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CN107399926A - A kind of glass fiber compound - Google Patents

A kind of glass fiber compound Download PDF

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Publication number
CN107399926A
CN107399926A CN201710757874.5A CN201710757874A CN107399926A CN 107399926 A CN107399926 A CN 107399926A CN 201710757874 A CN201710757874 A CN 201710757874A CN 107399926 A CN107399926 A CN 107399926A
Authority
CN
China
Prior art keywords
parts
barium titanate
powders
glass fiber
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710757874.5A
Other languages
Chinese (zh)
Inventor
吴永生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Huatong Fiber Co Ltd
Original Assignee
Nantong Huatong Fiber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Huatong Fiber Co Ltd filed Critical Nantong Huatong Fiber Co Ltd
Priority to CN201710757874.5A priority Critical patent/CN107399926A/en
Publication of CN107399926A publication Critical patent/CN107399926A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of glass fiber compound, is made up of the raw material of following parts by weight:40 70 parts of polyethylene powders, 10 20 parts of phenolic resin, 15 parts of fatty acid polyglycol glycol ethers, 24 parts of di-iron trioxides, 20 40 parts of silane couplers, 26 parts of color masterbatches, 15 parts of phosphorous acid, 13 parts of calgons, 24 parts of ethylene glycol, 13 parts of bamboo fiber felts, 4 10 parts of barium titanate powders, 13 parts of soda ash, 13 parts of quick limes, 46 parts of silica flours, 13 parts of bechilites, 24 parts of magnesia.The present invention expects light, the high and resistant to elevated temperatures advantage of intensity, and increase the dielectric constant of the formula by barium titanate powder, the preparation method of this kind of composite, technique is simple, it can implement on conventional equipment, this kind of composite has good intensity, rigidity and impact flexibility simultaneously, and technique is simple, cost is low, production efficiency is high.

