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CN107326531A - Multi-functional polypropylene fibre and glass fibre needle-punched composite and preparation method thereof - Google Patents

Multi-functional polypropylene fibre and glass fibre needle-punched composite and preparation method thereof Download PDF

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Publication number
CN107326531A
CN107326531A CN201710749765.9A CN201710749765A CN107326531A CN 107326531 A CN107326531 A CN 107326531A CN 201710749765 A CN201710749765 A CN 201710749765A CN 107326531 A CN107326531 A CN 107326531A
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CN
China
Prior art keywords
glass fibre
needle
fibre
fiber
polypropylene fibre
Prior art date
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Pending
Application number
CN201710749765.9A
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Chinese (zh)
Inventor
冷纯廷
邢天宝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jilin Huafang Electrostatic Mstar Technology Ltd
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Jilin Huafang Electrostatic Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jilin Huafang Electrostatic Mstar Technology Ltd filed Critical Jilin Huafang Electrostatic Mstar Technology Ltd
Priority to CN201710749765.9A priority Critical patent/CN107326531A/en
Publication of CN107326531A publication Critical patent/CN107326531A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209Inorganic fibres
    • D04H1/4218Glass fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/4291Olefin series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

Multi-functional polypropylene fibre and glass fibre needle-punched composite and preparation method thereof, belong to infant industry materials processing technology field, preparation method comprises the following steps:Fiber opens bag mixing;Comb;Lapping;Pre-needling;Main acupuncture;Trimming, winding and packaging;The present invention uses multi-functional polypropylene fibre with glass fibre for fiber raw material by weight percentage, utilize needle-punched non-woven production technology, multi-functional polypropylene fibre and glass fibre needle-punched composite is made, it strengthens automobile interior trim material with traditional polypropylene fibre compared with glass fibre needle-punched composite as the light bluk recombination of functional form, sound-absorption coefficient can improve 60%~70%, elongation can improve 120%, the auto parts and components of more complicated shape can be processed into, and are not in bottom splitting phenomena;Multi-functional polypropylene fibre can mitigate 10%~20% with glass fibre needle-punched composite compared with stack pile product, realize further light body.

