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CN107445424B - Device for realizing high-efficiency reduction and recycling of organic waste through thermocatalysis - Google Patents

Device for realizing high-efficiency reduction and recycling of organic waste through thermocatalysis Download PDF

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CN107445424B
CN107445424B CN201710666497.4A CN201710666497A CN107445424B CN 107445424 B CN107445424 B CN 107445424B CN 201710666497 A CN201710666497 A CN 201710666497A CN 107445424 B CN107445424 B CN 107445424B
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薛罡
甘雁飞
李响
陈红
张文启
叶婷婷
游继光
李君�
来思周
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
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    • B01D53/34Chemical or biological purification of waste gases
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Abstract

本发明提供了一种实现有机废物热催化高效减量及资源化的装置,有机废物进料系统连接配料釜物料进口,配料釜物料出口连接预反应釜、主反应釜物料进口,预反应釜物料出口连接主反应釜物料进口,主反应釜物料出口连接冷却釜物料进口,冷却釜物料出口连接固液分离系统;固液分离系统的部分液体出口连接水处理系统,水处理系统液体出口分别连接配料釜、预反应釜和主反应釜物料进口;主反应釜的夹套与热源系统连接;主反应釜的蒸汽出口连接配料釜和预反应釜蒸汽进口,冷却釜的蒸汽出口连接配料釜蒸汽进口;配料釜的冷却水进、出水口与冷却釜的冷却水出、进水口相连接。本发明有机废物减量效果良好,催化剂可回收利用,反应后固体产物可被资源化利用。

Figure 201710666497

The invention provides a device for realizing high-efficiency reduction and resource utilization of organic wastes by thermal catalysis. The organic waste feeding system is connected to the material inlet of the batching kettle, the material outlet of the batching kettle is connected to the pre-reaction kettle, the material inlet of the main reaction kettle, and the material of the pre-reaction kettle is connected. The outlet is connected to the material inlet of the main reaction kettle, the material outlet of the main reaction kettle is connected to the material inlet of the cooling kettle, and the material outlet of the cooling kettle is connected to the solid-liquid separation system; part of the liquid outlet of the solid-liquid separation system is connected to the water treatment system, and the liquid outlet of the water treatment system is connected to the ingredients respectively The material inlet of the kettle, the pre-reaction kettle and the main reaction kettle; the jacket of the main reaction kettle is connected to the heat source system; the steam outlet of the main reaction kettle is connected to the steam inlet of the batching kettle and the pre-reaction kettle, and the steam outlet of the cooling kettle is connected to the steam inlet of the batching kettle; The cooling water inlet and outlet of the batching kettle are connected with the cooling water outlet and inlet of the cooling kettle. The organic waste reduction effect of the invention is good, the catalyst can be recycled, and the solid product after the reaction can be used as a resource.

Figure 201710666497

Description

一种实现有机废物热催化高效减量及资源化的装置A device for realizing efficient thermal catalysis reduction and resource utilization of organic waste

技术领域technical field

本发明属于有机废物处理技术领域,尤其涉及一种通过热催化反应提高有机废物减量效果的装置。The invention belongs to the technical field of organic waste treatment, and in particular relates to a device for improving the reduction effect of organic waste through thermal catalytic reaction.

背景技术Background technique

有机废物是指高含水率(40%-99%)的有机质成分占无机成分大于30%的废物污泥,比如餐厨垃圾、喷涂行业有机废渣、有机高沸残液、医药合成废渣及污水处理厂产生的剩余污泥等。随着社会经济的快速发展,有机废物产生量越来越多(戴前进,方先金,黄鸥等.有机废物处理处置技术与产气利用前景[J].中国沼气,2008,26(6):17-32.),因此,有机废物减量已成为我国节能减排的重要问题。Organic waste refers to waste sludge with a high moisture content (40%-99%) whose organic content accounts for more than 30% of the inorganic content, such as kitchen waste, organic waste residues in the spraying industry, organic high-boiling residues, pharmaceutical synthesis wastes and sewage treatment Excess sludge produced by the plant, etc. With the rapid development of society and economy, more and more organic wastes are produced (Dai Qianjin, Fang Xianjin, Huang Ou, etc. Organic Waste Treatment and Disposal Technology and Prospect of Gas Production and Utilization [J]. China Biogas, 2008, 26(6): 17-32.), therefore, the reduction of organic waste has become an important issue of energy conservation and emission reduction in my country.

目前,有机废物主要通过焚烧、填埋等方式进行处置。At present, organic waste is mainly disposed of through incineration, landfill and other methods.

其中,焚烧是最有效、最彻底的有机废物处置方法,可实现极高的有机废物减量效果,但是焚烧处理的成本较高,并且有可能会产生二噁英等有毒有害气体,给环境带来二次污染(于强.化工固体废弃物焚烧处理及其参考数据分析[J].化学工业,2013,31(7):42-47.)。Among them, incineration is the most effective and thorough organic waste disposal method, which can achieve extremely high organic waste reduction effect. secondary pollution (Yu Qiang. Chemical solid waste incineration and its reference data analysis [J]. Chemical Industry, 2013, 31(7): 42-47.).

填埋是将有机废物运送至特定的填埋场进行填埋处置,该方法操作简单,处理费用较低,但是如果填埋的防渗技术不达标,土壤和地下水将受到巨大危害,还可能会有有毒气体扩散至大气中,造成二次污染。另外,填埋处置要求土地面积大,对于土地资源紧缺的地方,不适合采用这种有机废物处置方法(周涛,陈军.城市环境的大问题:污水处理厂处置浅析[J].环境保护科学,1998,24(6):11-12.)。Landfilling is to transport organic waste to a specific landfill for landfill disposal. This method is simple to operate and has low treatment costs. However, if the anti-seepage technology of the landfill is not up to standard, the soil and groundwater will be greatly harmed, and it may also be damaged. There are toxic gases diffused into the atmosphere, causing secondary pollution. In addition, landfill disposal requires a large area of land, and this method of organic waste disposal is not suitable for places where land resources are scarce (Zhou Tao, Chen Jun. Big Problems in Urban Environment: Analysis of Wastewater Treatment Plant Disposal [J]. Environmental Protection Science, 1998, 24(6):11-12.).

