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CN107372570A - A kind of suspension seed-coating agent containing guadipyr and its preparation method and application - Google Patents

A kind of suspension seed-coating agent containing guadipyr and its preparation method and application Download PDF

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CN107372570A
CN107372570A CN201710549864.2A CN201710549864A CN107372570A CN 107372570 A CN107372570 A CN 107372570A CN 201710549864 A CN201710549864 A CN 201710549864A CN 107372570 A CN107372570 A CN 107372570A
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suspension seed
coating agent
seed coating
sodium
agent containing
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马永强
董云鹏
覃兆海
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China Agricultural University
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
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    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • AHUMAN NECESSITIES
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    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/7071,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
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    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
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    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals

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Abstract

本发明公开了一种含戊吡虫胍的悬浮种衣剂及其制备方法与应用。所述含戊吡虫胍的悬浮种衣剂,其组成包括下述质量分数的原料:戊吡虫胍5‑30%、润湿分散剂3‑10%、成膜剂2‑10%、增稠剂0.1‑0.5%、防冻剂1‑10%、消泡剂0.2‑1%、水补足至100%。为了提高药物的治理效果,上述悬浮种衣剂中还可包括吡虫啉、晴菌唑、毒死蜱、苯醚甲环唑等组分。该含有戊吡虫胍的悬浮种衣剂可用于防治农作物病害和/或虫害。本发明将戊吡虫胍与其它活性成分复配制备悬浮种衣剂,所制备产品有较强的内吸性,并具有触杀、胃毒和内吸多重药效,有较好的防治效用。The invention discloses a suspension seed coating agent containing pentetamicloguanidine, a preparation method and application thereof. The suspension seed-coating agent containing pentametacoguan comprises the following mass fractions of raw materials: 5-30% of pentametacoguan, 3-10% of wetting and dispersing agent, 2-10% of film-forming agent, Thickener 0.1‑0.5%, antifreeze agent 1‑10%, defoamer 0.2‑1%, water to make up to 100%. In order to improve the treatment effect of the medicine, the above-mentioned suspension seed coating agent may also include components such as imidacloprid, bacconazole, chlorpyrifos, difenoconazole and the like. The suspension seed coating agent containing pentametagon can be used for preventing and controlling crop diseases and/or pests. In the present invention, pentametamiclon is compounded with other active components to prepare a suspension seed coating agent, and the prepared product has strong systemic property, multiple drug effects of contact killing, stomach poisoning and systemic drug effect, and has good control effect.

Description

一种含有戊吡虫胍的悬浮种衣剂及其制备方法和应用A kind of suspension seed coating agent containing pentetamicloguanidine and its preparation method and application

技术领域technical field

本发明属于农药制剂领域,具体涉及一种含有戊吡虫胍的悬浮种衣剂及其制备方法和应用。The invention belongs to the field of pesticide preparations, and in particular relates to a suspension seed coating agent containing pentetamicloguanidine, a preparation method and application thereof.

背景技术Background technique

戊吡虫胍,化学名称1-硝基-3-[(6-氯吡啶-3-基)甲基]-4-戊亚甲基氨基胍,属硝基缩氨基胍类化合物,是一种高效、低毒、低残留的全新杀虫剂,兼具新烟碱类杀虫剂和钠离子通道抑制剂类杀虫剂的结构特征,因而也兼具这两类杀虫剂的杀虫谱,具有广泛的应用范围,具有多作用靶标的特点,会使害虫产生抗药性的速度大大降低。该产品对蚜虫、飞虱、棉铃虫等多种刺吸式口器害虫都有较好的防治效果。Pentetamiguanidine, chemical name 1-nitro-3-[(6-chloropyridin-3-yl)methyl]-4-pentamethylene aminoguanidine, belongs to nitro aminoguanidine compounds, is a kind of A new insecticide with high efficiency, low toxicity, and low residue, which has both the structural characteristics of neonicotinoid insecticides and sodium ion channel inhibitor insecticides, and thus also has the insecticidal spectrum of these two types of insecticides , has a wide range of applications, and has the characteristics of multiple targets, which will greatly reduce the speed of pest resistance. The product has a good control effect on aphids, planthoppers, cotton bollworms and other piercing-sucking mouthparts pests.

吡虫啉,化学名称1-(6-氯吡啶-3-吡啶基甲基)-N-硝基亚咪唑烷-2-基胺,是烟碱类超高效杀虫剂,硝基亚甲基类化合物。吡虫啉具有广谱、高效、低毒、低残留,害虫不易产生抗性,对人、畜、植物和天敌安全等特点,并有触杀、胃毒和内吸多重药效。吡虫啉是烟碱乙酰胆碱受体的作用体,干扰害虫运动神经系统使化学信号传递失灵,害虫接触药剂后,中枢神经正常传导受阻,使其麻痹死亡。速效性好,药后1天即有较高的防效。防治如蚜虫、飞虱、粉虱、叶蝉、蓟马;对鞘翅目、双翅目和鳞翅目的某些害虫,如稻象甲、稻负泥虫、潜叶蛾等也有效。Imidacloprid, chemical name 1-(6-chloropyridin-3-pyridylmethyl)-N-nitroimidazolidin-2-ylamine, is a super efficient insecticide of the nicotinic class, a nitromethylene compound . Imidacloprid has the characteristics of broad spectrum, high efficiency, low toxicity and low residue, it is not easy for pests to develop resistance, it is safe to humans, animals, plants and natural enemies, and it has multiple effects of contact killing, stomach poisoning and systemic absorption. Imidacloprid is the action body of nicotinic acetylcholine receptors, which interferes with the motor nervous system of pests and causes the chemical signal transmission to fail. It has good quick-acting property, and it has a high control effect one day after taking the medicine. Control such as aphids, planthoppers, whiteflies, leafhoppers, and thrips; it is also effective for certain pests of Coleoptera, Diptera, and Lepidoptera, such as rice weevils, rice negative mudworms, and leaf miners.

晴菌唑,化学名称2-(4-氯苯基)-2-(1H,1,2,4-三唑-1-甲基)己腈,低毒,对病原菌的麦角甾醇的生物合成起抑制作用,对子囊菌、担子菌均具有较好的防治效果。该剂持效期长,对作物安全,有一定刺激生长作用。具有强内吸性、药效高,对作物安全,持效期长特点。具有预防和治疗作用。通过在苹果树上多次喷雾使用,发现对芽虫杀死力很强,可用于防治苹果树芽虫。Bacendazole, chemical name 2-(4-chlorophenyl)-2-(1H,1,2,4-triazole-1-methyl)hexonitrile, low toxicity, plays a role in the biosynthesis of ergosterol of pathogenic bacteria Inhibitory effect, and has good control effect on Ascomycetes and Basidiomycetes. The agent has a long-lasting effect, is safe to crops, and has a certain growth-stimulating effect. It has the characteristics of strong systemic property, high drug efficacy, safety to crops, and long-lasting effect. It has preventive and therapeutic effects. Through repeated spraying on apple trees, it is found that it has a strong killing effect on bud worms and can be used to prevent and control apple tree bud worms.

井冈霉素,是一种放线菌产生的抗生素,具有较强的内吸性,易被菌体细胞吸收并在其内迅速传导,干扰和抑制菌体细胞生长和发育。井冈霉素具有防效高、无药害、无污染的优良特性。主要用于水稻纹枯病,也可用于水稻稻曲病、玉米大小斑病以及蔬菜和棉花、豆类等作物病害的防治。Jinggangmycin, an antibiotic produced by actinomycetes, has strong systemic properties, is easily absorbed by bacterial cells and rapidly conducts in them, interfering with and inhibiting the growth and development of bacterial cells. Jinggangmycin has the excellent characteristics of high control efficiency, no phytotoxicity, and no pollution. It is mainly used for rice sheath blight, and it can also be used for the control of rice false smut, corn spot disease, vegetables, cotton, beans and other crop diseases.

吡蚜酮,化学名称4,5-二氢-6-甲基-4-(3-吡啶亚甲基氨基)-1,2,4-3(2H)-酮,属于吡啶类或三嗪酮类杀虫剂,是全新的非杀生性杀虫剂。吡蚜酮具有优异的阻断昆虫传毒功能,蚜虫或飞虱一接触到吡蚜酮几乎立即产生口针阻塞效应,立刻停止取食,并最终饥饿致死,此过程是不可逆转的。吡蚜酮对害虫具有触杀作用,同时还有内吸活性。在植物体内既能在木质部输导也能在韧皮部输导;因此既可用作叶面喷雾,也可用于土壤处理。由于其良好的输导特性,在茎叶喷雾后新长出的枝叶也可以得到有效保护。可防治蚜虫科、飞虱科、粉虱科、叶蝉科等多种害虫,如甘蓝蚜、棉蚜、麦蚜、桃蚜、小绿斑叶蝉、褐飞虱、灰飞虱、白背飞虱、甘薯粉虱及温室粉虱等。Pymetrozine, chemical name 4,5-dihydro-6-methyl-4-(3-pyridinemethyleneamino)-1,2,4-3(2H)-one, belongs to pyridines or triazones Insecticides are brand new non-biocide insecticides. Pymetrozine has an excellent function of blocking insect transmission of viruses. Once aphids or planthoppers come into contact with pymetrozine, they will almost immediately produce a stylet blocking effect, stop feeding immediately, and eventually starve to death. This process is irreversible. Pymetrozine has a contact effect on pests and also has systemic activity. In plants, it can be transported in both xylem and phloem; therefore, it can be used as a foliar spray or as a soil treatment. Thanks to its good transporting properties, new shoots and leaves can also be effectively protected after spraying the stems and leaves. It can control a variety of pests such as Aphididae, Planthoppers, Amylinidae, Leafhoppers, etc., such as cabbage aphids, cotton aphids, wheat aphids, peach aphids, green leafhoppers, brown planthoppers, brown planthoppers, white-backed planthoppers , sweet potato whitefly and greenhouse whitefly.

溴氰菊酯,化学名称α-氰基苯氧基苄基(1R,3R)-3-(2,2-二溴乙烯基)-2,2-二甲基环丙烷羧酸酯。具有触杀和胃毒作用,触杀作用迅速,击倒力强,没有熏蒸和内吸作用,在高浓度下对一些害虫有驱避作用。溴氰菊酯杀虫谱广,对鳞翅目、直翅目、缨翅目、半翅目、双翅目、鞘翅目等多种害虫有效。溴氰菊酯适用作物广泛,可应用于十字花科蔬菜、瓜类蔬菜、豆类蔬菜、茄果类蔬菜、芦笋、水稻、小麦、玉米、高粱、油菜、花生、大豆等多种作物。Deltamethrin, chemical name α-cyanophenoxybenzyl (1R,3R)-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate. It has contact and stomach poisoning effect, rapid contact effect, strong knockdown force, no fumigation and systemic effect, and has repellent effect on some pests at high concentration. Deltamethrin has a broad insecticidal spectrum and is effective against various pests such as Lepidoptera, Orthoptera, Thysanoptera, Hemiptera, Diptera, and Coleoptera. Deltamethrin is applicable to a wide range of crops, including cruciferous vegetables, melon vegetables, bean vegetables, nightshade vegetables, asparagus, rice, wheat, corn, sorghum, rape, peanuts, soybeans and other crops.

毒死蜱,又名氯吡硫磷,是乙酰胆碱酯酶抑制剂,属硫代磷酸酯类杀虫剂。作用机理是抑制昆虫体内神经中的乙酰胆碱酯酶AChE或胆碱酯酶ChE的活性而破坏了正常的神经冲动传导,引起一系列中毒症状如异常兴奋、痉挛、麻痹、死亡。毒死蜱具有胃毒、触杀、熏蒸三重作用,对水稻、小麦、棉花、果树、蔬菜、茶树上多种咀嚼式和刺吸式口器害虫均具有较好防效。其混用相容性好,可与多种杀虫剂混用且增效作用明显,无内吸作用,保障农产品、消费者的安全,适用于无公害优质农产品的生产。Chlorpyrifos, also known as chlorpyrifos, is an acetylcholinesterase inhibitor and belongs to the class of phosphorothioate insecticides. The mechanism of action is to inhibit the activity of acetylcholinesterase AChE or cholinesterase ChE in the nerves of insects and destroy the normal nerve impulse conduction, causing a series of poisoning symptoms such as abnormal excitement, convulsions, paralysis, and death. Chlorpyrifos has triple effects of stomach poisoning, contact killing and fumigation, and has good control effect on various chewing and sucking mouthparts pests on rice, wheat, cotton, fruit trees, vegetables and tea trees. It has good mixing compatibility, can be mixed with a variety of insecticides and has obvious synergistic effect, has no systemic effect, ensures the safety of agricultural products and consumers, and is suitable for the production of pollution-free and high-quality agricultural products.

