CN107213024A - Long-acting fragrance-retaining shower gel and preparation method thereof - Google Patents
Long-acting fragrance-retaining shower gel and preparation method thereof Download PDFInfo
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- CN107213024A CN107213024A CN201710524658.6A CN201710524658A CN107213024A CN 107213024 A CN107213024 A CN 107213024A CN 201710524658 A CN201710524658 A CN 201710524658A CN 107213024 A CN107213024 A CN 107213024A
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- aretaining
- shower cream
- fragrance
- essence
- longaacting fragrance
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- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000001879 gelation Methods 0.000 title 1
- 239000003205 fragrance Substances 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001993 wax Substances 0.000 claims abstract description 6
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 3
- 239000008367 deionised water Substances 0.000 claims abstract description 3
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 3
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 3
- 239000006071 cream Substances 0.000 claims description 57
- 239000012071 phase Substances 0.000 claims description 31
- -1 D-pantothenyl Chemical group 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 19
- 238000001816 cooling Methods 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000000470 constituent Substances 0.000 claims description 10
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 10
- 229920000053 polysorbate 80 Polymers 0.000 claims description 10
- 230000001804 emulsifying effect Effects 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 9
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 8
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000005642 Oleic acid Substances 0.000 claims description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 240000007817 Olea europaea Species 0.000 claims description 7
- 238000002470 solid-phase micro-extraction Methods 0.000 claims description 7
- 230000001954 sterilising effect Effects 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000000796 flavoring agent Substances 0.000 claims description 6
- 235000019634 flavors Nutrition 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 235000005979 Citrus limon Nutrition 0.000 claims description 5
- 244000131522 Citrus pyriformis Species 0.000 claims description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 235000019198 oils Nutrition 0.000 claims description 5
- 239000000600 sorbitol Substances 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 4
- 238000004458 analytical method Methods 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229940096992 potassium oleate Drugs 0.000 claims description 4
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims description 4
- 230000035807 sensation Effects 0.000 claims description 4
- 235000019615 sensations Nutrition 0.000 claims description 4
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 3
- 244000060011 Cocos nucifera Species 0.000 claims description 3
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 3
- 244000215777 Plumeria rubra Species 0.000 claims description 3
- 235000013087 Plumeria rubra Nutrition 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 235000018936 Vitellaria paradoxa Nutrition 0.000 claims description 3
- 241001135917 Vitellaria paradoxa Species 0.000 claims description 3
- 125000002252 acyl group Chemical group 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000004587 chromatography analysis Methods 0.000 claims description 3
- 238000004817 gas chromatography Methods 0.000 claims description 3
- 238000010813 internal standard method Methods 0.000 claims description 3
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 229940057910 shea butter Drugs 0.000 claims description 3
- 238000004088 simulation Methods 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 claims description 2
- 235000019489 Almond oil Nutrition 0.000 claims description 2
- 235000018330 Macadamia integrifolia Nutrition 0.000 claims description 2
- 240000000912 Macadamia tetraphylla Species 0.000 claims description 2
- 235000003800 Macadamia tetraphylla Nutrition 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims description 2
- 239000008168 almond oil Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 235000013871 bee wax Nutrition 0.000 claims description 2
- 239000012166 beeswax Substances 0.000 claims description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 239000010466 nut oil Substances 0.000 claims description 2
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- XXRYFVCIMARHRS-UHFFFAOYSA-N propan-2-yl n-dimethoxyphosphorylcarbamate Chemical compound COP(=O)(OC)NC(=O)OC(C)C XXRYFVCIMARHRS-UHFFFAOYSA-N 0.000 claims description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 2
- 229960003656 ricinoleic acid Drugs 0.000 claims description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 2
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 2
- 239000003760 tallow Substances 0.000 claims description 2
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims 2
- 235000011069 sorbitan monooleate Nutrition 0.000 claims 2
- 239000001593 sorbitan monooleate Substances 0.000 claims 2
- 229940035049 sorbitan monooleate Drugs 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 210000000481 breast Anatomy 0.000 claims 1
- 238000005260 corrosion Methods 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 239000004006 olive oil Substances 0.000 claims 1
- 235000008390 olive oil Nutrition 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 235000013599 spices Nutrition 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000002280 amphoteric surfactant Substances 0.000 abstract 1
- 239000003906 humectant Substances 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 description 9
- 239000003094 microcapsule Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000001514 detection method Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 102000004407 Lactalbumin Human genes 0.000 description 1
- 108090000942 Lactalbumin Proteins 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 125000003275 alpha amino acid group Chemical group 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/066—Multiple emulsions, e.g. water-in-oil-in-water
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a long-acting fragrance-retaining shower gel and a preparation method thereof. The long-acting fragrance-retaining shower gel is prepared from the following raw materials: A) a surfactant accounting for 2-45% of the component content; the surfactant is a mixture of two or more of anionic surfactant, amphoteric surfactant and nonionic surfactant; B) a humectant accounting for 0.1-15% of the component content; C) an emulsifier which accounts for 0.1-15% of the component content; D) waxes accounting for 1-10% of the component content; F) essence accounting for 0.1-5% of the components; G) deionized water is added to 100 percent, and all the components are in mass percent. The product of the invention has stable quality and pleasant fragrance, and the fragrance can last for 24 hours after use, thereby greatly improving the use feeling of the product after use.
