CN107315246A - A kind of photoswitch based on medium electrowetting effect - Google Patents
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Abstract
本发明公开了一种基于介质电润湿效应的光开关,该光开关采用三层结构,第一层为上极板,由方形透明玻璃1、透明电极2以及疏水薄膜3组成;第二层为方形透明玻璃层10,沿它的对角线开一条微流道5,流道中有受控离散电解质液滴4,在玻璃层同一水平面上开4个条形介质光波导6、7、8、9;第三层为下极板,由方形透明玻璃作基底15,多晶硅作衬底14,衬底上扩磷及光刻图形化微电极阵列13,电极阵列上有介质层12,介质层上涂覆一层疏水薄膜11。该光开关无需使用电机等复杂器件,使得制作成本、生产工艺大大降低,具有重要的技术价值和经济价值。
The invention discloses an optical switch based on the electrowetting effect of a medium. The optical switch adopts a three-layer structure. The first layer is an upper plate, which is composed of a square transparent glass 1, a transparent electrode 2 and a hydrophobic film 3; the second layer It is a square transparent glass layer 10, and a micro-flow channel 5 is opened along its diagonal, and there are controlled discrete electrolyte droplets 4 in the flow channel, and four strip-shaped dielectric optical waveguides 6, 7, 8 are opened on the same horizontal plane of the glass layer , 9; the third layer is the bottom plate, made of square transparent glass as substrate 15, polysilicon as substrate 14, phosphor-expanding and photolithography patterned microelectrode array 13 on the substrate, dielectric layer 12 is arranged on the electrode array, dielectric layer A layer of hydrophobic film 11 is coated on it. The optical switch does not need to use complex devices such as motors, which greatly reduces the production cost and production process, and has important technical and economic values.
Description
技术领域technical field
本发明涉及一种基于介质电润湿效应的光开关,属于光互联网中光交叉连接、光分插复用器件的技术领域。The invention relates to an optical switch based on the electric wetting effect of a medium, and belongs to the technical field of optical cross-connection and optical add-drop multiplexing devices in the optical Internet.
背景技术Background technique
光开关是光交换的核心器件,也是影响光网络性能的主要因素之一。光开关作为新一代全光联网网络的关键器件,主要用来实现光层面上的路由选择、波长选择、光交叉连接和自愈保护等功能。在全光网中,光分插复用器件(OADM)和光交叉连接(OXC)是不可缺少的网络节点设备,而光开关和光开关阵列则是这些设备中的核心器件。目前已经实用化的光开关,除了MEMS等少数类型的光开关以外,现有光开关的交换容量总是有限,很难制成大阵列,而且MEMS光开关本身在抗机械摩擦、磨损或震动等方面也存在不足之处。所以研制一种微流控的光开关具有重要的技术价值和应用前景。The optical switch is the core device of optical switching, and it is also one of the main factors affecting the performance of the optical network. As a key device of the new-generation all-optical networking network, the optical switch is mainly used to realize functions such as routing selection, wavelength selection, optical cross-connection and self-healing protection on the optical level. In an all-optical network, optical add-drop multiplexing devices (OADM) and optical cross-connects (OXC) are indispensable network node devices, and optical switches and optical switch arrays are the core devices in these devices. The optical switches that have been put into practical use at present, except for a few types of optical switches such as MEMS, the switching capacity of existing optical switches is always limited, it is difficult to make a large array, and the MEMS optical switch itself is resistant to mechanical friction, wear or vibration, etc. There are also deficiencies. Therefore, the development of a microfluidic optical switch has important technical value and application prospects.
发明内容Contents of the invention
本发明目的在于针对上述现有技术的不足,提出了一种基于介质电润湿效应的光开关,该光开关将介质电润湿效应应用于现代光通信技术中,通过驱动离散电解质液滴来控制光束的全反射和全透射,进而实现光开关的“开”和“关”动作。该光开关将电润湿效应与现代光通信技术相结合,该光开关无需使用电机等复杂器件,使得制作成本、生产工艺大大降低,具有重要的技术价值和经济价值。The purpose of the present invention is to address the shortcomings of the above-mentioned prior art, and propose an optical switch based on the dielectric electrowetting effect. The optical switch applies the dielectric electrowetting effect to modern optical communication technology, and drives discrete electrolyte droplets to Control the total reflection and total transmission of the light beam, and then realize the "on" and "off" actions of the optical switch. The optical switch combines the electrowetting effect with modern optical communication technology. The optical switch does not need to use complex devices such as motors, which greatly reduces the production cost and production process, and has important technical and economic values.