噻嗪酮,化学名称2-叔丁亚氨基-3-异丙基-5-苯基-3,4,5,6-四氢-2H-1,3,5-噻二嗪-4-酮。噻嗪酮属昆虫生长调节剂类杀虫剂,作用机理主要是通过不同受药部位,作用于昆虫神经内分泌系统,干扰心侧体、前胸腺体等的正常活动,呈现一系列不良反应。而这种不良反应是不可逆的,使害虫受药后不能复苏。主要用于水稻、茶树、蔬菜等作物的害虫防治,可有效地防治水稻上的大叶蝉科、飞虱科、蚧科、盾蚧科和粉蚧科等害虫。Buprofezin, chemical name 2-tert-butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiazin-4-one . Buprofezin belongs to the class of insect growth regulator insecticides. Its mechanism of action is mainly to act on the neuroendocrine system of insects through different drug-receiving sites, interfere with the normal activities of the lateral body of the heart and the anterior thymus, and present a series of adverse reactions. And this adverse reaction is irreversible, so that the pests cannot recover after receiving the medicine. It is mainly used for pest control of crops such as rice, tea trees, and vegetables, and can effectively control pests such as Leafhoppers, Planthoppers, Coccidae, Scutococcus and Mealyococcus on rice.

敌敌畏,有机磷类杀虫剂,为广谱性杀虫、杀螨剂。具有触杀、胃毒和熏蒸作用,具有高效、速效、持效期短、无残留等特点。触杀作用效果好,对害虫击倒力强而快。可用于蔬菜、果树和多种农田作物。Dichlorvos, an organophosphorus insecticide, is a broad-spectrum insecticide and acaricide. It has the functions of contact killing, stomach poisoning and fumigation, and has the characteristics of high efficiency, quick effect, short duration of effect and no residue. The contact effect is good, and the knockdown power to pests is strong and fast. Can be used for vegetables, fruit trees and a variety of field crops.

硫双威,化学名称为3,7,9,13四甲基-5-11二氧杂-2,8,14-三硫杂-4,7,9,12-四氮杂十五烷-3,12-二烯-6-10-二酮,硫双威主要是胃毒作用,几乎没有触杀作用,无熏蒸和内吸作用,有较强的选择性,在土壤中残效期很短。此品种对鳞翅目害虫有特效,并有杀卵作用,对棉蚜、叶蝉、蓟马和螨类无效,也可用于鞘翅目、双翅目及膜翅目害虫的防治。Thiodicarb, the chemical name is 3,7,9,13-tetramethyl-5-11-dioxa-2,8,14-trithia-4,7,9,12-tetraazapentadecane- 3, 12-diene-6-10-dione, thiodicarb mainly has stomach toxicity, almost no contact action, no fumigation and systemic action, strong selectivity, and short residual effect in soil. This variety has special effects on Lepidoptera pests and has ovicidal effect, but is ineffective against cotton aphids, leafhoppers, thrips and mites, and can also be used for the control of Coleoptera, Diptera and Hymenoptera pests.

苯醚甲环唑,化学名称为顺,反-3-氯-4-[4-甲基-2-1H-1,2,4-三唑-1-基甲基)-1,3-二哑戊烷-2-基)苯基4-氯苯基醚,内吸性杀菌,具保护和治疗作用。苯醚甲环唑是三唑类杀菌剂中安全性较高的,广泛应用于果树、蔬菜等作物,有效防治黑星病,黑痘病、白腐病、斑点落叶病、白粉病、褐斑病、锈病、条锈病等。防治对象对子囊亚门,担子菌亚门和包括链格孢属、壳二抱属、尾孢霉属、刺盘抱属、球座菌属、茎点霉属、柱隔孢属、壳针孢属、黑星菌属在内的半知菌,白粉菌科,锈菌目和某些种传病原茵有持久的保护和治疗活性,同时对甜菜褐斑病,小麦颖枯病、叶枯病、锈病和由几种致病菌引起的霉病,苹果黑星病、白粉病,葡萄白粉病,马铃薯早疫病,花生叶斑病、网斑病等均有较好的治疗效果。Difenoconazole, chemical name is cis, trans-3-chloro-4-[4-methyl-2-1H-1,2,4-triazol-1-ylmethyl)-1,3-di Dummy pentane-2-yl)phenyl 4-chlorophenyl ether, systemic bactericidal, protective and therapeutic. Difenoconazole is the safest of triazole fungicides. It is widely used in fruit trees, vegetables and other crops to effectively control scab, black pox, white rot, leaf spot, powdery mildew, and brown spot. Disease, rust, stripe rust, etc. The control objects are Ascomycotina, Basidiomycotina and include Alternaria, Cocodisporium, Cercospora, Spiropodium, Globula, Phoma, Cylindrosporium, and Septoria Deficient fungi including the genus Bacillus and Sclerotina genus, Powdery mildewaceae, Rust fungi and certain kinds of infectious pathogenic bacteria have long-lasting protective and therapeutic activity, and at the same time, they are effective against sugar beet brown spot, wheat glume blight, leaf blight Disease, rust and mildew caused by several pathogenic bacteria, apple scab, powdery mildew, grape powdery mildew, potato early blight, peanut leaf spot, net spot, etc. have good therapeutic effects.

噻虫胺,化学名称为(E)-1-(2-氯-1,3-噻唑-5-基甲基)-3-甲基-2-2-硝基胍,噻虫胺是新烟碱类中的一种杀虫剂,是一类高效安全、高选择性的新型杀虫剂,其作用与烟碱乙酰胆碱受体类似,具有触杀、胃毒和内吸活性。主要用于水稻、蔬菜、果树及其他作物上防治蚜虫、叶蝉、蓟马、飞虱等半翅目、鞘翅目、双翅目和某些鳞翅目类害虫的杀虫剂,具有高效、广谱、用量少、毒性低、药效持效期长、对作物无药害、使用安全、与常规农药无交互抗性等优点,有卓越的内吸和渗透作用。Clothianidin, the chemical name is (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-2-nitroguanidine, clothianidin is new smoke It is a kind of insecticide in alkali class, which is a new type of insecticide with high efficiency, safety and high selectivity. Its action is similar to that of nicotinic acetylcholine receptor, and it has contact killing, stomach poisoning and systemic activity. It is mainly used as an insecticide for preventing and controlling aphids, leafhoppers, thrips, planthoppers and other pests of Hemiptera, Coleoptera, Diptera and some Lepidoptera on rice, vegetables, fruit trees and other crops. It has the advantages of broad spectrum, less dosage, low toxicity, long duration of drug effect, no harm to crops, safe use, no cross-resistance with conventional pesticides, etc., and has excellent systemic and osmotic effects.

噻虫嗪,化学名称3-(2-氯-1,3-噻唑-5-基甲基)-5-甲基-1,3,5-恶二嗪-4-基叉(硝基)胺。可以有效防治同翅目、鳞翅目、鞘翅目、缨翅目害虫。其中对同翅目特效,如各种蚜虫、叶蝉、粉虱、飞虱等。Thiamethoxam, chemical name 3-(2-Chloro-1,3-thiazol-5-ylmethyl)-5-methyl-1,3,5-oxadiazin-4-ylidene(nitro)amine . It can effectively control pests of Homoptera, Lepidoptera, Coleoptera and Thysanoptera. Among them, it has special effects on Homoptera, such as various aphids, leafhoppers, whiteflies, and planthoppers.

咯菌腈,化学名为4-(2,2-二氟-1,3-苯并二氧杂环戊烯-4-基)吡咯-3-腈,咯菌腈具有抑菌和杀菌作用,主要通过抑制与葡萄糖磷酰化有关的转移,进而抑制真菌菌丝体的生长,最终导致病菌死亡;对灰霉菌的杀菌机制主要是溶解灰霉菌菌体的细胞壁,并快速破坏灰霉菌细胞膜上的疏水链,氧化溶解作为病菌生命活动主要物质的蛋白质,破坏蛋白质与核酸的合成,从而干扰破坏灰霉病菌的生物合成与生物氧化过程,此作用机理具有独特性和较长的持效期咯菌腈与现有的杀菌剂没有交互抗性,迄今为止没有发现任何副作用,是一种高效低毒的触杀性杀菌剂,广泛应用于种子处理中,以防止种子带菌和土壤传播造成的危害。Fludioxonil, the chemical name is 4-(2,2-difluoro-1,3-benzodioxol-4-yl)pyrrole-3-carbonitrile, fludioxonil has antibacterial and bactericidal effects, Mainly by inhibiting the transfer related to glucose phosphorylation, and then inhibiting the growth of fungal mycelium, and finally leading to the death of bacteria; Hydrophobic chain, oxidatively dissolves protein as the main substance of the life activities of bacteria, destroys the synthesis of protein and nucleic acid, thereby interfering with the biosynthesis and biological oxidation process of Botrytis cinerea, this mechanism of action is unique and has a long duration Nitrile has no cross-resistance with existing fungicides, and no side effects have been found so far. It is a contact fungicide with high efficiency and low toxicity. It is widely used in seed treatment to prevent damage caused by seed contamination and soil transmission.

吡唑醚菌酯,化学名称为甲基(N)-[[[1-(4-氯苯)吡唑-3基)-氧]-0-甲氧基]-N-甲氧氨基甲酸酯。吡唑醚菌酯为新型广谱杀菌剂。作用机理为线粒体呼吸抑制剂,即通过在细胞色素合成中阻止电子转移。具有保护、治疗、叶片渗透传导作用。吡唑醚菌酯对黄瓜白粉病、霜霉病和香蕉黑星病、叶斑病、菌核病等有较好的防治效果。Pyraclostrobin, the chemical name is methyl(N)-[[[1-(4-chlorophenyl)pyrazol-3yl)-oxy]-O-methoxy]-N-methoxycarbamate ester. Pyraclostrobin is a new broad-spectrum fungicide. The mechanism of action is an inhibitor of mitochondrial respiration, that is, by preventing electron transfer during cytochrome synthesis. It has the functions of protection, treatment and leaf penetration. Pyraclostrobin has good control effects on cucumber powdery mildew, downy mildew, banana scab, leaf spot, and sclerotinia.

氟虫腈,化学名称(RS)-5-氨基-1-(2,6-二氯-a,a,a-三氟-对-甲苯基)-4-三氟甲基亚磺酰基吡唑-3-腈,氟虫腈为GABA-氯离子通道抑制剂,与现有杀虫剂无交互抗性,对有机磷、有机氯、氨基甲酸酯、拟除虫菊酯等类杀虫剂已经产生抗性的或敏感的害虫均有较好的防治效果。适宜的作物有水稻、玉米、棉花、香蕉、甜菜、马铃薯、花生等,推荐剂量下对作物无药害。同时对卫生害虫的蟑螂防治也有非凡的效果。氟虫腈杀虫谱广,具有触杀、胃毒和中度内吸作用。既能防治地下害虫,又能防治地上害虫。既可用于茎叶处理和土壤处理,又可用于种子处理。主要防治对象包括蚜虫、叶蝉、鳞翅目幼虫、蝇类和鞘翅目等害虫。Fipronil, chemical name (RS)-5-amino-1-(2,6-dichloro-a,a,a-trifluoro-p-tolyl)-4-trifluoromethylsulfinylpyrazole -3-Nitronitrile, fipronil is a GABA-chloride channel inhibitor, has no cross-resistance with existing insecticides, and has produced organic phosphorus, organochlorine, carbamate, pyrethroids and other insecticides Both resistant and sensitive pests have better control effect. Suitable crops include rice, corn, cotton, banana, sugar beet, potato, peanut, etc. There is no phytotoxicity to crops under the recommended dosage. At the same time, it also has an extraordinary effect on the control of cockroaches, which are sanitary pests. Fipronil has a broad insecticidal spectrum, with contact, stomach toxicity and moderate systemic effects. It can control both underground pests and aboveground pests. It can be used for stem and leaf treatment, soil treatment, and seed treatment. The main control targets include aphids, leafhoppers, Lepidoptera larvae, flies and Coleoptera and other pests.

