CN107313287A - A kind of latex coating for being used to prepare packaging material for food - Google Patents
A kind of latex coating for being used to prepare packaging material for food Download PDFInfo
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- CN107313287A CN107313287A CN201710413859.9A CN201710413859A CN107313287A CN 107313287 A CN107313287 A CN 107313287A CN 201710413859 A CN201710413859 A CN 201710413859A CN 107313287 A CN107313287 A CN 107313287A
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- coating
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/12—Defoamers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Wrappers (AREA)
Abstract
It is an object of the invention to provide a kind of latex coating for being used to prepare packaging material for food, include the component of following mass percent：Styrene acrylic polymers 30% 50%；Dispersant 0.1% 1%；Defoamer 0.1% 1%；Calcined kaolin 19.8% 28%；Deionized water 20% 40%；The coating latex of the present invention is used to prepare the compound package material that novel environment friendly can be used for contact food.Extrusion coating paper prepared by the latex coating of the present invention is Biodegradable material, can reduce the pollution to environment, be environmentally friendly material.Extrusion coating paper prepared by latex coating of the present invention, can directly be crushed when paper is reclaimed into papermaking refining system.
Description
Technical field
The invention belongs to food-grade field of packaging material, and in particular to a kind of painting for being used to prepare packaging material for food
Cloth latex.
Background technology
Polymeric packaging material is often requested to have choke, protection against the tide because content is different, guarantor is fragrant, prevent fat migration etc.
A variety of functions, the packaging material of single variety can not usually meet this requirement, and therefore, polymer composite is in packaging field
It is widely used, particularly in terms of film article, different use requirements can be met from different barrier packaging materials.
Large-scale barrier material is mostly leaching membrane paper on existing market.Current leaching membrane paper is exactly coated plastic pellet by casting machine
In the composite of paper surface, main feature is exactly that this composite with grease proofing, waterproof (relative) and be able to can be sealed.
But the high polymer material (plastics) used in leaching membrane paper is substantially polyethylene (PE), polypropylene (PP) class has following deficiency：Polyolefin
The plastics of class can hardly be degraded, and pollution, non-environmental protection barrier material are produced to environment；And needed when reclaiming by materials such as PE and PP
Material is first separated with paper, then recycling, big for the film separating difficulty of low grammes per square metre, adds great amount of cost and energy consumption, and
And existing leaching membrane paper is due to the barrier with very high grease-proof and waterproof, (especially high temperature food), water in direct packaged food
Steam can not pass through barrier layer, and portion forms aqueous water and absorbed by food within a package, causes the change of the color, smell and taste of food etc..
The content of the invention
It is an object of the invention to provide a kind of latex coating for being used to prepare packaging material for food, this prepares latex and solved now
The problem of having leaching membrane paper barrier material non-degradable, so as to mitigate environmental pollution；Eliminating simultaneously when paper is reclaimed will obstruct
Material first does the process increased cost of institute and energy consumption problem of separating treatment with paper, so as to make up the deficiencies in the prior art.
Present invention firstly provides a kind of coating latex for being used to prepare environmentally friendly barrier material, mainly including following quality percentage
The component of ratio：
According to another preferred embodiment of the present invention, it is characterised in that：The styrene acrylic polymers, are benzene
Acrylic emulsion, its content is preferably 35-45% mass parts.
According to another preferred embodiment of the present invention, it is characterised in that：Described dispersant is sodium polyacrylate,
Its consumption is preferably 1% mass parts.
According to another preferred embodiment of the present invention, it is characterised in that：Described defoamer is eaten for organic oils class
Grade defoamer, its consumption is preferably 1% mass parts.
According to another preferred embodiment of the present invention, it is characterised in that：Described calcined kaolin is that 6250 mesh are forged
Kaolin is burnt, its consumption is preferably 28% mass parts.
According to another preferred embodiment of the present invention, it is characterised in that：Its consumption of described deionized water is preferably
25-35% mass parts.
The coating latex of the present invention is used to prepare the compound package material that novel environment friendly can be used for contact food.
Technical scheme obtains following technique effect：
(1) extrusion coating paper prepared by latex coating of the invention is Biodegradable material, can reduce the pollution to environment,
It is environmentally friendly material.
(2) extrusion coating paper prepared by latex coating of the present invention, can directly crush into papermaking when paper is reclaimed and be beaten system
System.
(3) extrusion coating paper prepared by latex coating of the invention, oil resistivity test uses T559 standards, takes KIT12 grades of surveys
Test solution is tested, and the grease proofing grades of KIT reach 12 grades.
(4) extrusion coating paper prepared by latex coating of the present invention, while with higher Water-proof and oil-proof performance also have compared with
High water vapo(u)r transmission.
Brief description of the drawings
Fig. 1：Extrusion coating paper layer structure schematic diagram prepared by the embodiment of the present invention 1.
