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CN107163631A - A kind of ecological nano anion inorganic mineral coating and preparation method thereof - Google Patents

A kind of ecological nano anion inorganic mineral coating and preparation method thereof Download PDF

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Publication number
CN107163631A
CN107163631A CN201710561760.3A CN201710561760A CN107163631A CN 107163631 A CN107163631 A CN 107163631A CN 201710561760 A CN201710561760 A CN 201710561760A CN 107163631 A CN107163631 A CN 107163631A
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CN
China
Prior art keywords
powder
inorganic mineral
mineral coating
defoamer
negative ion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710561760.3A
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Chinese (zh)
Inventor
王文廷
许�鹏
刘文军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Huacai Inorganic Coatings Co Ltd
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Henan Huacai Inorganic Coatings Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Henan Huacai Inorganic Coatings Co Ltd filed Critical Henan Huacai Inorganic Coatings Co Ltd
Priority to CN201710561760.3A priority Critical patent/CN107163631A/en
Publication of CN107163631A publication Critical patent/CN107163631A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of ecological nano anion inorganic mineral coating and preparation method thereof, belong to technical field of coatings.The coating is made up of the raw material of following mass percent:Dispersant 731a 2 8%, defoamer XHD 1 3%, levelling agent BYK306 1 3%, wetting agent X405 1 4%, titanium dioxide R706 5 20%, kaolin 5 15%, negative ion powder 1 5% refines mineral powder 2 10%, nano silicate 10 30%, thickener ASE60 1 5%, styrene-acrylic emulsion 4 20%, water 20 30%.The rational proportion that the present invention passes through above-mentioned each raw material, considerably improve stain resistance, water proofing property and the Scratch Resistance of paint film, avoid blacking scab, colour fading, dry linting, come off, while release anion that can be lasting, purify indoor environment, the sleep quality of people and the immunity of body are improved, its preparation technology of the coating is simple, easy to operate.

