CN107245675B - A kind of ultrasonic unit and preparation method thereof preparing carbon fiber aluminum-based compound material - Google Patents
A kind of ultrasonic unit and preparation method thereof preparing carbon fiber aluminum-based compound material Download PDFInfo
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- CN107245675B CN107245675B CN201710524728.8A CN201710524728A CN107245675B CN 107245675 B CN107245675 B CN 107245675B CN 201710524728 A CN201710524728 A CN 201710524728A CN 107245675 B CN107245675 B CN 107245675B
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- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 70
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 70
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 6
- 239000000463 material Substances 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title description 17
- 150000001875 compounds Chemical class 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims abstract description 29
- 239000002184 metal Substances 0.000 claims abstract description 29
- 238000001816 cooling Methods 0.000 claims abstract description 26
- 239000011156 metal matrix composite Substances 0.000 claims abstract description 24
- 239000002131 composite material Substances 0.000 claims abstract description 6
- 238000003860 storage Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/08—Making alloys containing metallic or non-metallic fibres or filaments by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/02—Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
- C22C49/04—Light metals
- C22C49/06—Aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
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- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
本发明涉及一种制备碳纤维铝基复合材料的超声波装置,包括伺服系统、超声波振动系统、冷却系统和气体保护系统,伺服系统下端连接有金属杆,金属杆下端连接有连接件,连接件下端连接有超声波振动系统,设有气体保护系统,坩埚置于气体保护装置内部,超声波变幅杆的周圈设有环形冷却装置,超声波振动系统一侧设置有提拉电机,提拉电机下端连接有弓形夹具,该设备冷却效率高,提高碳纤维在金属液中分散程度,降低碳纤维分散所需时间,从而减小碳纤维损伤,获得高质量碳纤维金属基复合材料。
The invention relates to an ultrasonic device for preparing carbon fiber aluminum-based composite materials, including a servo system, an ultrasonic vibration system, a cooling system and a gas protection system. A metal rod is connected to the lower end of the servo system, and a connecting piece is connected to the lower end of the metal rod. There is an ultrasonic vibration system and a gas protection system. The crucible is placed inside the gas protection device. The circumference of the ultrasonic horn is equipped with an annular cooling device. One side of the ultrasonic vibration system is equipped with a lifting motor, and the lower end of the lifting motor is connected to a bow. Fixture, this equipment has high cooling efficiency, improves the dispersion degree of carbon fiber in molten metal, reduces the time required for carbon fiber dispersion, thereby reducing carbon fiber damage and obtaining high-quality carbon fiber metal matrix composites.
Description
技术领域technical field
本发明属于材料设备领域,涉及在金属基复合材料制备过程中缩短制备周期,降低碳纤维损伤程度的装置及其制备方法,具体指一种制备连续碳纤维铝基复合材料的超声波装置及其制备方法。The invention belongs to the field of material equipment, and relates to a device and a preparation method for shortening the preparation cycle and reducing the degree of carbon fiber damage during the preparation of metal matrix composite materials, and specifically refers to an ultrasonic device for preparing continuous carbon fiber aluminum matrix composite materials and a preparation method thereof.
