CN107312382A - A kind of antioxidation environmental protection ink - Google Patents
A kind of antioxidation environmental protection ink Download PDFInfo
- Publication number
- CN107312382A CN107312382A CN201710652756.8A CN201710652756A CN107312382A CN 107312382 A CN107312382 A CN 107312382A CN 201710652756 A CN201710652756 A CN 201710652756A CN 107312382 A CN107312382 A CN 107312382A
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- China
- Prior art keywords
- parts
- resin
- environmental protection
- antioxidant
- protection ink
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- 230000007613 environmental effect Effects 0.000 title claims abstract description 27
- 230000003064 anti-oxidating effect Effects 0.000 title claims abstract description 24
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 26
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 26
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 18
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 16
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 16
- 229920000180 alkyd Polymers 0.000 claims abstract description 16
- 239000006184 cosolvent Substances 0.000 claims abstract description 16
- 239000003822 epoxy resin Substances 0.000 claims abstract description 16
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 16
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 16
- FSLGRPCWSUDGGH-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid;sodium Chemical compound [Na].C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 FSLGRPCWSUDGGH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 15
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 15
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 15
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 15
- 241001330002 Bambuseae Species 0.000 claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011425 bamboo Substances 0.000 claims abstract description 15
- 239000003610 charcoal Substances 0.000 claims abstract description 15
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 15
- 239000010439 graphite Substances 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 15
- 229920002101 Chitin Polymers 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 235000000072 L-ascorbyl-6-palmitate Nutrition 0.000 claims abstract description 9
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 claims abstract description 9
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 26
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 24
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 23
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 12
- 229930003268 Vitamin C Natural products 0.000 claims description 12
- 235000019154 vitamin C Nutrition 0.000 claims description 12
- 239000011718 vitamin C Substances 0.000 claims description 12
- 238000000227 grinding Methods 0.000 claims description 11
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 8
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 8
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 8
- 239000001630 malic acid Substances 0.000 claims description 8
- 235000011090 malic acid Nutrition 0.000 claims description 8
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 230000011218 segmentation Effects 0.000 claims description 7
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 6
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 6
- 239000007765 cera alba Substances 0.000 claims description 6
- 229940041616 menthol Drugs 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- -1 Vitamin C palmitic acid Ester Chemical class 0.000 claims description 2
- 229930003427 Vitamin E Natural products 0.000 claims description 2
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 235000019165 vitamin E Nutrition 0.000 claims description 2
- 229940046009 vitamin E Drugs 0.000 claims description 2
- 239000011709 vitamin E Substances 0.000 claims description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims 2
- 235000021314 Palmitic acid Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N n-hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 235000010265 sodium sulphite Nutrition 0.000 claims 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 7
- SEGBQNJGOCXIGC-FHERZECASA-N benzyl n-[(2s)-1-[(4-hydroxyoxolan-3-yl)amino]-4-methyl-1-oxopentan-2-yl]carbamate Chemical group N([C@@H](CC(C)C)C(=O)NC1C(COC1)O)C(=O)OCC1=CC=CC=C1 SEGBQNJGOCXIGC-FHERZECASA-N 0.000 abstract 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/12—Printing inks based on waxes or bitumen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A kind of antioxidation environmental protection ink, is made up of the component of following parts by weight：10 20 parts of waterborne polyurethane resin, 48 parts of water soluble alkyd resin, 10 20 parts of rosin modified phenolic resin, 36 parts of epoxy resin modified acrylic resin, 24 parts of polyvinyl alcohol, 13 parts of chitin, 35 parts of Vitamin C palmitate, 13 parts of methyl naphthalene sulfonic acid sodium, 5 10 parts of cosolvent, 24 parts of bamboo charcoal powder, 13 parts of graphite, 48 parts of pigment, 13 parts of modifying agent, 25 parts of antioxidant, 40 50 parts of water.The present invention is strong to the dispersed encapsulated ability of pigment, is difficult skinning, back dissolving is Well-recovered, low with environmental protection, safety, smell, film forming covering is good, wear-resisting and easily scrape, and many advantages, such as difficulty is struck off will not be become with standing time extension after printing.
Description
Technical field
The present invention relates to printing technology, and in particular to a kind of antioxidation environmental protection ink.
