CN107200481A - A kind of preparation technology of glass surface metal wire-drawing effect film - Google Patents
A kind of preparation technology of glass surface metal wire-drawing effect film Download PDFInfo
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- CN107200481A CN107200481A CN201710443379.7A CN201710443379A CN107200481A CN 107200481 A CN107200481 A CN 107200481A CN 201710443379 A CN201710443379 A CN 201710443379A CN 107200481 A CN107200481 A CN 107200481A
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- Prior art keywords
- ink
- drawing effect
- agent
- preparation technology
- glass
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- 239000011521 glass Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 40
- 230000000694 effects Effects 0.000 title claims abstract description 39
- 238000005491 wire drawing Methods 0.000 title claims abstract description 38
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 34
- 239000002184 metal Substances 0.000 title claims abstract description 34
- 238000005516 engineering process Methods 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 37
- 229920002799 BoPET Polymers 0.000 claims abstract description 14
- 238000004513 sizing Methods 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 14
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 12
- 238000007639 printing Methods 0.000 claims abstract description 11
- 238000005507 spraying Methods 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 239000004814 polyurethane Substances 0.000 claims description 28
- 229920002635 polyurethane Polymers 0.000 claims description 27
- 229920005989 resin Polymers 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 21
- 230000001235 sensitizing effect Effects 0.000 claims description 21
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- 239000007822 coupling agent Substances 0.000 claims description 11
- 239000003822 epoxy resin Substances 0.000 claims description 10
- 229920000647 polyepoxide Polymers 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 9
- 125000000524 functional group Chemical group 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- -1 chloride acrylic ester Chemical class 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 235000021050 feed intake Nutrition 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- WYRGOSDNPFGZFG-UHFFFAOYSA-K [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] hydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate propan-2-olate titanium(4+) Chemical compound [Ti+4].CC(C)[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)([O-])=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O WYRGOSDNPFGZFG-UHFFFAOYSA-K 0.000 claims description 3
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
- PSGCQDPCAWOCSH-BOURZNODSA-N exo-1,7,7-Trimethylbicyclo(2.2.1)hept-2-yl acrylate Chemical compound C1C[C@]2(C)C(OC(=O)C=C)C[C@H]1C2(C)C PSGCQDPCAWOCSH-BOURZNODSA-N 0.000 claims description 2
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 21
- 238000001723 curing Methods 0.000 description 9
- 238000012545 processing Methods 0.000 description 7
- 238000012546 transfer Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
- C03C17/322—Polyurethanes or polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
- C03C17/324—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
- C03C17/326—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Geochemistry & Mineralogy (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of preparation technology of glass surface metal wire-drawing effect film, including：S01：First UV ink rollers are applied on PET film, roll marks goes out wire-drawing effect thereon, semi-solid preparation sizing is carried out using LED/light source, carry out all solidstate sizing using ultraviolet mercury lamp after cooling；S02：The 2nd UV ink is coated in glass substrate surface, the PET film wire-drawing effect side pressure after solidifying in S01 steps is printed on the UV ink wet films of glass baseplate, semi-solid preparation sizing is carried out using LED/light source, removes PET film, then all solidstate sizing is carried out using ultraviolet mercury lamp；S03：Spraying or printing heat curing-type metal ink on the glass baseplate for completing S02 steps；S04：Spraying or printing closing ink on the glass baseplate for completing S03 steps.The preparation technology of metal wire-drawing effect film in the present invention has prepared the film layer with metal wire-drawing effect true to nature in glass article surface, and not only outward appearance is beautiful changeable, and technique is simple, with low cost, environmentally safe.
Description
Technical field
The invention belongs to glass material surface processing technique, and in particular to a kind of glass surface metal based on UV ink is drawn
The preparation technology of silk effect film.
Background technology
Metal wire-drawing effect is that showing has by being machined a kind of special visual effect formed in metal surface
The strain line of certain rule sense, the metal-like of complexed metal material in itself makes wire drawing process surface show the sight of high-grade luxury
Sense.Because metal wire-drawing effect in various processing decoration fields have received liking for consumer, it is widely used in various products
Appearance design in, such as 3C electronic products, ornament, household appliances.Metal wire-drawing effect is presented the completeest in metal surface
U.S., but in practical application area, the component in many products can not use metal material, if these non-metal items surfaces
Obtain metal wire-drawing effect just relatively difficult.In order to solve above-mentioned problem, in non-metallic materials such as wide variety of plastic cement, glass
The decorative cover with metal wire-drawing effect is also made in material surface, and many producers have developed corresponding technical scheme.Glass material
It is, in wide variety of common used materials such as 3C electronic products, small household appliances, daily adornment fields, to be especially used for above-mentioned field production
The appearance of product.
