CN107372540A - A kind of compound seed treating agent containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate and its application - Google Patents
A kind of compound seed treating agent containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate and its application Download PDFInfo
- Publication number
- CN107372540A CN107372540A CN201710522300.XA CN201710522300A CN107372540A CN 107372540 A CN107372540 A CN 107372540A CN 201710522300 A CN201710522300 A CN 201710522300A CN 107372540 A CN107372540 A CN 107372540A
- Authority
- CN
- China
- Prior art keywords
- treating agent
- rice
- ethyl ethylthio
- trifluoro
- ethylthio sulfonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 53
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical compound CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 150000001875 compounds Chemical class 0.000 title claims abstract description 27
- JWXJRRHHNXLANU-UHFFFAOYSA-N pyrimidine 1,2,3-trifluorobenzene Chemical compound N1=CN=CC=C1.FC=1C(=C(C=CC1)F)F JWXJRRHHNXLANU-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 241000209094 Oryza Species 0.000 claims abstract description 62
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 62
- 235000009566 rice Nutrition 0.000 claims abstract description 62
- -1 active component Chemical compound 0.000 claims abstract description 38
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 15
- 229920001285 xanthan gum Polymers 0.000 claims description 15
- 241001272567 Hominoidea Species 0.000 claims description 12
- 238000011282 treatment Methods 0.000 claims description 12
- 229920002401 polyacrylamide Polymers 0.000 claims description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 235000010489 acacia gum Nutrition 0.000 claims description 6
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 229920000609 methyl cellulose Polymers 0.000 claims description 6
- 239000001923 methylcellulose Substances 0.000 claims description 6
- 235000010981 methylcellulose Nutrition 0.000 claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 235000010413 sodium alginate Nutrition 0.000 claims description 5
- 239000000661 sodium alginate Substances 0.000 claims description 5
- 229940005550 sodium alginate Drugs 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 4
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000004040 coloring Methods 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 229920000151 polyglycol Polymers 0.000 claims description 4
- 239000010695 polyglycol Substances 0.000 claims description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 3
- 229920005610 lignin Polymers 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001814 pectin Substances 0.000 claims description 3
- 235000010987 pectin Nutrition 0.000 claims description 3
- 229920001277 pectin Polymers 0.000 claims description 3
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000575 pesticide Substances 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 229920001400 block copolymer Polymers 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 239000003599 detergent Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 235000015424 sodium Nutrition 0.000 claims 1
- 241001498622 Cixius wagneri Species 0.000 abstract description 12
- 238000012545 processing Methods 0.000 abstract description 8
- 239000003905 agrochemical Substances 0.000 abstract description 5
- 241001161749 Stenchaetothrips biformis Species 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 230000000749 insecticidal effect Effects 0.000 abstract description 2
- 230000007246 mechanism Effects 0.000 abstract description 2
- 230000006978 adaptation Effects 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 14
- 229920001296 polysiloxane Polymers 0.000 description 12
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 11
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 10
- 239000012153 distilled water Substances 0.000 description 9
- AJKNNUJQFALRIK-UHFFFAOYSA-N 1,2,3-trifluorobenzene Chemical class FC1=CC=CC(F)=C1F AJKNNUJQFALRIK-UHFFFAOYSA-N 0.000 description 8
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 description 8
- 150000004996 alkyl benzenes Chemical class 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 8
- 239000000391 magnesium silicate Substances 0.000 description 8
- 150000003871 sulfonates Chemical class 0.000 description 8
- 239000000375 suspending agent Substances 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 241000176086 Sogatella furcifera Species 0.000 description 2
- 241000255901 Tortricidae Species 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- YJVBLROMQZEFPA-UHFFFAOYSA-L acid red 26 Chemical compound [Na+].[Na+].CC1=CC(C)=CC=C1N=NC1=C(O)C(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=CC=C12 YJVBLROMQZEFPA-UHFFFAOYSA-L 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- LHZOTJOOBRODLL-UHFFFAOYSA-N 4-oxo-1-(pyrimidin-5-ylmethyl)-3-[3-(trifluoromethyl)phenyl]pyrido[1,2-a]pyrimidin-5-ium-2-olate Chemical compound O=C1[N+]2=CC=CC=C2N(CC=2C=NC=NC=2)C([O-])=C1C1=CC=CC(C(F)(F)F)=C1 LHZOTJOOBRODLL-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 241001093501 Rutaceae Species 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical class C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CRLNSROCLKFIOK-UHFFFAOYSA-N benzene;pyrimidine Chemical compound C1=CC=CC=C1.C1=CN=CN=C1 CRLNSROCLKFIOK-UHFFFAOYSA-N 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/06—Coating or dressing seed
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Soil Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of compound seed treating agent containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate, including active component, the active component is S-Ethyl ethylthio sulfonate and trifluoro-benzene pyrimidine, and its weight proportion is 1:10~10:1；The invention also discloses the compound seed treating agent to prevent and treat the application of planthopper.Advantage is：Its perfect adaptation is got up using the agricultural chemicals of different insecticidal mechanisms, for rice paddy seed processing, is had obvious synergistic effect, lasting period length compared with single dose, the paddy growth prometaphase need not prevent and treat planthopper, rice thripses, can reduce cost accounting by the present invention；Rice growing season dosage can be reduced, reduce the residual of environmental pollution and agricultural product, and to paddy growth safety, be both manually operable, also mechanically operable；Rice seedling, growth can be promoted simultaneously, improve the resistance of rice.