拌种灵,化学名称为2-氨基-4-甲基-5-甲酰苯胺基噻唑。是一种内吸性拌种用杀菌剂,具有内吸性,拌种后可进入种皮或种胚,杀死种子表面及潜伏在种子内部的病原菌;同时也可在种子发芽后进入幼芽和幼根,从而保护幼苗免受土壤病原菌的侵染。与福美双混配可防治小麦黑穗病、高梁黑穗病、棉花苗期病害等。用于防治禾谷类作物黑穗病,棉花角斑病,棉花、豆类苗期病害,红麻炭疽病。Seed dressing spirit, the chemical name is 2-amino-4-methyl-5-formanilinothiazole. It is a systemic fungicide for seed dressing. It has systemic properties. After seed dressing, it can enter the seed coat or embryo, kill the pathogenic bacteria on the surface of the seed and hidden in the seed; at the same time, it can also enter the young sprout after the seed germinates. and young roots, thereby protecting seedlings from soil pathogens. Mixed with thiram can control wheat smut, sorghum smut, cotton seedling diseases, etc. It is used to prevent and control smut of cereal crops, angular spot of cotton, seedling diseases of cotton and beans, and anthracnose of kenaf.

咪鲜胺,化学名称为N-丙基-N-[2-(2,4,6-三氯苯氧基)乙基]-咪唑-1-甲酰胺。为高效、广谱、低毒型杀菌剂,具有预防保护治疗等多重作用,内含咪鲜胺为咪唑类广谱杀菌剂。通过抑制甾醇的生物合成而起作用,无内吸作用,对于子囊菌和半知菌引起的多种病害防效极佳。采用基因诱导技术,激活植物抗病基因表达,速效性好,持效期长。常规使用防治瓜果蔬菜炭疽病、叶斑病。还可防治水稻恶苗病、稻瘟病等。柑橘炭疽病、蒂腐病、青霉病、绿霉病,香蕉炭疽病、叶斑病,芒果炭疽病,花生叶斑病,辣椒、茄子、甜瓜、番茄等蔬菜炭疽病。Prochloraz, the chemical name is N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-imidazole-1-carboxamide. It is a high-efficiency, broad-spectrum, low-toxic fungicide with multiple functions such as prevention, protection and treatment. It contains prochloraz, which is a broad-spectrum imidazole fungicide. It works by inhibiting the biosynthesis of sterols, has no systemic effect, and has excellent control effects on various diseases caused by Ascomycetes and Deuterobacteria. Using gene induction technology to activate the expression of plant disease resistance genes, it has good quick effect and long lasting effect. It is routinely used to prevent anthracnose and leaf spot of fruits and vegetables. It can also control rice bakanae disease, rice blast and so on. Citrus anthracnose, stem rot, penicillium, green mold, banana anthracnose, leaf spot, mango anthracnose, peanut leaf spot, pepper, eggplant, melon, tomato and other vegetable anthracnose.

萎锈灵,中文别名5,6-二氢-2-甲基-N-苯基-1,4-氧硫杂环己烯-3-甲酰胺,白色针状结晶,内吸选择性杂环类杀菌剂。对温血动物低毒。在土壤中容易分解消失,对鱼和鸟类比较安全,选择性强。除强酸、强碱情况外,在一般介质中较稳定。防治对象萎锈灵为选择性内吸杀菌剂,主要用于防治由锈菌和黑粉菌在多种作物上引起的锈病和黑粉(穗)病,对棉花立枯病、黄萎病也有效,如高粱散黑穗病、丝黑穗病、玉米丝黑穗病、麦类黑穗病、麦类锈病、谷子黑穗病以及棉花苗期病害。Wiltin, Chinese alias 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathione-3-carboxamide, white needle-like crystal, systemic selective heterocycle class of fungicides. Low toxicity to warm-blooded animals. It is easy to decompose and disappear in the soil, relatively safe to fish and birds, and has strong selectivity. It is relatively stable in general media except for strong acid and strong alkali. The object of prevention and control is rustling, which is a selective systemic fungicide. It is mainly used to prevent rust and smut (ear) disease caused by rust fungi and smut fungi on various crops. It is also effective against cotton blight and Verticillium wilt. Effective, such as sorghum loose smut, head smut, corn head smut, wheat smut, wheat rust, millet smut and cotton seedling disease.

氟唑环菌胺,化学名称为2’-[(1RS,2RS)-1,1’-联环丙烯-2-基]-3-(二氟),1-甲基吡唑-4-羧酸苯胺,分为顺式和反式结构。对玉米、麦类、水稻、大豆、棉花等作物上的丝黑穗病等有良好的防治效果。该物质低毒,用作种衣剂时,对多种种传、土传病害有较好的防治效果,还可促进作物根系的生长。Fluxazone, the chemical name is 2'-[(1RS,2RS)-1,1'-bicyclopropen-2-yl]-3-(difluoro),1-methylpyrazole-4-carboxy Acid aniline, divided into cis and trans structures. It has a good control effect on head smut on corn, wheat, rice, soybean, cotton and other crops. The substance has low toxicity, and when used as a seed coating agent, it has good control effects on various seed-borne and soil-borne diseases, and can also promote the growth of crop root systems.

噁霉灵,化学名称为3-羟基-5-甲基异恶唑。外观为无色结晶。恶霉灵作为是一种内吸性杀菌剂和土壤消毒剂,具有独特的作用机理。恶霉灵进入土壤后被土壤吸收并与土壤中的铁、铝等无机金属盐离子结合,有效抑制孢子的萌发和病原真菌菌丝体的正常生长或直接杀灭病菌,药效可达两周。恶霉灵能被植物的根吸收及在根系内移动,在植株内代谢产生两种糖苷,对作物有提高生理活性的效果,从而能促进植株生长,根的分蘖,根毛的增加和根的活性提高。因对土壤中病原菌以外的细菌、放线菌的影响很小,所以对土壤中微生物的生态不产生影响,在土壤中能分解成毒性很低的化合物,对环境安全。恶霉灵是广普性杀菌剂对多种病原真菌引起的植物病害有较高的防治结果,是一种高效低毒环保的杀菌剂、土壤消毒剂,同时又是一种植物生长调节剂。具有内吸性和传导性,能直接被植物根部吸收,且在植物体内移动迅速;在土壤中能提高药效,且持效期长,施用两周内仍有杀菌活性。作用机理独特,高效、微毒、无公害,能有效抑制病原真菌菌丝体的正常生长或直接杀灭病菌。具有促进作物根系生长发育、生根壮苗提高成活率的作用。Hymexazol, the chemical name is 3-hydroxy-5-methylisoxazole. Appearance is colorless crystal. As a systemic fungicide and soil disinfectant, hymexazol has a unique mechanism of action. After entering the soil, hymexazol is absorbed by the soil and combined with inorganic metal salt ions such as iron and aluminum in the soil, effectively inhibiting the germination of spores and the normal growth of pathogenic fungal mycelium or directly killing the bacteria, and the drug effect can reach two weeks . Hymexazol can be absorbed by the roots of plants and move in the root system, metabolize in plants to produce two kinds of glycosides, which can improve the physiological activity of crops, thereby promoting plant growth, root tillering, root hair increase and root activity improve. Because it has little effect on bacteria and actinomycetes other than pathogenic bacteria in the soil, it has no impact on the ecology of microorganisms in the soil, and can be decomposed into compounds with low toxicity in the soil, which is safe for the environment. Hymexazol is a broad-spectrum fungicide that has a high control effect on plant diseases caused by various pathogenic fungi. It is an efficient, low-toxic and environmentally friendly fungicide, soil disinfectant, and a plant growth regulator. It has systemic and conductive properties, can be directly absorbed by plant roots, and moves quickly in plants; it can improve the efficacy in soil, and has a long-lasting effect, and it still has bactericidal activity within two weeks of application. The mechanism of action is unique, highly efficient, slightly toxic, and pollution-free, and can effectively inhibit the normal growth of pathogenic fungal mycelia or directly kill pathogenic bacteria. It has the effect of promoting the growth and development of crop root system, taking root and strong seedling and improving the survival rate.

氯氰菊酯,氯氰菊酯常以黄色至琥珀色粘稠液体呈现,虽然难溶解于水,但能溶解于有机溶剂,例如醇类、氯代烃类、酮类、环己烷、苯、二甲苯等等。虽然在土壤和植物上容易分解,但是使一种速效神经毒素。具触杀和胃毒作用,对光热都稳定,药效比氯菊酯高,适用于防虫杀虫,例如蝇类、蚊类和蚋属等昆虫。适用于防治棉花、蔬菜、果树、茶树、森林等多种植物上的害虫及卫生害虫。Cypermethrin, cypermethrin usually presents as a yellow to amber viscous liquid. Although it is difficult to dissolve in water, it can be dissolved in organic solvents, such as alcohols, chlorinated hydrocarbons, ketones, cyclohexane, benzene, xylene, etc. Although readily decomposed on soil and plants, it is a fast-acting neurotoxin. It has contact and stomach poisoning effects, is stable to light and heat, and has higher efficacy than permethrin. It is suitable for insect control, such as flies, mosquitoes and gnats. It is suitable for controlling pests and sanitation pests on various plants such as cotton, vegetables, fruit trees, tea trees, and forests.

甲霜灵,化学名称D,L-N-(2,6-二甲基苯基)-N-(2-甲氧基乙酰)丙氨酸甲酯。属于低毒性杀菌剂。内吸性杀菌剂,具有保护和治疗作用,有双向传导性能。对霜霉病菌、疫霉病菌和腐病菌引起的多种作物霜霉病,瓜果蔬菜类的疫霉病、谷子白发病有效。Metalaxyl, chemical name D,L-N-(2,6-dimethylphenyl)-N-(2-methoxyacetyl)alanine methyl ester. It is a low toxicity fungicide. Systemic fungicide, with protective and therapeutic effects, has two-way conductivity. It is effective against downy mildew of various crops caused by downy mildew, phytophthora and rot fungus, phytophthora of melons, fruits and vegetables, and millet white.

硫双威,化学名称为3,7,9,13四甲基-5-11二氧杂-2,8,14-三硫杂-4,7,9,12-四氮杂十五烷-3,12-二烯-6-10-二酮。硫双威主要是胃毒作用,几乎没有触杀作用,无熏蒸和内吸作用,有较强的选择性,在土壤中残效期很短。此品种对鳞翅目害虫有特效,并有杀卵作用,对棉蚜、叶蝉、蓟马和螨类无效,也可用于防治鞘翅目、双翅目及膜翅目害虫。Thiodicarb, the chemical name is 3,7,9,13-tetramethyl-5-11-dioxa-2,8,14-trithia-4,7,9,12-tetraazapentadecane- 3,12-Diene-6-10-dione. Thiodicarb is mainly stomach poisoning, has almost no contact action, no fumigation and systemic action, has strong selectivity, and has a short residual effect in soil. This variety has special effects on Lepidoptera pests and has ovicidal effect, but is ineffective against cotton aphids, leafhoppers, thrips and mites, and can also be used to control Coleoptera, Diptera and Hymenoptera pests.

精甲霜灵,化学名称为N-(2,6-二甲苯基)-N-(甲氧基乙酰基)-D-丙胺酸甲酯。浅棕色,黏稠,透明液体。对霜霉病菌,疫霉病菌,腐霉病菌所致的蔬菜,果树,烟草,油料,棉花,粮食等作物病害具有高效。Metalaxyl, the chemical name is N-(2,6-xylyl)-N-(methoxyacetyl)-D-alanine methyl ester. Light brown, viscous, transparent liquid. It is highly effective against diseases caused by downy mildew, phytophthora, and pythium, such as vegetables, fruit trees, tobacco, oilseeds, cotton, and grain.

福美双,化学名称为四甲基秋兰姆二硫化物。对多种作物霜霉病、疫病、炭疽病、禾谷类黑穗病、苗期黄枯病有较好的防治。一种广谱保护性的福美系杀菌剂。一般用作种子处理,土壤处理或喷雾。Thiram, the chemical name is tetramethylthiuram disulfide. It has good control of downy mildew, blight, anthracnose, cereal smut, and seedling yellow blight of various crops. A broad-spectrum protective thiram fungicide. Generally used as seed treatment, soil treatment or spray.

五氯硝基苯,属有机氮保护性杀菌剂。对人、畜、鱼低毒,在土壤残效期长。主要用作土壤和种子处理。对多种蔬菜的苗期病害及土壤传染的病害有较好的防治效果。Pentachloronitrobenzene is an organic nitrogen protective fungicide. It has low toxicity to people, livestock and fish, and has a long residual effect in soil. Mainly used as soil and seed treatment. It has a good control effect on various vegetable seedling diseases and soil-borne diseases.

克菌丹,为广谱性杀菌剂,兼有保护和治疗作用。可用作叶面喷雾和种子处理。防治多种蔬菜的霜霉病、白粉病、炭疽病,西红柿和马铃薯早疫病、晚疫病。防治多种蔬菜的苗期立枯病、猝倒病。防治菜豆和蚕豆炭疽病、立枯病、根腐病。Captan, a broad-spectrum fungicide, has both protective and therapeutic effects. Can be used as a foliar spray and seed treatment. Control downy mildew, powdery mildew, anthracnose of various vegetables, early blight and late blight of tomatoes and potatoes. Prevention and treatment of seedling blight and damping-off of a variety of vegetables. Control bean and broad bean anthracnose, blight, root rot.

