CN107286711A - A kind of anti-corrosion type coating composition - Google Patents
A kind of anti-corrosion type coating composition Download PDFInfo
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- CN107286711A CN107286711A CN201710638764.7A CN201710638764A CN107286711A CN 107286711 A CN107286711 A CN 107286711A CN 201710638764 A CN201710638764 A CN 201710638764A CN 107286711 A CN107286711 A CN 107286711A
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- 238000005260 corrosion Methods 0.000 title claims abstract description 29
- 239000008199 coating composition Substances 0.000 title claims abstract description 20
- 239000007787 solid Substances 0.000 claims abstract description 38
- 239000000654 additive Substances 0.000 claims abstract description 35
- 230000000996 additive effect Effects 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 13
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 12
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920002635 polyurethane Polymers 0.000 claims abstract description 12
- 239000004814 polyurethane Substances 0.000 claims abstract description 12
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract 4
- -1 polyethylene Polymers 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical group 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 230000002421 anti-septic effect Effects 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 30
- 239000003973 paint Substances 0.000 description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- 238000010276 construction Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 2
- 230000003260 anti-sepsis Effects 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 229920002681 hypalon Polymers 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229920001585 atactic polymer Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of anti-corrosion type coating composition, including solid type component A, water solubility component B and additive composition, the solid type component A, water solubility component B and additive proportioning are 1：2~4：0.01；The solid type component A includes：40~80 parts of epoxy resin, 3~6 parts of polyurethane, 1~2 part of coupling agent, 5~10 parts of talcum powder；The water-soluble component B includes 60~80 parts of HCPE, 10~15 parts of butyl acrylate, 10~20 parts of methacrylic acid, 4~8 parts of styrene, 5~10 parts of fluororesin, 5~15 parts of nano titanium oxide.A kind of anti-corrosion type coating composition that the present invention is provided, it is easily manufactured, it is divided into solid-liquid binary states, easily transport storage, and with very strong antiseptic property.
Description
Technical field
The present invention relates to chemical technology field, and in particular to a kind of anti-corrosion type coating composition.
Background technology
Corrosion can bring about great losses.The annual economic loss caused by corrosion in the current whole world about at 1,000,000,000,000 dollars,
About 6 times of the natural calamity summation such as earthquake, floods, typhoon, loss of the U.S. in 2000 caused by corrosion reaches more than 3,000 hundred million
Dollar, and this numeral through measuring and calculating China in 2001 is up to 400,000,000,000 RMB, it is seen that the protection of corrosion is particularly significant.Mention
Anticorrosion, it is impossible to do not mention coating and coating antiseptic.Because, it is alternative wide in variety first, widely used, coating
The erosion of environment can be protected it from metal surface, while assigning the effects such as attractive in appearance, camouflage；Next to that easy construction, is fitted
Ying Xingguang, is not constrained by device area, shape, recoats and repair convenient；Last anticorrosion with coat can be with other anticorrosive measures
It is used in combination, just can obtains more perfect corrosion protection system.The anticorrosion of countries in the world facts have proved：Paint coatings anticorrosion is most
Effectively, it is most economical, using most common method.
Since 1960s, due to heavy construction appearance and people to anticorrosive paint application conditions, use when
Desired continuous improvement is imitated, the formulation of heavy antisepsis is occurred in that.Anticorrosive paint refers to apply and have under severe corrosive environment
There is the coating of long-acting service life, it has both sides implication：One refers to that corrosive environment is severe, and two refer to protect long lifespan.It is existing
Anticorrosive paint is developed into there is provided wide space for industrial technology.Metal and theoretical, the modern surface skill of nonmetallic protection
The development of the modern science and technology such as art, emerging synthetic material, rust resisting pigment, advanced coating equipment, modern detecting is attached most importance to
Anticorrosive paint provides good technology material conditions, has promoted the progress and development of anticorrosive paint.It can be said that heavy antisepsis is applied
The development level of material indicates that the development level of a national anticorrosive paint even indicates a national Sci-Tech Level.