Description
Technical field
The invention belongs to seed treatment field, more particularly to a kind of compound seed containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate
Inorganic agent and its application.
Background technology
Rice is one of main cereal crops in China, and its growth period disease pest species survey is more, especially insect, such as rice
The light time occurs for planthopper, thrips, leaf-roller, snout moth's larva etc., disease pest, and rice growing season needs medication spraying preventing and treating 5-6 times, sternly
The weight time needs medication 8-10 times, causes agricultural non -point pollution is serious, rice residual is exceeded etc., the added cost of Cotton Varieties by Small Farming Households.Such as
What reduces the dosage of agricultural chemicals, access times, is distinct issues in current Rice Production, pesticide reduction uses technology, except agricultural chemicals
Moistening spread technology, agricultural chemicals accuracy pesticide applying technology and super long effective medicament use outside, rice paddy seed treatment technology be it is easy easily
Row, the reachable effect got half the result with twice the effort.
Trifluoro-benzene pyrimidine (Triflumezopyrim, 3,4- dihydro -2,4- dioxos -1- (pyrimidine -5- ylmethyls) -3-
(α, α, α-trifluoromethyl-m-phenyl) -2H- pyridos [1,2- α] pyrimidine -1--3- salt) it is a kind of new mesoionic insecticides,
With efficient, holding effect, dosage is low, it is environmentally friendly the features such as, mainly prevent and treat water rice hopper, leafhopper etc..It is killed with anabasine
Worm agent has the different mechanism of action, and insect pollinator is had no adverse effect.
S-Ethyl ethylthio sulfonate (also known as antiseptic 402) is the derivative of allicin, be based on protection, have concurrently certain eradicant action,
The wide-spectrum bactericide of systemic action, it is poor to rice hoppers prevention effect.
The content of the invention
Goal of the invention：The first object of the present invention be to provide it is a kind of to rice hoppers prevention effect significantly, contain trifluoro
The compound seed treating agent of benzene pyrimidine and S-Ethyl ethylthio sulfonate；Second purpose is to provide the application of the inorganic agent.
Technical scheme：Compound seed treating agent of the invention containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate, including active component, should
Active component is S-Ethyl ethylthio sulfonate and trifluoro-benzene pyrimidine, and its weight proportion is 1:10~10:1.
Preferably, the weight proportion of S-Ethyl ethylthio sulfonate and trifluoro-benzene pyrimidine is 1:3~1:4.
Furtherly, the compound seed treating agent also includes auxiliary agent and carrier.Preferably, by weight percentage, it is active
Composition 10~60%, auxiliary agent 10~30%, surplus are carrier.
Further say, the auxiliary agent includes dispersant, film forming agent, thickener, antifreezing agent, colouring agent, synergist and disappeared
Infusion；The carrier is water.
Furtherly, the dispersant may include AEO, APES, polyoxyethylene
Aliphatic acid, phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fat
Fat acid polyethylene glycol, dodecyl benzene sulfonate, polyoxyethylene groups phenol formaldehyde condensate, polyoxyethylene poly-oxygen propylene aether block are total to
One or more in polymers, aliphatic alcohol polyoxyethylene sulfonate and lignin and its derivative sulfonate.Preferably, it is described
Dispersant include one or both of APES and alkylsulfonate.
The film forming agent may include Arabic gum, animal glue, pectin, xanthans, methylcellulose, ethyl cellulose, carboxylic
Sodium carboxymethylcellulose pyce, hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, polyethylene glycol, polyacrylamide or Sodium Polyacrylate
One or more, preferably can be polyacrylamide.
