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CN107396926A - It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic - Google Patents

It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic Download PDF

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Publication number
CN107396926A
CN107396926A CN201610344696.9A CN201610344696A CN107396926A CN 107396926 A CN107396926 A CN 107396926A CN 201610344696 A CN201610344696 A CN 201610344696A CN 107396926 A CN107396926 A CN 107396926A
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China
Prior art keywords
dcpta
crop
fluoxastrobin
antibacterial
composition
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CN201610344696.9A
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Chinese (zh)
Inventor
张伟
高云
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Shaanxi Welch Crop Protection Co Ltd
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Shaanxi Welch Crop Protection Co Ltd
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Priority to CN201610344696.9A priority Critical patent/CN107396926A/en
Publication of CN107396926A publication Critical patent/CN107396926A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/08Amines; Quaternary ammonium compounds containing oxygen or sulfur
    • A01N33/10Amines; Quaternary ammonium compounds containing oxygen or sulfur having at least one oxygen or sulfur atom directly attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Increase composition containing the antibacterial of DCPTA and methoxy acrylic the present invention relates to a kind of, effective active composition is active components A and active component B composition pesticide, and active components A is DCPTA, and active component B is selected from any one following compound:Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, the present composition has greater activity to the multiple diseases in various crop, and there is obvious synergistic effect, expand fungicidal spectrum, increase effective absorption of the crop to fertilizer simultaneously, supplemental crop inferior position part well grows, and adjusts the balance of crop internal water, so as to activate the metabolic system of crop, crop cell is promoted to increase, the characteristics of root activity is strengthened.

Description

It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic
Technical field
The invention belongs to technical field of pesticide, is related to a kind of antibacterial growth group containing DCPTA and methoxy acrylic Application of the compound on crops.
Technical background
DCPTA is absorbed by the stem and leaf of plant, and nucleus is directly acted in plant, is strengthened the activity of enzyme and is increased Add the content of slurries, grease and the class fat of plant, increase income crop yield.Significantly strengthen the photosynthesis of crop, make With rear blade inhales aobvious greening, thickening, change is big, increase the material such as the absorption to carbon dioxide and utilization rate, increase protein, lipid Accumulation storage, promote cell division and growth.
Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin, orysastrobin, pyridine Oxygen bacterium ester, kresoxim-methyl, pyraoxystrobin belong to triazole bactericidal agent, are widely used in the disease of crops.
However, in the real process of agricultural production, controlling disease is easiest to generate the problem that the production of disease drug resistance It is raw.Different cultivars composition is compounded, and is to prevent and treat the very common method of resistance disease.Heterogeneity is compounded, according to reality Application effect, to judge that certain compounding is synergy plus and or antagonism.In most cases, the compounding effect of sterilization All it is additive effect, really there is that the compounding of synergistic effect is seldom, especially synergistic effect is clearly, synergy ratio is very high answers With just less.Study, found DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, oxime by inventor Good synergy can be produced after bacterium ester, ZJ0712, dimoxystrobin, orysastrobin, ZEN 90160, kresoxim-methyl, pyraoxystrobin compounding Effect, and on DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, ether bacterium Amine, orysastrobin, ZEN 90160, kresoxim-methyl, the relevant report of pyraoxystrobin compounding not yet disclose.
The content of the invention
The purpose of the present invention is to propose to it is a kind of with synergistic function, use cost is low, effect is good contains DCPTA Antibacterial volume increase composition.
The present invention is to be achieved through the following technical solutions:
A kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic, composition is active components A and work Property composition B, active components A and active component B weight ratio be the ︰ 80 of 80 ︰ 1~1, and described active components A is DCPTA, active Composition B is selected from Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin, orysastrobin, pyridine One of oxygen bacterium ester, kresoxim-methyl, pyraoxystrobin are planted, and active components A and active component B more excellent weight ratio are 40 ︰ 1 in composition ~1 ︰ 40;It is the ︰ 25 of 15 ︰ 1~1 wherein to the weight of DCPTA and Fluoxastrobin ratio, is 20 ︰ to the weight of DCPTA and kresoxim-methyl ratio 1~1 ︰ 25, it is the ︰ 20 of 20 ︰ 1~1 to the weight of DCPTA and fluoxastrobin ratio, is to the weight of DCPTA and pyraclostrobin ratio The ︰ 25 of 20 ︰ 1~1.
