CN107254365A - One kind spray aqueous cleaning agent - Google Patents
One kind spray aqueous cleaning agent Download PDFInfo
- Publication number
- CN107254365A CN107254365A CN201710555622.4A CN201710555622A CN107254365A CN 107254365 A CN107254365 A CN 107254365A CN 201710555622 A CN201710555622 A CN 201710555622A CN 107254365 A CN107254365 A CN 107254365A
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- cleaning agent
- cleaning
- agent
- surfactant
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：Surfactant 15~40%, coupling agent 10~15%, complexing agent 1~5%, surplus are water.The cleaning agent is applied to giant cleaning showers, and the foam height of generation is low, can effectively remove the greasy dirt of product surface, improves cleaning production capacity, and the product after cleaning is without line is stayed, and residual is low, and damage will not be caused to base material, and service life is long, environment protection energy-saving efficient.
Description
Technical field
The invention belongs to cleaning agent technical field, it is related to a kind of spray aqueous cleaning agent.
Background technology
Low bubble cleaning agent in the market is a lot, but the foam produced mostly absolutely is more, is not suitable for cleaning showers.It is suitable
Substantial amounts of defoamer can be wherein added with cleaning showers, these defoamers mainly use polyether modified silicon oil, polyethers etc., these
The hydrophily of defoamer in itself is just bad, so often influences cleaning performance, and the product after cleaning is easy to generation watermark and stayed
Line.
The A of CN 102766879 disclose a kind of metallic combination part cleaning showers agent, cleaning agent raw material include polyether carboxylation,
Carboxylate, block polyether, ether surfactants, sodium gluconate, diethylene triamine pentacetic acid (DTPA) sodium, ethylenediamine tetra-acetic acid two
Sodium, sodium metasilicate, sodium benzoate, benzotriazole, triethanolamine, alcohols, glycol ether, deionized water, it is adaptable to ferrous metal and
The oil removing antirust cleaning of non-ferrous metal and the sub-assembly of both compositions, with extremely strong cleaning performance and longer inhibition week
Phase, noresidue does not cause discoloration, does not produce corrosion pit and the low bubble of environmental protection, the material such as not phosphorous, natrium nitrosum, at its waste liquid
Reason is easy, environment will not be polluted, be particularly suitable for use in normal temperature cleaning showers, consuming little energy in cleaning process.But institute
Cleaning showers agent complicated component is stated, and also has a small amount of foam and is produced.
The A of CN 104711615 are bright to disclose a kind of motor spray cleaning agent, and raw materials used and percentage by weight is as follows：It is sweet
Oily monostearate 1.2~8%, diethylene triamine pentacetic acid (DTPA) sodium 1.5~10%, monoethanolamine 5~20%, TA-E soil dispersions
The deionized water of agent 12~25%, corrosion inhibitor 5~12% and surplus.The residual quantity of the cleaning showers agent is big, also has few
Foam is measured to produce.
The content of the invention
To solve the technical problem that prior art is present, the present invention provides a kind of spray aqueous cleaning agent, the cleaning agent
Suitable for giant cleaning showers, the foam height of generation is low, can effectively remove the greasy dirt of product surface, improves cleaning production
Can, the product after cleaning is without line is stayed, and residual is low, and damage will not be caused to base material, and service life is long, environment protection energy-saving efficient.
To reach above-mentioned technique effect, the present invention takes following technical scheme：
The present invention provides a kind of spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Wherein, the mass fraction of the surfactant can be 15%, 16%, 18%, 20%, 22%, 25%,
28%th, 30%, 32%, 35%, 38% or 40% etc., the mass fraction of the coupling agent can be 10%, 10.5%, 11%,
11.5%th, 12%, 12.5%, 13%, 13.5%, 14%, 14.5% or 15% etc., the mass fraction of complexing agent can be 1%,
1.5%th, 2%, 2.5%, 3%, 3.5%, 4%, 4.5% or 5% etc., it is not limited to cited numerical value, above-mentioned each number
Other unrequited numerical value are equally applicable in the range of value.
As currently preferred technical scheme, include according to the composition of cleaning agent described in mass fraction meter：
As currently preferred technical scheme, include according to the composition of cleaning agent described in mass fraction meter：
As currently preferred technical scheme, the surfactant includes short chain carbon fatty alcohol polyethers, alkylol second
Any one in epoxide compound, short-chain alkyl ethoxylate or modified alkyl glucosides or at least two combination, the combination
Typical but non-limiting examples have：The combination of short chain carbon fatty alcohol polyethers and alkyl alcohol ethoxylates, alkyl alcohol ethoxylates
The combination of thing and short-chain alkyl ethoxylate, the combination of short-chain alkyl ethoxylate and modified alkyl glucosides, modified alkyl
The combination of glucosides and short chain carbon fatty alcohol polyethers or short chain carbon fatty alcohol polyethers, alkyl alcohol ethoxylates and modified alkyl glucosides
Combination etc..
