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CN107213824A - A kind of method and device for manufacturing urea for vehicle solution - Google Patents

A kind of method and device for manufacturing urea for vehicle solution Download PDF

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Publication number
CN107213824A
CN107213824A CN201710488454.1A CN201710488454A CN107213824A CN 107213824 A CN107213824 A CN 107213824A CN 201710488454 A CN201710488454 A CN 201710488454A CN 107213824 A CN107213824 A CN 107213824A
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CN
China
Prior art keywords
urea
vehicle solution
concentration sensor
stirred tank
concentration
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Granted
Application number
CN201710488454.1A
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Chinese (zh)
Other versions
CN107213824B (en
Inventor
胡坚南
张庆堂
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Shandong Sealan Environmental Technology Co Ltd
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Shandong Sealan Environmental Technology Co Ltd
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Priority to CN201710488454.1A priority Critical patent/CN107213824B/en
Publication of CN107213824A publication Critical patent/CN107213824A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/90Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms 
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F21/00Dissolving
    • B01F21/10Dissolving using driven stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20Measuring; Control or regulation
    • B01F35/21Measuring
    • B01F35/211Measuring of the operational parameters
    • B01F35/2115Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20Measuring; Control or regulation
    • B01F35/21Measuring
    • B01F35/2132Concentration, pH, pOH, p(ION) or oxygen-demand

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a kind of method and device for manufacturing urea for vehicle solution, this method includes:(a) raw material is added;(b) urea granules dissolve;(c) data monitoring and amendment;(d) data are calculated;(e) pure water is increased;(f) repeat step (c) data monitoring and amendment;(g) urea for vehicle solution is exported.The device includes control system, stirred tank, the urea concentration sensor inside stirred tank and temperature sensor;The upper end of stirred tank is provided with inlet channel, and inlet channel is provided with first flowmeter, and urea concentration sensor and first flowmeter are electrically connected with control system;Control system includes data acquisition amending unit.In summary, a kind of method and device of manufacture urea for vehicle solution of the present invention, the qualified urea for vehicle solution of concentration can not only be produced, can also avoid due to manpower-free feed intake error and urea concentration sensor low temperature Monitoring Data it is inaccurate caused by the underproof problem of urea concentration.