甲拌磷,学名二硫代磷酸O,O二乙基-S-乙硫基甲基酯。是透明的、有轻微臭味的油状液体,主要用途是内吸杀虫、杀螨剂,具胃毒、触杀和熏蒸作用。抑制胆碱酯酶活性,造成神经生理功能紊乱。甲拌磷对刺吸式口器和咀嚼式口器害虫都有效,如蚜虫、飞虱、蓟马、红蜘蛛等。Phorate, the scientific name is O, O diethyl-S-ethylthiomethyl dithiophosphate. It is a transparent oily liquid with a slight odor. It is mainly used as a systemic insecticide and acaricide. It has stomach poisoning, contact killing and fumigation effects. Inhibition of cholinesterase activity, resulting in neurophysiological dysfunction. Phorate is effective against both piercing-sucking and chewing mouthparts pests, such as aphids, planthoppers, thrips, red spiders, etc.

丁硫克百威,化学名称为2,3-二氢-2,2-二甲基苯并呋喃-7-基甲基氨基甲酸酯。丁硫克百威杀虫谱广,对蚜虫、柑桔锈壁虱等均有很高的杀灭效果。Carbosulfan, the chemical name is 2,3-dihydro-2,2-dimethylbenzofuran-7-ylmethyl carbamate. Carbosulfan has a wide insecticidal spectrum, and has a high killing effect on aphids and citrus rust ticks.

在农业生产上,如果作物长时间只以一种药来防治害虫,会造成害虫的抗药性大大提高而降低药性,因此采用不同种类的药物进行不同成分比例的复配,会有效提高药物的治理效果,还可以降低药物的使用量,延缓害虫的抗药性产生时间,是防治害虫的有效手段。In agricultural production, if crops only use one kind of medicine to control pests for a long time, it will greatly increase the resistance of pests and reduce the resistance of insecticides. Therefore, the use of different types of medicines for compounding with different proportions of ingredients will effectively improve the control of medicines It can also reduce the amount of medicine used and delay the time of pest resistance, which is an effective means of pest control.

种子包衣技术是我国九十年代广泛推广的一项植物保护技术,它具有综合防治、低毒高效、省种省药、保护环境、投入产出比高的特点。种子包衣是采取机械或手工方法,按一定比例将含有杀虫剂、杀菌剂、复合肥料、微量元素、植物生长调节剂、缓释剂和成膜剂等多种成分的种衣剂均匀包覆在种子表面,形成一层光滑、牢固的药膜。随着种子表面,形成一层光滑、牢固的药膜。随着种子的萌动、发芽、出苗和生长,包衣中的有效成分逐渐被植株根系吸收并传导到幼苗植株各部位,使种子及幼苗对种子带菌、土壤带菌及地下、地上害虫起到防治作用。药膜中的微肥可在底肥借力之前充分发挥效力。因此,包衣种子苗期生长旺盛,叶色浓绿,根系发达,植株健壮,从而实现增产增收的目的。Seed coating technology is a plant protection technology widely promoted in my country in the 1990s. It has the characteristics of comprehensive control, low toxicity and high efficiency, saving seeds and drugs, protecting the environment, and high input-output ratio. Seed coating is to use mechanical or manual methods to evenly coat the seed coating agent containing insecticides, fungicides, compound fertilizers, trace elements, plant growth regulators, slow-release agents and film-forming agents in a certain proportion. Cover the surface of the seeds to form a smooth, firm film. Along with the surface of the seeds, a smooth, firm medicinal film is formed. With the germination, germination, emergence and growth of the seeds, the active ingredients in the coating are gradually absorbed by the roots of the plants and transmitted to all parts of the seedlings, so that the seeds and seedlings can prevent and control the seed and soil bacteria and underground and above-ground pests . The micro-fertilizer in the drug film can fully exert its effectiveness before the base fertilizer takes advantage of it. Therefore, the coated seeds grow vigorously at the seedling stage, the leaves are dark green, the root system is developed, and the plants are strong, so as to achieve the purpose of increasing production and income.

发明内容Contents of the invention

本发明的目的是提供一种含戊吡虫胍的悬浮种衣剂及其制备方法。The object of the present invention is to provide a suspension seed coating agent containing pentametamiguan and its preparation method.

所述含戊吡虫胍的悬浮种衣剂,其组成包括下述质量分数的原料:The suspension seed-coating formulation containing pentametamiguan, its composition comprises the raw material of following mass fraction:

其中,悬浮种衣剂的粒径在1-6μm。Wherein, the particle size of the suspended seed coating agent is 1-6 μm.

为了进一步提高药物的治理效果,所述含戊吡虫胍的悬浮种衣剂还可包括下述质量分数的原料:In order to further improve the governance effect of medicine, the suspension seed-coating agent containing Pentetamiguan can also include the raw materials of the following mass fractions:

上述原料的质量百分含量不同时为0。The mass percent content of the above-mentioned raw materials is not 0 at the same time.

为了进一步提高药物的治理效果,所述含戊吡虫胍的悬浮种衣剂优选包括下述质量分数的原料:In order to further improve the governance effect of medicine, the suspension seed-coating agent containing Pentetamiguan preferably includes the raw materials of following mass fraction:

上述原料的质量百分含量不同时为0。The mass percent content of the above-mentioned raw materials is not 0 at the same time.

所述含戊吡虫胍的悬浮种衣剂中还可包括着色剂,其质量分数为0.1-1.2%。The suspension seed-coating agent containing pentametamiguan may also include a coloring agent, and its mass fraction is 0.1-1.2%.

更进一步的,本发明所述含戊吡虫胍的悬浮种衣剂优选为下述1)-3):Furthermore, the suspension seed coating agent containing pentametamiguan described in the present invention is preferably the following 1)-3):

1)所述含戊吡虫胍的悬浮种衣剂,包括下述质量分数的原料:1) The suspension seed-coating agent containing Pentetamiclon comprises the raw materials of the following mass fractions:

其中,戊吡虫胍与苯醚甲环唑的质量比可优选为1:2-3:2,具体可:5:5、10:10、10:20、20:20、30:20。Wherein, the mass ratio of pentametacoguan to difenoconazole may preferably be 1:2-3:2, specifically: 5:5, 10:10, 10:20, 20:20, 30:20.

2)所述含戊吡虫胍的悬浮种衣剂,包括下述质量分数的原料:2) The suspension seed-coating agent containing Pentetamiclon comprises the raw materials of following mass fraction:

其中,戊吡虫胍与毒死蜱的质量比可优选为1:2-3:2,具体可:5:5、10:10、10:20、20:20、30:20。Wherein, the mass ratio of pentaclofen to chlorpyrifos may preferably be 1:2-3:2, specifically: 5:5, 10:10, 10:20, 20:20, 30:20.

3)所述含戊吡虫胍的悬浮种衣剂,包括下述质量分数的原料:3) The suspension seed-coating agent containing Pentetamiclon comprises the raw materials of the following mass fractions:

其中,戊吡虫胍与咪鲜胺的质量比可优选为1:2-3:2,具体可:5:5、10:10、10:20、20:20、30:20。Wherein, the mass ratio of pentaclofen to prochloraz can be preferably 1:2-3:2, specifically: 5:5, 10:10, 10:20, 20:20, 30:20.

本发明所述的悬浮种衣剂,其中的润湿分散剂为:脂肪醇聚氧乙烯醚、蓖麻油聚氧乙烯醚非离子乳化剂、非离子型羟基聚环氧乙烷嵌段聚合物、聚羧酸脂类高分子分散剂、聚丙烯酸共聚物分散剂,烷基酚聚氧乙烯醚,烷基苯醚磺酸盐,亲水性的单梳状聚合物,烷基芳基聚氧乙烯醚磷酸酯、木质素磺酸盐、烷基萘磺酸钠、甲基萘磺酸甲醛缩合物硫酸盐、萘磺酸甲醛缩合物、亚甲基萘磺酸钠二丁基萘磺酸甲醛缩合物、N-甲基脂肪酰基牛磺酸钠、烷基酚聚氧乙烯醚甲醛缩合物硫酸盐、聚合羧酸钠、烷基酚聚氧乙烯醚硫酸酯、茶枯粉、皂素、亚硫酸纸浆废液、脂肪醇硫酸盐、十二烷基磺酸钠、脂肪酰胺-N-甲基牛磺酸钠盐、脂肪醇聚氧乙烯醚硫酸钠、EO/PO嵌段聚合物、嵌段聚醚、烷基苯醚磺酸盐、聚醚磷酸酯、萘磺酸盐缩聚物、聚羧酸盐、多苯乙烯苯醚磷酸酯和脂肪醇聚氧乙烯醚中的一种或几种。上述润湿分散剂均是本领域公知的物质,可通过各种商业渠道获得。The suspension seed coating agent of the present invention, wherein the wetting and dispersing agent is: fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether nonionic emulsifier, nonionic hydroxyl polyethylene oxide block polymer, Polycarboxylate polymer dispersant, polyacrylic acid copolymer dispersant, alkylphenol polyoxyethylene ether, alkylphenylene ether sulfonate, hydrophilic single-comb polymer, alkylaryl polyoxyethylene Ether phosphate, lignosulfonate, sodium alkylnaphthalenesulfonate, methylnaphthalenesulfonate formaldehyde condensate sulfate, naphthalenesulfonate formaldehyde condensate, sodium methylenenaphthalenesulfonate dibutylnaphthalenesulfonate formaldehyde condensation Sodium N-methyl fatty acyl taurate, alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, polycarboxylate sodium, alkylphenol polyoxyethylene ether sulfate, tea dry powder, saponin, sulfurous acid Pulp waste liquid, fatty alcohol sulfate, sodium dodecyl sulfonate, fatty amide-N-methyl taurine sodium salt, fatty alcohol polyoxyethylene ether sodium sulfate, EO/PO block polymer, block polymer One or more of ether, alkyl phenyl ether sulfonate, polyether phosphate, naphthalene sulfonate condensation polymer, polycarboxylate, polystyrene phenyl ether phosphate and fatty alcohol polyoxyethylene ether. The above wetting and dispersing agents are all well-known substances in the art and can be obtained through various commercial channels.

本发明所述的悬浮种衣剂,其中的成膜剂为:丙烯酸树脂改性酪蛋白成膜剂、壳聚糖、丙烯酸树脂聚氨酯共聚树脂、聚乙烯、丙烯酸酯改性丁二烯树脂、聚氨酯改性硝酸纤维、聚乙烯醇、聚乙二醇和聚醋酸乙烯中的一种或几种。Suspension seed coating agent of the present invention, wherein film forming agent is: acrylic resin modified casein film forming agent, chitosan, acrylic resin polyurethane copolymer resin, polyethylene, acrylate modified butadiene resin, polyurethane One or more of modified nitrocellulose, polyvinyl alcohol, polyethylene glycol and polyvinyl acetate.

本发明所述的悬浮种衣剂,其中的增稠剂为:瓜尔胶、硅酸铝镁水溶液、阿拉伯树胶、黄原胶、甲基纤维素、羟丙基甲基纤维素、羧甲基纤维素钠、羟乙基纤维素、钠基膨润土、有机膨润土和硅藻土中的一种或多种。The suspension seed coating agent of the present invention, wherein the thickener is: guar gum, aluminum magnesium silicate aqueous solution, gum arabic, xanthan gum, methyl cellulose, hydroxypropyl methyl cellulose, carboxymethyl One or more of sodium cellulose, hydroxyethyl cellulose, sodium bentonite, organic bentonite and diatomaceous earth.

本发明所述的悬浮种衣剂,其中的防冻剂为:乙醇、异丙醇、乙二醇、丙二醇、丙二醇丁醚、乙二醇丁醚醋酸酯、甲酰胺、氯化钙、醋酸钠和尿素中的一种或多种。Suspension seed coating agent of the present invention, wherein antifreezing agent is: ethanol, isopropanol, ethylene glycol, propylene glycol, propylene glycol butyl ether, ethylene glycol butyl ether acetate, formamide, calcium chloride, sodium acetate and One or more of urea.

本发明所述的悬浮种衣剂,其中的消泡剂为:有机硅类消泡剂(如AF-9909)。The suspension seed coating agent of the present invention, wherein the defoamer is: silicone defoamer (such as AF-9909).

