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CN107253756A - A kind of method that activated carbon sinters selenium-rich filtering element for treating water - Google Patents

A kind of method that activated carbon sinters selenium-rich filtering element for treating water Download PDF

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Publication number
CN107253756A
CN107253756A CN201710648884.5A CN201710648884A CN107253756A CN 107253756 A CN107253756 A CN 107253756A CN 201710648884 A CN201710648884 A CN 201710648884A CN 107253756 A CN107253756 A CN 107253756A
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China
Prior art keywords
activated carbon
selenium
rich
water
filter core
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Pending
Application number
CN201710648884.5A
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Chinese (zh)
Inventor
朱建林
黄光智
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Individual
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Individual
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Priority to CN201710648884.5A priority Critical patent/CN107253756A/en
Publication of CN107253756A publication Critical patent/CN107253756A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2055Carbonaceous material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/683Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42Materials comprising a mixture of inorganic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48Sorbents characterised by the starting material used for their preparation
    • B01J2220/4806Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Filtering Materials (AREA)

Abstract

The invention discloses a kind of method of activated carbon sintered filter core, the method that particularly a kind of use Rich selenium ore powders production activated carbon sinters selenium-rich filtering element for treating water, production technology is by 1, and material prepares, 2, formula combination, 3, stirring mixing;4, mould adds powder, 5, sintering, 6, cooling and demolding, 7, sequential test;8, classification storage, eight process compositions;Product adaptation obtains the selenium-rich water of the element containing selenium-rich as the element of filtering, purifier, belongs to water-treatment technology field, be especially suitable for and animal feeding and field of plant growing technology simultaneously in all kinds of water purification filter water treatment facilities.