Description

A kind of method and device for manufacturing urea for vehicle solution
Technical field
The invention belongs to urea for vehicle solution technique field, more particularly to a kind of method for manufacturing urea for vehicle solution and Device.
Background technology
In urea for vehicle solution production process, directly a certain amount of urea granules and ultra-pure water that measure are added and stirred Kettle is mixed, is mixed, stirred, you can the qualified urea for vehicle solution of concentration is obtained.In actual production, Manual material feeding process can Can occur surprisingly, such as urea granules are trickled down;Or there is certain difference between the urea amount of being actually loaded into and scalar quantity when dispatching from the factory in urea Not.Case above can all influence the concentration of urea for vehicle solution, cause the concentration of the urea for vehicle solution of production not meet and want Ask.
In the prior art, it is many that the concentration of urea liquid is monitored using urea concentration sensor, to ensure production The concentration of urea for vehicle solution is qualified.Due to needing constantly heat absorption in urea course of dissolution, the urea for vehicle just matched is molten The temperature of liquid is all than relatively low.The Monitoring Data of urea concentration sensor would generally be higher than the actual value of urea concentration under low temperature, by This error caused can influence the final quality of urea for vehicle solution.
The content of the invention
For disadvantages described above, first technical problem to be solved by this invention is:There is provided a kind of manufacture urea for vehicle molten The method of liquid, the qualified urea for vehicle solution of urea solubility can be produced using this method, reduce artificial operating mistake to urea The influence of solution concentration.
Second technical problem to be solved by this invention be:A kind of device for manufacturing urea for vehicle solution is provided, utilized The device can not only produce the qualified urea for vehicle solution of concentration, can also avoid due to manpower-free feed intake error and urea it is dense Spend sensor low temperature Monitoring Data and forbidden the caused underproof problem of urea concentration.
To solve above-mentioned first technical problem, the technical scheme is that:
A kind of method for manufacturing urea for vehicle solution, comprises the following steps:
(a) raw material is added:High purity water and urea granules are added into reactor, and monitor the addition of high purity water automatically: The high purity water of addition must not have urea granules, based on experience value the higher urea liquid of matched proportion density first;
(b) urea granules dissolve:Start motor to be stirred, until urea granules all dissolve;
(c) data monitoring and amendment:The concentration and temperature of urea for vehicle solution in reactor are monitored, and by data transfer It is modified to control system;
(d) data are calculated:According to the concentration of revised urea for vehicle solution and the amount of the high purity water added, control system System is automatic to be calculated, and matches the quality Δ m that qualified urea for vehicle solution also needs to the high purity water of additioni
(e) pure water is increased:The result calculated according to step (c), quantitative high purity water m is added into reactori, wherein mi ≤Δmi
(f) repeat step (c) data monitoring and amendment;
(g) urea for vehicle solution is exported:If the concentration of revised urea for vehicle solution is qualified, qualified automobile-used urine Plain solution is exported through liquid outlet, and the amount of the qualified urea for vehicle solution of automatic gauge;If unqualified, continue repeat step (d) with step (c) until producing the qualified urea for vehicle solution of concentration.
It is preferred that, in step (c) data monitoring and amendment, preset urea concentration sensor reading in control system The standard curve varied with temperature, record temperature urea concentration sensor reading ρ01With temperature sensor reading T01, to sighting target Directrix curve obtains the actual concentrations ρ of urea liquid1
It is preferred that, during step (d) data are calculated, the quality m of urea granules is added in calculation procedure (a) first0,
According toCalculate
Wherein m1To add the quality of high purity water for the first time, the reality for the first time after the conversion of the urea liquid of measurement is dense Spend ρ1
Secondly, the quality Δ m of high purity water will be added by calculating second2,
CalculateWherein ρ is molten for the urea for vehicle that needs are matched The concentration of liquid;
Similarly, the quality of the ith high purity water to be added can be calculated:
Wherein, Δ miThe theoretical value of the quality of the water added, m are needed for ithiThe matter for the water being actually added into for ith Amount;
