CN107394102A - Battery protecting apparatus, cover plate assembly and battery - Google Patents
Battery protecting apparatus, cover plate assembly and battery Download PDFInfo
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- CN107394102A CN107394102A CN201610328019.8A CN201610328019A CN107394102A CN 107394102 A CN107394102 A CN 107394102A CN 201610328019 A CN201610328019 A CN 201610328019A CN 107394102 A CN107394102 A CN 107394102A
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- 238000007789 sealing Methods 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000011253 protective coating Substances 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
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- 238000009423 ventilation Methods 0.000 claims 1
- 238000004880 explosion Methods 0.000 abstract description 4
- 229910001285 shape-memory alloy Inorganic materials 0.000 description 32
- 238000003466 welding Methods 0.000 description 11
- 230000002159 abnormal effect Effects 0.000 description 8
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000007747 plating Methods 0.000 description 5
- 230000005856 abnormality Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/574—Devices or arrangements for the interruption of current
- H01M50/581—Devices or arrangements for the interruption of current in response to temperature
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
本发明提供一种电池保护装置、盖板组件及电池,该电池保护装置包括盖板本体及温度记忆元件,所述盖板本体上设置有通气孔,所述温度记忆元件与盖板本体电连接并密封所述通气孔,所述温度记忆元件具有与第一电极端子断开的低温记忆形态及与第一电极端子导通的高温记忆形态,所述温度记忆元件能够在电池内部温度高于预设温控阀值时由低温记忆形态变形至高温记忆形态。本发明的电池保护装置,当电池内部温度超过温度记忆元件的预设温度阀值时,在第一电极端子与第二电极端子之间形成短路,利用盖板本体及温度记忆元件等结构的阻抗消耗了电池的残余能量,最大程度地降低电池起火或爆炸的风险。
The invention provides a battery protection device, a cover plate assembly and a battery. The battery protection device includes a cover plate body and a temperature memory element, the cover plate body is provided with a vent hole, and the temperature memory element is electrically connected to the cover plate body And seal the vent hole, the temperature memory element has a low-temperature memory form disconnected from the first electrode terminal and a high-temperature memory form connected to the first electrode terminal, and the temperature memory element can be used when the internal temperature of the battery is higher than the preset temperature. When the temperature control threshold is set, it is transformed from a low-temperature memory form to a high-temperature memory form. In the battery protection device of the present invention, when the internal temperature of the battery exceeds the preset temperature threshold value of the temperature memory element, a short circuit is formed between the first electrode terminal and the second electrode terminal, and the impedance of the structure of the cover body and the temperature memory element is used. The residual energy of the battery is consumed, minimizing the risk of battery fire or explosion.
Description
技术领域technical field
本发明属于电池安全防护技术领域,特别是涉及一种电池保护装置、盖板组件及电池。The invention belongs to the technical field of battery safety protection, and in particular relates to a battery protection device, a cover plate assembly and a battery.
背景技术Background technique
目前,绝大部分的电池其盖板上没有安全防护结构,盖板仅仅作为支撑极柱使用。当电池受到撞击、异物刺穿或者过热等滥用条件时,电池内部会发一系列复杂的电化学反应。当这些异常没有得到有效控制,电池发生热失控时,电池就会有起火甚至爆炸的危险。At present, most batteries have no safety protection structure on their cover plates, and the cover plates are only used as supporting poles. When the battery is subjected to abuse conditions such as impact, foreign object puncture or overheating, a series of complex electrochemical reactions will occur inside the battery. When these abnormalities are not effectively controlled and thermal runaway occurs in the battery, the battery may catch fire or even explode.
台湾专利TW093118829公开了一种电池保护装置,该电池具有至少二个导电端子、以及至少一导电引子,导电引子与导电端子保持接触以接通电路。该电池保护装置包含至少一断路单元,当环境温度高于一预定温度时,断路单元产生形变并使导电引子与导电端子分离以切断电路。该电池保护装置能够在电池发生热失控时,通过断路单元产生形变使导电引子与导电端子分离以切断电路,进而保护电池。Taiwan patent TW093118829 discloses a battery protection device, the battery has at least two conductive terminals and at least one conductive lead, and the conductive lead keeps in contact with the conductive terminals to connect the circuit. The battery protection device includes at least one disconnection unit. When the ambient temperature is higher than a predetermined temperature, the disconnection unit deforms and separates the conductive lead from the conductive terminal to cut off the circuit. The battery protection device can separate the conductive lead from the conductive terminal through the deformation of the breaking unit to cut off the circuit when the battery is thermally runaway, thereby protecting the battery.
但是,上述电池保护装置在电池发生热失控时,只是切断电路,切断电路时,由于电池电能并没有减小,往往电池内部还在进行复杂的电化学反应,这样,电池起火甚至爆炸的风险仍然较大。However, the above-mentioned battery protection device only cuts off the circuit when the battery is thermally runaway. When the circuit is cut off, because the battery power does not decrease, complex electrochemical reactions are often still going on inside the battery. In this way, the risk of battery fire or even explosion remains. larger.
