CN107225243A - A kind of foam metal material preparation method - Google Patents
A kind of foam metal material preparation method Download PDFInfo
- Publication number
- CN107225243A CN107225243A CN201710377466.7A CN201710377466A CN107225243A CN 107225243 A CN107225243 A CN 107225243A CN 201710377466 A CN201710377466 A CN 201710377466A CN 107225243 A CN107225243 A CN 107225243A
- Authority
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- Prior art keywords
- metal material
- foam metal
- powder
- foam
- scraper
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000006260 foam Substances 0.000 title description 36
- 239000007769 metal material Substances 0.000 title description 15
- 238000002360 preparation method Methods 0.000 title description 9
- 239000000843 powder Substances 0.000 description 23
- 229910052751 metal Inorganic materials 0.000 description 21
- 239000002184 metal Substances 0.000 description 21
- 238000000034 method Methods 0.000 description 10
- 239000011148 porous material Substances 0.000 description 9
- 238000010146 3D printing Methods 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 239000000428 dust Substances 0.000 description 8
- 238000000227 grinding Methods 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910001069 Ti alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000011800 void material Substances 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 238000009417 prefabrication Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000000110 selective laser sintering Methods 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 210000000080 chela (arthropods) Anatomy 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000005619 thermoelectricity Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/28—Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/70—Recycling
- B22F10/73—Recycling of powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/60—Planarisation devices; Compression devices
- B22F12/67—Blades
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
- B22F3/1103—Making porous workpieces or articles with particular physical characteristics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y50/00—Data acquisition or data processing for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/60—Treatment of workpieces or articles after build-up
- B22F10/64—Treatment of workpieces or articles after build-up by thermal means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/60—Treatment of workpieces or articles after build-up
- B22F10/66—Treatment of workpieces or articles after build-up by mechanical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- Powder Metallurgy (AREA)
Abstract
The present invention provides a kind of preparation method of foam metal material, controllable hole size can be obtained using the technique of 3D printing using metal dust and hole is distributed, obtain the second best in quality foam metal material, solve the problem of foam metal hole size and bad guarantee of its uniformity;And hole is distributed and shape can be designed the foam metal material for obtaining various performances according to the purposes of material.
Description
Technical field
The present invention relates to metal powder material field, more particularly to a kind of foam metal material preparation method.
Background technology
The characteristics such as the lightweight that foam metal material had both had with general porous material, have excellent mechanical performance again
With the physical property such as heat, electricity, and it is more easily regenerated into than polymeric foam, expands the application of porous material.With light weight,
It is a variety of physical compared with high specific strength, damping shock absorption, HI high impact energy absorption and excellent sound-absorbing, heat-insulated, radiating, electromagnetic shielding etc.
Can, oneself is applied in fields such as Aeronautics and Astronautics, automobile making, track traffics.In recent years, new technology, which develops, causes foam
The quality of metal is taken a favorable turn, and new diseases condition is also changed a lot.For example:In auto industry, due to peace
Increasingly increased demand in terms of complete and environmental protection, people start consideration and utilize foam metal.
Manufacture foam metal material can use the principle of the foam melt method method to be to add foaming agent in molten metal, make
Its heated produces is decomposed, and forms bubble in the solution, then cooled and solidified.It has the disadvantage that foaming process is difficult to control to, in solution
Foaming agent decompose and produce bubble, bubble gradually floats and the coalescence in floating-upward process, causes in product bubble distribution not
Uniform and local bubble size is excessive.Also shaft seal for powder, mixes a certain proportion of metal dust and blowing agent powder first,
Compacting obtains closely knit prefabrication, is then heat-treated near the fusing point of parent metal, decomposes foaming agent, discharged
Gas forces the prefabrication of compacting to be expanded into foam metal, and shaft seal for powder is easily controlled than foam melt method practical operation,
But hole size and its uniformity are also bad to be ensured.
Chinese patent 201010587152.8 is related to a kind of preparation method of foamed aluminium, and espespecially one kind need only once steep aluminium
Foam can be prepared by the method that a flux foaming of foam aluminum products prepares foamed aluminium, and step includes:Start thermoelectricity stove heat
Aluminium is completely melt to 800 DEG C;Toward addition calcium metal in aluminium liquid and stirred when cooling the temperature to 680 DEG C so that the surface of melt
Viscosity increase;Dose in melt and stirred so that titantium hydride is uniformly distributed in the melt after titantium hydride is pre-processed, filled
Decompose;Mould is heated, melt is put into the mould after Overheating Treatment, the thermal insulation foaming at a temperature of 650 DEG C,
Prefabricated component is taken out, air cooling makes high temperature foam melt shape in a mold, and prefabricated component then is taken out into water cooling, you can obtain foam
Aluminum products.Foam metal hole size made from this method and its uniformity are also bad to be ensured.
The content of the invention
The present invention provides a kind of preparation method of foam metal material, and the technique for using 3D printing using metal dust can be with
Controllable hole size and hole distribution are obtained, the second best in quality foam metal material is obtained, foam metal hole is solved big
The problem of small bad guarantee with its uniformity.And hole is distributed and shape can be designed according to the purposes of material and obtain various
The foam metal material of performance.
