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CN107460060A - A kind of micella osmosis type concentrates quick liquid detergent and preparation method - Google Patents

A kind of micella osmosis type concentrates quick liquid detergent and preparation method Download PDF

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Publication number
CN107460060A
CN107460060A CN201710704627.9A CN201710704627A CN107460060A CN 107460060 A CN107460060 A CN 107460060A CN 201710704627 A CN201710704627 A CN 201710704627A CN 107460060 A CN107460060 A CN 107460060A
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China
Prior art keywords
parts
micella
liquid detergent
osmosis type
cellulose ether
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CN201710704627.9A
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Chinese (zh)
Inventor
陈庆
曾军堂
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Chengdu New Keli Chemical Science Co Ltd
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Chengdu New Keli Chemical Science Co Ltd
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Priority to CN201710704627.9A priority Critical patent/CN107460060A/en
Publication of CN107460060A publication Critical patent/CN107460060A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2017—Monohydric alcohols branched
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C11D3/323—Amides; Substituted amides urea or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/362—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38618—Protease or amylase in liquid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to the production field of domestic chemical products, quick liquid detergent and preparation method are concentrated more particularly to a kind of micella osmosis type, by the way that low temperature disperses to form micella under water auxiliary by sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester and serine protease, cellulose ether, APG, sulfosuccinate composition concentrated type liquid detergent are then added.Its significant advantage is that micella has infiltration decomposition to greasy dirt, sweat stain, and the greasy dirt sweat stain decomposed under APG, sulfosuccinate emulsification is rapidly separated clothing.Particularly washed under normal temperature condition, micella has same infiltration decomposition to greasy dirt, sweat stain, and it has not only reached the purpose of cleaning, and has protective effect to fabric fibre.

Description

A kind of micella osmosis type concentrates quick liquid detergent and preparation method
Technical field
The present invention relates to the production field of domestic chemical products, and quick laundry is concentrated more particularly to a kind of micella osmosis type Liquid and preparation method.
Background technology
With our people's living standard step up and enhancing to health consciousness, China's house detergent disappear The amount of expense is increasing, shows very big development prospect.Predicted according to research, the coming years, Chinese daily-use chemical industry articles for use will be held Continuous steady-state growth, compound growth rate are maintained at 13.4% or so, and overall market can reach more than 2,000 hundred million yuan.
As the development of society and the raising of the level of consumption, people are also increasing to the demand of detergent.Domestic consumption Person gets used to the solid detergent based on washing powder and laundry soap always, and in recent years, increasing of the liquid detergent to be exceedingly fast Long speed is changing the Distribution Pattern of detergent market.Liquid detergent compared with solid detergent, it is easy to use, dissolving it is fast Speed, cold washing effect is good, system it is alkaline it is low, more gentle to fabric and skin, be adapted to mechanization washing process, while also have There is formula spirit.
The developing direction of detergent is at present：To green safe, multifunctional direction development；Research and design novel surface activity Agent molecule structure effective catalyst；Improve the use of natural reproducible raw material；Greenization preparation and clean manufacturing；Develop low thorn Sharp, hard water resistance, low-temperature resistance and the high value added product with the multiple functions such as submissive, nursing, antibacterial, color protection, pure and fresh.
Nowadays, liquid detergent is developed rapidly because its is environmentally friendly, without phosphorus, safe, easy to use.At present, do washing Liquid has progressively substituted washing powder as the requirement in the modern life.Compared with traditional solid detergent, liquid detergent Using preceding without dissolving, there is the advantages of easy to use, dissolving (scattered) speed is fast, and cold washing performance is good.Especially concentrate Liquid detergent active matter content is high, strong detergency, while also has and save packaging material, reduces cost of transportation, and reduce The advantages of storage space, is widely used.Liquid detergent is generally divided into normal laundry liquid detergent and underwear liquid detergent.Now on the market Liquid detergent whether normal laundry liquid detergent or underwear liquid detergent in washing process, are only used as simple cleaning agent, only The effect of decontamination can be played, does not have the effect of efficient antibacterial, antibacterial, prevent from going mouldy.In addition, commercial laundry liquid is more with surface Activating agent compounds some alkaline assistants to reach the purpose of decontamination, in spite of neutral products, it is also difficult to the effect of reaching antibacterial.With The growing interest to environmental problem, consumer also gradually recognizes that the raw material of concentrated product, packaging material dosage are few, to environment Discharge it is less, be advantageous to environmental protection.Thus, increasing consumer starts to receive concentrated product.But specifically producing During use, activating enzymes and bleaching agent are different from solid detergent in concentrated liquid detergent and stablized like that, easily inactivation Failure, therefore have to ensure clean result by increasing usage amount.