Description

A kind of glass fiber compound
Technical field
The invention belongs to polyester fiber field, and in particular to a kind of glass fiber compound.
Background technology
With the development of battlefield surroundings, in order to improve the battlefield survival of tactical missile, effectively compacting, destruction enemy's air defense Or early warning system, the flying speed of guided missile is more and more faster, and range is more and more remote, therefore tactical missile starts to propose more weight Add the requirement of harshness, existing tactical missile antenna house uses ceramic material mostly, because the density of material in itself is larger and material Toughness is poor, thus the weight of product is compared with use of the polymer matrix composites in antenna house, being greatly lowered antenna house Weight;It is continuous with " ecological awareness " but most polymer matrix composites heat resistances are poor, thus the scope used is smaller Enhancing, people increasingly pay attention to environmental protection, hygiene and health, wherein, processing characteristics is excellent, is used for various industrial products It is typically by glass fibers that plastics pollution on the environment has turned into the problem of general concern, particularly fibre reinforced composites Dimension, carbon fiber etc. are formed with plastic composition, and waste treatment is more difficult, and production environment is severe, and very big burden is added to environment, because This, natural fiber such as bamboo, fiber crops, lumber fibre etc. because its have it is light, inexpensive, be easy to get, biodegradable, environmentally safe etc. Feature causes the interest of people's development and application, although fiberglass surfacing is typically all surface-treated with soda ash, due to poly- Propylene is non-polar polymer material, poor with the interfacial adhesion strength of glass fibre, even if generally use adds part acid anhydrides and connect The polypropylene of branch improves interfacial adhesion strength, but raising of the glass fibre modification to Properties of Polypropylene is still limited.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of glass fiber compound.
In order to solve the above technical problems, the technical solution adopted by the present invention is:A kind of glass fiber compound, its innovative point It is:It is made up of the raw material of following parts by weight:40-70 parts polyethylene powders, 10-20 parts phenolic resin, 1-5 part fatty acid polyglycol second Glycol ethers, 2-4 parts di-iron trioxide, 20-40 parts silane coupler, 2-6 parts color masterbatch, 1-5 parts phosphorous acid, six inclined phosphorus of 1-3 parts Sour sodium, 2-4 parts ethylene glycol, 1-3 parts bamboo fiber felt, 4-10 parts barium titanate powder, 1-3 parts soda ash, 1-3 parts quick lime, 4-6 parts quartz Powder, 1-3 parts bechilite, 2-4 part magnesia.
Further, it is made up of the raw material of following parts by weight:40 parts of polyethylene powders, 10 parts of phenolic resin, 1 part of aliphatic acid Polyglycol ether, 2 parts of di-iron trioxides, 20 parts of silane couplers, 2 parts of color masterbatches, 1 part of phosphorous acid, 1 part of calgon, 2 parts Ethylene glycol, 1 part of bamboo fiber felt, 4 parts of barium titanate powders, 1 part of soda ash, 1 part of quick lime, 4 parts of silica flours, 1 part of bechilite, 2 parts of oxidations Magnesium.
Further, it is made up of the raw material of following parts by weight:70 parts of polyethylene powders, 20 parts of phenolic resin, 5 parts of aliphatic acid Polyglycol ether, 4 parts of di-iron trioxides, 40 parts of silane couplers, 6 parts of color masterbatches, 5 parts of phosphorous acid, 3 parts of calgons, 4 parts Ethylene glycol, 3 parts of bamboo fiber felts, 10 parts of barium titanate powders, 3 parts of soda ash, 3 parts of quick limes, 6 parts of silica flours, 3 parts of bechilites, 4 parts of oxidations Magnesium.
Further, it is made up of the raw material of following parts by weight:55 parts of polyethylene powders, 15 parts of phenolic resin, 3 parts of aliphatic acid Polyglycol ether, 3 parts of di-iron trioxides, 30 parts of silane couplers, 4 parts of color masterbatches, 3 parts of phosphorous acid, 2 parts of calgons, 3 parts Ethylene glycol, 2 parts of bamboo fiber felts, 7 parts of barium titanate powders, 2 parts of soda ash, 2 parts of quick limes, 5 parts of silica flours, 2 parts of bechilites, 3 parts of oxidations Magnesium.
Beneficial effects of the present invention are as follows:The present invention expects light, the high and resistant to elevated temperatures advantage of intensity, and passes through barium titanate powder Increase the dielectric constant of the formula, the preparation method of this kind of composite, technique is simple, can implement on conventional equipment, together When this kind of composite there is good intensity, rigidity and impact flexibility, and technique is simple, cost is low, production efficiency is high.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation Content disclosed by book understands other advantages and effect of the present invention easily.
A kind of glass fiber compound, it is made up of the raw material of following parts by weight:40-70 parts polyethylene powders, 10-20 part phenol Urea formaldehyde, 1-5 part fatty acid polyglycols glycol ether, 2-4 parts di-iron trioxide, 20-40 parts silane coupler, 2-6 parts color masterbatch, 1- 5 parts of phosphorous acid, 1-3 parts calgon, 2-4 parts ethylene glycol, 1-3 parts bamboo fiber felt, 4-10 parts barium titanate powder, 1-3 parts soda ash, 1-3 parts quick lime, 4-6 parts silica flour, 1-3 parts bechilite, 2-4 part magnesia.
Embodiment 1
A kind of glass fiber compound, it is made up of the raw material of following parts by weight:40 parts of polyethylene powders, 10 parts of phenolic resin, 1 part Fatty acid polyglycol glycol ether, 2 parts of di-iron trioxides, 20 parts of silane couplers, 2 parts of color masterbatches, 1 part of phosphorous acid, 1 part of hexa metaphosphoric acid Sodium, 2 parts of ethylene glycol, 1 part of bamboo fiber felt, 4 parts of barium titanate powders, 1 part of soda ash, 1 part of quick lime, 4 parts of silica flours, 1 part of bechilite, 2 Part magnesia.
Embodiment 2
A kind of glass fiber compound, it is made up of the raw material of following parts by weight:70 parts of polyethylene powders, 20 parts of phenolic resin, 5 parts Fatty acid polyglycol glycol ether, 4 parts of di-iron trioxides, 40 parts of silane couplers, 6 parts of color masterbatches, 5 parts of phosphorous acid, 3 parts of hexa metaphosphoric acids Sodium, 4 parts of ethylene glycol, 3 parts of bamboo fiber felts, 10 parts of barium titanate powders, 3 parts of soda ash, 3 parts of quick limes, 6 parts of silica flours, 3 parts of bechilites, 4 Part magnesia.
Embodiment 3
A kind of glass fiber compound, it is made up of the raw material of following parts by weight:55 parts of polyethylene powders, 15 parts of phenolic resin, 3 parts Fatty acid polyglycol glycol ether, 3 parts of di-iron trioxides, 30 parts of silane couplers, 4 parts of color masterbatches, 3 parts of phosphorous acid, 2 parts of hexa metaphosphoric acids Sodium, 3 parts of ethylene glycol, 2 parts of bamboo fiber felts, 7 parts of barium titanate powders, 2 parts of soda ash, 2 parts of quick limes, 5 parts of silica flours, 2 parts of bechilites, 3 Part magnesia.
The present invention expects light, the high and resistant to elevated temperatures advantage of intensity, and increases the dielectric constant of the formula by barium titanate powder, The preparation method of this kind of composite, technique is simple, can implement on conventional equipment, while this kind of composite has very well Intensity, rigidity and impact flexibility, and technique is simple, cost is low, production efficiency is high.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention Rights protection scope in.