The decorative cover with metal wire-drawing effect is prepared often through silk-screen printing on glass material surface in the prior art
Mode prepare, the design of wire-drawing effect is carried out by the pattern to silk screen, so that by silk-screen printing technique in glass material
Expect that surface obtains the ink layer with wire-drawing effect, the defect of this method is that the silk screen used in the prior art is all plane silk
Net, it is impossible to form stereoeffect true to nature, to reach stereoeffect more true to nature, then needs what is printed using multilayer UV ink
After mode, i.e. one layer of ink of silk-screen, treat its solidification and then again in one layer of ink of its surface silk-screen, then solidified, be repeated several times
After could obtain preferable pattern, the process costs are in the increase of geometry multiple, because not only will be using heat UV curing at double
Ink, in addition it is also necessary to spend substantial amounts of cost to be used to design integrated artistic flow, and propose the new technology such as multilayer overprinting process
Problem.
Then the problem of to solve multi-sheet printed bring, many processing producers propose directly etching glass article surface again
Special-effect lines is made in the method for carrying out ink spraying, and this method has destructiveness to glass article surface, does not possess extensively
Applicability, and hydrofluoric acid is used glass erosion liquid more, environmental pollution is overweight.Also researcher proposes to use thermal transfer work
Decorative layer is mounted on glass material surface by skill, carrier film that will be with figure line decorative layer by way of heating and pressurizeing,
Decorative layer is set to depart from carrier film so as to be transferred on material body using the cohesive force between glass material surface and decorative layer, this
The subject matter of the method for kind is that decorative layer invests glass material surface often through melt viscosity, when processing has space pattern
Glass material when, this method is difficult to meet demand.Meanwhile, PUR can send excessive organic gas in transfer process, right
Environment is polluted, and the decorative cover of transfer is easy to fall off after long-term use.
The content of the invention
The process with metal wire-drawing effect surface of outward appearance well is prepared on glass material surface for above-mentioned
In the problem of exist, the present invention to technical process improve that there is provided a kind of glass surface metal based on UV ink
The preparation technology of wire-drawing effect film, has been prepared in glass article surface by modified technique process and has been imitated with metal wire-drawing true to nature
The film layer of fruit, not only outward appearance is beautiful changeable, and technique is simple, with low cost, environmentally safe, process consistency is good, raw
Produce efficiency high, suitable for industrial mass production.
Effect in the present invention is realized by following scheme：
A kind of preparation technology of the glass surface metal wire-drawing effect film provided in the present invention, comprises the following steps：
S01：First UV ink rollers are applied on PET film, roll marks goes out wire-drawing effect thereon, semi-solid preparation is carried out using LED/light source
Sizing, carries out all solidstate sizing using ultraviolet mercury lamp after cooling；
S02：The 2nd UV ink is coated in glass substrate surface, the PET film wire-drawing effect side pressure after solidifying in S01 steps is printed on
On the UV ink wet films of glass baseplate, semi-solid preparation sizing is carried out using LED/light source, removes PET film, is then entered using ultraviolet mercury lamp
Row all solidstate is shaped；
S03：Spraying or printing heat curing-type metal ink on the glass baseplate for completing S02 steps, under the conditions of 150-170 DEG C
Baking 5-6 minutes；
S04：Spraying or printing closing ink, toast 7- under the conditions of 180-190 DEG C on the glass baseplate for completing S03 steps
10 minutes, obtain the glass that surface includes metal wire-drawing effect.
Further, LED/light source semi-solid preparation condition is in S01, S02 step：Using the LED/light source of 395-405nm wavelength,
Light source luminescent face power is 20-25W/cm2, hardening time is 10-12 seconds.All solidstate styling condition is in S01, S02 step：It is purple
Outer mercury lamp luminous intensity is 105-115mJ/cm2S, irradiation time is 3-5 minutes.