Description
Technical field
The present invention relates to a kind of bathing liquid composition, belong to daily chemical products field, and in particular to a kind of Longaacting fragrance-aretaining is taken a shower
Dew and preparation method thereof.
Background technology
Shower cream can adjust the fragrance of product by adding the odorants such as essence, and increase product fragrance remaining time, and one
As by increasing odorant amount, or using the essence of encapsulation, the former is simple and easy to apply but product fragrance can be made excessively strong,
Consumer can not receive, and latter process is complicated, typically directly purchases the finished product of commercially available microencapsulation, this improves product cost,
Constrain the diversity of product to a certain extent simultaneously.
Chinese patent CN104263513A, is related to a kind of essence microcapsule wall material and essence microcapsule；And give the perfume
The preparation method of smart microcapsule wall material and essence microcapsule：Occur Maillard reaction using lactalbumin and glucose and prepare wall
Material, then by spray drying process prepared by essence microcapsule.
Chinese patent CN 104861935A provide a kind of preparation method of phase-change microcapsule, and substep is carried out to performed polymer
The pH value of emulsion is added dropwise and controls, the phase-change microcapsule excellent performance of preparation, breakage rate is low, and the free formaldehyde content of residual is low.
It is main at present to reach that fragrance sustained release is still needed in terms of realizing lasting lasting, but technology by micro-capsule package technology
Further to improve.
The content of the invention
It is an object of the invention to provide a kind of Longaacting fragrance-aretaining shower cream, it uses compounded technology, it is ensured that shower cream it is lasting
Lasting, especially under given use condition, simple and autotelic change compounding mode be that can reach, the present invention is main logical
Cross Recipe and multiple emulsion technology realizes that product continues lasting.
Another object of the present invention is to provide the preparation method of Longaacting fragrance-aretaining shower cream, production process can be achieved by essence
Deng microencapsulation, the polytropy of product fragrance is realized.
The object of the invention to solve the technical problems is realized using following technical scheme.According to present invention proposition
A kind of Longaacting fragrance-aretaining shower cream, by percentage to the quality, include following each component：
A the surfactant of constituent content 2~45%) is accounted for, the surfactant is anion surfactant, both sexes
The mixture of two or more in surfactant, nonionic surfactant；
B the NMF of constituent content 0.1~15%) is accounted for；
C the emulsifying agent of constituent content 0.1~15%) is accounted for；
D the wax class of constituent content 1~10%) is accounted for；
F the essence of constituent content 0.1~5%) is accounted for；
G deionized water) is added to 100%.
The Longaacting fragrance-aretaining shower cream of the present invention, the surfactant is amino acid type surfactant, betaine type table
Face activating agent
The Longaacting fragrance-aretaining shower cream of the present invention, the soap is olive potassium oleate, olive enuatrol etc..
The Longaacting fragrance-aretaining shower cream of the present invention, the NMF is macadamia nut oil, shea butter, Sweet Almond Oil, D-pantothenyl aleohol etc..
The Longaacting fragrance-aretaining shower cream of the present invention, the emulsifying agent is Tween-80, D-sorbite
Acid anhydride monoleate, monoglyceride, stearine etc..
The Longaacting fragrance-aretaining shower cream of the present invention, the emulsifying agent is Tween-80, D-sorbite
Acid anhydride monoleate, monoglyceride, stearine etc..
The Longaacting fragrance-aretaining shower cream of the present invention, described wax class is beeswax, mineral tallow, microwax etc..