At present, why the concentration of present concentration liquid detergent can only be common twice or so, mainly by it is following two because Element influences.First is cost factor, if cycles of concentration is higher, the cost of liquid detergent is also by multiple increase even more high, then add Upper packaging, sale price is higher, and consumer is difficult to be received.Second is technical factor, if cycles of concentration is higher, it is necessary to solubilization technique, Need to add the solubilizer such as toluenesulfonic acid sodium salt, cumene sodium sulfonate, ethanol, isopropanol to reduce viscosity and improve mobility, but It is to add these solubilizer not having detergency much help, causes to waste.
The content of the invention
For the defects of existing concentrated liquid detergent uses enzyme preparation, bleaching agent is unstable, the present invention proposes a kind of glue Beam osmosis type concentrates quick liquid detergent and preparation method, can be washed under normal temperature condition, and micella has same to greasy dirt, sweat stain Infiltration decomposition, it has not only reached the purpose of cleaning, and has had protective effect to fabric fibre, also add concentration The concentration of liquid detergent.
To solve the above problems, the present invention uses following technical scheme：
A kind of micella osmosis type concentrates quick liquid detergent, by being prepared including following material：Sodium sulfite, xylene monosulfonic acid Sodium, ATBC, triphosphoric acid monooctyl ester, protease, cellulose ether, APG, sulfosuccinate, emulsifying agent and molten Agent.
The present invention by sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester and serine protease, Cellulose ether low temperature under water auxiliary disperses to form micella, then adds APG, sulfosuccinate composition concentrated type is washed Clothing liquid.Its significant advantage is that micella has infiltration decomposition, APG, sulfosuccinate emulsification to greasy dirt, sweat stain The lower greasy dirt sweat stain decomposed of effect is rapidly separated clothing.Particularly washed under normal temperature condition, micella has same to greasy dirt, sweat stain The infiltration decomposition of sample, it has not only reached the purpose of cleaning, and has protective effect to fabric fibre.
In the present invention, the proportioning of each material is an important factor for influenceing liquid detergent dirt-removing power and concentration, it is preferred that described Micella osmosis type concentrates quick liquid detergent, includes the material of following parts by weight：5 ~ 12 parts of sodium sulfite, sodium xylene sulfonate 3 ~ 8 Part, 2 ~ 15 parts of ATBC, 5 ~ 25 parts of triphosphoric acid monooctyl ester, 1 ~ 6 part of protease, 10 ~ 30 parts of cellulose ether, APG 6 ~ 30 ~ 80 parts of 18 parts, 8 ~ 16 parts of sulfosuccinate, 6 ~ 10 parts of emulsifying agent and solvent.It is further preferred that the micella osmosis type Quick liquid detergent is concentrated, includes 4 ~ 6 parts of 6 ~ 10 parts of material sodium sulfite, sodium xylene sulfonate, the citric acid three of following parts by weight 3 ~ 12 parts of butyl ester, 8 ~ 16 parts of triphosphoric acid monooctyl ester, 2 ~ 4 parts of protease, 12 ~ 25 parts of cellulose ether, 8 ~ 15 parts of APG, sulfo group amber 45 ~ 60 parts of 10 ~ 15 parts of amber acid esters, 8 ~ 10 parts of emulsifying agent and solvent.
In the present invention, protease can decompose the spots such as the blood in clothes, it is preferred that the protease is cysteine At least one of protease, serine protease and lucid asparagus protease propylhomoserin enzyme.
The cellulose ether is methyl cellulose ether, ethoxyl methyl cellulose ether, TYLOSE 30000, ethyl cellulose Plain ether, benzylcellulose ether, hydroxyethyl ether cellulose, hydroxypropyl methyl cellulose ether, cyanethyl cellulose ether, benzyl cyanoethyl At least one of cellulose ether, carboxymethyl hydroxyethyl cellulose ether and benzyl cellulose ether.
The emulsifying agent is coconut acid diethanolamide, cocinic acid formicester diglycollic amide, cocinic acid monoethanol Acid amides, lauric monoisopropanolamide, Stearic acid diethanolamine salt, stearic acid methyl ester diglycollic amide, stearic acid monoethanol acyl At least one of amine, oleic acid diethyl amide, oleic acid formicester diglycollic amide, myristic acid single ethanol amide.
