CN107384198A - A kind of Chinese herbal medicine mosquito repellent coating and preparation method thereof - Google Patents
A kind of Chinese herbal medicine mosquito repellent coating and preparation method thereof Download PDFInfo
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- CN107384198A CN107384198A CN201710557458.0A CN201710557458A CN107384198A CN 107384198 A CN107384198 A CN 107384198A CN 201710557458 A CN201710557458 A CN 201710557458A CN 107384198 A CN107384198 A CN 107384198A
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- chinese herbal
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- 239000000077 insect repellent Substances 0.000 title claims abstract description 54
- 238000000576 coating method Methods 0.000 title claims abstract description 51
- 241000411851 herbal medicine Species 0.000 title claims abstract description 50
- 239000011248 coating agent Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 35
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- 239000002562 thickening agent Substances 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 16
- 239000000080 wetting agent Substances 0.000 claims abstract description 16
- 229920002678 cellulose Polymers 0.000 claims abstract description 14
- 239000001913 cellulose Substances 0.000 claims abstract description 14
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 14
- 239000013530 defoamer Substances 0.000 claims abstract description 12
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 9
- 239000003921 oil Substances 0.000 claims description 17
- 235000010215 titanium dioxide Nutrition 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 13
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 11
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 241001252601 Blumea Species 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 241000276489 Merlangius merlangus Species 0.000 claims description 6
- -1 polyoxyethylene Polymers 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims 1
- 239000005909 Kieselgur Substances 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 210000000481 breast Anatomy 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 238000001802 infusion Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 241000238631 Hexapoda Species 0.000 abstract description 6
- 230000002265 prevention Effects 0.000 abstract description 6
- 241000255925 Diptera Species 0.000 abstract description 5
- 239000004480 active ingredient Substances 0.000 abstract description 4
- 230000001846 repelling effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 3
- FAMPSKZZVDUYOS-UHFFFAOYSA-N 2,6,6,9-tetramethylcycloundeca-1,4,8-triene Chemical compound CC1=CCC(C)(C)C=CCC(C)=CCC1 FAMPSKZZVDUYOS-UHFFFAOYSA-N 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 125000000217 alkyl group Polymers 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- VBIRCRCPHNUJAS-AFHBHXEDSA-N 4-[(1S,3aR,4S,6aR)-4-(1,3-benzodioxol-5-yl)tetrahydrofuro[3,4-c]furan-1-yl]-2-methoxyphenol Chemical compound C1=C(O)C(OC)=CC([C@@H]2[C@@H]3[C@@H]([C@H](OC3)C=3C=C4OCOC4=CC=3)CO2)=C1 VBIRCRCPHNUJAS-AFHBHXEDSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- VGAJNILINWUWOP-UHFFFAOYSA-N Eudesmane Natural products COC(=O)C(=C)C1C(O)C2C(=O)CCC(O)C2(C)CC1OC(=O)C(=C)CO VGAJNILINWUWOP-UHFFFAOYSA-N 0.000 description 1
- 241001013248 Eulepidotis folium Species 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 230000001147 anti-toxic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 1
- 229940116229 borneol Drugs 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- DYEQPYSFRWUNNV-APIJFGDWSA-N eudesmane Chemical compound C1CC[C@@H](C)[C@@H]2C[C@H](C(C)C)CC[C@]21C DYEQPYSFRWUNNV-APIJFGDWSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- BXWQUXUDAGDUOS-UHFFFAOYSA-N gamma-humulene Natural products CC1=CCCC(C)(C)C=CC(=C)CCC1 BXWQUXUDAGDUOS-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- QBNFBHXQESNSNP-UHFFFAOYSA-N humulene Natural products CC1=CC=CC(C)(C)CC=C(/C)CCC1 QBNFBHXQESNSNP-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- VPSRGTGHZKLTBU-UHFFFAOYSA-N piperitol Natural products COc1ccc(cc1OCC=C(C)C)C2OCC3C2COC3c4ccc5OCOc5c4 VPSRGTGHZKLTBU-UHFFFAOYSA-N 0.000 description 1