Further preferably, the first UV ink used in above-mentioned technique be high rigidity ink, by weight percentage, its into
Divide content as follows：
The pure third resin 20-30% of UV
Six functional groups aliphatic polyurethane 10-15%
Polyester chloride acrylic ester 10-15%
Epoxy resin 10-20%
Adhesive agent 2-4%
Monomer resin 15-30%
Sensitising agent 3-5%
Other auxiliary agents 1-2%
The preparation method of first UV ink is：First by the raw material in addition to sensitising agent according to pure third resins of UV, six functional groups
Aliphatic polyurethane, polyester chloride acrylic ester, epoxy resin, monomer resin, the order of other auxiliary agents feed intake successively, then stir
Mix it is uniform, be ground to after 1-3 μm and disperse 10-30 minutes under the conditions of 800-1500r/min；Then sensitising agent is put into, stirring is mixed
UV ink needed for being produced after closing uniformly.
Further, by weight percentage, its component content is as follows for the 2nd UV ink used in above-mentioned technique：
The pure third resin 20-30% of UV
Six functional groups aliphatic polyurethane and two functional group aliphatic polyurethane mixture 20-35%
Epoxy resin 20-30%
Adhesive agent 2-4%
Monomer resin 15-30%
Sensitising agent 3-5%
Other auxiliary agents 1-2%
Wherein, six functional groups aliphatic polyurethane and two functional group's aliphatic polyurethane mass ratioes are 1:（0.3-0.5）；
The preparation method of 2nd UV ink is：First by the raw material in addition to sensitising agent according to pure third resins of UV, six functional groups
Aliphatic polyurethane and two functional group's aliphatic polyurethane mixtures, polyester chloride acrylic ester, epoxy resin, monomer resin,
The order of other auxiliary agents feeds intake successively, then stirs, is ground to after 1-3 μm under the conditions of 800-1500r/min and disperses 10-
30 minutes；Then sensitising agent is put into, UV ink needed for being produced after being uniformly mixed.
Further preferably, the sensitising agent be light curing agent and coupling agent with（3-5）:1 composition, wherein light curing agent is
184th, tri- kinds of curing agent of ITS and TPO are with mass ratio 3:2:3 compositions, coupling agent is silane resin acceptor kh-550, KH-570, A-171
Or one kind in titanate coupling agent NDZ-201.
Further, the monomer resin is HDDA, TMPTA or IBOA.
Further, the six functional groups aliphatic polyurethane average weight-molecular mass is 1800-4500.
Further, other described auxiliary agents are organosilicon levelling agent.Still further preferably, the organosilicon levelling agent is moral
Modest 810 levelling agent.
The present invention has the advantages that：
1st, the process in the present invention can be obtained with metal true to nature drawing without carrying out destructive processing to glass baseplate
The appearance of silk effect.
2nd, the appearance with metal wire-drawing effect that the process in the present invention is prepared in glass substrate surface is not
It is only beautiful changeable, and technique is simple, with low cost, environmentally safe, process consistency is good, production efficiency is high, be applied to
Industrial mass production.
Embodiment
1st, the preparation of the first UV ink
The first UV ink is prepared in the present embodiment first.Using the preparation technology in the present invention, the first UV ink need to possess higher
Hardness and there is good separability with PET film, therefore be formulated using specific components, count by weight percentage, below
For the formula and composition of specific embodiment：
First UV ink hardness is high, not only good moldability, and easily being separated with PET film, meanwhile, in order to ensure technique in the present invention
The feature of environmental protection of process, uses high solid part composition ink, and the composition of the solid part of height is also beneficial to form relief film layer.
The light curing agent sensitising agent used in above-mentioned UV ink formulations be light curing agent and coupling agent with（3-5）:1 composition,
Wherein light curing agent is 184, tri- kinds of curing agent of ITS and TPO with mass ratio 3:2:3 compositions, coupling agent can use silane coupler
One kind in KH-550, KH-570, A-171 or titanate coupling agent NDZ-201, above-mentioned mixing sensitising agent and follow-up LED light
Source wavelength matches, and can effectively realize semi-cured state, coupling agent is used in conjunction with above-mentioned mixed curing agent can be effectively improved the first UV
The adhesive force of ink layer and the 2nd UV ink layers on glass material surface, is easy to follow-up technical process.For just in the present embodiment
In comparing, using silane resin acceptor kh-550, and using IBOA as monomer resin, used six functional groups aliphatic poly
Urethane average weight-molecular mass is 1800-4500, the six functional groups aliphatic polyurethane system of above-mentioned average weight-molecular mass
The viscosity and curing performance of the UV ink obtained best suit the requirement of process in the present invention.Other auxiliary agents used are modest for moral
810 levelling agents, all raw materials used are commercially available quality raw materials.