Preferably, the carbon number of short chain carbon fatty alcohol described in the short chain carbon fatty alcohol polyethers be 1~8, such as 1,2,3,4,
5th, 6,7 or 8 etc., it is not limited to other unrequited numerical value are equally applicable in cited numerical value, the number range.
Preferably, the carbon number of short chain carbon fatty alcohol described in the alkyl alcohol ethoxylates be 1~8, such as 1,2,3,4,
5th, 6,7 or 8 etc., it is not limited to other unrequited numerical value are equally applicable in cited numerical value, the number range.
Preferably, the carbon number of short-chain alkyl is 1~8 such as 1,2,3,4,5,6,7 or 8 in short-chain alkyl ethoxylate,
It is not limited to other unrequited numerical value are equally applicable in cited numerical value, the number range.
As currently preferred technical scheme, the coupling agent includes polyol ethers.
Preferably, the polyalcohol polyether includes dihydric alcohol polyethers, trihydroxylic alcohol polyethers, sorbeth or xylitol polyethers
In any one or at least two combination, combination typical case but non-limiting examples have：Dihydric alcohol polyethers and trihydroxylic alcohol are poly-
The combination of ether, the combination of trihydroxylic alcohol polyethers and sorbeth, the combination of sorbeth and xylitol polyethers, sorbierite gather
The combination of ether and xylitol polyethers or the combination of dihydric alcohol polyethers, trihydroxylic alcohol polyethers and sorbeth etc..
As currently preferred technical scheme, the complexing agent includes tetrasodium ethylenediamine tetraacetate, sodium citrate, grape
Any one in sodium saccharate or sodium tartrate or at least two combination, the combination is typical but non-limiting examples have：Second two
Combination, the combination of sodium citrate and sodium gluconate, sodium gluconate and the sodium tartrate of the sodium of amine tetraacethyl four and sodium citrate
Combination, the combination or tetrasodium ethylenediamine tetraacetate of sodium tartrate and tetrasodium ethylenediamine tetraacetate, sodium citrate and gluconic acid
Combination of sodium etc..
The present invention selects rational surfactant, and not only the binding ability of selected surfactant and greasy dirt is strong, and can
Effectively suppress the generation of foam, the present invention selects coupling agent again, not only further increases surfactant in the combination of greasy dirt
Ability, simultaneously because it can accelerate merging for aqueous phase and oil phase, surfactant and the coupling agent of selection act synergistically, it is ensured that clear
Almost non-foam is produced during washing.
Compared with prior art, the present invention at least has the advantages that：
(1) present invention provides a kind of spray aqueous cleaning agent, and the cleaning agent visually observes several during cleaning showers
Non-foam is produced；
(2) present invention provides a kind of spray aqueous cleaning agent, and the cleaning agent can effectively remove the greasy dirt of product surface, improve
Production capacity is cleaned, the product after cleaning is without line is stayed, and cleaning agent residual rate is less than 0.15%；
(3) present invention provides a kind of spray aqueous cleaning agent, and the cleaning agent will not cause damage, service life to base material
It is long, environment protection energy-saving efficient.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is only to aid in understanding the present invention, is not construed as the concrete restriction to the present invention.
Embodiment 1
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 2
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 3
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 4
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 5
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 6
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 7
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 8
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 9
One kind spray aqueous cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Comparative example 1
One kind spray aqueous cleaning agent, in addition to being added without C5 alkyl alcohol ethoxylates, other conditions with embodiment 7
It is identical.
Comparative example 2
One kind spray aqueous cleaning agent, in addition to being added without modified alkyl glucosides, other conditions are same as Example 7.
Comparative example 3
One kind spray aqueous cleaning agent, except being added without modified alkyl glucosides and C5 alkyl alcohol ethoxylates, and makes
With neopelex as surface catalyst outside, other conditions are same as Example 7.
Comparative example 4
One kind spray aqueous cleaning agent, in addition to being added without polyol ethers, other conditions are same as Example 7.
The cleaning showers agent described in embodiment 1-9 and comparative example 1-3 is applicable to enter the stainless steel surface for speckling with greasy dirt
Row cleaning, is tested the foam volume and the residual rate of cleaning agent produced in cleaning process, as a result as shown in table 1.
Table 1
| Project | Foam volume | Residual rate |
| Embodiment 1 | Non-foam | 0.12% |
| Embodiment 2 | Non-foam | 0.13% |
| Embodiment 3 | Non-foam | 0.13% |
| Embodiment 4 | Non-foam | 0.12% |
| Embodiment 5 | Non-foam | 0.14% |
| Embodiment 6 | Non-foam | 0.15% |
| Embodiment 7 | Non-foam | 0.12% |
| Embodiment 8 | Non-foam | 0.13% |
| Embodiment 9 | Non-foam | 0.14% |
| Comparative example 1 | A small amount of foam | 1.35% |
| Comparative example 2 | A small amount of foam | 0.26% |
| Comparative example 3 | A large amount of foams | 10.56% |
| Comparative example 4 | A large amount of foams | 10.42% |
According to table 1 as can be seen that embodiment 1-9 almost non-foam productions when cleaning showers carry the stainless steel of greasy dirt
It is raw, and residual rate is less than 0.15% after cleaning, and cause to have due to reducing the addition of surfactant in comparative example 1 and 2
A small amount of foam is produced, and residual rate is increased slightly, and the surfactant of comparative example 3 uses neopelex, and is contrasted
Example 4 has a large amount of foams to produce without using polyol ethers in cleaning process, and residual rate is all higher than 10%.
