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CN107267312B - Clothing cleaning agent and preparation method thereof - Google Patents

Clothing cleaning agent and preparation method thereof Download PDF

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Publication number
CN107267312B
CN107267312B CN201710502442.XA CN201710502442A CN107267312B CN 107267312 B CN107267312 B CN 107267312B CN 201710502442 A CN201710502442 A CN 201710502442A CN 107267312 B CN107267312 B CN 107267312B
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clothing
percent
cleaning agent
mixture
mass
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CN107267312A (en
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石建军
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Shenzhen Jiewang Fine Chemical Technology Co ltd
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Shenzhen Jiewang Fine Chemical Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5027Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/20Water-insoluble oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
    • C11D7/242Hydrocarbons branched
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
    • C11D7/245Hydrocarbons cyclic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/28Organic compounds containing halogen
    • C11D7/30Halogenated hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a clothing cleaning agent which comprises the following components in percentage by mass: 10 to 15 percent of No. 6 solvent oil, 20 to 25 percent of n-bromopropane, 4 to 8 percent of tetrachloroethylene, 15 to 20 percent of dichloromethane, 4 to 8 percent of cyclohexane, 25 to 30 percent of isohexane and 5 to 10 percent of silica gel powder; and lemon essence accounting for 0.25-0.35 percent of the total mass of the components. The clothing cleaning agent can also be mixed with liquefied petroleum gas to obtain clothing cleaning spray, so that the clothing cleaning agent is more convenient to use. The clothing cleaning agent is particularly suitable for western-style clothes, overcoat, full dress, silk clothing, hat and clothes which are not suitable for frequent cleaning and only need to be cleaned locally, such as hat and hat clothes, and the like, can effectively remove oil stains and other stubborn stains remained on the clothing, has good cleaning effect, does not damage clothing fibers, has wide raw material sources, has little damage to the environment, and completely meets the national environmental protection requirement. The invention also discloses a preparation method of the clothing cleaning agent.