The thickener may include xanthans, aluminium-magnesium silicate, Arabic gum, methylcellulose, PAA, alginic acid
One or more in sodium, polyvinyl alcohol or Sodium Polyacrylate, preferably can be xanthans, aluminium-magnesium silicate one or two.
The defoamer includes silicone, C8-10Aliphatic acid and C10-20Saturated fatty acid and its one kind in esters or
It is several.Preferably, the defoamer includes silicone, and silicone is specifically as follows dimethyl silicone polymer.
The colouring agent at least may include one kind in basic rhodamine, water-based rhodo, acid scarlet, preferably can be alkalescence
Rhodamine toner.
The synergist includes brassin.The dosage of the brassin for rice seed treating agent gross weight 0.01~
0.1%.Addition brassin is then advantageous to rice germination, promotes paddy growth, takes root, improves paddy rice anti contravariance, it is preferred that it contains
Amount can be 0.05%.
The antifreezing agent at least may include ethylene glycol, propane diols, glycerine, hexylene glycol, urea, ammonium sulfate, sodium chloride or
One kind in calcium chloride, preferably can be ethylene glycol.
The carrier can be water, preferably distilled water.
Beneficial effect：Compared with prior art, remarkable advantage of the invention is：First, the seed treatment is not only to water
Rice planthopper, rice thripses have prominent control effect, and the lasting period is grown, the paddy growth prometaphase need not prevent and treat planthopper,
Rice thripses, cost accounting can be reduced；Secondly, rice growing season dosage can not only be reduced, reduce environmental pollution and agricultural product
Residual, and to paddy growth safety, be both manually operable, also mechanically operable；Rice seedling, growth can be promoted simultaneously,
Improve the resistance of rice.
Embodiment
Technical scheme is described in further details with reference to embodiment.
Embodiment 1：The configuration of 22% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 2g S-Ethyl ethylthio sulfonates, 20g trifluoro-benzenes pyrimidine, 4g APESs, 2g alkyl benzene calcium sulfonates, 5g polyacrylamides
Amine, 4g ethylene glycol, 0.4g silicone compounds, basic rhodamine 1g, 0.1g xanthans, 0.8g aluminium-magnesium silicates, 0.05g rapes
Element, distilled water are mended to 100g, and 22% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine seed treatment suspending agent is made.
Embodiment 2：The configuration of 22% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 20g S-Ethyl ethylthio sulfonates, 2g trifluoro-benzenes pyrimidine, 5g APESs, 2g alkyl benzene calcium sulfonates, 6g polyacrylamides
Amine, 4g ethylene glycol, 0.4g silicone compounds, basic rhodamine 1g, 0.1g xanthans, 0.8g aluminium-magnesium silicates, 0.05g rapes
Element, distilled water are mended to 100g, and 22% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine seed treatment suspending agent is made.
Embodiment 3：The configuration of 16% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 4g S-Ethyl ethylthio sulfonates, 12g trifluoro-benzenes pyrimidine, 5g APESs, 2g alkyl benzene calcium sulfonates, 6g polyacrylamides
Amine, 4g ethylene glycol, 0.4g silicone compounds, basic rhodamine 1g, 0.1g xanthans, 0.8g aluminium-magnesium silicates, 0.05g rapes
Element, distilled water are mended to 100g, and 16% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine seed treatment suspending agent is made.
Embodiment 4：The configuration of 15% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 3g S-Ethyl ethylthio sulfonates, 12g trifluoro-benzenes pyrimidine, 5g APESs, 2g alkyl benzene calcium sulfonates, 5g polyacrylamides
Amine, 4g ethylene glycol, 0.4g silicone compounds, basic rhodamine 1g, 0.1g xanthans, 0.8g aluminium-magnesium silicates, 0.05g rapes
Element, distilled water are mended to 100g, and 15% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine seed treatment suspending agent is made.
Embodiment 5:The configuration of 18% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 6g S-Ethyl ethylthio sulfonates, 12g trifluoro-benzenes pyrimidine, 6g APESs, 3g alkyl benzene calcium sulfonates, 7g polyacrylamides
Amine, 4g ethylene glycol, 0.4g silicone compounds, basic rhodamine 1g, 0.1g xanthans, 0.8g aluminium-magnesium silicates, 0.05g rapes
Element, distilled water are mended to 100g, and 27% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine seed treatment suspending agent is made.