The solvent is at least one of water, glycerine.
In order to further lift the quality of liquid detergent, it is preferred that also include essence, pigment in the concentration liquid detergent, prevent At least one of rotten agent, cosolvent, inorganic salts, chelating agent, plant extraction liquid.
At present, more calcium, the water of magnesium ion are contained in water so that water quality " is hardened ", after general detergent adds, can produce Scum silica frost, causes the waste of detergent, and liquid detergent of the invention being capable of normal use in hard water.
Inorganic salts can increase the viscosity of liquid detergent, improve the feel of liquid detergent, it is preferred that the inorganic salts are sulfuric acid At least one of sodium, potassium sulfate, sodium chloride, potassium chloride, magnesium sulfate, magnesium chloride, calcium chloride.
The chelating agent is citric acid, tartaric acid, sodium metasilicate, sodium carbonate, oxygen di- sodium acetate, carboxymethyl hydroxymalonic acid At least one of sodium, nitrilotriacetic acid sodium, sodium ethylene diamine tetracetate.
The cosolvent is at least one of sodium xylene sulfonate, urea, ethanol, isopropanol.
Plant extraction liquid has certain health-care effect, and the effect of health care changes according to the species of plant, in addition, plant carries Take aromatic odor in liquid also can pleasant mental and body, the species of plant extraction liquid can be adjusted according to actual conditions in the present invention It is whole, can be that the present invention will not be repeated here, for example, the plant extraction liquid carries for ginger known to one of ordinary skill in the art Take in liquid, extract solution from aloe and orange peel extract solution, lemon extract, rose extract solution, lavender extract solution, tea tree extract solution It is at least one.
The preparation method that a kind of micella osmosis type concentrates quick liquid detergent comprises the following steps：
（1）By sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, protease, cellulose ether in solvent In be uniformly dispersed, formed micella；
（2）To step（1）Micella in add APG, sulfosuccinate and emulsifying agent, after being well mixed, that is, obtain glue Beam osmosis type concentrates quick liquid detergent.
In step（1）In, the scattered temperature is 20 ~ 45 DEG C, and jitter time is 5 ~ 30min.
A kind of micella osmosis type of the present invention concentrates quick liquid detergent and preparation method, compared with prior art, what it was protruded Feature and excellent effect are：
The present invention is by sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester and serine protease, fiber Plain ether low temperature under water auxiliary disperses to form micella, then adds APG, sulfosuccinate composition concentrated type liquid detergent. Its significant advantage, which is micella, has infiltration decomposition to greasy dirt, sweat stain, under APG, sulfosuccinate emulsification The greasy dirt sweat stain of decomposition is rapidly separated clothing.Particularly washed under normal temperature condition, micella has same ooze to greasy dirt, sweat stain Saturating decomposition, it has not only reached the purpose of cleaning, and has protective effect to fabric fibre.
Embodiment
Below by way of embodiment, the present invention is described in further detail, but this should not be interpreted as to the present invention Scope be only limitted to following example.In the case where not departing from above method thought of the present invention, according to ordinary skill The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
A kind of micella osmosis type concentrates quick liquid detergent, is made up of the material of following parts by weight：8 parts of sodium sulfite, dimethylbenzene sulphur Sour 5 parts of sodium, 5 parts of ATBC, 10 parts of triphosphoric acid monooctyl ester, caspase-3 part, 18 parts of cellulose ether, alkyl sugar 10 parts of glycosides, 12 parts of sulfosuccinate, 9 parts of lauric monoisopropanolamide, 30 parts of water, 2 parts of citric acid, 12 parts of magnesium sulfate, two 1 part of toluenesulfonic acid sodium salt, 12 parts of ginger extract.
Described micella osmosis type concentrates the preparation method of quick liquid detergent, and step is as follows：
（1）By sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, cysteine proteinase, cellulose Ether is dispersed in water, and 20min is disperseed at 30 DEG C and is uniformly dispersed, forms micella；
（2）To step（1）Micella in add APG, sulfosuccinate, lauric monoisopropanolamide, citric acid, Magnesium sulfate, sodium xylene sulfonate, ginger extract, after being well mixed, that is, obtain micella osmosis type and concentrate quick liquid detergent.