Description

A kind of method that activated carbon sinters selenium-rich filtering element for treating water
Technical field
It is particularly a kind of to be burnt using Rich selenium ore powders production activated carbon the present invention relates to a kind of method of activated carbon sintered filter core The method for tying selenium-rich filtering element for treating water, is adapted in all kinds of water purification filter water treatment facilities, is used as filtering, purifier Element simultaneously obtain the element containing selenium-rich selenium-rich water, belong to water-treatment technology field, be especially suitable for animal feeding and Field of plant growing technology.
Background technology
At present, drink water purifying is mostly to carry out filtration, purification using activated carbon, because activated carbon is in powdered, is used Inconvenience, and use ultra-high molecular weight polyethylene (UHMWPE) powder and active carbon powder prepare filter element have it is easy to process, The advantages of excellent performance, service life length, good filtration effect." three dirty " filtration treatment, white wine filtering, chemicals filtering, Increasingly it is taken seriously in terms of oil filtering, battery isolating film, therefore, Chinese patent CN01104366.0 " composite Carriers Active carbon rod and preparation method thereof ", it is characterized in that:A kind of active carbon stick as composite material carrier, it is characterised in that by weight Than being as carrier and 50%-75% by 25-50% ultra high molecular weight polyethylenes powder and high density polyethylene (HDPE) powder Activated carbon powder is blended in Pressurized-heated sintering in mould and constituted, ultra high molecular weight polyethylene powder and height in carrier The part by weight of density polyethylene powder compares 0.1-0.3 for 1.
Chinese patent CN201020540658.9 " a kind of granular active carbon compound filter element ", it is characterised in that:Including in The cylindric composite filter element (1) of sky, the capping (2) for being arranged on composite filter element two ends and being connected respectively with composite filter element two ends, institute Stating composite filter element includes coaxial package and the outer melt-blown filter (3) of contour cylindrical hollow and interior melt-blown filter (4), described outer molten The activity of bulk is provided with the space (5) formed between the inner surface of blown filter and the capping of the outer surface of interior melt-blown filter and two ends Charcoal particle (6), the activated carbon granule forms closely knit activated carbon adsorption layer.
But, conventional sintering activity carbon filtration core is all the method using activated carbon granule, because particle is big, general 8-10 Purpose granular activated carbon, its specific surface area is small, produce the proportion of sintered filter core more than 0, more than 7 grams/cc, can't be very The absorption property of good utilization activated carbon!Therefore, producing the problem that sintered filter core is research and development new product using active carbon powder;In State's patent:CN201320196759.2 and CN201320196759.2 " active carbon composite filter core manufacture device ", it includes Adhesive-bonded fabric machine, roller unit, powdered carbon sprinkler and heat pressure roller, adhesive-bonded fabric machine can produce adhesive-bonded fabric body;Roller unit Positioned at adhesive-bonded fabric machine process side and adhesive-bonded fabric body can be heated;Powdered carbon sprinkler is located at the top of roller unit and can sprayed Activated carbon powder is spilt in adhesive-bonded fabric body;Heat pressure roller is located at process side, and heat pressure roller is adjacent to roller unit and being capable of hot pressing quilt Spray the adhesive-bonded fabric body after activated carbon powder;Can heat adhesive-bonded fabric body by roller unit, and powdered carbon sprinkler can It is uniform maturely to make activated carbon powder adhesion in adhesive-bonded fabric body, and heat pressure roller makes activated carbon powder and adhesive-bonded fabric body sinter Close, therefore the utility model is pressed on adhesive-bonded fabric body in which can make activated carbon powder consolidation, therefore improve active carbon composite filter core Filter effect, and can reduce environment dust pollution, reduce manufacturing cost.
Although above-mentioned patent solves the Utilizing question of the specific surface area of activated carbon, but its unfortunately function it is single, also There is the defect of production technology inconvenience.
The content of the invention
The mesh of the present invention is to provide a kind of method that activated carbon sinters selenium-rich filtering element for treating water, it is characterized in that:Using activity Charcoal micro mist replaces granular activated carbon, increase and the selenium-rich ore deposit containing elemental selenium of activated carbon same particle sizes in corresponding conventional formula Powder, so that the sintered filter core containing selenium-rich element forms cellular three-D space structure, its micropore interlocks up and down, compares surface Long-pending is multiplied, so, WATER AS FLOW MEDIUM by the present invention sintered filter core by during three dimensions selenium-rich element just to richness Selenium element is carried out from abundant dissolving, so that, the WATER AS FLOW MEDIUM passed through is added selenium element, realize the purpose of production selenium-rich water.
What the present invention was realized in:It is can to make active ingredient with being connect by water according to using activated carbon sintered filter core Tactile area more fully feature, so that the WATER AS FLOW MEDIUM that Rich selenium ore powders can be passed through fully dissolves, obtains selenium-rich mineral matter Water, realizes the purpose of the present invention.