In recent years, anticorrosive paint had been achieved for rapid progress, and important function is served to the object protection under severe rugged environment, but
For current kind, also far from the requirement for meeting defense under different corrosive environments, while anticorrosive paint is present
Product it is supporting with seriation problem, reduce production and the use cost problem of anticorrosive paint, meet increasingly stricter ring
Guaranteed request problem etc. all annoyings the development of current anticorrosive paint.
HCPE (HCPE) is the chlorinity in atactic polymer of the polyethylene through chlorination, its molecule
Up to 60%~70%, double bond is free of in HCPE molecule, and chlorine atom is in random distribution, except adhering to
Outside the good water resistance of polyethylene, also with good weatherability, ozone resistance, anti-flammability, chemical-resistant and certain
Oil resistivity.HCPE resins are low for the permeability of steam, oxygen and ion, therefore, it is possible to effectively prevent oozing for corrosive medium
Thoroughly, so as to play good isolation closed protective effect to ground.In addition, HCPE resins have preferable cost performance, construction party
Just, application is not subject to seasonal restrictions, low-temperature curable, and the features such as recoatability is good, HCPE anticorrosive coatings have embodied a concentrated reflection of alkyd tune
With the advantage of paint, synthetic enamel, epoxy resin coating, chlorinated rubber paint and chlorosulfonated polyethylene paint, chlorinated rubber, phenol can be replaced
The anticorrosive paints such as aldehyde, epoxy-ester, chlorosulfonated polyethylene.But highly-chlorinated polyethylene belongs to thermoplastic resin, its film is more crisp, attachment
Power and less stable.Therefore flexible resin is usually added in actual application to improve the performance of film, improve film
Weather resistance (Bao Se and Gloss Retention) while improving adhesive force and the physical and mechanical properties such as gloss of film.Such as add alkyd
Resin, acrylic resin, chlorinated paraffin and plasticizer etc. are modified.
The applicant has applied for Patent No. 201210480897.3, aqueous acrylic modified high chlorination in 2012.11.23
Some problems, such as anti-corrosion more or less occur in the preparation method of polyethylene anti-corrosion coating, the anticorrosive paint in use
Time, weatherability, corrosion resistance, stain resistance be not good soon, it is therefore desirable to a kind of more excellent anticorrosive paint.
The content of the invention
It is an object of the invention to provide a kind of anti-corrosion type coating composition, solve one in above-mentioned prior art problem or
It is multiple.
According to an aspect of the present invention, a kind of anti-corrosion type coating composition, including solid type component A, water-soluble component B
With additive composition, the solid type component A, water solubility component B and additive proportioning are 1：2~4：0.01；The solid
Type component A includes：40~80 parts of epoxy resin, 3~6 parts of polyurethane, 1~2 part of coupling agent, 5~10 parts of talcum powder；It is described water-soluble
Property component B include 60~80 parts of HCPE, 10~15 parts of butyl acrylate, 10~20 parts of methacrylic acid, benzene
4~8 parts of ethene, 5~10 parts of fluororesin, 5~15 parts of nano titanium oxide.
A kind of anti-corrosion type coating composition that the present invention is provided, it is easily manufactured, it is divided into solid-liquid binary states, easily transport storage,
And with very strong antiseptic property.
In some embodiments, the additive is
In some embodiments, the coupling agent in the solid type component A is alkene based composition, including following homopolymerization
Polyethylene, polyethylene copolymer, HOPP, COPP, block copolymerization polypropylene or silane grafted polyethylene.
Embodiment
Embodiment 1
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：2：0.01；
Solid type component A includes：40 parts of epoxy resin, 3 parts of polyurethane, 1 part of coupling agent, 5 parts of talcum powder；
Water-soluble component B includes 60 parts of HCPE, 10 parts of butyl acrylate, 10 parts of methacrylic acid, benzene
4 parts of ethene, 5 parts of fluororesin, 5 parts of nano titanium oxide.
