CN107396926A - It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic - Google Patents
It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic Download PDFInfo
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- CN107396926A CN107396926A CN201610344696.9A CN201610344696A CN107396926A CN 107396926 A CN107396926 A CN 107396926A CN 201610344696 A CN201610344696 A CN 201610344696A CN 107396926 A CN107396926 A CN 107396926A
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- China
- Prior art keywords
- dcpta
- crop
- fluoxastrobin
- antibacterial
- composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 17
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 48
- 201000010099 disease Diseases 0.000 claims abstract description 47
- 239000005784 Fluoxastrobin Substances 0.000 claims abstract description 39
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims abstract description 39
- 239000005800 Kresoxim-methyl Substances 0.000 claims abstract description 29
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims abstract description 29
- 230000000694 effects Effects 0.000 claims abstract description 19
- 239000005869 Pyraclostrobin Substances 0.000 claims abstract description 17
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 241000221785 Erysiphales Species 0.000 claims description 16
- 241000233679 Peronosporaceae Species 0.000 claims description 11
- 230000008635 plant growth Effects 0.000 claims description 7
- 239000000375 suspending agent Substances 0.000 claims description 7
- 239000004563 wettable powder Substances 0.000 claims description 7
- 206010039509 Scab Diseases 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000003094 microcapsule Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 5
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 5
- 240000006365 Vitis vinifera Species 0.000 claims description 5
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 206010027146 Melanoderma Diseases 0.000 claims description 4
- 241000582441 Peronospora tabacina Species 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 20
- 150000001875 compounds Chemical class 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 230000002503 metabolic effect Effects 0.000 abstract description 7
- 239000000575 pesticide Substances 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000003337 fertilizer Substances 0.000 abstract 1
- 230000000855 fungicidal effect Effects 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- 230000000153 supplemental effect Effects 0.000 abstract 1
- 238000013329 compounding Methods 0.000 description 28
- 238000012360 testing method Methods 0.000 description 25
- 239000003814 drug Substances 0.000 description 23
- 230000012010 growth Effects 0.000 description 21
- 239000004480 active ingredient Substances 0.000 description 20
- 238000002474 experimental method Methods 0.000 description 18
- 230000003449 preventive effect Effects 0.000 description 17
- 240000008067 Cucumis sativus Species 0.000 description 14
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 14
- 241000196324 Embryophyta Species 0.000 description 12
- 230000033228 biological regulation Effects 0.000 description 12
- 239000002270 dispersing agent Substances 0.000 description 11
- 239000000080 wetting agent Substances 0.000 description 11
- 230000000857 drug effect Effects 0.000 description 10
- 239000012071 phase Substances 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- -1 ZJ0712 Chemical compound 0.000 description 8
- 239000000470 constituent Substances 0.000 description 8
- 239000000945 filler Substances 0.000 description 8
- URXNNPCNKVAQRA-XMHGGMMESA-N pyraoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C=2C=CC(Cl)=CC=2)=NN1C URXNNPCNKVAQRA-XMHGGMMESA-N 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 239000005857 Trifloxystrobin Substances 0.000 description 7
- JHIPUJPTQJYEQK-ZLHHXESBSA-N orysastrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1CO\N=C(/C)\C(=N\OC)\C(\C)=N\OC JHIPUJPTQJYEQK-ZLHHXESBSA-N 0.000 description 7
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 7
- 239000005762 Dimoxystrobin Substances 0.000 description 6
- WXUZAHCNPWONDH-DYTRJAOYSA-N dimoxystrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1COC1=CC(C)=CC=C1C WXUZAHCNPWONDH-DYTRJAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000002566 Capsicum Nutrition 0.000 description 5
- 206010067482 No adverse event Diseases 0.000 description 5
- 241000209140 Triticum Species 0.000 description 5
- 235000021307 Triticum Nutrition 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000013401 experimental design Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000004562 water dispersible granule Substances 0.000 description 5
- 240000008574 Capsicum frutescens Species 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000001390 capsicum minimum Substances 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 230000002708 enhancing effect Effects 0.000 description 4
- 244000183278 Nephelium litchi Species 0.000 description 3
