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CN107188443A - One kind is used to manually contaminate mortar and preparation method thereof - Google Patents

One kind is used to manually contaminate mortar and preparation method thereof Download PDF

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Publication number
CN107188443A
CN107188443A CN201710619004.1A CN201710619004A CN107188443A CN 107188443 A CN107188443 A CN 107188443A CN 201710619004 A CN201710619004 A CN 201710619004A CN 107188443 A CN107188443 A CN 107188443A
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China
Prior art keywords
water
soluble
sand
glue
mortar
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Granted
Application number
CN201710619004.1A
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Chinese (zh)
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CN107188443B (en
Inventor
李娅
杨会来
于丽佳
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First New Material Science & Technology Development Co Ltd
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First New Material Science & Technology Development Co Ltd
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Priority to CN201710619004.1A priority Critical patent/CN107188443B/en
Publication of CN107188443A publication Critical patent/CN107188443A/en
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Publication of CN107188443B publication Critical patent/CN107188443B/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1092Coating or impregnating with pigments or dyes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18Polyesters; Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

It is used to manually contaminate mortar and preparation method thereof the invention discloses one kind, the slurry is made up of water-soluble amino acrylic glue and sand source;Water-soluble amino acrylic gum is made up of following each raw materials:Water soluble acrylic resin, water, dispersant, anti-settling agent, levelling agent, defoamer, thickener, rutile titanium white powder, calcined kaolin, amino resins.The slurry utilizes water soluble acrylic resin and amino resins curing cross-linking reaction under the conditions of low-temperature bake, and water-soluble amino acrylic glue is made with the cooperation of each auxiliary agent, sand source is dyed using the water-soluble amino acrylic glue, so that the artificial color sand being made has higher mechanical stability, more conventional artificial color sand mechanical stability extends to 2h nondiscolourings.Due to taking water-soluble resin, VOC emission is low, ecological, environmental protective.