The preparation method of above-mentioned UV ink is：
First by the raw material in addition to sensitising agent according to pure third resins of UV, six functional groups aliphatic polyurethane, polyester chloride third
Olefin(e) acid ester, epoxy resin, monomer resin, the order of other auxiliary agents feed intake successively, then stir, be ground to after 1 μm
Disperse 20 minutes under the conditions of 1000r/min；Then sensitising agent is put into, UV ink needed for being produced after being uniformly mixed.
2nd, the preparation of the 2nd UV ink
Count by weight percentage, formula and composition below for specific embodiment：
In 2nd UV ink raw material selection it is identical with raw material in the first UV ink, its adhesive agent, monomer resin, sensitising agent, other
Auxiliary agent all selects identical with the formula in the first ink.Wherein, six functional groups aliphatic polyurethane and two functional group's aliphatic polies
Urethane mass ratio is 1:0.45.Using six functional groups aliphatic polyurethane and two functional groups fat in the 2nd UV ink of the present invention
The mixed mode of adoption urethane increases the quality of film forming, and the hardness of six functional groups aliphatic polyurethane main composition film forming makes attached
The film in glass surface has enough hardness, and two functional group's aliphatic polyurethanes can then be effectively improved the flexible of film forming
Property and adhesive force, to provide more convenient condition with fitting for the first UV film layers during following process, while also causing overall
Metal wire-drawing effect film after the completion of technique is more attractive, using more lasting.
The preparation method of above-mentioned UV ink is：
First by the raw material in addition to sensitising agent according to pure third resins of UV, six functional groups aliphatic polyurethane and two functional group's fat
Fat race polyurethane mixture, polyester chloride acrylic ester, epoxy resin, monomer resin, the order of other auxiliary agents feed intake successively, so
After stir, be ground to after 1 μm under the conditions of 1000r/min disperse 20 minutes；Then sensitising agent is put into, is uniformly mixed
After produce needed for UV ink.
The ductility of UV ink, processing characteristics and colour generation brightness consider made from summary, select No. 6 the oneth UV
Ink and No. 7 the 2nd UV ink carry out following technique.
3rd, the preparation of glass material surface metal wire-drawing effect film
From processing glass material, concrete technology step based on 10cm × 10cm × 5cm glass sheet in the present embodiment
It is as follows：
S01：First UV ink rollers are applied on PET film, roll marks goes out wire-drawing effect thereon, semi-solid preparation is carried out using LED/light source
Sizing, carries out all solidstate sizing using ultraviolet mercury lamp after cooling；
LED/light source semi-solid preparation condition is：Using the LED/light source of 395nm wavelength, light source luminescent face power is 22W/cm2, during solidification
Between be 10 seconds.All solidstate styling condition is：Ultraviolet mercury lamp luminous intensity is 105mJ/cm2S, irradiation time is 5 minutes.
S02：The 2nd UV ink is coated in glass substrate surface, by the PET film wire-drawing effect side pressure after solidifying in S01 steps
It is printed on the UV ink wet films of glass baseplate, carries out semi-solid preparation sizing using LED/light source, remove PET film, then utilize ultraviolet mercury
Lamp carries out all solidstate sizing；
LED/light source semi-solid preparation condition is：Using the LED/light source of 405nm wavelength, light source luminescent face power is 25W/cm2, during solidification
Between be 12 seconds.All solidstate styling condition is：Ultraviolet mercury lamp luminous intensity is 105mJ/cm2S, irradiation time is 5 minutes.
S03：Spraying or printing heat curing-type metal ink on the glass baseplate for completing S02 steps, under the conditions of 160 DEG C
Baking 5 minutes；The metal ink of different color and surface grain pattern can be selected in the step according to demand, with foregoing wire-drawing effect
Film is engaged the picture on surface for preparing more different patterns.
S04：Spraying or printing closing ink, 8 are toasted under the conditions of 180 DEG C on the glass baseplate for completing S03 steps
Minute, obtain the glass that surface includes metal wire-drawing effect.
By the glass sheet produced carries out adhesive force test, impact property test, normal temperature bubble is tested, water boils adhesive force
Test, comparative example is with the identical of 200 mesh steel mesh silk-screens using common UV ink of the prior art on identical material surface
Pattern.