Description

Multi-functional polypropylene fibre and glass fibre needle-punched composite and preparation method thereof
Technical field
The invention belongs to infant industry materials processing technology field, more particularly to multi-functional polypropylene fibre and glass fibre Needle-punched composite and preparation method thereof.
Background technology
Nowadays China turns into the automobile production and marketing state of maximum in the world, and automobile volume of production and marketing has broken through 25,000,000 within 2016. Garage had turned into the pillar industry that Chinese national economy develops already, moreover, development prospect is in the ascendant, especially light bluk recombination Strengthen automobile interior trim material, increasingly show good growth momentum.Automobile interior trim material turns into automobile cost performance Key factor, directly affect the market competitiveness and vitality of automobile.Automobile interior trim material is just progressively towards multi-functional Type, intellectuality, high-tech direction are developed, and this requires the raw material for producing automobile interior trim material to have high-tech content, To have multi-functional, intelligent.Polypropene staple occupies predominantly in thermoplasticity and thermoset automotive inner decoration material Position, especially polypropylene fibre and glass fibre light-weight composite reinforcing material, in automobile interior trim material, consumption is increasingly Greatly.Polypropylene biggest advantage is that proportion is small, is most light among synthetic fibers, rigidity and elasticity are good, and fusing point is low, very It is adapted to the light bluk recombination enhancing automobile interior trim material of processing.Glass fibre has high good anti-flammability, intensity, rigidity and elasticity It is good, it is cheap, it is the preferable raw material of automobile interior trim material.It is small using polypropylene fibre proportion, make up glass fibre ratio Weight is larger, and using polyacrylic low melting point performance, glass fiber mesh is bonded together under cryogenic, forms thermoplasticity vapour In-car package material, requires that reheating is molded into the various auto parts and components of heat curing-type according to different shape.Polypropylene fibre and glass Fibre prickling composite, played an important role in the automotive industry.For example, roof of the vehicle, automobile door plate liner, automobile Preceding turnover panel, end blocking, hat rack, wheel back of the body cover, carpet backing, back seat interior lining panel etc..Polypropylene is to substitute phenolic resin to add The most ideal material of work glass mat composite reinforcing material, so polypropene staple is widely used in novel light bluk recombination Strengthen in automobile interior trim material.Polypropene staple, using the change of processing parameter, can make it according to different purposes With higher-strength and larger elongation.For example, production glass mat needs polypropene staple elongation larger, from And, the low deficiency of glass fibre elongation is made up, is not in that splitting is existing when glass mat is molded into complicated shape so As still, by polyacrylic internal structure is determined, improving elongation has certain limitation.
The content of the invention
The purpose of the present invention is to use multi-functional polypropylene fibre, for raw material, to utilize needle-punched non-woven with glass fibre Production technology, is processed into multi-functional polypropylene fibre and glass fibre needle-punched composite.
Multi-functional polypropylene fibre and glass fibre needle-punched composite preparation method, it is characterised in that:Including following step Suddenly, and following steps are sequentially carried out,
Step 1: fiber opens bag mixing
By weight percentage, 15%~35% multi-functional polypropylene fibre is taken to be with 65%~85% glass fibre Fiber raw material, fiber raw material carries out thick shredding by opener pinion roller, and the fiber after thick shredding is rolled by serration Cylinder carries out smart shredding, obtains loose fiber;Loose fiber is entered in big storehouse cotton blender machine by conveyance conduit, is carried out fiber and is mixed Close;
Step 2: combing
The quantitative cotton feeder of air pressure will be transported to through air-flow through the big well-mixed fiber of storehouse cotton blender machine in the step one, mixed Condensating fiber is transported to carding machine by pressure, combs to formation single layer fibre net, and sent web by doffer and pattern doffing roller Enter the wild crops being made up of three pairs of rollers, web vertical transverse strength is reached unanimity;
Step 3: lapping
Web in step 2 is fed into lapping machine by exporting curtain, web is paved into by lapping machine according to technological requirement Thickness is 8mm~25mm;
Step 4: pre-needling