Description

One kind is used to manually contaminate mortar and preparation method thereof
Technical field
The present invention relates to building coating field, more particularly, to a kind of artificial dye mortar for being mainly used in true mineral varnish and its Preparation method.
Background technology
In recent years, with the development of real estate industry, the application of building coating is more and more extensive, and consumption is also increasing. Wherein true mineral varnish has the effect of natural-like stone, marble and granite, and irreplaceable status is occupied in building coating. One of primary raw material of true mineral varnish be natural colour sand, it is necessary to carry out the exploitation of former stone in some mineral resources, then size-reduced, screening And obtain.The original ecological environment for exploiting not only heavy damage locality in mine, and the dust granules produced are the masters of haze Want one of pollution sources.Another aspect natural colour sand has the characteristics of lot stability is poor, often results in the aberration of true mineral varnish.
Artificial coloured silk sand technology is arisen at the historic moment under above-mentioned restrictive condition, typically there is two kinds of colouring methods:Inorganic decoration method and Organic dye method.Inorganic decoration method is needed coloring material and sand source common calcination, high energy consumption, but mechanical stability at high temperature It is good;Organic dye method is that air drying or low-temperature bake are formed after mill base and filmogen are blended with sand source, energy consumption it is low but Mechanical stability is poor.And have engine dyeing sand method also with VOC discharge, it is unfavorable for environmental protection.
The content of the invention
Based on the problems of prior art, it is used to manually contaminate mortar and its system it is an object of the invention to provide one kind Preparation Method, not only improves the mechanical stability of artificial color sand, and has excellent weather resistance, and VOC emission is low..
The purpose of the present invention is achieved through the following technical solutions:
Embodiment of the present invention provides a kind of for manually contaminating mortar, by water-soluble amino acrylic glue and sand source group Into the water-soluble amino acrylic glue and the mass percent in sand source are:
Water-soluble amino acrylic glue 0.9~3
Sand source 97~99.1;
The water-soluble amino acrylic gum is made up of following each raw materials by mass percentage:
Embodiment of the present invention also provides a kind of preparation method for being used to manually contaminate mortar, of the present invention for preparing Be used for manually contaminate mortar, comprise the following steps:
By the formula each raw material of water-soluble acrylic-amino glue and Sha Yuan of the present invention for being used to manually contaminate mortar;
Prepare water-soluble amino acrylic glue:The water soluble acrylic resin of water-soluble amino acrylic glue is added scattered In cylinder, water is added after 10~15min of dispersion mixing, continues to mix after 10min by dispersant, anti-settling agent, levelling agent and defoamer It is added in dispersion cylinder, 10~20min is disperseed under 500~1000rpm rotary regimes, adds rutile titanium white powder and forge Kaolin is burnt, fineness is dispersed under 2200~3000rpm rotary regimes less than or equal to 30 μm, amino resins is added, 100~ The 300rpm slow-speed of revolution disperses 10min to system bubble-free, is eventually adding thickener regulation and arrives suitable viscosity, that is, obtains water solubility third Olefin(e) acid amino glue;
Prepare dye sand:Sand source is weighed, water-soluble amino acrylic glue is added and is well mixed both, regulation to dye sand material Required color, that is, obtain contaminating sand;
Coloring:Obtained dye sand is placed in drying plant and toasted at 100~130 DEG C after 10~30min, cooling is taken out To room temperature, that is, obtain being used to manually contaminate mortar.
As seen from the above technical solution provided by the invention, it is provided in an embodiment of the present invention to be used to manually contaminate mortar And preparation method thereof, its advantage is:
Using water soluble acrylic resin and amino resins curing cross-linking reaction under the conditions of low-temperature bake, and with each auxiliary agent Water-soluble amino acrylic glue is made in cooperation, sand source is dyed using the water-soluble amino acrylic glue so that be made The artificial color sand has higher mechanical stability, and more conventional artificial color sand mechanical stability extends to 2h nondiscolourings.Due to adopting Water-soluble resin, VOC emission is low, ecological, environmental protective.
Embodiment
With reference to the particular content of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely retouched State, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, Belong to protection scope of the present invention.
The embodiment of the present invention, which provides one kind, to be used to manually contaminate mortar, is made up of water-soluble amino acrylic glue and sand source, The water-soluble amino acrylic glue and the mass percent in sand source are:
Water-soluble amino acrylic glue 0.9~3
Sand source 97~99.1;
The water-soluble amino acrylic gum is made up of following each raw materials by mass percentage:
In above-mentioned dye mortar, the solid content of the water soluble acrylic resin in water-soluble amino acrylic glue for 40~ 51%;The solid content of the amino resins is 74~100%.
In above-mentioned dye mortar, the dispersant in water-soluble amino acrylic glue uses macromolecule dispersing agent;
The defoamer uses organic silicon defoamer;
The levelling agent uses organosilicon levelling agent.