- 241000233614 Phytophthora Species 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 239000006184 cosolvent Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 241001530056 Athelia rolfsii Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- 206010011732 Cyst Diseases 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 208000031513 cyst Diseases 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 235000021374 legumes Nutrition 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003217 pyrazoles Chemical class 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 239000005730 Azoxystrobin Substances 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000510928 Erysiphe necator Species 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 241000233629 Phytophthora parasitica Species 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- VSQUZVLNMULDCY-UHFFFAOYSA-N [O].C1=CC=NC=C1 Chemical compound [O].C1=CC=NC=C1 VSQUZVLNMULDCY-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000010165 autogamy Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000007938 effervescent tablet Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229940095686 granule product Drugs 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000006372 lipid accumulation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/08—Amines; Quaternary ammonium compounds containing oxygen or sulfur
- A01N33/10—Amines; Quaternary ammonium compounds containing oxygen or sulfur having at least one oxygen or sulfur atom directly attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Increase composition containing the antibacterial of DCPTA and methoxy acrylic the present invention relates to a kind of, effective active composition is active components A and active component B composition pesticide, and active components A is DCPTA, and active component B is selected from any one following compound:Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, the present composition has greater activity to the multiple diseases in various crop, and there is obvious synergistic effect, expand fungicidal spectrum, increase effective absorption of the crop to fertilizer simultaneously, supplemental crop inferior position part well grows, and adjusts the balance of crop internal water, so as to activate the metabolic system of crop, crop cell is promoted to increase, the characteristics of root activity is strengthened.
Description
Technical field
The invention belongs to technical field of pesticide, is related to a kind of antibacterial growth group containing DCPTA and methoxy acrylic
Application of the compound on crops.
Technical background
DCPTA is absorbed by the stem and leaf of plant, and nucleus is directly acted in plant, is strengthened the activity of enzyme and is increased
Add the content of slurries, grease and the class fat of plant, increase income crop yield.Significantly strengthen the photosynthesis of crop, make
With rear blade inhales aobvious greening, thickening, change is big, increase the material such as the absorption to carbon dioxide and utilization rate, increase protein, lipid
Accumulation storage, promote cell division and growth.
Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin, orysastrobin, pyridine
Oxygen bacterium ester, kresoxim-methyl, pyraoxystrobin belong to triazole bactericidal agent, are widely used in the disease of crops.
However, in the real process of agricultural production, controlling disease is easiest to generate the problem that the production of disease drug resistance
It is raw.Different cultivars composition is compounded, and is to prevent and treat the very common method of resistance disease.Heterogeneity is compounded, according to reality
Application effect, to judge that certain compounding is synergy plus and or antagonism.In most cases, the compounding effect of sterilization
All it is additive effect, really there is that the compounding of synergistic effect is seldom, especially synergistic effect is clearly, synergy ratio is very high answers
With just less.Study, found DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, oxime by inventor
Good synergy can be produced after bacterium ester, ZJ0712, dimoxystrobin, orysastrobin, ZEN 90160, kresoxim-methyl, pyraoxystrobin compounding
Effect, and on DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, ether bacterium
Amine, orysastrobin, ZEN 90160, kresoxim-methyl, the relevant report of pyraoxystrobin compounding not yet disclose.
The content of the invention
The purpose of the present invention is to propose to it is a kind of with synergistic function, use cost is low, effect is good contains DCPTA
Antibacterial volume increase composition.
The present invention is to be achieved through the following technical solutions:
A kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic, composition is active components A and work
Property composition B, active components A and active component B weight ratio be the ︰ 80 of 80 ︰ 1~1, and described active components A is DCPTA, active
Composition B is selected from Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin, orysastrobin, pyridine
One of oxygen bacterium ester, kresoxim-methyl, pyraoxystrobin are planted, and active components A and active component B more excellent weight ratio are 40 ︰ 1 in composition
~1 ︰ 40;It is the ︰ 25 of 15 ︰ 1~1 wherein to the weight of DCPTA and Fluoxastrobin ratio, is 20 ︰ to the weight of DCPTA and kresoxim-methyl ratio
1~1 ︰ 25, it is the ︰ 20 of 20 ︰ 1~1 to the weight of DCPTA and fluoxastrobin ratio, is to the weight of DCPTA and pyraclostrobin ratio
The ︰ 25 of 20 ︰ 1~1.