本发明所述的悬浮种衣剂,其中的着色剂(又称警色剂,可以提高悬浮种衣剂的使用安全)可以为水性玫红、酸性玫红、永固红(如永固红F4R)、水固紫等中的一种或几种。Suspension seed coating agent of the present invention, wherein coloring agent (also known as warning color agent, can improve the use safety of suspension seed coating agent) can be water-based rose red, acid rose red, permanent red (such as permanent red F4R ), one or more of water solid purple, etc.

所述含戊吡虫胍的悬浮种衣剂的制备方法,包括下述步骤:The preparation method of the suspension seed coating containing Pentetamiguan may further comprise the steps:

(1)按照上述配方要求,将原药戊吡虫胍或戊吡虫胍和吡虫啉、晴菌唑、井冈霉素、吡蚜酮、溴氰菊酯、毒死蜱、噻嗪酮、敌敌畏、硫双威、苯醚甲环唑、噻虫胺、噻虫嗪、咯菌腈、吡唑醚菌酯、氟虫腈、拌种灵、咪鲜胺、萎锈灵、氟唑环菌胺、噁霉灵、氯氰菊酯、甲霜灵、硫双威、精甲霜灵、福美双、五氯硝基苯、克菌丹、甲拌磷、丁硫克百威中的一种或多种、润湿分散剂、着色剂和水混合调浆;(1) According to the requirements of the above formula, the original drug pentaclofen or pentacloprid and imidacloprid, bacendazole, Jinggangmycin, pymetrozine, deltamethrin, chlorpyrifos, buprofezin, dichlorvos, thiobis Difenoconazole, clothianidin, thiamethoxam, fludioxonil, pyraclostrobin, fipronil, seed dressing, prochloraz, wilting, fluxachlor, and bad mold Wetting and dispersing Mixing agent, colorant and water;

(2)将所得浆料移入砂磨罐,通入冷却水进行砂磨直至物料的粒径在1-6μm达到98%以上后,过滤,浆料备用;(2) Move the obtained slurry into a sand milling tank, pass into cooling water and carry out sand grinding until the particle size of the material reaches more than 98% at 1-6 μm, filter, and the slurry is for subsequent use;

(3)把增稠剂配置成质量浓度为1-2%的水溶液、成膜剂和消泡剂一起加入到过滤后的浆料中,加水补足至100%,调试后检测,合格即为成品。(3) The thickener is configured into an aqueous solution with a mass concentration of 1-2%, and the film-forming agent and defoamer are added to the filtered slurry together, and water is added to make up to 100%, and it is tested after debugging, and the finished product is qualified .

本发明所述含有戊吡虫胍的悬浮种衣剂的应用也属于本发明的保护范围。The application of the suspension seed coating containing pentametamiguan in the present invention also belongs to the protection scope of the present invention.

所述应用为含有戊吡虫胍的悬浮种衣剂作为种子处理剂在防治农作物病害和/或虫害中的应用。The application is the application of the suspension seed coating agent containing pentaclove as a seed treatment agent in preventing and controlling crop diseases and/or pests.

其中所述农作物主要包括水稻、玉米、小麦、棉花、油菜、马铃薯、萝卜、甘蓝、高粱、花生、大豆等作物。Wherein the crops mainly include rice, corn, wheat, cotton, rapeseed, potato, radish, cabbage, sorghum, peanut, soybean and other crops.

所述病害主要是指由子囊菌纲、担子菌纲、半知菌纲、白粉菌科、锈菌目等的病原菌引起的病害。The diseases mainly refer to diseases caused by pathogenic bacteria of Ascomycetes, Basidiomycetes, Deuteromycetes, Erysidiomycetes, Rusts and the like.

所述半知菌纲包括链格孢属、壳二孢属、尾孢霉属、刺盘孢属、球痤菌属、茎点霉属、柱隔孢属、壳针孢属、黑星菌属。Said Deuteromycetes include Alternaria, Ascodiospora, Cercospora, Neptonia, Ballacne, Phoma, Septoria, Septoria, and Black Star belongs to.

所述害虫主要是蛴螬、叶甲、金针虫、地老虎、蚜虫、飞虱、粉虱、叶蝉、棉铃虫。The pests are mainly grubs, leaf beetles, day lilies, cutworms, aphids, planthoppers, whiteflies, leafhoppers, and cotton bollworms.

本发明提供的含有戊吡虫胍的悬浮种衣剂与现有技术相比,具有以下优点:Compared with the prior art, the suspension seed coating agent provided by the invention has the following advantages:

(1)本发明所述的悬浮种衣剂以戊吡虫胍和吡虫啉、晴菌唑、井冈霉素、吡蚜酮、溴氰菊酯、毒死蜱、噻嗪酮、敌敌畏、硫双威、苯醚甲环唑、噻虫胺、噻虫嗪、咯菌腈、吡唑醚菌酯、氟虫腈、拌种灵、咪鲜胺、萎锈灵、氟唑环菌胺、噁霉灵、氯氰菊酯、甲霜灵、硫双威、精甲霜灵、福美双、五氯硝基苯、克菌丹、甲拌磷、丁硫克百威中的一种或多种复配作为有效成分,具有成膜性好、包衣均匀、高效、低毒、低残留的优异性质。与戊吡虫胍或吡虫啉、晴菌唑、井冈霉素、吡蚜酮、溴氰菊酯、毒死蜱、噻嗪酮、敌敌畏、硫双威、苯醚甲环唑、噻虫胺、噻虫嗪、咯菌腈、吡唑醚菌酯、氟虫腈、拌种灵、咪鲜胺、萎锈灵、氟唑环菌胺、噁霉灵、氯氰菊酯、甲霜灵、硫双威、精甲霜灵、福美双、五氯硝基苯、克菌丹、甲拌磷、丁硫克百威中的单一成分相比,具有更好的杀虫效果。(1) The suspension seed coating agent of the present invention is composed of pentametamiguanidine and imidacloprid, bacconazole, Jinggangmycin, pymetrozine, deltamethrin, chlorpyrifos, buprofezin, dichlorvos, thiodicarb, benzo Diemeconazole, clothianidin, thiamethoxam, fludioxonil, pyraclostrobin, fipronil, seed dressing, prochloraz, wilting, fluxachlor, hymexazol, cypermethrin , metalaxyl, thiodicarb, metalaxyl, thiram, pentachloronitrobenzene, captan, phorate, and carbosulfan as active ingredients. Excellent film-forming properties, uniform coating, high efficiency, low toxicity, and low residue. With penetamicloguanidine or imidacloprid, bacconazole, Jinggangmycin, pymetrozine, deltamethrin, chlorpyrifos, buprofezin, dichlorvos, thiodicarb, difenoconazole, clothianidin, thiamethoxam , fludioxonil, pyraclostrobin, fipronil, seed dressing, prochloraz, wiltazol, fluxazone, hymexazol, cypermethrin, metalaxyl, thiodicarb, and nail cream It has better insecticidal effect compared with the single ingredients in methionine, thiram, pentachloronitrobenzene, captan, phorate, and carbosulfan.

(2)本发明所述悬浮种衣剂使用方便,在处理种子时,可以人工手动拌种,也可以机械拌种,可以大幅提高使用效率并满足不同使用场所的需要。(2) The suspension seed coating agent of the present invention is easy to use. When treating seeds, it can be manually or mechanically dressed, which can greatly improve the use efficiency and meet the needs of different places of use.

本发明将戊吡虫胍、吡虫啉、晴菌唑、井冈霉素、吡蚜酮、溴氰菊酯、毒死蜱、噻嗪酮、敌敌畏、硫双威、苯醚甲环唑、噻虫胺、噻虫嗪、咯菌腈、吡唑醚菌酯、氟虫腈、拌种灵、咪鲜胺、萎锈灵、氟唑环菌胺、噁霉灵、氯氰菊酯、甲霜灵、硫双威、精甲霜灵、福美双、五氯硝基苯、克菌丹、甲拌磷、丁硫克百威其中的一种、两种或多种复配制备悬浮种衣剂,所制备产品有较强的内吸性,并具有触杀、胃毒和内吸多重药效,有较好的防治效用。In the present invention, pentametamiguanine, imidacloprid, bacconazole, Jinggangmycin, pymetrozine, deltamethrin, chlorpyrifos, buprofezin, dichlorvos, thiodicarb, difenoconazole, clothianidin, thiazin Methmethoxam, fludioxonil, pyraclostrobin, fipronil, seed dressing, prochloraz, wilt, fluoxazone, hymexazol, cypermethrin, metalaxyl, thiodicarb, essence One, two or more of metalaxyl, thiram, pentachloronitrobenzene, captan, phorate, and carbosulfan are used to prepare suspension seed coating agents, and the prepared products have strong systemic, and has multiple effects of contact, stomach poisoning and systemic absorption, and has good control effect.

具体实施方式detailed description

下述实施例中所使用的实验方法如无特殊说明,均为常规方法。The experimental methods used in the following examples are conventional methods unless otherwise specified.

下述实施例中所用的材料、试剂等,如无特殊说明,均可从商业途径得到。The materials and reagents used in the following examples can be obtained from commercial sources unless otherwise specified.

下述实施例中的“%”均指质量百分含量。"%" in the following examples refers to mass percentage.

实施例1:5%戊吡虫胍的悬浮种衣剂Embodiment 1: the suspension seed-coating agent of 5% penetamicloguanidine

戊吡虫胍5%、壳聚糖8%、羟丙基甲基纤维素MJ 20000PS 0.1%、苯磺酸盐类阴离子YUS-TXC 3%、消泡剂DP-304 0.4%、异丙醇5%、永固红F4R 1.2%、水补足100%。Pentamicloguanidine 5%, chitosan 8%, hydroxypropyl methylcellulose MJ 20000PS 0.1%, benzenesulfonate anion YUS-TXC 3%, defoamer DP-304 0.4%, isopropanol 5 %, Everlasting Red F4R 1.2%, water make up 100%.

将除羟丙基甲基纤维素MJ 20000PS、异丙醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的羟丙基甲基纤维素MJ 20000PS的异丙醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到5%戊吡虫胍的悬浮种衣剂。Mix the remaining ingredients except hydroxypropyl methylcellulose MJ 20000PS, isopropanol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material is at After the 1-6μm reaches more than 98%, add hydroxypropyl methylcellulose MJ 20000PS isopropanol solution with a mass concentration of 5%, and film-forming agent and defoamer, mix well, add water to make up 100% and mix well , to obtain the suspension seed coating agent of 5% Pentamicloguanidine.

实施例2:15%戊吡虫胍和吡虫啉的悬浮种衣剂Embodiment 2: the suspension seed coating of 15% pentacloprid and imidacloprid

戊吡虫胍5%、吡虫啉10%、壳聚糖10%、羟丙基甲基纤维素MJ 40000PS 0.5%、木质素磺酸盐类YUS-WG4 10%、消泡剂AF-9909 0.4%、乙二醇5%、永固红F4R 1.2%、水补足100%。Pentacloprid 5%, imidacloprid 10%, chitosan 10%, hydroxypropyl methylcellulose MJ 40000PS 0.5%, lignosulfonate YUS-WG4 10%, defoamer AF-9909 0.4%, Ethylene glycol 5%, permanent red F4R 1.2%, water make up 100%.

将除羟丙基甲基纤维素MJ 40000PS、乙二醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的羟丙基甲基纤维素MJ 40000PS的乙二醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到15%戊吡虫胍和吡虫啉的悬浮种衣剂。Mix the remaining ingredients except hydroxypropyl methylcellulose MJ 40000PS, ethylene glycol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material is at After the 1-6μm reaches more than 98%, add 5% hydroxypropyl methylcellulose MJ 40000PS ethylene glycol solution, film-forming agent and defoamer and mix well, add water to make up 100% and mix well , to obtain a suspension seed coating of 15% pentacloprid and imidacloprid.

实施例3:20%戊吡虫胍和晴菌唑的悬浮种衣剂Embodiment 3: the suspension seed-coating agent of 20% pentetamicloguanidine and bacendazole

戊吡虫胍8%、晴菌唑12%、壳聚糖8%、黄原胶0.2%、磺酸盐类阴离子YUS-SXC6%、消泡剂DP-340 0.4%、丙二醇5%、永固红F4R1.2%、水补足100%。Pentaclofen 8%, Bacteril 12%, Chitosan 8%, Xanthan Gum 0.2%, Sulfonate Anion YUS-SXC 6%, Defoamer DP-340 0.4%, Propylene Glycol 5%, Permanent Red F4R1.2%, water make up 100%.