背景技术Background technique
超声波振动法制备连续碳纤维金属基复合材料是利用超声波产生的空化效应和声流效应。作用于碳纤维从而使碳纤维均匀分散从而制备碳纤维金属基复合材料的工艺方法。而碳纤维复合材料制备过程中碳纤维的完好程度以及碳纤维在熔体中的分散程度严重影响着碳纤维复合材料的力学性能。常规碳纤维金属基复合材料制备时碳纤维与金属液接触时间长,碳纤维损伤大,碳纤维在金属液中分散程度差,采用超声波振动制备连续碳纤维金属基复合材料可以极大的缩短碳纤维与金属液接触时间,减小碳纤维所受冲击力,极大程度上保证了碳纤维的完好,同时利用超声波使碳纤维均匀分散,达到提高碳纤维金属基复合材料力学性能的目的。目前由于超声波振头无法在大于120℃条件下服役,并且由于金属导热以及热辐射等原因无法长时间在金属熔炼过程中进行使用,需要有一种实验装置解决这些问题。The preparation of continuous carbon fiber metal matrix composites by ultrasonic vibration method utilizes the cavitation effect and acoustic flow effect generated by ultrasonic waves. It is a process for preparing carbon fiber metal matrix composites by acting on carbon fibers to uniformly disperse carbon fibers. The integrity of carbon fiber and the degree of dispersion of carbon fiber in the melt during the preparation of carbon fiber composites seriously affect the mechanical properties of carbon fiber composites. When conventional carbon fiber metal matrix composites are prepared, the contact time between carbon fibers and molten metal is long, the damage of carbon fibers is large, and the degree of dispersion of carbon fibers in molten metal is poor. The preparation of continuous carbon fiber metal matrix composites by ultrasonic vibration can greatly shorten the contact time between carbon fibers and molten metal. , reduce the impact force on the carbon fiber, and ensure the integrity of the carbon fiber to a great extent. At the same time, the ultrasonic wave is used to evenly disperse the carbon fiber to achieve the purpose of improving the mechanical properties of the carbon fiber metal matrix composite. At present, because the ultrasonic vibration head cannot be used under the condition of greater than 120°C, and it cannot be used in the metal smelting process for a long time due to metal heat conduction and heat radiation, etc., an experimental device is needed to solve these problems.
发明内容SUMMARY OF THE INVENTION
发明目的:Purpose of the invention:
本发明提供一种制备连续碳纤维金属基复合材料的超声波装置及制备方法,该设备冷却效率高,改变了碳纤维金属基复合材料制备时碳纤维与金属液接触时间长,碳纤维损伤大的现状,提高碳纤维在金属液中分散程度,降低碳纤维分散所需时间,从而减小碳纤维损伤,获得高质量碳纤维金属基复合材料。The invention provides an ultrasonic device and a preparation method for preparing continuous carbon fiber metal matrix composite materials. The cooling efficiency of the equipment is high, which changes the current situation that carbon fiber and metal liquid are in contact for a long time and carbon fiber damage is large during the preparation of carbon fiber metal matrix composite materials. The degree of dispersion in the metal liquid reduces the time required for carbon fiber dispersion, thereby reducing carbon fiber damage and obtaining high-quality carbon fiber metal matrix composites.
技术方案:Technical solutions:
一种制备碳纤维铝基复合材料的超声波装置,包括伺服系统、超声波振动系统、冷却系统和气体保护系统,其特征在于:伺服系统下端连接有金属杆,伺服系统内部装有电机,金属杆下端连接有连接件,连接件下端连接有超声波换能器,超声波换能器下端连接有超声波变幅杆,超声波变幅杆下端连接有超声波振头,所述超声波换能器通过信号线还连接有超声波发生器,超声波发生器、超声波换能器、超声波变幅杆和超声波振头组合成超声波振动系统,超声波振动系统下部设有熔炼保温炉,炉腔内部设有气体保护装置,坩埚置于气体保护装置内部,所述超声波变幅杆的周圈设有环形冷却装置,环形冷却装置的上端连接有导气管,导气管分别还连接有高压气体储存装置和气体保护装置,导气管、高压气体储存装置和环形冷却装置构成冷却系统,气体保护装置,导气管和高压气体储存装置构成气体保护系统,所述超声波振动系统一侧设置有提拉电机,提拉电机下端连接有弓形夹具。An ultrasonic device for preparing carbon fiber aluminum-based composite materials, including a servo system, an ultrasonic vibration system, a cooling system and a gas protection system, is characterized in that a metal rod is connected to the lower end of the servo system, a motor is installed inside the servo system, and the lower end of the metal rod is connected to There is a connecting piece, the lower end of the connecting piece is connected with an ultrasonic transducer, the lower end of the ultrasonic transducer is connected with an ultrasonic horn, and the lower end of the ultrasonic horn is connected with an ultrasonic vibration head, and the ultrasonic transducer is also connected with an ultrasonic transducer through a signal line. Generator, ultrasonic generator, ultrasonic transducer, ultrasonic horn and ultrasonic vibration head are combined to form an ultrasonic vibration system. The lower part of the ultrasonic vibration system is equipped with a melting and holding furnace, and a gas protection device is installed inside the furnace cavity. The crucible is placed in a gas protection device. Inside the device, the circumference of the ultrasonic horn is provided with an annular cooling device, the upper end of the annular cooling device is connected with an air guide tube, and the air guide tube is also connected with a high-pressure gas storage device and a gas protection device, the air guide tube, the high-pressure gas storage device A cooling system is formed with an annular cooling device, and a gas protection system is formed by a gas protection device, an air guide tube and a high-pressure gas storage device. A lifting motor is arranged on one side of the ultrasonic vibration system, and a bow-shaped clamp is connected to the lower end of the lifting motor.