- 230000029219 regulation of pH Effects 0.000 description 1
- 239000012173 sealing wax Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- HPOHAUWWDDPHRS-UHFFFAOYSA-N trans-piperitol Natural products CC(C)C1CCC(C)=CC1O HPOHAUWWDDPHRS-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- BURBOJZOZGMMQF-UHFFFAOYSA-N xanthoxylol Natural products C1=C(O)C(OC)=CC=C1C1C(COC2C=3C=C4OCOC4=CC=3)C2CO1 BURBOJZOZGMMQF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Chinese herbal medicine mosquito repellent coating and preparation method thereof, it is related to technical field of coatings.Including following components by weight：10 30 parts of deionized water, 0.1 0.2 parts of cellulose, 0.1 0.3 parts of pH adjusting agent, 0.1 0.5 parts of wetting agent, 0.2 0.4 parts of dispersant, 0.2 0.6 parts of defoamer, 1 1.5 parts of antifreezing agent, 100 250 parts of titanium dioxide, 15.3 25 parts of filler, 30 60 parts of Chinese herbal medicine mosquito repellent emulsion, 0.1 0.15 parts of coalescents, 0.1 0.8 parts of thickener, 0.3 0.8 parts of levelling agent, Chinese herbal medicine emulsion are folium artemisiae argyi fat liquor.The coating has the functions such as efficient mosquito repelling, insect prevention on the basis of the basic property of conventional interior wall coating is met, while the active ingredient of Chinese herbal medicine mosquito repellent emulsion slowly discharges in the coating, plays mosquito repellent, insect prevention effect for a long time.
Description
Technical field
The present invention relates to technical field of coatings, especially a kind of Chinese herbal medicine mosquito repellent coating and preparation method thereof.
Background technology
Inner wall surface sealing wax is relatively stable and ripe in terms of traditional performance and environmental protection at present, with people's life water
Flat raising, to the technical requirements of the industry, also more and more higher, conventional interior wall paint can not reach the requirement of people, therefore
The feature aspect of coating is developed.
It is also less on the research in mosquito repellent emulsion applications to coating although the research on mosquito repellent, antitoxin worm is more,
The dosage and technology of preparing of mosquito repellent emulsion have certain difference, determine that mosquito repellent emulsion is used in coating to mosquito repellent degree most
Good application conditions and technology are very necessary.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of Chinese herbal medicine mosquito repellent coating and preparation method thereof, and the coating is full
On the basis of the foot basic property of conventional interior wall coating, while there is the functions such as efficient mosquito repelling, insect prevention, while Chinese herbal medicine mosquito repellent
The active ingredient of emulsion slowly discharges in the coating, plays mosquito repellent, insect prevention effect for a long time.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of Chinese herbal medicine mosquito repellent coating, including by
Following components of parts by weight meter：
Deionized water 10-30 parts,
Cellulose 0.1-0.2 parts,
PH adjusting agent 0.1-0.3 parts,
Wetting agent 0.1-0.5 parts,
Dispersant 0.2-0.4 parts,
Defoamer 0.2-0.6 parts,
Antifreezing agent 1-1.5 parts,
Titanium dioxide 100-250 parts,
Filler 15.3-25 parts,
Chinese herbal medicine mosquito repellent emulsion 30-60 parts,
Coalescents 0.1-0.15 parts,
Thickener 0.1-0.8 parts,
Levelling agent 0.3-0.8 parts,
The Chinese herbal medicine emulsion is folium artemisiae argyi fat liquor.