Embodiment 6：The configuration of 25% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 20g S-Ethyl ethylthio sulfonates, 5g trifluoro-benzenes pyrimidine, 6g APESs, 3g alkyl benzene calcium sulfonates, 7g polyacrylamides
Amine, 4g ethylene glycol, 0.4g silicone compounds, basic rhodamine 1g, 0.1g xanthans, 0.8g aluminium-magnesium silicates, 0.05g rapes
Element, distilled water are mended to 100g, and 25% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent is made.
Preparation method：According to the formula of above-described embodiment, after active component, auxiliary component and carrier uniformly mixing,
Grind in sand mill 3~4 hours, pass through afterwards in below 5um after testing, you can be made at S-Ethyl ethylthio sulfonate and trifluoro-benzene pyrimidine rice paddy seed
Manage agent.
Test example：
Material to be tested：15% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent (embodiment 4), rice varieties are elegant water
123, rice white backed planthopper 2-3 age nymphs.
Test process：The 15% every 100 kilograms of seeds of S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent are set, 200 grams,
400 grams, 600 grams, every 2000 grams of the 100 kilograms of seeds of 10% imidacloprid wettable powder, the public affairs of 10% trifluoro-benzene pyrimidine suspending agent 100
600 grams of jin seed and blank control totally 6 processing.
Test method：Selected rice paddy seed, first with Seed soaking, by test process by the uniform medication of rice paddy seed after draining
Mix thoroughly, often processing sampling does germination test in incubator, often handles 100, is repeated 3 times.Seeding method：The basin alms bowl seedling machine transplanting of rice (5
Months 20 days sow, transplanting on June 21), Direct-seeding Rice (sowing on June 11), 20 days after basin alms bowl seedling planting, investigate the height of rice shoot
Degree, root quantity and fresh weight；Field experiment area often handles 0.25 mu, is repeated 3 times.Wherein by 20 days after basin alms bowl seedling, 30 days,
40 days, 50 days, brown paddy plant hopper is connect respectively, connects the residual work borer population for investigating each processing in 4 days after worm, and often processing is repeated 4 times, and calculates control
Effect.
Investigation method：Planthopper is sampled using parallel jump method basin alms bowl, often handles 10 basins, and per the cave rice of basin 2, investigation rice flies
The insect population of lice, with the natural insect population Growth Rate Calculation control effect of check plot.Result of the test：It is shown in Table 1-4.
Influence of the different agents Rice seeds treated of table 1 to Seedling Quality in Rice
Note：Data are four repetition averages in column (following table is same).
The control effect (interior) of the different agents Rice seeds treated Whitebacked Planthopper of table 2
Note：Data are to repeat average three times in column (following table is same)
Control effect (machine transplanting of rice field) of the different agents Rice seeds treated of table 3 to planthopper
Control effect (live field) of the different agents Rice seeds treated of table 4 to planthopper
Shown by table 1-4 laboratory test and field result, the processing of 15% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice paddy seed
Agent different amounts have preferable control effect to planthopper, every with 15% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
100 kilograms of 400~600 grams of seeds recommend dosage to be economical, and paddy growth is had no adverse effects, and can reduce the use of agricultural chemicals
Amount, reduce agricultural non -point pollution.
Applicant also carries out the experiment of small area to embodiment 1,2,3,5,6, and same each processing has to rice hoppers
Excellent control effect, it is possible to reduce the use of paddy growth prometaphase insecticide.
Control effect (machine transplanting of rice field) of the 5 different seed treatments of table to leaf-roller
To sum up, a kind of rice seed treating agent provided by the invention, it is according to the different insecticidal mechanisms of various medicaments, its is complete
U.S.A combines, and is further aided with suitable auxiliary agent and carrier, seeks most suitable with comparing rice paddy seed suitably to use
After amount processing and applied to the preventing and treating of planthopper, rice thripses, there is advantages below compared with traditional Control Insect Pests In Rice Field method：a)
Rice hoppers are had a significant effect, saved labor；B) significantly reduce rice spraying preventing and treating number, reduce environmental pollution and
The residual of agricultural product；C) the advantages of having the lasting period long, the paddy growth prometaphase need not prevent and treat planthopper, reduce cost；d)
Promote rice seedling, growth, improve the resistance of rice.
Embodiment 7：The configuration of 10% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 5g S-Ethyl ethylthio sulfonates, 5g trifluoro-benzenes pyrimidine, 7g APESs, 5g alkyl benzene calcium sulfonates, 8g polyacrylamides
Amine, 5g ethylene glycol, 0.8g silicone compounds, basic rhodamine 3g, 0.2g xanthans, 0.9g aluminium-magnesium silicates, 0.1g brassins,
Distilled water is mended to 100g, and 16% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine seed treatment suspending agent is made.