发明内容SUMMARY OF THE INVENTION

本发明要解决的技术问题是提供一种有机废物减量效果良好,催化剂可回收利用,能耗节省明显,反应后产物可被资源化利用,不会造成环境二次污染的装置。The technical problem to be solved by the present invention is to provide a device with good organic waste reduction effect, recyclable catalyst, obvious energy saving and resource utilization after reaction, without causing secondary pollution to the environment.

为了解决上述技术问题,本发明的技术方案是提供一种实现有机废物热催化高效减量及资源化的装置,其特征在于:包括配料釜,有机废物进料系统通过管道连接配料釜物料进口,配料釜物料出口通过管道分别连接预反应釜物料进口和主反应釜物料进口,预反应釜物料出口通过管道连接主反应釜物料进口,主反应釜物料出口通过管道连接冷却釜物料进口,冷却釜物料出口通过管道连接固液分离系统;固液分离系统的部分液体出口通过管道连接水处理系统,水处理系统液体出口通过管道分别连接配料釜物料进口、预反应釜物料进口和主反应釜物料进口;In order to solve the above-mentioned technical problems, the technical solution of the present invention is to provide a device for realizing high-efficiency reduction and recycling of organic wastes by thermal catalysis, which is characterized in that: it includes a batching kettle, and the organic waste feeding system is connected to the material inlet of the batching kettle through a pipeline, The material outlet of the batching kettle is connected to the material inlet of the pre-reaction kettle and the material inlet of the main reaction kettle respectively through pipes, the material outlet of the pre-reaction kettle is connected to the material inlet of the main reaction kettle through a pipeline, and the material outlet of the main reaction kettle is connected to the material inlet of the cooling kettle through a pipeline. The outlet is connected to the solid-liquid separation system through a pipeline; part of the liquid outlet of the solid-liquid separation system is connected to the water treatment system through a pipeline, and the liquid outlet of the water treatment system is connected to the material inlet of the batching kettle, the material inlet of the pre-reaction kettle and the material inlet of the main reaction kettle respectively through the pipeline;

主反应釜的夹套进口与热源系统的出口相连接,热源系统的进口与主反应釜的夹套出口相连接;The jacket inlet of the main reactor is connected with the outlet of the heat source system, and the inlet of the heat source system is connected with the jacket outlet of the main reactor;

主反应釜的蒸汽出口通过管道连接配料釜蒸汽进口和预反应釜蒸汽进口,冷却釜的蒸汽出口通过管道连接配料釜蒸汽进口,配料釜的不凝气出口通过管道连接VOCs处理系统;The steam outlet of the main reactor is connected to the steam inlet of the batching kettle and the steam inlet of the pre-reaction kettle through a pipeline, the steam outlet of the cooling kettle is connected to the steam inlet of the batching kettle through a pipeline, and the non-condensable gas outlet of the batching kettle is connected to the VOCs treatment system through a pipeline;

配料釜的冷却水出口与冷却釜的冷却水进口相连接,冷却釜的冷却水出口与配料釜的冷却水进口相连接,组成冷却水循环系统。The cooling water outlet of the batching kettle is connected with the cooling water inlet of the cooling kettle, and the cooling water outlet of the cooling kettle is connected with the cooling water inlet of the batching kettle to form a cooling water circulation system.

优选地,所述配料釜、预反应釜、主反应釜和冷却釜构成主反应系统,所述有机废物进料系统、热源系统、固液分离系统、水处理系统和VOCs处理系统构成附属反应系统。Preferably, the batching kettle, the pre-reaction kettle, the main reaction kettle and the cooling kettle constitute the main reaction system, and the organic waste feeding system, the heat source system, the solid-liquid separation system, the water treatment system and the VOCs treatment system constitute the auxiliary reaction system .

优选地,所述配料釜物料出口与预反应釜物料进口之间的管道上设有第一阀门、第二阀门和第一泵;所述配料釜物料出口与主反应釜物料进口之间的管道上设有第一阀门、第三阀门和第一泵;Preferably, the pipeline between the material outlet of the batching kettle and the material inlet of the pre-reaction kettle is provided with a first valve, a second valve and a first pump; the pipeline between the material outlet of the batching kettle and the material inlet of the main reactor is provided with a first valve, a second valve and a first pump; There is a first valve, a third valve and a first pump on it;

所述预反应釜物料出口与主反应釜物料进口之间的管道上设有第四阀门和第二泵;所述主反应釜物料出口与冷却釜物料进口之间的管道上设有第五阀门和第三泵;所述冷却釜物料出口与固液分离系统之间的管道上设有第六阀门和第四泵;A fourth valve and a second pump are arranged on the pipeline between the material outlet of the pre-reaction kettle and the material inlet of the main reactor; a fifth valve is arranged on the pipeline between the material outlet of the main reactor and the material inlet of the cooling kettle and the third pump; a sixth valve and a fourth pump are arranged on the pipeline between the material outlet of the cooling kettle and the solid-liquid separation system;

所述水处理系统液体出口与配料釜物料进口之间的管道上设有第五泵和第七阀门;所述水处理系统液体出口与预反应釜物料进口之间的管道上设有第五泵和第八阀门;所述水处理系统液体出口与主反应釜物料进口之间的管道上设有第五泵和第九阀门;A fifth pump and a seventh valve are arranged on the pipeline between the liquid outlet of the water treatment system and the material inlet of the batching kettle; a fifth pump is arranged on the pipeline between the liquid outlet of the water treatment system and the material inlet of the pre-reaction kettle and the eighth valve; the pipeline between the liquid outlet of the water treatment system and the material inlet of the main reactor is provided with a fifth pump and a ninth valve;

所述主反应釜的蒸汽出口与配料釜蒸汽进口之间的管道上设有第十阀门和第十一阀门;所述主反应釜的蒸汽出口与预反应釜蒸汽进口之间的管道上设有第十阀门和第十二阀门;The tenth valve and the eleventh valve are arranged on the pipeline between the steam outlet of the main reaction kettle and the steam inlet of the batching kettle; the pipeline between the steam outlet of the main reaction kettle and the steam inlet of the pre-reaction kettle is provided with The tenth valve and the twelfth valve;

所述冷却釜的蒸汽出口与配料釜蒸汽进口之间的管道上设有第十三阀门;所述配料釜的不凝气出口与VOCs处理系统之间的管道上设有第十四阀门。A thirteenth valve is arranged on the pipeline between the steam outlet of the cooling kettle and the steam inlet of the batching kettle; a fourteenth valve is arranged on the pipeline between the non-condensable gas outlet of the batching kettle and the VOCs treatment system.

