CN107189191A - A kind of closestool bristle head rapidoprint and preparation method thereof - Google Patents
A kind of closestool bristle head rapidoprint and preparation method thereof Download PDFInfo
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- CN107189191A CN107189191A CN201710553479.5A CN201710553479A CN107189191A CN 107189191 A CN107189191 A CN 107189191A CN 201710553479 A CN201710553479 A CN 201710553479A CN 107189191 A CN107189191 A CN 107189191A
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- molten condition
- closestool
- rapidoprint
- polyglutamic acid
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- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 241000549893 Carphochaete Species 0.000 title claims abstract description 12
- 229920002643 polyglutamic acid Polymers 0.000 claims abstract description 35
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 239000011347 resin Substances 0.000 claims abstract description 34
- 239000010695 polyglycol Substances 0.000 claims abstract description 32
- 229920000151 polyglycol Polymers 0.000 claims abstract description 31
- 108010020346 Polyglutamic Acid Proteins 0.000 claims abstract description 29
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims abstract description 25
- 150000003505 terpenes Chemical class 0.000 claims abstract description 25
- 235000007586 terpenes Nutrition 0.000 claims abstract description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- -1 pentaerythritol ester Chemical class 0.000 claims abstract description 16
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 125000003118 aryl group Chemical group 0.000 claims abstract description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 10
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 10
- 229920006235 chlorinated polyethylene elastomer Polymers 0.000 claims abstract description 10
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 10
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 10
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 230000035935 pregnancy Effects 0.000 claims abstract description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 5
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000009413 insulation Methods 0.000 claims description 35
- 238000002156 mixing Methods 0.000 claims description 31
- 238000010792 warming Methods 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 15
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical class CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 claims description 14
- 230000002708 enhancing effect Effects 0.000 claims description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 9
- 229920001038 ethylene copolymer Polymers 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 8
- 238000004898 kneading Methods 0.000 claims description 8
- 239000003595 mist Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 238000007710 freezing Methods 0.000 claims description 7
- 230000008014 freezing Effects 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 7
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 claims description 3
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims 1
- 238000005829 trimerization reaction Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 3
- 230000001680 brushing effect Effects 0.000 abstract description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical compound Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 241000256113 Culicidae Species 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- CTRPRMNBTVRDFH-UHFFFAOYSA-N 2-n-methyl-1,3,5-triazine-2,4,6-triamine Chemical compound CNC1=NC(N)=NC(N)=N1 CTRPRMNBTVRDFH-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0853—Ethene vinyl acetate copolymers
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0207—Bristles characterised by the choice of material, e.g. metal
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/04—Preparing bristles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of closestool bristle head rapidoprint and preparation method thereof, it is related to sanitary equipment accessory processing technique field, is made up of the raw material of following parts by weight：15 25 parts of ethylene-vinyl acetate copolymer, 5 10 parts of aromatic modified terpene resin, 35 parts of poly glycol monomethyl ether/polyglutamic acid, 35 parts of hydrogenated rosin pentaerythritol ester, 13 parts of chlorinated polyethylene rubber, 13 parts of polyvinyl butyral resin, 0.5 1 parts of nanometer titanium dioxide, 0.5 1 parts of superfine powder of polytetrafluoroethylene, 0.5 1 parts of hexamethylolmelamine pregnancy ether, 0.5 1 parts of DAAM, 0.1 0.5 parts of zirconium oxide, 0.01 0.1 parts of ferrocene.Brush filament flexibility, pliability and wearability are good made from rapidoprint of the present invention, can quickly clean the dirt of attachment inside closestool with water；And the dirt under brushing enters in rinse water immediately, is difficult to stick in brush filament.
Description
Technical field：
The present invention relates to sanitary equipment accessory processing technique field, and in particular to a kind of closestool bristle head rapidoprint and its system
Preparation Method.
Background technology：
Closestool is the necessary tool of each family, and cleaning closestool also becomes the thing that must be gone of daily life.If cleaning
Method it is improper or use burnisher it is improper, may it is cumbersome and time consuming, do not reach good cleaning effect also finally.Closestool
Brush is the cleaning attachment of closestool, is typically given when selling closestool as present to consumer.