将除黄原胶、丙二醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的黄原胶的丙二醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到20%戊吡虫胍和晴菌唑的悬浮种衣剂。Mix the remaining ingredients except xanthan gum, propylene glycol, film-forming agent (chitosan) and defoamer, and sand them in water with a sand mill until the particle size of the material reaches 98% or more at 1-6 μm , then add a propylene glycol solution of xanthan gum with a mass concentration of 5%, and mix well with a film-forming agent and a defoamer, add water to make up 100% and mix well, to obtain a suspension seed coat of 20% pentaclofen and bacconazole agent.

实施例4:20%戊吡虫胍和苯醚甲环唑的悬浮种衣剂Embodiment 4: the suspension seed coating of 20% penetamicloguanidine and difenoconazole

戊吡虫胍10%、苯醚甲环唑10%、壳聚糖10%、黄原胶0.5%、磺酸盐类阴离子YUS-A51G 10%、消泡剂AF-9909 0.4%、乙二醇5%、永固红F4R 1.2%、水补足100%。Pentaclox guanidine 10%, difenoconazole 10%, chitosan 10%, xanthan gum 0.5%, sulfonate anion YUS-A51G 10%, defoamer AF-9909 0.4%, ethylene glycol 5%, Everlasting Red F4R 1.2%, water make up 100%.

将除黄原胶、乙二醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的黄原胶的乙二醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到20%戊吡虫胍和苯醚甲环唑的悬浮种衣剂。Mix the remaining ingredients except xanthan gum, ethylene glycol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material reaches 98% at 1-6 μm After the above, add the ethylene glycol solution of xanthan gum with a mass concentration of 5%, and the film-forming agent and defoamer and mix well, add water to make up 100% and mix well to obtain 20% pentametamiclon and diphenoxylate Cycloconazole suspension seed coating.

实施例5:20%戊吡虫胍和毒死蜱的悬浮种衣剂Embodiment 5: Suspension seed coating of 20% pentaclofen and chlorpyrifos

戊吡虫胍10%、毒死蜱10%、壳聚糖7%、硅酸镁铝水溶液0.1%、聚氧乙烯醚非离子YUS-D1109S 5%、消泡剂DP-362 0.4%、乙醇5%、永固红1.2%、水补足100%。Pentaclofen 10%, chlorpyrifos 10%, chitosan 7%, magnesium aluminum silicate aqueous solution 0.1%, polyoxyethylene ether non-ionic YUS-D1109S 5%, defoamer DP-362 0.4%, ethanol 5%, Everlasting Red 1.2%, water make up 100%.

将除硅酸镁铝水溶液、乙醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的硅酸镁铝水溶液的乙醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到20%戊吡虫胍和毒死蜱的悬浮种衣剂。Mix the remaining ingredients except magnesium aluminum silicate aqueous solution, ethanol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material reaches 98% at 1-6 μm After the above, add an ethanol solution with a mass concentration of 5% magnesium-aluminum silicate aqueous solution, and a film-forming agent and a defoamer to mix well, add water to make up 100% and mix well to obtain a suspension of 20% pentaclofen and chlorpyrifos Seed coating agent.

实施例6:20%戊吡虫胍和咪鲜胺的悬浮种衣剂Embodiment 6: the suspension seed coating of 20% pentaclofen and prochloraz

戊吡虫胍10%、咪鲜胺10%、壳聚糖10%、硅酸镁铝水溶液0.5%、苯磺酸盐类阴离子YUS-TXC 10%、消泡剂DP-306 0.4%、乙醇5%、永固红F4R 1.2%、水补足100%。Pentaclofen 10%, prochloraz 10%, chitosan 10%, magnesium aluminum silicate aqueous solution 0.5%, benzenesulfonate anion YUS-TXC 10%, defoamer DP-306 0.4%, ethanol 5% %, Everlasting Red F4R 1.2%, water make up 100%.

将除硅酸镁铝水溶液、乙醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的硅酸镁铝水溶液的乙醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到20%戊吡虫胍和咪鲜胺的悬浮种衣剂。Mix the remaining ingredients except magnesium aluminum silicate aqueous solution, ethanol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material reaches 98% at 1-6 μm After the above, add an ethanol solution with a mass concentration of 5% magnesium aluminum silicate aqueous solution, and a film-forming agent and a defoamer to mix well, add water to make up 100% and mix well to obtain 20% pentaclofen and prochloraz suspension seed coating agent.

实施例7:30%戊吡虫胍、吡虫啉和晴菌唑的悬浮种衣剂Embodiment 7: the suspension seed coating agent of 30% pentacloprid, imidacloprid and bacconazole

10%戊吡虫胍、10%吡虫啉、10%晴菌唑、壳聚糖2%、羟丙基甲基纤维素MJ40000PS 0.1%、木质素磺酸盐类YUS-WG4 7%、消泡剂AF-9909 0.4%、丙二醇5%、永固红F4R1.2%、水补足100%。10% pentacloprid, 10% imidacloprid, 10% bacendazole, chitosan 2%, hydroxypropyl methylcellulose MJ40000PS 0.1%, lignosulfonate YUS-WG4 7%, defoamer AF -9909 0.4%, propylene glycol 5%, permanent red F4R 1.2%, water to make up 100%.

将除羟丙基甲基纤维素MJ 40000PS、丙二醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的羟丙基甲基纤维素MJ 40000PS的丙二醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到30%戊吡虫胍、吡虫啉和晴菌唑的悬浮种衣剂。Mix the remaining ingredients except hydroxypropyl methylcellulose MJ 40000PS, propylene glycol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material is between 1- After the 6μm reaches more than 98%, add 5% hydroxypropyl methylcellulose MJ 40000PS propylene glycol solution, film-forming agent and defoamer and mix well, add water to make up 100% and mix well to get 30% Suspension seed coating formulations of Pentacloprid, Imidacloprid and Bicconazole.

实施例8:40%戊吡虫胍、井冈霉素和毒死蜱的悬浮种衣剂Embodiment 8: the suspension seed coating agent of 40% pentaclofen, Jinggangmycin and chlorpyrifos

戊吡虫胍15%、井冈霉素10%、毒死蜱15%、壳聚糖7%、羟丙基甲基纤维素MJ40000PS 0.1%、磺酸盐类阴离子YUS-SXC 5%、消泡剂DP-347 0.4%、乙醇5%、永固红1.2%、水补足100%。Pentaclofen 15%, Jinggangmycin 10%, Chlorpyrifos 15%, Chitosan 7%, Hydroxypropylmethylcellulose MJ40000PS 0.1%, Sulfonate anion YUS-SXC 5%, Defoamer DP- 347 0.4%, ethanol 5%, permanent red 1.2%, water 100%.

将除羟丙基甲基纤维素、乙醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在1-6μm达到98%以上后,再加入质量浓度为5%的羟丙基甲基纤维素MJ 40000PS的乙醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到40%戊吡虫胍、井冈霉素和毒死蜱的悬浮种衣剂。Mix the remaining ingredients except hydroxypropyl methylcellulose, ethanol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material reaches 1-6 μm. After the concentration is above 98%, add the ethanol solution of hydroxypropyl methylcellulose MJ 40000PS with a mass concentration of 5%, and mix well with film-forming agent and defoamer, add water to make up 100% and mix well to obtain 40% pentapyril Suspension seed coatings of Chongguanidine, Jinggangmycin and Chlorpyrifos.

实施例9:50%戊吡虫胍、溴氰菊酯、毒死蜱和噻嗪酮的悬浮种衣剂Example 9: Suspension seed coating of 50% pentaclofen, deltamethrin, chlorpyrifos and buprofezin

戊吡虫胍15%、溴氰菊酯10%、毒死蜱10%、噻嗪酮15%、壳聚糖4%、羟丙基甲基纤维素MJ 20000PS 0.3%、苯磺酸盐类阴离子YUS-TXC 6%、消泡剂DP-377 0.4%、乙二醇5%、永固红F4R 1.2%、水补足100%。Pentaclofen 15%, deltamethrin 10%, chlorpyrifos 10%, buprofezin 15%, chitosan 4%, hydroxypropyl methylcellulose MJ 20000PS 0.3%, benzenesulfonate anion YUS- TXC 6%, defoamer DP-377 0.4%, ethylene glycol 5%, permanent red F4R 1.2%, water to make up 100%.

将除羟丙基甲基纤维素MJ 20000PS、乙二醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在2-6μm达到98%以上后,再加入质量浓度为5%的羟丙基甲基纤维素MJ 20000PS的乙二醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到50%戊吡虫胍、溴氰菊酯、毒死蜱和噻嗪酮的悬浮种衣剂。Mix the remaining ingredients except hydroxypropyl methylcellulose MJ 20000PS, ethylene glycol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material is at After the 2-6μm reaches more than 98%, add the ethylene glycol solution of hydroxypropyl methylcellulose MJ 20000PS with a mass concentration of 5%, and mix well with the film-forming agent and defoamer, add water to make up 100% and mix well , to obtain 50% suspension seed-coating formulations of pentetamicloguanidine, deltamethrin, chlorpyrifos and buprofezin.

实施例10:50%戊吡虫胍、吡虫啉、吡蚜酮、溴氰菊酯和敌敌畏的悬浮种衣剂Example 10: Suspension seed coating of 50% pentacloprid, imidacloprid, pymetrozine, deltamethrin and dichlorvos

戊吡虫胍10%、吡虫啉10%、吡蚜酮10%、溴氰菊酯10%、敌敌畏10%、壳聚糖6%、羟丙基甲基纤维素MJ 20000PS 0.5%、磺酸盐类阴离子YUS-A51G 5%、消泡剂AF-99090.4%、乙二醇5%、永固红F4R1.2%、水补足100%。Pentacloprid 10%, imidacloprid 10%, pymetrozine 10%, deltamethrin 10%, dichlorvos 10%, chitosan 6%, hydroxypropyl methylcellulose MJ 20000PS 0.5%, sulfonates Anion YUS-A51G 5%, defoamer AF-990 90.4%, ethylene glycol 5%, permanent red F4R 1.2%, water make up 100%.

将除羟丙基甲基纤维素MJ 20000PS、乙二醇、成膜剂(壳聚糖)和消泡剂外的其余成分混匀,在水中经砂磨机砂磨直至物料的磨粒径在2-6μm达到98%以上后,再加入质量浓度为5%的羟丙基甲基纤维素MJ 20000PS的乙二醇溶液,以及成膜剂和消泡剂混匀,加水补足100%并混匀,得到50%戊吡虫胍、吡虫啉、吡蚜酮、溴氰菊酯和敌敌畏的悬浮种衣剂。Mix the remaining ingredients except hydroxypropyl methylcellulose MJ 20000PS, ethylene glycol, film-forming agent (chitosan) and defoamer, and grind them in water with a sand mill until the particle size of the material is at After the 2-6μm reaches more than 98%, add the ethylene glycol solution of hydroxypropyl methylcellulose MJ 20000PS with a mass concentration of 5%, and mix well with the film-forming agent and defoamer, add water to make up 100% and mix well , to obtain 50% suspension seed coating formulations of pentametamicloguanidine, imidacloprid, pymetrozine, deltamethrin and dichlorvos.

实施例11:戊吡虫胍和苯醚甲环唑悬浮种衣剂的室内毒力测定Example 11: Indoor Toxicity Determination of Pentaclofen and Difenoconazole Suspension Seed Coatings

采用浸渍法进行室内毒力生物测定,选择蚜虫为目标害虫,重复3次,调查7天后的效果,实验结果见表1。Indoor virulence bioassay was carried out by dipping method, and aphids were selected as the target pests, repeated 3 times, and the effect after 7 days was investigated. The experimental results are shown in Table 1.

SR=LC50(理论值)/LC50(观察值)SR=LC50 (theoretical value)/LC50 (observed value)

表1戊吡虫胍、苯醚甲环唑复配对抗蚜虫的室内毒力测定结果分析表Table 1 Analysis table of indoor toxicity test results of pentametamicloguanidine and difenoconazole compound against aphids

注:编号4-6的悬浮种衣剂中除主药外的其它组分及含量,均与实施例4相同。Note: Except for the main ingredient, other components and contents in the suspension seed coating preparations numbered 4-6 are the same as in Example 4.

由表1可知,戊吡虫胍与苯醚甲环唑复配后的悬浮种衣剂,其增效比值均大于1.5,表现出明显的增效作用。It can be seen from Table 1 that the synergistic ratios of the suspension seed coating formulations compounded with pentaclofen and difenoconazole are all greater than 1.5, showing obvious synergistic effect.