发明内容Contents of the invention
本发明所要解决的技术问题是针对现有的采用切断电路方式进行电池保护的电池保护装置,在电池发生热失控而切断电路时电池电能并未减小,导致电池起火甚至爆炸的风险仍然较大的缺陷,提供一种电池保护装置。The technical problem to be solved by the present invention is aimed at the existing battery protection device that adopts the method of cutting off the circuit to protect the battery. When the battery is thermally out of control and the circuit is cut off, the battery power is not reduced, and the risk of causing the battery to catch fire or even explode is still relatively high. The invention provides a battery protection device.
本发明解决上述技术问题所采用的技术方案为:The technical solution adopted by the present invention to solve the problems of the technologies described above is:
提供一种电池保护装置,该电池具有第一电极端子及第二电极端子,第一电极端子及第二电极端子中的一个为正极端子,另一个为负极端子,所述电池保护装置包括盖板本体及温度记忆元件,所述盖板本体上设置有通气孔,所述温度记忆元件与盖板本体电连接并密封所述通气孔,所述温度记忆元件具有与第一电极端子断开的低温记忆形态及与第一电极端子导通的高温记忆形态,所述温度记忆元件能够在电池内部温度高于预设温控阀值时由低温记忆形态变形至高温记忆形态。A battery protection device is provided, the battery has a first electrode terminal and a second electrode terminal, one of the first electrode terminal and the second electrode terminal is a positive terminal, and the other is a negative terminal, the battery protection device includes a cover plate The main body and the temperature memory element, the cover body is provided with a vent hole, the temperature memory element is electrically connected to the cover body and seals the vent hole, and the temperature memory element has a low temperature that is disconnected from the first electrode terminal A memory form and a high-temperature memory form connected to the first electrode terminal, the temperature memory element can be transformed from a low-temperature memory form to a high-temperature memory form when the internal temperature of the battery is higher than a preset temperature control threshold.
进一步地,所述第一电极端子为负极端子,所述第二电极端子为正极端子。Further, the first electrode terminal is a negative terminal, and the second electrode terminal is a positive terminal.
进一步地,所述温度记忆元件为记忆合金或双金属片。Further, the temperature memory element is a memory alloy or a bimetallic sheet.
进一步地,所述预设温控阀值的取值范围为80-250℃。Further, the value range of the preset temperature control threshold is 80-250°C.
进一步地,所述电池保护装置还包括电连接在所述盖板本体与所述第二电极端子之间的短路电阻。Further, the battery protection device further includes a short-circuit resistor electrically connected between the cover body and the second electrode terminal.
进一步地,所述短路电阻的阻值R取值范围为:Further, the value range of the resistance R of the short-circuit resistor is:
1/(2Ic)<R<5/Ic,其中,Ic表示电池的充电电流的数值。1/(2Ic)<R<5/Ic, where Ic represents the value of the charging current of the battery.
根据本发明的电池保护装置,温度记忆元件与盖板本体电连接并密封所述通气孔,温度记忆元件具有与电池的第一电极端子断开的低温记忆形态及与第一电极端子导通的高温记忆形态,当电池内部温度超过温度记忆元件的预设温度阀值时,温度记忆元件根据“记忆”变形到预先进行基础处理的高温记忆形态,温度记忆元件与第一电极端子导通,由此,将第一电极端子、盖板本体及第二电极端子导通,进而在第一电极端子与第二电极端子之间形成短路,实现了电池内部短路,进而可以切断外部异常回路,把电池隔离出来,防止更大的安全隐患发生,防止因异常电池的引起连锁隐患。使得整个异常始于该异常电池,也终止于该异常电池,最大限度的降低电池滥用带来的风险。并且,发生短路时,利用盖板本体及温度记忆元件等结构的阻抗消耗了电池的残余能量,最大程度地降低电池起火或爆炸的风险。According to the battery protection device of the present invention, the temperature memory element is electrically connected to the cover plate body and seals the vent hole, and the temperature memory element has a low-temperature memory form disconnected from the first electrode terminal of the battery and a conductive electrode connected to the first electrode terminal. High-temperature memory form, when the internal temperature of the battery exceeds the preset temperature threshold of the temperature memory element, the temperature memory element is deformed according to the "memory" to the high-temperature memory form that has been pre-basically processed, and the temperature memory element is connected to the first electrode terminal. In this way, the first electrode terminal, the cover body and the second electrode terminal are connected, and then a short circuit is formed between the first electrode terminal and the second electrode terminal, which realizes the internal short circuit of the battery, and then can cut off the external abnormal circuit, and the battery Isolate it to prevent greater safety hazards from occurring, and prevent chain hazards caused by abnormal batteries. The whole abnormality starts from the abnormal battery and ends at the abnormal battery, so as to minimize the risk of battery abuse. Moreover, when a short circuit occurs, the residual energy of the battery is consumed by the impedance of the cover body and the temperature memory element, which minimizes the risk of battery fire or explosion.