Toilet brush, is made up of brush holder and brush.Brush directly determines cleaning effect, and numerous patents are had at present and are directed to brush
Structure be improved design, but cleaning effect depends not only upon the structure of brush and additionally depends on the material of brush.At present, brush
It is many to be formed using plastics or metal material processing.Metal brush is difficult to clean with water to edge dirt due to flexibility difference, therefore existing
Usually using plastics brush.People will often find that plastics brush is easily adhered dirt during toilet brush use, even in
Also it is difficult to the dirt removal on brush totally, there are health concerns, in the course of time will make using cleaning agent when scrubbing closestool
Brush changes colour and attracts mosquitos and flies, so as to directly shorten the service life of toilet brush.
The content of the invention：
The technical problems to be solved by the invention are that offer one kind can effectively brush dirt and itself is difficult bind dirt
Closestool bristle head rapidoprint and preparation method thereof.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of closestool bristle head rapidoprint, is made up of the raw material of following parts by weight：
15-25 parts of ethylene-vinyl acetate copolymer, aromatic modified terpene resin 5-10 parts, poly glycol monomethyl ether/poly
3-5 parts of glutamic acid, 3-5 parts of hydrogenated rosin pentaerythritol ester, 1-3 parts of chlorinated polyethylene rubber, 1-3 parts of polyvinyl butyral resin,
0.5-1 parts of nanometer titanium dioxide, 0.5-1 parts of superfine powder of polytetrafluoroethylene, 0.5-1 parts of hexamethylolmelamine pregnancy ether, double third
0.5-1 parts of ketone acrylamide, 0.1-0.5 parts of zirconium oxide, 0.01-0.1 parts of ferrocene.
The preparation method of the poly glycol monomethyl ether/polyglutamic acid is：35- is added dropwise under grinding into polyglutamic acid
40 DEG C of water add poly glycol monomethyl ether, are sufficiently mixed after microwave frequency 2450MHz, power output up to being completely dissolved
Microwave treatment 5-10min under 700W, stands and continues microwave treatment 5-10min after 10-15min, and adds polyethylene glycol oxide and poly-
Dimethyl diallyl ammonium chloride, microwave treatment 5-10min again after being well mixed, gained mixed liquor feeding spray dryer
In, dry gained particle and micro mist is made through micronizer, produce poly glycol monomethyl ether/polyglutamic acid.
The polyglutamic acid, poly glycol monomethyl ether, the matter of polyethylene glycol oxide and PDDA
Amount is than being 1-5:1-5:0.1-2:0.01-0.5.
A kind of preparation method of closestool bristle head rapidoprint, comprises the following steps：
(1) ethylene-vinyl acetate copolymer is warming up to molten condition insulation mixing 10-15min, adds hexamethylol
Melamine pregnancy ether and DAAM, are continuously maintained at molten condition insulation mixing 0.5-1h, after naturally cool to
Sealing freezing 3-5h in -15 DEG C of environment is sent into after room temperature, then granularity 0.5-1mm particle is made in size-reduced machine, produces modification
Ethylene-vinyl acetate copolymer；
(2) nanometer titanium dioxide and superfine powder of polytetrafluoroethylene are added into hydrogenated rosin pentaerythritol ester, melting is warming up to
State insulation mixing 15-30min, after naturally cool to room temperature, produces modified hydrogenated pentalyn；
(3) chlorinated polyethylene rubber and polyvinyl butyral resin are added into aromatic modified terpene resin, melting is warming up to
State insulation mixing 10-15min, adds zirconium oxide and ferrocene, is continuously maintained at molten condition insulation mixing 10-15min,
Produce enhancing terpene resin；
(4) by ethene improved-acetate ethylene copolymer, modified hydrogenated pentalyn, enhancing terpene resin and poly-
In glycol monoethyl ether/polyglutamic acid feeding kneading machine, 3-5min is kneaded under molten condition, and extruded shaping is made
Brush head is made in brush filament, finally assembling.
