CN107474675A - A kind of fluorescence paint - Google Patents
A kind of fluorescence paint Download PDFInfo
- Publication number
- CN107474675A CN107474675A CN201710810838.0A CN201710810838A CN107474675A CN 107474675 A CN107474675 A CN 107474675A CN 201710810838 A CN201710810838 A CN 201710810838A CN 107474675 A CN107474675 A CN 107474675A
- Authority
- CN
- China
- Prior art keywords
- paint
- fluorescent material
- parts
- fluorescence
- silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003973 paint Substances 0.000 title claims abstract description 50
- 239000000463 material Substances 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 15
- 229910000077 silane Inorganic materials 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 9
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical group OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 6
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- HZBAVWLZSLOCFR-UHFFFAOYSA-N oxosilane Chemical compound [SiH2]=O HZBAVWLZSLOCFR-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 10
- 238000005286 illumination Methods 0.000 abstract description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract description 4
- 239000003822 epoxy resin Substances 0.000 abstract description 2
- 229920000647 polyepoxide Polymers 0.000 abstract description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011295 pitch Substances 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical class [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of fluorescence paint, including following raw material by weight to be made：30 40 parts of methacrylate emulsions；8 10 parts of epoxy resin；8 15 parts of pitches；3 10 parts of modified fluorescent material；7 10 parts of curing agent；5 12 parts of titanium dioxides；13 parts of organic clays；13 parts of anti-blushing agents；25 parts of diphenylamines；25 parts of aluminum oxide.Using the present invention, it can prevent fluorescent material from absorbing water and play a part of protecting fluorescent material, so as to extend the luminescent lifetime of paint, moreover it is possible to lift the illumination effect of paint.
Description
Technical field
The present invention relates to one kind to paint, more particularly to a kind of fluorescence paint.
Background technology
Luminous paint can be used for covering with paint, lacquer, colour wash, etc. various marks, can play a part of night instruction.Existing luminous paint is usually will
Fluorescent material is added in paint by a certain percentage, it is agitated uniformly after, be made with lighting function paint.However, fluorescent material
Water absorbing force it is strong, the moisture in adsorbable air cause the impaired performance of excited atom so as to influence the service life of fluorescent material with
And the illumination effect of paint.For this reason, it may be necessary to provide a kind of new fluorescence paint, can delayed fluorescence powder service life, lifting oil
The illumination effect of paint.
The content of the invention
The technical problems to be solved by the invention are, there is provided a kind of fluorescence paint, can prevent fluorescent material from absorbing water and playing
The effect of fluorescent material is protected, so as to extend the luminescent lifetime of paint.
The technical problems to be solved by the invention also reside in, there is provided a kind of fluorescence paint, can lift the illumination effect of paint.
In order to solve the above-mentioned technical problem, the invention provides a kind of fluorescence paint, including following original by weight
Material is made：
As the improvement of such scheme, the modified fluorescent material is that fluorescent material is modified by silane；
Silane is counted by weight ratio：Fluorescent material=1.5-2.5：1.
It is manosil AS strontium or alkali earth metal aluminate available for modified fluorescent material as the improvement of such scheme.
As the improvement of such scheme, the silane is the ethoxy silane of methyl three or the ethoxy silane of vinyl three.
As the improvement of such scheme, the anti-blushing agent is montmorillonite powder.
As the improvement of such scheme, the curing agent is dodecanedioic acid curing agent.
As the improvement of such scheme, the grain diameter of the modified fluorescent material is 80-150 mesh.
Implement the present invention, have the advantages that：
The present invention is modified using silane to fluorescent material first so that silane is coated on fluorescent material appearance, in fluorescent material
Surface forms layer protecting film；Secondly, competition water suction can be formed with fluorescent material by introducing anti-blushing agent, so as to reduce fluorescent material
Water absorption；Meanwhile pitch is additionally added in formula can make paint have water resistance, the water resistance after film forming is painted in lifting.Pass through
The cooperation of inventive formulation each component, at utmost reduce because absorbing water to fluorescent material service life and the bad shadow of illumination effect
Ring.And the matrix resin in painting uses the methacrylate with the high grade of transparency, energy will be farthest by fluorescent material
The luminous energy of conversion is unobstructed to be passed out, and effectively lifts the illumination effect of paint.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, the present invention will be made below further detailed
Description.
Existing luminous paint due to be directly by fluorescent material put into existing paint it is agitated uniformly after obtain light-emitting oil
Paint, but there is water absorption character due to fluorescent material, if the moisture in exposure absorption air easy in atmosphere, so as to influence fluorescence
The illumination effect of powder.
To be made therefore, the invention provides a kind of fluorescence paint, including following raw material by weight：
Preferably, the invention provides a kind of fluorescence paint, including following raw material by weight to be made：
Unlike existing luminous paint, fluorescent material carries out fluorescent material before adding to paint and is modified work in the present invention
Modified fluorescent material is made in sequence, and modified fluorescent material is interior due to being wrapped in by silane, is not easy to be combined with external water molecule, so as to very
Fluorescent material is protected not to be destroyed well.Specific modification procedure is as follows：
(1) silane is counted by weight ratio：Fluorescent material=1.5-2.5：1 weighs silane and fluorescent material；
(2) fluorescent material is added in organic solvent and be uniformly dispersed, obtain mixed liquor；
(3) under agitation, silane and catalyst are added in above-mentioned mixed liquor, 50-80 DEG C of reaction temperature, during reaction
Between 2-5 hours, modified fluorescent material most is made through cooling down, filtering and dry afterwards.
