CN107353558A - 一种导电高分子材料 - Google Patents
一种导电高分子材料 Download PDFInfo
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- 239000002131 composite material Substances 0.000 title claims abstract description 17
- 229920001940 conductive polymer Polymers 0.000 title claims abstract description 17
- 239000002322 conducting polymer Substances 0.000 title claims abstract description 16
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 18
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 9
- 125000005234 alkyl aluminium group Chemical group 0.000 claims abstract description 9
- -1 benzene alkene Chemical class 0.000 claims abstract description 9
- 239000006229 carbon black Substances 0.000 claims abstract description 9
- 239000004917 carbon fiber Substances 0.000 claims abstract description 9
- 239000003365 glass fiber Substances 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 9
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000002148 esters Chemical class 0.000 claims abstract description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 8
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 3
- 235000019241 carbon black Nutrition 0.000 abstract 2
- 150000003926 acrylamides Chemical class 0.000 abstract 1
- 150000001253 acrylic acids Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- 239000002861 polymer material Substances 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
- C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
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- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
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- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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- C08F220/10—Esters
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
- C08G2261/3221—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
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Abstract
本发明公开了一种导电高分子材料，包括20‑30份吡咯单体、20‑30份丙烯酰胺、15‑20份苯烯、2‑6份玻璃纤维、5‑10份碳纤维、1‑2份炭黑、1‑2份稀土、1‑2份烷基铝、20‑40份丙烯酸酯类。其优点在于：本发明通过吡咯单体、丙烯酰胺、苯烯和丙烯酸酯类组混合物中添加玻璃纤维、碳纤维、炭黑、稀土、烷基铝制得大导电高分子材料，提供了导电高分子材料热稳定性强，并且易于加工，适于工业大规模生产。
Description
技术领域
本发明属于高分子材料技术领域，具体涉及一种导电高分子材料。
背景技术
随着现代工业的飞速发展，高分子材料的运用越来越广泛，各大高校、研究所都设置了高分子材料研究中心。高分子材料也称为聚合物材料，是以高分子聚合物为基质，配有其他助剂所构成的材料，高分子材料按特性分为橡胶、纤维、塑料、高分子粘合剂、高分子涂料和高分子基复合材料等。高分子材料在电气电子工业、航天业、建筑业、医疗器械、医疗包装、交通运输业、家用电气、农业等各行业中都有着广泛的应用。