The beneficial effects of the invention are as follows：There is raw material to be easy to get, step is processed for closestool bristle head rapidoprint of the present invention
Rapid simple and easy to do the characteristics of, obtained brush filament flexibility, pliability and wearability are good, can quickly clean the dirt of attachment inside closestool with water
Dirt；And the dirt under brushing enters in rinse water immediately, is difficult to stick in brush filament, tied so as to ensure that brush head is cleaned in closestool
The state of clean hygiene is kept after beam, so as to avoid because of attachment of the dirt in brush filament breed bacteria and attract asking for mosquitos and flies
Topic；The corrosion resistance of brush filament is strong simultaneously, can adapt to the use of strength detergent for toilet, it is to avoid common brush filament occurs in use
The phenomenon for coming off and being broken.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) 20g ethylene-vinyl acetate copolymers are warming up to molten condition insulation mixing 10min, add the hydroxyls of 0.5g six
Methyl melamine pregnancy ether and 0.5g DAAMs, are continuously maintained at molten condition insulation mixing 30min, treat nature
It is cooled to after room temperature and sends into sealing freezing 5h in -15 DEG C of environment, then granularity 0.5-1mm particle is made in size-reduced machine, produces
Ethene improved-acetate ethylene copolymer；
(2) 0.5g nanometer titanium dioxides and 0.5g superfine powder of polytetrafluoroethylene are added into 5g hydrogenated rosin pentaerythritol esters,
Molten condition insulation mixing 30min is warming up to, after naturally cool to room temperature, modified hydrogenated pentalyn is produced；
(3) 1g chlorinated polyethylene rubbers and 1g polyvinyl butyral resins, heating are added into the aromatic modified terpene resins of 10g
To molten condition insulation mixing 10min, 0.3g zirconium oxides and 0.01g ferrocene are added, molten condition insulation is continuously maintained at
10min is mixed, enhancing terpene resin is produced；
(4) by ethene improved-acetate ethylene copolymer, modified hydrogenated pentalyn, enhancing terpene resin and 3g
In poly glycol monomethyl ether/polyglutamic acid feeding kneading machine, 5min is kneaded under molten condition, and extruded shaping is made
Brush head is made in brush filament, finally assembling.
The preparation of poly glycol monomethyl ether/polyglutamic acid：Into 5g polyglutamic acids, 35-40 DEG C of water of dropwise addition is straight under grinding
To being completely dissolved, 5g poly glycol monomethyl ethers are added, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W
Microwave treatment 10min, stands and continues microwave treatment 10min after 15min, and add 0.5g polyethylene glycol oxides and 0.1g poly dimethyls
In diallyl ammonium chloride, microwave treatment 10min again after being well mixed, gained mixed liquor feeding spray dryer, institute is dried
Obtain particle and micro mist is made through micronizer, produce poly glycol monomethyl ether/polyglutamic acid.
Embodiment 2
(1) 25g ethylene-vinyl acetate copolymers are warming up to molten condition insulation mixing 15min, add the hydroxyl first of 1g six
Base melamine pregnancy ether and 0.5g DAAMs, are continuously maintained at molten condition insulation mixing 1h, treat natural cooling
Sealing freezing 5h in -15 DEG C of environment is sent into after to room temperature, then granularity 0.5-1mm particle is made in size-reduced machine, produces modification
Ethylene-vinyl acetate copolymer；
(2) 0.5g nanometer titanium dioxides and 0.5g superfine powder of polytetrafluoroethylene are added into 5g hydrogenated rosin pentaerythritol esters,
Molten condition insulation mixing 30min is warming up to, after naturally cool to room temperature, modified hydrogenated pentalyn is produced；
(3) 1g chlorinated polyethylene rubbers and 1g polyvinyl butyral resins, heating are added into the aromatic modified terpene resins of 5g
To molten condition insulation mixing 15min, 0.5g zirconium oxides and 0.02g ferrocene are added, molten condition insulation is continuously maintained at
15min is mixed, enhancing terpene resin is produced；
(4) by ethene improved-acetate ethylene copolymer, modified hydrogenated pentalyn, enhancing terpene resin and 5g
In poly glycol monomethyl ether/polyglutamic acid feeding kneading machine, 5min is kneaded under molten condition, and extruded shaping is made
Brush head is made in brush filament, finally assembling.
The preparation of poly glycol monomethyl ether/polyglutamic acid：Into 3g polyglutamic acids, 35-40 DEG C of water of dropwise addition is straight under grinding
To being completely dissolved, 3g poly glycol monomethyl ethers are added, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W
Microwave treatment 10min, stands and continues microwave treatment 5min after 10min, and add 0.2g polyethylene glycol oxides and 0.05g poly dimethyls
In diallyl ammonium chloride, microwave treatment 5min again after being well mixed, gained mixed liquor feeding spray dryer, gained is dried
Micro mist is made through micronizer in particle, produces poly glycol monomethyl ether/polyglutamic acid.