It is proposed by the present invention to increase composition for preventing and treating crops containing the antibacterial of DCPTA and methoxy acrylic
The purposes of upper disease, described crops include cereal crops, legume crop, fibre crops, sugar crop, melon crop, water
Orchard crop, dry fruit crop, hobby crop, root crop, oil crops, flower crop, medicinal crop, crop,
Green manure pasture crop;Described disease includes leaf spot, scab, false smut, rust, gray mold, powdery mildew, spot fallen leaves
Disease, banded sclerotial blight, brown rot, leaf blight, epidemic disease, anthrachose of grape, spot blight, black spot, anthracnose, shot hole, smut, wheel line
Disease, white rot, rice blast, bakanae disease, damping-off or sclerotiniose.
Described increases composition, wherein effective active composition content containing the antibacterial of DCPTA and methoxy acrylic
Account for the 0.0001%~80% of gross weight, preferably 0.001%~50%.
Described increases composition for preventing and treating crop disease and rush containing the antibacterial of DCPTA and methoxy acrylic
Enter the purposes of plant growth.
Surfactant selected by the antibacterial volume increase composition of the present invention is known in those skilled in the art:Can be with
One or more in dispersant, wetting agent, thickener or defoamer.This can also be contained according to different dosage forms, in preparation
Stabilizer, antifreeze well known to art personnel etc..
The antibacterial volume increase composition of the present invention, can be processed into acceptable formulation on any agricultural chemicals on demand, wherein excellent
Formulation is selected to be hanged for wettable powder, soluble granule, soluble powder, soluble liquid, water dispersible granules, aqua or micro-capsule
Floating agent, can also be made aqueous emulsion, microemulsion, suspending agent, effervescent tablet, seed coat agent.
Composition includes following constituent content when wettable powder is made:Active components A 0.01%~80%, active component
B 0.0001%~80%, dispersant 2%~10%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when soluble granule is made:Active components A 0.01%~80%, activity into
Point B0.0001%~80%, binding agent 0~8%, colouring agent 0.1%-2%, dispersant 2%~10%, wetting agent 2%~
10%th, filler surplus.
Composition includes following constituent content when soluble powder is made:Active components A 0.01%~80%, active component
B 0.0001%~80%, dispersant 2%~8%, wetting agent 1%-7%, stabilizer 0~5%, filler surplus.
Composition includes following constituent content when soluble liquid is made:Active components A 0.01%~50%, active component
B 0.0001%~50%, emulsifying agent 1%~10%, cosolvent 2%~6%, solvent add to 100%.
Composition includes following constituent content when water dispersible granules are made:Active components A 0.01%~80%, activity into
Point B 0.0001%~80%, dispersant 3%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~
8%th, filler surplus.
Composition includes following constituent content when aqua is made:Active components A 0.01%~50%, active component B
0.0001%~50%, cosolvent 2%~6%, wetting agent 1%-10%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when microcapsule suspending agent is made:Active components A 0.01%~50%, active component
B 0.0001%~50%, macromolecule cyst material 2%~10%, dispersant 1%~10%, solvent 1%~10%, emulsifying agent
1%~7%, defoamer 0.01%~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
The wettable powder the key technical indexes of the present invention:
The soluble granule the key technical indexes of the present invention:
The soluble powder the key technical indexes of the present invention:
The soluble liquid the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The aqua the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The advantage of the invention is that:
(1) DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin,
After orysastrobin, ZEN 90160, kresoxim-methyl, pyraoxystrobin compounding, there is obvious synergy and lasting effect;(2) grain is made
Thing, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, tubers
Crop, oil crops, flower crop, medicinal crop, crop, the disease on green manure pasture crop have greater activity;(3)
Reduce pesticide usage amount, reduce residual quantity of the agricultural chemicals on crop, alleviate environmental pollution;(4) to person poultry safety, environment
Compatibility is good;And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~12
DCPTA, active component B, dispersant, wetting agent, filler are well mixed in mixed cylinder, through airslide disintegrating mill
Remixed after crushing uniformly, you can wettable powder product of the present invention is made, is specifically shown in Table 1.
