in the waste finally excluded is very low.It is preferred that Ground, the copper content of poor slugging are 0.25~0.5wt%, and Fe and SiO in poor slugging2Weight ratio be 1.0~2.2:1.So Poor slugging slag type it is more stable, can be easier to separate with the second copper matte regulus.It is preferred that Fe and SiO in poor slugging2Weight ratio be 1.1 ~2.2:1.
In a preferred embodiment, copper smelting apparatus is additionally provided with cooling element.Can be more using cooling element Furnace lining and stove longevity are protected well, so that can enter during fusion process and dilution under conditions of high oxygen-enriched air and high temperature OK, smelting efficiency and matte grade are improved.Preferably, cooling element can be cooling jacket, can be arranged on copper smelting apparatus Side wall on, on the first partition wall 11 and the second partition wall 12.Such as side wall, the first partition wall 11 and the second partition wall of copper smelting apparatus 12 use Copper Water Jacket form.
Beneficial effects of the present invention are further illustrated by the following examples:
Embodiment 1
Copper smelting apparatus is as shown in figure 1, wherein:Smelting zone bottom forms 1200mm steps, smelting zone molten bath with stripping section Deeply, the second copper matte regulus thickness degree of the first copper matte regulus thickness 1200mm, stripping section and decanting zone is 300mm, and each area's thickness of slag layer is 1200mm。
Metallurgical process is as follows:
In smelting zone upper of furnace body charge door add Gold Concentrate under Normal Pressure, most copper concentrate, flux quartz, returning charge (blowing slag, Refining slag, flue dust, copper matte regulus chute cold burden and electrolysis return black copper), lump coal, be passed through by the blast orifice of smelting zone sidepiece first Oxygen-enriched air, its oxygen content are 85vol%, pressure 0.15MPa, high-grade first copper matte regulus of output, grade 78wt%;
Smelting slag flows into stripping section below the first partition wall and carries out dilution processing, during which from the charging positioned at stripping section top Reducing agent lump coal and coke powder are added in mouthful, while adds small part copper concentrate, by the second blast orifice of stripping section sidepiece to slag Oxygen-enriched air, oxygen-enriched air concentration 70vol% are passed through in layer, pressure is that 0.15MPa makes low-grade second copper matte regulus, grade 40wt%;
Poor slugging flows into decanting zone below the second partition wall and carries out sedimentation separation, and heated by electrodes is used during being somebody's turn to do, and poor Change the second copper matte regulus of area and decanting zone to mix with the first copper matte regulus from flowing into smelting zone, it is several from being arranged on smelting zone bottom Copper matte regulus outlet discharge, the grade for mixing copper matte regulus is 65wt%.The waste that decanting zone is isolated continuously or discontinuously is discharged from slag-drip opening, Its copper content is 0.35wt%, Fe/SiO in slag2=1.2.
During copper weld pool, caused flue gas is pooled together by the interval between partition wall and roof in each area, from cigarette Gas outlet discharge, is handled to gas cleaning unit.
Embodiment 2
Copper smelting apparatus is as shown in Fig. 2 wherein:Smelting zone bottom forms 500mm projections, smelting zone and dilution with stripping section The depth in area is deeper than decanting zone, and stripping section is than decanting zone depth 500mm.First copper matte regulus thickness 500mm, the second bronze medal in stripping section The thickness 500mm of matte layer, the second copper matte regulus thickness degree of decanting zone is 20mm, and each area's thickness of slag layer is 600mm.
Technique during copper weld pool is same as Example 1, and difference is:
First copper matte regulus is exported into discharge from the first copper matte regulus for being arranged on smelting zone, by the second copper matte regulus from being arranged on stripping section side The second copper matte regulus outlet discharge in portion.
Embodiment 3
Copper smelting apparatus is as shown in Fig. 2 thickness parameter equivalent integers 2.
Technique during copper weld pool is same as Example 1, and difference is:
Second copper matte regulus is flowed into smelting zone after overflowing from bulge-structure, after being mixed with the first copper matte regulus, by being arranged on melting The copper matte regulus outlet discharge of area bottom.
Embodiment 4
Copper smelting apparatus is as shown in Fig. 2 wherein:It is raised that smelting zone bottom and stripping section form 1000mm, smelting zone and poor It is deeper than decanting zone to change the depth in area, and stripping section is than decanting zone depth 1000mm.First copper matte regulus thickness 1000mm, in stripping section The thickness 1000mm of two copper matte regulus layers, the second copper matte regulus thickness degree of decanting zone is 100mm, and each area's thickness of slag layer is 500mm.Copper weld pool During technique it is as follows:
In smelting zone upper of furnace body charge door add Gold Concentrate under Normal Pressure, most copper concentrate, flux quartz, returning charge (blowing slag, Refining slag, flue dust, copper matte regulus chute cold burden and electrolysis return black copper), lump coal, pass through smelting zone at the top of set immersion spray Rifle is passed through oxygen-enriched air, and its oxygen content is 70vol%, pressure 0.15MPa, high-grade first copper matte regulus of output, grade 75wt%;
Smelting slag flows into stripping section below the first partition wall and carries out dilution processing, during which from the charging positioned at stripping section top Reducing agent lump coal and coke powder are added in mouthful, while adds small part copper concentrate, by the immersion spray gun at the top of stripping section to slag Oxygen-enriched air, oxygen-enriched air concentration 60vol% are passed through in layer, pressure is that 0.15MPa makes low-grade second copper matte regulus, grade 35wt%;
Poor slugging flows into decanting zone below the second partition wall and carries out sedimentation separation, and heated by electrodes is used during being somebody's turn to do, and poor Change the second copper matte regulus of area and decanting zone to mix with the first copper matte regulus from flowing into smelting zone, concentrate from being arranged on smelting zone bottom Copper matte regulus outlet discharge, the grade for mixing copper matte regulus is 60wt%.The waste that decanting zone is isolated continuously or discontinuously is discharged from slag-drip opening, Its copper content is 0.3wt%, Fe/SiO in slag2=1.8.
During copper weld pool, caused flue gas is pooled together by the interval between partition wall and roof in each area, from cigarette Gas outlet discharge, is handled to gas cleaning unit.
As can be seen from the above description, the above embodiments of the present invention realize following technique effect:
Copper weld pool is carried out using said apparatus provided by the invention, directly can be concentrated on melting, dilution and sedimentation separation One stove, it can realize in the case of output high-grade copper matte regulus while obtain the very low waste of copper content.And use a stove multi zone furnace Body structure type, process is few, and technological process greatly shortens, and floor space is few, reduced investment, cancels slag slow cooling and slag beneficiating process, Reduce material to have bad luck, save a large amount of human and material resources, labour cost is low, improves production efficiency, high financial profit.Therefore, this hair Bright device is ingenious in design, reasonable, energy-saving and environmental protection, green, has good value for applications.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies Change, equivalent substitution, improvement etc., should be included in the scope of the protection.