The Longaacting fragrance-aretaining shower cream of the present invention, the essence is added in product process through phase-change microcapsule.
The Longaacting fragrance-aretaining shower cream of the present invention, also includes the acceptable preservative of shower cream, pigment.
The Longaacting fragrance-aretaining shower cream of the present invention, the preparation method of the essence is：
1) fresh flower flavor is gathered：Using SPME (solid phase microextraction, needle-like equipment), its top contains polymer and helps to inhale
Attached odourant molecules；
2) the crucial odourant molecules gathered in fresh flower are analyzed by " headspace analysis "；The fresh flower flavor of collection is put in
In one closed container, volatile component is evaporated from sample matrices by heat temperature raising, reached in gas-liquid two-phase
Balance, directly extract top gas progress chromatography so that in sample survey volatile component composition and content.
3) by instrument " decoding " odourant molecules, manual simulation's synthesized aroma is created frangipanis and bursted forth the essence of sensation.It is fragrant
Qi leel son " decoding " finger-print of sample fragrance is mainly obtained by internal standard method for gas chromatography, then analyze each feature into
The concrete content divided, essence is manually prepared according to these information.
The Longaacting fragrance-aretaining shower cream of the present invention, it is characterised in that the preparation method of the shower cream is comprised the steps of：
1) water, 6% glycerine, 10% olive potassium oleate are heated to 80-85 DEG C, are stirred well to and are completely dissolved, and are incubated 10-15
Minute, sterilizing, stirring cooling；
2) 80 DEG C are cooled to, 20% Cocoamidopropyl betaine, 1% coconut oleoyl amine DEA, 2% cocounut oil acyl is sequentially added
Amine MEA, 5% sodium lauroyl sarcosine, 4% cocounut oil acyl hydrolysis avenin potassium, are stirred well to and are completely dissolved uniform, cooling；
3) 50-55 DEG C is cooled to, 2% ricinoleic acid amide hydroxypropyltrimonium chloride, 1% shea butter is sequentially added,
It is stirred well to and is completely dissolved uniform, cooling；
4) 42-45 DEG C is cooled to, 4% paraffin, 1% essence, 5%Tween80 and the 6%Span80 emulsified in advance is added
Mixture, after stirring, remaining essence is added, with appropriate lemon acid for adjusting pH value, pH value (10% water of test
Solution)：8.00~8.50；
The present invention Longaacting fragrance-aretaining shower cream preparation method, it is characterised in that the step 4) each component be by with
Lower step is made：
1) once emulsify：By 1% essence, 4.5% atoleine and 5%Tween80 (polyoxyethylene sorbitol acid anhydride list oleic acid
Ester) aqueous solution mixing, homogeneous 2min obtains O/W type emulsions；
2) second emulsifying：1) obtained O/W type emulsions in are slowly added into containing 6%Span80 (sorbitan list oleic acid
Ester) atoleine in, stirring 5min obtain O/W/O type emulsions.By above-mentioned technical proposal, the present invention has advantages below：
1) by many experiments, it is surprisingly found that the aroma retaining effect of Longaacting fragrance-aretaining shower cream can be by above-mentioned preparing process
Change.The present invention has the compound structure for including another dispersed phase in a dispersed phase according to multi-phase emulsion, passes through second emulsifying
Method constructs O1/W/O2System, part essence is wrapped in introversion so that essence can be with pro-skin class material in use
Finally discharge, so as to increase the amount of arrheaing of essence.
2) essence used in is to modulate essence by SPME fragrance of a flower acquisition technique, and people can be allowed to experience the sensation that fresh flower bursts forth.
3) simple by permanent lasting shower cream preparation method of the invention, cost is relatively low, raw materials used cheap and easy to get.
Embodiment
Following examples are intended to illustrate invention rather than limitation of the invention further.Unless stated otherwise, this hair
Bright all percentages are all calculated with the weight/mass percentage composition of composition, and all proportions are mass percent.
Embodiment 1
A kind of Longaacting fragrance-aretaining shower cream, by percentage to the quality, includes each component shown in table 1 below：
The component formula (percentage by weight %) of the Longaacting fragrance-aretaining shower cream of table 1
Essence can be prepared as follows described in the present embodiment, or use commercially available IFF Living series fragrants
Essence.