The each component of 1 embodiment of table 1~12 and parts by weight
The soluble granule of embodiment 13~24
DCPTA, active component B, binding agent (can add to be not added with), colouring agent, dispersant, wetting agent, filler are being mixed
It is well mixed in cylinder, is passing through extruder grain, drying, and screened obtained soluble granule product of the present invention, tool
Body is shown in Table 2.
The each component of 2 embodiment of table 13~24 and parts by weight
The soluble powder of embodiment 25~36
DCPTA, active component B, dispersant, wetting agent, stabilizer (can add to be not added with), filler are mixed in mixed cylinder
Close uniformly, remixed after airslide disintegrating mill crushes uniformly, you can soluble powder product of the present invention is made, is specifically shown in
Table 3.
The each component of 3 embodiment of table 25~36 and parts by weight
The soluble liquid of embodiment 37~44
Emulsifying agent, cosolvent are well mixed by high speed shear, add DCPTA, active component B, the ball in ball mill
Mill 2~3 hours, makes diameter of particle all below 5 μm, surplus is supplied with solvent, you can solubility of the present invention is made
Liquor product, is specifically shown in Table 4.
The each component of 4 embodiment of table 37~44 and parts by weight
The water dispersible granules of embodiment 45~52
DCPTA, active component B, dispersant, wetting agent, disintegrant, filler etc. are needed through air-flow crushing together
Particle diameter, add other auxiliary agents such as binding agent (can add to be not added with), obtain pelletize materials.Item is quantified into the fluid bed system of feeding
In grain drying machine after granulation and drying, you can water dispersible granules product of the present invention is made, is specifically shown in Table 5.
The each component of 5 embodiment of table 45~52 and content
The aqua of embodiment 53~60
DCPTA, active component B, wetting agent, antifreeze (can add to be not added with), solvent, deionized water etc. are mixed together,
The aqua product of the present composition is made, is specifically shown in Table 6.
The each component of 6 embodiment of table 53~60 and parts by weight
By Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin exchange or trifloxystrobin, ZJ0712, ether bacterium in table 1-6
Amine, orysastrobin, ZEN 90160, kresoxim-methyl, the Fluoxastrobin in pyraoxystrobin substitution tables, kresoxim-methyl, fluoxastrobin, pyrazoles ether bacterium
Novel formulation can be made in ester.
The microcapsule suspending agent of embodiment 61~63
DCPTA, active component B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, in shearing bar
Under part, by oil phase be added to containing emulsifying agent, pH adjusting agent, dispersant aqueous phase solution in, surplus is supplied with deionized water, two
Kind material reacts in oil-water interfaces, forms high score ascus wall, the well dispersed microcapsule suspending agent of the present composition is made
Product.Specifically it is shown in Table 7.
The each component of 7 embodiment of table 61~63 and parts by weight
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
It is fixed, clear and definite two kinds of medicaments compound by a certain percentage after synergy ratio (SR), SR < 0.5 are antagonism, 0.5≤SR≤1.5
For summation action, SR > 1.5 are synergistic effect, on this basis, then carry out field test.
Test method:After prerun determines the effective inhibition concentration scope of each medicament, medicament sets 5 respectively by active constituent content
Individual dosage processing, if clear water compares.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed
Rate method determines virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, calculates the net growth of each processing
Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm value (x), with minimum
Square law tries to achieve virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to Wadley methods
Two medicament different ratio synergy ratios (SR) are calculated, SR < 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action,
SR > 1.5 are synergistic effect.Calculation formula is as follows:
Wherein:A, b is respectively active components A and active component B ratio shared in combination;
A is DCPTA;
B is selected from Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin, trifloxystrobin, ZJ0712, dimoxystrobin, oxime ether bacterium
One of amine, ZEN 90160, kresoxim-methyl, pyraoxystrobin are planted.Application Example two:
For trying disease:Peronophythora litchi
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:Effective suppression of DCPTA and Fluoxastrobin active compound and the two different ratio mixture is determined by pilot study
Concentration range processed.
