CN107297153A - A kind of scale inhibition carbon membrane and its preparation method and application - Google Patents
A kind of scale inhibition carbon membrane and its preparation method and application Download PDFInfo
- Publication number
- CN107297153A CN107297153A CN201610237219.2A CN201610237219A CN107297153A CN 107297153 A CN107297153 A CN 107297153A CN 201610237219 A CN201610237219 A CN 201610237219A CN 107297153 A CN107297153 A CN 107297153A
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- China
- Prior art keywords
- scale inhibition
- carbon membrane
- water
- parts
- mesh
- Prior art date
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- Pending
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- 230000005764 inhibitory process Effects 0.000 title claims abstract description 94
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 77
- 239000012528 membrane Substances 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title abstract description 12
- 229910001868 water Inorganic materials 0.000 claims abstract description 78
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 76
- 239000002245 particle Substances 0.000 claims abstract description 40
- 239000000463 material Substances 0.000 claims abstract description 23
- 238000000746 purification Methods 0.000 claims abstract description 18
- 238000001914 filtration Methods 0.000 claims abstract description 13
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- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 19
- -1 phospho Chemical class 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
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- 108010010803 Gelatin Proteins 0.000 claims description 4
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 229920000159 gelatin Polymers 0.000 claims description 4
- 239000008273 gelatin Substances 0.000 claims description 4
- 235000019322 gelatine Nutrition 0.000 claims description 4
- 235000011852 gelatine desserts Nutrition 0.000 claims description 4
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- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- 229920001817 Agar Polymers 0.000 claims description 2
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- 229920006221 acetate fiber Polymers 0.000 claims description 2
- ACOGMWBDRJJKNB-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.CC(O)=O ACOGMWBDRJJKNB-UHFFFAOYSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
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- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001720 carbohydrates Chemical class 0.000 claims description 2
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- 239000001913 cellulose Chemical class 0.000 claims description 2
- 229920002678 cellulose Chemical class 0.000 claims description 2
- 229920006037 cross link polymer Polymers 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
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- 238000001125 extrusion Methods 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims description 2
- 229920001903 high density polyethylene Polymers 0.000 claims description 2
- 239000004700 high-density polyethylene Substances 0.000 claims description 2
- 239000000017 hydrogel Substances 0.000 claims description 2
- 229920005615 natural polymer Polymers 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
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- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 229920002379 silicone rubber Polymers 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 239000000022 bacteriostatic agent Substances 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- 239000000084 colloidal system Substances 0.000 abstract description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 10
- 239000013618 particulate matter Substances 0.000 abstract description 9
- 239000007787 solid Substances 0.000 abstract description 9
- 239000005416 organic matter Substances 0.000 abstract description 7
- 125000001309 chloro group Chemical group Cl* 0.000 abstract description 5
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 5
- 230000033228 biological regulation Effects 0.000 abstract description 4
- 239000002131 composite material Substances 0.000 abstract description 4
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- 231100000719 pollutant Toxicity 0.000 abstract description 4
- 238000000465 moulding Methods 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 5
- 229910001425 magnesium ion Inorganic materials 0.000 description 5
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 4
- ZMYKITJYWFYRFJ-UHFFFAOYSA-N 4-oxo-4-(2-phenylethylamino)butanoic acid Chemical compound OC(=O)CCC(=O)NCCC1=CC=CC=C1 ZMYKITJYWFYRFJ-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 4
- 239000001095 magnesium carbonate Substances 0.000 description 4
- ZJAOAACCNHFJAH-UHFFFAOYSA-N phosphonoformic acid Chemical compound OC(=O)P(O)(O)=O ZJAOAACCNHFJAH-UHFFFAOYSA-N 0.000 description 4
- 229920005596 polymer binder Polymers 0.000 description 4
- 239000002491 polymer binding agent Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 229940125717 barbiturate Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000011083 cement mortar Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229960005102 foscarnet Drugs 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 description 2
- 108010064470 polyaspartate Proteins 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 1