Background technology
Ink is the important materials for printing, and it is shown pattern, word on stock by printing or air brushing.Oil
Ink includes main component and auxiliary element, and they equably mix and form a kind of stickiness colloidal fluid through repeat-rolling.By
Link stuff, pigment, filler, auxiliary agent and solvent etc. are constituted.For books and periodicals, packing and decorating, building decoration and electronic circuit sheet material etc.
Various printings.As social demand increases, ink kind and yield also respective extension and growth.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of antioxidation environmental protection ink.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of antioxidation environmental protection ink, is made up of the component of following parts by weight：10-20 parts of waterborne polyurethane resin, water
4-8 parts of dissolubility alkyd resin, 10-20 parts of rosin modified phenolic resin, 3-6 parts of epoxy resin modified acrylic resin, polyethylene
2-4 parts of alcohol, 1-3 parts of chitin, 3-5 parts of Vitamin C palmitate, 1-3 parts of methyl naphthalene sulfonic acid sodium, 5-10 parts of cosolvent, bamboo charcoal powder
2-4 parts, 1-3 parts of graphite, 4-8 parts of pigment, 1-3 parts of modifying agent, 2-5 parts of antioxidant, 40-50 parts of water.
Above-mentioned antioxidation environmental protection ink, the component of preferably following parts by weight is made：15 parts of waterborne polyurethane resin, it is water-soluble
Property 6 parts of alkyd resin, 15 parts of rosin modified phenolic resin, 5 parts of epoxy resin modified acrylic resin, 3 parts of polyvinyl alcohol, crust
Plain 2 parts, 4 parts of Vitamin C palmitate, 2 parts of methyl naphthalene sulfonic acid sodium, 8 parts of cosolvent, 3 parts of bamboo charcoal powder, 2 parts of graphite, 6 parts of pigment,
2 parts of modifying agent, 4 parts of antioxidant, 45 parts of water.
The modifying agent is made up of the component of following parts by weight：4-6 parts of acetate, 2-3 parts of cera alba, caryophyllus oil 1-2
Part, 0.8-1 parts of vitamin E, 0.5-0.8 parts of vitamin C, 0.6-1 parts of menthol.
The component of the modifying agent preferably following parts by weight is made：5 parts of acetate, 2 parts of cera alba, 1 part of caryophyllus oil, dimension
Raw E0.9 parts of element, 0.6 part of vitamin C, 0.8 part of menthol.
Antioxidant is made up of the component of following parts by weight：3-5 parts of the tert-butyl alcohol, 3-6 parts of dicyclopentadiene, paracresol 2-
4 parts, 0.8-1.5 parts of paraffin, 2-3 parts of malic acid, 1-2 parts of citric acid.
The component of antioxidant preferably following parts by weight is made：4 parts of the tert-butyl alcohol, 5 parts of dicyclopentadiene, 3 parts of paracresol,
1.2 parts of paraffin, 2 parts of malic acid, 1 part of citric acid.
The preparation method of above-mentioned antioxidation environmental protection ink is to comprise the following steps：
A, by rosin modified phenolic resin, epoxy resin modified acrylic resin, polyvinyl alcohol, chitin, Vitamin C palm fibre
Glycerin monostearate, methyl naphthalene sulfonic acid sodium, are added sequentially in reactor, are heated to molten condition, and be stirred continuously；
B, by waterborne polyurethane resin, water soluble alkyd resin, bamboo charcoal powder, graphite, pigment mix, be heated to 120 degree, put
Enter to be stirred in mixer 20-30 minutes, mixing speed is 400-500r/min；
C, step a mixture mixed with step b mixture, add cosolvent, modifying agent, antioxidant, carry out
Stirring mixing, temperature control is in 70-80 degree, and mixing speed is 700-800r/min, and mixing time is 50-60 minutes；
D, moisture is added in the mixture that step c is handled well for 5 times, carries out five segmentation grindings, that is, obtain finished product.
Further, the speed of five segmentations grinding is respectively：30-40/rpm, 50-60/rpm, 70-80/rpm,
90-100/rpm, point five sections of grindings, more preferably, ink is finer and smoother for grinding effect, insoluble in caking, blocks oil-out.