It is proposed by the present invention to increase composition for preventing and treating crops containing the antibacterial of DCPTA and methoxy acrylic The purposes of upper disease, described crops include cereal crops, legume crop, fibre crops, sugar crop, melon crop, water Orchard crop, dry fruit crop, hobby crop, root crop, oil crops, flower crop, medicinal crop, crop, Green manure pasture crop;Described disease includes leaf spot, scab, false smut, rust, gray mold, powdery mildew, spot fallen leaves Disease, banded sclerotial blight, brown rot, leaf blight, epidemic disease, anthrachose of grape, spot blight, black spot, anthracnose, shot hole, smut, wheel line Disease, white rot, rice blast, bakanae disease, damping-off or sclerotiniose.
Described increases composition, wherein effective active composition content containing the antibacterial of DCPTA and methoxy acrylic Account for the 0.0001%~80% of gross weight, preferably 0.001%~50%.
Described increases composition for preventing and treating crop disease and rush containing the antibacterial of DCPTA and methoxy acrylic Enter the purposes of plant growth.
Surfactant selected by the antibacterial volume increase composition of the present invention is known in those skilled in the art:Can be with One or more in dispersant, wetting agent, thickener or defoamer.This can also be contained according to different dosage forms, in preparation Stabilizer, antifreeze well known to art personnel etc..
The antibacterial volume increase composition of the present invention, can be processed into acceptable formulation on any agricultural chemicals on demand, wherein excellent Formulation is selected to be hanged for wettable powder, soluble granule, soluble powder, soluble liquid, water dispersible granules, aqua or micro-capsule Floating agent, can also be made aqueous emulsion, microemulsion, suspending agent, effervescent tablet, seed coat agent.
Composition includes following constituent content when wettable powder is made:Active components A 0.01%~80%, active component B 0.0001%~80%, dispersant 2%~10%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when soluble granule is made:Active components A 0.01%~80%, activity into Point B0.0001%~80%, binding agent 0~8%, colouring agent 0.1%-2%, dispersant 2%~10%, wetting agent 2%~ 10%th, filler surplus.
Composition includes following constituent content when soluble powder is made:Active components A 0.01%~80%, active component B 0.0001%~80%, dispersant 2%~8%, wetting agent 1%-7%, stabilizer 0~5%, filler surplus.
Composition includes following constituent content when soluble liquid is made:Active components A 0.01%~50%, active component B 0.0001%~50%, emulsifying agent 1%~10%, cosolvent 2%~6%, solvent add to 100%.
Composition includes following constituent content when water dispersible granules are made:Active components A 0.01%~80%, activity into Point B 0.0001%~80%, dispersant 3%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~ 8%th, filler surplus.
Composition includes following constituent content when aqua is made:Active components A 0.01%~50%, active component B 0.0001%~50%, cosolvent 2%~6%, wetting agent 1%-10%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when microcapsule suspending agent is made:Active components A 0.01%~50%, active component B 0.0001%~50%, macromolecule cyst material 2%~10%, dispersant 1%~10%, solvent 1%~10%, emulsifying agent 1%~7%, defoamer 0.01%~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
The wettable powder the key technical indexes of the present invention:
The soluble granule the key technical indexes of the present invention:
The soluble powder the key technical indexes of the present invention:
The soluble liquid the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The aqua the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The advantage of the invention is that:
(1) DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin, After orysastrobin, ZEN 90160, kresoxim-methyl, pyraoxystrobin compounding, there is obvious synergy and lasting effect;(2) grain is made Thing, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, tubers Crop, oil crops, flower crop, medicinal crop, crop, the disease on green manure pasture crop have greater activity;(3) Reduce pesticide usage amount, reduce residual quantity of the agricultural chemicals on crop, alleviate environmental pollution;(4) to person poultry safety, environment Compatibility is good;And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but The invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~12
DCPTA, active component B, dispersant, wetting agent, filler are well mixed in mixed cylinder, through airslide disintegrating mill Remixed after crushing uniformly, you can wettable powder product of the present invention is made, is specifically shown in Table 1.
