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CN107245656B - A kind of the fin steel and its CSP production technology of excellent surface quality - Google Patents

A kind of the fin steel and its CSP production technology of excellent surface quality Download PDF

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Publication number
CN107245656B
CN107245656B CN201710455371.2A CN201710455371A CN107245656B CN 107245656 B CN107245656 B CN 107245656B CN 201710455371 A CN201710455371 A CN 201710455371A CN 107245656 B CN107245656 B CN 107245656B
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steel
section
rolling
fin
surface quality
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CN107245656A (en
Inventor
王成
郑海涛
谭佳梅
张超
刘义滔
宋波
赵敏
叶飞
张俊志
邱晨
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Wuhan Iron and Steel Co Ltd
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Wuhan Iron and Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

A kind of fin steel of excellent surface quality, component and wt% are as follows: C: it is no more than 0.01%, Mn:0.18~0.30%, Si:0~0.02%, Als: is no more than 0.005%, P:0~0.03%, S:0~0.01%, N:0.002~0.007%.Its technique: converter smelting;The refining of LF furnace;Slab enters soaking pit soaking;Using high-pressure water descaling;Before the rolling of each rack, first starts gap cooling water, carry out finish rolling using seven rack units afterwards;Section cooling;It batches.It is on the high side that the present invention solves fin steel oxidation iron sheet defect, and strip steel head and tail portion hit coiling clamp roller in the case where losing a state and generate the deficiency of roll marks defect, and the advantage of abbreviated system is given full play to, the coil of strip entire volume thickness and precision produced is fluctuated in 30 μm, entire volume length direction strength fluctuation within 20Mpa.

Description

A kind of the fin steel and its CSP production technology of excellent surface quality
Technical field
The present invention relates to a kind of ultra-low-carbon steel and its CSP production technologies, particularly belong to a kind of fin of excellent surface quality Steel and its CSP manufacturing technique method.
Background technique
Fin steel is the raw material of finned heat exchanger.The one kind of finned heat exchanger as heat-exchange device, is changed by it Hot cell is similar to fin and gains the name, and is mainly used for air in drying system and heats, is the capital equipment in hot air apparatus.Thermal medium It can be steam or hot water, it is also possible to which conduction oil is passed because, around piece, radiating fin and heat-dissipating pipe contact surface are big and tight using machinery Hot property is good, stablizes, and air is small by preventing, and heat exchange efficiency is high.For energy-saving and environment-friendly demand, fin output of steel in recent years Steady-state growth at home.Fin steel belongs to ultra-low-carbon steel, subsequent to carry out pickling, slitting and composite rolling, special use Way and manufacturing process, Surface Quality, plate shape, thickness and precision etc. require harsh.Surface is not allow for iron scale, greasy dirt, roller The defects of print, the problems such as bubble, peeling are otherwise easily generated in subsequent clad-rolling process, seriously affect composite rolling effect Fruit.
Before making the present invention, fin steel is produced mainly using traditional hot rolling producing line production using heavy slab.Using Traditional heavy slab and conventional hot rolling producing line are produced, and existing deficiency is: (1) product thickness precision is low: after fin steel Continuous process flow is pickling, slitting, composite rolling, and transverse direction and longitudinal direction thickness difference is no more than 30 μm after customer requirement slitting, institute It is very high to require hot rolling stock roll thickness and precision, it is desirable that convexity is no more than 50 μm, and wedge shape is no more than 20 μm, and longitudinal thickness is poor It must control within 30 μm, conventional hot rolling producing line is difficult to fully meet;(2) properties of product uniformity is poor: wanting when composite rolling Long rolling load fluctuation of demanding perfection is small, it is desirable that hot rolling stock roll overall length strength fluctuation is within 30MPa, and conventional hot rolling producing line is because rising The reason of speed rolling, cause strip end to end and middle portion temperature there are certain deviations, therefore overall length performance inconsistency is larger;(3) exist Edge upwarping defect: when conventional hot rolling producing line produces, within edge 15-30mm there are edge upwarping defect, on the one hand Lumber recovery is lower, on the other hand also results in more quality objection and complains and compensate;(4) production cycle is long: connecing and orders from contract Coil of strip delivery generally needs 1 month time, hands over phase more urgent contract for customer requirement, it is difficult to which punctual delivery meets visitor Family requires.
