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CN107475587A - A kind of magnesium lithium alloy and its processing technology containing beryllium and single-phase β - Google Patents

A kind of magnesium lithium alloy and its processing technology containing beryllium and single-phase β Download PDF

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Publication number
CN107475587A
CN107475587A CN201710822197.0A CN201710822197A CN107475587A CN 107475587 A CN107475587 A CN 107475587A CN 201710822197 A CN201710822197 A CN 201710822197A CN 107475587 A CN107475587 A CN 107475587A
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China
Prior art keywords
alloy
lithium alloy
magnesium lithium
magnesium
degree
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CN201710822197.0A
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Inventor
杨长江
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Guangzhou Xianzhi Technology Co Ltd
Guangzhou Yuzhi Technology Co Ltd
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Guangzhou Xianzhi Technology Co Ltd
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Priority to CN201710822197.0A priority Critical patent/CN107475587A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/02Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/06Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of magnesium or alloys based thereon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Conductive Materials (AREA)

Abstract

The invention discloses a kind of magnesium lithium alloy and its processing technology containing beryllium and single-phase β, by weight percentage, the composition of alloy is:Li:12.0 19.0wt.%, Be:0.1‑0.3wt.%,Ni:0.2‑0.4wt.%,Cu:1.0‑3.0wt.%,Ge:0.2‑0.4wt.%,Hf:0.1‑0.2wt.%,Sb:0.2‑0.4wt.%,Al:0.6 0.8wt.%, surplus are magnesium.By preferred multicomponent microalloying element formula and subsequent further optimization smelting technology and heat treatment parameter, the perfect matching of magnesium lithium alloy high temperature phase and hardening constituent is realized, finally obtains a kind of multicomponent microalloying novel high-strength heat resistant magnesium Zinc-lithium alloy material.The performance of the magnesium lithium alloy at room temperature:Yield strength is 118 142MPa, and tensile strength is 175 194MPa, and elongation percentage is 7 16%.At 100 degree, the performance of the magnesium lithium alloy:Yield strength is 115 136MPa, and tensile strength is 160 174MPa, and elongation percentage is 17 20%.The alloy smelting processing method is simple, and production cost is easy to industrialize large-scale application than relatively low.