本发明解决其技术问题所采取的技术方案是:一种基于介质电润湿效应的光开关,该光开关采用三层结构,第一层为上极板,该上极板包括方形透明玻璃1、透明电极2和疏水薄膜3;第二层为方形透明玻璃层10,沿它的对角线有一条微流道5、流道中有受控离散电解质液滴4,其折射率与透明玻璃匹配,在玻璃层同一水平面上有四个条形介质光波导6、7、8、9;第三层为下极板,该下极板包括方形透明玻璃基底15、多晶硅衬底14、衬底上扩磷及光刻图形化微电极阵列13、电极阵列上热氧化一层SiO2作介质层12、介质层上涂覆一层疏水薄膜11。本发明将中下两层透明玻璃板键合后在微流道5注入一滴电解质液滴4,再将上极板与中层玻璃板键合,此时液滴夹持在上下极板之间,周围填充物质是空气。下极板微电极阵列13和上极板透明电极2分别由引线19、16引至交流电源17正负极。由于液滴的驱动是在某单个微电极阵列上施加电压,因此本发明设置了一个四控开关k18,可保证液滴在整个微流道中往返移动。The technical solution adopted by the present invention to solve the technical problem is: an optical switch based on the dielectric electrowetting effect, the optical switch adopts a three-layer structure, the first layer is an upper plate, and the upper plate includes square transparent glass 1 , transparent electrode 2 and hydrophobic film 3; the second layer is a square transparent glass layer 10, along its diagonal there is a micro-flow channel 5, and there are controlled discrete electrolyte droplets 4 in the flow channel, and its refractive index matches the transparent glass , there are four strip-shaped dielectric optical waveguides 6, 7, 8, 9 on the same horizontal plane of the glass layer; the third layer is the lower plate, which includes a square transparent glass substrate 15, a polysilicon substrate 14, and Phosphorus diffusion and photolithography patterned micro-electrode array 13, a layer of SiO2 is thermally oxidized on the electrode array as a dielectric layer 12, and a layer of hydrophobic film 11 is coated on the dielectric layer. In the present invention, after the middle and lower layers of transparent glass plates are bonded, a drop of electrolyte liquid drop 4 is injected into the micro-flow channel 5, and then the upper plate and the middle glass plate are bonded. At this time, the liquid drop is clamped between the upper and lower plates. The surrounding filling substance is air. The micro-electrode array 13 on the lower plate and the transparent electrode 2 on the upper plate are led to the positive and negative poles of the AC power supply 17 by lead wires 19 and 16 respectively. Since the droplet is driven by applying a voltage on a single microelectrode array, the present invention sets a four-control switch k18 to ensure that the droplet moves back and forth in the entire microfluidic channel.
有益效果:Beneficial effect:
1、本发明将介质电润湿技术应用于光开关之中,通过电控离散液滴实现光开关的开和关,具有良好的操控性和适应性。1. The present invention applies the dielectric electrowetting technology to the optical switch, realizes the opening and closing of the optical switch by electronically controlling the discrete liquid droplets, and has good controllability and adaptability.
2、本发明结构简单、容易制作、成本低、电压低、能耗低、响应速度快、可集成封装,具有实际应用价值。2. The present invention is simple in structure, easy to manufacture, low in cost, low in voltage, low in energy consumption, fast in response, and can be integrated and packaged, and has practical application value.
3、本发明属微流控光器件,无需使用电机等复杂器件,具有很重要的技术价值和经济价值,将会在光通信领域取得广泛应用。3. The invention belongs to the microfluidic optical device, which does not need complex devices such as motors, has very important technical value and economic value, and will be widely used in the field of optical communication.
附图说明Description of drawings
图1为本发明的结构示意图。Fig. 1 is a structural schematic diagram of the present invention.
