CN107459865A - One kind printing reverse gloss oil ink of UV and preparation method thereof - Google Patents
One kind printing reverse gloss oil ink of UV and preparation method thereof Download PDFInfo
- Publication number
- CN107459865A CN107459865A CN201710673795.6A CN201710673795A CN107459865A CN 107459865 A CN107459865 A CN 107459865A CN 201710673795 A CN201710673795 A CN 201710673795A CN 107459865 A CN107459865 A CN 107459865A
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- reverse
- printing
- oil
- gloss oil
- ink
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- 230000002441 reversible effect Effects 0.000 title claims abstract description 77
- 238000007639 printing Methods 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000003921 oil Substances 0.000 claims abstract description 79
- 239000002199 base oil Substances 0.000 claims abstract description 35
- 230000000694 effects Effects 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000003085 diluting agent Substances 0.000 claims abstract description 12
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 7
- 206010034972 Photosensitivity reaction Diseases 0.000 claims abstract description 6
- 230000036211 photosensitivity Effects 0.000 claims abstract description 6
- 239000003999 initiator Substances 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 12
- 229910052737 gold Inorganic materials 0.000 claims description 12
- 239000010931 gold Substances 0.000 claims description 12
- 229910052709 silver Inorganic materials 0.000 claims description 12
- 239000004332 silver Substances 0.000 claims description 12
- 239000011087 paperboard Substances 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- 238000007711 solidification Methods 0.000 claims description 6
- 230000008023 solidification Effects 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical class C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 4
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 238000003854 Surface Print Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- WXPWZZHELZEVPO-UHFFFAOYSA-N (4-methylphenyl)-phenylmethanone Chemical class C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 WXPWZZHELZEVPO-UHFFFAOYSA-N 0.000 claims description 2
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 2
- QNJVYPYNVCLCBU-UHFFFAOYSA-N CCOP(=O)C(=O)c1c(C)cc(C)cc1C Chemical class CCOP(=O)C(=O)c1c(C)cc(C)cc1C QNJVYPYNVCLCBU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004258 Ethoxyquin Substances 0.000 claims description 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 claims description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 claims description 2
- 229940093500 ethoxyquin Drugs 0.000 claims description 2
- 235000019285 ethoxyquin Nutrition 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical class OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 229920001187 thermosetting polymer Polymers 0.000 claims description 2
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims 1
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical class C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 claims 1
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims 1
- -1 benzene Carbamoyl benzoate methyl esters Chemical group 0.000 claims 1
- LKFAPHHHWRMPGC-UHFFFAOYSA-N butan-1-ol prop-2-enoic acid Chemical compound CCCCO.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C LKFAPHHHWRMPGC-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000007046 ethoxylation reaction Methods 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 230000002262 irrigation Effects 0.000 abstract 1
- 238000003973 irrigation Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 239000004576 sand Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007717 exclusion Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 206010067171 Regurgitation Diseases 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003027 oil sand Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- NQSMEZJWJJVYOI-UHFFFAOYSA-N Methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 NQSMEZJWJJVYOI-UHFFFAOYSA-N 0.000 description 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Natural products C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Printing Methods (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses one kind printing reverse gloss oil ink of UV and preparation method thereof, it is made up of reverse base oil and reverse face oil, its drip irrigation device is to include the component of following parts by weight：The reverse base oil includes following components by weight percent：45 80 parts of UV-cured resin A, 10 25 parts of property diluent A, 59 parts of initiator A, 26 parts of filler A, 35 parts of auxiliary agent A；The reverse face oil includes following components by weight percent：30 55 parts of 30 42 parts of UV-cured resin B, reactive diluent B, 8 15 parts of photosensitivity promotor B, 5 10 parts of photoinitiator b, 01 parts of auxiliary agent B.It is an object of the invention to provide one kind printing reverse gloss oil ink of UV, reacts on surface by cohesion and produces frosting effect.
Description
【Technical field】
The invention belongs to printing-ink field, and in particular to one kind printing reverse gloss oil ink of UV and preparation method thereof.