Claims (12)

1. a kind of copper smelting apparatus, it is characterised in that the copper smelting apparatus is provided with inner chamber, and the inner chamber includes:
Smelting zone (10), the smelting zone (10) to copper concentrate carrying out melting to generate the first copper matte regulus and smelting slag;
Stripping section (20), the stripping section (20) are separated with the smelting zone (10) by the first partition wall (11), the stripping section (20) connected between the smelting zone (10) by smelting slag passage, and the stripping section (20) is used to enter the smelting slag Row dilution is handled to generate the second copper matte regulus and poor slugging;And
Decanting zone (30), the decanting zone (30) is separated with the stripping section (20) by the second partition wall (12), and the sedimentation Area (30) is located at the side of the remote smelting zone (10) of the stripping section (20), the decanting zone (30) and the stripping section (20) connected between by poor slugging passage, the decanting zone (30) is used to sink to second copper matte regulus and the poor slugging Drop separation.
2. copper smelting apparatus according to claim 1, it is characterised in that in the inner chamber, the smelting zone (10) and institute State the both sides that stripping section (20) is separately positioned on first partition wall (11) in the horizontal direction, the decanting zone (30) and described poor Change the both sides that area (20) are separately positioned on second partition wall (12) in the horizontal direction.
3. copper smelting apparatus according to claim 2, it is characterised in that the inner chamber is located at second partition wall (12) The bottom wall of lower section is inclined plane, and along the stripping section (20) to away from the stripping section (20) direction, it is described tilt towards Upper inclination.
4. copper smelting apparatus according to claim 3, it is characterised in that the bottom wall of the smelting zone (10) and the dilution Ledge structure is formed between the bottom wall in area (20), and the depth of the smelting zone (10) is more than the depth of the stripping section (20); The bottom of the smelting zone (10) is provided with copper matte regulus outlet.
5. copper smelting apparatus according to claim 3, it is characterised in that the inner chamber is located at first partition wall (11) Bulge-structure is additionally provided with the bottom wall of lower section, the smelting slag is formed between the bulge-structure and first partition wall (11) Passage;
The bottom of the smelting zone (10) is provided with the outlet of the first copper matte regulus, and the bottom of the stripping section (20) is provided with the second bronze medal Sulfonium exports;Or
The bottom of the smelting zone (10) is provided with copper matte regulus outlet.
6. the copper smelting apparatus according to any one of claim 2 to 5, it is characterised in that first partition wall (11), institute State the second partition wall (12) has interval between the roof of the copper smelting apparatus respectively, and the top of the copper smelting apparatus is also set It is equipped with exhanst gas outlet (101).
7. copper smelting apparatus according to any one of claim 1 to 5, it is characterised in that the smelting zone (10) is set There are the first charge door (102) and the first blast orifice (103), the smelting zone (10) is additionally provided with the first spray gun (13), and described Bottom of the injection direction of one spray gun (13) towards the smelting zone (10).
8. copper smelting apparatus according to any one of claim 1 to 5, it is characterised in that the stripping section (20) is set There are the second charge door (201) and the second blast orifice (202), the stripping section (20) is additionally provided with the second spray gun (21), and described Bottom of the injection direction of two spray guns (21) towards the stripping section (20).
9. copper smelting apparatus according to any one of claim 1 to 5, it is characterised in that the decanting zone (30) also sets It is equipped with heating unit (31), the heating unit (31) is being heated or be incubated to the decanting zone (30).
10. copper smelting apparatus according to claim 9, it is characterised in that the heating unit (31) is heating electrode And/or burner (312) (311).
11. copper smelting apparatus according to claim 9, it is characterised in that the decanting zone (30) is additionally provided with slag-drip opening (301)。
12. copper smelting apparatus according to any one of claim 1 to 5, it is characterised in that the copper smelting apparatus is also set It is equipped with cooling element.
CN201710842877.9A 2017-09-18 2017-09-18 Copper smelting apparatus Pending CN107488791A (en)

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CN111101001A (en) * 2020-01-16 2020-05-05 中国恩菲工程技术有限公司 One-step nickel smelting system and one-step nickel smelting method
CN111424191A (en) * 2020-05-07 2020-07-17 广州湘龙高新材料科技股份有限公司 Zinc alloy and preparation method thereof
CN111471876A (en) * 2020-05-07 2020-07-31 广州湘龙高新材料科技股份有限公司 Preparation method of zinc alloy
CN111850314A (en) * 2020-07-30 2020-10-30 中国恩菲工程技术有限公司 Oxygen-blown smelting process and system for electric furnace
CN111926133A (en) * 2020-10-10 2020-11-13 中国恩菲工程技术有限公司 Method and apparatus for smelting iron-based mineral
CN112981134A (en) * 2021-04-22 2021-06-18 中国恩菲工程技术有限公司 Continuous copper smelting process and continuous copper smelting system
WO2022227180A1 (en) * 2021-04-28 2022-11-03 东北大学 Copper smelting-thermal state vortex depletion integrated method
CN116426767A (en) * 2023-03-14 2023-07-14 盛屯能源金属化学(贵州)有限公司 Reinforced depletion technology and reinforced depletion furnace for nonferrous metal smelting slag

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CN108913914A (en) * 2018-09-21 2018-11-30 中国恩菲工程技术有限公司 Copper smelting apparatus
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CN111424191A (en) * 2020-05-07 2020-07-17 广州湘龙高新材料科技股份有限公司 Zinc alloy and preparation method thereof
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CN112981134A (en) * 2021-04-22 2021-06-18 中国恩菲工程技术有限公司 Continuous copper smelting process and continuous copper smelting system
WO2022227180A1 (en) * 2021-04-28 2022-11-03 东北大学 Copper smelting-thermal state vortex depletion integrated method
CN116426767A (en) * 2023-03-14 2023-07-14 盛屯能源金属化学(贵州)有限公司 Reinforced depletion technology and reinforced depletion furnace for nonferrous metal smelting slag

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Application publication date: 20171219