Calculate
It is preferred that, in step (c) data monitoring and amendment, temperature sensor and concentration sensor in question response kettle Registration it is stable after, then carry out data acquisition.
To solve above-mentioned second technical problem, the technical scheme is that:
It is a kind of manufacture urea for vehicle solution device, including control system, stirred tank, inside the stirred tank Urea concentration sensor and temperature sensor;The upper end of the stirred tank is provided with inlet channel, and inlet channel is provided with first Flowmeter, the urea concentration sensor and first flowmeter are electrically connected with the control system;The control system includes Data acquisition amending unit.
As an improvement, the urea concentration sensor is infrared photosensitizing type urea concentration sensor;The stirred tank Interior to be provided with darkroom, the urea concentration sensor is arranged in the darkroom.
As an improvement, it is additionally provided with the stirred tank on pump, the pump and is connected with flush pipe, the flush pipe The other end is directed at the urea concentration sensor.
As an improvement, the inside of the stirred tank is additionally provided with liquid level meter, and liquid level meter is electrically connected with the control system Connect.
As an improvement, the upper end of the stirred tank is additionally provided with charging aperture, and lower end, which is provided with liquid outlet, liquid outlet, pacifies Fill second flowmeter.
As an improvement, the distance of the urea concentration sensor to the stirred tank bottom for 25cm to 35cm it Between.
Above-mentioned technical proposal is employed, the beneficial effects of the invention are as follows:
1st, using the concentration of the real-time monitoring car urea liquid of urea concentration sensor, the inflow of high purity water is adjusted, directly To producing the qualified urea for vehicle solution of urea concentration.Control system includes data acquisition amending unit, to solve urea The problem of concentration sensor low temperature Monitoring Data is forbidden.
2nd, the amount of the urea for vehicle solution manufactured by second flowmeter energy automatic gauge is utilized.
3rd, urea concentration sensor is arranged in darkroom, it is ensured that urea concentration sensor is not disturbed by ambient light, monitoring As a result it is more accurate, reliable.
In summary, the method and device of a kind of manufacture urea for vehicle solution of the invention, can not only produce concentration conjunction The urea for vehicle solution of lattice, can also be avoided because feed intake error and urea concentration sensor low temperature Monitoring Data of manpower-free is inaccurate The underproof problem of caused urea concentration.
Brief description of the drawings
Fig. 1 is a kind of structural representation of the device of manufacture urea for vehicle solution of the present invention;
Fig. 2 is the standard curve that urea concentration sensor reading is varied with temperature;
Wherein:1- stirred tanks, 11- inlet channels, 12- water intaking valves, 13- first flowmeters, 14- charging apertures, 15- goes out liquid Mouthful, 16- second flowmeters, 17- liquid valves, 2- urea concentration sensors, 3- temperature sensors, 4- liquid level meters, 5- darkrooms, 6- Rotating shaft, 7- stirring vanes, 8- motors, 9- pumps, 91- flush pipes.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with drawings and Examples, The present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only to explain the present invention, It is not intended to limit the present invention.
Embodiment
As shown in Figure 1, a kind of device for manufacturing urea for vehicle solution, including control system (not shown), stirred tank 1st, inside stirred tank 1 urea concentration sensor 2, temperature sensor 3 and liquid level meter 4.The upper end of stirred tank 1 is provided with Inlet channel 11, inlet channel 11 is provided with water intaking valve 12 and first flowmeter 13.The upper end of stirred tank 1 is additionally provided with charging aperture 14, lower end, which is provided with liquid outlet 15, liquid outlet 15, installs second flowmeter 16 and liquid valve 17.
As shown in Figure 1, urea concentration sensor 2 is infrared photosensitizing type urea concentration sensor.Provided with dark in stirred tank 1 Room 5, urea concentration sensor 2 is arranged in darkroom 5, it is ensured that urea concentration sensor 2 is not disturbed by ambient light, monitoring As a result it is more accurate, reliable.Urea concentration sensor 2 arrives the distance of the bottom of stirred tank 1 between 25cm to 35cm.The position The region that bottom urea is not completely dissolved can be not only avoided, also can guarantee that urea concentration sensor 2 is placed in urea liquid, make Obtain Monitoring Data more accurate, reliable.Be provided with rotating shaft 6 and the stirring vane 7 in rotating shaft 6 in stirred tank 1, rotating shaft 6 with It is arranged on the motor 8 outside stirred tank 1 and rotates connection.It is additionally provided with stirred tank 1 on pump 9, pump 9 and is connected with flush pipe 91, is rushed Wash the other end alignment urea concentration sensor 2 of pipe 91.The automobile-used urine that flush pipe 91 sprays in urea for vehicle solution production process Plain solution constantly impacts urea concentration sensor 2, and bubble can be prevented to be attracted to the surface of urea concentration sensor 2, and urea is dense The Monitoring Data for spending sensor 2 is more accurate.