Embodiment 2
A kind of micella osmosis type concentrates quick liquid detergent, is made up of the material of following parts by weight：10 parts of sodium sulfite, dimethylbenzene sulphur Sour 6 parts of sodium, 12 parts of ATBC, 16 parts of triphosphoric acid monooctyl ester, 2 parts of serine protease, 25 parts of methyl cellulose ether, alkyl 8 parts of glucosides, 15 parts of sulfosuccinate, 8 parts of coconut acid diethanolamide, 20 parts of glycerine, 1 part of oxygen di- sodium acetate, chlorine Change 6 parts of calcium, 2 parts of urea, 6 parts of tea tree extract solution.
Described micella osmosis type concentrates the preparation method of quick liquid detergent, and step is as follows：
（1）By sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, serine protease, Methyl cellulose Plain ether is dispersed in glycerine, and 25min is disperseed at 25 DEG C and is uniformly dispersed, forms micella；
（2）To step（1）Micella in add APG, sulfosuccinate, coconut acid diethanolamide, oxygen di- vinegar Sour sodium, calcium chloride, urea, tea tree extract solution, after being well mixed, that is, obtain micella osmosis type and concentrate quick liquid detergent.
Embodiment 3
A kind of micella osmosis type concentrates quick liquid detergent, is made up of the material of following parts by weight：6 parts of sodium sulfite, dimethylbenzene sulphur Sour 4 parts of sodium, 3 parts of ATBC, 8 parts of triphosphoric acid monooctyl ester, 4 parts of serine protease, 12 parts of ethoxyl methyl cellulose ether, 15 parts of APG, 10 parts of sulfosuccinate, 10 parts of cocinic acid formicester diglycollic amide and 60 parts of water, carboxymethyl propyl alcohol two Sour 1 part of sodium, 8 parts of magnesium sulfate, 4 parts of urea, 8 parts of lemon extract.
Described micella osmosis type concentrates the preparation method of quick liquid detergent, and step is as follows：
（1）By sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, serine protease, ethoxy first Base cellulose ether is dispersed in water, and 5min is disperseed at 45 DEG C and is uniformly dispersed, forms micella；
（2）To step（1）Micella in add APG, sulfosuccinate, cocinic acid formicester diglycollic amide, carboxylic first Base hydroxymalonic acid sodium, magnesium sulfate, urea, lemon extract, after being well mixed, that is, obtain the quick laundry of micella osmosis type concentration Liquid.
Embodiment 4
A kind of micella osmosis type concentrates quick liquid detergent, is made up of the material of following parts by weight：12 parts of sodium sulfite, dimethylbenzene sulphur Sour 3 parts of sodium, 15 parts of ATBC, 25 parts of triphosphoric acid monooctyl ester, 6 parts of lucid asparagus protease propylhomoserin enzyme, carboxy methyl hydroxyethyl are fine Tie up plain 10 parts of ether, 18 parts of APG, 16 parts of sulfosuccinate, 6 parts of oleic acid formicester diglycollic amide and 80 parts of water, nitrilo three 5 parts of sodium acetate, 10 parts of sodium chloride, 5 parts of isopropanol, 3 parts of orange peel extract solution.
Described micella osmosis type concentrates the preparation method of quick liquid detergent, and step is as follows：
（1）By sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, lucid asparagus protease propylhomoserin enzyme, carboxylic Methyl hydroxyethylcellulose ether is dispersed in water, and 30min is disperseed at 20 DEG C and is uniformly dispersed, forms micella；
（2）To step（1）Micella in add APG, sulfosuccinate, oleic acid formicester diethanol acyl, nitrilotriacetic acid Sodium, sodium chloride, isopropanol, orange peel extract solution, after being well mixed, that is, obtain micella osmosis type and concentrate quick liquid detergent.
Embodiment 5
A kind of micella osmosis type concentrates quick liquid detergent, is made up of the material of following parts by weight：5 parts of sodium sulfite, dimethylbenzene sulphur Sour 8 parts of sodium, 2 parts of ATBC, 5 parts of triphosphoric acid monooctyl ester, 1 part of lucid asparagus protease propylhomoserin enzyme, TYLOSE 30000 30 Part, 6 parts of APG, 8 parts of sulfosuccinate, 10 parts of oleic acid diethyl amide and 50 parts of water, 2 parts of sodium ethylene diamine tetracetate, 5 parts of sodium sulphate, 8 parts of urea, 5 parts of extract solution from aloe.
