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CN107338649A - A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property - Google Patents

A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property Download PDF

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Publication number
CN107338649A
CN107338649A CN201710613985.9A CN201710613985A CN107338649A CN 107338649 A CN107338649 A CN 107338649A CN 201710613985 A CN201710613985 A CN 201710613985A CN 107338649 A CN107338649 A CN 107338649A
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Prior art keywords
parts
fiber
ramie
viscose rayon
solution
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CN201710613985.9A
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Chinese (zh)
Inventor
潘学东
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Anhui Yayuan Printing And Dyeing Co Ltd
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Anhui Yayuan Printing And Dyeing Co Ltd
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Priority to CN201710613985.9A priority Critical patent/CN107338649A/en
Publication of CN107338649A publication Critical patent/CN107338649A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/267—Glass
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D06M13/21—Halogenated carboxylic acids; Anhydrides, halides or salts thereof
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
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    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
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    • D06M2101/10—Animal fibres
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/40—Fibres of carbon
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00—Inorganic fibres
    • D10B2101/02—Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
    • D10B2101/06—Glass
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    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
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    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
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    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
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    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

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  • Engineering & Computer Science (AREA)
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  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property, its raw material includes polyester fiber, acetate fiber, plumage velvet, aloe fibre, cotton fiber, zein fiber, bamboo-carbon fibre, glass fibre, polyester fiber, chitin fiber, gummy fiber, modified waterproof agent, waterproof reinforcing agent, propane diols and pentanediol.The ramie viscose rayon cotton interwoven fabric of the present invention not only has excellent mechanical property, also with outstanding water resistance.

Description

A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property
Technical field
The present invention relates to the technical field of fabric, more particularly to a kind of ramie viscose rayon cotton with excellent water proofing property to hand over Knitted fabric.
Background technology
Ramie main component is cellulose fibre.Grade in natural remie fiber containing pectin, lignin, wax and ash miscellaneous Matter, therefore fracture strength is higher, wet strength is high, and breaking ductility is low, therefore, the fabric pretreatment difficulty using ramie as component Greatly, it is desirable to which high, viscose rayon is using native cellulose as raw material, is process by certain chemical method, and common viscose glue is fine The dimension wet strength of molecule is poor, and fracture strength is low and breaking ductility is high, and its cortex construction has considerable influence to dyeing, and acid and alkali-resistance is low. Although ramie viscose rayon cotton interwoven fabric of the prior art can not expire with certain mechanical property, its water resistance Demand during foot actual use, so needing a kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property of design badly.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of ramie viscose glue with excellent water proofing property Synthetic cotton interwoven fabric, not only with excellent mechanical property, also with outstanding water resistance.
A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property proposed by the present invention, its raw material is by weight Including：Polyester fiber 30-50 parts, acetate fiber 5-15 parts, plumage velvet 4-9 parts, aloe fibre 2-6 parts, cotton fiber 1-5 parts, jade Rice fiber 3-8 parts, bamboo-carbon fibre 2-6 parts, glass fibre 1-4 parts, polyester fiber 3-5 parts, chitin fiber 2-6 parts, natural gum are fine Tie up 1-4 parts, modified waterproof agent 3-9 parts, waterproof reinforcing agent 2-6 parts, propane diols 5-15 parts, pentanediol 4-9 parts.
Preferably, modified waterproof agent is prepared by following technique：Kynoar and ramee are well mixed, Heating, insulation, it is then immersed in neopelex solution and is well mixed, stands, then in chitosan solution is placed in Immersion, is then placed in pyromellitic trimethylsilyl chloride solution and soaks, and is dried after washing, is cooled to room temperature and obtains being modified waterproof agent.
Preferably, modified waterproof agent is prepared by following technique：Kynoar and ramee are well mixed, 150-170 DEG C is warming up to, is incubated 20-40min, is then immersed in neopelex solution and is well mixed, stands 110- 130min, then soaks 5-15min in chitosan solution is placed in, and is then placed in pyromellitic trimethylsilyl chloride solution and soaks 15- 35min, wash after 80-90 DEG C of dry 5-15min, be cooled to room temperature and obtain being modified waterproof agent.
Preferably, in the preparation technology of modified waterproof agent, Kynoar, ramee, neopelex The weight ratio of solution, chitosan solution and pyromellitic trimethylsilyl chloride solution is 2-5：1-3：3-5：2-6：2-3.