更优选地,所述的第一阀门、第二阀门、第三阀门、第四阀门、第五阀门、第六阀门、第七阀门、第八阀门、第九阀门、第十阀门、第十一阀门、第十二阀门、第十三阀门、第十四阀门均为气动球阀;More preferably, the first valve, second valve, third valve, fourth valve, fifth valve, sixth valve, seventh valve, eighth valve, ninth valve, tenth valve, eleventh valve The valve, the twelfth valve, the thirteenth valve and the fourteenth valve are all pneumatic ball valves;

所述第一泵为螺杆泵;所述第二泵和第三泵均为凸轮式双转子泵;所述第四泵为气动隔膜泵;所述第五泵为潜水泵。The first pump is a screw pump; the second pump and the third pump are both cam type double rotor pumps; the fourth pump is a pneumatic diaphragm pump; and the fifth pump is a submersible pump.

优选地,所述配料釜内设有第一搅拌电机和第一冷凝盘管。Preferably, the batching kettle is provided with a first stirring motor and a first condensing coil.

所述预反应釜内设有第二搅拌电机;所述预反应釜上设有第一温度计、第一压力表和第一安全阀;The pre-reaction kettle is provided with a second stirring motor; the pre-reaction kettle is provided with a first thermometer, a first pressure gauge and a first safety valve;

所述主反应釜内设有第三搅拌电机;所述主反应釜上设有第二温度计、第二压力表、第二安全阀;所述主反应釜还连接惰性气路。The main reactor is provided with a third stirring motor; the main reactor is provided with a second thermometer, a second pressure gauge and a second safety valve; the main reactor is also connected to an inert gas path.

所述冷却釜内设有第二冷凝盘管。The cooling kettle is provided with a second condensing coil.

优选地,所述热源系统为导热油加热和蒸汽加热的一种或者两种。Preferably, the heat source system is one or both of heat-conducting oil heating and steam heating.

优选地,所述固液分离系统为离心机、叠螺机或压滤机的一种。Preferably, the solid-liquid separation system is one of a centrifuge, a screw stacker or a filter press.

优选地,所述水处理系统采用蒸发处理和膜分离工艺处理的一种或者两种;所述VOCs处理系统采用催化光解、等离子体和活性炭吸附中的一种或者多种。Preferably, the water treatment system adopts one or both of evaporation treatment and membrane separation process; the VOCs treatment system adopts one or more of catalytic photolysis, plasma and activated carbon adsorption.

优选地,所述有机废物进料系统通过螺旋输送机将有机废物和催化剂输送至配料釜内;配料釜通过搅拌电机将有机废物与催化剂混合搅拌均匀,并将搅拌均匀后的部分物料输送至主反应釜、部分物料输送至预反应釜;开启热源系统,给主反应釜升温加热反应;反应结束后,关闭热源系统,开始闪蒸;闪蒸结束后,开启配料釜和冷却釜之间的冷却水循环系统,并卸料;第一批物料反应结束;将预反应釜内物料输送至主反应釜,开始第二批物料反应;Preferably, the organic waste feeding system transports the organic waste and the catalyst into the batching kettle through a screw conveyor; the batching kettle mixes and stirs the organic waste and the catalyst uniformly through a stirring motor, and transports part of the uniformly stirred material to the main The reaction kettle and some materials are transported to the pre-reaction kettle; the heat source system is turned on, and the main reaction kettle is heated and reacted; after the reaction is completed, the heat source system is turned off and flash evaporation is started; after the flash evaporation, the cooling between the batching kettle and the cooling kettle is turned on water circulation system, and unloading; the first batch of material reaction ends; the material in the pre-reaction kettle is transported to the main reaction kettle, and the second batch of material reaction is started;

通过VOCs处理系统将配料釜内残余的气体进行处理,冷却釜内反应后的混合物进入固液分离系统进行脱水;脱水完毕后,将部分脱水液回流至水处理系统进行处理;处理结束后,将处理后的脱水液分别回流至主反应釜、预反应釜和配料釜,从而实现催化剂的回收利用,还能冲洗釜壁;剩余的脱水液排入废水处理厂,固体泥饼用作燃料或吸附材料。The residual gas in the batching kettle is treated by the VOCs treatment system, and the reacted mixture in the cooling kettle enters the solid-liquid separation system for dehydration; after the dehydration is completed, part of the dehydration liquid is returned to the water treatment system for treatment; after the treatment, the The treated dehydration liquid is returned to the main reaction kettle, pre-reaction kettle and batching kettle respectively, so as to realize the recovery and utilization of the catalyst, and can also wash the wall of the kettle; the remaining dehydration liquid is discharged into the wastewater treatment plant, and the solid mud cake is used as fuel or adsorption. Material.

更优选地,所述催化剂为按如下质量百分比配置而成的有机催化剂:草酸0.5%-10%、乙酸1%-15%、丙酸15%-50%、乳酸15%-40%、柠檬酸10%-55%,溶剂为水。More preferably, the catalyst is an organic catalyst configured according to the following mass percentages: 0.5%-10% of oxalic acid, 1%-15% of acetic acid, 15%-50% of propionic acid, 15%-40% of lactic acid, citric acid 10%-55%, the solvent is water.

相比现有技术,本发明提供的实现有机废物热催化高效减量及资源化的装置具有如下有益效果:Compared with the prior art, the device for realizing efficient thermal catalysis reduction and recycling of organic wastes provided by the present invention has the following beneficial effects:

(1)该热催化减量装置为撬装一体化设备,便于管理和操作。(1) The thermal catalytic reduction device is a skid-mounted integrated device, which is convenient for management and operation.

(2)该装置的热源系统有导热油和蒸汽两种选择,可根据实际需求选择更优的供热方式。(2) The heat source system of the device has two choices of heat transfer oil and steam, and a better heating method can be selected according to actual needs.