Description

A kind of magnesium lithium alloy and its processing technology containing beryllium and single-phase β
Technical field
The present invention relates to technical field of alloy, specifically, is related to a kind of magnesium lithium alloy.
Background technology
The density of lithium only has 0.53g/cm3, add it the magnesium lithium alloy formed in magnesium.Magnesium lithium alloy density about 1.3- 1.6g/cm3, it is current density minimum, specific strength highest constructional alloy.Different with tissue according to lithium content, magnesium lithium alloy can It is divided into three classes:Amount containing lithium is less than 5.5wt.% alloy, and it is organized as the solid solution (α phases) that lithium is dissolved in hcp magnesium;Amount containing lithium is big In 10.2wt.% alloy, it is organized as uniform bcc solid solution (β phases).When lithium content is between 5. 5wt.% and l0. 2wt.% When middle, alloy is organized for two-phase a+ β.
Magnesium lithium alloy is light, specific stiffness is high, conductive and heat-conductive, can be used as casing for electric appliances and instrument board, effective loss of weight;Excellent Capability of electromagnetic shielding and ultralight high strength characteristics, it is the ideal material as guidance component and control cabinet housing;Ultralight high-strength spy Property makes the optimal material of empennage loss of weight.In addition, magnesium lithium alloy can also be used to manufacture missile tail and control cabinet housing, electricity Device circuit substrate, the shell of electric-controlled equipment, gyroscope, armour material, weapon direction equipment, the small arms carried during individual combat And equipment, and stretcher, cartridge clip etc..In 3C industries:Magnesium lithium alloy has excellent capability of electromagnetic shielding, therefore is closed using magnesium lithium Gold prepares 3C Product parts, can not only realize weight loss effect, additionally it is possible to reduces electromagnetic interference, makes the data of transmission truer Accurately, infringement of the electromagnetism to human body can also be reduced when it is used as case material.
Currently used for the magnesium lithium alloy of lightweight occasion, mainly include magnesium lithium-aluminium and magnesium lithium-zinc system.Wherein, magnesium lithium- Aluminium system generates intermetallic compound by the addition of aluminium and carries out second-phase strength, also by being solid-solubilized in α phases be dissolved by force Change.But these strengthen effects with temperature rise and fall quickly, and gained alloy material mechanical property phase at room temperature To poor.Magnesium lithium-kirsite belongs to precipitation hardening type, and cost is than less expensive, but the mechanical property of such alloy at room temperature It is relatively poor.Moreover, existing magnesium lithium alloy is low in the prevalence of elevated temperature strength, casting character is poor, slag charge handling process length etc. Problem.In addition, occur in the world in recent years can high temperature resistant and tool high-strength magnesium-lithium alloy formula in all contain valuable member Element, be not suitable for industrialized big production and application.α phases are Patterns for Close-Packed Hexagonal Crystal, and its plastic deformation ability is poor, and deformation processing is stranded Hardly possible, processing efficiency are low, and are difficult further post forming, cause the market share of in the market deformation α phase magnesium lithium alloys very low, Seriously constrain its large-scale application of (sheet material, section bar, tubing etc.) in Aero-Space and electronics industry.β phases it is cold and hot Forming ability is higher than α phase, it is allowed to which deflection is up to 50-60%.Great application prospect in national economy and modernization construction Single-phase β high-strength temperature-resistants magnesium lithium alloy, at home and abroad report all fewer.
High-performance β phase magnesium lithium alloy of the research and development with independent intellectual property right, for expanding magnesium lithium alloy application, improve China The technology content and class of manufacturing industry product, Chinese magnesium lithium alloy smelting, the technical level of processing industry are lifted, it is autonomous to grasp first The core technology for entering magnesium lithium alloy material development is significant.This patent provides a kind of containing the conjunction of beryllium and single-phase β magnesium lithium Gold, and the alloy belongs to deforming alloy.As structural member in use, not only can be significantly under the conditions of equipment Requirement be light-weighted Weight is reduced, can also further drop low-alloyed usage amount by using the high intensity of alloy.It is expected that in the near future, it is high The magnesium lithium alloy of intensity can be used on a large scale in fields such as the energy, electric power, communication, traffic, and can be in more engineerings There is more deep application extension in field.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of magnesium lithium alloy containing beryllium and single-phase β.
To achieve these goals, the present invention adopts the following technical scheme that:
A kind of magnesium lithium alloy containing beryllium and single-phase β.By weight percentage, the composition of alloy is:Li:12.0-19.0wt.%, Be: 0.1-0.3wt.%, Ni: 0.2-0.4wt.%, Cu: 1.0-3.0wt.%, Ge: 0.2-0.4wt.%, Hf: 0.1- 0.2wt.%, Sb: 0.2-0.4wt.%, Al:0.6-0.8wt.%, surplus are magnesium.
The preparation method of above-mentioned magnesium lithium alloy, comprises the following steps:As above the raw material matched is added to argon gas protection In electric induction furnace, and use silicon carbide crucible.Sensing heating forms alloy solution to 750-850 degree, and is imitated using electromagnetic agitation It should be sufficiently stirred 10 minutes or so.Alloy liquid is cast to waterglass or stone after the insulation of 750-850 degree stands 10 minutes Casting is carried out in black mould.Ingot casting is subjected to deformation process at room temperature, amount is 20-30% under every time rolling.Every 3 Secondary rolling needs to carry out an intermediate heat-treatment to eliminate processing hardening, and technique is:360 degree of 1 hours of insulation.After rolling most Whole Technology for Heating Processing is:Vacuum solid solution handles 250 degree and is incubated 4 hours;Vacuum aging handles 230 degree and is incubated 4 hours.