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 1
- OQLZINXFSUDMHM-UHFFFAOYSA-N Acetamidine Chemical compound CC(N)=N OQLZINXFSUDMHM-UHFFFAOYSA-N 0.000 description 1
- OGSPWJRAVKPPFI-UHFFFAOYSA-N Alendronic Acid Chemical compound NCCCC(O)(P(O)(O)=O)P(O)(O)=O OGSPWJRAVKPPFI-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 206010017815 Gastric perforation Diseases 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 101150096185 PAAS gene Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 229910006367 Si—P Inorganic materials 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 208000007107 Stomach Ulcer Diseases 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 229940062527 alendronate Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- STNSYZSNIYTNMI-UHFFFAOYSA-N azane;[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methylphosphonic acid Chemical compound N.OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O STNSYZSNIYTNMI-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 210000005258 dental pulp stem cell Anatomy 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 206010016766 flatulence Diseases 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 201000005917 gastric ulcer Diseases 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Abstract
Incrustation scale can be effectively prevented to generate and removed with good chlorine residue the scale inhibition carbon membrane of efficiency the invention discloses a kind of；Fraction includes 80~150 15~35 parts of mesh scale inhibition particle powdered carbons by weight；150~250 15~40 parts of mesh scale inhibition particle powdered carbons；250~350 5~15 parts of mesh scale inhibition particle powdered carbons；10~30 parts of binding agent.The invention also discloses the preparation method of above-mentioned scale inhibition carbon membrane.The scale inhibition carbon membrane of the present invention, using Powdered Activated Carbon as base material composite scale material and other additives, by being formulated allotment, moulding process regulation is prepared from scale inhibition carbon membrane, it has accurate filtering accuracy, water body solid particulate matter can effectively be obstructed, iron rust, silt, bacterium, the insoluble matters such as colloid, also adsorbable chlorine residue, the pollutants such as organic matter, it is simultaneously slow, it is long-acting to discharge scale inhibition composition, effectively solve hot water, treat the scale inhibition problem captured kindly for a long time in water purification field, in Domestic water purifying, Central water purification, commercial water purification, water heater, the field such as HVAC and solar water has extensive, significant application value.
Description
Technical field
The present invention relates to technical field of water purification, more particularly to a kind of scale inhibition carbon membrane and preparation method thereof and should
With being filtered out by carbon membrane, adsorb organic matter, bacterium, colloid and treat pollutant, while release is dynamical
The scale inhibition factor, efficiently suppresses incrustation scale generation.
Background technology
As rapid industrial development water pollution is also increasingly severe, safe drinking water can have been drunk
The problem of being paid high attention to as people, therefore water purification industry develops rapidly, except solving Organic substance in water, thin
Bacterium, colloid etc. pollute beyond the region of objective existence, and incrustation scale is insoluble problem all the time.
Contain calcium, magnesium ion and carbonate, bicarbonate radical, sulfate radical etc. in water.When water reaches necessarily
Temperature, calcium therein, magnesium ion are combined with acid group, and generation calcium carbonate, magnesium carbonate, calcium sulfate etc. are separated out
Precipitation, so as to form incrustation scale.
Calcium ions are more in general water, therefore the main component of incrustation scale is generally calcium salt.
Composition:Calcium carbonate (magnesium).(magnesium) containing calcium bicarbonate in water, these are all solvable, after water boils, two
Person is decomposed into carbonate deposition.
Ca(HCO3)2=CaCO3↓+CO2↑+H2O
Because magnesium hydroxide is than magnesium carbonate more indissoluble, therefore the magnesium carbonate of generation can be converted into magnesium hydroxide.
MgCO3+H20=Mg (OH)2↓+CO2↑
Incrustation scale is broadly divided into hard scale and soft dirty two kinds according to the difference of its Crack cause and shaped state.When
When in water containing impurity such as carbonate colloid, bacterium and organic matters, carbonate is similar in cement mortar
Sandstone, and colloid, bacterium and organic matter etc. are then equivalent to the cement in cement mortar, when water-borne glue body,
The stickum such as bacterium and organic matter and carbonate collective effect, then formd under the conditions of high-temperature boiling and
The hard scale that container (or pipe surface) adheres to each other.Once and the stickum such as colloid, bacterium and organic matter
After being removed, even if calcium, magnesium ion and carbon acid ion concentration are very high in water, also only form into it is pure white and
The loose soft dirt of the carbonate easily removed, without producing hard scale.
