CN107445205A - A kind of method for producing sodium metavanadate and products thereof and application - Google Patents
A kind of method for producing sodium metavanadate and products thereof and application Download PDFInfo
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- CN107445205A CN107445205A CN201710707972.8A CN201710707972A CN107445205A CN 107445205 A CN107445205 A CN 107445205A CN 201710707972 A CN201710707972 A CN 201710707972A CN 107445205 A CN107445205 A CN 107445205A
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- CN
- China
- Prior art keywords
- sodium
- ammonium
- metavanadate
- sodium metavanadate
- present
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 25
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 25
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 17
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims abstract description 15
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 238000002425 crystallisation Methods 0.000 claims abstract description 9
- 230000008025 crystallization Effects 0.000 claims abstract description 9
- 238000001556 precipitation Methods 0.000 claims abstract description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- 230000002000 scavenging effect Effects 0.000 claims description 8
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 7
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000003750 conditioning effect Effects 0.000 claims description 6
- 229910001456 vanadium ion Inorganic materials 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 238000005272 metallurgy Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000706 filtrate Substances 0.000 abstract description 3
- 239000000047 product Substances 0.000 abstract description 3
- 230000035484 reaction time Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 159000000000 sodium salts Chemical class 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229910001385 heavy metal Inorganic materials 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 238000006481 deamination reaction Methods 0.000 description 2
- XDBSEZHMWGHVIL-UHFFFAOYSA-M hydroxy(dioxo)vanadium Chemical compound O[V](=O)=O XDBSEZHMWGHVIL-UHFFFAOYSA-M 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PAJMKGZZBBTTOY-UHFFFAOYSA-N 2-[[2-hydroxy-1-(3-hydroxyoctyl)-2,3,3a,4,9,9a-hexahydro-1h-cyclopenta[g]naphthalen-5-yl]oxy]acetic acid Chemical compound C1=CC=C(OCC(O)=O)C2=C1CC1C(CCC(O)CCCCC)C(O)CC1C2 PAJMKGZZBBTTOY-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910019501 NaVO3 Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000009615 deamination Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The invention discloses a kind of method for producing sodium metavanadate and products thereof and application.It the described method comprises the following steps：Soluble ammonium salt is added in containing vanadium leachate and carries out precipitation, obtains ammonium vanadate；Sodium salt is added into ammonium vanadate to be dissolved, and obtains sodium vanadate solution；By sodium vanadate solution evaporative crystallization, sodium metavanadate is obtained.The present invention is without the use of desiliconizing agent, and technique is simple, the reaction time is short, easy to operate；Filtrate can be included into the heavy ammonium metavanadate of vanadium factory and recycle, and pollution is few；Technique productions step is simplified, energy consumption is low, advantage of lower cost.
Description
Technical field
The invention belongs to field of metallurgy, more particularly, to a kind of method for producing sodium metavanadate and products thereof and application.
Background technology
Sodium metavanadate, molecular formula NaVO3, molecular weight 121.93.White or flaxen crystal, relative density 2.79, melt
630 DEG C of point.It is dissolved in water, solubility is 21.1g/100ml H at 25 DEG C2O, it is 38.8g/100ml/H at 75 DEG C2O, it is slightly soluble in
Ethanol.Can be used as chemical reagent, catalyst, drier, mordant, manufacture ammonium vanadate and potassium metavanadate, be also used for medical treatment photograph,
Plant inoculating and corrosion inhibitor etc..
In the prior art, the preparation method of sodium metavanadate comprises the following steps：By ammonium metavanadate and sodium carbonate, sodium acid carbonate
Or sodium hydroxide is added to the water dissolving, microwave heating vacuumizes carry out deamination reaction simultaneously；Solution after deamination is stirred and steamed
Hair crystallization, adds ethanol, separates out solid；Obtained solidliquid mixture is filtered, and with ethanol rinse, obtains sodium metavanadate and consolidates
Body, vacuum drying.Also it is oriented containing desiliconizing agent is added in vanadium leachate, insoluble matter is removed, obtains low-silicon and low-phosphorous scavenging solution containing vanadium；To
Low-silicon and low-phosphorous scavenging solution containing vanadium adds soluble ammonium salt and carries out precipitation, obtains ammonium vanadate；With sodium hydroxide, sodium carbonate or bicarbonate
Sodium dissolves ammonium vanadate, removes insoluble matter, obtains sodium vanadate solution, evaporative crystallization obtains high-purity sodium metavanadate.
