CN107244816A - A kind of production technology of ultraviolet ray intercepting glass - Google Patents
A kind of production technology of ultraviolet ray intercepting glass Download PDFInfo
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- CN107244816A CN107244816A CN201710444528.1A CN201710444528A CN107244816A CN 107244816 A CN107244816 A CN 107244816A CN 201710444528 A CN201710444528 A CN 201710444528A CN 107244816 A CN107244816 A CN 107244816A
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- parts
- glass
- ultraviolet ray
- production technology
- ray intercepting
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- 239000011521 glass Substances 0.000 title claims abstract description 86
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 24
- 238000005516 engineering process Methods 0.000 title claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 239000000839 emulsion Substances 0.000 claims abstract description 32
- 238000010438 heat treatment Methods 0.000 claims abstract description 26
- 238000005342 ion exchange Methods 0.000 claims abstract description 24
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000002360 preparation method Methods 0.000 claims abstract description 20
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 17
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002253 acid Substances 0.000 claims abstract description 15
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 238000002203 pretreatment Methods 0.000 claims abstract description 10
- 238000010306 acid treatment Methods 0.000 claims abstract description 8
- 238000000137 annealing Methods 0.000 claims abstract description 8
- 238000007654 immersion Methods 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 14
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical class COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 229960000892 attapulgite Drugs 0.000 claims description 7
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 claims description 7
- 229910000024 caesium carbonate Inorganic materials 0.000 claims description 7
- 239000001110 calcium chloride Substances 0.000 claims description 7
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 7
- 229910052625 palygorskite Inorganic materials 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 7
- 239000003643 water by type Substances 0.000 claims description 7
- 235000010333 potassium nitrate Nutrition 0.000 claims description 6
- 239000004323 potassium nitrate Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
- 239000000834 fixative Substances 0.000 claims description 5
- 239000008103 glucose Substances 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 3
- 229930091371 Fructose Natural products 0.000 claims description 3
- 239000005715 Fructose Substances 0.000 claims description 3
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- -1 salicyl ester phenyl ester Chemical class 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims 2
- 239000005711 Benzoic acid Substances 0.000 claims 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000001103 potassium chloride Substances 0.000 claims 1
- 235000011164 potassium chloride Nutrition 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 4
- 238000002834 transmittance Methods 0.000 abstract description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- 235000019796 monopotassium phosphate Nutrition 0.000 description 5
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical class [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- HGRNRWNRNVPVMM-UHFFFAOYSA-N benzene-1,3-diol;benzoic acid Chemical compound OC1=CC=CC(O)=C1.OC(=O)C1=CC=CC=C1 HGRNRWNRNVPVMM-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000005308 flint glass Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/04—Tempering or quenching glass products using gas
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/26—Cellulose ethers
- C09D101/28—Alkyl ethers
- C09D101/286—Alkyl ethers substituted with acid radicals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Glass Compositions (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of production technology of ultraviolet ray intercepting glass, the production technology comprises the following steps：（1）The preparation of nanometer titanium dioxide silicon emulsion；（2）The preparation of antiultraviolet liquid；（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, preheat and be incubated；（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln；（5）The coating and heat treatment of antiultraviolet liquid：By the glass of ion-exchange treatment antiultraviolet liquid described in even spread while hot, it is re-fed into annealing furnace and is heat-treated；（6）It is cooled and shaped：Glass after heat treatment is sent into air grid, then the ultraviolet ray intercepting glass is made in natural cooling.Simple production process of the invention is controllable, is adapted to large-scale production, and the ultraviolet ray intercepting glass produced can efficiently obstruct ultraviolet, and fire resistance is excellent, and light transmittance is high, steady quality, deformation that long-time is heated and exposure will not bubble.
Description
Technical field
The present invention relates to safety glass technical field, and in particular to a kind of production technology of ultraviolet ray intercepting glass.