Additive is 5 parts.
Embodiment 2
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：2：0.01；
Solid type component A includes：60 parts of epoxy resin, 4.5 parts of polyurethane, 1.5 parts of coupling agent, 7.5 parts of talcum powder；
Water-soluble component B includes 7 parts of HCPE, 12.5 parts of butyl acrylate, 15 parts of methacrylic acid, benzene
6 parts of ethene, 7.5 parts of fluororesin, 10 parts of nano titanium oxide.
Additive is 6.5 parts.
Embodiment 3
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：2：0.01；
Solid type component A includes：80 parts of epoxy resin, 6 parts of polyurethane, 2 parts of coupling agent, 10 parts of talcum powder；
Water-soluble component B includes 80 parts of HCPE, 15 parts of butyl acrylate, 20 parts of methacrylic acid, benzene
8 parts of ethene, 10 parts of fluororesin, 15 parts of nano titanium oxide.
Additive is 10 parts.
Embodiment 4
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：3：0.01；
Solid type component A includes：40 parts of epoxy resin, 3 parts of polyurethane, 1 part of coupling agent, 5 parts of talcum powder；
Water-soluble component B includes 60 parts of HCPE, 10 parts of butyl acrylate, 10 parts of methacrylic acid, benzene
4 parts of ethene, 5 parts of fluororesin, 5 parts of nano titanium oxide.
Additive is 5 parts.
Embodiment 5
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：3：0.01；
Solid type component A includes：60 parts of epoxy resin, 4.5 parts of polyurethane, 1.5 parts of coupling agent, 7.5 parts of talcum powder；
Water-soluble component B includes 7 parts of HCPE, 12.5 parts of butyl acrylate, 15 parts of methacrylic acid, benzene
6 parts of ethene, 7.5 parts of fluororesin, 10 parts of nano titanium oxide.
Additive is 6.5 parts.
Embodiment 6
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：3：0.01；
Solid type component A includes：80 parts of epoxy resin, 6 parts of polyurethane, 2 parts of coupling agent, 10 parts of talcum powder；
Water-soluble component B includes 80 parts of HCPE, 15 parts of butyl acrylate, 20 parts of methacrylic acid, benzene
8 parts of ethene, 10 parts of fluororesin, 15 parts of nano titanium oxide.
Additive is 10 parts.
Embodiment 7
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：4：0.01；
Solid type component A includes：40 parts of epoxy resin, 3 parts of polyurethane, 1 part of coupling agent, 5 parts of talcum powder；
Water-soluble component B includes 60 parts of HCPE, 10 parts of butyl acrylate, 10 parts of methacrylic acid, benzene
4 parts of ethene, 5 parts of fluororesin, 5 parts of nano titanium oxide.
Additive is 5 parts.
Embodiment 8
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：4：0.01；
Solid type component A includes：60 parts of epoxy resin, 4.5 parts of polyurethane, 1.5 parts of coupling agent, 7.5 parts of talcum powder；
Water-soluble component B includes 7 parts of HCPE, 12.5 parts of butyl acrylate, 15 parts of methacrylic acid, benzene
6 parts of ethene, 7.5 parts of fluororesin, 10 parts of nano titanium oxide.
Additive is 6.5 parts.
Embodiment 9
A kind of anti-corrosion type coating composition, configuration solid type component A, water solubility component B and additive are constituted, it is above-mentioned in,
Solid type component A, water solubility component B and additive proportioning are 1：4：0.01；
Solid type component A includes：80 parts of epoxy resin, 6 parts of polyurethane, 2 parts of coupling agent, 10 parts of talcum powder；
Water-soluble component B includes 80 parts of HCPE, 15 parts of butyl acrylate, 20 parts of methacrylic acid, benzene
8 parts of ethene, 10 parts of fluororesin, 15 parts of nano titanium oxide.