标识说明:方形透明玻璃-1;透明电极-2;上极板疏水薄膜-3;方形透明玻璃层-10;微流道-5;受控离散电解质液滴-4;条形波导-6、7、8、9;下极板疏水薄膜-11;SiO2介质层-12;微电极阵列-13;多晶硅衬底-14;方形透明玻璃基底-15;上极板电极引线-16;下极板电极引线-19;交流电源-17;四控开关k-19。Logo description: square transparent glass-1; transparent electrode-2; upper plate hydrophobic film-3; square transparent glass layer-10; microchannel-5; controlled discrete electrolyte droplets-4; 7, 8, 9; lower plate hydrophobic film-11; SiO 2 dielectric layer-12; microelectrode array-13; polysilicon substrate-14; square transparent glass substrate-15; upper plate electrode leads-16; Plate electrode lead-19; AC power supply-17; four-control switch k-19.
图2为光开关截面示意图。Fig. 2 is a schematic cross-sectional view of an optical switch.
标识说明:方形透明玻璃-1;透明电极-2;上极板疏水薄膜-3;受控离散电解质液滴4;微流道-5;方形透明玻璃层-10;下极板疏水薄膜-11;SiO2介质层-12;微电极阵列-13;多晶硅衬底-14;方形透明玻璃基底-15。Logo description: square transparent glass-1; transparent electrode-2; upper plate hydrophobic film-3; controlled discrete electrolyte droplets 4; microchannel-5; square transparent glass layer-10; ; SiO 2 dielectric layer-12; microelectrode array-13; polysilicon substrate-14; square transparent glass substrate-15.
图3、图4为基于介质电润湿原理驱动离散液滴的光开关示意图。Figure 3 and Figure 4 are schematic diagrams of optical switches that drive discrete droplets based on the principle of dielectric electrowetting.
其中,图3为光束全部反射,即光开关的“开”状态;图4为光束全透射,即光开关的“关”状态。Among them, Fig. 3 shows the total reflection of the light beam, that is, the "on" state of the optical switch; Fig. 4 shows the total transmission of the light beam, that is, the "off" state of the optical switch.
具体实施方式detailed description
下面结合说明书附图对本发明作进一步的详细描述。The present invention will be described in further detail below in conjunction with the accompanying drawings.
如图1所示,本发明提供了一种基于介质电润湿效应的光开关,该光开关采用三层结构,第一层为上极板,该上极板由方形透明玻璃1、透明电极2以及疏水薄膜3组成;第二层为方形透明玻璃层10,沿它的对角线开一条微流道5,流道中有受控离散电解质液滴4,其折射率与透明玻璃匹配,在玻璃层同一水平面上开4个条形介质光波导6、7、8、9。第三层为下极板,该下极板由方形透明玻璃作基底15、多晶硅作衬底14、衬底上扩磷及光刻图形化微电极阵列13、电极阵列上热氧化一层SiO2作介质层12和介质层上涂覆一层疏水薄膜11。本发明将中下两层透明玻璃板键后在微流道5注入一滴电解质液滴4,再将上极板与中层玻璃板键合,此时液滴夹持在上下极板之间,周围填充物质是空气。下极板微电极阵列13和上极板透明电极2分别由引线19、16引至交流电源17正负极。由于液滴的驱动是在某单个微电极阵列上施加电压,因此本发明设置了一个四控开关k18,可保证液滴在整个微流道中往返移动。As shown in Figure 1, the present invention provides an optical switch based on the dielectric electrowetting effect. The optical switch adopts a three-layer structure, the first layer is an upper plate, and the upper plate is made of a square transparent glass 1, a transparent electrode 2 and a hydrophobic film 3; the second layer is a square transparent glass layer 10, and a micro-channel 5 is opened along its diagonal, and there are controlled discrete electrolyte droplets 4 in the channel, whose refractive index matches that of the transparent glass. Four strip dielectric optical waveguides 6, 7, 8, 9 are opened on the same horizontal plane of the glass layer. The third layer is the lower plate, which is made of square transparent glass as the substrate 15, polysilicon as the substrate 14, phosphor-spreading and photolithography patterned micro-electrode array 13 on the substrate, and a layer of SiO2 thermally oxidized on the electrode array. A layer of hydrophobic film 11 is applied as the medium layer 12 and on the medium layer. In the present invention, after the middle and lower transparent glass plates are bonded, a drop of electrolyte liquid drop 4 is injected into the micro-channel 5, and then the upper plate and the middle glass plate are bonded. The filling substance is air. The micro-electrode array 13 on the lower plate and the transparent electrode 2 on the upper plate are led to the positive and negative poles of the AC power supply 17 by lead wires 19 and 16 respectively. Since the droplet is driven by applying a voltage on a single microelectrode array, a four-control switch k18 is provided in the present invention to ensure that the droplet moves back and forth in the entire microfluidic channel.