Background technology
Antiultraviolet composite fireproof glass is that fireprotection layer specific proportions dispensing can effectively end when being irradiated by ultraviolet
Ultraviolet and translucency is good；When fire occurs, fireprotection layer specific proportions dispensing will absorb fire in large quantities by foaming and intumescing
The heat of flame transmission, prevents the heat that burning is produced from counter-fire towards the transmission in the fiery face of the back of the body.In actual use, it is common compound anti-
It is weaker that flint glass penetrates obstructing capacity to ultraviolet, and fire-resistant fluid can become milky and generation under ultraviolet long-term irradiation
Steam bubble, loses the transparent functional of glass, therefore limits application.Common pad pasting or coating against UV-radiation glass are also because using
The limitation of the time limit, the particularly slightly higher occasion of sunshine equitemperature, its aging speed are constantly accelerated, and film layer, coating gradually go bad,
Effect weakens with the time.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of production work of ultraviolet ray intercepting glass
Skill, the technique is simply controllable, is adapted to large-scale production, and the ultraviolet ray intercepting glass produced can efficiently obstruct ultraviolet, fire resisting
Function admirable, light transmittance is high, steady quality, deformation that long-time is heated and exposure will not bubble.
The present invention solves technical problem and adopted the following technical scheme that：
A kind of production technology of ultraviolet ray intercepting glass, comprises the following steps：
（1）The preparation of nanometer titanium dioxide silicon emulsion：By weight, by 20~40 parts of glycerine, 20~30 parts of function monomers, 5
~10 parts of heat-resisting stabilizing agents, 3~8 parts of carbon forming agents, 1~5 part of anti ultraviolet agent, 30~40 parts of deionized waters, 20~30 parts of nanometers two
Silicon oxide particle is mixed evenly, and obtains the nanometer titanium dioxide silicon emulsion；
（2）The preparation of antiultraviolet liquid：By weight, by 50~80 parts of nanometer titanium dioxide silicon emulsions, 5~12 parts of biphosphates
Potassium, 1~5 part of fixative, 1~3 part of organic silicon modified by polyether, 6~10 parts of dipropylene glycol methyl ethers, 10~16 parts of carboxymethyl celluloses
Sodium is mixed evenly, and stands 20~30min, is filtrated to get the antiultraviolet liquid；
（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, be preheated to 360~380
DEG C and be incubated 30~40min；
（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln, 590~600 DEG C are heated to, ion is handed over
Change 15~18 hours；
（5）The coating and heat treatment of antiultraviolet liquid：By the glass of ion-exchange treatment antiultraviolet described in even spread while hot
Liquid, is re-fed into 680~700 DEG C of annealing furnace and is heat-treated, and the time of heat treatment is per 45~55s of mm of thickness；
（6）It is cooled and shaped：By the glass after heat treatment take out and with 400~450mm/s speed feeding air grid carry out it is air-cooled into
Type, is cooled to after 180~200 DEG C that the ultraviolet ray intercepting glass is made in natural cooling again.
Preferably, the function monomer in the silica emulsion is in acrylic acid, methacrylic acid or polyacrylamide
One or more combinations.
Preferably, the heat-resisting stabilizing agent in the silica emulsion is aluminium hydroxide, calcium hydroxide, borax, calcium oxide
In one or more combinations.
Preferably, the carbon forming agent in the silica emulsion is one or more groups in fructose, glucose, sucrose
Close.
Preferably, the anti ultraviolet agent in the silica emulsion is salicyl ester phenyl ester, 2,4-DihydroxyBenzophenone, 2-
One or more combinations in hydroxyl -4- oxy-octyl benzophenones, single benzoic acid resorcinol.
Preferably, the fixative is one or more combinations in zinc oxide, aluminum oxide, starch.
Preferably, the step（3）Acid solution is pressed for the hydrofluoric acid solution of concentration 15~20% with 5~10% salpeter solution
According to volume ratio 3:1 is formulated.
Preferably, the step（4）Caesium potassium salt soln includes the raw material of following parts by weight：20~30 parts of silver nitrate, nitric acid
10~20 parts of potassium, 5~10 parts of cesium nitrate, 1~5 part of calcium chloride, 2~8 parts of magnesium chloride, 10~20 parts of cesium carbonate, aluminum oxide 5~10
Part, 1~3 part of attapulgite.
Preferably, the step（6）Blast when air-cooled is 50~80Kpa, and centre wind pressure is 65~75Kpa.
Compared with prior art, the present invention has following beneficial effect：
（1）The production technology of the ultraviolet ray intercepting glass of the present invention, including the preparation of nanometer titanium dioxide silicon emulsion, antiultraviolet liquid
The step such as preparation, glass pre-treatment, ion-exchange treatment, the coating of antiultraviolet liquid and heat treatment, cooling and shaping, technique letter
It is single controllable, it is adapted to large-scale production, the ultraviolet ray intercepting glass produced can efficiently obstruct ultraviolet, and fire resistance is excellent, thoroughly
Light rate is high, steady quality, deformation that long-time is heated and exposure will not bubble.