The each component of 1 embodiment of table 1~12 and parts by weight
The soluble granule of embodiment 13~24
DCPTA, active component B, binding agent (can add to be not added with), colouring agent, dispersant, wetting agent, filler are being mixed It is well mixed in cylinder, is passing through extruder grain, drying, and screened obtained soluble granule product of the present invention, tool Body is shown in Table 2.
The each component of 2 embodiment of table 13~24 and parts by weight
The soluble powder of embodiment 25~36
DCPTA, active component B, dispersant, wetting agent, stabilizer (can add to be not added with), filler are mixed in mixed cylinder Close uniformly, remixed after airslide disintegrating mill crushes uniformly, you can soluble powder product of the present invention is made, is specifically shown in Table 3.
The each component of 3 embodiment of table 25~36 and parts by weight
The soluble liquid of embodiment 37~44
Emulsifying agent, cosolvent are well mixed by high speed shear, add DCPTA, active component B, the ball in ball mill Mill 2~3 hours, makes diameter of particle all below 5 μm, surplus is supplied with solvent, you can solubility of the present invention is made Liquor product, is specifically shown in Table 4.
The each component of 4 embodiment of table 37~44 and parts by weight
The water dispersible granules of embodiment 45~52
DCPTA, active component B, dispersant, wetting agent, disintegrant, filler etc. are needed through air-flow crushing together Particle diameter, add other auxiliary agents such as binding agent (can add to be not added with), obtain pelletize materials.Item is quantified into the fluid bed system of feeding In grain drying machine after granulation and drying, you can water dispersible granules product of the present invention is made, is specifically shown in Table 5.
The each component of 5 embodiment of table 45~52 and content
The aqua of embodiment 53~60
DCPTA, active component B, wetting agent, antifreeze (can add to be not added with), solvent, deionized water etc. are mixed together, The aqua product of the present composition is made, is specifically shown in Table 6.
The each component of 6 embodiment of table 53~60 and parts by weight
By Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin exchange or trifloxystrobin, ZJ0712, ether bacterium in table 1-6 Amine, orysastrobin, ZEN 90160, kresoxim-methyl, the Fluoxastrobin in pyraoxystrobin substitution tables, kresoxim-methyl, fluoxastrobin, pyrazoles ether bacterium Novel formulation can be made in ester.
The microcapsule suspending agent of embodiment 61~63
DCPTA, active component B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, in shearing bar Under part, by oil phase be added to containing emulsifying agent, pH adjusting agent, dispersant aqueous phase solution in, surplus is supplied with deionized water, two Kind material reacts in oil-water interfaces, forms high score ascus wall, the well dispersed microcapsule suspending agent of the present composition is made Product.Specifically it is shown in Table 7.
The each component of 7 embodiment of table 61~63 and parts by weight
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey It is fixed, clear and definite two kinds of medicaments compound by a certain percentage after synergy ratio (SR), SR < 0.5 are antagonism, 0.5≤SR≤1.5 For summation action, SR > 1.5 are synergistic effect, on this basis, then carry out field test.
Test method:After prerun determines the effective inhibition concentration scope of each medicament, medicament sets 5 respectively by active constituent content Individual dosage processing, if clear water compares.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed Rate method determines virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, calculates the net growth of each processing Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm value (x), with minimum Square law tries to achieve virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to Wadley methods Two medicament different ratio synergy ratios (SR) are calculated, SR < 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action, SR > 1.5 are synergistic effect.Calculation formula is as follows:
Wherein:A, b is respectively active components A and active component B ratio shared in combination;
A is DCPTA;
B is selected from Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin, oxime ether bacterium One of amine, ZEN 90160, kresoxim-methyl, pyraoxystrobin are planted.Application Example two:
For trying disease:Peronophythora litchi
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:Effective suppression of DCPTA and Fluoxastrobin active compound and the two different ratio mixture is determined by pilot study Concentration range processed.