另外,本发明还提供了一种盖板组件,包括第一电极端子、第二电极端子、用于所述第一电极端子与盖板本体之间绝缘密封的第一绝缘密封结构、用于所述第二电极端子与盖板本体之间密封的第二密封结构及上述的电池保护装置,所述盖板主体上设置有第一通孔及第二通孔,所述第一电极端子及第二电极端子分别插接在所述第一通孔及第二通孔中。In addition, the present invention also provides a cover assembly, including a first electrode terminal, a second electrode terminal, a first insulating and sealing structure for insulating and sealing between the first electrode terminal and the cover body, and a first insulating and sealing structure for the first electrode terminal and the cover body. The second sealing structure for sealing between the second electrode terminal and the cover plate body and the above battery protection device, the cover plate body is provided with a first through hole and a second through hole, the first electrode terminal and the second through hole The two electrode terminals are plugged into the first through hole and the second through hole respectively.
进一步地,所述盖板组件还包括连接在所述第一电极端子的外侧端的第一外引出片,所述温度记忆元件在低温记忆形态与所述第一外引出片断开,并在高温记忆形态与所述第一外引出片接触导通。Further, the cover plate assembly also includes a first lead-out piece connected to the outer end of the first electrode terminal, the temperature memory element is disconnected from the first lead-out piece in the low-temperature memory state, and is The shape is in contact with the first external lead-out piece.
进一步地,所述盖板组件还包括短路电阻及连接在所述第二电极端子的外侧端的第二外引出片,所述短路电阻电连接在所述盖板本体与所述第二外引出片之间。Further, the cover plate assembly also includes a short-circuit resistor and a second lead-out piece connected to the outer end of the second electrode terminal, the short-circuit resistor is electrically connected between the cover plate body and the second lead-out piece between.
进一步地,所述温度记忆元件朝向所述接触片的一侧表面设置金属镀层。Further, a metal plating layer is provided on a surface of the temperature memory element facing the contact piece.
进一步地,所述温度记忆元件设置有金属镀层以外的表面设置非金属防护涂层。Further, the temperature memory element is provided with a non-metallic protective coating on the surface other than the metal coating.
进一步地,所述第一绝缘密封结构包括由外向内依次套设在所述第一电极端子上的第一绝缘环、第一碟片及第一绝缘密封件,所述第一绝缘环固定在所述第一电极端子上,所述第一碟片的内沿设置在所述第一绝缘密封件与第一绝缘环之间,所述第一碟片的外沿设置在所述第一绝缘密封件与盖板本体之间,所述第一绝缘密封件连接在所述盖板本体与第一内引出片之间,所述第一内引出片固定在所述第一电极端子的内侧端。Further, the first insulating sealing structure includes a first insulating ring, a first disc and a first insulating sealing member which are sequentially sleeved on the first electrode terminal from outside to inside, and the first insulating ring is fixed on the On the first electrode terminal, the inner edge of the first disc is arranged between the first insulating seal and the first insulating ring, and the outer edge of the first disc is arranged on the first insulating ring. Between the seal and the cover body, the first insulating seal is connected between the cover body and the first inner lead-out piece, and the first inner lead-out piece is fixed on the inner end of the first electrode terminal .
进一步地,所述第二密封结构包括由外向内依次套设在所述第二电极端子上的第二绝缘环、第二碟片及第二绝缘密封件,所述第二绝缘环固定在所述第二电极端子上,所述第二碟片的内沿设置在所述第二绝缘密封件与第二绝缘环之间,所述第二碟片的外沿设置在所述第二绝缘密封件与盖板本体之间,所述第二绝缘密封件连接在所述盖板本体与第二内引出片之间,所述第二内引出片固定在所述第二电极端子的内侧端。Further, the second sealing structure includes a second insulating ring, a second disc, and a second insulating seal that are sequentially sleeved on the second electrode terminal from outside to inside, and the second insulating ring is fixed on the second electrode terminal. On the second electrode terminal, the inner edge of the second disc is set between the second insulating seal and the second insulating ring, and the outer edge of the second disc is set between the second insulating seal Between the cover plate body and the cover plate body, the second insulating seal is connected between the cover plate body and the second inner lead-out piece, and the second inner lead-out piece is fixed on the inner side end of the second electrode terminal.
另外,本发明还提供了一种电池,其包括上述的盖板组件。In addition, the present invention also provides a battery, which includes the above-mentioned cover assembly.
附图说明Description of drawings
图1是本发明一实施例提供的盖板组件的结构示意图;Fig. 1 is a schematic structural view of a cover assembly provided by an embodiment of the present invention;
图2是本发明一实施例提供的电池保护装置的正常工作状态(记忆合金处于低温记忆形态);Fig. 2 is a normal working state of the battery protection device provided by an embodiment of the present invention (memory alloy is in a low-temperature memory state);
图3是本发明一实施例提供的电池保护装置的短路状态(记忆合金处于高温记忆形态);Fig. 3 is a short-circuit state of the battery protection device provided by an embodiment of the present invention (the memory alloy is in a high-temperature memory state);
图4是本发明一实施例提供的盖板组件其第二电极端子附近的局部放大图。Fig. 4 is a partial enlarged view of the cover assembly provided by an embodiment of the present invention near the second electrode terminal.