（2）The antiultraviolet liquid of the present invention, by adding the material of several functions, such as heat-resisting stabilizing agent, carbon forming agent, anti-
Ultraviolet dose, nanometer silicon dioxide particle, dispersant, fixative, be both needed to simple mixing, filtering technique and obtain the anti-purple
Outside line liquid, possess be evenly distributed, a variety of advantages that heat-resisting cold-resistant, uvioresistant, light transmittance are high；Antiultraviolet liquid is simply coated on
After glass surface and heat treatment, glass surface will be compound in, will not change inside glass answers pressure and mechanical performance.
（3）The caesium potassium salt soln that uses of ion-exchange treatment of the present invention, due to potassium, caesium, etc. the ion of relatively large radius deposit
In the surface texture more compact of extruding glass surface generation stress glass.
（4）The air-cooled shaping different parts of the present invention use different wind pressures, further enhancing the mechanical property of glass
With thermal shock resistance, while avoid heated ultraviolet erosion time it is long when crimping burst problem, improve glass
Application and use value.
Embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1.
A kind of production technology of ultraviolet ray intercepting glass, comprises the following steps：
（1）The preparation of nanometer titanium dioxide silicon emulsion：By weight, by 28 parts of glycerine, 25 parts of acrylic acid, 8 parts of calcium hydroxide,
4 parts of glucose, 2 parts of 2-hydroxy-4-n-octoxybenzophenones, 36 parts of deionized waters, 25 parts of nanometer silicon dioxide particles mixing
Stir, obtain the nanometer titanium dioxide silicon emulsion.
（2）The preparation of antiultraviolet liquid：By weight, by 60 parts of nanometer titanium dioxide silicon emulsions, 7 parts of potassium dihydrogen phosphates, 2
Part zinc oxide, 1 part of organic silicon modified by polyether, 6 parts of dipropylene glycol methyl ethers, 12 parts of sodium carboxymethylcelluloses are mixed evenly, quiet
25min is put, the antiultraviolet liquid is filtrated to get.
（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, be preheated to 360
DEG C and be incubated 40min；Acid solution is the hydrofluoric acid solution and 8% salpeter solution of concentration 16% according to volume ratio 3:1 is formulated.
（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln, 590 DEG C, ion exchange are heated to
18 hours.Caesium potassium salt soln includes the raw material of following parts by weight：22 parts of silver nitrate, 13 parts of potassium nitrate, 7 parts of cesium nitrate, calcium chloride 2
Part, 6 parts of magnesium chloride, 15 parts of cesium carbonate, 5 parts of aluminum oxide, 3 parts of attapulgite.
（5）The coating and heat treatment of antiultraviolet liquid：By anti-purple described in the glass of ion-exchange treatment while hot even spread
Outside line liquid, is re-fed into 680~700 DEG C of annealing furnace and is heat-treated, and the time of heat treatment is per 45~55s of mm of thickness.
（6）It is cooled and shaped：Glass after heat treatment is taken out and sector-style is entered with 400~450mm/s speed feeding air grid
Cold forming, is cooled to after 180~200 DEG C that the ultraviolet ray intercepting glass is made in natural cooling again.Blast when air-cooled for 50~
80Kpa, centre wind pressure is 65~75Kpa.
Embodiment 2.
A kind of production technology of ultraviolet ray intercepting glass, comprises the following steps：
（1）The preparation of nanometer titanium dioxide silicon emulsion：By weight, by 30 parts of glycerine, 22 parts of polyacrylamides, 7 parts of hydrogen-oxygens
Change aluminium, 6 parts of sucrose, 2 parts of 2,4 dihydroxyl benzophenones, 38 parts of deionized waters, 25 parts of nanometer silicon dioxide particles to mix
Uniformly, the nanometer titanium dioxide silicon emulsion is obtained.
（2）The preparation of antiultraviolet liquid：By weight, by 56 parts of nanometer titanium dioxide silicon emulsions, 10 parts of potassium dihydrogen phosphates,
4 parts of starch, 3 parts of organic silicon modified by polyether, 7 parts of dipropylene glycol methyl ethers, 13 parts of sodium carboxymethylcelluloses are mixed evenly, and stand
20min, is filtrated to get the antiultraviolet liquid.
（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, be preheated to 372
DEG C and be incubated 36min；Acid solution is the hydrofluoric acid solution and 10% salpeter solution of concentration 17% according to volume ratio 3:1 prepare and
Into.