The beneficial effects of the invention are as follows：
The present invention selects waterborne polyurethane resin, and rosin modified phenolic resin has added water soluble alkyd resin, epoxy
Resin modified acrylic resin, and cosolvent, modifying agent are added, antioxidant, pliability of the present invention is high, and pigment is divided
Bales Off wraps up in ability by force, is difficult skinning, back dissolving is Well-recovered, the problem of half tone is easily blocked when solving ink printing, with green
Environmental protection, safety, smell are low, and film forming covering is good, wear-resisting and easily scrape, and will not become difficulty as standing time extends after printing and scrape
Except many advantages, such as, it is to avoid use toluene, dimethylbenzene, the toxic organic solvents such as ethyl acetate.The preparation method of the present invention is simple,
Efficiently, product qualification rate is high, workable, suitable mass mechanized production.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of antioxidation environmental protection ink, is made up of the component of following parts by weight：10 parts of waterborne polyurethane resin, it is water-soluble
4 parts of alkyd resin, 10 parts of rosin modified phenolic resin, 3 parts of epoxy resin modified acrylic resin, 2 parts of polyvinyl alcohol, chitin
1 part, 3 parts of Vitamin C palmitate, 1 part of methyl naphthalene sulfonic acid sodium, 5 parts of cosolvent, 2 parts of bamboo charcoal powder, 1 part of graphite, 4 parts of pigment change
Good dose 1 part, 2 parts of antioxidant, 40 parts of water.
The modifying agent is made up of the component of following parts by weight：4 parts of acetate, 2 parts of cera alba, 1 part of caryophyllus oil, dimension life
It is plain E0.8 parts, 0.5 part of vitamin C, 0.6 part of menthol.
Antioxidant is made up of the component of following parts by weight：3 parts of the tert-butyl alcohol, 3 parts of dicyclopentadiene, 2 parts of paracresol, stone
0.8 part of wax, 2 parts of malic acid, 1 part of citric acid.
The preparation method of above-mentioned antioxidation environmental protection ink is to comprise the following steps：
A, by rosin modified phenolic resin, epoxy resin modified acrylic resin, polyvinyl alcohol, chitin, Vitamin C palm fibre
Glycerin monostearate, methyl naphthalene sulfonic acid sodium, are added sequentially in reactor, are heated to molten condition, and be stirred continuously；
B, by waterborne polyurethane resin, water soluble alkyd resin, bamboo charcoal powder, graphite, pigment mix, be heated to 120 degree, put
Enter to be stirred in mixer 20 minutes, mixing speed is 400r/min；
C, step a mixture mixed with step b mixture, add cosolvent, modifying agent, antioxidant, carry out
Stirring mixing, temperature control is at 70 degree, and mixing speed is 700r/min, and mixing time is 50 minutes；
D, moisture is added in the mixture that step c is handled well for 5 times, carries out five segmentation grindings, the speed point of grinding
It is not：30/rpm, 50/rpm, 70/rpm, 90/rpm, that is, obtain finished product.
Embodiment 2
A kind of antioxidation environmental protection ink, is made up of the component of following parts by weight：20 parts of waterborne polyurethane resin, it is water-soluble
8 parts of alkyd resin, 20 parts of rosin modified phenolic resin, 6 parts of epoxy resin modified acrylic resin, 4 parts of polyvinyl alcohol, chitin
3 parts, 5 parts of Vitamin C palmitate, 3 parts of methyl naphthalene sulfonic acid sodium, 10 parts of cosolvent, 4 parts of bamboo charcoal powder, 3 parts of graphite, 8 parts of pigment change
Good dose 3 parts, 5 parts of antioxidant, 50 parts of water.
The modifying agent is made up of the component of following parts by weight：6 parts of acetate, 3 parts of cera alba, 2 parts of caryophyllus oil, dimension life
It is plain E1 parts, 0.8 part of vitamin C, 1 part of menthol.
Antioxidant is made up of the component of following parts by weight：5 parts of the tert-butyl alcohol, 6 parts of dicyclopentadiene, 4 parts of paracresol, stone
1.5 parts of wax, 3 parts of malic acid, 2 parts of citric acid.