Adhesion test method is：The pattern of transfer or printing to material surface carries out hundred lattice experiments, then uses
3M adhesive tapes are even drawn 5 times in same position.Impact property test method be：The pattern of transfer or printing to material surface enters
Row 500g weight 1m height freely falling body is tested.Normal temperature bubble is tested：The pattern of the transfer on material surface or printing is normal
Temperature is soaked into running water 24 hours, then carries out hundred lattice experiments, is then even drawn 5 times in same position using 3M adhesive tapes.Water is boiled
Adhesion test method is：Material is positioned in boiling water to boil hundred lattice experiments are carried out after 1 hour, then using 3M adhesive tapes identical
Even draw 5 times position.
Test result is as follows：
Attachment of the metal wire-drawing effect film that the method for the present invention is prepared it can be seen from test result on glass material surface
Power, shock resistance, anti-poor environment performance all as screen printing process product of the prior art, have fully met work
The demand of industry application, and the metal wire-drawing surface three-dimensional effect prepared of the inventive method is good a kind of aluminium sheet very true to nature
Wire-drawing effect, and upper mass-tone and the metal wire-drawing effect at grey bottom are too wide in the gap after comparative example silk-screen.The preparation provided in the present invention
Method efficiency high, green pollution-free, can greatly save cost, create good economic benefit and social benefit.
It is last it should be noted that above example is only entered to the technical scheme that illustrates the embodiment of the present invention rather than to it
Row limitation, although the embodiment of the present invention is described in detail with reference to preferred embodiment, one of ordinary skill in the art
It should be understood that the technical scheme of the embodiment of the present invention can still be modified or equivalent substitution, and these are changed or waited
It can not also make the scope of amended technical scheme disengaging technical scheme of the embodiment of the present invention with replacing.
Claims (10)
1. a kind of preparation technology of glass surface metal wire-drawing effect film, it is characterised in that comprise the following steps：
S01：First UV ink rollers are applied on PET film, roll marks goes out wire-drawing effect thereon, semi-solid preparation is carried out using LED/light source
Sizing, carries out all solidstate sizing using ultraviolet mercury lamp after cooling；
S02：The 2nd UV ink is coated in glass substrate surface, the PET film wire-drawing effect side pressure after solidifying in S01 steps is printed on
On the UV ink wet films of glass baseplate, semi-solid preparation sizing is carried out using LED/light source, removes PET film, is then entered using ultraviolet mercury lamp
Row all solidstate is shaped；
S03：Spraying or printing heat curing-type metal ink on the glass baseplate for completing S02 steps, under the conditions of 150-170 DEG C
Baking 5-6 minutes；
S04：Spraying or printing closing ink, toast 7- under the conditions of 180-190 DEG C on the glass baseplate for completing S03 steps
10 minutes, obtain the glass that surface includes metal wire-drawing effect.
2. preparation technology as claimed in claim 1, it is characterised in that：LED/light source semi-solid preparation condition is in S01, S02 step：Adopt
With the LED/light source of 395-405nm wavelength, light source luminescent face power is 20-25W/cm2, hardening time is 10-12 seconds.
3. preparation technology as claimed in claim 1, it is characterised in that：All solidstate styling condition is in S01, S02 step：Ultraviolet mercury
Intensity of light is 105-115mJ/cm2S, irradiation time is 3-5 minutes.
4. preparation technology as claimed in claim 1, it is characterised in that：
The first UV ink used in the technique is high rigidity ink, and by weight percentage, its component content is as follows：
The pure third resin 20-30% of UV
Six functional groups aliphatic polyurethane 10-15%
Polyester chloride acrylic ester 10-15%
Epoxy resin 10-20%
Adhesive agent 2-4%
Monomer resin 15-30%
Sensitising agent 3-5%
Other auxiliary agents 1-2%
The preparation method of first UV ink is：First by the raw material in addition to sensitising agent according to pure third resins of UV, six functional groups
Aliphatic polyurethane, polyester chloride acrylic ester, epoxy resin, monomer resin, the order of other auxiliary agents feed intake successively, then stir
Mix it is uniform, be ground to after 1-3 μm and disperse 10-30 minutes under the conditions of 800-1500r/min；Then sensitising agent is put into, stirring is mixed
UV ink needed for being produced after closing uniformly.