Toxicity test result
Toxicity test analysis of results table of the DCPTA of table 7 with azoxystrobin compound to peronophythora litchi
As shown in Table 7, DCPTA is matched in 1 80~80 ︰ 1 of ︰ to the synergy ratio SR of peronophythora litchi with Fluoxastrobin 1.5 are all higher than, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when matching somebody with somebody for DCPTA and Fluoxastrobin Than in 1 25~15 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.40.Tested through applicant and find DCPTA Optimum ratio with Fluoxastrobin is 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1st, 2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16, 1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, especially when DCPTA and Fluoxastrobin weight ratio are 1: Synergy ratio is maximum when 4, and synergistic effect is the most obvious.
Application Example three:
For trying disease:Powdery mildew of cucumber
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:Effective suppression of DCPTA and kresoxim-methyl active compound and the two different ratio mixture is determined by pilot study Concentration range processed.
Toxicity test result
The DCPTA of table 8 compounds the toxicity test analysis of results table to powdery mildew of cucumber with kresoxim-methyl
As shown in Table 8, DCPTA matches equal to the synergy ratio SR of powdery mildew of cucumber in 1 80~80 ︰ 1 of ︰ with kresoxim-methyl More than 1.5, illustrate that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when the proportioning of DCPTA and kresoxim-methyl In 1 25~20 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.30.Through applicant test find DCPTA with The optimum ratio of kresoxim-methyl be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1, 8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12nd, 1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, especially when DCPTA is 1 with kresoxim-methyl weight ratio:Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example four:
For trying disease:Powdery mildew of cucumber
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:The effective of DCPTA and fluoxastrobin active compound and the two different ratio mixture is determined by pilot study Inhibition concentration scope.
Toxicity test result
The DCPTA of table 9 compounds the toxicity test analysis of results table to powdery mildew of cucumber with fluoxastrobin
As shown in Table 9, DCPTA is matched in 1 80~80 ︰ 1 of ︰ to the synergy ratio SR of powdery mildew of cucumber with fluoxastrobin 1.5 are all higher than, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when DCPTA and fluoxastrobin For proportioning in 1 20~20 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.20.Tested through applicant and find volume increase The optimum ratio of amine and fluoxastrobin is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1st, 9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1:2nd, 1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10th, 1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, especially when DCPTA and fluoxastrobin Weight ratio is 1:Synergy ratio is maximum when 2, and synergistic effect is the most obvious.
Application Example five:
For trying disease:Cucumber downy mildew
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:Having for DCPTA and pyraclostrobin active compound and the two different ratio mixture is determined by pilot study Imitate inhibition concentration scope.
Toxicity test result
The DCPTA of table 10 compounds the toxicity test analysis of results table to cucumber downy mildew with pyraclostrobin
As shown in Table 10, DCPTA is matched in 1 80~80 ︰ 1 of ︰ to the synergy ratio of cucumber downy mildew with pyraclostrobin SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when DCPTA and pyrazoles ether bacterium For the proportioning of ester in 1 25~20 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.25.Test and find through applicant The optimum ratio of DCPTA and pyraclostrobin be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1, 11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9th, 1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24, 1 ︰ 25, especially when DCPTA and pyraclostrobin weight ratio are 1:Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example six
For studying thing:Tomato
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:DCPTA and the regulation plant life of active component B both different ratio mixture are determined by pilot study Long concentration range.
The DCPTA of table 11 and regulation growth of the mixed liquid of active component B and its different proportion to tomato
As shown in Table 11, after DCPTA and active component B are used in mixed way, can activated plant metabolic system and give birth to plant Long quickening vigor enhancing, promotes plant cell to increase, and root activity is strengthened, and reaches volume increase purpose, and DCPTA exists with active component B During 1 80~80 ︰ 1 of ︰, there is stronger adjustment effect.
Found through experiment:After DCPTA and active component B compounding to the peronospora tabacina in various crop, anthracnose, rust, Downy mildew, epidemic disease, leaf mold, shot hole, powdery mildew, scab, blight dis-ease, anthrachose of grape, black spot, leaf spot, spot fallen leaves The preventing and treating of disease, brown spot, spike rot, glume blight or net blotch has obvious synergistic effect, and synergy ratio SR is all higher than 1.5.