To achieve the above object, the technical solution adopted by the present invention is as follows:
A kind of foam metal material preparation method, using metal dust, foam cells size is prepared using 3D printing technique
Adjustable controllable foam metal material is distributed with hole.
Further, the preparation process is as follows:
1) technological design:Initially set up three-dimensional digital-to-analogue and import three-dimensional digital-to-analogue, then three-dimensional digital-to-analogue is layered, and
Build processing support;
2) prepare before processing;
3) part is printed, and is specifically included:
(a) powder feeding:Metal dust is sent into print job chamber from surplus powder chamber using scraper;
(b) powdering:Scraper carries out powdering with specific thicknesses;
(c) scraper is retracted:After the completion of powdering, scraper raises 1mm upwards, then retracts powdering original position;
(d) selective laser sintering:Start laser to be sintered the powder completed;
(e) (b), (c), (d) three step are repeated until part prints completion;
(f) excessive powder is reclaimed:After printing is completed, unnecessary powder is recycled;
4) part is post-processed.
Further, the void shape of the foam metal material is tetrahedron, hexahedron, dodecahedron, triangular prism, six ribs
Post or ellipse, pore size 0.1-6mm;Or the pore membrane structure of the foam metal material is triangle pore membrane, tetrahedral pore
Film, hexahedron pore membrane or dodecahedron pore membrane, pore membrane internal diameter size 0.1-5mm, 0.3-3mm of wall thickness;Or the foam metal
The space grid structure of material is spatial triangle truss or space tetrahedron truss.
Further, the metal dust be Cu, Ag, Ti, Zn, Al, stainless steel, Fe and its alloy powder any or
A variety of, the particle size range of metal dust is 20 μm -150 μm.
The distribution of foam metal material hole and shape prepared by the inventive method can be designed according to the purposes of material
To the foam metal material of various performances, and can solve foams slump in traditional preparation process, produce in foams crack,
The problems such as big cavity and thicker bubble-free layer being produced in foams.
Brief description of the drawings
The prism void shape foam aluminium alloy plate schematic diagrames of Fig. 1 six;
The tri-angle-holed film bubble foam titanium alloy schematic diagrames of Fig. 2;
Fig. 3 space truss stainless steel foam plate schematic diagrames.
Embodiment
Below by the drawings and specific embodiments, the present invention will be further described, but is not meant to present invention guarantor
Protect the limitation of scope.
The present invention provides a kind of preparation method of foam metal material, and specific implementation step is as follows:
1) technological design:Initially set up three-dimensional digital-to-analogue and import three-dimensional digital-to-analogue, then three-dimensional digital-to-analogue is layered, and
Build processing support;
2) prepare before processing:
(a) lathe is cleared up:3D printing lathe is cleaned out, it is ensured that free from foreign meter and other metal dusts;
(b) scraper levelness is corrected:Scraper levelness is corrected;
(c) protective gas is poured:Protection gas shielded is poured to continual in 3D printing lathe working chamber;
(d) metal dust is loaded:The powder for needing to print is fitted into 3D printing lathe working chamber;
(e) powder is tentatively paved by hand:Powder is tentatively paved by hand with scoop;
(f) powder is paved automatically:Lathe automatic power spreading function is opened, powder is further paved;
(g) powder level degree is corrected:Levelness to powder is tested and corrected
3) part is printed
(a) powder feeding:Metal dust is sent into print job chamber from surplus powder chamber using scraper;
(b) powdering:Scraper carries out powdering with specific thicknesses;
(c) scraper is retracted:After the completion of powdering, scraper raises 1mm upwards, then retracts powdering original position;
(d) selective laser sintering:Start laser to be sintered the powder completed;
(e) (b), (c), (d) three step are repeated until part prints completion;
(f) excessive powder is reclaimed:After printing is completed, unnecessary powder is recycled;
4) part is post-processed:
(a) polishing:Pincers worker carries out surface polishing to part;
(b) it is heat-treated:Printed part is made annealing treatment;
(c) blast:Destressing blast is carried out to the part after heat treatment;
5) examine:Product inspection is carried out to the part post-processed.
Specific embodiment is as follows:
Embodiment 1
Foamed Al-allov such as Fig. 1 is prepared, the three-dimensional digital-to-analogue of foamed material is set up, void shape is six prisms, and
Even distribution, is ready for 20 μm -50 μm of A356 Al alloy powders, is filled with nitrogen to 3D printing lathe and protects, Ran Houjin
Row part is printed, after part printing terminates, and polishing is carried out to part, and heat treatment is blown sand, examined.
Embodiment 2
Foam titanium alloy material such as Fig. 2 is prepared, the three-dimensional digital-to-analogue for setting up foamed material is tri-angle-holed membrane structure, and uniformly
Distribution, is ready for 50 μm of -100 μm of titanium alloy metal dusts, is filled with nitrogen to 3D printing lathe and protects, then carry out zero
Part is printed, after part printing terminates, and polishing is carried out to part, and heat treatment is blown sand, examined.