如图2所示的三层结构介质电润湿驱动式光开关的截面图。光开关“开”和“关”的实现基于离散电解质液滴的介质电润湿驱动效应。具体地讲,本发明通过在介质膜下面的微电极阵列上施加电势来改变介质膜与表面液体的润湿特性,即通过局部改变液滴和固体表面的三相接触角(即在气、液、固三相交点处所作的气-液界面的切线与固-液交界线之间的夹角),造成液滴两端不对称形变,使液滴内部产生压强差,实现了对液滴传输的操作和控制。本发明设计的电润湿效应仅发生在上下极板与离散电解质液滴之间,微流道侧壁与液滴虽也会有接触角存在,但两侧壁没有加电极,因此可认为液体与侧壁的接触角在驱动过程中不变。当开关k打开时,液滴的形状成对称分布,见图中虚线部分,液滴与上、下极板的接触角分别是θt和θ0,忽略重力的影响,其值都为疏水表面的初始接触角;当开关k闭合时,由于介质上电润湿作用,液滴与右侧极板间的接触角发生变化,见图中实线部分。由于上极板疏水层厚度很薄,上层疏水层电容很大,外加电压的分压很小,因此在上极板的接触角θt几乎不发生变化;而外加电压大部分都压降在下极板上,所以液滴与下极板的接触角明显变小,其值θv可以由Young-Lippmann方程近似描述。The cross-sectional view of the three-layer structure dielectric electrowetting-driven optical switch shown in FIG. 2 . The realization of the optical switch "on" and "off" is based on the dielectric electrowetting actuation effect of discrete electrolyte droplets. Specifically, the present invention changes the wetting characteristics of the dielectric film and the surface liquid by applying a potential on the microelectrode array below the dielectric film, that is, by locally changing the three-phase contact angle between the liquid droplet and the solid surface (that is, in the gas, liquid , the angle between the tangent line of the gas-liquid interface and the solid-liquid boundary line at the intersection point of the solid three-phase), resulting in asymmetric deformation at both ends of the droplet, causing a pressure difference inside the droplet, and realizing the transmission of the droplet operation and control. The electrowetting effect designed in the present invention only occurs between the upper and lower plates and the discrete electrolyte droplets. Although there are contact angles between the side walls of the microchannel and the droplets, there are no electrodes on the two side walls, so it can be considered as a liquid The contact angle with the sidewall does not change during actuation. When the switch k is turned on, the shape of the droplet is distributed symmetrically, as shown in the dotted line in the figure, the contact angles between the droplet and the upper and lower plates are θ t and θ 0 respectively, ignoring the influence of gravity, the values are all hydrophobic surfaces The initial contact angle of ; when the switch k is closed, due to the electrowetting effect on the medium, the contact angle between the droplet and the right plate changes, as shown in the solid line in the figure. Since the hydrophobic layer of the upper plate is very thin, the capacitance of the upper hydrophobic layer is very large, and the partial voltage of the applied voltage is very small, so the contact angle θ t on the upper plate hardly changes; while most of the applied voltage drops on the lower plate plate, so the contact angle between the droplet and the lower plate becomes significantly smaller, and its value θ v can be approximately described by the Young-Lippmann equation.