Additive is 10 parts.
Embodiment 10
For not additivated component in embodiment 9.
Embodiment 11
For the product in the applicant 201210480897.3.
Experimental data compares
Experimental Comparison is carried out to the product in 1~embodiment of embodiment 11 with 10% (acid, alkali and inorganic salts) respectively；Implement
Product in 1~embodiment of example 11 is non-foaming, do not fall off；
Retention time, embodiment 1：60~65 days；Embodiment 2：62~67 days；Embodiment 3：67~70；
Embodiment 4:62~66 days；Embodiment 5:68~71 days；Embodiment 6:72~75 days；
Embodiment 7:71~76 days；Embodiment 8:72~77 days；Embodiment 9:71~79 days；
Embodiment 10:45~50 days；Embodiment 11,30~35 days.
Therefore, it is resistance to by data above contrast it is known that the corrosion resistant performance of this product is significantly better than equivalents on the market
Rotten performance is good.
Described above is only the preferred embodiment of the present invention, it is noted that to those skilled in the art, not
On the premise of departing from the invention design, some similar modification and improvement can also be made, these also should be regarded as the present invention
Protection domain within.
Claims (3)
1. a kind of anti-corrosion type coating composition, it is characterised in that including solid type component A, water solubility component B and additive group
Into the solid type component A, water solubility component B and additive proportioning are 1：2~4：0.01；The solid type component A bags
Include：40~80 parts of epoxy resin, 3~6 parts of polyurethane, 1~2 part of coupling agent, 5~10 parts of talcum powder；The water-soluble component B bags
Include 60~80 parts of HCPE, 10~15 parts of butyl acrylate, 10~20 parts of methacrylic acid, styrene 4~8
Part, 5~10 parts of fluororesin, 5~15 parts of nano titanium oxide.
2. a kind of anti-corrosion type coating composition according to claim 1, it is characterised in that the additive is
3. a kind of anti-corrosion type coating composition according to claim 1, it is characterised in that in the solid type component A
Coupling agent is alkene based composition, including following homopolymerisation polyethylene, polyethylene copolymer, HOPP, COPP, block
COPP or silane grafted polyethylene.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710638764.7A CN107286711A (en) | 2017-07-31 | 2017-07-31 | A kind of anti-corrosion type coating composition |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710638764.7A CN107286711A (en) | 2017-07-31 | 2017-07-31 | A kind of anti-corrosion type coating composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108864836A (en) * | 2018-08-01 | 2018-11-23 | 苏州嘉迈德电子科技有限公司 | A kind of metal product anticorrosive paint and anti-corrosion metal plate |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863854A (en) * | 2012-10-18 | 2013-01-09 | 山东聊城齐鲁特种涂料有限责任公司 | High chlorinated potyethlene anti-corrosive paint and preparation method thereof |
| CN102993836A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Preparation method of novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
| CN102993837A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
| CN103894107A (en) * | 2012-12-28 | 2014-07-02 | 南通市晗泰化工有限公司 | Active surfactant containing no APEO |
-
2017
- 2017-07-31 CN CN201710638764.7A patent/CN107286711A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863854A (en) * | 2012-10-18 | 2013-01-09 | 山东聊城齐鲁特种涂料有限责任公司 | High chlorinated potyethlene anti-corrosive paint and preparation method thereof |
| CN102993836A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Preparation method of novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
| CN102993837A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
| CN103894107A (en) * | 2012-12-28 | 2014-07-02 | 南通市晗泰化工有限公司 | Active surfactant containing no APEO |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108864836A (en) * | 2018-08-01 | 2018-11-23 | 苏州嘉迈德电子科技有限公司 | A kind of metal product anticorrosive paint and anti-corrosion metal plate |
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Application publication date: 20171024 |