(3)配料釜设有冷凝盘管装置,主反应釜产生的蒸汽闪蒸至配料釜时,可使蒸汽快速液化,从而提高搅拌电机的工作效率,使得有机废物与催化剂能够更好混合均匀,主反应釜产生的蒸汽闪蒸至预反应釜时,可提前让物料进行预反应,使得物料在主反应釜中所需的反应温度和反应时间大大降低,从而节省能耗。(3) The batching kettle is equipped with a condensing coil device. When the steam generated by the main reaction kettle is flashed to the batching kettle, the steam can be rapidly liquefied, thereby improving the working efficiency of the stirring motor, so that the organic waste and the catalyst can be mixed better and evenly. When the steam generated by the main reaction kettle is flashed to the pre-reaction kettle, the material can be pre-reacted in advance, so that the reaction temperature and reaction time required by the material in the main reaction kettle are greatly reduced, thereby saving energy consumption.

(4)当主反应釜向冷却釜卸料时,冷却釜会充满大量蒸汽,通过冷却釜的冷凝盘管装置可液化一部分蒸汽,剩余的蒸汽由于气压作用可通过管道输送至配料釜,从而使这部分蒸汽得到充分利用。(4) When the main reaction kettle is unloaded to the cooling kettle, the cooling kettle will be filled with a large amount of steam. A part of the steam can be liquefied by the condensation coil device of the cooling kettle, and the remaining steam can be transported to the batching kettle through the pipeline due to the action of air pressure. Part of the steam is fully utilized.

(5)整个反应装置产生的VOCs,最终通过管道汇集在配料釜内,这部分VOCs再通过管路输送至VOCs处理系统,从而不会产生二次污染问题。(5) The VOCs generated by the entire reaction device are finally collected in the batching kettle through the pipeline, and this part of the VOCs is then transported to the VOCs treatment system through the pipeline, so that there will be no secondary pollution problem.

(6)通过在该装置内加入自主研发的高效有机催化剂可显著提高该装置对有机废物的减量效果。(6) By adding a self-developed high-efficiency organic catalyst into the device, the reduction effect of the device on organic waste can be significantly improved.

(7)固液分离系统得到的部分脱水液通过水处理系统处理后,再回流至配料釜、预反应釜和主反应釜,从而可以回收利用脱水液中残余的催化剂,另外,这些脱水液还能够分别对配料釜、预反应釜和主反应釜的内壁进行冲洗,防止有物料残留在釜壁上。(7) After the partial dehydration liquid obtained by the solid-liquid separation system is processed by the water treatment system, it is returned to the batching still, the pre-reaction still and the main reaction still, so that the residual catalyst in the dehydration liquid can be recycled. In addition, these dehydration liquids also The inner wall of the batching kettle, the pre-reaction kettle and the main reaction kettle can be washed respectively to prevent material from remaining on the kettle wall.

(8)固液分离系统得到的固体泥饼热值含量相对于原有机废物的热值提高了23%-32%,该固体泥饼为疏松多孔的活性吸附材料,可用于废水的处理,而且通过加入催化剂,反应能耗可降低58%-80%,另外空白实验减量效果达到50%-71%,热催化实验减量效果达到60%-82%。(8) The calorific value of the solid mud cake obtained by the solid-liquid separation system is increased by 23%-32% compared with the calorific value of the original organic waste. The solid mud cake is a loose and porous active adsorption material, which can be used for wastewater treatment, and By adding the catalyst, the energy consumption of the reaction can be reduced by 58%-80%, and the reduction effect of the blank experiment can reach 50%-71%, and the reduction effect of the thermal catalysis experiment can reach 60%-82%.

附图说明Description of drawings

图1为本实施例提供的实现有机废物热催化高效减量及资源化的装置结构示意图。FIG. 1 is a schematic structural diagram of a device for realizing efficient thermal catalysis reduction and resource utilization of organic waste provided in this embodiment.

具体实施方式Detailed ways

下面结合具体实施例,进一步阐述本发明。The present invention will be further described below in conjunction with specific embodiments.

图1为本实施例提供的实现有机废物热催化高效减量及资源化的装置结构示意图,所述的实现有机废物热催化高效减量及资源化的装置包括有机废物进料系统24,有机废物进料系统24通过管道连接配料釜A27的物料进口,将有机废物和有机催化剂分别输送至配料釜A27。配料釜A27内设有搅拌电机21,打开搅拌电机21,将有机废物与有机催化剂配置成混合均匀的反应物料。1 is a schematic structural diagram of a device for realizing efficient thermal catalysis reduction and recycling of organic waste provided by the present embodiment, and the device for realizing efficient thermal catalysis reduction and recycling of organic waste includes an organic waste feeding system 24, and an organic waste feed system 24. The feeding system 24 is connected to the material inlet of the batching kettle A27 through a pipeline, and transports the organic waste and the organic catalyst to the batching kettle A27 respectively. There is a stirring motor 21 in the batching kettle A27, and the stirring motor 21 is turned on to configure the organic waste and the organic catalyst into a uniformly mixed reaction material.

配料釜A27物料出口通过管道连接主反应釜C34的物料进口。配料釜A27物料出口与主反应釜C34物料进口之间的管道上设有第一阀门29、第三阀门20和第一泵30。主反应釜34的夹套35进口与热源系统8的出口相连接,热源系统8的进口与主反应釜34的夹套35出口相连接。待配料釜A27里物料搅拌均匀后,打开第一阀门29、第三阀门20和第一泵30,将配料釜A27里部分物料输送至主反应釜C34。待输送完毕后,关闭第一阀门29、第三阀门20和第一泵30,然后开启热源系统8,开始给主反应釜C34升温加热反应。The material outlet of the batching kettle A27 is connected to the material inlet of the main reactor C34 through a pipeline. A first valve 29, a third valve 20 and a first pump 30 are arranged on the pipeline between the material outlet of the batching kettle A27 and the material inlet of the main reactor C34. The inlet of the jacket 35 of the main reactor 34 is connected with the outlet of the heat source system 8 , and the inlet of the heat source system 8 is connected with the outlet of the jacket 35 of the main reactor 34 . After the materials in the batching kettle A27 are evenly stirred, the first valve 29, the third valve 20 and the first pump 30 are opened, and part of the materials in the batching kettle A27 are transported to the main reactor C34. After the transportation is completed, the first valve 29, the third valve 20 and the first pump 30 are closed, and then the heat source system 8 is turned on to start the heating reaction for the main reactor C34.