Effect experiment part:Test medicine is researched and developed by Shaanxi Welch Crop Protection Co., Ltd., provided, comparison medicament 125mg/l DCPTAs aqua (autogamy), 25% Fluoxastrobin suspending agent (purchased in market), 30% kresoxim-methyl wettable powder (purchased in market), 250g/L pyraclostrobin missible oils (purchased in market), 10% fluoxastrobin missible oil (purchased in market).
The DCPTA of Application Example seven is given birth to fractions of active ingredient B and its compounding preventing and treating powdery mildew of cucumber drug effect and regulation Long Experiment on Function
This test arrangement investigates powdery mildew of cucumber disease index before Xian District, Shanxi Province suburban area, medicine, occurs just in disease Phase dispenser, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser Rate.Result of the test is as follows:
The DCPTA of table 12 and fractions of active ingredient B compoundings preventing and treating powdery mildew of cucumber drug effect and regulation growth experiment
As can be seen from Table 12, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat powdery mildew of cucumber, through application People, which tests, finds DCPTA with can also effectively prevent and treat cucumber downy mildew, scab, blight dis-ease after fractions of active ingredient B compoundings, Prevention effect is above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and make plant growth Quickening vigor strengthens, and strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example eight grows with fractions of active ingredient B and its compounding preventing and treating capsicum epidemic disease drug effect and regulation Experiment on Function
This test arrangement investigates capsicum epidemic disease disease index before Xianyang, Shanxi province city Liquan County, medicine, occurs just in disease Phase dispenser, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser Rate.Result of the test is as follows:
The DCPTA of table 13 and fractions of active ingredient B compoundings preventing and treating capsicum epidemic disease drug effect and regulation growth experiment
As can be seen from Table 13, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat capsicum epidemic disease, through applicant Experiment finds that DCPTA with can also effectively prevent and treat pepper anthracnose, powdery mildew, anthracnose after fractions of active ingredient B compoundings, is prevented Control effect and be above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and add plant growth Fast vigor enhancing, strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example nine is given birth to fractions of active ingredient B and its compounding preventing and treating wheat smut drug effect and regulation Long Experiment on Function
This test arrangement investigates wheat smut disease index before Xianyang, Shanxi province city Liquan County, medicine, occurs in disease Dispenser at initial stage, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser Rate.Result of the test is as follows:
The DCPTA of table 14 and fractions of active ingredient B compoundings preventing and treating wheat smut drug effect and regulation growth experiment
As can be seen from Table 14, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat wheat smut, through application People, which tests, finds that DCPTA with can also effectively prevent and treat wheat rust, banded sclerotial blight, powdery mildew after fractions of active ingredient B compoundings, is prevented Control effect and be above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and add plant growth Fast vigor enhancing, strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example ten is given birth to fractions of active ingredient B and its compounding preventing and treating downy mildew of garpe drug effect and regulation Long Experiment on Function
This test arrangement investigates downy mildew of garpe disease index before Shaanxi Province Weinan City Dali County, medicine, occurs in disease Dispenser at initial stage, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser Rate.Result of the test is as follows:
The DCPTA of table 15 and fractions of active ingredient B compoundings preventing and treating downy mildew of garpe drug effect and regulation growth experiment
As can be seen from Table 15, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat downy mildew of garpe, through application People, which tests, finds DCPTA with can also effectively prevent and treat uncinula necator, anthracnose, anthrachose of grape after fractions of active ingredient B compoundings, Prevention effect is above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and make plant growth Quickening vigor strengthens, and strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example 11 and fractions of active ingredient B and its compounding preventing and treating sigatoka drug effect and regulation Growth is tested
This test arrangement investigates sigatoka disease index before Xishuangbanna of Yunnan province, medicine, in disease early period of origination Dispenser, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth rate of crop is investigated after second of dispenser. Result of the test is as follows:
The DCPTA of table 16 and fractions of active ingredient B compoundings preventing and treating sigatoka drug effect and regulation growth experiment
As can be seen from Table 16, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat sigatoka, through application People test find can also effectively to prevent and treat after DCPTA and fractions of active ingredient B compounding banana spike rot, leaf spot, anthracnose, Scab, prevention effect are above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and make Plant growth accelerates vigor enhancing, strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The experiment by different places throughout the country is drawn afterwards, DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyrrole To a variety of after azoles kresoxim-methyl, trifloxystrobin, ZJ0712, dimoxystrobin, orysastrobin, ZEN 90160, kresoxim-methyl, pyraoxystrobin compounding Peronospora tabacina, anthracnose, rust, downy mildew, epidemic disease, leaf mold, shot hole, powdery mildew, scab, blight dis-ease on crop, The preventive effect of the Common Diseases such as anthrachose of grape, black spot, leaf spot, spot defoliation, brown spot, spike rot, glume blight or net blotch It is obvious better than single dose preventive effect, synergistic effect more than 96%.