The preparation method of above-mentioned antioxidation environmental protection ink is to comprise the following steps：
A, by rosin modified phenolic resin, epoxy resin modified acrylic resin, polyvinyl alcohol, chitin, Vitamin C palm fibre
Glycerin monostearate, methyl naphthalene sulfonic acid sodium, are added sequentially in reactor, are heated to molten condition, and be stirred continuously；
B, by waterborne polyurethane resin, water soluble alkyd resin, bamboo charcoal powder, graphite, pigment mix, be heated to 120 degree, put
Enter to be stirred in mixer 30 minutes, mixing speed is 500r/min；
C, step a mixture mixed with step b mixture, add cosolvent, modifying agent, antioxidant, carry out
Stirring mixing, temperature control is at 80 degree, and mixing speed is 800r/min, and mixing time is 60 minutes；
D, moisture is added in the mixture that step c is handled well for 5 times, carries out five segmentation grindings, the speed point of grinding
It is not：40/rpm, 60/rpm, 80/rpm, 100/rpm, that is, obtain finished product.
Control group 1
A kind of antioxidation environmental protection ink, is made up of the component of following parts by weight：10 parts of waterborne polyurethane resin, it is water-soluble
4 parts of alkyd resin, 10 parts of rosin modified phenolic resin, 3 parts of epoxy resin modified acrylic resin, 2 parts of polyvinyl alcohol, chitin
1 part, 3 parts of Vitamin C palmitate, 1 part of methyl naphthalene sulfonic acid sodium, 5 parts of cosolvent, 2 parts of bamboo charcoal powder, 1 part of graphite, 4 parts of pigment resist
2 parts of oxidant, 40 parts of water.
The antioxidant tert-butyl alcohol.
The preparation method of above-mentioned antioxidation environmental protection ink is to comprise the following steps：
A, by rosin modified phenolic resin, epoxy resin modified acrylic resin, polyvinyl alcohol, chitin, Vitamin C palm fibre
Glycerin monostearate, methyl naphthalene sulfonic acid sodium, are added sequentially in reactor, are heated to molten condition, and be stirred continuously；
B, by waterborne polyurethane resin, water soluble alkyd resin, bamboo charcoal powder, graphite, pigment mix, be heated to 120 degree, put
Enter to be stirred in mixer 20 minutes, mixing speed is 400r/min；
C, step a mixture mixed with step b mixture, add cosolvent, modifying agent, antioxidant, carry out
Stirring mixing, temperature control is at 70 degree, and mixing speed is 700r/min, and mixing time is 50 minutes；
D, moisture is added in the mixture that step c is handled well for 5 times, carries out five segmentation grindings, the speed point of grinding
It is not：30/rpm, 50/rpm, 70/rpm, 90/rpm, that is, obtain finished product.
Control group 2
A kind of antioxidation environmental protection ink, is made up of the component of following parts by weight：20 parts of waterborne polyurethane resin, it is water-soluble
8 parts of alkyd resin, 20 parts of rosin modified phenolic resin, 6 parts of epoxy resin modified acrylic resin, 4 parts of polyvinyl alcohol, chitin
3 parts, 5 parts of Vitamin C palmitate, 3 parts of methyl naphthalene sulfonic acid sodium, 10 parts of cosolvent, 4 parts of bamboo charcoal powder, 3 parts of graphite, 8 parts of pigment change
Good dose 3 parts, 5 parts of antioxidant, 50 parts of water.
The modifying agent is made up of the component of following parts by weight：2 parts of acetate, 1 part of cera alba, 1 part of caryophyllus oil, dimension life
It is plain E0.5 parts, 0.3 part of vitamin C, 0.5 part of menthol.
Antioxidant is made up of the component of following parts by weight：2 parts of the tert-butyl alcohol, 4 parts of dicyclopentadiene, 1 part of paracresol, stone
0.5 part of wax, 0.3 part of malic acid, 0.2 part of citric acid.
The preparation method of above-mentioned antioxidation environmental protection ink is to comprise the following steps：
A, by rosin modified phenolic resin, epoxy resin modified acrylic resin, polyvinyl alcohol, chitin, Vitamin C palm fibre
Glycerin monostearate, methyl naphthalene sulfonic acid sodium, are added sequentially in reactor, are heated to molten condition, and be stirred continuously；
B, by waterborne polyurethane resin, water soluble alkyd resin, bamboo charcoal powder, graphite, pigment mix, be heated to 120 degree, put
Enter to be stirred in mixer 30 minutes, mixing speed is 500r/min；
C, step a mixture mixed with step b mixture, add cosolvent, modifying agent, antioxidant, water, enter
Row stirring mixing, temperature control is at 80 degree, and mixing speed is 800r/min, and mixing time is 60 minutes, that is, obtains product.