说明书中的附图标记如下:The reference signs in the instructions are as follows:
1、盖板本体;101、第一通孔;102、第二通孔;103、通气孔;104、注液孔;2、第一电极端子;201、第一缓冲环;3、第一内引出片;4、第一外引出片;401、接触片;5、第二电极端子;501、第二缓冲环;6、第二内引出片;7、第二外引出片;8、记忆合金;9、短路电阻;10、第一绝缘密封结构;11、第二密封结构;12、防爆阀;13、注液孔保护结构;14、第一绝缘环;15、第一碟片;16、第一绝缘密封件;17、第一焊接保护片;18、第二绝缘环;19、第二碟片;20、第二绝缘密封件;21、第二焊接保护片。1. Cover body; 101. First through hole; 102. Second through hole; 103. Vent hole; 104. Liquid injection hole; 2. First electrode terminal; 201. First buffer ring; 3. First inner Lead-out piece; 4. First outer lead-out piece; 401. Contact piece; 5. Second electrode terminal; 501. Second buffer ring; 6. Second inner lead-out piece; 7. Second outer lead-out piece; 8. Memory alloy ; 9, short circuit resistance; 10, first insulating sealing structure; 11, second sealing structure; 12, explosion-proof valve; 13, liquid injection hole protection structure; 14, first insulating ring; 15, first disc; 16, 17. The first welding protection sheet; 18. The second insulating ring; 19. The second disc; 20. The second insulating sealing piece; 21. The second welding protection sheet.
具体实施方式detailed description
为了使本发明所解决的技术问题、技术方案及有益效果更加清楚明白,以下结合附图及实施例,对本发明进行进一步的详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In order to make the technical problems, technical solutions and beneficial effects solved by the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.
如图1所示,本发明一实施例提供的盖板组件,包括盖板本体1、第一电极端子2、第一内引出片3、第一外引出片4、第二电极端子5、第二内引出片6、第二外引出片7、记忆合金8、短路电阻9、用于第一电极端子2与盖板本体1之间的绝缘密封的第一绝缘密封结构10及用于第二电极端子5与盖板本体1之间的密封的第二密封结构11。其中,盖板本体1、记忆合金8及短路电阻9构成电池保护装置。所述短路电阻9电连接在所述盖板本体1与所述第二外引出片7之间。As shown in Figure 1, the cover assembly provided by an embodiment of the present invention includes a cover body 1, a first electrode terminal 2, a first inner lead-out piece 3, a first outer lead-out piece 4, a second electrode terminal 5, a first Two inner lead-out sheets 6, second outer lead-out sheets 7, memory alloy 8, short-circuit resistor 9, first insulating sealing structure 10 for insulating sealing between the first electrode terminal 2 and the cover plate body 1 and for the second A sealed second sealing structure 11 between the electrode terminal 5 and the cover body 1 . Wherein, the cover body 1 , memory alloy 8 and short circuit resistor 9 constitute a battery protection device. The short circuit resistor 9 is electrically connected between the cover body 1 and the second lead-out piece 7 .
本实施例中,所述短路电阻8的阻值R取值范围为:In this embodiment, the value range of the resistance R of the short-circuit resistor 8 is:
1/(2Ic)<R<5/Ic (1);1/(2Ic)<R<5/Ic (1);
其中,Ic表示电池的充电电流的数值。充电电流Ic的单位与阻值R的单位在同一层级,即若Ic的单位为安培,则短路电阻的阻值R的单位为欧姆;若Ic的单位为毫安,则短路电阻的阻值R的单位为毫欧。式(1)中,Ic仅表示数值大小。式(1)中短路电阻的阻值R优选范围,依据充电电源的不同而设计,这样,能够降低短路电阻产生过大的焦耳热。Among them, Ic represents the numerical value of the charging current of the battery. The unit of the charging current Ic is at the same level as the unit of the resistance R, that is, if the unit of Ic is ampere, the unit of the resistance R of the short-circuit resistance is ohms; if the unit of Ic is mA, the resistance R of the short-circuit resistance is The unit is milliohm. In formula (1), Ic only represents the numerical value. The optimal range of resistance R of the short-circuit resistance in formula (1) is designed according to different charging power sources, so that excessive Joule heat generated by the short-circuit resistance can be reduced.
本实施例中,温度记忆元件为记忆合金8。如图1所示,所述盖板主体1上设置有第一通孔101及第二通孔102,所述第一电极端子2及第二电极端子5分别插接在所述第一通孔101及第二通孔102中,所述第一内引出片3及第二内引出片6分别焊接在所述第一电极端子2及第二电极端子5的内侧端,所述第一外引出片4及第二外引出片7分别焊接在所述第一电极端子2及第二电极端子5的外侧端。In this embodiment, the temperature memory element is memory alloy 8 . As shown in Figure 1, the cover body 1 is provided with a first through hole 101 and a second through hole 102, and the first electrode terminal 2 and the second electrode terminal 5 are plugged into the first through hole respectively. 101 and the second through hole 102, the first inner lead-out piece 3 and the second inner lead-out piece 6 are respectively welded to the inner ends of the first electrode terminal 2 and the second electrode terminal 5, and the first outer lead-out piece The piece 4 and the second lead-out piece 7 are welded to the outer ends of the first electrode terminal 2 and the second electrode terminal 5 respectively.