Applicant states that the present invention illustrates detailed process equipment and the technological process of the present invention by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, do not mean that the present invention has to rely on above-mentioned detailed
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
Addition, selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention etc., all fall within the present invention's
Within the scope of protection domain and disclosure.
Claims (6)
1. one kind spray aqueous cleaning agent, it is characterised in that the composition according to cleaning agent described in mass fraction meter includes：
Surfactant 15~40%；
Coupling agent 10~15%；
Complexing agent 1~5%；
Surplus is water.
2. cleaning agent according to claim 1, it is characterised in that according to the composition bag of cleaning agent described in mass fraction meter
Include：
Surfactant 20~30%；
Coupling agent 11~14%；
Complexing agent 2~4%；
Surplus is water.
3. cleaning agent according to claim 1 or 2, it is characterised in that according to the composition of cleaning agent described in mass fraction meter
Including：
Surfactant 25%；
Coupling agent 12%；
Complexing agent 3%；
Surplus is water.
4. the cleaning agent according to claim any one of 1-3, it is characterised in that the surfactant includes short chain carbon fat
Any one in fat alcohol polyethers, alkyl alcohol ethoxylates, short-chain alkyl ethoxylate or modified alkyl glucosides or at least two
The combination planted；
Preferably, the carbon number of short chain carbon fatty alcohol described in the short chain carbon fatty alcohol polyethers is 1~8；
Preferably, the carbon number of short-chain alkyl is 1~8 in short-chain alkyl ethoxylate.
5. the cleaning agent according to claim any one of 1-4, it is characterised in that the coupling agent is polyol ethers；
Preferably, the polyalcohol polyether includes appointing in dihydric alcohol polyethers, trihydroxylic alcohol polyethers, sorbeth or xylitol polyethers
Meaning it is a kind of or at least two combinations.
6. the cleaning agent according to claim any one of 1-5, it is characterised in that the complexing agent includes ethylenediamine tetra-acetic acid
Any one in four sodium, sodium citrate, sodium gluconate or sodium tartrate or at least two combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710555622.4A CN107254365B (en) | 2017-07-10 | 2017-07-10 | Spraying water-based cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710555622.4A CN107254365B (en) | 2017-07-10 | 2017-07-10 | Spraying water-based cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107254365A true CN107254365A (en) | 2017-10-17 |
| CN107254365B CN107254365B (en) | 2020-11-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710555622.4A Active CN107254365B (en) | 2017-07-10 | 2017-07-10 | Spraying water-based cleaning agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109536294A (en) * | 2018-03-16 | 2019-03-29 | 东莞市华启清洗剂科技有限公司 | A kind of environment-friendly water-based cleaning agent |
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|---|---|---|---|---|
| CA2066008A1 (en) * | 1991-04-15 | 1992-10-16 | Robert J. Rhinesmith | Foam reduction in non-aqueous, liquid, heavy-duty laundry detergent containing secondary ethoxylate nonionic surfactant |
| WO1993017772A1 (en) * | 1992-03-10 | 1993-09-16 | Henkel Kommanditgesellschaft Auf Aktien | Paraffin-based foam control agent |
| US5542950A (en) * | 1994-11-10 | 1996-08-06 | Henkel Corporation | Alkyl polyglycosides in textile scour/bleach processing |
| AU5725200A (en) * | 1999-06-10 | 2001-01-02 | Cognis Corporation | Gloss retention compositions |
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2017
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|---|---|---|---|---|
| CA2066008A1 (en) * | 1991-04-15 | 1992-10-16 | Robert J. Rhinesmith | Foam reduction in non-aqueous, liquid, heavy-duty laundry detergent containing secondary ethoxylate nonionic surfactant |
| WO1993017772A1 (en) * | 1992-03-10 | 1993-09-16 | Henkel Kommanditgesellschaft Auf Aktien | Paraffin-based foam control agent |
| US5542950A (en) * | 1994-11-10 | 1996-08-06 | Henkel Corporation | Alkyl polyglycosides in textile scour/bleach processing |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109536294A (en) * | 2018-03-16 | 2019-03-29 | 东莞市华启清洗剂科技有限公司 | A kind of environment-friendly water-based cleaning agent |
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| Publication number | Publication date |
|---|---|
| CN107254365B (en) | 2020-11-20 |
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