Reference examples 1
(1) 25g ethylene-vinyl acetate copolymers are warming up to molten condition insulation mixing 15min, add the hydroxyl first of 1g six
Base melamine pregnancy ether and 0.5g DAAMs, are continuously maintained at molten condition insulation mixing 1h, treat natural cooling
Sealing freezing 5h in -15 DEG C of environment is sent into after to room temperature, then granularity 0.5-1mm particle is made in size-reduced machine, produces modification
Ethylene-vinyl acetate copolymer；
(2) 1g chlorinated polyethylene rubbers and 1g polyvinyl butyral resins, heating are added into the aromatic modified terpene resins of 5g
To molten condition insulation mixing 15min, 0.5g zirconium oxides and 0.02g ferrocene are added, molten condition insulation is continuously maintained at
15min is mixed, enhancing terpene resin is produced；
(3) ethene improved-acetate ethylene copolymer, 5g hydrogenated rosins pentaerythritol ester, enhancing terpene resin and 5g are gathered
In glycol monoethyl ether/polyglutamic acid feeding kneading machine, 5min is kneaded under molten condition, and brush is made in extruded shaping
Brush head is made in silk, finally assembling.
The preparation of poly glycol monomethyl ether/polyglutamic acid：Into 3g polyglutamic acids, 35-40 DEG C of water of dropwise addition is straight under grinding
To being completely dissolved, 3g poly glycol monomethyl ethers are added, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W
Microwave treatment 10min, stands and continues microwave treatment 5min after 10min, and add 0.2g polyethylene glycol oxides and 0.05g poly dimethyls
In diallyl ammonium chloride, microwave treatment 5min again after being well mixed, gained mixed liquor feeding spray dryer, gained is dried
Micro mist is made through micronizer in particle, produces poly glycol monomethyl ether/polyglutamic acid.
Reference examples 2
(1) 25g ethylene-vinyl acetate copolymers are warming up to molten condition insulation mixing 15min, add the hydroxyl first of 1g six
Base melamine pregnancy ether and 0.5g DAAMs, are continuously maintained at molten condition insulation mixing 1h, treat natural cooling
Sealing freezing 5h in -15 DEG C of environment is sent into after to room temperature, then granularity 0.5-1mm particle is made in size-reduced machine, produces modification
Ethylene-vinyl acetate copolymer；
(2) 0.5g nanometer titanium dioxides and 0.5g superfine powder of polytetrafluoroethylene are added into 5g hydrogenated rosin pentaerythritol esters,
Molten condition insulation mixing 30min is warming up to, after naturally cool to room temperature, modified hydrogenated pentalyn is produced；
(3) 1g chlorinated polyethylene rubbers and 1g polyvinyl butyral resins, heating are added into the aromatic modified terpene resins of 5g
To molten condition insulation mixing 15min, 0.5g zirconium oxides and 0.02g ferrocene are added, molten condition insulation is continuously maintained at
15min is mixed, enhancing terpene resin is produced；
(4) by ethene improved-acetate ethylene copolymer, modified hydrogenated pentalyn, enhancing terpene resin and 5g
In poly glycol monomethyl ether/polyglutamic acid feeding kneading machine, 5min is kneaded under molten condition, and extruded shaping is made
Brush head is made in brush filament, finally assembling.
The preparation of poly glycol monomethyl ether/polyglutamic acid：Into 3g polyglutamic acids, 35-40 DEG C of water of dropwise addition is straight under grinding
To being completely dissolved, 3g poly glycol monomethyl ethers are added, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W
Microwave treatment 10min, stands and continues microwave treatment 5min after 10min, in gained mixed liquor feeding spray dryer, dries gained
Micro mist is made through micronizer in particle, produces poly glycol monomethyl ether/polyglutamic acid.