Described micella osmosis type concentrates the preparation method of quick liquid detergent, and step is as follows：
（1）By sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, lucid asparagus protease propylhomoserin enzyme, carboxylic Methyl cellulose ether is dispersed in water, and 15min is disperseed at 30 DEG C and is uniformly dispersed, forms micella；
（2）To step（1）Micella in add APG, sulfosuccinate, oleic acid diethyl amide, ethylenediamine tetra-acetic acid Sodium, sodium sulphate, urea, extract solution from aloe, after being well mixed, that is, obtain micella osmosis type and concentrate quick liquid detergent.
Comparative example 1
A kind of micella osmosis type concentrates quick liquid detergent, is made up of the material of following parts by weight：5 parts of sodium sulfite, dimethylbenzene sulphur Sour 8 parts of sodium, 2 parts of ATBC, 5 parts of triphosphoric acid monooctyl ester, 30 parts of TYLOSE 30000,6 parts of APG, sulfosuccinic 50 parts of 8 parts of acid esters, 10 parts of oleic acid diethyl amide and water, 2 parts of sodium ethylene diamine tetracetate, 5 parts of sodium sulphate, 8 parts of urea, aloe carry Take 5 parts of liquid.
Described micella osmosis type concentrates the preparation method of quick liquid detergent, and step is as follows：
（1）Sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, TYLOSE 30000 are dispersed in water In, scattered 15min is uniformly dispersed at 30 DEG C；
（2）To step（1）Micella in add APG, sulfosuccinate, oleic acid diethyl amide, ethylenediamine tetra-acetic acid Sodium, sodium sulphate, urea, extract solution from aloe, after being well mixed, that is, obtain micella osmosis type and concentrate quick liquid detergent.
Comparative example 2
A kind of micella osmosis type concentrates quick liquid detergent, is made up of the material of following parts by weight：5 parts of sodium sulfite, citric acid three 50 parts of 2 parts of butyl ester, 5 parts of triphosphoric acid monooctyl ester, 6 parts of APG, 8 parts of sulfosuccinate, 10 parts of oleic acid diethyl amide and water, 2 parts of sodium ethylene diamine tetracetate, 5 parts of sodium sulphate, 8 parts of urea, 5 parts of extract solution from aloe.
Described micella osmosis type concentrates the preparation method of quick liquid detergent, and step is as follows：
（1）Sodium sulfite, ATBC, triphosphoric acid monooctyl ester are dispersed in water, it is scattered equal that 15min is disperseed at 30 DEG C It is even；
（2）To step（1）Micella in add APG, sulfosuccinate, oleic acid diethyl amide, ethylenediamine tetra-acetic acid Sodium, sodium sulphate, urea, extract solution from aloe, after being well mixed, that is, obtain micella osmosis type and concentrate quick liquid detergent.
Test：
According to GB-T13174-2008《Dress material detergent detergency and the measure of circulation scourability》It is required that from carbon black oil Three kinds of soiled cottons such as soiled cotton, albumen soiled cotton, sebum soiled cotton are as experimental subjects, using the liquid detergent of comparative example 1 as reference liquid detergent, Obtained decontamination ratio is that experimental result is as shown in table 1.
Table 1：
Sample Carbon black greasy dirt cloth Albumen soiled cotton Sebum soiled cotton
Embodiment 1 2.1 5.3 2.6
Embodiment 2 2.0 4.5 2.8
Embodiment 3 1.8 4.2 2.1
Embodiment 4 1.6 4.1 2.3
Embodiment 5 1.9 3.8 2.3
Comparative example 1 1.0 1.0 1.0
Comparative example 2 0.9 0.8 1.3

Claims (10)

1. a kind of micella osmosis type concentrates quick liquid detergent, it is characterised in that by being prepared including following material：Sulfurous acid Sodium, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, protease, cellulose ether, APG, sulfosuccinic acid Ester, emulsifying agent and solvent.
2. micella osmosis type according to claim 1 concentrates quick liquid detergent, it is characterised in that by including following parts by weight Material be prepared：5 ~ 12 parts of sodium sulfite, 3 ~ 8 parts of sodium xylene sulfonate, 2 ~ 15 parts of ATBC, triphosphoric acid monooctyl ester 5 ~ 25 parts, 1 ~ 6 part of protease, 10 ~ 30 parts of cellulose ether, 6 ~ 18 parts of APG, 8 ~ 16 parts of sulfosuccinate, emulsifying agent 6 ~ 10 parts and 30 ~ 80 parts of solvent.