所述连接件为周圈螺纹的连接件,与金属杆和超声波换能器通过螺纹扣固定。The connecting piece is a connecting piece with a circumferential thread, and is fixed with the metal rod and the ultrasonic transducer through a threaded buckle.
所述环形冷却装置为环形似“弹簧”螺旋状,上部形状为竖直向上状,下端部为封闭状态,朝向超声波变幅杆的方向布满圆孔。The annular cooling device is in the shape of a ring-like "spring" spiral, the upper part is vertically upward, and the lower end is closed, and is full of round holes facing the direction of the ultrasonic horn.
所述圆孔直径为1~4mm。The diameter of the circular hole is 1-4mm.
所述气体保护装置内侧朝向设有孔洞。Holes are provided on the inner side of the gas protection device.
所述气体保护装置内部中空有孔洞结构,孔径大小随着高度增加逐渐变大。The inside of the gas protection device is hollow and has a hole structure, and the size of the holes gradually becomes larger as the height increases.
所述弓形夹具具有一定预紧力。The bow-shaped clamp has a certain pre-tightening force.
一种制备单向碳纤维金属基复合材料的方法,其特征在于:坩埚内金属熔体熔化后,通过气体保护系统通入一定量的惰性保护气体;然后将固定在弓形夹具上的单向碳纤维用提拉电机放入坩埚内;同时用伺服系统将超声波振动系统精确定位于距离碳纤维一定高度的位置,施加一定时间及一定振幅振动,从而使单向碳纤维分散,金属熔体填充到碳纤维间隙,将碳纤维均匀包裹,制备成单向碳纤维金属基复合材料;最终利用伺服系统及提拉电机将单向碳纤维金属基复合材料及超声波振动系统移出冷却。A method for preparing unidirectional carbon fiber metal matrix composites, characterized in that: after the metal melt in the crucible is melted, a certain amount of inert protective gas is introduced through a gas protection system; Put the pulling motor into the crucible; at the same time, use the servo system to precisely position the ultrasonic vibration system at a certain height from the carbon fiber, apply a certain time and a certain amplitude of vibration, so that the unidirectional carbon fiber is dispersed, and the metal melt fills the carbon fiber gap. The carbon fiber is evenly wrapped and prepared into a unidirectional carbon fiber metal matrix composite material; finally, the unidirectional carbon fiber metal matrix composite material and the ultrasonic vibration system are removed for cooling by using a servo system and a lifting motor.
优点及效果:Advantages and effects:
本发明所述的制备装置相比于传统碳纤维金属基复合材料制备装置具有操作简洁、安全系数高的特性,本发明所述制备方法相比于传统制备方法具有碳纤维损伤小,碳纤维分散均匀且分散程度高,复合材料生产周期短、效率高,适合连续生产等优点,引入环形冷却装置很好地解决了传统的制备装置散热差的严重问题。Compared with the traditional carbon fiber metal matrix composite material preparation device, the preparation device of the present invention has the characteristics of simple operation and high safety factor. Compared with the traditional preparation method, the preparation method of the present invention has the advantages of small carbon fiber damage, uniform and dispersed carbon fiber High degree, short production cycle of composite materials, high efficiency, suitable for continuous production, etc., the introduction of annular cooling device has solved the serious problem of poor heat dissipation of traditional preparation devices.