导电高分子材料是具有导电功能（包括半导电性、金属导电性和超导电性）、电导率在 10S/m 以上的聚合物材料。高分子导电材料具有密度小、易加工、耐腐蚀、可大面积成膜以及电导率可在十多个数量级的范围内进行调节等特点，不仅可作为多种金属材料和无机导电材料的代用品，而且已成为许多先进工业部门和尖端技术领域不可缺少的一类材料。聚苯胺作为高分子导电材料的一种，除了其电特性外，还具有能够由廉价的苯胺比较简便地合成、且在显示导电性的状态下显示出对氧等的优异的稳定性的优点和特性。但其加工性不好和稳定性不高造成的，严重阻碍了导电高分材料在工业上的应用。尤其在电器元件中的应用，需要导电材料具有良好的热稳定性，否则，即使其它性能再好，也无法应用。
发明内容
本发明的目的在于针对现有技术的不足，现提供一种热稳定性强、易于加工的导电高分子材料。
为解决上述技术问题，本发明采用的技术方案为：一种导电高分子材料，其创新点在于：以重量份计，包括如下组分：
吡咯单体 20-30份
丙烯酰胺 20-30份
苯烯 15-20份
玻璃纤维 2-6份
碳纤维 5-10份
炭黑 1-2份
稀土 1-2份
烷基铝 1-2份
丙烯酸酯类 20-40份
进一步的，所述丙烯酸酯类为丙烯酸甲酯、丙烯酸丁酯、甲基丙烯酸甲酯中的一种或两种的混合物。
本发明的有益效果如下：本发明通过吡咯单体、丙烯酰胺、苯烯和丙烯酸酯类组混合物中添加玻璃纤维、碳纤维 、炭黑、稀土、烷基铝制得大导电高分子材料，提供了导电高分子材料热稳定性强，并且易于加工，适于工业大规模生产。
具体实施方式
以下由特定的具体实施例说明本发明的实施方式，熟悉此技术的人士可由本说明书所揭露的内容轻易地了解本发明的其他优点及功效。
实施例1
一种导电高分子材料，以重量份计，包括如下组分：
吡咯单体 20份
丙烯酰胺 20份
苯烯 15份
玻璃纤维 2份
碳纤维 5份
炭黑 1份
稀土 1份
烷基铝 1份
丙烯酸甲酯 20份
实施例2
一种导电高分子材料，以重量份计，包括如下组分：
吡咯单体 30份
丙烯酰胺 30份
苯烯 20份
玻璃纤维 6份
碳纤维 10份
炭黑 2份
稀土 2份
烷基铝 2份
丙烯酸丁酯 40份
实施例3
一种导电高分子材料，以重量份计，包括如下组分：
吡咯单体 25份
丙烯酰胺 25份
苯烯 17份
玻璃纤维 4份
碳纤维 7份
炭黑 1.5份
稀土 1.5份
烷基铝 1.5份
甲基丙烯酸甲酯 30份
本发明通过吡咯单体、丙烯酰胺、苯烯和丙烯酸酯类组混合物中添加玻璃纤维、碳纤维、炭黑、稀土、烷基铝制得大导电高分子材料，提供了导电高分子材料热稳定性强，并且易于加工，适于工业大规模生产。
上述实施例只是本发明的较佳实施例，并不是对本发明技术方案的限制，只要是不经过创造性劳动即可在上述实施例的基础上实现的技术方案，均应视为落入本发明专利的权利保护范围内。
Claims (2)
1.一种导电高分子材料，其特征在于：以重量份计，包括如下组分：
吡咯单体 20-30份
丙烯酰胺 20-30份
苯烯 15-20份
玻璃纤维 2-6份
碳纤维 5-10份
炭黑 1-2份
稀土 1-2份
烷基铝 1-2份
丙烯酸酯类 20-40份。
2.根据权利要求1所述的一种导电高分子材料，其特征在于：所述丙烯酸酯类为丙烯酸甲酯、丙烯酸丁酯、甲基丙烯酸甲酯中的一种或两种的混合物。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101023138A (zh) * | 2004-09-22 | 2007-08-22 | 信越聚合物株式会社 | 导电性组合物及其制造方法、抗静电涂料、抗静电膜、抗静电涂膜、滤光器、光信息记录媒体、电容器及其制造方法 |
| CN101418107A (zh) * | 2007-10-22 | 2009-04-29 | 东丽纤维研究所（中国）有限公司 | 纳米石墨高电导率复合材料及其制备方法 |
| CN103224694A (zh) * | 2013-04-18 | 2013-07-31 | 苏州旭光聚合物有限公司 | 一种导电pbt复合材料 |
| CN106589939A (zh) * | 2015-10-15 | 2017-04-26 | 徐文智 | 一种导电高分子材料 |
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- 2017-05-27 CN CN201710387631.7A patent/CN107353558A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101023138A (zh) * | 2004-09-22 | 2007-08-22 | 信越聚合物株式会社 | 导电性组合物及其制造方法、抗静电涂料、抗静电膜、抗静电涂膜、滤光器、光信息记录媒体、电容器及其制造方法 |
| CN101418107A (zh) * | 2007-10-22 | 2009-04-29 | 东丽纤维研究所（中国）有限公司 | 纳米石墨高电导率复合材料及其制备方法 |
| CN103224694A (zh) * | 2013-04-18 | 2013-07-31 | 苏州旭光聚合物有限公司 | 一种导电pbt复合材料 |
| CN106589939A (zh) * | 2015-10-15 | 2017-04-26 | 徐文智 | 一种导电高分子材料 |
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