【Background technology】
UV glazing ink refers in the case where ultraviolet irradiates, and is connected gloss oil ink with the ultraviolet light of energy using different wave length
Monomer in material aggregates into polymer.Because UV gloss oil has without volatile solvent, odorless, non-stimulated, curing rate is fast,
The features such as cured film is tough and tensile, solvent resistant and be widely used in print field.UV printing varnish species is various, generally there is UV offset printing light
Oil, UV silk-screen printings gloss oil, UV intaglio printings gloss oil, UV flexographic printing gloss oil etc., and the reverse glazing ink of UV is by reverse
Base oil and inversely upper smooth surface oil combined printing, the reverse glazing ink of UV is mainly the printing of reverse effect, and it is mainly used in respectively
On eka-gold silver foil printed matter, all kinds of high-grade packing boxes, decoration painting, high-grade label etc. can be produced, is that high-grade printing is led in recent years
The research emphasis in domain.
【The content of the invention】
It is an object of the invention to provide one kind printing reverse gloss oil ink of UV.
It is a further object of the present invention to provide a kind of preparation method printed with the reverse gloss oil ink of UV.
One kind printing reverse gloss oil ink of UV, is made up of reverse base oil and reverse face oil, includes the group of following parts by weight
Point：
The reverse base oil includes following components by weight percent：
The reverse face oil includes following components by weight percent：
Preferably, the UV-cured resin A is obtained by thermosetting hard resin and polyester acrylate mixed dissolution.
Epoxy acrylic resin and multifunctional urethane acrylate curing rate are fast.
Preferably, the reactive diluent A is glycerol propoxylate triacrylate (G3.5POTA), 2- Phenoxyethyls third
One or more mixing in olefin(e) acid ester, 1,6- hexylene glycols double methacrylate, the acrylate of dipentaerythritol five/six (DPHA)
Thing.
Preferably, the light trigger A is methyl o-benzoylbenzoate (OMBB), 2,4- diethyl thioxanthones
(DETX), one kind in 2- methyl isophthalic acids-(4- methyl mercaptos phenyl) -2- morpholine -1- acetone (907), 4- methyl benzophenones (MBP)
Or a variety of mixtures.
Preferably, the filler A is the mixture of light magnesium carbonate, wax powder and both-end hydroxy polyethers modified silicon oil, described
Auxiliary agent A is defoamer and levelling agent.Described defoamer in BYK-034, BYK-035, BYK-037, BYK-038 one
Kind, the levelling agent is one kind in dimethyl silicone polymer, PSI, acrylate, when base oil and face oil
After printing, both institute's contact areas are because of component generation cohesion reaction in filler A and face oil, and produce mutual exclusion and form transparent small
Grain, shows pitted skin frosted finish effect.
Preferably, the UV-cured resin B is modified epoxy acrylate resin and multifunctional urethane acrylate
Mix.The region of no face oil contact at base oil covering, because UV-cured resin B forms the mirror effect of high glaze.
Preferably, the reactive diluent B be propylene glycol diacrylate (DPGDA), two contracting propane diols pair acrylic acid
Ester, double pentaerythritol C5 methacrylate, ethoxylated trimethylolpropane triacrylate and ethoxyquin trimethylolpropane tris
One or more mixtures in acrylate (TMP3EOTA).
Preferably, the photoinitiator b is 2,4- diethyl thioxanthones (DETX), 1- hydroxycyclohexyl phenyl ketones
(184) one or more mixtures in, 2,4,6- trimethylbenzoyl phosphinic acid ethyl esters (TPO), the photosensitivity promotor are
One or more mixtures in special tertiary amine acrylate and response type tertiary amine aided initiating.