配料釜A27物料出口还通过管道连接预反应釜B31物料进口,配料釜A27物料出口与预反应釜B31物料进口之间的管道上设有第一阀门29、第二阀门19和第一泵30。打开第一阀门29、第二阀门19和第一泵30,将配料釜A27里物料输送至预反应釜B31。待输送完毕后,关闭第一阀门29、第二阀门19和第一泵30。The material outlet of batching kettle A27 is also connected to the material inlet of pre-reaction kettle B31 through a pipeline, and the pipeline between the material outlet of batching kettle A27 and the material inlet of pre-reaction kettle B31 is provided with a first valve 29, a second valve 19 and a first pump 30. Open the first valve 29, the second valve 19 and the first pump 30, and transfer the materials in the batching kettle A27 to the pre-reaction kettle B31. After the delivery is completed, the first valve 29 , the second valve 19 and the first pump 30 are closed.

主反应釜C34的蒸汽出口可通过管道连接配料釜A27蒸汽进口和预反应釜B31蒸汽进口。主反应釜C34的蒸汽出口与配料釜A27蒸汽进口之间的管道上设有第十阀门10和第十一阀门2,主反应釜C34的蒸汽出口与预反应釜B31蒸汽进口之间的管道上设有第十阀门10和第十二阀门4。待反应结束后,关闭热源系统8,开启第十阀门10、第十一阀门2和第十二阀门4,开始闪蒸。待闪蒸结束后,关闭第十阀门10、第十一阀门2和第十二阀门4。The steam outlet of the main reaction kettle C34 can be connected to the steam inlet of the batching kettle A27 and the steam inlet of the pre-reaction kettle B31 through a pipeline. The tenth valve 10 and the eleventh valve 2 are arranged on the pipeline between the steam outlet of the main reactor C34 and the steam inlet of the batching reactor A27, and the pipeline between the steam outlet of the main reactor C34 and the steam inlet of the pre-reactor B31 is provided on the pipeline. A tenth valve 10 and a twelfth valve 4 are provided. After the reaction is completed, the heat source system 8 is closed, the tenth valve 10, the eleventh valve 2 and the twelfth valve 4 are opened, and flash evaporation is started. After the flashing is over, the tenth valve 10 , the eleventh valve 2 and the twelfth valve 4 are closed.

主反应釜C34物料出口通过管道连接冷却釜D40物料进口,主反应釜C34物料出口与冷却釜D40物料进口之间的管道上设有第五阀门36和第三泵37。配料釜A27的冷却水出口25与冷却釜D40的冷却水进口39相连接,冷却釜D40的冷却水出口38与配料釜A27的冷却水进口26相连接。开启冷却水循环系统,然后打开第五阀门36和第三泵37,准备开始卸料。The material outlet of the main reactor C34 is connected to the material inlet of the cooling kettle D40 through a pipeline, and a fifth valve 36 and a third pump 37 are provided on the pipeline between the material outlet of the main reactor C34 and the material inlet of the cooling kettle D40. The cooling water outlet 25 of the batching kettle A27 is connected to the cooling water inlet 39 of the cooling kettle D40, and the cooling water outlet 38 of the cooling kettle D40 is connected to the cooling water inlet 26 of the batching kettle A27. Turn on the cooling water circulation system, then open the fifth valve 36 and the third pump 37, ready to start discharging.

冷却釜D40的蒸汽出口可通过管道连接配料釜A27蒸汽进口,冷却釜D40的蒸汽出口与配料釜A27蒸汽进口之间的管道上设有第十三阀门44。在卸料的同时,打开第十三阀门44。待卸料结束,关闭第五阀门36、第三泵37和第十三阀门44。The steam outlet of the cooling kettle D40 can be connected to the steam inlet of the batching kettle A27 through a pipeline, and a thirteenth valve 44 is provided on the pipeline between the steam outlet of the cooling kettle D40 and the steam inlet of the batching kettle A27. Simultaneously with the discharge, the thirteenth valve 44 is opened. When the discharging is finished, the fifth valve 36 , the third pump 37 and the thirteenth valve 44 are closed.

预反应釜B31物料出口通过管道连接主反应釜C34物料进口,预反应釜B31物料出口与主反应釜C34物料进口之间的管道上设有第四阀门32和第二泵33。打开第四阀门32和第二泵33,将预反应釜B31内物料输送至主反应釜C34,准备开始第二批物料反应。The material outlet of the pre-reaction kettle B31 is connected to the material inlet of the main reaction kettle C34 through a pipeline, and the pipeline between the material outlet of the pre-reaction kettle B31 and the material inlet of the main reactor C34 is provided with a fourth valve 32 and a second pump 33. Open the fourth valve 32 and the second pump 33, and transfer the materials in the pre-reaction kettle B31 to the main reactor C34, ready to start the reaction of the second batch of materials.

配料釜A27的不凝气出口通过管道连接VOCs处理系统23,配料釜A27的不凝气出口与VOCs处理系统23之间的管道上设有第十四阀门22。打开第十四阀门22,通过VOCs处理系统23将配料釜A27内残余的气体进行处理。The non-condensable gas outlet of the batching kettle A27 is connected to the VOCs treatment system 23 through a pipeline, and a fourteenth valve 22 is provided on the pipeline between the non-condensable gas outlet of the batching kettle A27 and the VOCs processing system 23 . Open the fourteenth valve 22, and process the residual gas in the batching kettle A27 through the VOCs treatment system 23.

冷却釜D40物料出口通过管道连接固液分离系统45,冷却釜D40物料出口与固液分离系统45之间的管道上设有第六阀门41和第四泵42。打开第六阀门41和第四泵42,使反应后的混合物进入固液分离系统45进行脱水。The material outlet of the cooling kettle D40 is connected to the solid-liquid separation system 45 through a pipeline, and a sixth valve 41 and a fourth pump 42 are provided on the pipeline between the material outlet of the cooling kettle D40 and the solid-liquid separation system 45 . Open the sixth valve 41 and the fourth pump 42 so that the reacted mixture enters the solid-liquid separation system 45 for dehydration.