如图1及图2所示,所述盖板本体1上设置有通气孔103,所述记忆合金8通过焊接或铆接的方式固定在所述通气孔103的边缘并密封所述通气孔103,在保证连接强度的情况下,记忆合金8与盖板本体1的连接区域应尽可能小。所述第一外引出片4远离所述第一电极端子2的一端向盖板本体1方向弯折形成与所述温度记忆元件相向的接触片401。由于,接触片401是第一外引出片4向盖板本体1方向弯折形成,进而接触片401更加靠近记忆合金8,这样,减小了记忆合金8与接触片401由断开到接触时,记忆合金8的形变量。As shown in Figures 1 and 2, the cover body 1 is provided with a vent hole 103, the memory alloy 8 is fixed on the edge of the vent hole 103 by welding or riveting and seals the vent hole 103, Under the condition of ensuring the connection strength, the connection area between the memory alloy 8 and the cover body 1 should be as small as possible. The end of the first lead-out piece 4 away from the first electrode terminal 2 is bent toward the cover body 1 to form a contact piece 401 facing the temperature memory element. Because the contact piece 401 is formed by bending the first outer lead-out piece 4 to the direction of the cover plate body 1, and then the contact piece 401 is closer to the memory alloy 8, thus reducing the time from disconnection to contact between the memory alloy 8 and the contact piece 401. , The deformation of memory alloy 8.
本实施例中,记忆合金8具有与第一电极端子2断开的低温记忆形态(图2所示的状态)及与第一电极端子2导通的高温记忆形态(图3所示的形态),所述记忆合金8在图2所示的低温记忆形态与所述第一外引出片4断开,并在图3所示的高温记忆形态与所述第一外引出片4的接触片401接触导通。所述记忆合金8能够在电池内部温度高于预设温控阀值时由图2所示的低温记忆形态变形至图3所示的高温记忆形态。In this embodiment, the memory alloy 8 has a low-temperature memory form (state shown in FIG. 2 ) disconnected from the first electrode terminal 2 and a high-temperature memory form (state shown in FIG. 3 ) connected to the first electrode terminal 2. , the memory alloy 8 is disconnected from the first lead-out piece 4 in the low-temperature memory form shown in FIG. Contact conduction. The memory alloy 8 can be transformed from the low-temperature memory form shown in FIG. 2 to the high-temperature memory form shown in FIG. 3 when the internal temperature of the battery is higher than the preset temperature control threshold.
本实施例中,记忆合金8优选为双程记忆合金。当然,在其它实施例中,也可以是单程记忆合金或者是全程记忆合金。记忆合金可以是但不限于Cu基、Ni基或Fe基记忆合金。In this embodiment, the memory alloy 8 is preferably a two-way memory alloy. Of course, in other embodiments, it may also be a one-way memory alloy or a full-range memory alloy. Memory alloys can be but not limited to Cu-based, Ni-based or Fe-based memory alloys.
本实施例中,所述预设温控阀值的取值范围为80-250℃。更进一步地的优选范围为80-150℃。即,当电池发生热失控时,内部温度快速上升至80-250℃之间的一个值时,记忆合金8由图2所示的低温记忆形态变形至图3所示的高温记忆形态,通过第一外引出片4的接触片401与记忆合金8的接触,将第一电极端子2与盖板本体1导通,而由于短路电阻9电连接在盖板本体1与第二外引出片7之间,使得此时,第一电极端子2与第二电极端子5之间短路。In this embodiment, the value range of the preset temperature control threshold is 80-250°C. A further preferred range is 80-150°C. That is, when thermal runaway occurs in the battery and the internal temperature rises rapidly to a value between 80-250°C, memory alloy 8 is deformed from the low-temperature memory form shown in FIG. 2 to the high-temperature memory form shown in FIG. The contact between the contact piece 401 of an outer lead-out piece 4 and the memory alloy 8 conducts the first electrode terminal 2 with the cover plate body 1, and due to the short circuit resistor 9 is electrically connected between the cover plate body 1 and the second outer lead-out piece 7 At this time, the first electrode terminal 2 and the second electrode terminal 5 are short-circuited.
本实施例中,如图1所示,所述盖板本体1上还设置有注液孔104及防爆阀12,所述注液孔104的外侧设置有注液孔保护结构13。In this embodiment, as shown in FIG. 1 , the cover body 1 is further provided with a liquid injection hole 104 and an explosion-proof valve 12 , and a liquid injection hole protection structure 13 is provided outside the liquid injection hole 104 .
本实施例中,为了保证第一外引出片4与记忆合金8接触良好,接触阻抗够低,记忆合金8朝向所述第一外引出片4的接触片401的一侧表面设置金属镀层。此处的金属镀层包括但不限于金、银及镍等导电性能优越且化学性能稳定的材料,此处优选银镀层,既然能满足低阻抗要求,又能很好的控制产品成本。金属镀层的厚度为5μm~60μm,进一步优选为8~20μm。In this embodiment, in order to ensure good contact between the first lead-out piece 4 and the memory alloy 8 and low enough contact resistance, the surface of the memory alloy 8 facing the contact piece 401 of the first lead-out piece 4 is provided with a metal plating layer. The metal plating here includes but is not limited to gold, silver, nickel and other materials with superior electrical conductivity and stable chemical properties. Silver plating is preferred here, since it can meet the low impedance requirement and can control the product cost well. The thickness of the metal plating layer is 5 μm to 60 μm, more preferably 8 to 20 μm.