Claims (4)

  1. A kind of 1. glass fiber compound, it is characterised in that:It is made up of the raw material of following parts by weight:40-70 parts polyethylene powders, 10-20 parts phenolic resin, 1-5 part fatty acid polyglycols glycol ether, 2-4 parts di-iron trioxide, 20-40 parts silane coupler, 2-6 parts Color masterbatch, 1-5 parts phosphorous acid, 1-3 parts calgon, 2-4 parts ethylene glycol, 1-3 parts bamboo fiber felt, 4-10 parts barium titanate powder, 1-3 parts soda ash, 1-3 parts quick lime, 4-6 parts silica flour, 1-3 parts bechilite, 2-4 part magnesia.
  2. A kind of 2. glass fiber compound according to claim 1, it is characterised in that:By the raw material structure of following parts by weight Into:40 parts of polyethylene powders, 10 parts of phenolic resin, 1 part of fatty acid polyglycol glycol ether, 2 parts of di-iron trioxides, 20 parts it is silane coupled Agent, 2 parts of color masterbatches, 1 part of phosphorous acid, 1 part of calgon, 2 parts of ethylene glycol, 1 part of bamboo fiber felt, 4 parts of barium titanate powders, 1 part it is pure Alkali, 1 part of quick lime, 4 parts of silica flours, 1 part of bechilite, 2 parts of magnesia.
  3. A kind of 3. glass fiber compound according to claim 1, it is characterised in that:By the raw material structure of following parts by weight Into:70 parts of polyethylene powders, 20 parts of phenolic resin, 5 parts of fatty acid polyglycol glycol ethers, 4 parts of di-iron trioxides, 40 parts it is silane coupled Agent, 6 parts of color masterbatches, 5 parts of phosphorous acid, 3 parts of calgons, 4 parts of ethylene glycol, 3 parts of bamboo fiber felts, 10 parts of barium titanate powders, 3 parts it is pure Alkali, 3 parts of quick limes, 6 parts of silica flours, 3 parts of bechilites, 4 parts of magnesia.
  4. A kind of 4. glass fiber compound according to claim 1, it is characterised in that:By the raw material structure of following parts by weight Into:55 parts of polyethylene powders, 15 parts of phenolic resin, 3 parts of fatty acid polyglycol glycol ethers, 3 parts of di-iron trioxides, 30 parts it is silane coupled Agent, 4 parts of color masterbatches, 3 parts of phosphorous acid, 2 parts of calgons, 3 parts of ethylene glycol, 2 parts of bamboo fiber felts, 7 parts of barium titanate powders, 2 parts it is pure Alkali, 2 parts of quick limes, 5 parts of silica flours, 2 parts of bechilites, 3 parts of magnesia.
CN201710757874.5A 2017-08-29 2017-08-29 A kind of glass fiber compound Pending CN107399926A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710757874.5A CN107399926A (en) 2017-08-29 2017-08-29 A kind of glass fiber compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710757874.5A CN107399926A (en) 2017-08-29 2017-08-29 A kind of glass fiber compound

Publications (1)

Publication Number Publication Date
CN107399926A true CN107399926A (en) 2017-11-28

Family

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Family Applications (1)

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CN201710757874.5A Pending CN107399926A (en) 2017-08-29 2017-08-29 A kind of glass fiber compound

Country Status (1)

Country Link
CN (1) CN107399926A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128982A (en) * 1994-05-28 1996-08-14 伊索福圣戈班公司 glass fiber composition
CN102849957A (en) * 2012-08-23 2013-01-02 巨石集团有限公司 Glass fiber composition
CN104403262A (en) * 2014-11-06 2015-03-11 上海复合材料科技有限公司 High-dielectric low-loss phenolic glass fiber composite material and preparation method thereof
CN104987656A (en) * 2015-07-01 2015-10-21 安徽丹凤电子材料股份有限公司 Formula of glass fiber composite
CN106316214A (en) * 2015-07-10 2017-01-11 潘文进 Glass fiber composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128982A (en) * 1994-05-28 1996-08-14 伊索福圣戈班公司 glass fiber composition
CN102849957A (en) * 2012-08-23 2013-01-02 巨石集团有限公司 Glass fiber composition
CN104403262A (en) * 2014-11-06 2015-03-11 上海复合材料科技有限公司 High-dielectric low-loss phenolic glass fiber composite material and preparation method thereof
CN104987656A (en) * 2015-07-01 2015-10-21 安徽丹凤电子材料股份有限公司 Formula of glass fiber composite
CN106316214A (en) * 2015-07-10 2017-01-11 潘文进 Glass fiber composition

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Application publication date: 20171128