（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln, 596 DEG C, ion exchange are heated to
16 hours.Caesium potassium salt soln includes the raw material of following parts by weight：28 parts of silver nitrate, 18 parts of potassium nitrate, 8 parts of cesium nitrate, calcium chloride 1
Part, 3 parts of magnesium chloride, 12 parts of cesium carbonate, 8 parts of aluminum oxide, 3 parts of attapulgite.
（5）The coating and heat treatment of antiultraviolet liquid：By anti-purple described in the glass of ion-exchange treatment while hot even spread
Outside line liquid, is re-fed into 680~700 DEG C of annealing furnace and is heat-treated, and the time of heat treatment is per 45~55s of mm of thickness.
（6）It is cooled and shaped：Glass after heat treatment is taken out and sector-style is entered with 400~450mm/s speed feeding air grid
Cold forming, is cooled to after 180~200 DEG C that the ultraviolet ray intercepting glass is made in natural cooling again.Blast when air-cooled for 50~
80Kpa, centre wind pressure is 65~75Kpa.
Embodiment 3.
A kind of production technology of ultraviolet ray intercepting glass, comprises the following steps：
（1）The preparation of nanometer titanium dioxide silicon emulsion：By weight, by 30 parts of glycerine, 30 parts of methacrylic acids, 9 parts of boraxs,
7 parts of fructose, 5 parts of salicyl ester phenyl esters, 33 parts of deionized waters, 27 parts of nanometer silicon dioxide particles are mixed evenly, and obtain described
Nanometer titanium dioxide silicon emulsion.
（2）The preparation of antiultraviolet liquid：By weight, by 73 parts of nanometer titanium dioxide silicon emulsions, 7 parts of potassium dihydrogen phosphates, 4
Part aluminum oxide, 2 parts of organic silicon modified by polyether, 9 parts of dipropylene glycol methyl ethers, 15 parts of sodium carboxymethylcelluloses are mixed evenly, quiet
20~30min is put, the antiultraviolet liquid is filtrated to get.
（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, be preheated to 372
DEG C and be incubated 36min；Acid solution is the hydrofluoric acid solution and 8% salpeter solution of concentration 18% according to volume ratio 3:1 is formulated.
（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln, 597 DEG C, ion exchange are heated to
17 hours.Caesium potassium salt soln includes the raw material of following parts by weight：20 parts of silver nitrate, 13 parts of potassium nitrate, 8 parts of cesium nitrate, calcium chloride 4
Part, 7 parts of magnesium chloride, 18 parts of cesium carbonate, 6 parts of aluminum oxide, 2 parts of attapulgite.
（5）The coating and heat treatment of antiultraviolet liquid：By anti-purple described in the glass of ion-exchange treatment while hot even spread
Outside line liquid, is re-fed into 680~700 DEG C of annealing furnace and is heat-treated, and the time of heat treatment is per 45~55s of mm of thickness.
（6）It is cooled and shaped：Glass after heat treatment is taken out and sector-style is entered with 400~450mm/s speed feeding air grid
Cold forming, is cooled to after 180~200 DEG C that the ultraviolet ray intercepting glass is made in natural cooling again.Blast when air-cooled for 50~
80Kpa, centre wind pressure is 65~75Kpa.
Embodiment 4.
A kind of production technology of ultraviolet ray intercepting glass, comprises the following steps：
（1）The preparation of nanometer titanium dioxide silicon emulsion：By weight, by 38 parts of glycerine, 24 parts of acrylic acid, 9 parts of calcium oxide, 8
Part glucose, 5 parts of single benzoic acid resorcinols, 38 parts of deionized waters, 25 parts of nanometer silicon dioxide particles are mixed evenly,
Obtain the nanometer titanium dioxide silicon emulsion.
（2）The preparation of antiultraviolet liquid：By weight, by 77 parts of nanometer titanium dioxide silicon emulsions, 12 parts of potassium dihydrogen phosphates,
5 parts of starch, 3 parts of organic silicon modified by polyether, 10 parts of dipropylene glycol methyl ethers, 14 parts of sodium carboxymethylcelluloses are mixed evenly, quiet
30min is put, the antiultraviolet liquid is filtrated to get.
（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, be preheated to 380
DEG C and be incubated 40min；Acid solution is the hydrofluoric acid solution and 5% salpeter solution of concentration 20% according to volume ratio 3:1 is formulated.