A kind of method that activated carbon sinters selenium-rich filtering element for treating water, it is characterized in that:Using known activated carbon sintered filter core Technology, the 20-50% of the increase gross mass Rich selenium ore powders in conventional formula, is further continued for after being sufficiently stirred for being added to often Produced in the stainless steel mould of rule according to the conventional method of activated carbon sintered filter core.A kind of activated carbon sintering of described production The production technology of the method for selenium-rich filtering element for treating water by:1, material prepares, and 2, formula combination, 3, stirring mixing, 4, mould adds powder, 5, sintering, 6, cooling and demolding, 7, sequential test, 8, classification storage, eight process compositions;Specific steps content is:1st, will be required A kind of material of activated carbon sintering selenium-rich filtering element for treating water requires accurate according to the technical formula of production conventional activated carbon sintered filter core Standby material;2nd, the Rich selenium ore powders with above-mentioned material same particle sizes are prepared according to the 20-50% of above-mentioned total formula weight;3rd, will be above-mentioned Material is added in special powder mixer and is sufficiently stirred for;Above-mentioned powder mixer, which is that food grade powder is convertible, to be stirred Machine is mixed, granular material can be sufficiently mixed;4th, it will be loaded into by the mixed-powder being sufficiently stirred in required stainless steel mould And pressurize, it is to avoid mixed-powder can not be compacted, shaping;5th, the above-mentioned product through overcompaction is put into sintering together with mould to set In standby, conventional activated carbon filter core sintering is carried out;6th, mould is taken out, air-cooled, the demoulding in normal temperature environment is carried out, takes out product --- Activated carbon selenium-rich sintered filter core;7th, according to conventional technique, detection, packaging and warehousing.
The present invention realizes the mesh that a kind of activated carbon sinters selenium-rich filtering element for treating water due to using above-mentioned technique and method 's.It is arranged on when using in running water all kinds of water purification filter water treatment facilities, is used as filtering, water purification selenium-rich hydration treatment device Element, one-object-many-purposes are that water treatment field adds a kind of Noval water-treating device part.It is particularly suitable for drinking and plant for animal Cultivation occasion, the technology of the present invention is ripe, and water purification performance is easy to be accepted, and product with standardized production and can install letter Just, it is cheap, it is convenient to promote.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples:
Fig. 1 is the technical process block diagram of conventional activated carbon sintered filter core;
Fig. 2 is a kind of embodiment of the present invention:A kind of technical process square frame of the method for activated carbon sintering selenium-rich filtering element for treating water Figure.In figure, A=ultra-high molecular weight polyethylene;B=activated carbon micro mist;KF=Rich selenium ore powders;JB=stirring mixing;MJ=mould;ZM= Mould adds powder;SJ=sintering furnace;LQ=cooling of coming out of the stove;JY=inspection;FP=waste product;RK=finished product storage.
Embodiment
Reference picture 1, Fig. 2 technical process block diagram, is produced according to technical process file.
A kind of the first embodiment of activated carbon sintering selenium-rich filtering element for treating water:It is convenient in order to utilize original case of water purifier Filter core is changed, the present embodiment is using conventional water purification catridge housing size:46 millimeters of diameter.22 millimeters of endoporus, the milli of length 205 Meter, 210 grams of net weight is according to the size design of this model:46 millimeters of micro mist activated carbon sintering selenium-rich filtering element for treating water external diameter, This production quantity 1000 is determined before 22 millimeters of endoporus, 205 millimeters of length, production, material 210 is needed altogether according to above-mentioned specification Kilogram, according to 5:5 formula is:Ultra-high molecular weight polyethylene is 105 kg;Activated carbon micro mist is 105 kg
This needs the material weight to be respectively:Ultra-high molecular weight polyethylene, 1, according to production batch and recipe requirements by required material Expect ultra-high molecular weight polyethylene, active carbon powder is added to special powder mixer and is stirred ten minutes, then will be ready Poured into Rich selenium ore powders according to the addition of above-mentioned Size calculation in powder mixer and continue to stir 10 minutes, process stainless steel Mould, during production, carries out according to Fig. 2 production technology, is specifically:Pressed using micro mist activated carbon sintered filter core material prescription More solito 5:5 ratio, puddling adds the Rich selenium ore powders of gross weight 30% after 10 minutes in powder mixer, continues to stir 20 minutes, then the sufficient mixed-powder of above-mentioned mixing is added in preprepared stainless steel mould and carries out conventional burning Knot, is cooled down, and is stripped, and examines storage, and the selenium-rich sintered filter core that the production of this formula is randomly selected from warehouse for finished product is installed to conventional surpass The water side of water dispenser is filtered, Shanghai City world Ying Geer is sent in the beverage bottle for discharging water and using Jing Guo cleaning treatment for one minute of starting shooting Detect that certification group carries out heavy metal Indexs measure, examination criteria GB/T5749-2006《Standards for drinking water quality》Detection As a result:The mg/litre of Se content 0.0983, more than arm's length standard, other elements index is all qualified.
A kind of activated carbon sinters second of embodiment of method of selenium-rich filtering element for treating water:Specifically:Using micro mist activated carbon Sintered filter core material prescription 5:5 formula is carried out dispensing and stirred 10 minutes using special powder mixer, adds gross weight 50% Rich selenium ore powders, continue to stir 20 minutes, the sufficient mixed-powder of above-mentioned mixing then are added into preprepared and burnt Normal sintering is carried out in knot filter core stainless steel mould, is cooled down, storage is examined in the demoulding.The life of this formula is randomly selected from warehouse for finished product The selenium-rich sintered filter core of production is installed to the water side of conventional ultrafiltration water dispenser, and then start discharges water one minute, using through over cleaning Beverage bottle pour water and be sent to Foshan City product quality supervision office according to national standard GB/T5750,6-2006《Drinking water standard is examined Survey method, metal index》Selenium element content reaches that 0.28 milli gram/cc above-mentioned technique can easily carry out streamline burning Knot production, is so achieved that the purpose of the batch production of the present invention.