实施例12:戊吡虫胍和苯醚甲环唑悬浮种衣剂防治玉米蛴螬的田间药效Example 12: Field efficacy of Pentaclofen and Difenoconazole Suspended Seed Coatings in Controlling Corn Grubs

1试验目的:戊吡虫胍和苯醚甲环唑悬浮种衣剂防治玉米蛴螬的田间药效实验,测定该悬浮种衣剂对蛴螬的防治效果。1. Purpose of the test: The field efficacy experiment of pentametracoguanidine and difenoconazole suspension seed coating agent to control corn grub, and to determine the control effect of the suspension seed coating agent on grub.

2试验条件2 test conditions

试验对象:蛴螬Test object: grub

试验作物:玉米Test crop: corn

试验药剂:实施例4制备的20%戊吡虫胍和苯醚甲环唑悬浮种衣剂(其中,戊吡虫胍和苯醚甲环唑的质量比为10:10)Test medicament: 20% pentametacoguan and difenoconazole suspension seed coating prepared in Example 4 (wherein the mass ratio of pentametacoguan and difenoconazole is 10:10)

对照药剂:10%戊吡虫胍溶液,10%苯醚甲环唑溶液Control agents: 10% Pentaclove guanidine solution, 10% Difenoconazole solution

试验地点:河北省石家庄市正定县Test location: Zhengding County, Shijiazhuang City, Hebei Province

3试验方法3 test method

将玉米种以戊吡虫胍和苯醚甲环唑悬浮种衣剂、戊吡虫胍悬浮种衣剂、苯醚甲环唑悬浮种衣剂和空白清水拌种处理后播种。玉米齐苗20天后调查蛴螬活虫数量。The corn seeds were sown after being treated with pentametacon and difenoconazole suspension seed coating, pentametacon suspension seed coating, difenoconazole suspension seed coating and blank water. Investigate the number of live grubs 20 days after the corn seedlings are assembled.

4样本采集和药效计算方法4 Sample collection and efficacy calculation method

齐苗20天后在分布不同种衣剂地点中随机五点取样,挖图调查土中蛴螬数量,计算防虫效果。After 20 days, the seedlings were randomly sampled at five points in the locations where different seed coating agents were distributed, and the number of grubs in the soil was dug to investigate the number of grubs, and the insect control effect was calculated.

5结果与分析5 Results and Analysis

表2戊吡虫胍和苯醚甲环唑悬浮种衣剂防治玉米蛴螬试验结果Table 2 Test results of pentametamiclon and difenoconazole suspension seed coatings on corn grub control

注:编号B的悬浮种衣剂为实施例4制备的产品,编号A\C\D的悬浮种衣剂中除主药外的其它组分及含量,均与编号B相同。Note: The suspension seed-coating preparation of number B is the product prepared in Example 4, and the other components and contents of the suspension seed-coating preparations of numbers A\C\D are the same as those of number B except the main ingredient.

从表2可以看出,试验中复配的戊吡虫胍和苯醚甲环唑悬浮种衣剂防虫效果优于单独的戊吡虫胍溶液和苯醚甲环唑溶液,并且随着有效成分含量的增加,防虫效果也随之增加。试验表明该戊吡虫胍和苯醚甲环唑悬浮种衣剂对于田间地下害虫有良好的防治效果。As can be seen from Table 2, in the test, the insect-proof effect of compounded pentametacon and difenoconazole suspension seed coating is better than that of separate pentametacon solution and difenoconazole solution, and with the active ingredient As the content increases, the insect repellent effect also increases. Tests have shown that the suspension seed coating formulation of pentaclofen and difenoconazole has a good control effect on underground pests in the field.

实施例13:戊吡虫胍和毒死蜱悬浮种衣剂的室内毒力测定Example 13: Indoor Toxicity Determination of Pentetamicloguanidine and Chlorpyrifos Suspension Seed Coatings

采用浸渍法进行室内毒力生物测定,选择蚜虫为目标害虫,重复3次,调查7天后的效果,实验结果见表1。Indoor virulence bioassay was carried out by dipping method, and aphids were selected as the target pests, repeated 3 times, and the effect after 7 days was investigated. The experimental results are shown in Table 1.

SR=LC50(理论值)/LC50(观察值)SR=LC50 (theoretical value)/LC50 (observed value)

表3戊吡虫胍、毒死蜱复配对抗蚜虫的室内毒力测定结果分析表Table 3 Analysis table of indoor toxicity test results of pentameticoguanidine and chlorpyrifos compound against aphids

注:编号4-6的悬浮种衣剂中除主药外的其它组分及含量,均与实施例5相同。Note: Except for the main ingredient, other components and contents in the suspension seed coating preparations numbered 4-6 are the same as those in Example 5.

由表3可知,戊吡虫胍与毒死蜱复配后的悬浮种衣剂,其增效比值均大于1.5,表现出明显的增效作用。It can be seen from Table 3 that the synergistic ratios of the suspension seed coating formulations compounded with pentetamicloguanidine and chlorpyrifos are all greater than 1.5, showing obvious synergistic effect.

实施例14:戊吡虫胍和毒死蜱悬浮种衣剂防治玉米蛴螬的田间药效Example 14: Field efficacy of pentametamiguanidine and chlorpyrifos suspension seed coating agent in controlling corn grubs

1试验目的:戊吡虫胍和毒死蜱悬浮种衣剂防治玉米蛴螬的田间药效实验,测定该悬浮种衣剂对蛴螬的防治效果。1. Purpose of the test: The field efficacy experiment of Pentaclofen and chlorpyrifos suspension seed coating agent to control corn grubs, and to determine the control effect of the suspension seed coating agent on grubs.

2试验条件2 test conditions

试验对象:蛴螬Test object: grub

试验作物:玉米Test crop: corn

试验药剂:实施例5制备的20%戊吡虫胍和毒死蜱悬浮种衣剂(其中,戊吡虫胍和毒死蜱的质量比为10:10)Test medicament: the 20% pentetamicloguanidine and chlorpyrifos suspension seed coating preparation prepared in Example 5 (wherein the mass ratio of pentetamicloguanidine and chlorpyrifos is 10:10)

对照药剂:10%戊吡虫胍溶液,10%毒死蜱溶液Control agent: 10% pentaclofen solution, 10% chlorpyrifos solution

试验地点:河北省石家庄市正定县Test location: Zhengding County, Shijiazhuang City, Hebei Province

3试验方法3 test method

将玉米种以戊吡虫胍和毒死蜱悬浮种衣剂、戊吡虫胍悬浮种衣剂、毒死蜱悬浮种衣剂和空白清水拌种处理后播种。玉米齐苗20天后调查蛴螬活虫数量。The corn seeds were sown after being treated with pentameticoguanidine and chlorpyrifos suspension seed coating agent, pentametrex guanidine suspension seed coating agent, chlorpyrifos suspension seed coating agent and blank water. Investigate the number of live grubs 20 days after the corn seedlings are assembled.

4样本采集和药效计算方法4 Sample collection and efficacy calculation method

齐苗20天后在分布不同种衣剂地点中随机五点取样,挖图调查土中蛴螬数量,计算防虫效果。After 20 days, the seedlings were randomly sampled at five points in the locations where different seed coating agents were distributed, and the number of grubs in the soil was dug to investigate the number of grubs, and the insect control effect was calculated.

5结果与分析5 Results and Analysis

表4戊吡虫胍和毒死蜱悬浮种衣剂防治玉米蛴螬试验结果Table 4 Test results of pentametamicloguanidine and chlorpyrifos suspension seed coating agent to control corn grub

注:编号B的悬浮种衣剂为实施例5制备的产品,编号A\C\D的悬浮种衣剂中除主药外的其它组分及含量,均与编号B相同。Note: The suspension seed coating agent with number B is the product prepared in Example 5, and the other components and contents of the suspension seed coating agent with numbers A\C\D are the same as those of number B except the main ingredient.

从表4可以看出试验中复配的戊吡虫胍和毒死蜱悬浮种衣剂防虫效果优于单独的戊吡虫胍溶液和毒死蜱溶液,并且随着有效成分含量的增加,防虫效果也随之增加。试验表明该戊吡虫胍和毒死蜱悬浮种衣剂对于田间地下害虫有良好的防治效果。As can be seen from Table 4, the insect-proof effect of the compounded pentameticoguanidine and chlorpyrifos suspension seed coating agent in the test is better than that of the separate pentameticoguanidine solution and chlorpyrifos solution, and with the increase of the active ingredient content, the insect-proof effect is also thereupon. Increase. Tests have shown that the suspended seed coating agent of pentaclofen and chlorpyrifos has a good control effect on subterranean pests in the field.

实施例15:戊吡虫胍和咪鲜胺悬浮种衣剂的室内毒力测定Example 15: Indoor Toxicity Determination of Pentaclofen and Prochloraz Suspension Seed Coatings

采用浸渍法进行室内毒力生物测定,选择蚜虫为目标害虫,重复3次,调查7天后的效果,实验结果见表1。Indoor virulence bioassay was carried out by dipping method, and aphids were selected as the target pests, repeated 3 times, and the effect after 7 days was investigated. The experimental results are shown in Table 1.

SR=LC50(理论值)/LC50(观察值)SR=LC50 (theoretical value)/LC50 (observed value)

表5戊吡虫胍、咪鲜胺复配对抗蚜虫的室内毒力测定结果分析表Table 5 Analysis table of indoor toxicity test results of pentametamiguanidine and prochloraz compound against aphids

注:编号4-6的悬浮种衣剂中除主药外的其它组分及含量,均与实施例6相同。Note: Except for the main ingredient, other components and contents in the suspension seed coating preparations numbered 4-6 are the same as those in Example 6.

由表5可知,戊吡虫胍与咪鲜胺复配后的悬浮种衣剂,其增效比值均大于1.5,表现出明显的增效作用。It can be seen from Table 5 that the synergistic ratios of the suspension seed coating formulations compounded with pentaclofen and prochloraz are all greater than 1.5, showing obvious synergistic effect.

实施例15:戊吡虫胍和咪鲜胺悬浮种衣剂防治玉米蛴螬的田间药效Example 15: Field efficacy of pentaclofen and prochloraz suspension seed coatings in controlling corn grubs

1试验目的:戊吡虫胍和咪鲜胺悬浮种衣剂防治玉米蛴螬的田间药效实验,测定该悬浮种衣剂对蛴螬的防治效果。1. Purpose of the test: The field efficacy experiment of pentaclofen and prochloraz suspension seed coating agent to control corn grub, and to determine the control effect of the suspension seed coating agent on grub.

2试验条件2 test conditions

试验对象:蛴螬Test object: grub

试验作物:玉米Test crop: corn

试验药剂:实施例6制备的20%戊吡虫胍和咪鲜胺悬浮种衣剂(其中,戊吡虫胍和咪鲜胺的质量比为10:10)Test medicament: the 20% pentaclox and prochloraz suspension seed coating prepared in Example 6 (wherein the mass ratio of pentaclox and prochloraz is 10:10)

对照药剂:10%戊吡虫胍溶液,10%咪鲜胺溶液Control agent: 10% pentaclofen solution, 10% prochloraz solution

试验地点:河北省石家庄市正定县Test location: Zhengding County, Shijiazhuang City, Hebei Province

3试验方法3 test method

将玉米种以戊吡虫胍和咪鲜胺悬浮种衣剂、戊吡虫胍悬浮种衣剂、咪鲜胺悬浮种衣剂和空白清水拌种处理后播种。玉米齐苗20天后调查蛴螬活虫数量。The corn seeds were sown after being treated with pentaclofen and prochloraz suspension seed coating agent, pentametrex guanidine suspension seed coating agent, prochloraz suspension seed coating agent and blank water. Investigate the number of live grubs 20 days after the corn seedlings are assembled.

4样本采集和药效计算方法4 Sample collection and efficacy calculation method

齐苗20天后在分布不同种衣剂地点中随机五点取样,挖图调查土中蛴螬数量,计算防虫效果。After 20 days, the seedlings were randomly sampled at five points in the locations where different seed coating agents were distributed, and the number of grubs in the soil was dug to investigate the number of grubs, and the insect control effect was calculated.

5结果与分析5 Results and Analysis

表6戊吡虫胍和咪鲜胺悬浮种衣剂防治玉米蛴螬试验结果Table 6 Test results of pentaclofen and prochloraz suspension seed coatings for the control of corn grubs

注:编号B的悬浮种衣剂为实施例6制备的产品,编号A\C\D的悬浮种衣剂中除主药外的其它组分及含量,均与编号B相同。Note: The suspension seed coating agent with number B is the product prepared in Example 6, and the other components and contents of the suspension seed coating agent with numbers A\C\D are the same as those of number B except the main ingredient.