水处理系统7液体出口通过管道分别连接配料釜A27物料进口、预反应釜B31物料进口和主反应釜C34物料进口,水处理系统7液体出口与配料釜A27物料进口之间的管道上设有第五泵6和第七阀门1。水处理系统7液体出口与预反应釜B31物料进口之间的管道上设有第五泵6和第八阀门3。水处理系统7液体出口与主反应釜C34物料进口之间的管道上设有第五泵6和第九阀门5。待脱水完毕后,关闭第六阀门41和第四泵42,然后将部分脱水液回流至水处理系统7进行处理。待处理结束后,打开第五泵6、第九阀门5、第八阀门3和第七阀门1,再将处理后的脱水液分别回流至主反应釜C、预反应釜B和配料釜A,从而实现催化剂的回收利用,还能冲洗釜壁。剩余的脱水液排入废水处理厂,固体泥饼用作燃料或吸附材料。The liquid outlet of water treatment system 7 is connected to the material inlet of batching kettle A27, the material inlet of pre-reaction kettle B31 and the material inlet of main reactor C34 through pipes, respectively. Five pump 6 and seventh valve 1. A fifth pump 6 and an eighth valve 3 are provided on the pipeline between the liquid outlet of the water treatment system 7 and the material inlet of the pre-reactor B31. A fifth pump 6 and a ninth valve 5 are arranged on the pipeline between the liquid outlet of the water treatment system 7 and the material inlet of the main reactor C34. After the dehydration is completed, the sixth valve 41 and the fourth pump 42 are closed, and then part of the dehydration liquid is returned to the water treatment system 7 for treatment. After the treatment is finished, the fifth pump 6, the ninth valve 5, the eighth valve 3 and the seventh valve 1 are opened, and then the dehydrated liquid after the treatment is returned to the main reactor C, the pre-reaction still B and the batching still A respectively, In this way, the recovery and utilization of the catalyst can be realized, and the wall of the kettle can also be washed. The remaining dewatering liquid is discharged to the wastewater treatment plant, and the solid mud cake is used as fuel or adsorbent material.

应当理解的是,虽然在这里可能使用量术语“第一”、“第二”等等来描述各个单元,但是这些单元不应当受这些术语限制。使用这些术语仅仅是为了将一个单元与另一个单元进行区分。举例来说,在不背离示例性实施例的范围的情况下,第一单元可以被称为第二单元,并且类似地第二单元可以被称为第一单元。It will be understood that, although the quantitative terms "first," "second," etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are used only to distinguish one unit from another. For example, a first element could be termed a second element, and, similarly, a second element could be termed a first element, without departing from the scope of example embodiments.

以上所述,仅为本发明的较佳实施例,并非对本发明任何形式上和实质上的限制,应当指出,对于本技术领域的普通技术人员,在不脱离本发明方法的前提下,还将可以做出若干改进和补充,这些改进和补充也应视为本发明的保护范围。凡熟悉本专业的技术人员,在不脱离本发明的精神和范围的情况下,当可利用以上所揭示的技术内容而做出的些许更动、修饰与演变的等同变化,均为本发明的等效实施例;同时,凡依据本发明的实质技术对上述实施例所作的任何等同变化的更动、修饰与演变,均仍属于本发明的技术方案的范围内。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention in any form or substance. It should be pointed out that for those skilled in the art, without departing from the method of the present invention, the Several improvements and supplements can be made, and these improvements and supplements should also be regarded as the protection scope of the present invention. All those skilled in the art, without departing from the spirit and scope of the present invention, can utilize the above-disclosed technical content to make some changes, modifications and equivalent changes of evolution, all belong to the present invention. Equivalent embodiments; at the same time, any modification, modification and evolution of any equivalent changes made to the above embodiments according to the essential technology of the present invention still fall within the scope of the technical solutions of the present invention.

Claims (7)