Incrustation scale is generally cemented in container or pipe surface.In hot water field, the generation of incrustation scale often causes largely
The problem of, first, hard scale thermal conductivity is very poor, heating surface heat transfer situation can be caused to deteriorate, so as to waste combustion
Material or electric power.Secondly, if incrustation scale is cemented in water heater or boiler inner wall, can also due to expanding with heat and contract with cold and
Unbalance stress, significantly increases the danger of water heater and boiler explosion or even blast.In addition, incrustation scale
It when cementing, also can usually adhere to plurality of heavy metal ion, if the container is used to contain drinking water, have
Heavy metal ion is excessively dissolved in the risk of drinking-water.Incrustation scale fragment enters in stomach can discharge calcium with hydrochloric acid reaction
Magnesium ion and carbon dioxide, the former is the necessary material of calculus, but incrustation scale and calculus are not closed directly
System, the latter can then make one flatulence, feel bad, and gastric ulcer patient is it may also happen that the danger of gastric perforation.
On the other hand, in water purification industry, ultrafiltration water purification technology develops for many years, and technology maturation can effective mistake
The impurity such as solid particulate matter, colloid in drainage body, but ultrafiltration water purification product is then protected and suffered from all the time
Scale removal can not be removed so that it cannot popularizing on a large scale, particularly in the poor north of condition of water quality
Area and southwest cannot get popularization and application.Corresponding to be, RO reverse osmose pure-water technologies are in water purification
Large-scale application is obtained in industry, its superelevation filtering accuracy (0.0001 micron) is benefited from,
All calcium ions and magnesium ions are filtered out, the problem of water outlet will not produce incrustation scale can be adapted in the whole country
Various condition of water quality, detection demonstration has diversity, operability, the higher institute of convincingness in marketing
Popularization and application are also liked with businessman.But water purification machine there is also one it is important the problem of, be in high-hardness water
The stifled film of regional easily generation reverse osmosis membrane, the problem of membrane lifetime is reduced, it is because of high rigidity to trace it to its cause
Water quality area scale crystal forms, is grown on the fenestra of counter-infiltration and causes counter-infiltration to fenestra progress blocking
Membrane lifetime is reduced.
As can be seen here, it is vigorous in the multiple fields mitigation and antiscaling technology market demand such as hot water, water purification.But it is current
There is no suitable technology, product to meet the scale inhibition demand in these fields, industrially the resistance such as conventional Si-P crystal
Dirty agent Chang Yinwei release is too fast, big so as to exist, Use Limitation is short, expensive, potential safety hazard for pharmaceutical quantities
The problems such as big.
Therefore, the present invention discloses a kind of scale inhibition carbon membrane technology, using Powdered Activated Carbon as base material composite scale material
Material and other additives, are prepared from scale inhibition carbon membrane, it has by being formulated allotment, moulding process regulation
Accurate filtering accuracy, can effectively obstruct water body solid particulate matter, iron rust, silt, bacterium, colloid etc.
Insoluble matter, the pollutant such as also adsorbable chlorine residue, organic matter, while slowly, it is long-acting discharge scale inhibition composition,
Effectively solve the problems, such as that hot water, water purification field treat the scale inhibition captured kindly for a long time, Domestic water purifying, Central water purification,
The fields such as commercial water purification, water heater, HVAC and solar water have extensive, significant application value.
The content of the invention
Incrustation scale can be effectively prevented to generate and gone with good chlorine residue it is an object of the invention to provide a kind of
Scale inhibition carbon membrane except efficiency and preparation method thereof.
The problem of in order to solve above-mentioned technology, the technical solution adopted by the present invention is：A kind of scale inhibition carbon membrane,
Include following components by weight：
80~150 15~35 parts of mesh scale inhibition particle powdered carbons；
150~250 15~40 parts of mesh scale inhibition particle powdered carbons；
250~350 5~15 parts of mesh scale inhibition particle powdered carbons；
10~30 parts of binding agent.
It is preferred that, the scale inhibition carbon membrane, by weight including following components：
80~150 18 parts of mesh scale inhibition particle powdered carbons；
150~250 18 parts of mesh scale inhibition particle powdered carbons；
250~350 6 parts of mesh scale inhibition particle powdered carbons；
18 parts of binding agent.