Preferably, the manufacture craft of folium artemisiae argyi fat liquor is：Phase inversion is selected, Arlacel-80 and Tween-60 are added into folium artemisiae argyi
In oil, 35-45 DEG C of heating stirring, make Arlacel-80 and Tween-60 complete to be dissolved in Blumea oil, add deionized water under agitation,
The deionized water being initially added into is w/o type emulsion in oil phase with droplet distribution, is further continued for adding water, with amount of deionized water
Increase, emulsion occur micro- conversion, are changed into O/W type emulsions, the O/W types emulsion of preparation is stirred at 35-45 DEG C, equal to disperseing
After even, sheared with cutter, obtain folium artemisiae argyi fat liquor.
It is further preferred that in the manufacture craft of folium artemisiae argyi fat liquor：The quality of Arlacel-80, Tween-60 and deionized water point
It is not 6 times of folium artemisiae argyi oil quality, 6 times, 8 times.
Preferably, wetting agent is polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block
Any one in copolymer.
Preferably, thickener is any one that alkali soluble rises in class thickener and polyacrylic ester thickener.
Preferably, cellulose is hydroxyethyl cellulose.
Preferably, dispersant is ammonium polyacrylate salt dispersant.
Preferably, defoamer is mineral oil defoaming agent；Titanium dioxide is rutile titanium white powder；Levelling agent is polyurethanes stream
Flat agent；The antifreezing agent is ethylene glycol.
Preferably, filler is one or more combinations in calcined kaolin, diatomite, powdered whiting.
The preparation method of said herbal medicine mosquito repellent coating, comprises the following steps：
（1）First deionized water is added in retort, stirring, adds cellulose, pH adjusting agent, wetting agent, dispersant, defoaming
Agent, antifreezing agent, are stirred until homogeneous；
（2）Titanium dioxide, filler are added, is stirred to fineness≤55um；
（3）Chinese herbal medicine mosquito repellent emulsion is eventually adding, coalescents, levelling agent, stirring, thickener is added and is thickened to 25 DEG C, Si Tuo
Silent viscosimeter 80-100KU, is made Chinese herbal medicine mosquito repellent coating.
Experiment shows：The coating of the present invention prepared by folium artemisiae argyi fat liquor, is brushed in the side of glass box and non-brushing glass
The side of glass case, put 50 mosquitoes and enter in glass box, there are 2 mosquitoes close to swiped through side has been applied, therefore, it was demonstrated that use folium artemisiae argyi
Coating of the present invention prepared by fat liquor possesses repelling effect.
It is using beneficial effect caused by above-mentioned technical proposal：
（1）Coating of the present invention has efficient mosquito repelling, insect prevention on the basis of the basic property of conventional interior wall coating is met
Etc. function, while the active ingredient of Chinese herbal medicine mosquito repellent emulsion slowly discharges in the coating, plays mosquito repellent, insect prevention effect for a long time；
（2）In folium artemisiae argyi fat liquor of the present invention, folium artemisiae argyi has special smell and eudesmane composition, has the function that expelling parasite is mosquito-proof, from
The volatile oil main chemical compositions extracted in folium artemisiae argyi are cineole, camphor, borneol, piperitol, humulene, cineole etc., because
This, coating prepared by folium artemisiae argyi fat liquor has mosquito-repelling function, and has the function that faint scent, conduces to sleep.
Embodiment
The present invention is further illustrated by the following examples.It should be understood that these embodiments are the explainations of the present invention
And citing, the scope of the present invention is not limited in any form.
Embodiment 1
A kind of Chinese herbal medicine mosquito repellent coating, including following components by weight：
18 parts of deionized water,
0.15 part of cellulose,
0.25 part of pH adjusting agent,
0.3 part of wetting agent,
0.3 part of dispersant,
0.5 part of defoamer,
1 part of antifreezing agent,
250 parts of titanium dioxide,
20 parts of filler,
60 parts of Chinese herbal medicine mosquito repellent emulsion,
0.1 part of coalescents
0.5 part of thickener,
0.5 part of levelling agent,
Wherein, Chinese herbal medicine emulsion is folium artemisiae argyi fat liquor, and its manufacture craft is：Phase inversion is selected, by Arlacel-80 and Tween-60
Add in Blumea oil, 40 DEG C of heating stirrings, make Arlacel-80 and Tween-60 complete to be dissolved in Blumea oil, be slowly added under agitation
Deionized water, the deionized water being initially added into are w/o type emulsion in oil phase with droplet distribution, are further continued for plus water, with go from
The increase of sub- water, emulsion occur micro- conversion, are changed into O/W type emulsions, the O/W type emulsions of preparation are placed on into magnetic stirring apparatus
In, temperature is set as 40 DEG C, the thick emulsion of finely dispersed Blumea oil is obtained after stirring 30min, by the thick emulsion of the Blumea oil made
Blumea oil miniemulsion, i.e. folium artemisiae argyi fat liquor are obtained with the high-speed shearing machine shearing regular hour.