Though invention more than is with the reaction time is short, supplies consumption is few, filtrate can be included into heavy ammonium metavanadate recycling of vanadium factory etc.
Advantage, but processing step complexity easily causes secondary pollution, it is necessary to using desiliconizing agent, is not suitable for significantly promoting.
The content of the invention
The purpose of the present invention is to break away from the step for desiliconizing agent is used in the traditional handicraft for prepare sodium metavanadate, realizes work
Skill step is simple, does not cause secondary pollution, the purpose that can significantly promote.
To achieve these goals, the first aspect of the present invention provides a kind of method for producing sodium metavanadate, methods described
Comprise the following steps：
Soluble ammonium salt is added in containing vanadium leachate and carries out precipitation, obtains ammonium metavanadate；
Sodium hydroxide is added into ammonium metavanadate to be dissolved, and obtains sodium vanadate solution；
By sodium vanadate solution evaporative crystallization, sodium metavanadate is obtained.
In the present invention, the pH containing vanadium leachate is adjusted as 8.5~9.5 using conditioning agent.
In the present invention, reaction temperature is 60~70 DEG C.
In the present invention, the conditioning agent is sodium hydroxide and/or sodium acid carbonate.
In the present invention, the mol ratio of the ammonium ion in ammonium salt and vanadium ion in scavenging solution containing vanadium is 0.45~0.75: 1.
In the present invention, soluble ammonium salt includes at least one of ammonium sulfate, ammonium chloride and ammonium nitrate.
In the present invention, the ammonium sulfate, ammonium chloride and ammonium nitrate are AR.
The second aspect of the present invention provide as it is described produce the method for sodium metavanadate made from sodium metavanadate.
In the present invention, the composition of sodium metavanadate contains the NaVO no less than 99.7% by weight percentage3, heavy metal contains
Amount is not more than 0.03%.
The third aspect of the present invention provides application of the described sodium metavanadate in field of metallurgy.
Compared with prior art, the present invention has advantages below:
1st, without the use of desiliconizing agent, technique is simple, the reaction time is short, easy to operate；
2nd, filtrate can be included into the heavy ammonium metavanadate of vanadium factory and recycle, and pollution is few；
3rd, technique productions step is simplified, energy consumption is low, advantage of lower cost.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The preferred embodiment of the present invention is described in more detail below.Although the following describe being preferable to carry out for the present invention
Mode, however, it is to be appreciated that may be realized in various forms the present invention without should be limited by embodiments set forth herein.Phase
Instead, there is provided these embodiments be in order that the present invention is more thorough and complete, and can be by the scope of the present invention intactly
It is communicated to those skilled in the art.
A kind of method for producing sodium metavanadate of offer of the present invention, the described method comprises the following steps：
Soluble ammonium salt is added in containing vanadium leachate and carries out precipitation, obtains ammonium metavanadate；Hydrogen is added into ammonium metavanadate
Sodium oxide molybdena is dissolved, and obtains sodium vanadate solution；By sodium vanadate solution evaporative crystallization, sodium metavanadate is obtained.
In the present invention, the pH containing vanadium leachate is adjusted as 8.5~9.5 using conditioning agent.
In the present invention, reaction temperature is 60~70 DEG C.
In the present invention, the conditioning agent is sodium hydroxide and/or sodium acid carbonate.
In the present invention, the mol ratio of the ammonium ion in ammonium salt and vanadium ion in scavenging solution containing vanadium is 0.45~0.75: 1.