Preferably, in the preparation technology of modified waterproof agent, the mass fraction of neopelex solution is 0.1- 0.3%.
Preferably, in the preparation technology of modified waterproof agent, the mass fraction of chitosan solution is 3-5%.
Preferably, in the preparation technology of modified waterproof agent, the mass fraction of pyromellitic trimethylsilyl chloride solution is 12-14%.
Preferably, waterproof reinforcing agent is prepared by following technique：It is by weight that 5-15 part polyvinylpyrrolidones is molten Liquid and 20-30 part n-amyl alcohols are well mixed, ultrasonic 40-50min, then add the lemon that 3-9 parts mass fraction is 5.5-8.5% Acid sodium solution is well mixed, and is subsequently added into 1-5 parts ammoniacal liquor and 3-6 part tetraethyl orthosilicates are well mixed, in 650-850r/min Rotating speed stirs 2-5min, is warming up to 75-85 DEG C, is incubated 16-20h, is washed with deionized 1-3 times and centrifuges, and centrifugation turns Speed is 3800-4200r/min, and 2-4h is then dried in 45-55 DEG C of baking oven, room temperature is cooled to and obtains waterproof reinforcing agent.
A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property of the present invention, it is fine that its raw material includes terylene Dimension, acetate fiber, plumage velvet, aloe fibre, cotton fiber, zein fiber, bamboo-carbon fibre, glass fibre, polyester fiber, chitin Fiber, gummy fiber, modified waterproof agent, waterproof reinforcing agent, propane diols and pentanediol.The ramie viscose rayon cotton of the present invention is handed over Knitted fabric not only has excellent mechanical property, also with outstanding water resistance.Wherein, modified waterproof agent is inclined by that will gather PVF and ramee are well mixed, and are heated up, and insulation, are then immersed in neopelex solution and are well mixed, quiet Put, then soaked in chitosan solution is placed in, be then placed in pyromellitic trimethylsilyl chloride solution and soak, dried after washing, cooling Obtain being modified waterproof agent to room temperature, Kynoar is modified by ramee, it is molten with neopelex As modified additive, obtained modification waterproof agent has excellent waterproof for liquid, chitosan solution and pyromellitic trimethylsilyl chloride solution Permeability, apply in the ramie viscose rayon cotton interwoven fabric of the present invention and effectively increase its waterproof and breathable performance.Wherein, Waterproof reinforcing agent ultrasound, then adds sodium citrate solution by the way that polyvinylpyrrolidonesolution solution and n-amyl alcohol are well mixed It is well mixed, be subsequently added into ammoniacal liquor and tetraethyl orthosilicate be well mixed, stir, heat up, insulation, be washed with deionized and from The heart separates, and is then dried in baking oven, is cooled to room temperature and obtains waterproof reinforcing agent, using tetraethyl orthosilicate as catalyst, to poly- second Alkene pyrrolidone solution is modified, obtained waterproof reinforcing agent, is coordinated with modified waterproof agent, is applied to having for the present invention In the ramie viscose rayon cotton interwoven fabric of excellent water proofing property, its waterproof and breathable, resistant antibacterial and antiultraviolet are effectively increased Performance.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair In bright protection domain.
In embodiment, the parts by weight of polyester fiber can be 30 parts, 35 parts, 40 parts, 45 parts, 50 parts；Acetic acid is fine The parts by weight of dimension can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight of plumage velvet It can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts to measure part；The weight of aloe fibre It can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts to measure part；The parts by weight of cotton fiber can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Corn is fine The parts by weight of dimension can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；Bamboo charcoal is fine The parts by weight of dimension can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of glass fibre can be 1 part, 1.5 parts, 2 parts, 2.5 Part, 3 parts, 3.5 parts, 4 parts；The parts by weight of polyester fiber can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight of chitin fiber It can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts to measure part；The parts by weight of gummy fiber can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of modified waterproof agent can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；Waterproof reinforcing agent Parts by weight can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of propane diols can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The parts by weight of pentanediol can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 Part, 7.5 parts, 8 parts, 8.5 parts, 9 parts.
Embodiment 1
A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property proposed by the present invention, its raw material is by weight Including：40 parts of polyester fiber, 10 parts of acetate fiber, 6.5 parts of plumage velvet, 4 parts of aloe fibre, 3 parts of cotton fiber, zein fiber 5.5 Part, 4 parts of bamboo-carbon fibre, 2.5 parts of glass fibre, 4 parts of polyester fiber, 4 parts of chitin fiber, 2.5 parts of gummy fiber, modified waterproof 6 parts of auxiliary agent, 4 parts of waterproof reinforcing agent, 10 parts of propane diols, 6.5 parts of pentanediol.