Description

Clothing cleaning agent and preparation method thereof
Technical Field
The invention belongs to the technical field of cleaning preparations, and particularly relates to a clothing cleaning agent and a preparation method thereof.
Background
In daily life, people often wear western-style clothes, overcoat, full dress, silk clothes, hats, ties and other washing fabrics, and the cloth of the washing fabrics is generally real silk and artificial fiber, so that the washing fabrics are not suitable for frequent washing, otherwise, the bad phenomena of clothes deformation, silk drawing and the like are easily caused; however, after long-term use, greasy dirt or other stubborn stains are inevitably produced, and people generally adopt a local cleaning mode to treat the stains.
At present, partial cleaning agents can be used for locally cleaning the clothes made of the materials, but the formula of the cleaning agents or products is not advanced enough, and raw materials have certain pollution or harm to the environment; or the cleaning effect is not ideal, and the reaction is not rapid enough; or the dirt-removing ability is obvious, but the material of the clothes is damaged to a certain extent.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a clothing detergent and a preparation method thereof.
In order to achieve the purpose of the invention, the invention adopts the following technical scheme:
a clothing cleaner comprises the following components in percentage by mass:
Figure BDA0001333994260000011
and lemon essence accounting for 0.25-0.35 percent of the total mass of the components.
Further, the clothing cleaning agent comprises the following components in percentage by mass:
Figure BDA0001333994260000021
and lemon essence accounting for 0.25 percent of the total mass of the components.
Further, the clothing cleaning agent comprises the following components in percentage by mass:
Figure BDA0001333994260000022
and lemon essence accounting for 0.31 percent of the total mass of the components.
Further, the clothing cleaning agent comprises the following components in percentage by mass:
Figure BDA0001333994260000023
Figure BDA0001333994260000031
and lemon essence accounting for 0.35 percent of the total mass of the components.
Further, the clothing detergent also comprises liquefied petroleum gas; the mass ratio of the sum of the mass of the No. 6 solvent oil, the n-bromopropane, the tetrachloroethylene, the dichloromethane, the cyclohexane, the isohexane, the silica gel powder and the lemon essence to the mass of the liquefied petroleum gas is 2.3: 1-2.5: 1.
Another object of the present invention is to provide a method for preparing a clothing detergent as described above, comprising:
step S1, mixing and uniformly stirring 6# solvent oil, tetrachloroethylene, dichloromethane and silica gel powder to obtain a first mixture;
step S2, adding n-bromopropane and lemon essence into the first mixture, and uniformly stirring to obtain a second mixture;
step S3, mixing cyclohexane and isohexane and stirring uniformly to obtain a third mixture;
and step S4, mixing the second mixture and the third mixture and stirring uniformly.
Further, the preparation method further comprises the following steps: and S5, mixing the liquid obtained in the step S4 and the liquefied petroleum gas according to the mass ratio of 2.3: 1-2.5: 1 to form a spray.
The clothing cleaning agent is obtained by reasonably preparing the components and the using amount of the components, is particularly suitable for western-style clothes, overcoat, full dress, silk clothes, hats, ties and other clothing which are not suitable for frequent cleaning and only need to be locally cleaned, and can effectively remove stubborn stains remained on the clothing, and has good cleaning effect; compared with similar products in the prior art, the clothing cleaning agent provided by the invention does not damage clothing fibers, and the raw materials of the clothing cleaning agent have little damage to the environment, so that the clothing cleaning agent completely meets the national environmental protection requirements.
Detailed Description
Hereinafter, embodiments of the present invention will be described in detail. This invention may, however, be embodied in many different forms and should not be construed as limited to the specific embodiments set forth herein. Rather, these embodiments are provided to explain the principles of the invention and its practical application to thereby enable others skilled in the art to understand the invention for various embodiments and with various modifications as are suited to the particular use contemplated.
It will be understood that, although the terms "first," "second," etc. may be used herein to describe various mixed materials, these mixed materials should not be limited by these terms. These terms are only used to distinguish one mixed substance from another.
The invention provides a clothing cleaning agent, which is particularly suitable for carrying out local cleaning treatment on western-style clothes, overcoat, full dress, silk clothes, hats, ties and other clothes which are not suitable for frequent cleaning; the clothing cleaning agent comprises the following components in percentage by mass:
Figure BDA0001333994260000041
and lemon essence accounting for 0.25-0.35 percent of the total mass of the components.
Specifically, the No. 6 solvent oil has excellent oil stain dissolving capacity, and mainly plays a role in dissolving oil stains and stabilizing a system in the finally obtained clothing cleaning agent; tetrachloroethylene is used as a metal degreasing solvent, and plays a role in dissolving, softening and emulsifying grease; the methylene dichloride has the advantages of strong dissolving capacity, quite low toxicity and the like, and plays roles of degreasing and demoulding in the clothing cleaning agent; the main function of lemon essence is to mask the raw material odor and provide a pleasant light flavor.
The above-mentioned clothing cleaner of the present invention will be shown below by way of specific examples, but the clothing cleaner according to the present invention is not limited to the specific compositions of the following examples 1 to 3, and the following examples 1 to 3 are merely examples of some of the specific compositions of the clothing cleaner of the present invention.
Table 1 compositions of the garment cleaners of examples 1-3
Figure BDA0001333994260000042
It should be noted that, in the clothing detergents of examples 1 to 3, the total mass of the 6# solvent oil, n-bromopropane, tetrachloroethylene, dichloromethane, cyclohexane, isohexane and silica gel powder was regarded as 100%, and the amount of the lemon essence added was 0.25 to 0.35% based on the above 100%, but the total mass of all the components of the 6# solvent oil, n-bromopropane, tetrachloroethylene, dichloromethane, cyclohexane, isohexane, silica gel powder and lemon essence was not regarded as 100%.
The clothing cleaner is prepared by the following method:
and step S1, mixing the No. 6 solvent oil, tetrachloroethylene, dichloromethane and silica gel powder, and uniformly stirring to obtain a first mixture.
The following example is given as an example, and the other examples are only required to replace the amount of the corresponding substance.
Specifically, the 6# solvent oil accounting for 10% of the total mass of the 6# solvent oil, the n-bromopropane, the tetrachloroethylene, the dichloromethane, the cyclohexane, the isohexane and the silica gel powder, the 6% solvent oil, the 6% tetrachloroethylene, the 17% dichloromethane and the 10% silica gel powder are mixed and stirred to obtain a first mixture.
And step S2, adding the n-bromopropane and the lemon essence into the first mixture, and uniformly stirring to obtain a second mixture.
Specifically, 22% of n-bromopropane and 0.25% of lemon essence in parts by mass of the 6# solvent oil, the n-bromopropane, the tetrachloroethylene, the dichloromethane, the cyclohexane, the isohexane and the silica gel powder are added into the first mixture to be mixed and stirred, so as to obtain a second mixture.
Step S3, mixing cyclohexane and isohexane and stirring uniformly to obtain a third mixture;
specifically, cyclohexane and isohexane accounting for 5% of total mass of the 6# solvent oil, n-bromopropane, tetrachloroethylene, dichloromethane, cyclohexane, isohexane and silica gel powder were mixed and stirred to obtain a third mixture.
And step S4, mixing the second mixture and the third mixture and stirring uniformly.
Specifically, the second mixture obtained in the above step S2 and the third mixture obtained in the step S3 are mixed and stirred, and finally the clothing detergent in a liquid phase is obtained.
Generally, the mixing process in the steps S1, S2, S3 and S4 may be performed in a mixing tank.
Example 4
For ease of use of the garment cleaner, it is clear that the spray form is more convenient than the liquid phase, and therefore the garment cleaner having the ingredients described in examples 1-3 can be made into a garment cleaning spray.
Specifically, the liquid-phase clothing cleaning agent obtained in examples 1 to 3 and liquefied petroleum gas are mixed and canned according to a mass ratio of 2.3:1 to 2.5:1, preferably about 2.4:1 in this example, to obtain the clothing cleaning spray.
Compared with other similar products in the prior art, the clothing cleaning agent in a liquid phase form or a spray form has the advantages of simple and convenient use and remarkable cleaning effect, can effectively remove oil stains and other stubborn stains on residual clothing, and does not damage clothing fibers; meanwhile, the clothing cleaner provided by the embodiment of the invention has wide raw material sources and small environmental damage, and completely meets the national environmental protection requirements.
While the invention has been shown and described with reference to certain embodiments, those skilled in the art will understand that: various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents.