The preparation method of the essence is：
1) fresh flower flavor is gathered：Using SPME (solid phase microextraction, needle-like equipment), its top contains polymer and helps to inhale
Attached odourant molecules；
2) the crucial odourant molecules gathered in fresh flower are analyzed by " headspace analysis "；The fresh flower flavor of collection is put in
In one closed container, volatile component is evaporated from sample matrices by heat temperature raising, reached in gas-liquid two-phase
Balance, directly extract top gas progress chromatography so that in sample survey volatile component composition and content.
3) by instrument " decoding " odourant molecules, manual simulation's synthesized aroma is created frangipanis and bursted forth the essence of sensation.It is fragrant
Qi leel son " decoding " finger-print of sample fragrance is mainly obtained by internal standard method for gas chromatography, then analyze each feature into
The concrete content divided, essence is manually prepared according to these information.
The preparation method of the Longaacting fragrance-aretaining shower cream of above-described embodiment, comprises the following steps：
1) A heat phases are stirred well to and are completely dissolved to 80-85 DEG C, are incubated 10-15 minutes, sterilizing, stirring drop
Temperature；
2) 80 DEG C are cooled to, B phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
3) 50-55 DEG C is cooled to, C phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
4) 42-45 DEG C is cooled to, the D phases emulsified in advance are added, after stirring, remaining essence is added, uses
Appropriate lemon acid for adjusting pH value, pH value (10% aqueous solution of test)：8.00~8.50；
Remarks：D phases carry out second emulsifying in advance：
1) once emulsify：By 0.5% essence, 4.5% atoleine and 5%Tween80 (polyoxyethylene sorbitol acid anhydride list oil
Acid esters) aqueous solution mixing.Homogeneous 2min, obtains O/W type emulsions.
2) second emulsifying：1) obtained O/W type emulsions in are slowly added into 6% (the sorbitan list oleic acid containing Span80
Ester) atoleine in, stirring 5min obtain O/W/O type emulsions.
5) sample, detection is qualified rear canned.
Embodiment 2
A kind of Longaacting fragrance-aretaining shower cream, by percentage to the quality, includes each component as shown in table 2 below：
The component formula (percentage by weight %) of the Longaacting fragrance-aretaining shower cream of table 2
The essence of the present embodiment is using the serial essence of commercially available IFF Living.
The preparation method of the Longaacting fragrance-aretaining shower cream of above-described embodiment, comprises the following steps：
1) A heat phases are stirred well to and are completely dissolved to 80-85 DEG C, are incubated 10-15 minutes, sterilizing, stirring drop
Temperature；
2) 80 DEG C are cooled to, B phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
3) 50-55 DEG C is cooled to, C phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
4) 42-45 DEG C is cooled to, the D phases emulsified in advance are added, after stirring, is adjusted with appropriate citric acid
PH value, pH value (10% aqueous solution of test)：8.00~8.50；
Remarks：D phases carry out second emulsifying in advance：
1) once emulsify：By 1% essence, 4.5% atoleine and 5%Tween80 (polyoxyethylene sorbitol acid anhydride list oleic acid
Ester) aqueous solution mixing.Homogeneous 2min, obtains O/W type emulsions.
2) second emulsifying：1) obtained O/W type emulsions in are slowly added into 6% (the sorbitan list oleic acid containing Span80
Ester) atoleine in, stirring 5min obtain O/W/O type emulsions.
5) sample, detection is qualified rear canned.
Embodiment 3
A kind of Longaacting fragrance-aretaining shower cream, by percentage to the quality, includes each component shown in table 3 below：
The component formula (percentage by weight %) of the Longaacting fragrance-aretaining shower cream of table 3
Essence described in the present embodiment is using the serial essence of commercially available IFF Living.
The preparation method of the Longaacting fragrance-aretaining shower cream of above-described embodiment, comprises the following steps：
1) A heat phases are stirred well to and are completely dissolved to 80-85 DEG C, are incubated 10-15 minutes, sterilizing, stirring drop
Temperature；
2) 80 DEG C are cooled to, B phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
3) 50-55 DEG C is cooled to, C phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
4) 42-45 DEG C is cooled to, the D phases emulsified in advance are added, after stirring, is adjusted with appropriate citric acid
PH value, pH value (10% aqueous solution of test)：8.00~8.50；
Remarks：D phases carry out second emulsifying in advance：
1) once emulsify：By 0.5% essence, 4% atoleine and 4%Tween80 (polyoxyethylene sorbitol acid anhydride list oleic acid
Ester) aqueous solution mixing.Homogeneous 2min, obtains O/W type emulsions.