Claims (6)

1. a kind of increase composition containing the antibacterial of DCPTA and methoxy acrylic, effective active composition is active components A With active component B, it is characterised in that:Active components A and active component B weight ratio are the ︰ 80 of 80 ︰ 1~1, described activity into It is DCPTA to divide A, and active component B is selected from one of Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin kind.
2. according to claim 1 increase composition containing the antibacterial of DCPTA and methoxy acrylic, its feature exists In:Active components A and active component B weight ratio are the ︰ 40 of 40 ︰ 1~1 in composition.
3. according to claim 2 increase composition containing the antibacterial of DCPTA and methoxy acrylic, its feature exists In:
It is the ︰ 25 of 15 ︰ 1~1 to the weight of DCPTA and Fluoxastrobin ratio;
It is the ︰ 25 of 20 ︰ 1~1 to the weight of DCPTA and kresoxim-methyl ratio;
It is the ︰ 20 of 20 ︰ 1~1 to the weight of DCPTA and fluoxastrobin ratio;
It is the ︰ 25 of 20 ︰ 1~1 to the weight of DCPTA and pyraclostrobin ratio;.
4. according to any one of claim 1 to 3 increase containing the antibacterial of DCPTA and methoxy acrylic combines Thing, it is characterised in that:Composition is made wettable powder, soluble granule, soluble powder, soluble liquid, moisture and dissipated Granula, aqua or microcapsule suspending agent.
5. according to claim 4 increase composition for preventing and treating work containing the antibacterial of DCPTA and methoxy acrylic Thing disease and the purposes for promoting plant growth.
6. purposes according to claim 5, it is characterised in that:Described disease include peronospora tabacina, anthracnose, rust, Downy mildew, epidemic disease, leaf mold, shot hole, powdery mildew, scab, blight dis-ease, anthrachose of grape, black spot, leaf spot, spot fallen leaves Disease, brown spot, spike rot, glume blight or net blotch.
CN201610344696.9A 2016-05-21 2016-05-21 It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic Withdrawn CN107396926A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107853311A (en) * 2017-12-06 2018-03-30 郑州郑氏化工产品有限公司 A kind of DCPTA and bactericide two-spot complex composition
CN108760963A (en) * 2018-05-28 2018-11-06 广东省农业科学院植物保护研究所 The high performance liquid chromatography tandem mass spectrum analysis method of pyraclostrobin and its metabolin

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105475315A (en) * 2015-12-18 2016-04-13 广东中迅农科股份有限公司 Pesticide composition containing pyraclostrobin and naphthylacetic acid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105475315A (en) * 2015-12-18 2016-04-13 广东中迅农科股份有限公司 Pesticide composition containing pyraclostrobin and naphthylacetic acid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107853311A (en) * 2017-12-06 2018-03-30 郑州郑氏化工产品有限公司 A kind of DCPTA and bactericide two-spot complex composition
CN108760963A (en) * 2018-05-28 2018-11-06 广东省农业科学院植物保护研究所 The high performance liquid chromatography tandem mass spectrum analysis method of pyraclostrobin and its metabolin

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Application publication date: 20171128