Claims (4)

1. a kind of method that activated carbon sinters selenium-rich filtering element for treating water, it is characterized in that:Using known activated carbon sintered filter core skill Art, the 20-50% of increase gross mass Rich selenium ore powders, are further continued for being added to routine after being sufficiently stirred in conventional formula Stainless steel mould in produced according to the conventional method of activated carbon sintered filter core.
2. a kind of method that activated carbon sinters selenium-rich filtering element for treating water, it is characterized in that:Production technology is by 1, and material prepares, 2, formula Combination, 3. stirring mixing;4, mould adds powder, 5, sintering;6, cooling and demolding;7, sequential test;8, classification storage;In specific steps Rong Shi:1st, a kind of required activated carbon is sintered into the material of selenium-rich filtering element for treating water according to the skill of production conventional activated carbon sintered filter core Art recipe requirements prepare material, 2, the 20-50% preparations according to above-mentioned total formula weight and the selenium-rich ore deposit of above-mentioned material same particle sizes Powder;3rd, above-mentioned material is added in special powder mixer and be sufficiently stirred for;4th, by the mixed powder by being sufficiently stirred for End is loaded into required stainless steel mould and pressurizeed, it is to avoid mixed-powder can not be compacted, shaping;5th, by above-mentioned through overcompaction Product is put into agglomerating plant together with mould, carries out conventional activated carbon filter core sintering;6th, mould is taken out, air-cooled or water is carried out One kind in cold, is stripped in normal temperature environment, takes out product --- activated carbon selenium-rich sintered filter core;7th, carried out on streamline by It is individual to examine;8, close inspection is required according to standard, by attribute classification, packaging and warehousing.
3. the method that a kind of activated carbon according to required by claim 2 sinters selenium-rich filtering element for treating water, it is characterized in that:Stirring The special powder mixer that hybrid technique is used is the convertible mixer of food-grade.
4. the method that a kind of activated carbon according to required by claim 2 sinters selenium-rich filtering element for treating water, it is characterized in that:Mould is Conventional sintered filter core stainless steel mould.
CN201710648884.5A 2017-08-01 2017-08-01 A kind of method that activated carbon sinters selenium-rich filtering element for treating water Pending CN107253756A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109453741A (en) * 2018-10-30 2019-03-12 广东工业大学 Heavy metal and arsenic, the sintering activity charcoal of fluorine ion and preparation method thereof in a kind of efficient absorption water
CN110124394A (en) * 2019-05-13 2019-08-16 江西虔农农业股份有限公司 A kind of preparation method of selenium-rich titanium-based filtering element for treating water
CN112933742A (en) * 2021-03-02 2021-06-11 全硒时代(深圳)生物科技发展有限公司 Method for manufacturing filter element with organic selenium
CN112933740A (en) * 2021-02-07 2021-06-11 全硒时代(深圳)生物科技发展有限公司 Method for oil purification decoloration selenium-rich sintered filter element
CN116835748A (en) * 2023-07-21 2023-10-03 山东共筑农业集团有限公司 Selenium-rich ceramic particle water purification filter element and preparation method thereof

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CN101642652A (en) * 2009-08-31 2010-02-10 金碧娥 Selenium-rich nano-silver active carbon filter element and preparation method thereof
CN102350129A (en) * 2011-06-21 2012-02-15 黄光智 Integrated water purifying filter core for removing fluorine and filtering
CN102887558A (en) * 2011-07-19 2013-01-23 夏涛 Drinking water purifying material containing nano-selenium and preparation method of drinking water purifying material
CN103071400A (en) * 2013-01-05 2013-05-01 宁波爱去欧净水设备科技有限公司 Manufacturing method of microporous membrane sinter filter element
CN203196461U (en) * 2013-04-18 2013-09-18 崧泉企业股份有限公司 Activated carbon composite filter core manufacturing device
CN103381322A (en) * 2013-06-25 2013-11-06 蚌埠凤凰滤清器有限责任公司 Active carbon filter core and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101642652A (en) * 2009-08-31 2010-02-10 金碧娥 Selenium-rich nano-silver active carbon filter element and preparation method thereof
CN102350129A (en) * 2011-06-21 2012-02-15 黄光智 Integrated water purifying filter core for removing fluorine and filtering
CN102887558A (en) * 2011-07-19 2013-01-23 夏涛 Drinking water purifying material containing nano-selenium and preparation method of drinking water purifying material
CN103071400A (en) * 2013-01-05 2013-05-01 宁波爱去欧净水设备科技有限公司 Manufacturing method of microporous membrane sinter filter element
CN203196461U (en) * 2013-04-18 2013-09-18 崧泉企业股份有限公司 Activated carbon composite filter core manufacturing device
CN103381322A (en) * 2013-06-25 2013-11-06 蚌埠凤凰滤清器有限责任公司 Active carbon filter core and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109453741A (en) * 2018-10-30 2019-03-12 广东工业大学 Heavy metal and arsenic, the sintering activity charcoal of fluorine ion and preparation method thereof in a kind of efficient absorption water
CN110124394A (en) * 2019-05-13 2019-08-16 江西虔农农业股份有限公司 A kind of preparation method of selenium-rich titanium-based filtering element for treating water
CN112933740A (en) * 2021-02-07 2021-06-11 全硒时代(深圳)生物科技发展有限公司 Method for oil purification decoloration selenium-rich sintered filter element
CN112933742A (en) * 2021-03-02 2021-06-11 全硒时代(深圳)生物科技发展有限公司 Method for manufacturing filter element with organic selenium
CN116835748A (en) * 2023-07-21 2023-10-03 山东共筑农业集团有限公司 Selenium-rich ceramic particle water purification filter element and preparation method thereof

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