Modified waterproof agent is prepared by following technique：By weight by 3.5 parts of Kynoar and 2 parts of ramees It is well mixed, 160 DEG C are warming up to, is incubated 30min, it is molten to be then immersed in the neopelex that 4 parts of mass fractions are 0.2% It is well mixed in liquid, stands 120min, is then soaked 10min in the chitosan solution that 4 parts of mass fractions are 4% is placed in, connect To be placed in the pyromellitic trimethylsilyl chloride solution that 2.5 parts of mass fractions are 13% and soak 25min, wash after 85 DEG C of dry 10min, Room temperature is cooled to obtain being modified waterproof agent.
Waterproof reinforcing agent is prepared by following technique：By weight by 10 parts of polyvinylpyrrolidonesolution solutions and 25 parts just Amylalcohol is well mixed, ultrasonic 45min, is then added the sodium citrate solution that 6 parts of mass fractions are 7% and is well mixed, then adds Enter 3 parts of ammoniacal liquor and 4.5 parts of tetraethyl orthosilicates are well mixed, 3.5min is stirred in 750r/min rotating speeds, be warming up to 80 DEG C, insulation 18h, it is washed with deionized 2 times and centrifuges, centrifugal rotational speed 4000r/min, 3h is then dried in 50 DEG C of baking ovens, it is cold But waterproof reinforcing agent is obtained to room temperature.
Embodiment 2
A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property proposed by the present invention, its raw material is by weight Including：30 parts of polyester fiber, 15 parts of acetate fiber, 4 parts of plumage velvet, 6 parts of aloe fibre, 1 part of cotton fiber, 8 parts of zein fiber, bamboo 2 parts of Carbon fibe, 4 parts of glass fibre, 3 parts of polyester fiber, 6 parts of chitin fiber, 1 part of gummy fiber, modified 9 parts of waterproof agent, 2 parts of waterproof reinforcing agent, 15 parts of propane diols, 4 parts of pentanediol.
Modified waterproof agent is prepared by following technique：2 parts of Kynoar and 3 parts of ramees are mixed by weight Close uniformly, be warming up to 150 DEG C, be incubated 40min, be then immersed in the neopelex solution that 3 parts of mass fractions are 0.3% In be well mixed, stand 110min, then be placed in 6 parts of mass fractions be 3% chitosan solution in soak 15min, then It is placed in the pyromellitic trimethylsilyl chloride solution that 2 parts of mass fractions are 14% and soaks 15min, washes after 90 DEG C of dry 5min, cooling Obtain being modified waterproof agent to room temperature.
Waterproof reinforcing agent is prepared by following technique：By weight by 5 parts of polyvinylpyrrolidonesolution solutions and 30 parts just Amylalcohol is well mixed, ultrasonic 40min, is then added the sodium citrate solution that 9 parts of mass fractions are 5.5% and is well mixed, then Add 5 parts of ammoniacal liquor and 3 parts of tetraethyl orthosilicates are well mixed, 2min is stirred in 850r/min rotating speeds, be warming up to 85 DEG C, insulation 16h, it is washed with deionized 3 times and centrifuges, centrifugal rotational speed 3800r/min, 2h is then dried in 55 DEG C of baking ovens, it is cold But waterproof reinforcing agent is obtained to room temperature.
Embodiment 3
A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property proposed by the present invention, its raw material is by weight Including：50 parts of polyester fiber, 5 parts of acetate fiber, 9 parts of plumage velvet, 2 parts of aloe fibre, 5 parts of cotton fiber, 3 parts of zein fiber, bamboo 6 parts of Carbon fibe, 1 part of glass fibre, 5 parts of polyester fiber, 2 parts of chitin fiber, 4 parts of gummy fiber, modified 3 parts of waterproof agent, 6 parts of waterproof reinforcing agent, 5 parts of propane diols, 9 parts of pentanediol.
Modified waterproof agent is prepared by following technique：5 parts of Kynoar and 1 part of ramee are mixed by weight Close uniformly, be warming up to 170 DEG C, be incubated 20min, be then immersed in the neopelex solution that 5 parts of mass fractions are 0.1% In be well mixed, stand 130min, then be placed in 2 parts of mass fractions be 5% chitosan solution in soak 5min, then put 35min is soaked in the pyromellitic trimethylsilyl chloride solution that 3 parts of mass fractions are 12%, washes after 80 DEG C of dry 15min, is cooled to Room temperature obtains being modified waterproof agent.