A kind of preparation method printed with the reverse gloss oil ink of UV, comprises the following steps：
(1) UV-cured resin A, reactive diluent A, light trigger A, filler A and auxiliary agent A are mixed and stirred in proportion
Mix uniformly, obtain just mixed thing A；
(2) first mixed thing A is ground 2-3 times with three-roller, it is 5 below μ to be ground to fineness, and the UV for producing the present invention is inverse
To gloss oil base oil ink, the reverse gloss oil base oil ink of UV obtained is ecru opaque fluid；
(3) in proportion UV-cured resin B, reactive diluent B, photosensitivity promotor B are mixed and stirred for uniformly, obtaining
Just mixed thing B；
(4) added after photoinitiator b being heated into abundant dissolving in just mixed thing B, add auxiliary agent B and disperse 40 minutes, produce
The reverse gloss oil face oil ink of UV of the present invention, the reverse gloss oil face oil ink of UV obtained is light yellow clear fluid.
A kind of typography of the reverse gloss oil of gold and silver paperboard printing UV, comprises the following steps：
(1) it is PET light gold and silver paperboards, to select ground, it is desirable to dyne value on PET light gold and silver cards surface will reach 38,
And surfacing, with offset press PS versions in the reverse base oils of paperboard surface printing UV, and pass through UV ultraviolet light dry solidifications；
(2) the reverse face oil of UV, is carried out by full version coating by last group of font of offset press again, afterwards by UV ultraviolet lights
Dry solidification；
(3) highlighted bloom effect is presented in the region for, not printing base oil, and pitted skin mill is presented in base oil and the overlapping printing zone of face oil
Sand effect.
Compared with prior art, the invention has the advantages that and advantage：
1) a kind of, printing reverse gloss oil ink of UV of the invention, UV-cured resin and auxiliary agent ratio during adjustment is formulated
Example, the reverse base oils of the UV is had excellent printing adaptability, and the epoxy acrylic of smooth surface oil is inversely gone up with reference to the UV
The advantages of resin and fast multifunctional urethane acrylate curing rate, make both print after institute contact area produce mutual exclusion and
Transparent little particle is formed, shows pitted skin frosted finish effect, and non-contact area then shows the mirror effect of high glaze, is tradition
Milled sand varnish ink institute it is irrealizable；
2) a kind of, printing reverse gloss oil ink of UV of the invention, does not add the PVC sand face in traditional frosted ink
Powder, it is to make both contact areas produce mutual exclusion using reverse typography to realize frosted finish effect, and non-contacting light region, tool
There is preferable tack, continuous printing demand can be met, printing efficiency is high, in material surface good fluidity, is not cracked, firmly
Degree can reach what more than 3H, either traditional UV oil polishes, or water lustering oil can not all meet；
3) a kind of, printing reverse gloss oil ink of UV of the invention, its glazing process and existing line printing coating technology
Compare, the position by the printing of reverse base oil is not glossy, and the place by the printing of reverse base oil is due to base oil and oil polish
Incompatible principle and cause rough effect, such as the little particle of transparent frosted finish effect so as to cause effect contrast, makes to hold
Printing expressive force can be had more by printing thing, and image effect is suitable for printing technology extensively, save process, cost-effective, value
Printing industry is obtained to promote；
4) a kind of, printing reverse gloss oil ink preparation methods of UV of the invention, technique is simple, easy to operate, and cost is low
And can realize while line print production, being capable of high efficiency large-scale industrial production；
5) a kind of, production method of printing plate of reverse gloss oil of gold and silver paperboard printing UV of the invention, can by print speed come
The thickness in sand face is controlled, the fast texture of speed is thick, and then texture is thin slowly for speed, can also pass through base oil and the upper fuel volume adjusting paint of face oil
The thickness degree of film controls the thickness in sand face, and thinner frosted particle diameter is thicker otherwise thinner, can use just reverse and regurgitation to technique
Printing, so-called just inversely to refer to carry out line printing on 5+1,6+1 or 7+1UV printing machine, regurgitation is offline to then referring to
Printing, offline printing refer to the printed matter for printing color ink be first coating it is reverse on smooth surface oil, republish reverse base oil, draw
Equal printing effect.