It should be noted that it is 80-150 mesh by modified modification fluorescent powder grain particle diameter.
Preferably, it is manosil AS strontium or alkali earth metal aluminate available for modified fluorescent material.The silane is methyl three
Ethoxy silane or the ethoxy silane of vinyl three.The curing agent is dodecanedioic acid curing agent.
In addition, using the methacrylate of the high grade of transparency in the formula of fluorescence paint of the present invention, paint has in itself
There are translucency well, naked power.And the silicon-containing compound for being modified phosphor surface covering also has very high transparency, because
This can farthest by fluorescent material convert luminous energy it is unobstructed pass out, after tested find using fluorescence of the present invention paint apply
Film layer luminous efficiency and fluorescent lifetime after film are substantially better than existing fluorescence paint institute film layer.
And the performances such as the resistance to acids and bases for causing paint, soil resistance, wear-resisting, pressure-resistant, impact resistance that add of epoxy resin obtain
Further lifting.
In order to further reduce fluorescent material and the moisture in air, protection against the tide is also added in fluorescence paint of the present invention
Agent, it is preferable that the anti-blushing agent is montmorillonite powder.Pitch is additionally added in formula can make paint have water resistance, lifting paint
Water resistance after film forming.
To sum up, the present invention is modified using silane to fluorescent material first so that silane is coated on fluorescent material appearance, glimmering
Light powder surface forms layer protecting film；Secondly, competition water suction can be formed with fluorescent material by introducing anti-blushing agent, so as to reduce fluorescence
The water absorption of powder；Meanwhile pitch is additionally added in formula can make paint have water resistance, the water resistance after film forming is painted in lifting.
By the cooperation of inventive formulation each component, at utmost reduce because absorbing water to the bad of fluorescent material service life and illumination effect
Influence.And the matrix resin in painting uses the methacrylate with the high grade of transparency, energy will be farthest by fluorescence
The unobstructed illumination effect for passing out, effectively lifting paint of luminous energy of powder conversion.
Further illustrated below by way of specific embodiment.
Embodiment 1
A kind of fluorescence paint, including following raw material by weight are made：
Embodiment 2
A kind of fluorescence paint, including following raw material by weight are made：
Embodiment 3
A kind of fluorescence paint, including following raw material by weight are made：
Embodiment 4
A kind of fluorescence paint, including following raw material by weight are made：
Described above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (7)
1. a kind of fluorescence paint, it is characterised in that be made including following raw material by weight：
2. fluorescence paint as claimed in claim 1, it is characterised in that the modified fluorescent material is to be carried out by silane to fluorescent material
It is modified；
Silane is counted by weight ratio：Fluorescent material=1.5-2.5：1.
3. fluorescence paint as claimed in claim 2, it is characterised in that golden for manosil AS strontium or alkaline earth available for modified fluorescent material
Belong to aluminate.
4. fluorescence paint as claimed in claim 2, it is characterised in that the silane is the ethoxy silane of methyl three or the second of vinyl three
Oxosilane.
5. fluorescence paint as claimed in claim 1, it is characterised in that the anti-blushing agent is montmorillonite powder.
6. fluorescence paint as claimed in claim 1, it is characterised in that the curing agent is dodecanedioic acid curing agent.
7. fluorescence paint as claimed in claim 1, it is characterised in that the grain diameter of the modified fluorescent material is 80-150 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710810838.0A CN107474675A (en) | 2017-09-11 | 2017-09-11 | A kind of fluorescence paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710810838.0A CN107474675A (en) | 2017-09-11 | 2017-09-11 | A kind of fluorescence paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107474675A true CN107474675A (en) | 2017-12-15 |
Family
ID=60584035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710810838.0A Pending CN107474675A (en) | 2017-09-11 | 2017-09-11 | A kind of fluorescence paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107474675A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103436249A (en) * | 2013-09-13 | 2013-12-11 | 武汉工程大学 | Organic silicon wrapped fluorescent powder for light emitting coating and preparation method and application thereof |
| CN105315866A (en) * | 2014-07-31 | 2016-02-10 | 天津市新丽华色材有限责任公司 | Waterproof light-emitting paint |
| CN105949947A (en) * | 2016-05-20 | 2016-09-21 | 林歆 | Fluorescent paint, and preparation method and application thereof |
| CN106378290A (en) * | 2016-08-29 | 2017-02-08 | 山东霞光实业有限公司 | Wood-plastic product with luminous surface layer and preparation method of wood-plastic product |
-
2017
- 2017-09-11 CN CN201710810838.0A patent/CN107474675A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103436249A (en) * | 2013-09-13 | 2013-12-11 | 武汉工程大学 | Organic silicon wrapped fluorescent powder for light emitting coating and preparation method and application thereof |
| CN105315866A (en) * | 2014-07-31 | 2016-02-10 | 天津市新丽华色材有限责任公司 | Waterproof light-emitting paint |
| CN105949947A (en) * | 2016-05-20 | 2016-09-21 | 林歆 | Fluorescent paint, and preparation method and application thereof |
| CN106378290A (en) * | 2016-08-29 | 2017-02-08 | 山东霞光实业有限公司 | Wood-plastic product with luminous surface layer and preparation method of wood-plastic product |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |
|
| RJ01 | Rejection of invention patent application after publication |