Control system includes data acquisition amending unit (not shown).As shown in Figure 2, urea concentration sensor 2 is normal Data stabilization that the lower urea concentration sensor of temperature is measured and accurate, the data measured under low temperature are dense higher than the reality of urea liquid Degree.The standard curve that the preset reading of urea concentration sensor 2 is varied with temperature in data acquisition amending unit, to solve urea The problem of Monitoring Data is inaccurate under the low temperature of concentration sensor 2.Urea concentration sensor 2, water intaking valve 12, first flowmeter 13, Two flowmeters 16, liquid valve 17, liquid level meter 4, temperature sensor 3 and motor 8 are electrically connected with control system.
A kind of method for manufacturing urea for vehicle solution:Comprise the following steps:
(a) raw material is added:High purity water and urea granules are added into reactor, and monitor the addition of high purity water automatically: The high purity water of addition must not have urea granules, based on experience value the higher urea liquid of matched proportion density first.In general, The concentration requirement of urea for vehicle solution is 32.5%, then it is required that rule of thumb, the urea that the High-efficient Water at this moment added is produced The concentration of solution should be higher than 32.5%.
(b) urea granules dissolve:Start motor to be stirred, until urea granules all dissolve.Because urea granules are molten Solution is a process constantly absorbed heat, and generally about 20 minutes or so, treats the registration of temperature sensor and urea concentration sensor All stablize, illustrate that urea granules fully dissolve.
(c) data monitoring and amendment:Monitor the concentration and temperature of urea for vehicle solution in reactor, the middle temperature of question response kettle After the registration stabilization for spending sensor and concentration sensor, then carry out data acquisition.And transfer data to control system and repaiied Just;Record temperature urea concentration sensor reading ρ01With temperature sensor reading T01, reference standard curve acquisition urea liquid Actual concentrations ρ1
(d) data are calculated:According to the concentration of revised urea for vehicle solution and the amount of the high purity water added, control system System is automatic to be calculated, and matches the quality Δ m that qualified urea for vehicle solution also needs to the high purity water of additioni
The quality m of urea granules is added in calculation procedure (a) first0,
According toCalculate
Wherein m1To add the quality of high purity water for the first time, the reality for the first time after the conversion of the urea liquid of measurement is dense Spend ρ1
Secondly, the quality Δ m of second of high purity water to be added is calculated2,
CalculateWherein ρ is molten for the urea for vehicle that needs are matched The concentration of liquid;
Similarly, the amount of the ith high purity water to be added can be calculated:
Wherein, Δ miThe theoretical value of the quality of the water added, m are needed for ithiThe matter for the water being actually added into for ith Amount;
Calculate
(e) pure water is increased:The result calculated according to step (c), quantitative high purity water is added into reactor, is added high The quality m of pure water2≤Δm2.It is preferred in the present embodiment,
(f) repeat step (c):If the concentration of revised urea for vehicle solution is qualified, qualified urea for vehicle solution Exported through liquid outlet, and the amount of the qualified urea for vehicle solution of automatic gauge;If unqualified, continue repeat step (d) and step Suddenly (c) is until produce the qualified urea for vehicle solution of concentration.
By adding water and detecting several times, until the urea for vehicle solution of production reaches the concentration value that we require.
In summary, the method and device of a kind of manufacture urea for vehicle solution of the invention, can be avoided because manpower-free throws Expect that error and urea concentration sensor low temperature Monitoring Data are forbidden the caused underproof problem of urea for vehicle solution concentration, The concentration of the urea for vehicle solution produced is qualified, and quality is high.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in the scope of the protection.