2) second emulsifying：1) obtained O/W type emulsions in are slowly added into 6% (the sorbitan list oleic acid containing Span80
Ester) atoleine in, stirring 5min obtain O/W/O type emulsions.
5) sample, detection is qualified rear canned.
Comparative example 1
A kind of Longaacting fragrance-aretaining shower cream, by percentage to the quality, includes each component as shown in table 4 below：
The component formula (percentage by weight %) of the Longaacting fragrance-aretaining shower cream of table 4
The preparation method of above-mentioned Longaacting fragrance-aretaining shower cream, comprises the following steps：
The preparation method of the Longaacting fragrance-aretaining shower cream of above-described embodiment, comprises the following steps：
1) A heat phases are stirred well to and are completely dissolved to 80-85 DEG C, are incubated 10-15 minutes, sterilizing, stirring drop
Temperature；
2) 80 DEG C are cooled to, B phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
3) 50-55 DEG C is cooled to, C phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
4) 42-45 DEG C is cooled to, D phases are added, after stirring, with appropriate lemon acid for adjusting pH value, pH value (is surveyed
Try 10% aqueous solution)：8.00~8.50；
5) sample, detection is qualified rear canned.
Comparative example 2
A kind of Longaacting fragrance-aretaining shower cream, by percentage to the quality, includes each component as shown in table 5 below：
The component formula (percentage by weight %) of the Longaacting fragrance-aretaining shower cream of table 5
The preparation method of the Longaacting fragrance-aretaining shower cream of above-described embodiment, comprises the following steps：
1) A heat phases are stirred well to and are completely dissolved to 80-85 DEG C, are incubated 10-15 minutes, sterilizing, stirring drop
Temperature；
2) 80 DEG C are cooled to, B phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
3) 50-55 DEG C is cooled to, C phases are sequentially added, is stirred well to and is completely dissolved uniform, cooling；
4) 42-45 DEG C is cooled to, D phases are added, after stirring, with appropriate lemon acid for adjusting pH value, pH value (is surveyed
Try 10% aqueous solution)：8.00~8.50；
5) sample, detection is qualified rear canned.
It is effect application test example below.
Integrated and sentenced according to the test basis of QB1994-2004≤shower cream >=(adult type) and cosmetics safety technical specification
Determine principle, obtain following check conclusion as shown in table 6：
The cosmetics safety technical specification of table 6 is detected
From above-mentioned assay, Longaacting fragrance-aretaining shower cream produced by the present invention complies fully with adult type shower cream product
Requirement, and in the present invention, the Longaacting fragrance-aretaining shower cream pleasant aroma simultaneously can lasting lasting.
2nd, by the fragrance remaining time of shower cream made from 1-3 of embodiment of the present invention Longaacting fragrance-aretaining shower cream and comparative example 1,2
And fragrance preference degree test result see the table below shown in 7.
The embodiment 1-3 of table 7 and shower cream contrast test made from comparative example 1,2
| Title | Essence adds phase | Fragrance remaining time/hour | Fragrance likes degree min |
| Embodiment 1 | O1 | 26 | 8 |
| Embodiment 2 | O1 | 24 | 9 |
| Embodiment 3 | O1 | 24 | 9 |
| Comparative example 1 | O2 | 8 | 6 |
| Comparative example 2 | O1 | 3 | 8 |
From above-mentioned test result, after being handled through multiple emulsion, the lasting of Longaacting fragrance-aretaining shower cream produced by the present invention
Effect is up to more than 24 hours, and fragrance remaining time is 3 times of the fragrance remaining time of comparative example.Fragrance preference degree is also better than comparative example.
The above described is only a preferred embodiment of the present invention, any formal limitation not is made to the present invention, therefore
It is every without departing from technical solution of the present invention content, what the technical spirit according to the present invention was made to above example any simply repaiies
Change, equivalent variations and modification, in the range of still falling within technical solution of the present invention.
Claims (10)
1. a kind of Longaacting fragrance-aretaining shower cream, it is characterised in that by percentage to the quality, includes following each component：
A the surfactant of constituent content 2~45%) is accounted for, the surfactant is anion surfactant, amphoteric surface
The mixture of two or more in activating agent, nonionic surfactant；
B the NMF of constituent content 0.1~15%) is accounted for；
C the emulsifying agent of constituent content 0.1~15%) is accounted for；
D the wax class of constituent content 1~10%) is accounted for；
F the essence of constituent content 0.1~5%) is accounted for；
G deionized water) is added to 100%.