3. micella osmosis type according to claim 2 concentrates quick liquid detergent, it is characterised in that by including following parts by weight Material be prepared：6 ~ 10 parts of sodium sulfite, 4 ~ 6 parts of sodium xylene sulfonate, 3 ~ 12 parts of ATBC, triphosphoric acid monooctyl ester 8 ~ 16 parts, 2 ~ 4 parts of protease, 12 ~ 25 parts of cellulose ether, 8 ~ 15 parts of APG, 10 ~ 15 parts of sulfosuccinate, emulsifying agent 8 ~ 10 parts and 45 ~ 60 parts of solvent.
4. the micella osmosis type according to any one in claim 1 ~ 3 concentrates quick liquid detergent, it is characterised in that described Protease is at least one of cysteine proteinase, serine protease and lucid asparagus protease propylhomoserin enzyme.
5. the micella osmosis type according to any one in claim 1 ~ 3 concentrates quick liquid detergent, it is characterised in that described Cellulose ether is methyl cellulose ether, ethoxyl methyl cellulose ether, TYLOSE 30000, cellulose ether, benzyl fibre Tie up plain ether, hydroxyethyl ether cellulose, hydroxypropyl methyl cellulose ether, cyanethyl cellulose ether, benzyl cyanide cellulose ether, carboxylic At least one of methyl hydroxyethylcellulose ether and benzyl cellulose ether.
6. the micella osmosis type according to any one in claim 1 ~ 3 concentrates quick liquid detergent, it is characterised in that described Emulsifying agent is coconut acid diethanolamide, cocinic acid formicester diglycollic amide, coconut monoethanolamide, laurate list Isopropanol amide, Stearic acid diethanolamine salt, stearic acid methyl ester diglycollic amide, stearic acid monoethanolamide, oleic acid diethanol At least one of acid amides, oleic acid formicester diglycollic amide, myristic acid single ethanol amide.
7. the micella osmosis type according to any one in claim 1 ~ 3 concentrates quick liquid detergent, it is characterised in that described Solvent is at least one of water, glycerine.
8. the micella osmosis type according to any one in claim 1 ~ 3 concentrates quick liquid detergent, it is characterised in that also wraps Include at least one of essence, pigment, preservative, cosolvent, inorganic salts, chelating agent, plant extraction liquid.
9. a kind of micella osmosis type according to any one in claim 1 ~ 8 concentrates the preparation method of quick liquid detergent, It is characterised in that it includes following steps：
（1）By sodium sulfite, sodium xylene sulfonate, ATBC, triphosphoric acid monooctyl ester, protease, cellulose ether in solvent In be uniformly dispersed, formed micella；
（2）To step（1）Micella in add APG, sulfosuccinate and emulsifying agent, after being well mixed, that is, obtain glue Beam osmosis type concentrates quick liquid detergent.
10. micella osmosis type according to claim 9 concentrates the preparation method of quick liquid detergent, it is characterised in that in step Suddenly（1）In, the scattered temperature is 20 ~ 45 DEG C, and jitter time is 5 ~ 30min.
CN201710704627.9A 2017-08-17 2017-08-17 A kind of micella osmosis type concentrates quick liquid detergent and preparation method Withdrawn CN107460060A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1037960A1 (en) * 1997-12-08 2000-09-27 Henkel Kommanditgesellschaft auf Aktien Shaped bodies of detergent with improved disintegration properties
CN101880606A (en) * 2009-05-07 2010-11-10 3M创新有限公司 Liquid cleaning composition with biomembrane removing function
CN103289834A (en) * 2013-05-22 2013-09-11 吴江市德佐日用化学品有限公司 Sterilizing non-phosphorus washing powder
CN103351956A (en) * 2013-07-01 2013-10-16 陈后前 Eider down cleaning and caring agent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1037960A1 (en) * 1997-12-08 2000-09-27 Henkel Kommanditgesellschaft auf Aktien Shaped bodies of detergent with improved disintegration properties
CN101880606A (en) * 2009-05-07 2010-11-10 3M创新有限公司 Liquid cleaning composition with biomembrane removing function
CN103289834A (en) * 2013-05-22 2013-09-11 吴江市德佐日用化学品有限公司 Sterilizing non-phosphorus washing powder
CN103351956A (en) * 2013-07-01 2013-10-16 陈后前 Eider down cleaning and caring agent and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
汪多仁: "《精细化工品实用生产技术手册：增塑剂化学品生产配方和合成工艺》", 31 August 1999, 科学技术文献出版社 *

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