Claims (2)

1. The clothing cleaning agent is characterized by comprising the following components in percentage by mass:
10% of No. 6 solvent oil, 22% of n-bromopropane, 6% of tetrachloroethylene, 17% of dichloromethane, 5% of cyclohexane, 30% of isohexane, 10% of silica gel powder, 0.25% of lemon essence and liquefied petroleum gas in the total mass of the components; in the alternative, the first and second sets of the first,
15% of No. 6 solvent oil, 24% of n-bromopropane, 8% of tetrachloroethylene, 19% of dichloromethane, 4% of cyclohexane, 25% of isohexane, 10% of silica gel powder, 0.31% of lemon essence and liquefied petroleum gas in the total mass of the components; in the alternative, the first and second sets of the first,
15% of No. 6 solvent oil, 20% of n-bromopropane, 4% of tetrachloroethylene, 15% of dichloromethane, 8% of cyclohexane, 30% of isohexane, 8% of silica gel powder, 0.35% of lemon essence and liquefied petroleum gas in the total mass of the components;
the mass ratio of the sum of the mass of the No. 6 solvent oil, the n-bromopropane, the tetrachloroethylene, the dichloromethane, the cyclohexane, the isohexane, the silica gel powder and the lemon essence to the mass of the liquefied petroleum gas is 2.3: 1-2.5: 1.
2. A method of preparing the garment cleaner of claim 1, comprising:
step S1, mixing and uniformly stirring 6# solvent oil, tetrachloroethylene, dichloromethane and silica gel powder to obtain a first mixture;
step S2, adding n-bromopropane and lemon essence into the first mixture, and uniformly stirring to obtain a second mixture;
step S3, mixing cyclohexane and isohexane and stirring uniformly to obtain a third mixture;
step S4, mixing the second mixture and the third mixture and stirring uniformly;
and S5, mixing the liquid obtained in the step S4 and the liquefied petroleum gas according to the mass ratio of 2.3: 1-2.5: 1 to form a spray.
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069064A (en) * 1992-05-29 1993-02-17 湖北省荆门市再生资源开发公司 Fabric spraying dry-cleaning agent and method for making thereof
CN1101073A (en) * 1994-11-25 1995-04-05 金锋 High-efficiency dry detergent for textile and its making method
CN1105386A (en) * 1994-01-11 1995-07-19 北京新技术研究所 Efficient spray dry-cleaning stain remover
CN1111303A (en) * 1994-05-04 1995-11-08 穆俊英 Water-free oil stain spray detergent for fabric and its products
CN1171437A (en) * 1996-07-19 1998-01-28 吕龙华 Formula of dry-cleaning agent for clothes and productive method thereof
CN102839063A (en) * 2011-06-21 2012-12-26 王欣 Preparation method of fur clothes cleaning agent
CN104152280A (en) * 2014-07-26 2014-11-19 青岛启源振东电气有限公司 Efficient and environment-friendly detergent
CN104419538A (en) * 2013-08-28 2015-03-18 青岛医防消毒专业技术中心 Oil-stain-removing clothes dry cleaning agent

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069064A (en) * 1992-05-29 1993-02-17 湖北省荆门市再生资源开发公司 Fabric spraying dry-cleaning agent and method for making thereof
CN1105386A (en) * 1994-01-11 1995-07-19 北京新技术研究所 Efficient spray dry-cleaning stain remover
CN1111303A (en) * 1994-05-04 1995-11-08 穆俊英 Water-free oil stain spray detergent for fabric and its products
CN1101073A (en) * 1994-11-25 1995-04-05 金锋 High-efficiency dry detergent for textile and its making method
CN1171437A (en) * 1996-07-19 1998-01-28 吕龙华 Formula of dry-cleaning agent for clothes and productive method thereof
CN102839063A (en) * 2011-06-21 2012-12-26 王欣 Preparation method of fur clothes cleaning agent
CN104419538A (en) * 2013-08-28 2015-03-18 青岛医防消毒专业技术中心 Oil-stain-removing clothes dry cleaning agent
CN104152280A (en) * 2014-07-26 2014-11-19 青岛启源振东电气有限公司 Efficient and environment-friendly detergent

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