In the manufacture craft of folium artemisiae argyi fat liquor：The quality of Arlacel-80, Tween-60 and deionized water is folium artemisiae argyi oil respectively
6 times, 6 times, 8 times of amount.
Dispersant is ammonium polyacrylate salt dispersant.For the 963 of Tao Shi.
Defoamer is the A10 of BASF.
Titanium dioxide is the rutile titanium white powder of chloridising production, is the LR996 of imperial boa；
Filler is a variety of combination of calcined kaolin, diatomite, powdered whiting；Calcined kaolin is high for the calcining of Shanxi gold space
Ridge soil DB80, diatomite are Celite 499, and powdered whiting is the powdered whiting CC-700 of wide good fortune.
Thickener is that alkali soluble rises class thickener；
Levelling agent is no-solvent polyurethane class levelling agent, specific such as the 2025 of French Gao Tai.
Coalescents are selected from the graceful extraordinary Chemical Co., Ltd. of neat Tracie Ruiz-Conforto, and such coalescents can TEXANOL.
PH adjusting agent is selected from the AMP-95 of DOW Chemical.
Wetting agent is polyoxyethylene aliphatic alcohol ether.
Cellulose is hydroxyethyl cellulose.
Antifreezing agent is ethylene glycol.
The preparation method of said herbal medicine mosquito repellent coating, comprises the following steps：
（1）First deionized water is added in retort A, stirred with 100-200rpm speed, mixes and sequentially adds cellulose, pH regulations
Agent, wetting agent, dispersant, defoamer, antifreezing agent, 2min is stirred to uniform with 500-800rpm speed；
（2）It is slowly added to titanium dioxide, filler successively in retort A again, 30min is stirred with 1000-1200rpm speed, stopped
Machine, test fineness, it is desirable to fineness≤55um；
（3）Chinese herbal medicine mosquito repellent emulsion, coalescents, levelling agent, with 800-1200rpm's are finally slowly added in retort A
Speed stirs 5 minutes, surveys initial viscosity, according to initial viscosity, adds thickener and carries out being thickened to 25 DEG C, stormer viscosity meter
80-100KU, Chinese herbal medicine mosquito repellent coating is made.
Embodiment 1 is made into Chinese herbal medicine mosquito repellent coating to be detected, it is as follows to obtain table 1：
Embodiment 2
The difference of embodiment 2 and embodiment 1 is：
A kind of Chinese herbal medicine mosquito repellent coating, including following components by weight：
30 parts of deionized water,
0.2 part of cellulose,
0.15 part of pH adjusting agent,
0.4 part of wetting agent,
0.4 part of dispersant,
0.5 part of defoamer,
1.5 parts of antifreezing agent,
250 parts of titanium dioxide,
20 parts of filler,
50 parts of Chinese herbal medicine mosquito repellent emulsion,
0.15 part of coalescents
0.3 part of thickener,
0.5 part of levelling agent,
In the manufacture craft of folium artemisiae argyi fat liquor：The quality of Arlacel-80, Tween-60 and deionized water is the 6 of folium artemisiae argyi oil quality respectively
Times, 6 times, 8 times.
Thickener is polyacrylic ester thickener.
Wetting agent is polyoxyethylated alkyl phenol.