Reference examples 3
(1) 25g ethylene-vinyl acetate copolymers are warming up to molten condition insulation mixing 15min, add the hydroxyl first of 1g six
Base melamine pregnancy ether and 0.5g DAAMs, are continuously maintained at molten condition insulation mixing 1h, treat natural cooling
Sealing freezing 5h in -15 DEG C of environment is sent into after to room temperature, then granularity 0.5-1mm particle is made in size-reduced machine, produces modification
Ethylene-vinyl acetate copolymer；
(2) 0.5g nanometer titanium dioxides and 0.5g superfine powder of polytetrafluoroethylene are added into 5g hydrogenated rosin pentaerythritol esters,
Molten condition insulation mixing 30min is warming up to, after naturally cool to room temperature, modified hydrogenated pentalyn is produced；
(3) by ethene improved-acetate ethylene copolymer, modified hydrogenated pentalyn, the aromatic modified terpenes trees of 5g
In fat and 5g poly glycol monomethyl ethers/polyglutamic acid feeding kneading machine, knead 5min under molten condition, and it is extruded into
Brush filament is made in type, and brush head is made in finally assembling.
The preparation of poly glycol monomethyl ether/polyglutamic acid：Into 3g polyglutamic acids, 35-40 DEG C of water of dropwise addition is straight under grinding
To being completely dissolved, 3g poly glycol monomethyl ethers are added, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W
Microwave treatment 10min, stands and continues microwave treatment 5min after 10min, and add 0.2g polyethylene glycol oxides and 0.05g poly dimethyls
In diallyl ammonium chloride, microwave treatment 5min again after being well mixed, gained mixed liquor feeding spray dryer, gained is dried
Micro mist is made through micronizer in particle, produces poly glycol monomethyl ether/polyglutamic acid.
Reference examples 4
(1) 0.5g nanometer titanium dioxides and 0.5g superfine powder of polytetrafluoroethylene are added into 5g hydrogenated rosin pentaerythritol esters,
Molten condition insulation mixing 30min is warming up to, after naturally cool to room temperature, modified hydrogenated pentalyn is produced；
(2) 1g chlorinated polyethylene rubbers and 1g polyvinyl butyral resins, heating are added into the aromatic modified terpene resins of 5g
To molten condition insulation mixing 15min, 0.5g zirconium oxides and 0.02g ferrocene are added, molten condition insulation is continuously maintained at
15min is mixed, enhancing terpene resin is produced；
(3) 25g ethylene-vinyl acetate copolymers, modified hydrogenated pentalyn, enhancing terpene resin and 5g are gathered
In glycol monoethyl ether/polyglutamic acid feeding kneading machine, 5min is kneaded under molten condition, and brush is made in extruded shaping
Brush head is made in silk, finally assembling.
The preparation of poly glycol monomethyl ether/polyglutamic acid：Into 3g polyglutamic acids, 35-40 DEG C of water of dropwise addition is straight under grinding
To being completely dissolved, 3g poly glycol monomethyl ethers are added, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W
Microwave treatment 10min, stands and continues microwave treatment 5min after 10min, and add 0.2g polyethylene glycol oxides and 0.05g poly dimethyls
In diallyl ammonium chloride, microwave treatment 5min again after being well mixed, gained mixed liquor feeding spray dryer, gained is dried
Micro mist is made through micronizer in particle, produces poly glycol monomethyl ether/polyglutamic acid.
Embodiment 3
Respectively embodiment 1, embodiment 2, reference examples 1, reference examples 2, reference examples 3, the made brush head of reference examples 4 are entered to exercise
With performance test, test result is as shown in table 1.
The performance of the made brush head of the embodiment of the present invention of table 1
| Group | The dirt property cleaned with water | Dirt adhesiveness | Service life |
| Embodiment 1 | * * * * | * | * * * * |
| Embodiment 2 | * * * * | * | * * * * |
| Reference examples 1 | * * * | * | * * * |
| Reference examples 2 | * * | * * | * * |
| Reference examples 3 | * | * * * | * |
| Reference examples 4 | * | * * * * | * |
Because the dirt property cleaned with water, dirt adhesiveness and service life of brush head are difficult to accurate measure, so herein with *
Number come characterize experiment in observe service condition.The column * of the dirt property cleaned with water one number is more, illustrates the dirt of hairbrush
The property cleaned with water is stronger；The column * of dirt adhesiveness one number is more, illustrates that hairbrush is more easy to bind dirt；The column * of service life one
Number is more, illustrates that the service life of hairbrush is longer.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (4)
1. a kind of closestool bristle head rapidoprint, it is characterised in that：It is made up of the raw material of following parts by weight：
15-25 parts of ethylene-vinyl acetate copolymer, aromatic modified terpene resin 5-10 parts, poly glycol monomethyl ether/many polyglutamics
Sour 3-5 parts, 3-5 parts of hydrogenated rosin pentaerythritol ester, 1-3 parts of chlorinated polyethylene rubber, 1-3 parts of polyvinyl butyral resin, nanometer
0.5-1 parts of titanium dioxide, 0.5-1 parts of superfine powder of polytetrafluoroethylene, 0.5-1 parts of hexamethylolmelamine pregnancy ether, diacetone third
0.5-1 parts of acrylamide, 0.1-0.5 parts of zirconium oxide, 0.01-0.1 parts of ferrocene.