1.一种实现有机废物热催化高效减量及资源化的装置,其特征在于:包括配料釜(27),有机废物进料系统(24)通过管道连接配料釜(27)物料进口,配料釜(27)物料出口通过管道分别连接预反应釜(31)物料进口和主反应釜(34)物料进口,预反应釜(31)物料出口通过管道连接主反应釜(34)物料进口,主反应釜(34)物料出口通过管道连接冷却釜(40)物料进口,冷却釜(40)物料出口通过管道连接固液分离系统(45);固液分离系统(45)的部分液体出口通过管道连接水处理系统(7),水处理系统(7)液体出口通过管道分别连接配料釜(27)物料进口、预反应釜(31)物料进口和主反应釜(34)物料进口;1. a device that realizes thermally catalyzed high-efficiency reduction and resource utilization of organic waste, is characterized in that: comprise batching still (27), and organic waste feeding system (24) is connected to the material inlet of batching still (27) by pipeline, and batching still (27) The material outlet is respectively connected to the material inlet of the pre-reaction kettle (31) and the material inlet of the main reaction kettle (34) through a pipeline, and the material outlet of the pre-reaction kettle (31) is connected to the material inlet of the main reaction kettle (34) through a pipeline, and the main reaction kettle (34) is connected through a pipeline. (34) The material outlet is connected to the material inlet of the cooling kettle (40) through a pipeline, and the material outlet of the cooling kettle (40) is connected to the solid-liquid separation system (45) through a pipeline; part of the liquid outlet of the solid-liquid separation system (45) is connected to the water treatment system through a pipeline The system (7), the liquid outlet of the water treatment system (7) are respectively connected to the material inlet of the batching kettle (27), the material inlet of the pre-reaction kettle (31) and the material inlet of the main reaction kettle (34) through pipes; 主反应釜(34)的夹套(35)进口与热源系统(8)的出口相连接,热源系统(8)的进口与主反应釜(34)的夹套(35)出口相连接;The inlet of the jacket (35) of the main reactor (34) is connected with the outlet of the heat source system (8), and the inlet of the heat source system (8) is connected with the outlet of the jacket (35) of the main reactor (34); 主反应釜(34)的蒸汽出口通过管道连接配料釜(27)蒸汽进口和预反应釜(31)蒸汽进口,冷却釜(40)的蒸汽出口通过管道连接配料釜(27)蒸汽进口,配料釜(27)的不凝气出口通过管道连接VOCs处理系统(23);The steam outlet of the main reaction kettle (34) is connected to the steam inlet of the batching kettle (27) and the steam inlet of the pre-reaction kettle (31) through a pipeline, and the steam outlet of the cooling kettle (40) is connected to the steam inlet of the batching kettle (27) through a pipeline. The non-condensable gas outlet of (27) is connected to the VOCs treatment system (23) through a pipeline; 配料釜(27)的冷却水出口(25)与冷却釜(40)的冷却水进口(39)相连接,冷却釜(40)的冷却水出口(38)与配料釜(27)的冷却水进口(26)相连接,组成冷却水循环系统;The cooling water outlet (25) of the batching kettle (27) is connected with the cooling water inlet (39) of the cooling kettle (40), and the cooling water outlet (38) of the cooling kettle (40) is connected with the cooling water inlet of the batching kettle (27) (26) connected to form a cooling water circulation system; 所述配料釜(27)物料出口与预反应釜(31)物料进口之间的管道上设有第一阀门(29)、第二阀门(19)和第一泵(30);所述配料釜(27)物料出口与主反应釜(34)物料进口之间的管道上设有第一阀门(29)、第三阀门(20)和第一泵(30);A first valve (29), a second valve (19) and a first pump (30) are arranged on the pipeline between the material outlet of the batching kettle (27) and the material inlet of the pre-reaction kettle (31); the batching kettle (27) A first valve (29), a third valve (20) and a first pump (30) are provided on the pipeline between the material outlet and the material inlet of the main reactor (34); 所述预反应釜(31)物料出口与主反应釜(34)物料进口之间的管道上设有第四阀门(32)和第二泵(33);所述主反应釜(34)物料出口与冷却釜(40)物料进口之间的管道上设有第五阀门(36)和第三泵(37);所述冷却釜(40)物料出口与固液分离系统(45)之间的管道上设有第六阀门(41)和第四泵(42);A fourth valve (32) and a second pump (33) are arranged on the pipeline between the material outlet of the pre-reaction kettle (31) and the material inlet of the main reaction kettle (34); the material outlet of the main reaction kettle (34) is provided with a fourth valve (32) and a second pump (33). A fifth valve (36) and a third pump (37) are arranged on the pipeline between the material inlet of the cooling kettle (40); the pipeline between the material outlet of the cooling kettle (40) and the solid-liquid separation system (45) There is a sixth valve (41) and a fourth pump (42) on it; 所述水处理系统(7)液体出口与配料釜(27)物料进口之间的管道上设有第五泵(6)和第七阀门(1);所述水处理系统(7)液体出口与预反应釜(31)物料进口之间的管道上设有第五泵(6)和第八阀门(3);所述水处理系统(7)液体出口与主反应釜(34)物料进口之间的管道上设有第五泵(6)和第九阀门(5);A fifth pump (6) and a seventh valve (1) are arranged on the pipeline between the liquid outlet of the water treatment system (7) and the material inlet of the batching kettle (27); the liquid outlet of the water treatment system (7) is connected to the A fifth pump (6) and an eighth valve (3) are arranged on the pipeline between the material inlets of the pre-reaction kettle (31); between the liquid outlet of the water treatment system (7) and the material inlet of the main reaction kettle (34) There is a fifth pump (6) and a ninth valve (5) on the pipeline of the pump; 所述主反应釜(34)的蒸汽出口与配料釜(27)蒸汽进口之间的管道上设有第十阀门(10)和第十一阀门(2);所述主反应釜(34)的蒸汽出口与预反应釜(31)蒸汽进口之间的管道上设有第十阀门(10)和第十二阀门(4);A tenth valve (10) and an eleventh valve (2) are provided on the pipeline between the steam outlet of the main reaction still (34) and the steam inlet of the batching still (27); A tenth valve (10) and a twelfth valve (4) are arranged on the pipeline between the steam outlet and the steam inlet of the pre-reaction kettle (31); 所述冷却釜(40)的蒸汽出口与配料釜(27)蒸汽进口之间的管道上设有第十三阀门(44);所述配料釜(27)的不凝气出口与VOCs处理系统(23)之间的管道上设有第十四阀门(22);A thirteenth valve (44) is provided on the pipeline between the steam outlet of the cooling kettle (40) and the steam inlet of the batching kettle (27); the non-condensable gas outlet of the batching kettle (27) and the VOCs treatment system ( A fourteenth valve (22) is provided on the pipeline between 23); 所述配料釜(27)内设有第一搅拌电机(21)和第一冷凝盘管(28);The batching kettle (27) is provided with a first stirring motor (21) and a first condensing coil (28); 所述预反应釜(31)内设有第二搅拌电机(17);所述预反应釜(31)上设有第一温度计(18)、第一压力表(16)和第一安全阀(15);The pre-reaction kettle (31) is provided with a second stirring motor (17); the