本实施例中,为了防止记忆合金8里面的活性元素参与电化学反应,在记忆合金8的设置有金属镀层以外的表面设置非金属防护涂层,如PPS、PPO及氟碳涂层等。当非金属防护涂层的厚度小于30μm时,会因为非金属防护涂层的致密性原因,导致电池内部的电解液渗入,可能导致非金属防护涂层局部失效。当非金属防护涂层的厚度过厚时,很容易出现记忆合金8变形导致非金属防护涂层表面产生裂纹,且成本也会增加。因而,非金属防护涂层的厚度优选为30-300μm,进一步优选为50-150μm。In this embodiment, in order to prevent the active elements in the memory alloy 8 from participating in the electrochemical reaction, a non-metallic protective coating, such as PPS, PPO and fluorocarbon coating, is provided on the surface of the memory alloy 8 other than the metal coating. When the thickness of the non-metallic protective coating is less than 30 μm, due to the compactness of the non-metallic protective coating, the electrolyte inside the battery will infiltrate, which may lead to partial failure of the non-metallic protective coating. When the thickness of the non-metallic protective coating is too thick, deformation of the memory alloy 8 is likely to cause cracks on the surface of the non-metallic protective coating, and the cost will also increase. Therefore, the thickness of the non-metallic protective coating is preferably 30-300 μm, more preferably 50-150 μm.
本实施例中,如图2所示,所述第一绝缘密封结构10包括由外向内依次套设在所述第一电极端子2上的第一绝缘环14、第一碟片15及第一绝缘密封件16,所述第一绝缘环14固定在所述第一电极端子2上,所述第一碟片15的内沿设置在所述第一绝缘密封件16与第一绝缘环14之间,所述第一碟片15的外沿设置在所述第一绝缘密封件16与盖板本体1之间,所述第一绝缘密封件16连接在所述盖板本体1与第一内引出片3之间,所述第一内引出片3固定在所述第一电极端子2的内侧端。所述第一电极端子2的外侧端外周上形成有第一缓冲环201,所述第一缓冲环201焊接在所述第一绝缘环14上,第一缓冲环201能够缓冲第一电极端子2与第一绝缘环14的焊接应力。另外,第一绝缘密封件16与第一内引出片3之间还设置有第一焊接保护片17,以保护第一电极端子2与第一内引出片3的焊接,防止第一内引出片3焊接中被损坏。具体装配时,第一绝缘环14的外侧表面焊接在第一缓冲环201上,所述第一碟片15的内沿焊接在所述第一绝缘环14的内侧表面,所述第一碟片15的外沿焊接在盖板本体1的内侧表面,第一绝缘密封件16插入第一碟片15的内腔中,第一内引出片3与第一电极端子2的内侧端焊接,并以此支撑第一绝缘密封件16。In this embodiment, as shown in FIG. 2, the first insulating sealing structure 10 includes a first insulating ring 14, a first disc 15 and a first An insulating seal 16, the first insulating ring 14 is fixed on the first electrode terminal 2, and the inner edge of the first disc 15 is arranged between the first insulating seal 16 and the first insulating ring 14 Between, the outer edge of the first disc 15 is arranged between the first insulating seal 16 and the cover body 1, and the first insulating seal 16 is connected between the cover body 1 and the first inner Between the lead-out pieces 3 , the first inner lead-out piece 3 is fixed on the inner end of the first electrode terminal 2 . A first buffer ring 201 is formed on the outer periphery of the first electrode terminal 2, and the first buffer ring 201 is welded on the first insulating ring 14, and the first buffer ring 201 can buffer the first electrode terminal 2. Welding stress with the first insulating ring 14. In addition, a first welding protection sheet 17 is also provided between the first insulating seal 16 and the first inner lead sheet 3 to protect the welding of the first electrode terminal 2 and the first inner lead sheet 3 and prevent the first inner lead sheet from 3 Damaged during welding. During specific assembly, the outer surface of the first insulating ring 14 is welded on the first buffer ring 201, the inner edge of the first disc 15 is welded on the inner surface of the first insulating ring 14, and the first disc The outer edge of 15 is welded on the inner surface of the cover body 1, the first insulating seal 16 is inserted into the inner cavity of the first disc 15, the first inner lead-out piece 3 is welded to the inner end of the first electrode terminal 2, and This supports the first insulating seal 16 .