附图说明Description of drawings
下面结合附图对本发明进行详细说明:The present invention is described in detail below in conjunction with accompanying drawing:
图1为连续碳纤维金属基复合材料超声波装置总体安装示意图。Figure 1 is a schematic diagram of the overall installation of the continuous carbon fiber metal matrix composite ultrasonic device.
所述标注为:1.伺服系统、2.超声波换能器、3.超声波变幅杆、4.导气管、5.高压气体储存装置、6.环形冷却装置、7.超声波振头、8.金属熔体、9.连续碳纤维、10.气体保护装置、11.熔炼保温炉、12.坩埚、13.弓形夹具、14.提拉电机、15.超声波发生器、16.连接件、17.金属杆。The labels are: 1. Servo system, 2. Ultrasonic transducer, 3. Ultrasonic horn, 4. Airway, 5. High-pressure gas storage device, 6. Annular cooling device, 7. Ultrasonic vibration head, 8. Metal melt, 9. Continuous carbon fiber, 10. Gas protection device, 11. Melting and holding furnace, 12. Crucible, 13. Bow fixture, 14. Lifting motor, 15. Ultrasonic generator, 16. Connector, 17. Metal pole.
具体实施方式Detailed ways
本发明提供一种制备连续碳纤维金属基复合材料的超声波装置及其制备方法,改变碳纤维金属基复合材料制备时碳纤维与金属液接触时间长,碳纤维损伤大的现状,提高碳纤维在金属液中分散程度,降低碳纤维分散所需时间,从而减小碳纤维损伤,获得高质量碳纤维金属基复合材料。The invention provides an ultrasonic device for preparing a continuous carbon fiber metal matrix composite material and a preparation method thereof, which can change the current situation that the carbon fiber is in contact with the metal liquid for a long time and the carbon fiber is damaged greatly during the preparation of the carbon fiber metal matrix composite material, and improve the degree of dispersion of the carbon fiber in the metal liquid , reduce the time required for carbon fiber dispersion, thereby reducing carbon fiber damage, and obtaining high-quality carbon fiber metal matrix composites.
实施例:Example:
如图1所示,伺服系统1下端连接有金属杆17,伺服系统1内部装有电机,金属杆17可通过电机的控制,实现上、下、左、右、前和后的移动,金属杆17下端螺纹扣连接有连接件16,连接件16为周圈螺纹的连接件,与金属杆17和超声波换能器2通过螺纹扣固定,连接件16下端螺纹扣连接有超声波换能器2,连接件为周圈螺纹的连接件,可通过螺纹进入螺纹扣的长度微调超声波换能器2的高度,超声波换能器2下端螺纹扣连接有超声波变幅杆3,超声波变幅杆3下端螺纹扣连接有超声波振头7,所述超声波换能器2通过信号线还连接有超声波发生器15,用于发射超声波信号,超声波发生器15、超声波换能器2、超声波变幅杆3和超声波振头7组合成超声波振动系统,超声波振动系统下部设有熔炼保温炉11,炉腔内部设有气体保护装置10,气体保护装置10内侧朝向设有孔洞,孔洞结构孔径大小随着高度增加逐渐变大,坩埚12置于气体保护装置10内部,所述超声波变幅杆3的周圈设有环形冷却装置6,环形冷却装置6为环形似“弹簧”螺旋状,上部形状为竖直向上状,下端部为封闭状态,朝向超声波变幅杆3的方向布满1~4mm圆孔,环形冷却装置6的上端连接有导气管4,导气管4分别还连接有高压气体储存装置5和气体保护装置10,导气管4、高压气体储存装置5和环形冷却装置6构成冷却系统,气体保护装置10,导气管4和高压气体储存装置5构成气体保护系统,所述超声波振动系统一侧设置有提拉电机14,提拉电机14下端连接有具有一定预紧力的弓形夹具13。As shown in Figure 1, a metal rod 17 is connected to the lower end of the servo system 1, and a motor is installed inside the servo system 1. The metal rod 17 can be controlled by the motor to move up, down, left, right, forward and backward. The threaded buckle at the lower end of the 17 is connected with a connector 16, the connector 16 is a connector with a circumferential thread, and is fixed with the metal rod 17 and the ultrasonic transducer 2 by a threaded buckle, and the threaded buckle at the lower end of the connector 16 is connected with the ultrasonic transducer 2, The connecting piece is a connecting piece with a circumferential thread, and the height of the ultrasonic transducer 2 can be fine-tuned through the length of the thread into the threaded