CSP production line is the sheet billet continuous casting and rolling production line of a new generation, and, pulling rate short with process be fast, steel-making steel rolling Rigid connection, the features such as constant speed rolling temperature uniformity is good.It produces under this process condition, product thickness precision is high, performance wave Move small, plate shape is excellent, while entering furnace to hot rolled coil offline only several hours time, specific condition lower delivery cycle from molten iron It is short, it can preferably meet customer need.To give full play to thin slab continuous casting and rolling producing line advantage, preferably meet customer need, Fin steel is transplanted to the production of CSP producing line.But when using CSP technique production fin steel, there are following deficiencies: (1) iron scale Defect: the heating method and rolling mill practice of CSP producing line soaking pit are different from conventional hot rolling producing line, while dephosphorization equipment ability is again not And conventional hot rolling producing line, scale defect control are always the weak link of continuous casting and rolling technique of sheet bar.On the one hand it influences Fin steel coil pickled surface quality;On the other hand, many defect frames are formed on CSP surface quality detection instrument, influence is mingled with, Checking and identifying for the other defects such as greasy dirt, easily leads to defect and fails to judge, and generates corrresponding quality objection.(2) coiling clamp roller roll marks Defect: since fin steel steel is partially soft, strip steel head is easy to form coiler pinch-roll and hit, cause in high-speed wind-up The fractionlet etc. that strip steel head is peeled off is adhered to plus send roller surface, in subsequent coiling process, is pressed into belt steel surface, forms roller Print defect.Iron scale and coiling clamp roller roll marks defect problem seriously constrain opening for the such high value added product of CSP producing line Hair and propulsion.
Through retrieving, at present seldom there are above-mentioned surface quality problems, especially coiling clamp roller roll marks in routine hot rolling producing line Defect.And similar CSP producing line is without the knowhow of similar fin steel, the solution that can not refer to and learn from.
Summary of the invention
It is an object of the invention to overcome the shortcomings of the prior art, solution fin steel oxidation iron sheet defect is on the high side, with And strip steel head and tail portion hit coiling clamp roller in the case where losing a state and generate the deficiency of roll marks defect, and give full play to short stream The advantage of journey technique, provide plate shape is excellent, thickness and precision fluctuation 30 μm, performance uniformity it is good, entire volume length direction intensity wave Move the fin steel and its CSP manufacturing technique method of the excellent surface quality for meeting downstream Customer Quality requirement within 20Mpa.
Realize the measure of above-mentioned purpose:
A kind of fin steel of excellent surface quality, component and weight percent content are as follows: C: it is no more than 0.01%, Mn: 0.18~0.30%, Si:0~0.02%, Als: be no more than 0.005%, P:0~0.03%, S:0~0.01%, N:0.002~ 0.007%, remaining is Fe and inevitable impurity.
Preferably: the weight percent content of C are as follows: 0.003 ~ 0.01%.
Preferably: the weight percent content of Mn are as follows: 0.20 ~ 0.30%.
Preferably: the weight percent content of N are as follows: 0.003~0.007%.