本实施例中,第一绝缘密封结构10及第二密封结构11采用类似的结构,即如图4所示,所述第二密封结构11包括由外向内依次套设在所述第二电极端子5上的第二绝缘环18、第二碟片19及第二绝缘密封件20,所述第二绝缘环18固定在所述第二电极端子5上,所述第二碟片19的内沿设置在所述第二绝缘密封件20与第二绝缘环18之间,所述第二碟片19的外沿设置在所述第二绝缘密封件20与盖板本体1之间,所述第二绝缘密封件20连接在所述盖板本体1与第二内引出片6之间,所述第二内引出片6固定在所述第二电极端子5的内侧端。所述第二电极端子5的外侧端外周上形成有第二缓冲环501,所述第二缓冲环501焊接在所述第二绝缘环18上,第二缓冲环501能够缓冲第二电极端子2与第二绝缘环16之间的焊接应力。另外,第二绝缘密封件20与第二内引出片6之间还设置有第二焊接保护片21,以保护第二电极端子5与第二内引出片6的焊接,防止第二内引出片6焊接中被损坏。具体装配时,第二绝缘环18的外侧表面焊接在第二缓冲环501上,所述第二碟片19的内沿焊接在所述第二绝缘环18的内侧表面,所述第二碟片19的外沿焊接在盖板本体1的内侧表面,第二绝缘密封件20插入第二碟片19的内腔中,第二内引出片6与第二电极端子5的内侧端焊接,并以此支撑第二绝缘密封件20。In this embodiment, the first insulating and sealing structure 10 and the second sealing structure 11 adopt a similar structure, that is, as shown in FIG. 5, the second insulating ring 18, the second disc 19 and the second insulating seal 20, the second insulating ring 18 is fixed on the second electrode terminal 5, and the inner edge of the second disc 19 It is arranged between the second insulating seal 20 and the second insulating ring 18, the outer edge of the second disc 19 is arranged between the second insulating seal 20 and the cover body 1, and the first Two insulating seals 20 are connected between the cover body 1 and the second inner lead-out piece 6 , and the second inner lead-out piece 6 is fixed on the inner side of the second electrode terminal 5 . A second buffer ring 501 is formed on the outer circumference of the outer end of the second electrode terminal 5, and the second buffer ring 501 is welded on the second insulating ring 18, and the second buffer ring 501 can buffer the second electrode terminal 2. The welding stress with the second insulating ring 16. In addition, a second welding protection sheet 21 is also provided between the second insulating seal 20 and the second inner lead sheet 6 to protect the welding of the second electrode terminal 5 and the second inner lead sheet 6 and prevent the second inner lead sheet from 6 was damaged during welding. During specific assembly, the outer surface of the second insulating ring 18 is welded on the second buffer ring 501, the inner edge of the second disc 19 is welded on the inner surface of the second insulating ring 18, and the second disc The outer edge of 19 is welded on the inner surface of the cover body 1, the second insulating seal 20 is inserted into the inner cavity of the second disc 19, the second inner lead-out piece 6 is welded to the inner end of the second electrode terminal 5, and This supports the second insulating seal 20 .
本实施例中,第一绝缘环14及第二绝缘环18可以是陶瓷绝缘环。第一碟片15、第二碟片19均为环形金属碟片,以提供良好的支撑。In this embodiment, the first insulating ring 14 and the second insulating ring 18 may be ceramic insulating rings. Both the first disc 15 and the second disc 19 are annular metal discs to provide good support.
当然,在其它实施例中,第一绝缘密封结构10与第二密封结构11也可以采用不同的结构,即第二密封结构11可以不提供盖板本体1与第二电极端子5之间的绝缘。当然,第一绝缘密封结构10与第二密封结构11还可以采用其它常规的结构形式。Of course, in other embodiments, the first insulating sealing structure 10 and the second sealing structure 11 may also adopt different structures, that is, the second sealing structure 11 may not provide insulation between the cover body 1 and the second electrode terminal 5 . Of course, the first insulating and sealing structure 10 and the second sealing structure 11 can also adopt other conventional structural forms.
另外,优选地,本实施例中,第一电极端子2为负极端子,第二电极端子5为正极端子。相应地,第一内引出片3、第一外引出片4为负极内引出片、负极外引出片,第二内引出片6、第二外引出片7为正极内引出片、正极外引出片。这样,短路电阻9连接在正极外引出片与盖板本体1之间,记忆合金8与负极外引出片相对。In addition, preferably, in this embodiment, the first electrode terminal 2 is a negative terminal, and the second electrode terminal 5 is a positive terminal. Correspondingly, the first inner lead-out sheet 3 and the first outer lead-out sheet 4 are the negative inner lead-out sheet and the negative electrode outer lead-out sheet, and the second inner lead-out sheet 6 and the second outer lead-out sheet 7 are the positive electrode inner lead-out sheet and the positive electrode outer lead-out sheet . In this way, the short-circuit resistor 9 is connected between the positive electrode lead-out piece and the cover plate body 1, and the memory alloy 8 is opposite to the negative electrode lead-out piece.