It is preferred that, the binding agent is low density polyethylene, high density polyethylene, poly- second
One kind in alcohol PVA.
Further, the scale inhibition particle powdered carbon is made by following methods：By pure water and ethanol with 10:1
Volume ratio configures mixed liquor, weighs scale inhibition material and is put into the mixed liquor of water and ethanol, is heated to 70 degree simultaneously
Constant temperature is stirred, after it is completely dissolved, and particle powdered carbon is added thereto and soaks and stirs 4 hours, is filtered
Drying was both obtained.
Further, the scale inhibition carbon membrane is made by following methods：In step by pure water and ethanol with 10:1
Volume ratio configuration mixed liquor, weigh scale inhibition material and be put into the mixed liquor of water and ethanol, be heated to 70 degree
And constant temperature is stirred, after it is completely dissolved, particle powdered carbon is added thereto and soaks and stir 4 hours, mistake
After filter drying is both obtained, in addition to, weigh the mixed liquor that a certain amount of additive is dissolved in 110 water and ethanol
(volume ratio 10：1), above-mentioned particle powdered carbon is added thereto and soaks and stirs 4 hours, filtering drying was both
.
It is preferred that, the content of reason again of the scale inhibition material is 0.05~30%.
It is preferred that, the scale inhibition material is organic phospho acid, polyalcohol phosphonate ester, organic phosphonate, organic
One or more of mixtures in Barbiturates, polycarboxylic acid, specifically, including organic phospho acid series：
Amino trident di 2 ethylhexyl phosphonic acid (ATMP), 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP), ethylenediamine tetramethylene phosphine
(EDTMP), polyalcohol phosphonate ester, glycine dimethylene-phosphonic acid (GDMP), DPSC, second two
The methene Alendronate (EDTMPS) of amine four, DTPMP (DTPMPA), DPA,
The phosphorus (AEDP) of ethanamidine base ethylidene two, PBTCA etc.；Organic phosphonate：Sulfophenyl dimethyl pitches phosphonic acids
(SAPDP), AAPA, AACA, ATMP sodium salt, sylvite, HEDP sodium salt etc.；It is organic
Barbiturates：Sodium citrate, sodium alginate, sodium oxalate etc.；Polycarboxylic acid：Polyacrylic acid (PAA),
Sodium Polyacrylate (PAAS), hydrolyzed maleic anhydride (HPMA), copolymer of maleic anhydride and acrylic acid
(MA-AA), acrylic acid and 2- acrylamide-2-methyl propane sulfonics copolymer (AA/AMPS), gather
Epoxysuccinic acid (PESA), poly-aspartate (PASP), copolymer of phosphono carboxylic acid (POCA)
Deng.
It is preferred that, the additive be antibiotic bacteriostat, zeolite, diatomite in powder, polyhexene, polyethylene,
Polyacrylic acid, Sodium Polyacrylate, polyacrylamide, the acetate ethylene copolymer of ethene one, polyvinyl acetate
One acetate fiber, adipic acid, salicylic acid, polyvinyl alcohol, cross-linked polymer, polymethacrylates,
Silicon rubber, agar, the ester of the higher fatty acids of slightly solubility or higher aliphatic, natural polymer gelatin,
Polymer starch, cellulose derivative, the synthesis macromolecule of the carbohydrate such as my primary amine, protein
One or more of mixtures in thing PVP, PEG, polysaccharide hydrogel.
Additive can play carbon membrane support, carbon membrane other function point analysis, the regulation of carbon membrane precision, scale inhibition into
Divide the regulation of the parameters such as rate of release.
Present invention also offers a kind of method for preparing above-mentioned scale inhibition carbon membrane, following steps are specifically included：Take
The scale inhibition particle powdered carbon of different meshes is well mixed with binding agent, is existed by sleeve method or extrusion molding
Sintering is prepared from a temperature of 120~300 DEG C.
It is preferred that, the sintering time is 10 minutes~4 hours.