A kind of CSP production technology of the fin steel of excellent surface quality, step:
1) converter smelting is carried out, and controls P≤0.0015% in endpoint molten steel;
2) it is refined in LF furnace, and carries out RH application of vacuum, be cast into base in CSP conticaster later, control slab is thick Degree is 70mm;
3) slab enters soaking pit progress soaking, controls slab tapping temperature at 1110~1140 DEG C;Time inside furnace does not surpass Cross 35min;
Soaking pit takes " two-part " heating, it may be assumed that 1 ~ 5 section be bringing-up section, heating rate in 15 ~ 25 DEG C/min, and Each section of air-fuel ratio is controlled in this stage 1.2 ~ 1.3;6 ~ 10 sections are soaking zone, control in this stage each section of air-fuel ratio 1.3 ~ 1.4;
4) it using high-pressure water descaling to casting billet surface non-oxidation iron sheet, and controls de-scaling water inlet pressure and is not less than 200bar, outlet pressure are not less than 240bar;
5) before the rolling of each rack, first start gap cooling water;And finish rolling is carried out using seven rack units, control its end Temperature is rolled at 880 ~ 920 DEG C;Strip steel head plate speed is controlled within 8.0m/s;
It is that 17, F3 setting value is that F1 setting value is 12, F2 setting value by adjustment F1-F4 rack roll gap cooling water timing 21.5, F4 setting values are 26;
6) section cooling is carried out, therebetween, leading portion opens the mode that a valve closes a valve using the interval type of cooling;And in steel The length direction of band takes both ends low, the high coiling temperature mode of rest part, that is, take the lead and each 10m length of tail in, it is cold But coiling temperature extremely is at 570 ~ 590 DEG C, and the cooling coiling temperature of rest part is at 610 ~ 630 DEG C.
7) it is batched.
The mechanism and effect of each element and main technique in the present invention:
C: in the present invention, the purpose for selecting Ultra-low carbon design is ferritic structure as much as possible in order to obtain, to subtract Fe in few structure of steel3C phase, the excellent ferritic structure of plasticity and toughness are conducive to subsequent composite rolling.Meanwhile by C content control The solid solution C content hereinafter, as far as possible in reduction ferrite is made 0.01%, so that ferritic structure is obtained profound purification, favorably It is rolled in the subsequent metal composite good with ductility.
Mn: increasing the relative quantity of steel medium pearlite, and tissue made to attenuate, and improves intensity.In this steel grade, suitably reduction Mn Content, guarantee suitable intensity.Meanwhile suitable Mn can eliminate the adverse effect of S, from this point of view, Mn is beneficial Element, but when content is low, effect is not significant.Mn/S >=20 ~ 25 are generally required, control S in crystallization in the precipitation of crystal boundary, thus Reduce hot-short sensibility of the steel billet in hot rolling.Accordingly, control Mn content is 0.18 ~ 0.30%.
Si: increasing the intensity of steel, reduces the ductility of steel, is unfavorable for the follow-up cold deformation performance of strip, thus it is more low more It is good.Si content is controlled in the present invention 0~0.02%.
P: phosphorus is residual elements in steel, and maximum harm is that segregation is serious, increases temper brittleness, significantly reduces the modeling of steel Property and toughness, cause steel to be easy embrittlement namely so-called " cold short " phenomenon in cold working.Phosphorus also has adverse effect to weldability, It should strictly control, control P content is 0~0.03% in the present invention.
S: sulphur is segregated seriously in steel, deteriorates the quality of steel.At high temperature, the plasticity for reducing steel is a kind of harmful element, Easily lead to the hot-short phenomenon of steel.Therefore sulphur should be controlled strictly, control S content is 0~0.01% in the present invention.
Als: in the present invention, there is balance in Als content and O, according to the practical control situation of field trash, control in the present invention Als content is being no more than 0.005%.
Why the present invention controls 1 ~ 5 section of soaking pit as weak oxide atmosphere, and each section of air-fuel ratio is 1.2 ~ 1.3, soaking pit 6 ~ 10 sections are strong oxidizing property atmosphere, control each section of air-fuel ratio 1.3 ~ 1.4.It is, since the steel alloy content is seldom, in furnace Interior Mn, Si etc. are smaller to the structure and thickness effect of iron scale.So soaking pit leading portion uses weak oxide atmosphere, in bringing-up section Generate imperfect combustion product, CO and H2Concentration increase, inhibit H2O and CO2Oxidation to slab, while avoiding depositing in furnace gas In free oxonium ion, the iron scale based on FeO is formed in billet surface, and suitably reduce iron scale thickness.In back segment Using strong oxidizing property atmosphere, make the O in furnace gas2, CO2And H2O carries out Strong oxdiative to FeO, and FeO is converted into Fe2O3Based on The more loose iron scale of structure is easily removed convenient for subsequent de-scaling process.