In the present invention, soluble ammonium salt includes at least one of ammonium sulfate, ammonium chloride and ammonium nitrate.
In the present invention, the ammonium sulfate, ammonium chloride and ammonium nitrate are AR.
Present invention additionally comprises as it is described produce the method for sodium metavanadate made from sodium metavanadate.
In the present invention, the composition of sodium metavanadate contains the NaVO no less than 99.7% by weight percentage3, heavy metal contains
Amount is not more than 0.03%.
Embodiment 1
Precipitation is carried out to the ammonium sulfate being made up of containing addition in vanadium leachate AR, obtains ammonium metavanadate；To inclined
Sodium hydroxide is added in ammonium vanadate to be dissolved, and obtains sodium vanadate solution；By sodium vanadate solution evaporative crystallization, metavanadic acid is obtained
Sodium.In the present invention, the pH containing vanadium leachate is adjusted as 8.5 using sodium hydroxide.In the present invention, reaction temperature is 60 DEG C.The present invention
In, the mol ratio of the ammonium ion in ammonium salt and vanadium ion in scavenging solution containing vanadium is 0.45: 1.
In the present invention, the composition of sodium metavanadate contains the NaVO no less than 99.7% by weight percentage3, heavy metal contains
Amount is not more than 0.03%.
Embodiment 2
Precipitation is carried out to the ammonium chloride being made up of containing addition in vanadium leachate AR, obtains ammonium metavanadate；To inclined
Sodium salt is added in ammonium vanadate to be dissolved, and obtains sodium vanadate solution；By sodium vanadate solution evaporative crystallization, sodium metavanadate is obtained.
In the present invention, the pH containing vanadium leachate is adjusted as 9 using sodium hydroxide.In the present invention, reaction temperature is 65 DEG C.This hair
In bright, the mol ratio of the ammonium ion in ammonium salt and vanadium ion in scavenging solution containing vanadium is 0.65: 1.
In the present invention, the composition of sodium metavanadate contains the NaVO no less than 99.7% by weight percentage3, heavy metal contains
Amount is not more than 0.03%.
Embodiment 3
Precipitation is carried out to the ammonium nitrate being made up of containing addition in vanadium leachate AR, obtains ammonium metavanadate；To inclined
Sodium hydroxide is added in ammonium vanadate to be dissolved, and obtains sodium vanadate solution；By sodium vanadate solution evaporative crystallization, metavanadic acid is obtained
Sodium.In the present invention, the pH containing vanadium leachate is adjusted as 9.5 using sodium hydroxide.In the present invention, reaction temperature is 70 DEG C.The present invention
In, the mol ratio of the ammonium ion in ammonium salt and vanadium ion in scavenging solution containing vanadium is 0.75: 1.
The composition of the present embodiment sodium metavanadate contains the NaVO no less than 99.7% by weight percentage3, heavy metal contains
Amount is not more than 0.03%.
It is described above various embodiments of the present invention, described above is exemplary, and non-exclusive, and
It is not limited to disclosed each embodiment.In the case of without departing from the scope and spirit of illustrated each embodiment, for this skill
Many modifications and changes will be apparent from for the those of ordinary skill in art field.
Claims (10)
- A kind of 1. method for producing sodium metavanadate, it is characterised in that the described method comprises the following steps：Soluble ammonium salt is added in containing vanadium leachate and carries out precipitation, obtains ammonium metavanadate；Sodium hydroxide is added into ammonium metavanadate to be dissolved, and obtains sodium vanadate solution；By sodium vanadate solution evaporative crystallization, sodium metavanadate is obtained.
- 2. the method according to claim 1 for producing sodium metavanadate, wherein, using conditioning agent adjust the pH containing vanadium leachate as 8.5~9.5.
- 3. the method according to claim 1 for producing sodium metavanadate, wherein, reaction temperature is 60~70 DEG C.