Therefore, using the technical scheme of the embodiment of the present invention, have the advantages that：The present invention's
Scale inhibition carbon membrane has accurate filtering accuracy, can effectively obstruct water body solid particulate matter, iron rust, silt,
The insoluble matters such as bacterium, colloid, the pollutant such as also adsorbable chlorine residue, organic matter, while playing activated carbon sheet
The efficacy of adsorption for the unique molecular sieve-type that body has, slow, long-acting can discharge the scale inhibition factor, two-way
Effect reaches the generation for suppressing incrustation scale, effectively solves hot water, water purification field and treats the scale inhibition captured kindly for a long time and ask
Topic, in fields such as Domestic water purifying, Central water purification, commercial water purification, water heater, HVAC and solar waters
With extensive, significant application value.
Figure of description
Fig. 1 is scale inhibition carbon membrane technical principle schematic diagram of the present invention.
Embodiment
The present invention will be described in detail with specific examples below below, herein schematic implementation of the invention
Example and explanation are used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1：The preparation of scale inhibition particle powdered carbon
By pure water and ethanol with 10:1 volume ratio configures 110 milliliters of mixed liquors, weighs 4 grams of scale inhibition materials
HPMA is put into the mixed liquor of water and ethanol, is heated to 70 degree and constant temperature stirring, after it is completely dissolved,
100 grams of particle powdered carbons are added thereto and soaks and stirs 4 hours, filtering drying had both obtained HPMA contents and has been
4% scale inhibition particle powdered carbon I.
By pure water and ethanol with 10:1 volume ratio configures 110 milliliters of mixed liquors, weighs 4 grams of scale inhibition materials
PESA is put into the mixed liquor of water and ethanol, is heated to 70 degree and constant temperature stirring, after it is completely dissolved,
100 grams of particle powdered carbons are added thereto and soaks and stirs 4 hours, filtering drying is stand-by, weighs 4 grams of days
Right gelatin is dissolved in the mixed liquor (volume ratio 10 of 110 water and ethanol：1) above-mentioned particle powdered carbon, is added it
Middle to soak and stir 4 hours, filtering drying had both obtained the scale inhibition particle powdered carbon II that PESA contents are 4%.
By pure water and ethanol with 10:1 volume ratio configures 110 milliliters of mixed liquors, weighs 10 grams of scale inhibition materials
PBTCA is put into the mixed liquor of water and ethanol, is heated to 70 degree and constant temperature stirring, is treated that it is completely dissolved
Afterwards, 100 grams of particle powdered carbons are added thereto and soak and stir 4 hours, filtering drying is stand-by, weighs 10
Gram natural gelatin is dissolved in the mixed liquor (volume ratio 10 of 110 water and ethanol：1), above-mentioned particle powdered carbon is added
Enter wherein to soak and stir 4 hours, filtering drying had both obtained the scale inhibition particle powdered carbon that PBTCA contents are 10%
III。
Embodiment 2：Scale inhibition carbon membrane B1 preparation
Respectively by 90 grams of 80-150 mesh, 90 grams of 150-250 mesh, 30 grams of 250-350 mesh composite scales
Particle powdered carbon (is produced, scale inhibition material HPMA weight contents by Yin Jia Environmental Protection Technology Co., Ltd of Huizhou City
Scale inhibition particle powdered carbon I for 4%) and 90 grams of LDPE binding agents insert in compounding jar and stir and evenly mix, will
This compound powder is added to be compacted in grinding tool by compacting machine, is toasted 2 hours at 170 DEG C, and demoulding cutting was both
Obtain scale inhibition carbon membrane B1 (sizes：External diameter=63mm, internal diameter=35mm, length=240mm).
Comparative example 2：Common carbon membrane A1 preparation
Respectively by 90 grams of 80-150 mesh, 90 grams of 150-250 mesh, 30 grams of 250-350 mesh actives
Powdered carbon and 90 grams of LDPE binding agents are inserted in compounding jar and stirred and evenly mixed, and this compound powder is added in grinding tool
Be compacted by compacting machine, at 170 DEG C toast 2 hours, the demoulding cutting both common carbon membrane A1 (sizes：
External diameter=63mm, internal diameter=35mm, length=240mm).