θ0是v=0时的初始接触角,ε0、εr分别是真空的介电常数和介质层的有效介电常数,d是疏水介质层有效厚度。γlg为电解质液滴与空气之间的表面张力,当在电极和离散电解质液滴间施加电势v后,由Young-Lippmann方程可以看出,液滴的三相接触角随外加电势v的绝对值增大而变小,而且它与介质层的厚度、介电常数都有关。需指出当外加电压增加到某一定值时,接触角变成最小,若再增加外加电势,接触角不再变化,这种现象称接触角饱和。因此,本发明在芯片设计过程中为避免该现象,提出用交流电源驱动。θ 0 is the initial contact angle when v=0, ε 0 and ε r are the dielectric constant of vacuum and the effective dielectric constant of the dielectric layer, respectively, and d is the effective thickness of the hydrophobic dielectric layer. γ lg is the surface tension between the electrolyte droplet and the air. When a potential v is applied between the electrode and the discrete electrolyte droplet, it can be seen from the Young-Lippmann equation that the three-phase contact angle of the droplet varies with the absolute value of the applied potential v The value increases and becomes smaller, and it is related to the thickness and dielectric constant of the dielectric layer. It should be pointed out that when the applied voltage increases to a certain value, the contact angle becomes the minimum. If the applied potential is increased again, the contact angle will not change. This phenomenon is called contact angle saturation. Therefore, in order to avoid this phenomenon in the chip design process, the present invention proposes to drive with AC power.
本发明由于介质电润湿效应使液滴在右侧下电极上的三相接触角变小,造成了液滴不对称形变并产生内部压强差,利用解析方法以及压强与液滴两侧曲率半径和表面张力的关系可推导出简化的液滴两侧压强差表达式为:In the present invention, due to the dielectric electrowetting effect, the three-phase contact angle of the droplet on the lower electrode on the right becomes smaller, resulting in asymmetric deformation of the droplet and an internal pressure difference. The relationship between the surface tension and the simplified expression of the pressure difference on both sides of the droplet can be deduced as:
其中D为上下极板间距,ε0、εr分别是真空的介电常数和介质层的有效介电常数,d是疏水介质层有效厚度。Where D is the distance between the upper and lower plates, ε 0 and ε r are the dielectric constant of the vacuum and the effective dielectric constant of the dielectric layer, respectively, and d is the effective thickness of the hydrophobic dielectric layer.
所以本发明通过在液滴两侧中某一侧微型电极阵列上施加电势差v,可改变液滴单侧的三相接触角造成液滴非对称形变并产生内部压强差,从而实现对液滴的操作和控制。Therefore, the present invention can change the three-phase contact angle on one side of the droplet by applying a potential difference v on the micro-electrode array on one side of the droplet to cause asymmetric deformation of the droplet and generate an internal pressure difference, thereby realizing the control of the droplet. operation and control.
本发明光开关的具体实施方式包括:初始时刻液滴位于任意两微电极阵列之间,当开关k闭合液滴某一侧微电极阵列时,由于介质上电润湿作用,液滴单侧三相接触角变小,造成液滴不对称形变并产生内部压强差,从而驱动液滴向施加电压的微电极阵列一侧移动。适当调节电压大小,当液滴运动到图3位置时,从条形光波导6入射的的光束在方形透明玻璃内到达微流道固-气界面时,光从光密介质进入光疏介质,且入射角大于临界角,光束全部发生全反射并从条形光波导7出射,此为光开关的“开”状态;当液滴运动到图4位置时,从条形光波导6入射的光束在方形透明玻璃内到达微流道固-液界面时,由于方形透明玻璃和液滴折射率相同,光束全部透射进入条形光波导8然后出射,此为光开关的“关”状态。The specific implementation of the optical switch of the present invention includes: the droplet is located between any two microelectrode arrays at the initial moment, when the switch k closes the microelectrode array on one side of the droplet, due to the electrowetting effect on the medium, three The phase contact angle becomes smaller, causing asymmetric deformation of the droplet and creating an internal pressure difference, which drives the droplet to move towards the side of the microelectrode array where the voltage is applied. Properly adjust the voltage, when the droplet moves to the position shown in Figure 3, when the light beam incident from the strip optical waveguide 6 reaches the solid-air interface of the microchannel in the square transparent glass, the light enters the optically thinner medium from the optically denser medium, And the angle of incidence is greater than the critical angle, all the beams are totally reflected and exit from the strip optical waveguide 7, which is the "on" state of the optical switch; when the droplet moves to the position shown in Figure 4, the incident beam from the strip optical waveguide 6 When reaching the solid-liquid interface of the microchannel in the square transparent glass, since the refractive index of the square transparent glass is the same as that of the liquid droplet, all light beams are transmitted into the strip optical waveguide 8 and then exit. This is the "off" state of the optical switch.
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