pre-reaction kettle (31) is provided with a first thermometer (18), a first pressure gauge (16) and a first safety valve ( 15); 所述主反应釜(34)内设有第三搅拌电机(12);所述主反应釜(34)上设有第二温度计(14)、第二压力表(13)、第二安全阀(11);所述主反应釜(34)还连接惰性气路(9);The main reactor (34) is provided with a third stirring motor (12); the main reactor (34) is provided with a second thermometer (14), a second pressure gauge (13), a second safety valve ( 11); Described main reactor (34) also connects inert gas path (9); 所述冷却釜(40)内设有第二冷凝盘管(43);The cooling kettle (40) is provided with a second condensing coil (43); 所述有机废物进料系统(24)通过螺旋输送机将有机废物和催化剂输送至配料釜(27)内;配料釜(27)通过搅拌电机(21)将有机废物与催化剂混合搅拌均匀,并将搅拌均匀后的部分物料输送至主反应釜(34)、部分物料输送至预反应釜(31);开启热源系统(8),给主反应釜(34)升温加热反应;反应结束后,关闭热源系统(8),开始闪蒸;闪蒸结束后,开启配料釜(27)和冷却釜(40)之间的冷却水循环系统,并卸料;第一批物料反应结束;将预反应釜(31)内物料输送至主反应釜(34),开始第二批物料反应;The organic waste feeding system (24) transports the organic waste and the catalyst into the batching kettle (27) through the screw conveyor; the batching kettle (27) mixes the organic waste and the catalyst uniformly by the stirring motor (21), and mixes the organic waste and the catalyst uniformly. After stirring, part of the material is transported to the main reactor (34), and part of the material is transported to the pre-reactor (31); the heat source system (8) is turned on, and the main reactor (34) is heated and reacted; after the reaction is completed, the heat source is turned off The system (8) starts flashing; after the flashing is finished, the cooling water circulation system between the batching kettle (27) and the cooling kettle (40) is opened, and unloading; the reaction of the first batch of materials ends; the pre-reaction kettle (31 ) in the material is transported to the main reactor (34), starts the second batch of material reaction; 通过VOCs处理系统(23)将配料釜(27)内残余的气体进行处理,冷却釜(40)内反应后的混合物进入固液分离系统(45)进行脱水;脱水完毕后,将部分脱水液回流至水处理系统(7)进行处理;处理结束后,将处理后的脱水液分别回流至主反应釜(34)、预反应釜(31)和配料釜(27),从而实现催化剂的回收利用,还能冲洗釜壁;剩余的脱水液排入废水处理厂,固体泥饼用作燃料或吸附材料。The residual gas in the batching kettle (27) is processed by the VOCs treatment system (23), and the reacted mixture in the cooling kettle (40) enters the solid-liquid separation system (45) for dehydration; after the dehydration is completed, part of the dehydration liquid is refluxed To the water treatment system (7) for treatment; after the treatment, the dehydrated liquid after the treatment is returned to the main reaction still (34), the pre-reaction still (31) and the batching still (27) respectively, thereby realizing the recycling of the catalyst, The wall of the kettle can also be washed; the remaining dewatering liquid is discharged to the wastewater treatment plant, and the solid mud cake is used as fuel or adsorption material. 2.如权利要求1所述的一种实现有机废物热催化高效减量及资源化的装置,其特征在于:所述配料釜(27)、预反应釜(31)、主反应釜(34)和冷却釜(40)构成主反应系统,所述有机废物进料系统(24)、热源系统(8)、固液分离系统(45)、水处理系统(7)和VOCs处理系统(23)构成附属反应系统。2. a kind of device that realizes thermal catalysis high-efficiency reduction and resource utilization of organic waste as claimed in claim 1, is characterized in that: described batching still (27), pre-reaction still (31), main reaction still (34) and the cooling kettle (40) constitute a main reaction system, the organic waste feeding system (24), the heat source system (8), the solid-liquid separation system (45), the water treatment system (7) and the VOCs treatment system (23) are constituted Auxiliary Response System. 3.如权利要求2所述的一种实现有机废物热催化高效减量及资源化的装置,其特征在于:所述的第一阀门(29)、第二阀门(19)、第三阀门(20)、第四阀门(32)、第五阀门(36)、第六阀门(41)、第七阀门(1)、第八阀门(3)、第九阀门(5)、第十阀门(10)、第十一阀门(2)、第十二阀门(4)、第十三阀门(44)、第十四阀门(22)均为气动球阀;3. A device for realizing efficient thermal catalysis reduction and resource utilization of organic waste as claimed in claim 2, characterized in that: the first valve (29), the second valve (19), the third valve ( 20), the fourth valve (32), the fifth valve (36), the sixth valve (41), the seventh valve (1), the eighth valve (3), the ninth valve (5), the tenth valve (10) ), the eleventh valve (2), the twelfth valve (4), the thirteenth valve (44), and the fourteenth valve (22) are all pneumatic ball valves; 所述第一泵(30)为螺杆泵;所述第二泵(33)和第三泵(37)均为凸轮式双转子泵;所述第四泵(42)为气动隔膜泵;所述第五泵(6)为潜水泵。The first pump (30) is a screw pump; the second pump (33) and the third pump (37) are both cam type double rotor pumps; the fourth pump (42) is a pneumatic diaphragm pump; the The fifth pump (6) is a submersible pump. 4.如权利要求1所述的一种实现有机废物热催化高效减量及资源化的装置,其特征在于:所述热源系统(8)为导热油加热和蒸汽加热的一种或者两种。4. A device for realizing efficient thermal catalysis reduction and recycling of organic waste as claimed in claim 1, wherein the heat source system (8) is one or both of heat-conducting oil heating and steam heating. 5.如权利要求1所述的一种实现有机废物热催化高效减量及资源化的装置,其特征在于:所述固液分离系统(45)为离心机、叠螺机或压滤机的一种。5. A device for realizing thermally catalyzed high-efficiency reduction and resource utilization of organic waste as claimed in claim 1, wherein the solid-liquid separation system (45) is a centrifuge, screw stacker or filter press. A sort of. 6.如权利要求1所述的一种实现有机废物热催化高效减量及资源化的装置,其特征在于:所述水处理系统(7)采用蒸发处理和膜分离工艺处理的一种或者两种;所述VOCs处理系统(23)采用催化光解、等离子体和活性炭吸附中的一种或者多种。6. A device for realizing efficient thermal catalysis reduction and resource utilization of organic waste as claimed in claim 1, wherein the water treatment system (7) adopts one or both of evaporation treatment and membrane separation process treatment. The VOCs treatment system (23) adopts one or more of catalytic photolysis, plasma and activated carbon adsorption. 7.如权利要求1所述的一种实现有机废物热催化高效减量及资源化的装置,其特征在于:所述催化剂为按如下质量百分比配置而成的有机催化剂:草酸0.5%-10%、乙酸1%-15%、丙酸15%-50%、乳酸15%-40%、柠檬酸10%-55%,溶剂为水。7. A device for realizing efficient thermal catalysis reduction and recycling of organic waste as claimed in claim 1, wherein the catalyst is an organic catalyst configured by the following mass percentages: 0.5%-10% of oxalic acid , acetic acid 1%-15%, propionic acid 15%-50%, lactic acid 15%-40%, citric acid 10%-55%, and the solvent is water.
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