Filler is calcined kaolin.
The preparation method of said herbal medicine mosquito repellent coating, comprises the following steps：
（1）First deionized water is added in retort A, so that 100-200rpm speed stirring sequentially adds cellulose, pH is adjusted
Agent, wetting agent, dispersant, defoamer, antifreezing agent, 2min is stirred to uniform with 500-800rpm speed；
（2）It is slowly added to titanium dioxide, filler successively in retort A again, 30min is stirred with 1000-1200rpm speed, stopped
Machine, test fineness, it is desirable to fineness≤55um；
（3）Chinese herbal medicine mosquito repellent emulsion, coalescents, levelling agent, with 800-1200rpm's are finally slowly added in retort A
Speed stirs 5 minutes, surveys initial viscosity, according to initial viscosity, adds thickener and carries out being thickened to 25 DEG C, stormer viscosity meter
80-100KU, Chinese herbal medicine mosquito repellent coating is made.
Embodiment 2 is made into Chinese herbal medicine mosquito repellent coating to be detected, it is as follows to obtain table 2：
Embodiment 3
The difference of embodiment 3 and embodiment 1 is：
A kind of Chinese herbal medicine mosquito repellent coating coating, including following components by weight：
15 parts of deionized water,
0.1 part of cellulose,
0.2 part of pH adjusting agent,
0.3 part of wetting agent,
0.2 part of dispersant,
0.3 part of defoamer,
1.5 parts of antifreezing agent,
200 parts of titanium dioxide,
25 parts of filler,
40 parts of Chinese herbal medicine mosquito repellent emulsion,
0.15 part of coalescents
0.4 part of thickener,
0.5 part of levelling agent,
In the manufacture craft of folium artemisiae argyi fat liquor：The quality of Arlacel-80, Tween-60 and deionized water is the 6 of folium artemisiae argyi oil quality respectively
Times, 6 times, 8 times.
Wetting agent is polyoxyethylene polyoxypropylene block copolymer.
Filler is powdered whiting.
The preparation method of said herbal medicine mosquito repellent coating, comprises the following steps：
（1）First deionized water is added in retort A, so that 100-200rpm speed stirring sequentially adds cellulose, pH is adjusted
Agent, wetting agent, dispersant, defoamer, antifreezing agent, 2min is stirred to uniform with 500-800rpm speed；
（2）It is slowly added to titanium dioxide, filler successively in retort A again, 30min is stirred with 1000-1200rpm speed, stopped
Machine, test fineness, it is desirable to fineness≤55um；
（3）Chinese herbal medicine mosquito repellent emulsion, coalescents, levelling agent, with 800-1200rpm's are finally slowly added in retort A
Speed stirs 5 minutes, surveys initial viscosity, according to initial viscosity, adds thickener and carries out being thickened to 25 DEG C, stormer viscosity meter
80-100KU, Chinese herbal medicine mosquito repellent coating is made.
Embodiment 3 is made into Chinese herbal medicine mosquito repellent coating to be detected, it is as follows to obtain table 3：
From table 1, table 2 and table 3, on the basis of the basic property of conventional interior wall coating is met, while there is mosquito repellent, prevent
The functions such as worm, while the active ingredient of Chinese herbal medicine emulsion slowly discharges in the coating, long-term role.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, the present invention
Claimed scope is by appended claims, specification and its equivalent thereof.
Claims (10)
- A kind of 1. Chinese herbal medicine mosquito repellent coating, it is characterised in that：Including following components by weight：Deionized water 10-30 parts,Cellulose 0.1-0.2 parts,PH adjusting agent 0.1-0.3 parts,Wetting agent 0.1-0.5 parts,Dispersant 0.2-0.4 parts,Defoamer 0.2-0.6 parts,Antifreezing agent 1-1.5 parts,Titanium dioxide 100-250 parts,Filler 15.3-25 parts,Chinese herbal medicine mosquito repellent emulsion 30-60 parts,Coalescents 0.1-0.15 parts,Thickener 0.1-0.8 parts,Levelling agent 0.3-0.8 parts,The Chinese herbal medicine emulsion is folium artemisiae argyi fat liquor.