2. closestool bristle head rapidoprint according to claim 1, it is characterised in that：The poly glycol monomethyl ether/
The preparation method of polyglutamic acid is：35-40 DEG C of water is added dropwise until being completely dissolved into polyglutamic acid under grinding, adds poly-
Glycol monoethyl ether, is sufficiently mixed after microwave treatment 5-10min under microwave frequency 2450MHz, power output 700W, stands
Continue microwave treatment 5-10min after 10-15min, and add polyethylene glycol oxide and PDDA, mixing is equal
In microwave treatment 5-10min again after even, gained mixed liquor feeding spray dryer, gained particle is dried through ultramicro grinding mechanism
Into micro mist, poly glycol monomethyl ether/polyglutamic acid is produced.
3. closestool bristle head rapidoprint according to claim 2, it is characterised in that：The polyglutamic acid, poly- second
The mass ratio of glycol monomethyl ether, polyethylene glycol oxide and PDDA is 1-5:1-5:0.1-2:0.01-
0.5。
4. a kind of preparation method of closestool bristle head rapidoprint, it is characterised in that：Comprise the following steps：
(1) ethylene-vinyl acetate copolymer is warming up to molten condition insulation mixing 10-15min, adds hexamethylol trimerization
Cyanamide pregnancy ether and DAAM, are continuously maintained at molten condition insulation mixing 0.5-1h, after naturally cool to room temperature
Afterwards send into -15 DEG C of environment in sealing freezing 3-5h, then size-reduced machine granularity 0.5-1mm particle is made, produce it is ethene improved -
Acetate ethylene copolymer；
(2) nanometer titanium dioxide and superfine powder of polytetrafluoroethylene are added into hydrogenated rosin pentaerythritol ester, molten condition is warming up to
Insulation mixing 15-30min, after naturally cool to room temperature, produces modified hydrogenated pentalyn；
(3) chlorinated polyethylene rubber and polyvinyl butyral resin are added into aromatic modified terpene resin, molten condition is warming up to
Insulation mixing 10-15min, adds zirconium oxide and ferrocene, is continuously maintained at molten condition insulation mixing 10-15min, produces
Strengthen terpene resin；
(4) by ethene improved-acetate ethylene copolymer, modified hydrogenated pentalyn, enhancing terpene resin and poly- second two
In alcohol monomethyl ether/polyglutamic acid feeding kneading machine, 3-5min is kneaded under molten condition, and brush is made in extruded shaping
Brush head is made in silk, finally assembling.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710553479.5A CN107189191A (en) | 2017-07-08 | 2017-07-08 | A kind of closestool bristle head rapidoprint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710553479.5A CN107189191A (en) | 2017-07-08 | 2017-07-08 | A kind of closestool bristle head rapidoprint and preparation method thereof |
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Family
ID=59882948
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795211A (en) * | 2018-05-25 | 2018-11-13 | 安徽新创智能科技有限公司 | A method of slowing down shared bicycle coating color decoloration |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1254260A (en) * | 1997-03-13 | 2000-05-24 | 诺威蒂克企业公司 | Cleaning element for rotating brush, made of ethylene vinyl acetate (EVA) copolymer |
| CN205579291U (en) * | 2016-03-08 | 2016-09-14 | 李爱良 | Telescopic fixed brush shovel |
-
2017
- 2017-07-08 CN CN201710553479.5A patent/CN107189191A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1254260A (en) * | 1997-03-13 | 2000-05-24 | 诺威蒂克企业公司 | Cleaning element for rotating brush, made of ethylene vinyl acetate (EVA) copolymer |
| CN205579291U (en) * | 2016-03-08 | 2016-09-14 | 李爱良 | Telescopic fixed brush shovel |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795211A (en) * | 2018-05-25 | 2018-11-13 | 安徽新创智能科技有限公司 | A method of slowing down shared bicycle coating color decoloration |
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Application publication date: 20170922 |