buckle. The buckle is connected with an ultrasonic vibration head 7, and the ultrasonic transducer 2 is also connected with an ultrasonic generator 15 through a signal line for transmitting ultrasonic signals. The ultrasonic generator 15, the ultrasonic transducer 2, the ultrasonic horn 3 and the ultrasonic wave The vibration heads 7 are combined into an ultrasonic vibration system. The lower part of the ultrasonic vibration system is provided with a melting and holding furnace 11. A gas protection device 10 is provided inside the furnace cavity. A hole is provided on the inner side of the gas protection device 10. The diameter of the hole structure gradually changes as the height increases. Large, the crucible 12 is placed inside the gas protection device 10, the circumference of the ultrasonic horn 3 is provided with an annular cooling device 6, the annular cooling device 6 is in the shape of a "spring" spiral, and the upper part is vertically upward. The lower end is in a closed state, and the direction of the ultrasonic horn 3 is covered with 1~4mm round holes. The upper end of the annular cooling device 6 is connected with an air guide tube 4, and the air guide tube 4 is also connected with a high-pressure gas storage device 5 and a gas protection device. 10. The air guide tube 4, the high-pressure gas storage device 5 and the annular cooling device 6 form a cooling system, the gas protection device 10, the air guide tube 4 and the high-pressure gas storage device 5 form a gas protection system, and one side of the ultrasonic vibration system is provided with a pull Motor 14, the lower end of the lifting motor 14 is connected with a bow clamp 13 with a certain pre-tightening force.
上述装置制备单向碳纤维金属基复合材料的方法:坩埚12内金属熔体8熔化后,通过气体保护系统通入一定量的惰性保护气体;然后将固定在弓形夹具13上的单向碳纤维9用提拉电机14放入坩埚内;同时用伺服系统1将超声波振动系统精确定位于距离碳纤维一定高度的位置,施加一定时间及一定振幅振动,从而使单向碳纤维9分散,金属熔体8填充到碳纤维间隙,将碳纤维均匀包裹,制备成单向碳纤维金属基复合材料;最终利用伺服系统及提拉电机将单向碳纤维金属基复合材料及超声波振动系统移出冷却。The method for preparing unidirectional carbon fiber metal matrix composites by the above-mentioned device: After the metal melt 8 in the crucible 12 is melted, a certain amount of inert protective gas is introduced through the gas protection system; then the unidirectional carbon fiber 9 fixed on the bow-shaped fixture 13 is used Put the pulling motor 14 into the crucible; at the same time, use the servo system 1 to precisely locate the ultrasonic vibration system at a certain height from the carbon fiber, and apply vibration for a certain period of time and with a certain amplitude, so that the unidirectional carbon fiber 9 is dispersed, and the metal melt 8 is filled into the crucible. In the carbon fiber gap, the carbon fiber is evenly wrapped to prepare a unidirectional carbon fiber metal matrix composite material; finally, the unidirectional carbon fiber metal matrix composite material and the ultrasonic vibration system are removed for cooling by using a servo system and a lifting motor.
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