Embodiment 3：Scale inhibition carbon membrane B2 preparation
Respectively by 90 grams of 80-150 mesh, 110 grams of 150-250 mesh, 40 grams of 250-350 mesh composite scales
Particle powdered carbon (is produced, scale inhibition material PESA weight contents by Yin Jia Environmental Protection Technology Co., Ltd of Huizhou City
Scale inhibition particle powdered carbon II for 4%) and 60 grams of LDPE high polymer binders insert in compounding jar and stir mixed
It is even, this compound powder is added and is compacted in grinding tool by compacting machine, is toasted 2 hours at 190 DEG C, the demoulding
Cutting both obtains scale inhibition carbon membrane B2 (sizes：External diameter=63mm, internal diameter=35mm, length=240mm).
Comparative example 3：Common carbon membrane A2 preparation
Respectively by 90 grams of 80-150 mesh, 110 grams of 150-250 mesh, 40 grams of 250-350 mesh actives
Powdered carbon and 60 grams of LDPE high polymer binders are inserted in compounding jar and stirred and evenly mixed, and this compound powder is added
Be compacted in grinding tool by compacting machine, at 190 DEG C toast 2 hours, the demoulding cutting both common carbon membrane A2
(size：External diameter=63mm, internal diameter=35mm, length=240mm).
Embodiment 4：Scale inhibition carbon membrane B3 preparation
Respectively by 100 grams of 80-150 mesh, 130 grams of 150-250 mesh, the compound resistance of 40 grams of 250-350 mesh
Dirty particle powdered carbon (is produced, scale inhibition material PBTCA weight contains by Yin Jia Environmental Protection Technology Co., Ltd of Huizhou City
Measure as 10% scale inhibition particle powdered carbon III) and 30 grams of LDPE high polymer binders insert in compounding jar and stir mixed
It is even, this compound powder is added and is compacted in grinding tool by compacting machine, is toasted 2 hours at 190 DEG C, the demoulding
Cutting both obtains scale inhibition carbon membrane B3 (sizes：External diameter=63mm, internal diameter=35mm, length=240mm).
Comparative example 4：Common carbon membrane A3 preparation
100 grams of 80-150 mesh, 130 grams of 150-250 mesh, 40 grams of 250-350 mesh are commonly lived respectively
Property powdered carbon and 30 grams of LDPE high polymer binders are inserted in compounding jar and stirred and evenly mixed, and this compound powder is added
Enter in grinding tool and to be compacted by compacting machine, toasted 2 hours at 190 DEG C, demoulding cutting both common carbon membrane
A3 (sizes：External diameter=63mm, internal diameter=35mm, length=240mm).
Embodiment 5：A1, A2, A3 and B1, B2, B3 are to insoluble matters such as solid particulate matter, colloids
Remove efficiency
Using underground water as source water, under 2.0bar pressure by the common carbon membrane A1 encapsulated, A2,
A3 and scale inhibition B1, B2, B3, gathered data obtain the insoluble matters such as solid particulate matter, colloid respectively
Remove efficiency.
Table one：Active carbon stick is detected to the removal efficiency of the insoluble matters such as solid particulate matter, colloid and contrasted
Data above can be seen that common carbon membrane can effectively obstruct water body solid particulate matter, iron rust, silt,
The insoluble matters such as bacterium, colloid, with the addition of the scale inhibition carbon membrane of scale inhibition material to solid particulate matter, iron rust, mud
The insoluble matters such as sand, bacterium, colloid have equal removal effect.
Embodiment 6：A1, A2, A3 and B1, B2, B3 scale inhibition efficacy test
Use environment on the spot is simulated in configuration hard water TDS630, discontinuous water flowing 5T is carried out and (often flows 10L
Water stops 5 minutes), flow is constant (4L/min), uses scale inhibition carbon membrane and common carbon film water flowing, water intaking
0L, 1000L, 2000L, 3000L, 4000L, 5000L scale inhibition efficiency are detected after sample is boiled respectively.