The web obtained in the step 3 is fed into needing machine by exporting curtain, needling treatment is carried out, is had It is that 5mm~20mm, intensity are multi-functional polypropylene fibre and glass fibre needle-punched composite more than 50N to have thickness;
Step 5: main acupuncture
Repeated Acupuncture process step, 2~3 times, it is 5mm~20mm, intensity to be multi-functional more than 70N to obtain with thickness Polypropylene fibre and glass fibre needle-punched composite;
Step 6: trimming, winding and packaging
The multi-functional polypropylene fibre of finished product that the step 5 is obtained utilizes cutting with glass fibre needle-punched composite Machine carries out horizontal cutting, in will be after laterally cutting many crimp function polypropylene fibre and glass fibre needle-punched composite In rolls, using mould chartered plane carry out plastic packaging.
A kind of many work(prepared by described multi-functional polypropylene fibre and glass fibre needle-punched composite preparation method Can polypropylene fibre and glass fibre needle-punched composite.
By above-mentioned design, the present invention can bring following beneficial effect:The present invention proposes a kind of multi-functional poly- Tacryl and glass fibre needle-punched composite and preparation method thereof, by weight percentage, the present invention using 15%~ 35% multi-functional polypropylene fibre and 65%~85% glass fibre are fiber raw material, are given birth to using needle-punched non-woven Production. art, is made multi-functional polypropylene fibre and glass fibre needle-punched composite, and it strengthens vapour as the light bluk recombination of functional form Upholstery material compared with glass fibre needle-punched composite, only with regard to absorbing sound and lowering noise function, is inhaled with traditional polypropylene fibre Phonetic system number can improve 60%~70%;Elongation can improve 120%, can be processed into zero, the automobile of more complicated shape Part, and be not in bottom splitting phenomena;The deficiency of polypropylene itself is also compensate for simultaneously, enhances endurance ageing resistance Can, the tough sexual function of thermosetting processing is also improved, multi-functional polypropylene fibre is used as work(with glass fibre needle-punched composite The light bluk recombination enhancing automobile interior trim material of energy type, can mitigate 10%~20%, realization is more entered compared with same thickness product The light body of one step.
Brief description of the drawings
Below in conjunction with the drawings and specific embodiments, the present invention is further illustrated:
Fig. 1 is that multi-functional polypropylene fibre of the invention and the technological process of glass fibre needle-punched composite preparation method are shown It is intended to.
Embodiment
Prepared as shown in figure 1, the present invention proposes a kind of multi-functional polypropylene fibre with glass fibre needle-punched composite Method, it is characterised in that:Comprise the following steps, and following steps are sequentially carried out,
Step 1: fiber opens bag mixing
By weight percentage, 15%~35% multi-functional polypropylene fibre is taken to be with 65%~85% glass fibre Fiber raw material, fiber raw material carries out thick shredding by opener pinion roller, and the fiber after thick shredding is rolled by serration Cylinder carries out smart shredding, obtains loose fiber;Loose fiber is entered in big storehouse cotton blender machine by conveyance conduit, is carried out fiber and is mixed Close;
Step 2: combing
The quantitative cotton feeder of air pressure will be transported to through air-flow through the big well-mixed fiber of storehouse cotton blender machine in the step one, mixed Condensating fiber is transported to carding machine by pressure, combs to formation single layer fibre net, and sent web by doffer and pattern doffing roller Enter the wild crops being made up of three pairs of rollers, web vertical transverse strength is reached unanimity;
Step 3: lapping
Web in step 2 is fed into lapping machine by exporting curtain, web is paved into by lapping machine according to technological requirement Thickness is 8mm~25mm;
Step 4: pre-needling
The web obtained in the step 3 is fed into needing machine by exporting curtain, needling treatment is carried out, is had It is that 5mm~20mm, intensity are multi-functional polypropylene fibre and glass fibre needle-punched composite more than 50N to have thickness;
Step 5: main acupuncture
Repeated Acupuncture process step, 2~3 times, it is 5mm~20mm, intensity to be multi-functional more than 70N to obtain with thickness Polypropylene fibre and glass fibre needle-punched composite;
Step 6: trimming, winding and packaging
The multi-functional polypropylene fibre of finished product that the step 5 is obtained utilizes cutting with glass fibre needle-punched composite Machine carries out horizontal cutting, in will be after laterally cutting many crimp function polypropylene fibre and glass fibre needle-punched composite In rolls, using mould chartered plane carry out plastic packaging.