Compared with prior art, the present invention has the advantages that:
(1)Patent of the present invention be directed to current high temperature under magnesium lithium alloy performance drastically reduce and deterioration provides a kind of novel materials Solution.Using the thermodynamics in materialogy and phase diagram theory to instruct, added by main and secondary in preferred alloy Added elements improve the consistency in alloy in the big temperature range of the high-temperature stability of hardening constituent and phase content.By preferred Inexpensive multicomponent microalloying element formula, the formation for magnesium lithium alloy high temperature phase and hardening constituent provide thermodynamic condition; By subsequent further optimization smelting technology and heat treatment parameter, realize magnesium lithium alloy high temperature phase and hardening constituent perfect Match somebody with somebody, finally obtain a kind of novel high-strength heat resistant magnesium Zinc-lithium alloy material.
(2)The alloy has low phase solidification temperature range, and hot cracking tendency is big when can solve to cast, and casting hole is bright Aobvious, elevated temperature strength is low to wait technical barrier.Smelting processing method is simple, and production cost is than relatively low.It is easy to industrialize large-scale application.
(3)The performance of the magnesium lithium alloy at room temperature:Yield strength is 118-142MPa, tensile strength 175-194MPa, Elongation percentage is 7-16%.At 100 degree, the performance of the magnesium lithium alloy:Yield strength is 115-136MPa, tensile strength 160- 174MPa, elongation percentage 17-20%.
Embodiment
Embodiment 1
A kind of magnesium lithium alloy containing beryllium and single-phase β.By weight percentage, the chemical composition of alloy is:Li:13.9wt.%, Be: 0.2wt.%, Ni: 0.3wt.%, Cu: 2.4wt.%, Ge: 0.3wt.%, Hf: 0.1wt.%, Sb: 0.2wt.%, Al:0.6wt.%, surplus are magnesium.The preparation method of alloy:As above the raw material matched is added to the electric induction furnace of argon gas protection It is interior, and use silicon carbide crucible.Sensing heating forms alloy solution, and be sufficiently stirred 10 minutes using galvanomagnetic-effect to 800 degree Left and right.Alloy liquid is cast in waterglass mould for 10 minutes in 800 degree of insulations and carries out casting.By ingot casting at room temperature Deformation process is carried out, amount is 25% under every time rolling.Every 3 passes need to carry out an intermediate heat-treatment to eliminate processing Hardening, technique are:360 degree of 1 hours of insulation.Final Heat Treatment Process after rolling is:Vacuum solid solution handles 250 degree of insulations 4 Hour;Vacuum aging handles 230 degree and is incubated 4 hours.The performance of the magnesium lithium alloy at room temperature:Yield strength is 125MPa, tension Intensity is 180MPa, elongation percentage 8%.At 100 degree, the performance of the magnesium lithium alloy:Yield strength is 120MPa, and tensile strength is 165MPa, elongation percentage 18%.The alloy uses 2 years under 100 degree, has no obvious mechanical property decay.
Embodiment 2
A kind of magnesium lithium alloy containing beryllium and single-phase β.By weight percentage, the chemical composition of alloy is:Li:17.4wt.%, Be: 0.2wt.%, Ni: 0.2wt.%, Cu: 1.9wt.%, Ge: 0.3wt.%, Hf: 0.1wt.%, Sb: 0.2wt.%, Al:0.7wt.%, surplus are magnesium.The preparation method of alloy:As above the raw material matched is added to the electric induction furnace of argon gas protection It is interior, and use silicon carbide crucible.Sensing heating forms alloy solution, and be sufficiently stirred 10 minutes using galvanomagnetic-effect to 800 degree Left and right.Alloy liquid is cast in waterglass mould for 10 minutes in 800 degree of insulations and carries out casting.By ingot casting at room temperature Deformation process is carried out, amount is 25% under every time rolling.Every 3 passes need to carry out an intermediate heat-treatment to eliminate processing Hardening, technique are:360 degree of 1 hours of insulation.Final Heat Treatment Process after rolling is:Vacuum solid solution handles 250 degree of insulations 4 Hour;Vacuum aging handles 230 degree and is incubated 4 hours.The performance of the magnesium lithium alloy at room temperature:Yield strength is 125MPa, tension Intensity is 185MPa, elongation percentage 12%.At 100 degree, the performance of the magnesium lithium alloy:Yield strength is 118MPa, and tensile strength is 172MPa, elongation percentage 18%.The alloy uses 2 years under 100 degree, has no obvious mechanical property decay.
Embodiment 3
A kind of magnesium lithium alloy containing beryllium and single-phase β.By weight percentage, the chemical composition of alloy is:Li:17.5wt.%, Be: 0.1wt.%, Ni: 0.4wt.%, Cu: 2.8wt.%, Ge: 0.3wt.%, Hf: 0.1wt.%, Sb: 0.3wt.%, Al:0.6wt.%, surplus are magnesium.The preparation method of alloy:As above the raw material matched is added to the electric induction furnace of argon gas protection It is interior, and use silicon carbide crucible.Sensing heating forms alloy solution, and be sufficiently stirred 10 minutes using galvanomagnetic-effect to 800 degree Left and right.Alloy liquid is cast in waterglass mould for 10 minutes in 800 degree of insulations and carries out casting.By ingot casting at room temperature Deformation process is carried out, amount is 25% under every time rolling.Every 3 passes need to carry out an intermediate heat-treatment to eliminate processing Hardening, technique are:360 degree of 1 hours of insulation.Final Heat Treatment Process after rolling is:Vacuum solid solution handles 250 degree of insulations 4 Hour;Vacuum aging handles 230 degree and is incubated 4 hours.The performance of the magnesium lithium alloy at room temperature:Yield strength is 130MPa, tension Intensity is 185MPa, elongation percentage 12%.At 100 degree, the performance of the magnesium lithium alloy:Yield strength is 122MPa, and tensile strength is 168MPa, elongation percentage 19%.The alloy uses 2 years under 100 degree, has no obvious mechanical property decay.