- 4. the method according to claim 1 for producing sodium metavanadate, wherein, the conditioning agent is sodium hydroxide and/or carbon Sour hydrogen sodium.
- 5. the method according to claim 1 for producing sodium metavanadate, wherein, the ammonium ion in ammonium salt and scavenging solution containing vanadium The mol ratio of middle vanadium ion is 0.45~0.75: 1.
- 6. the method according to claim 1 for producing sodium metavanadate, wherein, the soluble ammonium salt includes ammonium sulfate, chlorine Change at least one of ammonium and ammonium nitrate.
- 7. the method according to claim 6 for producing sodium metavanadate, wherein, the ammonium sulfate, ammonium chloride and ammonium nitrate are equal For AR.
- 8. as described in any one in claim 1-7 produce the method for sodium metavanadate made from sodium metavanadate.
- 9. sodium metavanadate according to claim 8, it is characterised in that the composition of sodium metavanadate contains by weight percentage NaVO no less than 99.7%3, content of beary metal is not more than 0.03%.
- 10. sodium metavanadate described in claim 9 is in the application of field of metallurgy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710707972.8A CN107445205A (en) | 2017-08-17 | 2017-08-17 | A kind of method for producing sodium metavanadate and products thereof and application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710707972.8A CN107445205A (en) | 2017-08-17 | 2017-08-17 | A kind of method for producing sodium metavanadate and products thereof and application |
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| CN107445205A true CN107445205A (en) | 2017-12-08 |
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| CN201710707972.8A Pending CN107445205A (en) | 2017-08-17 | 2017-08-17 | A kind of method for producing sodium metavanadate and products thereof and application |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110723750A (en) * | 2019-10-24 | 2020-01-24 | 成都先进金属材料产业技术研究院有限公司 | Direct preparation of high-purity V from alkaline vanadium-containing leaching solution2O5Method (2) |
| CN112899483A (en) * | 2021-01-18 | 2021-06-04 | 武汉科技大学 | Method for selectively extracting and separating vanadium from vanadium-molybdenum waste residue |
| CN117105267A (en) * | 2023-09-20 | 2023-11-24 | 攀钢集团研究院有限公司 | Method for preparing sodium metavanadate from sodium vanadate solution |
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| CN101746822A (en) * | 2009-12-30 | 2010-06-23 | 攀钢集团攀枝花钢钒有限公司 | Method for extracting sodium metavanadate from vanadium extraction leaching solution |
| CN104495925A (en) * | 2015-01-07 | 2015-04-08 | 攀钢集团研究院有限公司 | Method for preparing sodium metavanadate |
| CN106430305A (en) * | 2016-08-31 | 2017-02-22 | 大连博融新材料股份有限公司 | Production method of high-density ammonium metavanadate |
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2017
- 2017-08-17 CN CN201710707972.8A patent/CN107445205A/en active Pending
Patent Citations (3)
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| CN101746822A (en) * | 2009-12-30 | 2010-06-23 | 攀钢集团攀枝花钢钒有限公司 | Method for extracting sodium metavanadate from vanadium extraction leaching solution |
| CN104495925A (en) * | 2015-01-07 | 2015-04-08 | 攀钢集团研究院有限公司 | Method for preparing sodium metavanadate |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110723750A (en) * | 2019-10-24 | 2020-01-24 | 成都先进金属材料产业技术研究院有限公司 | Direct preparation of high-purity V from alkaline vanadium-containing leaching solution2O5Method (2) |
| CN112899483A (en) * | 2021-01-18 | 2021-06-04 | 武汉科技大学 | Method for selectively extracting and separating vanadium from vanadium-molybdenum waste residue |
| CN112899483B (en) * | 2021-01-18 | 2023-08-15 | 武汉科技大学 | Method for selectively extracting and separating vanadium from vanadium-molybdenum waste residues |
| CN117105267A (en) * | 2023-09-20 | 2023-11-24 | 攀钢集团研究院有限公司 | Method for preparing sodium metavanadate from sodium vanadate solution |
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