By weight percentage, the present invention uses 15%~35% multi-functional polypropylene fibre and 65%~85% glass Glass fiber is fiber raw material, using needle-punched non-woven production technology, and the light bluk recombination enhancing automobile inside of functional form is made Exterior material, it is specific to be blended using modification infusorial earth with polypropylene fusion, multi-functional polypropylene agglomerate is made, with multi-functional polypropylene Multi-functional polypropylene fibre is made in master batch spinning,
The preparation method of wherein multi-functional polypropylene agglomerate comprises the following steps:
Step 1: the preparation of modification infusorial earth
By weight percentage, take 0.5%~2.0% aluminate coupling agent, 0.5%~1.0% Nacl and 97%~ 99% diatomite feeds high speed mixing smelting machine, is mixed in high speed mixing smelting machine with 800 revs/min~1000 revs/min of rotating speed, mixes The conjunction time is 20 minutes~30 minutes, and normal temperature is naturally cooled to after mixing, modification infusorial earth is obtained;
Carried out Step 2: will be fed through modification infusorial earth made from step one and polypropylene according to formula rate in mixer Mixing, obtains batch mixing, wherein described formula rate is by weight percentage, is made up of following raw material:20% modification infusorial earth With 80% polypropylene;
Step 3: the batch mixing that step 2 is obtained is transported to comminutor after melting mixing by twin-screw extrusion by air-flow Obtain a diameter of 3mm strand;
Step 4: the strand obtained through step 3 carries out Slow cooling by hot bath first, the temperature of hot bath is 85 DEG C~105 DEG C, cooled down subsequently into tepidarium, warm water bath temperature is 45 DEG C~65 DEG C, enters finally into cold bath and is cooled down, Cold water bath temperature is 5 DEG C~10 DEG C, strand is cut into length for 3mm by strand cutoff tool after water-bath, so as to be made poly- third Alkene master batch.
The production technology of multi-functional polypropylene fibre comprises the following steps:
Step 1: taking polypropylene agglomerate, under the conditions of 90 DEG C, dry 4 hours, the polypropylene agglomerate is by by weight hundred The modification infusorial earth of fraction meter 5%~20% and the blending of 80%~95% polypropylene fusion are made, and wherein modification infusorial earth is with weight Percentage meter is made up of following raw material:0.5%~2.0% aluminate coupling agent, 0.5%~1.0% Nacl and 97%~ 99% diatomite;
Step 2: will be added to through the dried polypropylene agglomerate of step one in melting screw rod A as cortex, by polypropylene Section is added in melting screw rod B as sandwich layer, and cortex and sandwich layer are according to mass percent 50:50 are added to metering pump of spinning machine In, obtain after fiber, fiberizing through spinneret extrusion leading by oil rod, three roads of spinning oil groove after heating melting, filtering Obtain fibre bundle after stretching machine, first forming machine, crimping machine, by above-mentioned fibre bundle by second forming machine, fiber trimmer, Cutting machine, fibre finish machine and baling press, obtain multi-functional polypropylene fibre;
The melt index of polypropylene agglomerate in described addition melting screw rod A is 68g/10min, adds melting screw rod B In polypropylene chip melt index be 32g/10min.
Multi-functional polypropylene fibre prepared by preparation method proposed by the present invention and glass fibre needle-punched composite, as A kind of functional form automotive interior material, with multifunctionality, for example;Ageing resistance, toughness, absorbing formaldehyde function, inhale peculiar smell, remove Smelly, releasing negative oxygen ion, breathing damping, air purification function, heat-proof combustion-resistant, sterilizing, extinction delustring, absorbing sound and lowering noise function Etc..Multi-functional polypropylene fibre and glass fiber compound material, can improve the sound-absorption coefficient of automobile interior trim material 60%~70%;The automobile interior trim material weight of same thickness can mitigate 10%~20%, so that, strengthen light bluk recombination The technology application of automobile interior trim material can improve a class again, and production technology level steps and gone up a higher platform again Rank.This multi-functional polypropylene fibre and glass fibre needle-punched composite, will make light bluk recombination enhancing automobile interior trim material More there is feature, intellectuality, it will make automobile interior trim material industry occur huge change, and it will lead automobile inside Exterior material is progressively towards high-tech, multifunctionality, intelligent direction development.Its Social benefit and economic benefit is all highly significant , the application space of multi-functional polypropylene fibre and this composite of glass fibre is huge, and development prospect is very optimistic.