Hard water collocation method：24.3g calcium chloride+11.12g magnesium chloride+24.3g sodium acid carbonate+80L running water；
Hardness：Calcium value：110ppm；Total alkalinity：3.5m mol/L；TDS:630ppm；Electrical conductivity：
1530us/cm。
Table two：Different carbon membrane scale inhibition test comparisons
Data above, which can be seen that scale inhibition carbon membrane, can effectively suppress the formation of incrustation scale, and can be slow, long-acting
The scale inhibition factor is discharged, effect of long-acting scale inhibition is reached, greatly improves the scale inhibition life-span of scale inhibition carbon membrane.
The technical scheme provided above the embodiment of the present invention is described in detail, used herein
Specific case is set forth to the principle and embodiment of the embodiment of the present invention, and above example is said
It is bright to be only applicable to help the principle for understanding the embodiment of the present invention；Simultaneously for the general technology people of this area
Member, according to the embodiment of the present invention, will change in embodiment and application,
In summary, this specification content should not be construed as limiting the invention.
Claims (10)
1. a kind of scale inhibition carbon membrane, it is characterised in that by weight including following components：
80~150 15~35 parts of mesh scale inhibition particle powdered carbons；
150~250 15~40 parts of mesh scale inhibition particle powdered carbons；
250~350 5~15 parts of mesh scale inhibition particle powdered carbons；
10~30 parts of binding agent.
2. a kind of scale inhibition carbon membrane according to claim 1, it is characterised in that by weight including following
Component：80~150 18 parts of mesh scale inhibition particle powdered carbons；
150~250 18 parts of mesh scale inhibition particle powdered carbons；
250~350 6 parts of mesh scale inhibition particle powdered carbons；
18 parts of binding agent.
3. a kind of scale inhibition carbon membrane according to claim 1 or 2, it is characterised in that：The binding agent is
One kind in LDPE, HDPE, PVA.
4. a kind of scale inhibition carbon membrane according to claim 1 or 2, it is characterised in that the scale inhibition particle charcoal
Powder is made by following methods：By pure water and ethanol with 10:1 volume ratio configuration mixed liquor, weighs scale inhibition
Material is put into the mixed liquor of water and ethanol, is heated to 70 degree and constant temperature stirring, after it is completely dissolved,
Particle powdered carbon is added thereto and soaks and stirs 4 hours, filtering drying was both obtained.
5. a kind of scale inhibition carbon membrane according to claim 4, it is characterised in that the scale inhibition carbon membrane is by following
Method is made：In step by pure water and ethanol with 10:1 volume ratio configuration mixed liquor, weighs scale inhibition material
Material is put into the mixed liquor of water and ethanol, is heated to 70 degree and constant temperature stirring, after it is completely dissolved,
Particle powdered carbon is added thereto and soaks and stirs 4 hours, after filtering drying is both obtained, in addition to, claim
A certain amount of additive is taken to be dissolved in the mixed liquor (volume ratio 10 of 110 water and ethanol：1), will be above-mentioned
Particle powdered carbon, which is added thereto, to be soaked and stirs 4 hours, and filtering drying was both obtained.
6. a kind of scale inhibition carbon membrane according to claim 5, it is characterised in that：The weight of the scale inhibition material
Content is 0.05~30%.
7. a kind of scale inhibition carbon membrane according to claim 5 or 6, it is characterised in that：The scale inhibition material is
One kind in organic phospho acid, polyalcohol phosphonate ester, organic phosphonate, organic acid salt, polycarboxylic acid
Or several mixtures.
8. a kind of scale inhibition carbon membrane according to claim 5 or 6, it is characterised in that：The additive is anti-
Bacterium bacteriostatic agent, zeolite, diatomite in powder, polyhexene, polyethylene, polyacrylic acid, Sodium Polyacrylate,
Polyacrylamide, the acetate ethylene copolymer of ethene one, the acetate fiber of polyvinyl acetate one, adipic acid,
Salicylic acid, polyvinyl alcohol, cross-linked polymer, polymethacrylates, silicon rubber, agar, indissoluble
The higher fatty acids of property or the ester of higher aliphatic, natural polymer gelatin, my primary amine, albumen
The polymer starch of the carbohydrate such as matter, cellulose derivative, synthetic high polymer PVP, PEG,
One or more of mixtures in polysaccharide hydrogel.