Embodiment 8：The configuration of 60% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine rice seed treating agent
By 30g S-Ethyl ethylthio sulfonates, 30g trifluoro-benzenes pyrimidine, 2g APESs, 2g alkyl benzene calcium sulfonates, 1.89g poly- third
Acrylamide, 2g ethylene glycol, 0.2g silicone compounds, basic rhodamine 1g, 0.1g xanthans, 0.8g aluminium-magnesium silicates, 0.01g rues
Tongue element, distilled water are mended to 100g, and 16% S-Ethyl ethylthio sulfonate trifluoro-benzene pyrimidine seed treatment suspending agent is made.
In the embodiment, dispersant is alternatively into AEO, APES, polyoxyethylene fat
Fat acid, phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fat
Acid polyethylene glycol, dodecyl benzene sulfonate, polyoxyethylene groups phenol formaldehyde condensate, polyoxyethylene poly-oxygen propylene aether block copolymerization
One or more in thing, aliphatic alcohol polyoxyethylene sulfonate and lignin and its derivative sulfonate.
Film forming agent is alternatively into Arabic gum, animal glue, pectin, xanthans, methylcellulose, ethyl cellulose, carboxylic first
Base sodium cellulosate, hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, polyethylene glycol, the one of polyacrylamide or Sodium Polyacrylate
Kind is several.
Thickener alternatively into xanthans, aluminium-magnesium silicate, Arabic gum, methylcellulose, PAA, sodium alginate,
One or more in polyvinyl alcohol or Sodium Polyacrylate.
The defoamer is alternatively into silicone, C8-10Aliphatic acid and C10-20Saturated fatty acid and its esters in one
Kind is several.
The colouring agent is alternatively into one kind in basic rhodamine, water-based rhodo, acid scarlet.
Claims (10)
1. a kind of compound seed treating agent containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate, including active component, it is characterised in that：The work
Property composition be S-Ethyl ethylthio sulfonate and trifluoro-benzene pyrimidine, its weight proportion is 1:10~10:1.
2. the compound seed treating agent according to claim 1 containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate, it is characterised in that：Institute
The weight proportion for stating S-Ethyl ethylthio sulfonate and trifluoro-benzene pyrimidine is 1:3~1:4.
3. the compound seed treating agent according to claim 1 containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate, it is characterised in that：Should
Compound seed treating agent also includes auxiliary agent and carrier.
4. the compound seed treating agent according to claim 3 containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate, it is characterised in that：With
Percentage by weight meter, active component 10~60%, auxiliary agent 10~30%, surplus are carrier.
5. the compound seed treating agent containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate according to claim 3 or 4, its feature exist
In：The auxiliary agent includes dispersant, film forming agent, thickener, antifreezing agent, colouring agent, synergist and defoamer；The carrier is
Water.
6. the compound seed treating agent according to claim 5 containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate, it is characterised in that：Institute
Stating dispersant includes AEO, APES, polyoxyethylene fatty acid, phenethyl phenol mela mine-formaldehyde resin
Polyoxyethyl ether, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol ethylene glycol, detergent alkylate
Sulfonate, polyoxyethylene groups phenol formaldehyde condensate, polyoxyethylene poly-oxygen propylene aether block copolymer, AEO sulphur
One or more in hydrochlorate and lignin and its derivative sulfonate.
7. a kind of compound seed treating agent containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate according to claim 5, its feature exist
In：The film forming agent includes Arabic gum, animal glue, pectin, xanthans, methylcellulose, ethyl cellulose, carboxymethyl cellulose
One kind in plain sodium, hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, polyethylene glycol, polyacrylamide and Sodium Polyacrylate or
It is several.
8. a kind of compound seed treating agent containing trifluoro-benzene pyrimidine and S-Ethyl ethylthio sulfonate according to claim 5, its feature exist
In：The thickener includes xanthans, aluminium-magnesium silicate, Arabic gum, methylcellulose, PAA, sodium alginate, polyethylene
One or more in alcohol or Sodium Polyacrylate.
9. application of the compound seed treating agent according to claim 1 in rice hoppers are prevented and treated.
10. application of the compound seed treating agent according to claim 9 in rice hoppers are prevented and treated, it is characterised in that：
The application is dressed seed using seed treatment rice paddy seed, and every 100 kilograms of rice paddy seed pesticide dosages are 400-600 grams.
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| CN111616155A (en) * | 2020-07-03 | 2020-09-04 | 浙江中山化工集团股份有限公司 | Pesticide composition containing trifluorobenzene pyrimidine and chamaejasmine |
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