Toxicity test result
Toxicity test analysis of results table of the DCPTA of table 7 with azoxystrobin compound to peronophythora litchi
As shown in Table 7, DCPTA is matched in 1 80~80 ︰ 1 of ︰ to the synergy ratio SR of peronophythora litchi with Fluoxastrobin
1.5 are all higher than, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when matching somebody with somebody for DCPTA and Fluoxastrobin
Than in 1 25~15 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.40.Tested through applicant and find DCPTA
Optimum ratio with Fluoxastrobin is 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰
1st, 2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,
1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, especially when DCPTA and Fluoxastrobin weight ratio are 1:
Synergy ratio is maximum when 4, and synergistic effect is the most obvious.
Application Example three:
For trying disease:Powdery mildew of cucumber
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:Effective suppression of DCPTA and kresoxim-methyl active compound and the two different ratio mixture is determined by pilot study
Concentration range processed.
Toxicity test result
The DCPTA of table 8 compounds the toxicity test analysis of results table to powdery mildew of cucumber with kresoxim-methyl
As shown in Table 8, DCPTA matches equal to the synergy ratio SR of powdery mildew of cucumber in 1 80~80 ︰ 1 of ︰ with kresoxim-methyl
More than 1.5, illustrate that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when the proportioning of DCPTA and kresoxim-methyl
In 1 25~20 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.30.Through applicant test find DCPTA with
The optimum ratio of kresoxim-methyl be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,
8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰
12nd, 1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, especially when
DCPTA is 1 with kresoxim-methyl weight ratio:Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example four:
For trying disease:Powdery mildew of cucumber
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:The effective of DCPTA and fluoxastrobin active compound and the two different ratio mixture is determined by pilot study
Inhibition concentration scope.
Toxicity test result
The DCPTA of table 9 compounds the toxicity test analysis of results table to powdery mildew of cucumber with fluoxastrobin
As shown in Table 9, DCPTA is matched in 1 80~80 ︰ 1 of ︰ to the synergy ratio SR of powdery mildew of cucumber with fluoxastrobin
1.5 are all higher than, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when DCPTA and fluoxastrobin
For proportioning in 1 20~20 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.20.Tested through applicant and find volume increase
The optimum ratio of amine and fluoxastrobin is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰
1st, 9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1:2nd, 1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰
10th, 1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, especially when DCPTA and fluoxastrobin
Weight ratio is 1:Synergy ratio is maximum when 2, and synergistic effect is the most obvious.
Application Example five:
For trying disease:Cucumber downy mildew
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:Having for DCPTA and pyraclostrobin active compound and the two different ratio mixture is determined by pilot study
Imitate inhibition concentration scope.
Toxicity test result
The DCPTA of table 10 compounds the toxicity test analysis of results table to cucumber downy mildew with pyraclostrobin
As shown in Table 10, DCPTA is matched in 1 80~80 ︰ 1 of ︰ to the synergy ratio of cucumber downy mildew with pyraclostrobin
SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when DCPTA and pyrazoles ether bacterium
For the proportioning of ester in 1 25~20 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.25.Test and find through applicant
The optimum ratio of DCPTA and pyraclostrobin be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,
11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰
9th, 1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,
1 ︰ 25, especially when DCPTA and pyraclostrobin weight ratio are 1:Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example six
For studying thing:Tomato
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design:DCPTA and the regulation plant life of active component B both different ratio mixture are determined by pilot study
Long concentration range.
The DCPTA of table 11 and regulation growth of the mixed liquid of active component B and its different proportion to tomato
As shown in Table 11, after DCPTA and active component B are used in mixed way, can activated plant metabolic system and give birth to plant
Long quickening vigor enhancing, promotes plant cell to increase, and root activity is strengthened, and reaches volume increase purpose, and DCPTA exists with active component B
During 1 80~80 ︰ 1 of ︰, there is stronger adjustment effect.
Found through experiment:After DCPTA and active component B compounding to the peronospora tabacina in various crop, anthracnose, rust,
Downy mildew, epidemic disease, leaf mold, shot hole, powdery mildew, scab, blight dis-ease, anthrachose of grape, black spot, leaf spot, spot fallen leaves
The preventing and treating of disease, brown spot, spike rot, glume blight or net blotch has obvious synergistic effect, and synergy ratio SR is all higher than 1.5.