【Embodiment】
Further illustrate that one kind of the present invention prints reverse gloss oil ink in conjunction with specific embodiments：
Table 1：Embodiment 1-4 each components weight forms
(1) UV-cured resin A, reactive diluent A, light trigger A, filler A and auxiliary agent A are mixed and stirred in proportion
Mix uniformly, obtain just mixed thing A；
(2) first mixed thing A is ground 2-3 times with three-roller, it is 5 below μ to be ground to fineness, and the UV for producing the present invention is inverse
To gloss oil base oil ink, the reverse gloss oil base oil ink of UV obtained is ecru opaque fluid；
(3) in proportion UV-cured resin B, reactive diluent B, photosensitivity promotor B are mixed and stirred for uniformly, obtaining
Just mixed thing B；
(4) added after photoinitiator b being heated into abundant dissolving in just mixed thing B, add auxiliary agent B and disperse 40 minutes, produce
The reverse gloss oil face oil ink of UV of the present invention, the reverse gloss oil face oil ink of UV obtained is light yellow clear fluid.
A kind of typography of reverse gloss oil of gold and silver paperboard printing UV of the present invention, comprises the following steps：
(1) it is PET light gold and silver paperboards, to select ground, it is desirable to dyne value on PET light gold and silver cards surface will reach 38,
And surfacing, with offset press PS versions in the reverse base oils of paperboard surface printing UV, and pass through UV ultraviolet light dry solidifications；
(2) the reverse face oil of UV, is carried out by full version coating by last group of font of offset press again, afterwards by UV ultraviolet lights
Dry solidification；
(3) highlighted bloom effect is presented in the region for, not printing base oil, and pitted skin mill is presented in base oil and the overlapping printing zone of face oil
Sand effect.
Base oil and face oil, are successively printed on stock by a kind of printing reverse gloss oil ink of UV of the present invention, both
Overlapping region forms uniform frosting, and third dimension is strong, and can by control print speed printing speed control frosted granular size spacing, and
Only brushing base oil region, surface are highlighted highlight area, and printing efficiency is high, and surface effect is good.
A kind of printing reverse gloss oil ink of UV of the present invention, is to be made using reverse glazing process on same printed matter simultaneously
The highlighted light effect of minute surface and transparent pitted skin frosted finish effect be present, the reverse glazing ink of UV uses reverse base oil and reverse glazing
Face oil is constructed on all kinds of gold and silver paperboard printed matters, and precondition is that gold and silver card printing product must print color ink through UV
After illumination curing, reverse base oil and the print of reverse upper smooth surface oil are then carried out using line or offline reverse typography
Brush, make reverse base oil and inversely upper smooth surface oil contact area produces cohesion reaction and forms the ink film of fine granularity, show
Bright pitted skin frosted finish effect, non-contact area then form the mirror effect of high glaze, and generally speaking, reverse glazing solves commonly
Key issue present in glazing process, and the contrast effect that common oil polish is not accomplished can be reached, imitate the printing of printed matter
Fruit distinctness is beautiful, it is more exquisite, make packaging external appearance more bright and glittering.
Claims (10)
1. one kind printing reverse gloss oil ink of UV, is made up of reverse base oil and reverse face oil, it is characterised in that：Including following heavy
Measure the component of part：
The reverse base oil includes following components by weight percent：
The reverse face oil includes following components by weight percent：
A kind of 2. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that：The UV-cured resin A
Obtained by thermosetting hard resin and polyester acrylate mixed dissolution.
A kind of 3. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that：The reactive diluent A is third
Aoxidize glycerol tri-acrylate (G3.5POTA), 2- phenoxyethyl acrylates, 1,6- hexylene glycols double methacrylate, two seasons penta
One or more mixtures in the acrylate of tetrol five/six (DPHA).
A kind of 4. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that：The light trigger A is adjacent benzene
Carbamoyl benzoate methyl esters (OMBB), 2,4- diethyl thioxanthones (DETX), 2- methyl isophthalic acids-(4- methyl mercaptos phenyl) -2- morpholines -
One or more mixtures in 1- acetone (907), 4- methyl benzophenones (MBP).
A kind of 5. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that：The filler A is lightweight carbonic acid
The mixture of magnesium, wax powder and both-end hydroxy polyethers modified silicon oil, the auxiliary agent A are defoamer and levelling agent.
A kind of 6. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that：The UV-cured resin B
For modified epoxy acrylate resin and multifunctional urethane acrylate mixture.