Claims (3)

1. a kind of magnesium lithium alloy and its processing technology containing beryllium and single-phase β, it is characterised in that the group of alloy by weight percentage Turn into:Li:12.0-19.0wt.%, Be: 0.1-0.3wt.%, Ni: 0.2-0.4wt.%, Cu: 1.0-3.0wt.%, Ge: 0.2-0.4wt.%, Hf: 0.1-0.2wt.%, Sb: 0.2-0.4wt.%, Al:0.6-0.8wt.%, surplus are magnesium.
2. the preparation method of magnesium lithium alloy according to claim 1, it is characterised in that comprise the following steps:By what is as above matched Raw material is added in the electric induction furnace of argon gas protection, and uses silicon carbide crucible, and it is molten that sensing heating to 750-850 degree forms alloy Liquid, and be sufficiently stirred 10 minutes or so using electromagnetic agitation effect, by alloy liquid after the insulation of 750-850 degree stands 10 minutes It is cast in waterglass or graphite jig and carries out casting.
3. the hot-working method of magnesium lithium alloy according to claim 1, it is characterised in that comprise the following steps:By ingot casting in room Temperature is lower to carry out deformation process, and amount is 20-30% under every time rolling, and every 3 passes need to carry out an intermediate heat-treatment to disappear Except processing is hardened, technique is:360 degree, 1 hour, the Final Heat Treatment Process after rolling was:Vacuum solid solution handles 250 degree, and 4 is small When;Vacuum aging handles 230 degree, 4 hours;Then water quenching.
CN201710822197.0A 2017-09-13 2017-09-13 A kind of magnesium lithium alloy and its processing technology containing beryllium and single-phase β Withdrawn CN107475587A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112105753A (en) * 2018-04-23 2020-12-18 佳能株式会社 Magnesium-lithium alloy
CN115287514A (en) * 2018-04-23 2022-11-04 佳能株式会社 Magnesium-lithium alloy

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112105753A (en) * 2018-04-23 2020-12-18 佳能株式会社 Magnesium-lithium alloy
EP3770288A4 (en) * 2018-04-23 2021-12-22 Canon Kabushiki Kaisha Magnesium-lithium-based alloy
CN115287514A (en) * 2018-04-23 2022-11-04 佳能株式会社 Magnesium-lithium alloy
CN115287514B (en) * 2018-04-23 2023-11-03 佳能株式会社 Magnesium-lithium alloy
US11840749B2 (en) 2018-04-23 2023-12-12 Canon Kabushiki Kaisha Magnesium-lithium-based alloy

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