Effect experiment part:Test medicine is researched and developed by Shaanxi Welch Crop Protection Co., Ltd., provided, comparison medicament
125mg/l DCPTAs aqua (autogamy), 25% Fluoxastrobin suspending agent (purchased in market), 30% kresoxim-methyl wettable powder (purchased in market),
250g/L pyraclostrobin missible oils (purchased in market), 10% fluoxastrobin missible oil (purchased in market).
The DCPTA of Application Example seven is given birth to fractions of active ingredient B and its compounding preventing and treating powdery mildew of cucumber drug effect and regulation
Long Experiment on Function
This test arrangement investigates powdery mildew of cucumber disease index before Xian District, Shanxi Province suburban area, medicine, occurs just in disease
Phase dispenser, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser
Rate.Result of the test is as follows:
The DCPTA of table 12 and fractions of active ingredient B compoundings preventing and treating powdery mildew of cucumber drug effect and regulation growth experiment
As can be seen from Table 12, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat powdery mildew of cucumber, through application
People, which tests, finds DCPTA with can also effectively prevent and treat cucumber downy mildew, scab, blight dis-ease after fractions of active ingredient B compoundings,
Prevention effect is above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and make plant growth
Quickening vigor strengthens, and strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example eight grows with fractions of active ingredient B and its compounding preventing and treating capsicum epidemic disease drug effect and regulation
Experiment on Function
This test arrangement investigates capsicum epidemic disease disease index before Xianyang, Shanxi province city Liquan County, medicine, occurs just in disease
Phase dispenser, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser
Rate.Result of the test is as follows:
The DCPTA of table 13 and fractions of active ingredient B compoundings preventing and treating capsicum epidemic disease drug effect and regulation growth experiment
As can be seen from Table 13, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat capsicum epidemic disease, through applicant
Experiment finds that DCPTA with can also effectively prevent and treat pepper anthracnose, powdery mildew, anthracnose after fractions of active ingredient B compoundings, is prevented
Control effect and be above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and add plant growth
Fast vigor enhancing, strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example nine is given birth to fractions of active ingredient B and its compounding preventing and treating wheat smut drug effect and regulation
Long Experiment on Function
This test arrangement investigates wheat smut disease index before Xianyang, Shanxi province city Liquan County, medicine, occurs in disease
Dispenser at initial stage, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser
Rate.Result of the test is as follows:
The DCPTA of table 14 and fractions of active ingredient B compoundings preventing and treating wheat smut drug effect and regulation growth experiment
As can be seen from Table 14, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat wheat smut, through application
People, which tests, finds that DCPTA with can also effectively prevent and treat wheat rust, banded sclerotial blight, powdery mildew after fractions of active ingredient B compoundings, is prevented
Control effect and be above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and add plant growth
Fast vigor enhancing, strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example ten is given birth to fractions of active ingredient B and its compounding preventing and treating downy mildew of garpe drug effect and regulation
Long Experiment on Function
This test arrangement investigates downy mildew of garpe disease index before Shaanxi Province Weinan City Dali County, medicine, occurs in disease
Dispenser at initial stage, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth of crop is investigated after second of dispenser
Rate.Result of the test is as follows:
The DCPTA of table 15 and fractions of active ingredient B compoundings preventing and treating downy mildew of garpe drug effect and regulation growth experiment
As can be seen from Table 15, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat downy mildew of garpe, through application
People, which tests, finds DCPTA with can also effectively prevent and treat uncinula necator, anthracnose, anthrachose of grape after fractions of active ingredient B compoundings,
Prevention effect is above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and make plant growth
Quickening vigor strengthens, and strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The DCPTA of Application Example 11 and fractions of active ingredient B and its compounding preventing and treating sigatoka drug effect and regulation
Growth is tested
This test arrangement investigates sigatoka disease index before Xishuangbanna of Yunnan province, medicine, in disease early period of origination
Dispenser, 5 days after dispenser, investigate disease indexes and calculate preventive effect within 15 days, 30 days, the growth rate of crop is investigated after second of dispenser.