5. preparation technology as claimed in claim 1, it is characterised in that：
By weight percentage, its component content is as follows for the 2nd UV ink used in the technique：
The pure third resin 20-30% of UV
Six functional groups aliphatic polyurethane and two functional group aliphatic polyurethane mixture 20-35%
Epoxy resin 20-30%
Adhesive agent 2-4%
Monomer resin 15-30%
Sensitising agent 3-5%
Other auxiliary agents 1-2%
Wherein, six functional groups aliphatic polyurethane and two functional group's aliphatic polyurethane mass ratioes are 1:（0.3-0.5）；
The preparation method of 2nd UV ink is：First by the raw material in addition to sensitising agent according to pure third resins of UV, six functional groups
Aliphatic polyurethane and two functional group's aliphatic polyurethane mixtures, polyester chloride acrylic ester, epoxy resin, monomer resin,
The order of other auxiliary agents feeds intake successively, then stirs, is ground to after 1-3 μm under the conditions of 800-1500r/min and disperses 10-
30 minutes；Then sensitising agent is put into, UV ink needed for being produced after being uniformly mixed.
6. the preparation technology as described in claim 4-5 is any, it is characterised in that：The sensitising agent be light curing agent and coupling agent with
（3-5）:1 composition, wherein light curing agent are 184, tri- kinds of curing agent of ITS and TPO with mass ratio 3:2:3 compositions, coupling agent is silicon
One kind in alkane coupling agent KH-550, KH-570, A-171 or titanate coupling agent NDZ-201.
7. the preparation technology as described in claim 4-5 is any, it is characterised in that：The monomer resin be HDDA, TMPTA or
IBOA。
8. the preparation technology as described in claim 4-5 is any, it is characterised in that：The six functional groups aliphatic polyurethane weight is homogeneous
It is 1800-4500 to molecular mass.
9. the preparation technology as described in claim 4-5 is any, it is characterised in that：Other described auxiliary agents are organosilicon levelling agent.
10. preparation technology as claimed in claim 9, it is characterised in that：The organosilicon levelling agent is modest 810 levelling agent of moral.
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| CN108929044A (en) * | 2018-05-25 | 2018-12-04 | 佛山市高明绿色德化工有限公司 | A method of preparing highlighted metallochrome glass coating |
| CN109052984A (en) * | 2018-07-25 | 2018-12-21 | 东莞市万协塑胶科技有限公司 | Colored crystal glass and metal-imitated wire drawing process on surface of colored crystal glass |
| CN115974422A (en) * | 2022-12-29 | 2023-04-18 | 蓝思科技（长沙）有限公司 | Preparation method of glass surface texture, glass with texture and application |
| CN109941026B (en) * | 2019-04-04 | 2023-05-16 | 谭宏伟 | Floor surface digital printing archaizing processing technology |
| CN117206150A (en) * | 2023-08-04 | 2023-12-12 | 索菲亚家居股份有限公司 | Edge sealing belt with metal wiredrawing texture effect and processing method |
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| CN205498222U (en) * | 2016-03-15 | 2016-08-24 | 东莞景丰塑胶制品有限公司 | Plastic brushed sheet |
| CN106280689A (en) * | 2016-08-26 | 2017-01-04 | 佛山市高明绿色德化工有限公司 | A kind of LED UV ink and preparation method thereof, using method |
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| CN103419538A (en) * | 2013-07-23 | 2013-12-04 | 霍浩麟 | Production process for transferring and printing PET (Polyester) transfer film onto metal plate |
| CN205498222U (en) * | 2016-03-15 | 2016-08-24 | 东莞景丰塑胶制品有限公司 | Plastic brushed sheet |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108929044A (en) * | 2018-05-25 | 2018-12-04 | 佛山市高明绿色德化工有限公司 | A method of preparing highlighted metallochrome glass coating |
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| CN109052984A (en) * | 2018-07-25 | 2018-12-21 | 东莞市万协塑胶科技有限公司 | Colored crystal glass and metal-imitated wire drawing process on surface of colored crystal glass |
| CN109941026B (en) * | 2019-04-04 | 2023-05-16 | 谭宏伟 | Floor surface digital printing archaizing processing technology |
| CN115974422A (en) * | 2022-12-29 | 2023-04-18 | 蓝思科技（长沙）有限公司 | Preparation method of glass surface texture, glass with texture and application |
| CN115974422B (en) * | 2022-12-29 | 2025-04-11 | 蓝思科技（长沙）有限公司 | Preparation method of glass surface texture, glass with texture and application |
| CN117206150A (en) * | 2023-08-04 | 2023-12-12 | 索菲亚家居股份有限公司 | Edge sealing belt with metal wiredrawing texture effect and processing method |
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Application publication date: 20170926 |