In above-mentioned dye mortar, rutile titanium white powder uses import rutile titanium white powder.
In above-mentioned dye mortar, water-soluble amino acrylic glue also includes:By weight percentage 1~19% aqueous color Slurry.
In above-mentioned dye mortar, sand source is using any of wind sand, river sand, calcite, quartz or several.
Above-mentioned water-soluble amino acrylic glue is one-component, is not reacted under normal temperature.
Embodiment of the present invention also provides a kind of preparation method for being used to manually contaminate mortar, of the present invention for preparing Be used for manually contaminate mortar, comprise the following steps:
By the formula each raw material of water-soluble acrylic-amino glue and Sha Yuan of the present invention for being used to manually contaminate mortar;
Prepare water-soluble amino acrylic glue:The water soluble acrylic resin of water-soluble amino acrylic glue is added scattered In cylinder, water is added after 10~15min of dispersion mixing, continues to mix after 10min by dispersant, anti-settling agent, levelling agent and defoamer It is added in dispersion cylinder, 10~20min is disperseed under 500~1000rpm rotary regimes, adds rutile titanium white powder and forge Kaolin is burnt, fineness is dispersed under 2200~3000rpm rotary regimes less than or equal to 30 μm, amino resins is added, 100~ The 300rpm slow-speed of revolution disperses 10min to system bubble-free, is eventually adding thickener regulation and arrives suitable viscosity, that is, obtains water solubility third Olefin(e) acid amino glue;
Prepare dye sand:Sand source (wind sand, river sand, calcite, quartz etc.) is weighed, addition water-soluble amino acrylic glue is simultaneously Both are well mixed, color needed for regulation to dye sand material obtains contaminating sand;
Coloring:Obtained dye sand is placed in drying plant and toasted at 100~130 DEG C after 10~30min, cooling is taken out To room temperature, that is, obtain manually contaminating sand.
In above-mentioned preparation method, preparing water-soluble amino acrylic glue step also includes:
Adjust after suitable viscosity, add aqueous color paste under 300~500rpm low speed states, regulation color is to water-soluble Property color needed for acrylic-amino glue.
The slurry of the present invention is dyed to sand source, makes manually to contaminate sand production process not only environmental protection, reduction energy consumption but also dye Smalt mechanical stability can bring up to 2h nondiscolourings, and the resistance to acids and bases and ultraviolet aging resistance ability of dyeing sand, which have, in addition significantly carries It is high.
The embodiment of the present invention is specifically described in further detail below.
Embodiment 1
The present embodiment provides a kind of for artificial dye mortar, is made up of water-soluble amino acrylic glue and sand source, by weight Measure percentage, water-soluble amino acrylic glue:0.9%, sand source:99.1%;
Wherein, water-soluble amino acrylic glue is made up of following each component by mass percentage:
The above-mentioned preparation method for being used to manually contaminate mortar, comprises the following steps:
Prepare water-soluble amino acrylic glue:First 60% water soluble acrylic resin is added in dispersion cylinder, disperses mixed Close and water is added after 10~15min, continue that dispersant, anti-settling agent, levelling agent, defoamer are added into dispersion cylinder after mixing 10min In, 10~20min is disperseed in the state of 500~1000rpm, import titanium dioxide is added, calcined kaolin 2200~ 3000rpm is dispersed to fineness≤30 μm, adds amino resins, and 100~300rpm of low speed disperses 10min to system bubble-free, most It is to obtain water-soluble amino acrylic glue to suitable viscosity to add thickener regulation afterwards;
Further, above-mentioned steps also include:To obtained water-soluble amino acrylic under low speed 300~500rpm states Glue adds aqueous iron yellow pulp, is well mixed;
Contaminate sand and coloring:Weigh water-soluble amino acrylic glue and sand source is well mixed, be placed in baking oven 100~130 DEG C Room temperature packaging is cooled to after 10~30min of baking, that is, obtains manually contaminating sand.
Embodiment 2
The present embodiment provides a kind of for artificial dye mortar, is made up of water-soluble amino acrylic glue and sand source, by weight Measure percentage, water-soluble amino acrylic glue:3%, sand source:97%;
Wherein, water-soluble amino acrylic glue is made up of following each component by mass percentage:
The above-mentioned preparation method for being used to manually contaminate mortar, comprises the following steps:
Prepare water-soluble amino acrylic glue:First 40% water-soluble acrylic is added in dispersion cylinder, dispersion mixing 10 Water is added after~15min, continues that dispersant, anti-settling agent, levelling agent, defoamer are added in dispersion cylinder after mixing 10min, Disperse 10~20min in the state of 500~1000rpm, add import titanium dioxide, 2200~3000rpm points of calcined kaolin Fineness≤30 μm are dissipated to, 6% amino resins is added, 100~300rpm of low speed disperses 10min to system bubble-free, is eventually adding Thickener regulation is to obtain water-soluble amino acrylic glue to suitable viscosity;
Further above-mentioned steps also include:To obtained water-soluble amino acrylic under low speed 300~500rpm states Glue adds 19% aqueous rust slurry, is well mixed;
Contaminate sand and coloring:Weigh water-soluble amino acrylic glue and sand source is well mixed, be placed in baking oven 100~130 DEG C Room temperature packaging is cooled to after 10~30min of baking, that is, obtains manually contaminating sand.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can be readily occurred in, It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims Enclose and be defined.