Fig. 2：The biodegradable datagram of extrusion coating paper prepared by the embodiment of the present invention 1.
Fig. 3:Extrusion coating paper and existing leaching membrane paper prepared by body paper, the embodiment of the present invention 1 reclaim beating resultses comparison diagram.
Fig. 4：Extrusion coating paper and existing leaching membrane paper water proofing property contrast experiment figure prepared by body paper, the embodiment of the present invention 1.
Embodiment
Leaching membrane paper used at present is in order to reach choke, protection against the tide, guarantor is fragrant, prevent a variety of functions such as fat migration, and adopts
With PE or PP materials；Cause the leaching membrane paper being made to there is non-degradable, reclaim difficult, the problems such as big to resource consumption.
The problem of in order to solve above-mentioned, applicant is transformed the component and proportioning that are coated with latex, and is equipped with optimization
Preparation method, so as to facilitate the present invention.
The technical scheme is further described with reference to the accompanying drawings and examples, but protection scope of the present invention is simultaneously
This is not limited only to, person skilled in art can make some nonessential modifications and adaptations according to foregoing invention content.
Styrene acrylic polymers used in the embodiment of the present invention are by BASF Aktiengesellschaft with article No.S 440 is sold.
Dispersant used is the sodium polyacrylate dispersant that DOW Chemical is produced in the embodiment of the present invention, and the trade mark is
ACUMER 9400。
Defoamer used is the organic oil based food level defoamer that DOW Chemical is produced in the embodiment of the present invention, and the trade mark is
Airase 4500。
Calcined kaolin used is commercially available 6250 mesh calcined kaolin in the embodiment of the present invention.
Styrene acrylic polymers used in the present invention are by BASF Aktiengesellschaft with article No.S 440 goes out
Sell.
Embodiment 1
First by aqueous ammonium salt modified phenylethylene acrylate copolymer 35%；Dispersant 1%；Defoamer 1%；Calcine kaolinite
Native (6250 mesh) 28%；Deionized water 35% is added in scattered stirred tank, in 25-35 DEG C, speed of agitator 1500r/min conditions
Lower dispersed with stirring 1 hour, discharges standby.As shown in figure 1, the extrusion coating paper is coated with by packaging for foodstuff wrapping paper 1 and latex coating
The barrier layer 2 that drying is formed is constituted.Take 21 grams/m of food wrapper to do base material, applied mixture using coating process
Cloth is on the paper, and wherein coating speed is 20 ms/min, and the drying temperature of composite is 65 DEG C after coating.What is obtained is compound
Paper layer structure is as shown in Figure 1.
The extrusion coating paper of preparation is carried out to cut out sample detection：Sample coatings thickness is 8um, and oil resistivity test uses T559 standards,
KIT12 grades of test droplets are taken to wipe test fluid observation pattern, without phenomenon of osmosis, the grease proofing grades of KIT after specimen surface, 15s
For 12 grades.
Fig. 2 is the biological degraded line chart of the extrusion coating paper prepared by the present embodiment, when the time reaching 63 days, and quality is damaged
Mistake has reached 57.3%, it is seen that with good biological degradability, is environmentally friendly material.
Paper and existing leaching membrane paper of the Fig. 3 from left to right for body paper, prepared by the present embodiment be directly beaten after slurries figure,
Parts of plastics is difficult into slurry after the directly mashing of existing leaching membrane paper, so existing leaching membrane paper must can just be beaten after first paper separation
Slurry；And the paper prepared by the present embodiment is identical with body paper, all recyclable rear directly mashing.
The water resistance test chart of Fig. 4 extrusion coating papers from left to right for body paper, prepared by the present embodiment and existing leaching membrane paper,
90 DEG C, 30ml are showered into specimen surface, body paper has been waterlogged after 1 minute, the extrusion coating paper prepared by the present embodiment and existing
There is leaching membrane paper still without permeable point, the water resistance of the extrusion coating paper prepared by the present embodiment is higher.
Table 1 is the water vapo(u)r transmission experimental data of body paper, the extrusion coating paper prepared by the present embodiment and existing leaching membrane paper, silicon
Glue water absorption represents that water vapour passes through the weight absorbed after each pattern by silica gel, is used as the water vapo(u)r transmission of each pattern
Sign.As shown in table 1, prepared by the present embodiment extrusion coating paper and the water vapo(u)r transmission of body paper is close, with good water
Vapor permeability, the water vapo(u)r transmission of better than existing leaching membrane paper.Extrusion coating paper prepared by the present embodiment possesses to be drenched with existing
While the high Water-proof and oil-proof of film paper, it may have very high water vapo(u)r transmission.