Result of the test is as follows:
The DCPTA of table 16 and fractions of active ingredient B compoundings preventing and treating sigatoka drug effect and regulation growth experiment
As can be seen from Table 16, DCPTA after fractions of active ingredient B compoundings with can effectively prevent and treat sigatoka, through application
People test find can also effectively to prevent and treat after DCPTA and fractions of active ingredient B compounding banana spike rot, leaf spot, anthracnose,
Scab, prevention effect are above 96%, better than the preventive effect of single dose, preventive effect phase length, and can activated plant metabolic system and make
Plant growth accelerates vigor enhancing, strengthens the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The experiment by different places throughout the country is drawn afterwards, DCPTA and Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyrrole
To a variety of after azoles kresoxim-methyl, trifloxystrobin, ZJ0712, dimoxystrobin, orysastrobin, ZEN 90160, kresoxim-methyl, pyraoxystrobin compounding
Peronospora tabacina, anthracnose, rust, downy mildew, epidemic disease, leaf mold, shot hole, powdery mildew, scab, blight dis-ease on crop,
The preventive effect of the Common Diseases such as anthrachose of grape, black spot, leaf spot, spot defoliation, brown spot, spike rot, glume blight or net blotch
It is obvious better than single dose preventive effect, synergistic effect more than 96%.
Claims (6)
1. a kind of increase composition containing the antibacterial of DCPTA and methoxy acrylic, effective active composition is active components A
With active component B, it is characterised in that:Active components A and active component B weight ratio are the ︰ 80 of 80 ︰ 1~1, described activity into
It is DCPTA to divide A, and active component B is selected from one of Fluoxastrobin, kresoxim-methyl, fluoxastrobin, pyraclostrobin kind.
2. according to claim 1 increase composition containing the antibacterial of DCPTA and methoxy acrylic, its feature exists
In:Active components A and active component B weight ratio are the ︰ 40 of 40 ︰ 1~1 in composition.
3. according to claim 2 increase composition containing the antibacterial of DCPTA and methoxy acrylic, its feature exists
In:
It is the ︰ 25 of 15 ︰ 1~1 to the weight of DCPTA and Fluoxastrobin ratio;
It is the ︰ 25 of 20 ︰ 1~1 to the weight of DCPTA and kresoxim-methyl ratio;
It is the ︰ 20 of 20 ︰ 1~1 to the weight of DCPTA and fluoxastrobin ratio;
It is the ︰ 25 of 20 ︰ 1~1 to the weight of DCPTA and pyraclostrobin ratio;.
4. according to any one of claim 1 to 3 increase containing the antibacterial of DCPTA and methoxy acrylic combines
Thing, it is characterised in that:Composition is made wettable powder, soluble granule, soluble powder, soluble liquid, moisture and dissipated
Granula, aqua or microcapsule suspending agent.
5. according to claim 4 increase composition for preventing and treating work containing the antibacterial of DCPTA and methoxy acrylic
Thing disease and the purposes for promoting plant growth.
6. purposes according to claim 5, it is characterised in that:Described disease include peronospora tabacina, anthracnose, rust,
Downy mildew, epidemic disease, leaf mold, shot hole, powdery mildew, scab, blight dis-ease, anthrachose of grape, black spot, leaf spot, spot fallen leaves
Disease, brown spot, spike rot, glume blight or net blotch.
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CN107853311A (en) * | 2017-12-06 | 2018-03-30 | 郑州郑氏化工产品有限公司 | A kind of DCPTA and bactericide two-spot complex composition |
CN108760963A (en) * | 2018-05-28 | 2018-11-06 | 广东省农业科学院植物保护研究所 | The high performance liquid chromatography tandem mass spectrum analysis method of pyraclostrobin and its metabolin |
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CN105475315A (en) * | 2015-12-18 | 2016-04-13 | 广东中迅农科股份有限公司 | Pesticide composition containing pyraclostrobin and naphthylacetic acid |
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Patent Citations (1)
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CN105475315A (en) * | 2015-12-18 | 2016-04-13 | 广东中迅农科股份有限公司 | Pesticide composition containing pyraclostrobin and naphthylacetic acid |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107853311A (en) * | 2017-12-06 | 2018-03-30 | 郑州郑氏化工产品有限公司 | A kind of DCPTA and bactericide two-spot complex composition |
CN108760963A (en) * | 2018-05-28 | 2018-11-06 | 广东省农业科学院植物保护研究所 | The high performance liquid chromatography tandem mass spectrum analysis method of pyraclostrobin and its metabolin |
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Application publication date: 20171128 |