Claims (8)

1. one kind is used to manually contaminate mortar, it is characterised in that be made up of water-soluble amino acrylic glue and sand source, described water-soluble Property acrylic-amino glue and the mass percent in sand source are:
Water-soluble amino acrylic glue 0.9~3
Sand source 97~99.1;
The water-soluble amino acrylic gum is made up of following each raw materials by mass percentage:
2. it is according to claim 1 a kind of for manually contaminating mortar, it is characterised in that the water-soluble amino acrylic The solid content of water soluble acrylic resin in glue is 40~51%;The solid content of the amino resins is 74~100%.
3. it is according to claim 1 a kind of for manually contaminating mortar, it is characterised in that the water-soluble amino acrylic Dispersant in glue uses macromolecule dispersing agent;
The defoamer uses organic silicon defoamer;
The levelling agent uses organosilicon levelling agent.
4. it is according to claim 1 a kind of for manually contaminating mortar, it is characterised in that the rutile titanium white powder is used Import rutile titanium white powder.
5. one kind according to any one of Claims 1-4 is used to manually contaminate mortar, it is characterised in that the water solubility Acrylic-amino glue also includes:By weight percentage 1~19% aqueous color paste.
6. one kind according to any one of Claims 1-4 is used to manually contaminate mortar, it is characterised in that adopt in the sand source With any of wind sand, river sand, calcite, quartz or several.
7. a kind of preparation method for being used to manually contaminate mortar, it is characterised in that for preparing any one of claim 1 to 6 institute That states is used for manually dye mortar, comprises the following steps:
Being used for as described in any one of claim 1 to 6 manually contaminates each original of formula water-soluble acrylic-amino glue of mortar Material and sand source;
Prepare water-soluble amino acrylic glue:The water soluble acrylic resin of water-soluble amino acrylic glue is added into dispersion cylinder In, water is added after 10~15min of dispersion mixing, continues to add dispersant, anti-settling agent, levelling agent and defoamer after mixing 10min Enter into dispersion cylinder, 10~20min is disperseed under 500~1000rpm rotary regimes, rutile titanium white powder and calcining is added Kaolin, is dispersed to fineness less than or equal to 30 μm under 2200~3000rpm rotary regimes, adds amino resins, 100~ The 300rpm slow-speed of revolution disperses 10min to system bubble-free, is eventually adding thickener regulation and arrives suitable viscosity, that is, obtains water solubility third Olefin(e) acid amino glue;
Prepare dye sand:Sand source is weighed, water-soluble amino acrylic glue is added and is well mixed both, needed for regulation to dye sand material Color, that is, obtain contaminating sand;
Coloring:Obtained dye sand is placed in drying plant and toasted at 100~130 DEG C after 10~30min, taking-up is cooled to room Temperature, that is, obtain being used to manually contaminate mortar.
8. a kind of preparation method for being used to manually contaminate mortar according to claim 7, it is characterised in that described to prepare water Soluble acrylic amino glue step also includes:
Adjust after suitable viscosity, aqueous color paste, regulation color to water solubility third are added under 300~500rpm low speed states Color needed for olefin(e) acid amino glue.
CN201710619004.1A 2017-07-26 2017-07-26 One kind is for manually contaminating mortar and preparation method thereof Active CN107188443B (en)

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CN107188443B CN107188443B (en) 2019-11-01

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640600A (en) * 2018-05-21 2018-10-12 成都建工预筑科技有限公司 A kind of colour foam concrete
CN108840604A (en) * 2018-06-29 2018-11-20 河南颂源涂料有限公司 A kind of artificial color sand and preparation method thereof
CN110255969A (en) * 2019-06-19 2019-09-20 郑州科威科建筑材料有限公司 A kind of reflective insulation sand and preparation method thereof
CN112694777A (en) * 2020-12-31 2021-04-23 亚士创能新材料(滁州)有限公司 Colorant for artificial colored sand, and preparation method and application thereof
CN112852292A (en) * 2021-01-07 2021-05-28 广东美涂士建材股份有限公司 Dyeing resin for sand dyeing
CN113004757A (en) * 2021-04-06 2021-06-22 陈素平 Dyed sand slurry, artificial colored sand and preparation method
CN114350219A (en) * 2022-03-09 2022-04-15 富思特新材料科技发展股份有限公司 Water-based reflective heat-insulation dyed mortar material, preparation method and application thereof, and preparation method of dyed sand

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105505220A (en) * 2015-12-26 2016-04-20 铃鹿复合建材(上海)有限公司 Water-based colored stone

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105505220A (en) * 2015-12-26 2016-04-20 铃鹿复合建材(上海)有限公司 Water-based colored stone

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640600A (en) * 2018-05-21 2018-10-12 成都建工预筑科技有限公司 A kind of colour foam concrete
CN108640600B (en) * 2018-05-21 2020-11-24 成都建工预筑科技有限公司 Colored foam concrete
CN108840604A (en) * 2018-06-29 2018-11-20 河南颂源涂料有限公司 A kind of artificial color sand and preparation method thereof
CN110255969A (en) * 2019-06-19 2019-09-20 郑州科威科建筑材料有限公司 A kind of reflective insulation sand and preparation method thereof
CN112694777A (en) * 2020-12-31 2021-04-23 亚士创能新材料(滁州)有限公司 Colorant for artificial colored sand, and preparation method and application thereof
CN112852292A (en) * 2021-01-07 2021-05-28 广东美涂士建材股份有限公司 Dyeing resin for sand dyeing
CN112852292B (en) * 2021-01-07 2022-05-06 广东美涂士建材股份有限公司 Dyeing resin for sand dyeing
CN113004757A (en) * 2021-04-06 2021-06-22 陈素平 Dyed sand slurry, artificial colored sand and preparation method
CN114350219A (en) * 2022-03-09 2022-04-15 富思特新材料科技发展股份有限公司 Water-based reflective heat-insulation dyed mortar material, preparation method and application thereof, and preparation method of dyed sand

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