Claims (2)

1. multi-functional polypropylene fibre and glass fibre needle-punched composite preparation method, it is characterised in that:Comprise the following steps, And following steps are sequentially carried out,
Step 1: fiber opens bag mixing
By weight percentage, the multi-functional polypropylene fibre and 65%~85% glass fibre for taking 15%~35% are fiber Raw material, fiber raw material carries out thick shredding by opener pinion roller, and the fiber after thick shredding enters by serration roller Row essence shredding, obtains loose fiber;Loose fiber is entered in big storehouse cotton blender machine by conveyance conduit, carries out fiber mixing;
Step 2: combing
The quantitative cotton feeder of air pressure will be transported to through air-flow through the big well-mixed fiber of storehouse cotton blender machine in the step one, mixing is fine Dimension is transported to carding machine by pressure, combs to forming single layer fibre net, and by doffer and pattern doffing roller by web feeding by The wild crops of three pairs of roller compositions, make web vertical transverse strength reach unanimity;
Step 3: lapping
Web in step 2 is fed into lapping machine by exporting curtain, web is paved into thickness by lapping machine according to technological requirement For 8mm~25mm;
Step 4: pre-needling
The web obtained in the step 3 is fed into needing machine by exporting curtain, needling treatment is carried out, obtaining has thickness Degree is that 5mm~20mm, intensity are multi-functional polypropylene fibre and glass fibre needle-punched composite more than 50N;
Step 5: main acupuncture
Repeated Acupuncture process step, 2~3 times, obtain with thickness be 5mm~20mm, intensity for more than 70N multi-functional poly- third Alkene fiber and glass fibre needle-punched composite;
Step 6: trimming, winding and packaging
The multi-functional polypropylene fibre of finished product and the glass fibre needle-punched composite that the step 5 is obtained are entered using cutting machine Row laterally cutting, by many being curled into function polypropylene fibre with glass fibre needle-punched composite after laterally cutting Volume, plastic packaging is carried out using chartered plane is moulded.
2. a kind of multi-functional polypropylene fibre as described in claim 1 is prepared with glass fibre needle-punched composite preparation method Multi-functional polypropylene fibre and glass fibre needle-punched composite.
CN201710749765.9A 2017-08-28 2017-08-28 Multi-functional polypropylene fibre and glass fibre needle-punched composite and preparation method thereof Pending CN107326531A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN107326531A true CN107326531A (en) 2017-11-07

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108589033A (en) * 2018-04-24 2018-09-28 大连神润新材料有限公司 The production technology of nana intelligent type odorlessness automotive interior material
CN108691093A (en) * 2018-06-21 2018-10-23 冷纯廷 A kind of pavement and its production technology containing nano-powder material
CN109023719A (en) * 2018-06-06 2018-12-18 常州大学 A kind of blended hot composite reinforcing material of polypropylene fibre continuous glass fibre and preparation method thereof
CN109130373A (en) * 2018-07-27 2019-01-04 大连神润新材料有限公司 The preparation method of the nonmetallic gadget material of nana intelligent automobile inside
CN112606443A (en) * 2020-11-27 2021-04-06 合肥杰迈特汽车新材料有限公司 Processing technology of ultra-light GMT plate
CN114311887A (en) * 2021-12-30 2022-04-12 浙江华江科技股份有限公司 Lightweight high-tear-resistance bottom protection composite material for vehicle

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CN106676751A (en) * 2017-01-17 2017-05-17 吉林省华纺静电材料科技有限公司 Needle-punched nonwoven fabric electrostatic fiber filter screen and manufacturing method thereof
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108589033A (en) * 2018-04-24 2018-09-28 大连神润新材料有限公司 The production technology of nana intelligent type odorlessness automotive interior material
CN109023719A (en) * 2018-06-06 2018-12-18 常州大学 A kind of blended hot composite reinforcing material of polypropylene fibre continuous glass fibre and preparation method thereof
CN108691093A (en) * 2018-06-21 2018-10-23 冷纯廷 A kind of pavement and its production technology containing nano-powder material
CN109130373A (en) * 2018-07-27 2019-01-04 大连神润新材料有限公司 The preparation method of the nonmetallic gadget material of nana intelligent automobile inside
CN112606443A (en) * 2020-11-27 2021-04-06 合肥杰迈特汽车新材料有限公司 Processing technology of ultra-light GMT plate
CN114311887A (en) * 2021-12-30 2022-04-12 浙江华江科技股份有限公司 Lightweight high-tear-resistance bottom protection composite material for vehicle

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