A kind of 7. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that：The reactive diluent B is two
Propylene glycol diacrylate (DPGDA), two contracting propane diols double methacrylates, double pentaerythritol C5 methacrylate, ethoxylation three
One or more in hydroxymethyl-propane triacrylate and ethoxyquin trimethylolpropane trimethacrylate (TMP3EOTA) are mixed
Compound.
A kind of 8. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that：The photoinitiator b is 2,4-
Diethyl thioxanthone (DETX), 1- hydroxycyclohexyl phenyl ketones (184), 2,4,6- trimethylbenzoyl phosphinic acid ethyl esters
(TPO) one or more mixtures in, the photosensitivity promotor B are that special tertiary amine acrylate and response type tertiary amine help
One or more mixtures in initiator.
9. a kind of preparation method printed with the reverse gloss oil ink of UV, it is characterised in that comprise the following steps：
(1), UV-cured resin A, reactive diluent A, light trigger A, filler A and auxiliary agent A are mixed and stirred in proportion
Uniformly, just mixed thing A is obtained；
(2), first mixed thing A is ground 2-3 times with three-roller, it is 5 below μ to be ground to fineness, and the UV for producing the present invention is reverse
Gloss oil base oil ink, the reverse gloss oil base oil ink of UV obtained are ecru opaque fluid；
(3), in proportion UV-cured resin B, reactive diluent B, photosensitivity promotor B are mixed and stirred for uniformly, obtaining just
Mixed thing B；
(4) added after photoinitiator b, is heated into abundant dissolving in just mixed thing B, add auxiliary agent B and disperse 40 minutes, produce this hair
The reverse gloss oil face oil ink of bright UV, the reverse gloss oil face oil ink of UV obtained are light yellow clear fluid.
10. a kind of typography of the reverse gloss oil of gold and silver paperboard printing UV, it is characterised in that comprise the following steps：
(1) it is PET light gold and silver paperboards, to select ground, it is desirable to which dyne value on PET light gold and silver cards surface will reach 38, and table
Face is smooth, with offset press PS versions in the reverse base oils of paperboard surface printing UV, and passes through UV ultraviolet light dry solidifications；
(2) the reverse face oil of UV, is carried out by full version coating by last group of font of offset press again, dried afterwards by UV ultraviolet lights
Solidification；
(3) highlighted bloom effect is presented in the region for, not printing base oil, and pitted skin frosted effect is presented in base oil and the overlapping printing zone of face oil
Fruit.
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| CN201710673795.6A CN107459865A (en) | 2017-08-09 | 2017-08-09 | One kind printing reverse gloss oil ink of UV and preparation method thereof |
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| CN108070293A (en) * | 2018-02-05 | 2018-05-25 | 浙江美浓材料科技有限公司 | A kind of reverse light ink and preparation method thereof |
| CN108587309A (en) * | 2018-07-26 | 2018-09-28 | 惠州市至上新材料有限公司 | With the big online reverse ink of gravure UV in gold and silver cardboard material |
| CN109263324A (en) * | 2018-09-05 | 2019-01-25 | 河南省防伪保密印刷公司（河南省邮电印刷厂） | A kind of processing technology of reverse glazing |
| CN109278435A (en) * | 2018-09-10 | 2019-01-29 | 河南省防伪保密印刷公司（河南省邮电印刷厂） | A kind of environmental protection sense of touch oil glazing process |
| CN110183898A (en) * | 2019-05-08 | 2019-08-30 | 广州市帝天印刷材料有限公司 | A kind of production method of the reverse frosting technology of UV |
| CN110217008A (en) * | 2019-06-23 | 2019-09-10 | 贵州西牛王印务有限公司 | A kind of method of gift package surface light and dumb light combined printing |