Why the present invention uses leading portion interval cooling means (valve is opened, and a valve closes), is on the one hand to inhibit Thickness of the iron sheet in layer-cold roller way increases;On the other hand it is to cause thermal stress uneven in order to avoid continuously cold by force, is changed with reaching The purpose of kind plate shape.When back segment is cooling, more thicker iron scale three times can be formed in section cooling leading portion high temperature, and leading portion The cooling thickness for advantageously reducing iron scale.
Why the present invention opens F1-F4 rack roll gap cooling water in advance, is to reduce strip steel head temperature, Jin Erzeng Add strip steel head intensity, the probability of happening of meat is glued when reducing head impact coiling clamp roller.
Why in laminar flow, using ladder refrigerating mode, (namely the both ends temperature of steel band is low, rest part temperature by the present invention High mode), it controls in steel coil head and tail portion 10m length, at 570 ~ 590 DEG C, rest part temperature exists cooling temperature 610-630 DEG C, lost and hit under a state to reduce super low carbon soft steel head and tail portion to improve strip steel head and tail portion intensity It hits coiling clamp roller and causes viscous meat, reduce roll marks defect and change the original sentence to.
The present invention is compared with prior art:
First, the present invention is by shortening the reasonable of time inside furnace, low-temperature heat, furnace atmosphere optimization and the type of cooling Matching, obtains the strip that surface iron sheet is easy to pickling.
Second, the present invention solves super low carbon soft steel head by limitation strip steel head plate speed and head and tail temperature control The problem of hitting pinch roller under portion and tail portion mistake state, and being easy to generate viscous meat, lead to roll marks defect.
Third, the present invention plays the advantage of thin slab continuous casting and rolling abbreviated system, make full use of constant speed rolling temperature equal The good feature of even property keeps thickness and precision high, and performance uniformity is good, i.e. fluctuation is no more than 30 μm, entire volume length direction strength fluctuation Within 20Mpa, excellent surface quality, and it can be widely applied to finned heat exchanger with good thermally conductive, forming property Field.
Fourth, present invention process, production process control is stablized, and overcomes thin slab continuous casting and rolling producing line quality control on the surface The big disadvantage of difficulty solves the big technical bottleneck for restricting CSP producing line production super low carbon soft steel.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, convenient for more clearly understanding the present invention, but it Limiting the invention.
Table 1 is various embodiments of the present invention and comparative example chemical component comparative example;
Table 2 is the main technologic parameters list of various embodiments of the present invention and comparative example;
Table 3 is various embodiments of the present invention and comparative example thickness and precision, mechanics properties testing situation.
Various embodiments of the present invention are produced according to following technique:
1) converter smelting is carried out, and controls P≤0.0015% in endpoint molten steel;
2) it is refined in LF furnace, and carries out RH application of vacuum, be cast into base in CSP conticaster later, control slab is thick Degree is 70mm;
3) slab enters soaking pit progress soaking, controls slab tapping temperature at 1110~1140 DEG C;Time inside furnace does not surpass Cross 35min;
Soaking pit takes " two-part " heating, it may be assumed that 1 ~ 5 section be bringing-up section, heating rate in 15 ~ 25 DEG C/min, and Each section of air-fuel ratio is controlled in this stage 1.2 ~ 1.3;6 ~ 10 sections are soaking zone, control in this stage each section of air-fuel ratio 1.3 ~ 1.4;
4) it using high-pressure water descaling to casting billet surface non-oxidation iron sheet, and controls de-scaling water inlet pressure and is not less than 200bar, outlet pressure are not less than 240bar;
5) before the rolling of each rack, first start gap cooling water;And finish rolling is carried out using seven rack units, control its end Temperature is rolled at 880 ~ 920 DEG C;Strip steel head plate speed is controlled within 8.0m/s;
It is that 17, F3 setting value is that F1 setting value is 12, F2 setting value by adjustment F1-F4 rack roll gap cooling water timing 21.5, F4 setting values are 26;
6) section cooling is carried out, therebetween, leading portion opens the mode that a valve closes a valve using the interval type of cooling;And in steel The length direction of band takes both ends low, the high coiling temperature mode of rest part, that is, take the lead and each 10m length of tail in, it is cold But coiling temperature extremely is at 570 ~ 590 DEG C, and the cooling coiling temperature of rest part is at 610-630 DEG C.