当然,在其它实施例中,也可以反过来设置,即第一电极端子2为正极端子,第二电极端子5为负极端子。由于盖板本体1是与电池壳体导通的,当第二电极端子为负极端子时,短路电阻连接在负极外引出片与盖板本体之间,从而将负极端子与壳体导通,会出现析锂现象,导致电池容量降低。因而,该实施例中,优选地,通过其它手段避免析锂现象。Of course, in other embodiments, it can also be reversed, that is, the first electrode terminal 2 is a positive terminal, and the second electrode terminal 5 is a negative terminal. Since the cover plate body 1 is connected to the battery case, when the second electrode terminal is the negative terminal, the short-circuit resistor is connected between the negative lead-out piece and the cover plate body, so that the negative terminal and the case are connected, and the The phenomenon of lithium precipitation occurs, resulting in a decrease in battery capacity. Therefore, in this embodiment, preferably, the phenomenon of lithium precipitation is avoided by other means.
上述实施例的电池保护装置,其原理如下:The principle of the battery protection device in the above embodiment is as follows:
当电池受到撞击、异物刺穿或者过热等滥用条件时,电池热失控,电池内部温度会随着热失控的发生而升高。当内部温度超过记忆合金8的预设温度阀值时,记忆合金8的金相组织发生变化,根据“记忆”变形到预先进行基础处理的高温记忆形态(图3所示的形态),记忆合金8与第一外引出片4接触导通,由此,将第一电极端子2、第一外引出片4、盖板本体1、短路电阻9、第二外引出片7及第二电极端子5导通,进而在第一电极端子2与第二电极端子5之间形成短路,实现了电池内部短路,进而可以切断外部异常回路,把电池隔离出来,防止更大的安全隐患发生,防止因异常电池的引起连锁隐患。使得整个异常始于该异常电池,也终止于该异常电池,最大限度的降低电池滥用带来的风险。并且,发生短路时,利用短路电阻、盖板本体及记忆合金等结构的阻抗消耗电池残余能量,最大程度地降低电池起火或爆炸的风险。When the battery is subjected to abuse conditions such as impact, foreign object puncture, or overheating, the battery will run away thermally, and the internal temperature of the battery will increase as the thermal runaway occurs. When the internal temperature exceeded the preset temperature threshold of the memory alloy 8, the metallographic structure of the memory alloy 8 changed, and according to the "memory" deformation to the high-temperature memory form (the form shown in Figure 3) that carried out the basic treatment in advance, the memory alloy 8 is in contact with the first lead-out piece 4, thereby connecting the first electrode terminal 2, the first lead-out piece 4, the cover body 1, the short circuit resistor 9, the second lead-out piece 7 and the second electrode terminal 5 Conduction, and then form a short circuit between the first electrode terminal 2 and the second electrode terminal 5, realize the internal short circuit of the battery, and then can cut off the external abnormal circuit, isolate the battery, prevent greater safety hazards from occurring, and prevent abnormal The battery causes chain hidden dangers. The whole abnormality starts from the abnormal battery and ends at the abnormal battery, so as to minimize the risk of battery abuse. Moreover, when a short circuit occurs, the residual energy of the battery is consumed by the short circuit resistance, the impedance of the cover body and memory alloy, and the risk of battery fire or explosion is minimized.
另外,在其它实施例中,还可以用双金属片等具有类似的形状记忆功能的元件替代上述实施例中的记忆合金。In addition, in other embodiments, the memory alloy in the above-mentioned embodiments may also be replaced by elements having a similar shape-memory function such as a bimetallic sheet.
另外,在其它实施例中,也可以取消短路电阻,直接将第二电极端子或第二外引出片与盖板本体电连接。由于第二电极端子与盖板本体之间不需要绝缘,因而,在本实施例中,第二密封结构可以不包括第二绝缘环。In addition, in other embodiments, the short-circuit resistor may also be eliminated, and the second electrode terminal or the second lead-out piece may be directly electrically connected to the cover body. Since there is no need for insulation between the second electrode terminal and the cover body, in this embodiment, the second sealing structure may not include the second insulating ring.
另外,本发明还提供了一种电池,其包括壳体、极芯及上述的盖板组件。极芯由正极片、隔膜及负极片卷绕得到。盖板组件从壳体的开口处插入并与壳体固定,通过盖板组件上的注液孔,注入电解液至盖板组件与壳体之间的密闭空间。正极片及负极片上设置有正极极耳及负极极耳。In addition, the present invention also provides a battery, which includes a casing, a pole core and the above-mentioned cover plate assembly. The pole core is obtained by winding a positive electrode sheet, a separator and a negative electrode sheet. The cover plate assembly is inserted from the opening of the housing and fixed with the housing, and the electrolyte is injected into the closed space between the cover plate assembly and the housing through the liquid injection hole on the cover plate assembly. Positive pole tabs and negative pole tabs are arranged on the positive pole piece and the negative pole piece.
若第一电极端子2为正极端子,则第一内引出片连接到正极极耳上,第二内引出片连接到负极极耳上。If the first electrode terminal 2 is a positive terminal, the first inner lead-out piece is connected to the positive pole lug, and the second inner lead-out piece is connected to the negative pole lug.
反过来,若第一电极端子2为负极端子,则第一内引出片连接到负极极耳上,第二内引出片连接到正极极耳上。Conversely, if the first electrode terminal 2 is a negative terminal, then the first inner lead-out piece is connected to the negative pole lug, and the second inner lead-out piece is connected to the positive pole lug.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range.
Claims (16)
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