| CN110228306A (en) * | 2019-06-29 | 2019-09-13 | 青岛红杉包装有限公司 | The reverse frosted printing technology of packing box |
| CN110303783A (en) * | 2019-07-06 | 2019-10-08 | 陆良福牌彩印有限公司 | A kind of reverse gloss oil printing packaging paper of UV meets the technology of high speed auto packer adaptability |
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| CN110920284A (en) * | 2019-11-25 | 2020-03-27 | 东莞市信彩包装有限公司 | Printing method for mimeograph matte texture |
| CN111662632A (en) * | 2020-05-20 | 2020-09-15 | 中牟县美林包装有限责任公司 | Local reverse UV printing method for packaging box |
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| CN113263848A (en) * | 2021-05-10 | 2021-08-17 | 余冲 | Gloss oil frosted hollow printing process |
| CN115627098A (en) * | 2022-10-20 | 2023-01-20 | 湖北中烟工业有限责任公司 | Reverse UV ink for cigarette packaging paper and printing process thereof |
| CN115742594A (en) * | 2022-11-25 | 2023-03-07 | 湖南裕同印刷包装有限公司 | Fine decoration texture printing process based on UV offset printing lettering oil |
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| CN116855128A (en) * | 2023-07-12 | 2023-10-10 | 云南侨通包装印刷有限公司 | Offset printing coating dermatoglyph effect ink and preparation method and use method thereof |
| CN116970303A (en) * | 2023-07-18 | 2023-10-31 | 天津宜药印务有限公司 | Sand dyeing gloss oil and printing process |
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| CN108070293A (en) * | 2018-02-05 | 2018-05-25 | 浙江美浓材料科技有限公司 | A kind of reverse light ink and preparation method thereof |
| CN108587309A (en) * | 2018-07-26 | 2018-09-28 | 惠州市至上新材料有限公司 | With the big online reverse ink of gravure UV in gold and silver cardboard material |
| CN109263324A (en) * | 2018-09-05 | 2019-01-25 | 河南省防伪保密印刷公司（河南省邮电印刷厂） | A kind of processing technology of reverse glazing |
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| CN110183898A (en) * | 2019-05-08 | 2019-08-30 | 广州市帝天印刷材料有限公司 | A kind of production method of the reverse frosting technology of UV |
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| CN110217008A (en) * | 2019-06-23 | 2019-09-10 | 贵州西牛王印务有限公司 | A kind of method of gift package surface light and dumb light combined printing |
| CN110228306A (en) * | 2019-06-29 | 2019-09-13 | 青岛红杉包装有限公司 | The reverse frosted printing technology of packing box |
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| CN110920284A (en) * | 2019-11-25 | 2020-03-27 | 东莞市信彩包装有限公司 | Printing method for mimeograph matte texture |
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| CN111942042A (en) * | 2020-08-26 | 2020-11-17 | 重庆宏劲印务有限责任公司 | Method for printing 3D effect refraction pattern by using flexography process |
| CN113263848A (en) * | 2021-05-10 | 2021-08-17 | 余冲 | Gloss oil frosted hollow printing process |
| CN116640470A (en) * | 2022-02-15 | 2023-08-25 | 深圳有为技术控股集团有限公司 | Preparation and application of a kind of LED-UV reverse varnish |
| CN115627098A (en) * | 2022-10-20 | 2023-01-20 | 湖北中烟工业有限责任公司 | Reverse UV ink for cigarette packaging paper and printing process thereof |
| CN115627098B (en) * | 2022-10-20 | 2024-05-10 | 湖北中烟工业有限责任公司 | Reverse UV ink for cigarette packaging paper and printing process thereof |
| CN115742594A (en) * | 2022-11-25 | 2023-03-07 | 湖南裕同印刷包装有限公司 | Fine decoration texture printing process based on UV offset printing lettering oil |
| CN116855128A (en) * | 2023-07-12 | 2023-10-10 | 云南侨通包装印刷有限公司 | Offset printing coating dermatoglyph effect ink and preparation method and use method thereof |
| CN116970303A (en) * | 2023-07-18 | 2023-10-31 | 天津宜药印务有限公司 | Sand dyeing gloss oil and printing process |
| CN116970303B (en) * | 2023-07-18 | 2024-05-10 | 天津宜药印务有限公司 | Sand dyeing gloss oil and printing process |
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Application publication date: 20171212 |