Embodiment 3
Stainless steel foam alloy material such as Fig. 3 is prepared, the three-dimensional digital-to-analogue of foamed material, spatial triangle truss knot is set up
Structure, is ready for 100 μm of -150 μm of stainless steel alloy metal dusts, is filled with nitrogen to 3D printing lathe and protects, Ran Houjin
Row part is printed, after part printing terminates, and polishing is carried out to part, and heat treatment is blown sand, examined.
Furthermore, it is necessary to illustrate, the specific embodiment described in this specification, its each several part title etc. can not
Together, the equivalent or simple change that all construction, feature and principles according to described in inventional idea of the present invention are done, is included in the present invention
In the protection domain of patent.Those skilled in the art can do various each to described specific embodiment
The modification of sample or supplement or using similar mode substitute, without departing from the present invention structure or surmount the claims
Defined scope, all should belong to protection scope of the present invention.
Claims (4)
1. a kind of foam metal material preparation method, it is characterised in that:Using metal dust, foam is prepared using 3D printing technique
Hole size and hole are distributed adjustable controllable foam metal material.
2. according to claim 1 foam metal material preparation method, it is characterised in that:Specific preparation process is as follows:
1) technological design:Initially set up three-dimensional digital-to-analogue and import three-dimensional digital-to-analogue, then three-dimensional digital-to-analogue is layered, and builds
Processing support;
2) prepare before processing;
3) part is printed, and is specifically included:
(a) powder feeding:Metal dust is sent into print job chamber from surplus powder chamber using scraper;
(b) powdering:Scraper carries out powdering with specific thicknesses;
(c) scraper is retracted:After the completion of powdering, scraper raises 1mm upwards, then retracts powdering original position;
(d) selective laser sintering:Start laser to be sintered the powder completed;
(e) (b), (c), (d) three step are repeated until part prints completion;
(f) excessive powder is reclaimed:After printing is completed, unnecessary powder is recycled;
4) part post processing and inspection.
3. according to any one of the claim 1-2 foam metal material preparation methods, it is characterised in that:The foam metal material
The void shape of material is tetrahedron, hexahedron, dodecahedron, triangular prism, six prisms or ellipse, pore size 0.1-6mm;Or
The pore membrane structure of the foam metal material is triangle pore membrane, tetrahedron pore membrane, hexahedron pore membrane or dodecahedron pore membrane, hole
Film internal diameter size 0.1-5mm, 0.3-3mm of wall thickness;Or the space grid structure of the foam metal material is spatial triangle
Truss or space tetrahedron truss.
4. according to any one of the claim 1-2 foam metal material preparation methods, it is characterised in that the metal dust is
Cu, Ag, Ti, Zn, Al, stainless steel, Fe and its alloy powder it is any or a variety of, the particle size range of metal dust is 20 μ
m-150μm。
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107855529A (en) * | 2017-12-23 | 2018-03-30 | 安徽金源家居工艺品有限公司 | A kind of preparation method of hanging chair stand blister steel |
CN110369724A (en) * | 2019-07-25 | 2019-10-25 | 北京科技大学 | A kind of 3D printing preparation method of high intensity, porous structural titanium alloy part |
CN111331138A (en) * | 2020-02-19 | 2020-06-26 | 北京锦灏科技有限公司 | Method for preparing foam metal thin-wall composite pipe with controllable filling density gradient |
CN111957970A (en) * | 2020-08-21 | 2020-11-20 | 南昌大学 | Porous titanium, preparation method and application thereof |
WO2021129552A1 (en) * | 2019-12-23 | 2021-07-01 | 宝山钢铁股份有限公司 | Metal matrix composite material and preparation method therefor |
WO2023123670A1 (en) * | 2021-12-30 | 2023-07-06 | 苏州大学 | Method for preparing closed-cell steel foam by means of laser additive manufacturing technique |
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CN105566891A (en) * | 2016-02-24 | 2016-05-11 | 江苏道勤新材料科技有限公司 | TPU-based foam 3D printing material |
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CN1652377A (en) * | 2004-02-06 | 2005-08-10 | 长沙力元新材料股份有限公司 | Special foamed nickel material |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107855529A (en) * | 2017-12-23 | 2018-03-30 | 安徽金源家居工艺品有限公司 | A kind of preparation method of hanging chair stand blister steel |
CN110369724A (en) * | 2019-07-25 | 2019-10-25 | 北京科技大学 | A kind of 3D printing preparation method of high intensity, porous structural titanium alloy part |
WO2021129552A1 (en) * | 2019-12-23 | 2021-07-01 | 宝山钢铁股份有限公司 | Metal matrix composite material and preparation method therefor |
CN111331138A (en) * | 2020-02-19 | 2020-06-26 | 北京锦灏科技有限公司 | Method for preparing foam metal thin-wall composite pipe with controllable filling density gradient |
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