Table 1 is the present invention and control group performance test
Experiment proves the smooth exquisiteness of ink that the present invention makes, environmental protection is nontoxic, film forming is fast, anti-oxidant.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (8)
1. a kind of antioxidation environmental protection ink, is made up of the component of following parts by weight：10-20 parts of waterborne polyurethane resin, it is water-soluble
Property 4-8 parts of alkyd resin, 10-20 parts of rosin modified phenolic resin, 3-6 parts of epoxy resin modified acrylic resin, polyvinyl alcohol
2-4 parts, 1-3 parts of chitin, 3-5 parts of Vitamin C palmitate, 1-3 parts of methyl naphthalene sulfonic acid sodium, 5-10 parts of cosolvent, bamboo charcoal powder 2-
4 parts, 1-3 parts of graphite, 4-8 parts of pigment, 1-3 parts of modifying agent, 2-5 parts of antioxidant, 40-50 parts of water.
2. antioxidation environmental protection ink according to claim 1, it is characterised in that the component system of preferred following parts by weight
Into：15 parts of waterborne polyurethane resin, 6 parts of water soluble alkyd resin, 15 parts of rosin modified phenolic resin, epoxy resin modification propylene
5 parts of acid resin, 3 parts of polyvinyl alcohol, 2 parts of chitin, 4 parts of Vitamin C palmitate, 2 parts of methyl naphthalene sulfonic acid sodium, 8 parts of cosolvent,
3 parts of bamboo charcoal powder, 2 parts of graphite, 6 parts of pigment, 2 parts of modifying agent, 4 parts of antioxidant, 45 parts of water.
3. antioxidation environmental protection ink according to claim 1 or 2, it is characterised in that the antioxidant composition is by following heavy
The component of amount number is made：10-20 parts of sodium tripolyphosphate, 5-10 parts of sodium sulfite, 3-6 parts of dicyclopentadiene, paracresol 2-4
Part, 5-8 parts of malic acid.
4. antioxidation environmental protection ink according to claim 3, it is characterised in that the modifying agent preferably following parts by weight
Component be made：5 parts of acetate, 2 parts of cera alba, 1 part of caryophyllus oil, 0.9 part of vitamin E, 0.6 part of vitamin C, menthol 0.8
Part.
5. antioxidation environmental protection ink according to claim 1 or 2, it is characterised in that antioxidant is by following parts by weight
Component be made：3-5 parts of the tert-butyl alcohol, 3-6 parts of dicyclopentadiene, 2-4 parts of paracresol, 0.8-1.5 parts of paraffin, 2-3 parts of malic acid,
1-2 parts of citric acid.
6. antioxidation environmental protection ink according to claim 5, it is characterised in that antioxidant by following parts by weight group
Divide and be made：The component of antioxidant preferably following parts by weight is made：4 parts of the tert-butyl alcohol, 5 parts of dicyclopentadiene, 3 parts of paracresol,
1.2 parts of paraffin, 2 parts of malic acid, 1 part of citric acid.
7. a kind of preparation method for preparing any one of the claim 1 or 2 antioxidation environmental protection ink, it is characterised in that including
Following steps：
A, by rosin modified phenolic resin, epoxy resin modified acrylic resin, polyvinyl alcohol, chitin, Vitamin C palmitic acid
Ester, methyl naphthalene sulfonic acid sodium, are added sequentially in reactor, are heated to molten condition, and be stirred continuously；
B, by waterborne polyurethane resin, water soluble alkyd resin, bamboo charcoal powder, graphite, pigment mix, be heated to 120 degree, be put into and stir
Mix and be stirred in machine 20-30 minutes, mixing speed is 400-500r/min；
C, step a mixture mixed with step b mixture, add cosolvent, modifying agent, antioxidant, be stirred
Mixing, temperature control is in 70-80 degree, and mixing speed is 700-800r/min, and mixing time is 50-60 minutes；
D, moisture is added in the mixture that step c is handled well for 5 times, carries out five segmentation grindings, that is, obtain finished product.