Waterproof reinforcing agent is prepared by following technique：By weight by 15 parts of polyvinylpyrrolidonesolution solutions and 20 parts just Amylalcohol is well mixed, ultrasonic 50min, is then added the sodium citrate solution that 3 parts of mass fractions are 8.5% and is well mixed, then Add 1 part of ammoniacal liquor and 6 parts of tetraethyl orthosilicates are well mixed, 5min is stirred in 650r/min rotating speeds, be warming up to 75 DEG C, insulation 20h, it is washed with deionized 1 time and centrifuges, centrifugal rotational speed 4200r/min, 4h is then dried in 45 DEG C of baking ovens, it is cold But waterproof reinforcing agent is obtained to room temperature.
Embodiment 4
A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property proposed by the present invention, its raw material is by weight Including：35 parts of polyester fiber, 12 parts of acetate fiber, 5 parts of plumage velvet, 5 parts of aloe fibre, 2 parts of cotton fiber, 7 parts of zein fiber, bamboo 3 parts of Carbon fibe, 5 parts of glass fibre, 3.5 parts of polyester fiber, 5 parts of chitin fiber, 2 parts of gummy fiber, modified waterproof agent 8 Part, 3 parts of waterproof reinforcing agent, 12 parts of propane diols, 5 parts of pentanediol.
Modified waterproof agent is prepared by following technique：By weight by 3 parts of Kynoar and 2.5 parts of ramees It is well mixed, 155 DEG C are warming up to, is incubated 35min, is then immersed in the DBSA that 3.5 parts of mass fractions are 0.25% It is well mixed in sodium solution, stands 115min, is then soaked in the chitosan solution that 5 parts of mass fractions are 3.5% is placed in 12min, then it is placed in the pyromellitic trimethylsilyl chloride solution that 2.2 parts of mass fractions are 13.5% and soaks 18min, wash after 88 DEG C 8min is dried, room temperature is cooled to and obtains being modified waterproof agent.
Waterproof reinforcing agent is prepared by following technique：By weight by 8 parts of polyvinylpyrrolidonesolution solutions and 28 parts just Amylalcohol is well mixed, ultrasonic 42min, is then added the sodium citrate solution that 8 parts of mass fractions are 5.8% and is well mixed, then Add 4 parts of ammoniacal liquor and 4 parts of tetraethyl orthosilicates are well mixed, 3min is stirred in 820r/min rotating speeds, be warming up to 82 DEG C, insulation 17h, it is washed with deionized 3 times and centrifuges, centrifugal rotational speed 3900r/min, 2.5h is then dried in 52 DEG C of baking ovens, It is cooled to room temperature and obtains waterproof reinforcing agent.
Embodiment 5
A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property proposed by the present invention, its raw material is by weight Including：45 parts of polyester fiber, 8 parts of acetate fiber, 8 parts of plumage velvet, 3 parts of aloe fibre, 4 parts of cotton fiber, 4 parts of zein fiber, bamboo 5 parts of Carbon fibe, 2 parts of glass fibre, 4.5 parts of polyester fiber, 3 parts of chitin fiber, 3 parts of gummy fiber, modified waterproof agent 4 Part, 5 parts of waterproof reinforcing agent, 8 parts of propane diols, 8 parts of pentanediol.
Modified waterproof agent is prepared by following technique：By weight by 4 parts of Kynoar and 1.5 parts of ramees It is well mixed, 165 DEG C are warming up to, is incubated 25min, is then immersed in the DBSA that 4.5 parts of mass fractions are 0.15% It is well mixed in sodium solution, stands 125min, is then soaked in the chitosan solution that 3 parts of mass fractions are 4.5% is placed in 8min, then it is placed in the pyromellitic trimethylsilyl chloride solution that 2.8 parts of mass fractions are 12.5% and soaks 32min, wash after 82 DEG C 12min is dried, room temperature is cooled to and obtains being modified waterproof agent.