（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln, 600 DEG C, ion exchange are heated to
18 hours.Caesium potassium salt soln includes the raw material of following parts by weight：30 parts of silver nitrate, 10 parts of potassium nitrate, 10 parts of cesium nitrate, calcium chloride
5 parts, 2 parts of magnesium chloride, 20 parts of cesium carbonate, 5 parts of aluminum oxide, 1 part of attapulgite.
（5）The coating and heat treatment of antiultraviolet liquid：By anti-purple described in the glass of ion-exchange treatment while hot even spread
Outside line liquid, is re-fed into 680~700 DEG C of annealing furnace and is heat-treated, and the time of heat treatment is per 45~55s of mm of thickness.
（6）It is cooled and shaped：Glass after heat treatment is taken out and sector-style is entered with 400~450mm/s speed feeding air grid
Cold forming, is cooled to after 180~200 DEG C that the ultraviolet ray intercepting glass is made in natural cooling again.Blast when air-cooled for 50~
80Kpa, centre wind pressure is 65~75Kpa.
Embodiment 5.
A kind of production technology of ultraviolet ray intercepting glass, comprises the following steps：
（1）The preparation of nanometer titanium dioxide silicon emulsion：By weight, by 40 parts of glycerine, 30 parts of polyacrylamides, 5 parts of boraxs,
8 parts of glucose, 1 part of anti ultraviolet agent, 40 parts of deionized waters, 30 parts of nanometer silicon dioxide particles are mixed evenly, and obtain described
Nanometer titanium dioxide silicon emulsion.
（2）The preparation of antiultraviolet liquid：By weight, by 80 parts of nanometer titanium dioxide silicon emulsions, 12 parts of potassium dihydrogen phosphates,
1 part of zinc oxide, 1 part of organic silicon modified by polyether, 6 parts of dipropylene glycol methyl ethers, 10 parts of sodium carboxymethylcelluloses are mixed evenly, quiet
20min is put, the antiultraviolet liquid is filtrated to get.
（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, be preheated to 360
DEG C and be incubated 40min；Acid solution is the hydrofluoric acid solution and 10% salpeter solution of concentration 15% according to volume ratio 3:1 prepare and
Into.
（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln, 600 DEG C, ion exchange are heated to
15 hours.Caesium potassium salt soln includes the raw material of following parts by weight：30 parts of silver nitrate, 10 parts of potassium nitrate, 10 parts of cesium nitrate, calcium chloride
1 part, 2 parts of magnesium chloride, 10 parts of cesium carbonate, 5 parts of aluminum oxide, 3 parts of attapulgite.
（5）The coating and heat treatment of antiultraviolet liquid：By anti-purple described in the glass of ion-exchange treatment while hot even spread
Outside line liquid, is re-fed into 680~700 DEG C of annealing furnace and is heat-treated, and the time of heat treatment is per 45~55s of mm of thickness.
（6）It is cooled and shaped：Glass after heat treatment is taken out and sector-style is entered with 400~450mm/s speed feeding air grid
Cold forming, is cooled to after 180~200 DEG C that the ultraviolet ray intercepting glass is made in natural cooling again.Blast when air-cooled for 50~
80Kpa, centre wind pressure is 65~75Kpa.
The production technology of the ultraviolet ray intercepting glass of the present invention, includes preparation, the antiultraviolet liquid of nanometer titanium dioxide silicon emulsion
Preparation, glass pre-treatment, ion-exchange treatment, the step, the technique such as the coating of antiultraviolet liquid and heat treatment, cooling and shaping
It is simple controllable, it is adapted to large-scale production, the ultraviolet ray intercepting glass produced can efficiently obstruct ultraviolet, and fire resistance is excellent,
Light transmittance is high, steady quality, deformation that long-time is heated and exposure will not bubble.
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, also should be regarded as the present invention
Protection domain.