从表6可以看出,试验中复配的戊吡虫胍和咪鲜胺悬浮种衣剂防虫效果优于单独的戊吡虫胍溶液和咪鲜胺溶液,并且随着有效成分含量的增加,防虫效果也随之增加。试验表明该戊吡虫胍和咪鲜胺悬浮种衣剂对于田间地下害虫有良好的防治效果。As can be seen from Table 6, the insect-proof effect of the compounded pentidine guanidine and prochloraz suspension seed coating agent in the test is better than that of the separate pentidine guanidine solution and prochloraz solution, and with the increase of active ingredient content, The insect repellent effect also increases accordingly. Tests have shown that the suspended seed coating formulation of pentaclofen and prochloraz has a good control effect on underground pests in the field.

Claims (10)

1.一种含戊吡虫胍的悬浮种衣剂,其组成包括下述质量分数的原料:1. a kind of suspension seed coating containing Pentetamiclon, its composition comprises the raw material of following mass fraction: 其中,悬浮种衣剂的粒径为1-6μm。Wherein, the particle size of the suspended seed coating agent is 1-6 μm. 2.根据权利要求1所述的悬浮种衣剂,其特征在于:所述含戊吡虫胍的悬浮种衣剂还包括下述质量分数的原料:2. suspension seed coating agent according to claim 1, is characterized in that: the suspension seed coating agent containing pentametamiguan also comprises the raw material of following mass fraction: 上述原料的质量百分含量不同时为0;The mass percentage of the above raw materials is not 0 at the same time; 优选包括下述质量分数的原料:Preferably comprise the raw material of following mass fraction: 上述原料的质量百分含量不同时为0。The mass percent content of the above-mentioned raw materials is not 0 at the same time. 3.根据权利要求1或2所述的悬浮种衣剂,其特征在于:所述含戊吡虫胍的悬浮种衣剂选自为下述1)-3):3. The suspension seed coating agent according to claim 1 or 2, characterized in that: the suspension seed coating agent containing Pentametamiguan is selected from the following 1)-3): 1)所述含戊吡虫胍的悬浮种衣剂,包括下述质量分数的原料:1) The suspension seed-coating agent containing Pentetamiclon comprises the raw materials of the following mass fractions: 其中,戊吡虫胍与苯醚甲环唑的质量比优选为1:2-3:2;Wherein, the mass ratio of Pentaclox and Difenoconazole is preferably 1:2-3:2; 2)所述含戊吡虫胍的悬浮种衣剂,包括下述质量分数的原料:2) The suspension seed-coating agent containing Pentetamiclon comprises the raw materials of following mass fraction: 其中,戊吡虫胍与毒死蜱的质量比优选为1:2-3:2;Wherein, the mass ratio of pentaclofen and chlorpyrifos is preferably 1:2-3:2; 3)所述含戊吡虫胍的悬浮种衣剂,包括下述质量分数的原料:3) The suspension seed-coating agent containing Pentetamiclon comprises the raw materials of the following mass fractions: 其中,戊吡虫胍与咪鲜胺的质量比优选为1:2-3:2。Wherein, the mass ratio of pentaclofen to prochloraz is preferably 1:2-3:2. 4.根据权利要求1-3任一项所述的悬浮种衣剂,其特征在于:所述含戊吡虫胍的悬浮种衣剂中还包括着色剂,其质量分数为0.1-1.2%。4. The suspension seed coating agent according to any one of claims 1-3, characterized in that: the suspension seed coating agent containing pentametamiguanin also includes a coloring agent with a mass fraction of 0.1-1.2%. 5.根据权利要求1-4任一项所述的悬浮种衣剂,其特征在于:所述润湿分散剂为脂肪醇聚氧乙烯醚、蓖麻油聚氧乙烯醚非离子乳化剂、非离子型羟基聚环氧乙烷嵌段聚合物、聚羧酸脂类高分子分散剂、聚丙烯酸共聚物分散剂,烷基酚聚氧乙烯醚,烷基苯醚磺酸盐,亲水性的单梳状聚合物,烷基芳基聚氧乙烯醚磷酸酯、木质素磺酸盐、烷基萘磺酸钠、甲基萘磺酸甲醛缩合物硫酸盐、萘磺酸甲醛缩合物、亚甲基萘磺酸钠二丁基萘磺酸甲醛缩合物、N-甲基脂肪酰基牛磺酸钠、烷基酚聚氧乙烯醚甲醛缩合物硫酸盐、聚合羧酸钠、烷基酚聚氧乙烯醚硫酸酯、茶枯粉、皂素、亚硫酸纸浆废液、脂肪醇硫酸盐、十二烷基磺酸钠、脂肪酰胺-N-甲基牛磺酸钠盐、脂肪醇聚氧乙烯醚硫酸钠、EO/PO嵌段聚合物、嵌段聚醚、烷基苯醚磺酸盐、聚醚磷酸酯、萘磺酸盐缩聚物、聚羧酸盐、多苯乙烯苯醚磷酸酯和脂肪醇聚氧乙烯醚中的一种或几种;5. The suspension seed coating agent according to any one of claims 1-4, characterized in that: the wetting and dispersing agent is fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether nonionic emulsifier, nonionic Type hydroxyl polyethylene oxide block polymer, polycarboxylate polymer dispersant, polyacrylic acid copolymer dispersant, alkylphenol polyoxyethylene ether, alkylphenylene ether sulfonate, hydrophilic mono Comb polymer, alkylaryl polyoxyethylene ether phosphate, lignosulfonate, sodium alkylnaphthalenesulfonate, methylnaphthalenesulfonate formaldehyde condensate sulfate, naphthalenesulfonate formaldehyde condensate, methylene Sodium naphthalene sulfonate dibutylnaphthalene sulfonate formaldehyde condensate, sodium N-methyl fatty acyl taurate, alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, polycarboxylate sodium, alkylphenol polyoxyethylene ether Sulfate ester, tea dry powder, saponin, sulfite pulp waste liquor, fatty alcohol sulfate, sodium dodecylsulfonate, fatty amide-N-methyl taurine sodium salt, fatty alcohol polyoxyethylene ether sodium sulfate , EO/PO block polymer, block polyether, alkyl phenyl ether sulfonate, polyether phosphate, naphthalene sulfonate condensation polymer, polycarboxylate, polystyrene phenyl ether phosphate and fatty alcohol poly One or more of oxyethylene ethers; 所述成膜剂为丙烯酸树脂改性酪蛋白成膜剂、壳聚糖、丙烯酸树脂聚氨酯共聚树脂、聚乙烯、丙烯酸酯改性丁二烯树脂、聚氨酯改性硝酸纤维、聚乙烯醇、聚乙二醇和聚醋酸乙烯中的一种或几种;The film forming agent is acrylic resin modified casein film forming agent, chitosan, acrylic resin polyurethane copolymer resin, polyethylene, acrylate modified butadiene resin, polyurethane modified nitrocellulose, polyvinyl alcohol, polyethylene One or more of diol and polyvinyl acetate; 所述增稠剂为瓜尔胶、硅酸铝镁水溶液、阿拉伯树胶、黄原胶、甲基纤维素、羟丙基甲基纤维素、羧甲基纤维素钠、羟乙基纤维素、钠基膨润土、有机膨润土和硅藻土中的一种或几种;The thickener is guar gum, aluminum magnesium silicate aqueous solution, gum arabic, xanthan gum, methyl cellulose, hydroxypropyl methyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl cellulose, sodium One or more of base bentonite, organic bentonite and diatomite; 所述防冻剂为乙醇、异丙醇、乙二醇、丙二醇、丙二醇丁醚、乙二醇丁醚醋酸酯、甲酰胺、氯化钙、醋酸钠和尿素中的一种或几种;The antifreezing agent is one or more of ethanol, isopropanol, ethylene glycol, propylene glycol, propylene glycol butyl ether, ethylene glycol butyl ether acetate, formamide, calcium chloride, sodium acetate and urea; 所述消泡剂为有机硅类消泡剂;Described defoamer is organosilicon type defoamer; 所述着色剂为水性玫红、酸性玫红、永固红和水固紫中的一种或几种。The coloring agent is one or more of water-based rose red, acid rose red, permanent red and water-fixed violet. 6.制备权利要求1-5任一项所述的悬浮种衣剂的方法,包括下述步骤:6. prepare the method for the suspension seed coating described in any one of claim 1-5, comprise the steps: (1)按照权利要求1-5任一项所述的悬浮种衣剂原料组成配比,将原药戊吡虫胍或戊吡虫胍和吡虫啉、晴菌唑、井冈霉素、吡蚜酮、溴氰菊酯、毒死蜱、噻嗪酮、敌敌畏、硫双威、苯醚甲环唑、噻虫胺、噻虫嗪、咯菌腈、吡唑醚菌酯、氟虫腈、拌种灵、咪鲜胺、萎锈灵、氟唑环菌胺、噁霉灵、氯氰菊酯、甲霜灵、硫双威、精甲霜灵、福美双、五氯硝基苯、克菌丹、甲拌磷、丁硫克百威中的一种或多种、润湿分散剂和水混合调浆;(1) According to the raw material composition proportioning of the suspension seed coating agent described in any one of claims 1-5, the former drug pentetamiclon or pentetamiclon and imidacloprid, bacconazole, Jinggangmycin, pymetrozine , deltamethrin, chlorpyrifos, buprofezin, dichlorvos, thiodicarb, difenoconazole, clothianidin, thiamethoxam, fludioxonil, pyraclostrobin, fipronil, seed dressing, Prochloraz, wilting, flurafen, hymexazol, cypermethrin, metalaxyl, thiodicarb, metalaxyl, thiram, pentachloronitrobenzene, captan, phorate, One or more of carbosulfan, wetting and dispersing agent and water are mixed for slurry preparation; (2)将所得浆料移入砂磨罐,通入冷却水进行砂磨直至物料的粒径在1-6μm达到98%以上后,过滤,浆料备用;(2) Move the obtained slurry into a sand milling tank, pass into cooling water and carry out sand grinding until the particle size of the material reaches more than 98% at 1-6 μm, filter, and the slurry is for subsequent use; (3)把增稠剂配置成质量浓度为1-2%的水溶液、成膜剂和消泡剂一起加入到过滤后的浆料中,加水补足至100%。(3) The thickener is configured as an aqueous solution with a mass concentration of 1-2%, and the film-forming agent and the defoamer are added to the filtered slurry together, and water is added to make up to 100%. 7.根据权利要求6所述的方法,其特征在于:所述悬浮种衣剂包括着色剂,所述着色剂在步骤(1)中加入。7. The method according to claim 6, characterized in that: the suspension seed coating agent includes a colorant, and the colorant is added in step (1). 8.权利要求1-5任一项所述含有戊吡虫胍的悬浮种衣剂在防治农作物病害和/或虫害中的应用。8. The application of the suspended seed coating agent containing pentaclofen according to any one of claims 1-5 in the prevention and treatment of crop diseases and/or pests. 9.根据权利要求8所述的应用,其特征在于:所述农作物包括下述至少一种:水稻、玉米、小麦、棉花、油菜、马铃薯、萝卜、甘蓝、高粱、花生和大豆。9. The application according to claim 8, characterized in that: the crops include at least one of the following: rice, corn, wheat, cotton, rapeseed, potato, radish, cabbage, sorghum, peanut and soybean. 10.根据权利要求8或9所述的应用,其特征在于:所述病害是指由子囊菌纲、担子菌纲、半知菌纲、白粉菌科、锈菌目的病原菌引起的病害;10. The application according to claim 8 or 9, characterized in that: said disease refers to a disease caused by pathogenic bacteria of Ascomycetes, Basidiomycetes, Deuteromycetes, Erysidiomycetes, and Rusts; 所述半知菌纲包括链格孢属、壳二孢属、尾孢霉属、刺盘孢属、球痤菌属、茎点霉属、柱隔孢属、壳针孢属、黑星菌属;Said Deuteromycetes include Alternaria, Ascodiospora, Cercospora, Neptonia, Ballacne, Phoma, Septoria, Septoria, and Black Star belongs to 所述害虫包括下述至少一种:蛴螬、叶甲、金针虫、地老虎、蚜虫、飞虱、粉虱、叶蝉、棉铃虫。The pests include at least one of the following: grubs, leaf beetles, needleworms, cutworms, aphids, planthoppers, whiteflies, leafhoppers, and cotton bollworms.
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CN114223489A (en) * 2021-12-21 2022-03-25 山西农业大学高寒区作物研究所(山西省农业科学院高寒区作物研究所) Northern dry land potato art-machine integrated cultivation method
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CN111345310A (en) * 2018-12-20 2020-06-30 合肥星宇化学有限责任公司 Insecticidal and bactericidal composition, preparation and application thereof
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