8. a kind of preparation method for preparing antioxidation environmental protection ink described in claim 7, it is characterised in that five segmentations are ground
The speed of mill is respectively：30-40/rpm, 50-60/rpm, 70-80/rpm, 90-100/rpm.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107699054A (en) * | 2017-09-25 | 2018-02-16 | 浙江纳美新材料股份有限公司 | A kind of nanometer UV ink-jets mill base and preparation method |
| CN107933128A (en) * | 2017-11-28 | 2018-04-20 | 蚌埠昆仑彩印包装有限公司 | A kind of typography of Packaging Box |
| CN107932985A (en) * | 2017-11-28 | 2018-04-20 | 蚌埠昆仑彩印包装有限公司 | A kind of typography for improving the anti-ageing performance of Packaging Box |
| CN108058472A (en) * | 2017-11-28 | 2018-05-22 | 蚌埠昆仑彩印包装有限公司 | A kind of typography for improving Packaging Box insect prevention performance |
| CN108058501A (en) * | 2017-11-28 | 2018-05-22 | 蚌埠昆仑彩印包装有限公司 | For the typography of Packaging Box |
| CN108068484A (en) * | 2017-11-28 | 2018-05-25 | 蚌埠昆仑彩印包装有限公司 | A kind of environmental printing technique of Packaging Box |
| CN108081775A (en) * | 2017-11-28 | 2018-05-29 | 蚌埠昆仑彩印包装有限公司 | A kind of typography for improving Packaging Box water resistance |
| CN108329498A (en) * | 2018-01-10 | 2018-07-27 | 合肥盛鼎包装材料有限公司 | A kind of production printing technology of PVA film |
| CN108382091A (en) * | 2018-01-10 | 2018-08-10 | 合肥盛鼎包装材料有限公司 | A kind of environmental printing technique of packing case |
| CN108394196A (en) * | 2018-01-10 | 2018-08-14 | 合肥盛鼎包装材料有限公司 | A kind of environmental printing technique of packaging film |
| CN110016258A (en) * | 2019-04-18 | 2019-07-16 | 襄阳金飞环彩色包装有限公司 | A kind of preparation method of anti-oxidant printing ink |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107699054A (en) * | 2017-09-25 | 2018-02-16 | 浙江纳美新材料股份有限公司 | A kind of nanometer UV ink-jets mill base and preparation method |
| CN107933128A (en) * | 2017-11-28 | 2018-04-20 | 蚌埠昆仑彩印包装有限公司 | A kind of typography of Packaging Box |
| CN107932985A (en) * | 2017-11-28 | 2018-04-20 | 蚌埠昆仑彩印包装有限公司 | A kind of typography for improving the anti-ageing performance of Packaging Box |
| CN108058472A (en) * | 2017-11-28 | 2018-05-22 | 蚌埠昆仑彩印包装有限公司 | A kind of typography for improving Packaging Box insect prevention performance |
| CN108058501A (en) * | 2017-11-28 | 2018-05-22 | 蚌埠昆仑彩印包装有限公司 | For the typography of Packaging Box |
| CN108068484A (en) * | 2017-11-28 | 2018-05-25 | 蚌埠昆仑彩印包装有限公司 | A kind of environmental printing technique of Packaging Box |
| CN108081775A (en) * | 2017-11-28 | 2018-05-29 | 蚌埠昆仑彩印包装有限公司 | A kind of typography for improving Packaging Box water resistance |
| CN108329498A (en) * | 2018-01-10 | 2018-07-27 | 合肥盛鼎包装材料有限公司 | A kind of production printing technology of PVA film |
| CN108382091A (en) * | 2018-01-10 | 2018-08-10 | 合肥盛鼎包装材料有限公司 | A kind of environmental printing technique of packing case |
| CN108394196A (en) * | 2018-01-10 | 2018-08-14 | 合肥盛鼎包装材料有限公司 | A kind of environmental printing technique of packaging film |
| CN110016258A (en) * | 2019-04-18 | 2019-07-16 | 襄阳金飞环彩色包装有限公司 | A kind of preparation method of anti-oxidant printing ink |
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