Table 1
| Sample | 1 | 2 | 3 |
| Sample name | Blank pattern | Embodiment 1 prepares paper | Existing leaching membrane paper |
| Silica gel original weight (g) | 10.00 | 10.00 | 10.00 |
| Originate gross weight (g) | 243.32 | 243.21 | 242.81 |
| Test condition | 90%/38 DEG C of relative humidity | 90%/38 DEG C of relative humidity | 90%/38 DEG C of relative humidity |
| Gross weight (g) after 24 hours | 246.43 | 246.23 | 243.05 |
| Silica gel water absorption (g) | 3.11 | 3.02 | 0.24 |
Embodiment 2
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 3
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 4
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 6
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 7
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 8
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 105 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 9
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 10
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 11
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 105 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 12
First by styrene acrylic polymers 35%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 35% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 13
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 14
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 15
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 16
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 17
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 18
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 19
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 20
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 21
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 22
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 23
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 85 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 24
First by styrene acrylic polymers 40%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 30% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 125 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 25
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 45 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 26
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 27
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 20 ms/min, and the drying temperature of composite is 105 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 28
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 45 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 29
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 30
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 40 ms/min, and the drying temperature of composite is 105 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 31
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 45 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 32
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 33
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 60 ms/min, and the drying temperature of composite is 105 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 34
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 45 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 35
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 65 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
Embodiment 36
First by styrene acrylic polymers 45%；Dispersant 1%；Defoamer 1%；Calcined kaolin (6250 mesh)
28%；Deionized water 25% is added in scattered stirred tank, the dispersed with stirring under the conditions of 25-35 DEG C, speed of agitator 1500r/min
1 hour, discharge standby.As shown in figure 1, what the extrusion coating paper was formed by packaging for foodstuff wrapping paper 1 and latex coating coating drying
Barrier layer 2 is constituted, and takes 21 grams/m of food wrapper to do base material, and mixture is applied on the paper using coating process,
Wherein coating speed is 75 ms/min, and the drying temperature of composite is 105 DEG C after coating.Finally cut out sample detection：Sample coatings
Thickness is 8um, and oil resistivity test uses T559 standards, takes KIT12 grades of test droplets to wipe test fluid after specimen surface, 15s
Pattern is observed, without phenomenon of osmosis, the grease proofing grades of KIT are 12 grades.
The biological degradability of composite prepared by above-described embodiment, mashing property and water vapo(u)r transmission and embodiment 1
The effect of the material of preparation is similar.
Claims (8)
1. a kind of latex coating for being used to prepare packaging material for food, it is characterised in that described coating latex includes following matter
Measure the component of percentage：
2. latex is coated with as claimed in claim 1, it is characterised in that described styrene acrylic polymers are phenylpropyl alcohol breast
Liquid, its content is preferably 35-45% mass parts.
3. latex is coated with as claimed in claim 1, it is characterised in that described dispersant is sodium polyacrylate, its consumption
Preferably 1% mass parts.
4. latex is coated with as claimed in claim 1, it is characterised in that described defoamer is organic oils based food level froth breaking
Agent, its consumption is preferably 1% mass parts.
5. latex is coated with as claimed in claim 1, it is characterised in that described calcined kaolin is that 6250 mesh calcine kaolinite
Soil, its consumption is preferably 28% mass parts.
6. latex is coated with as claimed in claim 1, it is characterised in that described deionized water consumption is 25-35% mass parts.
7. application of the coating latex in food packaging composite is prepared described in claim 1.
8. application as claimed in claim 7, it is characterised in that described composite is wrapping paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710413859.9A CN107313287A (en) | 2017-06-05 | 2017-06-05 | A kind of latex coating for being used to prepare packaging material for food |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710413859.9A CN107313287A (en) | 2017-06-05 | 2017-06-05 | A kind of latex coating for being used to prepare packaging material for food |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107313287A true CN107313287A (en) | 2017-11-03 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575825A (en) * | 2009-06-05 | 2009-11-11 | 万国纸业太阳白卡纸有限公司 | Paper for manufacturing paper cup/paper bowl |
| CN102378725A (en) * | 2009-04-03 | 2012-03-14 | 柯思纳斯有限公司 | A pigment coated paperboard adapted for sterilizable packages |
| CN106245459A (en) * | 2016-09-05 | 2016-12-21 | 珠海红塔仁恒包装股份有限公司 | A kind of true qualities flexible package punch paper and production technology thereof |
-
2017
- 2017-06-05 CN CN201710413859.9A patent/CN107313287A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102378725A (en) * | 2009-04-03 | 2012-03-14 | 柯思纳斯有限公司 | A pigment coated paperboard adapted for sterilizable packages |
| CN101575825A (en) * | 2009-06-05 | 2009-11-11 | 万国纸业太阳白卡纸有限公司 | Paper for manufacturing paper cup/paper bowl |
| CN106245459A (en) * | 2016-09-05 | 2016-12-21 | 珠海红塔仁恒包装股份有限公司 | A kind of true qualities flexible package punch paper and production technology thereof |
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Application publication date: 20171103 |