Claims (9)
1. a kind of production technology of ultraviolet ray intercepting glass, it is characterised in that comprise the following steps：
（1）The preparation of nanometer titanium dioxide silicon emulsion：By weight, by 20~40 parts of glycerine, 20~30 parts of function monomers, 5
~10 parts of heat-resisting stabilizing agents, 3~8 parts of carbon forming agents, 1~5 part of anti ultraviolet agent, 30~40 parts of deionized waters, 20~30 parts of nanometers two
Silicon oxide particle is mixed evenly, and obtains the nanometer titanium dioxide silicon emulsion；
（2）The preparation of antiultraviolet liquid：By weight, by 50~80 parts of nanometer titanium dioxide silicon emulsions, 5~12 parts of biphosphates
Potassium, 1~5 part of fixative, 1~3 part of organic silicon modified by polyether, 6~10 parts of dipropylene glycol methyl ethers, 10~16 parts of carboxymethyl celluloses
Sodium is mixed evenly, and stands 20~30min, is filtrated to get the antiultraviolet liquid；
（3）Glass pre-treatment：Acid treatment is carried out to glass surface using acid solution, then cleans, dry, be preheated to 360~380
DEG C and be incubated 30~40min；
（4）Ion-exchange treatment：By the glass immersion after preheating in caesium potassium salt soln, 590~600 DEG C are heated to, ion is handed over
Change 15~18 hours；
（5）The coating and heat treatment of antiultraviolet liquid：By the glass of ion-exchange treatment antiultraviolet described in even spread while hot
Liquid, is re-fed into 680~700 DEG C of annealing furnace and is heat-treated, and the time of heat treatment is per 45~55s of mm of thickness；
（6）It is cooled and shaped：By the glass after heat treatment take out and with 400~450mm/s speed feeding air grid carry out it is air-cooled into
Type, is cooled to after 180~200 DEG C that the ultraviolet ray intercepting glass is made in natural cooling again.
2. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that in the silica emulsion
Function monomer be acrylic acid, methacrylic acid or polyacrylamide in one or more combinations.
3. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that in the silica emulsion
Heat-resisting stabilizing agent be aluminium hydroxide, calcium hydroxide, borax, calcium oxide in one or more combinations.
4. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that in the silica emulsion
Carbon forming agent be fructose, glucose, sucrose in one or more combinations.
5. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that in the silica emulsion
Anti ultraviolet agent be salicyl ester phenyl ester, 2,4 dihydroxyl benzophenone, 2-hydroxy-4-n-octoxybenzophenone, single benzoic acid
One or more combinations in resorcinol.
6. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that the fixative is oxidation
One or more combinations in zinc, aluminum oxide, starch.
7. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that the step（3）Acid solution
Hydrofluoric acid solution and 5~10% salpeter solution for concentration 15~20% is according to volume ratio 3:1 is formulated.
8. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that the step（4）Caesium sylvite
Solution includes the raw material of following parts by weight：20~30 parts of silver nitrate, 10~20 parts of potassium nitrate, 5~10 parts of cesium nitrate, calcium chloride 1
~5 parts, 2~8 parts of magnesium chloride, 10~20 parts of cesium carbonate, 5~10 parts of aluminum oxide, 1~3 part of attapulgite.
9. the production technology of ultraviolet ray intercepting glass according to claim 1, it is characterised in that the step（6）When air-cooled
Blast be 50~80Kpa, centre wind pressure be 65~75Kpa.
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|---|---|---|---|---|
| CN1800068A (en) * | 2005-12-15 | 2006-07-12 | 南京工业大学 | Transparent heat insulation glass |
| CN104291688A (en) * | 2014-09-03 | 2015-01-21 | 宁波市合鑫玻璃科技有限公司 | Processing technology for single-sheet cesium potassium fireproof glass |
| CN105295742A (en) * | 2015-11-18 | 2016-02-03 | 中国建筑材料科学研究总院 | Fire-proof glue of fire-proof glass, preparation method thereof and composite fire-proof glass |
| CN105313399A (en) * | 2014-06-20 | 2016-02-10 | 长沙金利盾节能科技有限公司 | Anti-ultraviolet heat-insulation glass film |
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2017
- 2017-06-13 CN CN201710444528.1A patent/CN107244816A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1800068A (en) * | 2005-12-15 | 2006-07-12 | 南京工业大学 | Transparent heat insulation glass |
| CN105313399A (en) * | 2014-06-20 | 2016-02-10 | 长沙金利盾节能科技有限公司 | Anti-ultraviolet heat-insulation glass film |
| CN104291688A (en) * | 2014-09-03 | 2015-01-21 | 宁波市合鑫玻璃科技有限公司 | Processing technology for single-sheet cesium potassium fireproof glass |
| CN105295742A (en) * | 2015-11-18 | 2016-02-03 | 中国建筑材料科学研究总院 | Fire-proof glue of fire-proof glass, preparation method thereof and composite fire-proof glass |
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Application publication date: 20171013 |