7) it is batched.
Table 1 is the chemical component and its weight of Ultra-low carbon fin steel in invention Examples 1 to 10 and comparative example Percentage, surplus are Fe and inevitable impurity.
1 various embodiments of the present invention of table and comparative example chemical component comparative example (wt%)
2 various embodiments of the present invention of table and comparative example main technologic parameters list
3 various embodiments of the present invention of table and comparative example thickness and precision, mechanics properties testing situation
As seen from Table 3, within 30 μm, coil of strip overall length strength fluctuation exists the coil of strip overall length thickness fluctuation of each embodiment Within 20Mpa, and non-oxidation iron sheet, coiling clamp roller roll marks defect change the original sentence to plate shape and excellent surface quality.And comparative example 1 because Scale defect is changed the original sentence to, and comparative example 2 is changed the original sentence to because of coiling clamp roller roll marks defect.
Above-described embodiment is only the best example, rather than a limitation of the embodiments of the present invention.

Claims (1)

1. a kind of CSP production technology of the fin steel of excellent surface quality, step:
1) converter smelting is carried out, and controls P≤0.0015% in endpoint molten steel;
2) it is refined in LF furnace, and carries out RH application of vacuum, be cast into base in CSP conticaster later, control slab thickness is 70mm;
3) slab enters soaking pit progress soaking, controls slab tapping temperature at 1110~1140 DEG C;Time inside furnace is no more than 35min;
Soaking pit takes " two-part " heating, it may be assumed that 1 ~ 5 section is bringing-up section, and heating rate is controlled in 15 ~ 25 DEG C/min Each section of air-fuel ratio is 1.2 ~ 1.3 in this stage;6 ~ 10 sections are soaking zone, control in this stage each section of air-fuel ratio 1.3 ~ 1.4;
4) using high-pressure water descaling to casting billet surface non-oxidation iron sheet, and de-scaling water inlet pressure is controlled not less than 200bar, out Mouth pressure is not less than 240bar;
5) before the rolling of each rack, first start gap cooling water;And finish rolling is carried out using seven rack units, control its finish to gauge temperature Degree is at 880 ~ 920 DEG C;Strip steel head plate speed is controlled within 8.0m/s;
F1-F4 rack roll gap cooling water timing is adjusted, be 12, F2 setting value by F1 setting value be 17, F3 setting value is 21.5, F4 Setting value is 26;
6) section cooling is carried out, therebetween, leading portion opens the mode that a valve closes a valve using the interval type of cooling;And in steel band Length direction takes both ends low, the high coiling temperature mode of rest part, that is, take the lead and each 10m length of tail in, be cooled to Coiling temperature at 570 ~ 590 DEG C, the cooling coiling temperature of rest part is at 610 ~ 630 DEG C;
7) it is batched;
The fin steel of the excellent surface quality, component and weight percent content are as follows: C: be no more than 0.01%, Mn:0.18~ 0.30%, Si:0~0.02%, Als: be no more than 0.005%, P:0~0.03%, S:0~0.01%, N:0.002~0.007%, remaining For Fe and inevitable impurity.
CN201710455371.2A 2017-06-16 2017-06-16 A kind of the fin steel and its CSP production technology of excellent surface quality Active CN107245656B (en)

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CN1875124A (en) * 2003-11-05 2006-12-06 新日本制铁株式会社 Thin steel sheet excelling in surface property, moldability and workability and process for producing the same
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