Claims (10)

1. a kind of method for manufacturing urea for vehicle solution, it is characterised in that comprise the following steps:
(a) raw material is added:High purity water and urea granules are added into reactor, and monitor the addition of high purity water automatically:Add High purity water must not have urea granules, the higher urea liquid of matched proportion density first based on experience value;
(b) urea granules dissolve:Start motor to be stirred, until urea granules all dissolve;
(c) data monitoring and amendment:The concentration and temperature of urea for vehicle solution in reactor are monitored, and transfers data to control System is modified;
(d) data are calculated:According to the concentration of revised urea for vehicle solution and the amount of the high purity water added, control system is automatic Calculate, match the quality Δ m that qualified urea for vehicle solution also needs to the high purity water of additioni
(e) pure water is increased:The result calculated according to step (c), quantitative high purity water m is added into reactori, wherein mi≤Δ mi
(f) repeat step (c) data monitoring and amendment;
(g) urea for vehicle solution is exported:If the concentration of revised urea for vehicle solution is qualified, qualified urea for vehicle solution Exported through liquid outlet, and the amount of the qualified urea for vehicle solution of automatic gauge;If unqualified, continue repeat step (d) and step Suddenly (c) is until produce the qualified urea for vehicle solution of concentration.
2. the method for manufacture urea for vehicle solution according to claim 1, it is characterised in that:Step (c) the data prison In surveying and correcting, the standard curve that preset urea concentration sensor reading is varied with temperature in control system records temperature urea Concentration sensor reading ρ01With temperature sensor reading T01, the actual concentrations ρ of reference standard curve acquisition urea liquid1
3. the method for manufacture urea for vehicle solution according to claim 1, it is characterised in that:Step (d) the data meter In calculation,
The quality m of urea granules is added in calculation procedure (a) first0,
According toCalculate
Wherein m1To add the quality of high purity water, the actual concentrations ρ after the conversion of the urea liquid measured for the first time for the first time1
Secondly, the quality Δ m for the high purity water that second of needs is added is calculated2,
CalculateWherein ρ is dense for the urea for vehicle solution of needs proportioning Degree;
Similarly, can calculate ith will add the amount of high purity water:
Wherein, Δ miThe theoretical value of the quality of the water added, m are needed for ithiThe quality for the water being actually added into for ith;
Calculate
4. the method for manufacture urea for vehicle solution according to claim 1, it is characterised in that:Step (c) the data prison In surveying and correcting, after the registration of temperature sensor and concentration sensor is stable in question response kettle, then data acquisition is carried out.
5. a kind of device for being used to realize the manufacture urea for vehicle solution described in claim 1, it is characterised in that:Including control system System, stirred tank, the urea concentration sensor inside the stirred tank and temperature sensor;The upper end of the stirred tank is set Have an inlet channel, inlet channel is provided with first flowmeter, the urea concentration sensor and first flowmeter with the control System electrical connection processed;The control system includes data acquisition amending unit.
6. the device of manufacture urea for vehicle solution according to claim 5, it is characterised in that:The urea concentration sensor For infrared photosensitizing type urea concentration sensor;Darkroom is provided with the stirred tank, the urea concentration sensor is arranged on described In darkroom.
7. the device of manufacture urea for vehicle solution according to claim 5, it is characterised in that:It is additionally provided with the stirred tank Flush pipe is connected with pump, the pump, the other end of the flush pipe is directed at the urea concentration sensor.
8. the device of manufacture urea for vehicle solution according to claim 5, it is characterised in that:The inside of the stirred tank is also Provided with liquid level meter, liquid level meter is electrically connected with the control system.
9. the device of manufacture urea for vehicle solution according to claim 5, it is characterised in that:The upper end of the stirred tank is also Provided with charging aperture, lower end, which is provided with liquid outlet, liquid outlet, installs second flowmeter.
10. the device of manufacture urea for vehicle solution according to claim 5, it is characterised in that:The urea concentration sensing Device to the stirred tank bottom distance be 25cm to 35cm between.
CN201710488454.1A 2017-06-23 2017-06-23 Method and device for manufacturing urea solution for vehicle Active CN107213824B (en)

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Application Number Priority Date Filing Date Title
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CN107213824B CN107213824B (en) 2022-12-30

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107744730A (en) * 2017-11-07 2018-03-02 山东新蓝环保科技有限公司 A kind of quick manufacturing machine of urea for vehicle solution
CN108970461A (en) * 2018-09-07 2018-12-11 珠海格力智能装备有限公司 Agitating unit and have its urea machine
CN109126490A (en) * 2018-09-07 2019-01-04 珠海格力智能装备有限公司 Method and device for preparing urea solution
CN111589312A (en) * 2020-06-01 2020-08-28 珠海格力智能装备有限公司 Method and device for dissolving urea, storage medium, processor and stirring system
CN112426961A (en) * 2020-11-02 2021-03-02 珠海格力智能装备有限公司 Method and device for generating urea solution and system for generating urea solution

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Publication number Priority date Publication date Assignee Title
CN107744730A (en) * 2017-11-07 2018-03-02 山东新蓝环保科技有限公司 A kind of quick manufacturing machine of urea for vehicle solution
CN108970461A (en) * 2018-09-07 2018-12-11 珠海格力智能装备有限公司 Agitating unit and have its urea machine
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CN112426961A (en) * 2020-11-02 2021-03-02 珠海格力智能装备有限公司 Method and device for generating urea solution and system for generating urea solution

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