2. Longaacting fragrance-aretaining shower cream according to claim 1, it is characterised in that：The surfactant is olive oleic acid
Any two or two or more mixtures in potassium, olive enuatrol, soap.
3. Longaacting fragrance-aretaining shower cream according to claim 2, it is characterised in that：The soap is olive potassium oleate or olive oil
The mixing of sour sodium or both.
4. Longaacting fragrance-aretaining shower cream according to claim 1, it is characterised in that：The NMF is macadamia nut oil, breast wood fruit
The mixing of one or both of oil, Sweet Almond Oil, D-pantothenyl aleohol.
5. Longaacting fragrance-aretaining shower cream according to claim 1, it is characterised in that：The emulsifying agent is polyoxyethylene sorbitol
Acid anhydride monoleate, sorbitan monooleate, monoglyceride, stearine etc..
6. Longaacting fragrance-aretaining shower cream according to claim 1, it is characterised in that：Described wax class is beeswax, mineral tallow, crystallite
Wax etc..
Longaacting fragrance-aretaining shower cream according to claim 2, it is characterised in that：The essence is added in product process through phase
Become microencapsulation.
7. Longaacting fragrance-aretaining shower cream according to claim 1, it is characterised in that：Also include the acceptable anti-corrosion of shower cream
Agent, pigment.
8. Longaacting fragrance-aretaining shower cream according to claim 1, it is characterised in that：The preparation method of the essence is：
1) fresh flower flavor is gathered：Using SPME methods, solid phase microextraction, its top of the needle-like equipment are carried out using needle-like equipment
End helps to adsorb odourant molecules containing polymer；
2) the crucial odourant molecules gathered in fresh flower are analyzed by " headspace analysis "；The headspace analysis is specifically：Will
The fresh flower flavor of collection is put in a closed container, volatile component is volatilized from sample matrices by heat temperature raising
Come, balance is reached in gas-liquid two-phase, directly extract top gas and carry out chromatography, so that volatile component in sample survey
Composition and content；
3) by instrument " decoding " odourant molecules, manual simulation's synthesized aroma is created frangipanis and bursted forth the essence of sensation；The perfume (or spice)
Qi leel son " decoding " finger-print of sample fragrance is mainly obtained by internal standard method for gas chromatography, then analyze each feature into
The concrete content divided, essence is manually prepared according to these information.
9. a kind of preparation method of Longaacting fragrance-aretaining shower cream, it is characterised in that comprise the steps of：
1) water, 6% glycerine, 10% olive potassium oleate are heated to 80-85 DEG C, are stirred well to and are completely dissolved, 10-15 points of insulation
Clock, sterilizing, stirring cooling；
2) 80 DEG C are cooled to, 20% Cocoamidopropyl betaine, 1% coconut oleoyl amine DEA, 2% coconut oleoyl amine is sequentially added
MEA, 5% sodium lauroyl sarcosine, 4% cocounut oil acyl hydrolysis avenin potassium, are stirred well to and are completely dissolved uniform, cooling；
3) 50-55 DEG C is cooled to, 2% ricinoleic acid amide hydroxypropyltrimonium chloride, 1% shea butter is sequentially added, fully
Stirring is uniform to being completely dissolved, cooling；
4) 42-45 DEG C is cooled to, 4% paraffin, 1% essence, 5%Tween80 and the 6%Span80's that addition has been emulsified in advance is mixed
Compound, after stirring, adds remaining essence, and with appropriate lemon acid for adjusting pH value, (test 10% is water-soluble for pH value
Liquid)：8.00~8.50.
10. the preparation method of the Longaacting fragrance-aretaining shower cream described in claim 9, it is characterised in that the step 4) each component
Through the following steps that being made：
1) once emulsify：By 1% essence, 4.5% atoleine and 5%Tween80 (Tween-80)
The aqueous solution is mixed, and homogeneous 2min obtains O/W type emulsions；
2) second emulsifying：1) obtained O/W type emulsions in are slowly added into containing 6%Span80's (sorbitan monooleate)
In atoleine, stirring 5min obtains O/W/O type emulsions.
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