Waterproof reinforcing agent is prepared by following technique：By weight by 12 parts of polyvinylpyrrolidonesolution solutions and 22 parts just Amylalcohol is well mixed, ultrasonic 48min, is then added the sodium citrate solution that 4 parts of mass fractions are 8.2% and is well mixed, then Add 2 parts of ammoniacal liquor and 5 parts of tetraethyl orthosilicates are well mixed, 4min is stirred in 680r/min rotating speeds, be warming up to 78 DEG C, insulation 19h, it is washed with deionized 1 time and centrifuges, centrifugal rotational speed 4100r/min, 3.5h is then dried in 48 DEG C of baking ovens, It is cooled to room temperature and obtains waterproof reinforcing agent.
The raw material of the ramie viscose rayon cotton interwoven fabric with excellent water proofing property in embodiment 1- embodiments 5 is carried out Blending is compiled into fabric, and fabric progressive can be detected, and obtained data are as shown in table 1.
Table 1：
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (8)

1. a kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property, it is characterised in that its raw material wraps by weight Include：Polyester fiber 30-50 parts, acetate fiber 5-15 parts, plumage velvet 4-9 parts, aloe fibre 2-6 parts, cotton fiber 1-5 parts, corn Fiber 3-8 parts, bamboo-carbon fibre 2-6 parts, glass fibre 1-4 parts, polyester fiber 3-5 parts, chitin fiber 2-6 parts, gummy fiber 1-4 parts, modified waterproof agent 3-9 parts, waterproof reinforcing agent 2-6 parts, propane diols 5-15 parts, pentanediol 4-9 parts.
2. the ramie viscose rayon cotton interwoven fabric according to claim 1 with excellent water proofing property, it is characterised in that change Property waterproof agent is prepared by following technique：Kynoar and ramee are well mixed, heated up, insulation, is then soaked Enter in neopelex solution and be well mixed, stand, then soaked in chitosan solution is placed in, be then placed in equal benzene Soaked in front three solution of acid chloride, dried after washing, be cooled to room temperature and obtain being modified waterproof agent.
3. the ramie viscose rayon cotton interwoven fabric according to claim 1 or 2 with excellent water proofing property, its feature exist In modified waterproof agent is prepared by following technique：Kynoar and ramee are well mixed, are warming up to 150- 170 DEG C, 20-40min is incubated, is then immersed in neopelex solution and is well mixed, stands 110-130min, then 5-15min is soaked in chitosan solution is placed in, is then placed in pyromellitic trimethylsilyl chloride solution and soaks 15-35min, wash after 80-90 DEG C of dry 5-15min, is cooled to room temperature and obtains being modified waterproof agent.
4. the ramie viscose rayon cotton interwoven fabric with excellent water proofing property according to claim any one of 1-3, it is special Sign is that in the preparation technology of modified waterproof agent, Kynoar, ramee, neopelex solution, shell gather The weight of sugar juice and pyromellitic trimethylsilyl chloride solution ratio is 2-5：1-3：3-5：2-6：2-3.
5. the ramie viscose rayon cotton interwoven fabric with excellent water proofing property according to claim any one of 1-4, it is special Sign is that in the preparation technology of modified waterproof agent, the mass fraction of neopelex solution is 0.1-0.3%.
6. the ramie viscose rayon cotton interwoven fabric with excellent water proofing property according to claim any one of 1-5, it is special Sign is that in the preparation technology of modified waterproof agent, the mass fraction of chitosan solution is 3-5%.
7. the ramie viscose rayon cotton interwoven fabric with excellent water proofing property according to claim any one of 1-6, it is special Sign is that in the preparation technology of modified waterproof agent, the mass fraction of pyromellitic trimethylsilyl chloride solution is 12-14%.
8. the ramie viscose rayon cotton interwoven fabric with excellent water proofing property according to claim any one of 1-7, it is special Sign is that waterproof reinforcing agent is prepared by following technique：By weight by 5-15 parts polyvinylpyrrolidonesolution solution and 20-30 Part n-amyl alcohol is well mixed, ultrasonic 40-50min, then adds the sodium citrate solution that 3-9 parts mass fraction is 5.5-8.5% It is well mixed, it is subsequently added into 1-5 parts ammoniacal liquor and 3-6 part tetraethyl orthosilicates is well mixed, is stirred in 650-850r/min rotating speeds 2-5min, 75-85 DEG C is warming up to, is incubated 16-20h, is washed with deionized 1-3 times and centrifuges, centrifugal rotational speed 3800- 4200r/min, 2-4h is then dried in 45-55 DEG C of baking oven, room temperature is cooled to and obtains waterproof reinforcing agent.
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