9. a kind of method of the scale inhibition carbon membrane prepared as described in claim 1~8 any one, it is characterised in that
Comprise the following steps：Take the scale inhibition particle powdered carbon of different meshes to be well mixed with binding agent, pass through sleeve
Method or extrusion molding are sintered 10 minutes~4 hours at a temperature of 120~300 DEG C and are prepared from.
10. scale inhibition carbon membrane as described in claim 1~8 any one is in the application in water purification field.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002018487A (en) * | 2000-07-10 | 2002-01-22 | Miura Co Ltd | Water treatment method for boiler system |
| CN1509257A (en) * | 2002-01-31 | 2004-06-30 | ���弼����˾ | Microporous filter media, filtration system containing same and method of making and using |
| US7112280B2 (en) * | 2002-08-12 | 2006-09-26 | 3M Innovative Properties Company | Gas porous polymer filter and methods of use |
| CN103167940A (en) * | 2010-11-04 | 2013-06-19 | 3M创新有限公司 | Method of forming filter elements |
| CN204661419U (en) * | 2015-03-31 | 2015-09-23 | 广州市韩天然电子科技有限公司 | A kind of environment-friendly type scale inhibitor ball sintered with gac |
| CN105148844A (en) * | 2015-09-30 | 2015-12-16 | 江苏通瑞环保科技发展有限公司 | Preparing method for activated carbon filter element material with sterilization function |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102489075B (en) * | 2011-11-29 | 2013-12-11 | 无锡格瑞普尔膜科技有限公司 | Method for preparing deep filtering medium having selective filtering capability |
| CN103435123B (en) * | 2013-08-16 | 2014-12-17 | 浙江朝晖过滤技术股份有限公司 | Multi-grade activated carbon sintered filter element and manufacturing method thereof |
| CN103480204B (en) * | 2013-09-25 | 2015-05-13 | 厦门建霖工业有限公司 | Gradient type multiple-structure sintering carbon rod and preparation method thereof |
-
2016
- 2016-04-15 CN CN201610237219.2A patent/CN107297153A/en active Pending
- 2016-11-14 WO PCT/CN2016/105786 patent/WO2017177673A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002018487A (en) * | 2000-07-10 | 2002-01-22 | Miura Co Ltd | Water treatment method for boiler system |
| CN1509257A (en) * | 2002-01-31 | 2004-06-30 | ���弼����˾ | Microporous filter media, filtration system containing same and method of making and using |
| US7112280B2 (en) * | 2002-08-12 | 2006-09-26 | 3M Innovative Properties Company | Gas porous polymer filter and methods of use |
| CN103167940A (en) * | 2010-11-04 | 2013-06-19 | 3M创新有限公司 | Method of forming filter elements |
| CN204661419U (en) * | 2015-03-31 | 2015-09-23 | 广州市韩天然电子科技有限公司 | A kind of environment-friendly type scale inhibitor ball sintered with gac |
| CN105148844A (en) * | 2015-09-30 | 2015-12-16 | 江苏通瑞环保科技发展有限公司 | Preparing method for activated carbon filter element material with sterilization function |
Non-Patent Citations (1)
| Title |
|---|
| 全国工业表面活性剂生产技术协作组和全国工业表面活性剂中心: "《2000工业表面活性剂技术经济文集》", 31 October 2000 * |
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| CN109316965A (en) * | 2018-10-22 | 2019-02-12 | 华中科技大学 | Application of organic phosphonates as forward osmosis extraction solutes and forward osmosis devices |
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| CN111634988A (en) * | 2020-05-27 | 2020-09-08 | 惠州市银嘉环保科技有限公司 | Reactive Oxygen Species (ROS) purification membrane and preparation method and application thereof |
| CN111659256A (en) * | 2020-06-20 | 2020-09-15 | 深圳市优福环保科技有限公司 | Scale inhibition filter membrane and preparation method thereof |
| CN114349138A (en) * | 2022-01-11 | 2022-04-15 | 佛山市芯耀环保科技有限公司 | Scale-inhibiting antibacterial material and preparation method thereof |
| CN114349106A (en) * | 2022-01-11 | 2022-04-15 | 佛山市芯耀环保科技有限公司 | Scale inhibition antibacterial activated carbon rod |
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