- A kind of 2. Chinese herbal medicine mosquito repellent coating according to claim 1, it is characterised in that the making work of the folium artemisiae argyi fat liquor Skill is：Select phase inversion, Arlacel-80 and Tween-60 added in Blumea oil, 35-45 DEG C of heating stirring, make Arlacel-80 and Tween-60 is completed to be dissolved in Blumea oil, adds deionized water under agitation, the deionized water being initially added into is with droplet distribution in oil Xiang Zhong, it is w/o type emulsion, is further continued for adding water, with the increase of amount of deionized water, micro- conversion occurs for emulsion, is changed into O/W types breast Liquid, the O/W types emulsion of preparation is stirred at 35-45 DEG C, to after being uniformly dispersed, sheared with cutter, obtains folium artemisiae argyi fat liquor.
- A kind of 3. Chinese herbal medicine mosquito repellent coating according to claim 2, it is characterised in that the manufacture craft of folium artemisiae argyi fat liquor In：The quality of Arlacel-80, Tween-60 and deionized water is 6 times of folium artemisiae argyi oil quality respectively, 6 times, 8 times.
- 4. a kind of Chinese herbal medicine mosquito repellent coating according to claim 1, it is characterised in that the wetting agent is polyoxyethylene alkane Base phenolic ether, polyoxyethylene aliphatic alcohol ether, any one in polyoxyethylene polyoxypropylene block copolymer.
- A kind of 5. Chinese herbal medicine mosquito repellent coating according to claim 1, it is characterised in that the thickener be alkali soluble rise class increasing Any one in thick dose and polyacrylic ester thickener.
- 6. a kind of Chinese herbal medicine mosquito repellent coating according to claim 1, it is characterised in that the cellulose is hydroxy ethyl fiber Element.
- 7. a kind of Chinese herbal medicine mosquito repellent coating according to claim 1, it is characterised in that the dispersant is ammonium polyacrylate Salt dispersant.
- 8. a kind of Chinese herbal medicine mosquito repellent coating according to claim 1, it is characterised in that the defoamer disappears for mineral oils Infusion；The titanium dioxide is rutile titanium white powder；The levelling agent is polyurethanes levelling agent；The antifreezing agent is ethylene glycol.
- 9. a kind of Chinese herbal medicine mosquito repellent coating according to claim 1, it is characterised in that the filler is calcined kaolin, silicon One or more combinations in diatomaceous earth, powdered whiting.
- A kind of 10. preparation method of Chinese herbal medicine mosquito repellent coating according to claim any one of 1-9, it is characterised in that bag Include following steps：（1）First deionized water is added in retort, stirring, adds cellulose, pH adjusting agent, wetting agent, dispersant, defoaming Agent, antifreezing agent, are stirred until homogeneous；（2）Titanium dioxide, filler are added, is stirred to fineness≤55um；（3）Chinese herbal medicine mosquito repellent emulsion is eventually adding, coalescents, levelling agent, stirring, thickener is added and is thickened to 25 DEG C, Si Tuo Silent viscosimeter 80-100KU, is made Chinese herbal medicine mosquito repellent coating.
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| CN116218271A (en) * | 2022-12-23 | 2023-06-06 | 龙牌涂料(北京)有限公司 | Chinese herbal medicine composite silica sol, preparation method thereof and interior wall coating containing same |
| CN116218271B (en) * | 2022-12-23 | 2024-07-16 | 龙牌涂料(北京)有限公司 | Chinese herbal medicine composite silica sol, preparation method thereof and interior wall coating containing same |
| CN116035044A (en) * | 2023-01-05 | 2023-05-02 | 龙牌涂料(北京)有限公司 | Chinese herbal medicine insect repellent, paint thereof and preparation method thereof |
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