Description

A kind of ecological nano anion inorganic mineral coating and preparation method thereof
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of ecological nano anion inorganic mineral coating and its preparation Method.
Background technology
As people's living standard is improved constantly, interior decoration is increasingly luxurious, attractive in appearance, and people pursue comfortable high-grade life While, for the pursuit also more and more higher of healthy, safe and environment-friendly theory.However, because indoor pollution influences the thing of human health Part is on the increase.Investigation shows that 60% disease is relevant with room air pollution, and 80% cancer is relevant with living environment.Cause This, high-efficient and lasting purifies the air of a room, and keeps pure and fresh, healthy environment to be that people are extremely urgent and pursues a goal.
The appearance of ecological nano anion inorganic coating, can allow people indoors breath freshening, health air.It is ecological The research and development of nano-negative ion inorganic coating, are, according to being mission for ecological, the healthy living environment of public's foundation, to breach and apply within the walls Material thoroughly eliminates the harm that VOC is caused to human body in coating, breached without formaldehyde, without this two big world property problem of VOC Interior wall coating material focuses on decorative effect merely and have ignored the limitation of health, is filled with for decoration in respecting for life Contain.The release anion of ecological nano anion inorganic coating energy continuation, with mankind's sleep is improved, improves the work(of immunity Energy.
The content of the invention
For above-mentioned purpose, the present invention provides a kind of ecological nano anion inorganic mineral coating and preparation method thereof.
In order to realize foregoing invention purpose, the technical solution adopted by the present invention is as follows,
A kind of ecological nano anion inorganic mineral coating is designed, is made up of the raw material of following mass percent:Dispersant 2-8%, defoamer 1-3%, levelling agent 1-3%, wetting agent 1-4%, titanium dioxide 5-20%, kaolin 5-15%, negative ion powder 1-5%, refines mineral powder 2-10%, nano silicate 10-30%, thickener 1-5%, styrene-acrylic emulsion 4-20%, water 20- 30%.
Preferably, the ecological nano anion inorganic mineral coating, is made up of the raw material of following mass percent:It is scattered Agent 6%, defoamer 1%, levelling agent 3%, wetting agent 1.5%, titanium dioxide 15%, kaolin 10%, negative ion powder 1.5%, essence Mineral powder 5% processed, nano silicate 15%, thickener 3%, styrene-acrylic emulsion 14%, water 25%.
Preferably, the ecological nano anion inorganic mineral coating, is made up of the raw material of following mass percent:It is scattered Agent 6%, defoamer 2%, levelling agent 1%, wetting agent 1.5%, titanium dioxide 20%, kaolin 5%, negative ion powder 2% refines ore deposit Thing powder 3%, nano silicate 20%, thickener 2%, styrene-acrylic emulsion 7.5%, water 30%.
Preferably, the ecological nano anion inorganic mineral coating, is made up of the raw material of following mass percent:It is scattered Agent 4%, defoamer 2%, levelling agent 2%, wetting agent 2%, titanium dioxide 15%, kaolin 10%, negative ion powder 1% refines ore deposit Thing powder 5%, nano silicate 19%, thickener 3%, styrene-acrylic emulsion 10%, water 27%.
The preferred model of the dispersant is 731a.
The preferred model of the defoamer is XHD.
The preferred model of the levelling agent is BYK306.
The preferred model of the wetting agent is X405.
The preferred model of the titanium dioxide is R706.
It is preferred that, the preferred model of the thickener is ASE60.
The negative ion powder (produces the principle of anion, a kind of artificial synthesized or proportioning grandidierite using nature Thing, typically all tourmaline powder+lanthanide series or rare earth element, the ratio of its rare earth elements greatly exceed electrically Stone flour, rare earth has accounted for more than 60%), preferably ultra-fine level negative ion powder.
The invention also discloses a kind of preparation method of ecological nano anion inorganic mineral coating, comprise the following steps,
Raw material is weighed according to above-mentioned mass percent,
1) high speed dispersor is opened, water, dispersant, defoamer, levelling agent, wetting agent are slowly added to successively, is mixed 10min is stirred, thick compound is obtained;
2) to step 1) obtained by thick compound in sequentially add titanium dioxide, kaolin, negative ion powder, refined mineral powder, High-speed stirred, until the fineness of compound reaches 40 μm;
3) to step 2) obtained by compound in addition nano silicate and emulsion, be sufficiently stirred for being uniformly dispersed;
4) in the state of stirring, to step 3) gained compound in add thickener, mix thoroughly;
5) quality inspection is qualified, packaging filtering.
It is preferred that, the model of the dispersant is 731a, and the model of the defoamer is XHD.
It is preferred that, the model of the levelling agent is BYK306, and the model of the wetting agent is X405.
It is preferred that, the model of the titanium dioxide is R706, and the model of the thickener is ASE60.
It is preferred that, the negative ion powder is ultra-fine level negative ion powder.
Compared with the prior art, beneficial effects of the present invention are embodied in:
The ecological nano anion inorganic mineral coating that the present invention is provided, the stain resistance of paint film, water proofing property and anti-scratch Wiping property is significantly improved, the lasting release anion of energy, is purified indoor environment, is improved the sleep quality of people and the immunity of body; The preparation technology of the coating is simple, easy to operate.
Embodiment
With reference to specific embodiment be described in detail technical scheme, it is as described below, be only to the present invention compared with Good embodiment, not does the limitation of other forms to the present invention.In the examples below involved instrument and equipment for example without Special instruction, is routine instrument device;Involved raw material is commercially available convenient source unless otherwise instructed;Involved Processing and fabricating step, is conventional machining making step unless otherwise instructed.
Negative ion powder used is ultra-fine level negative ion powder in the present invention, is purchased from Hebei Lingshou County auspicious up to the limited public affairs of mining industry Department, the mesh of specification 1250, refined mineral powder used is purchased from the thick moral mineral powder in Hebei Lingshou County.
Embodiment 1
A kind of ecological nano anion inorganic mineral coating, is made up of the raw material of following mass percent:Dispersant 731a 6%, defoamer XHD 1%, levelling agent BYK306 3%, wetting agent X405 1.5%, titanium dioxide R706 15%, kaolin 10%, ultra-fine level negative ion powder 1.5% refines mineral powder 5%, nano silicate 15%, thickener ASE60 3%, phenylpropyl alcohol breast Liquid 14%, water 25%.
Embodiment 2
A kind of ecological nano anion inorganic mineral coating, is made up of the raw material of following mass percent:Dispersant 731a 6%, defoamer XHD 2%, levelling agent BYK306 1%, wetting agent X405 1.5%, titanium dioxide R706 20%, kaolin 5%, ultra-fine level negative ion powder 2% refines mineral powder 3%, nano silicate 20%, thickener ASE60 2%, styrene-acrylic emulsion 7.5%, water 30%.
Embodiment 3
A kind of ecological nano anion inorganic mineral coating, is made up of the raw material of following mass percent:Dispersant 731a 4%, defoamer XHD 2%, levelling agent BYK306 2%, wetting agent X405 2%, titanium dioxide R706 15%, kaolin 10%, Ultra-fine level negative ion powder 1%, refined mineral powder 5%, nano silicate 19%, thickener ASE60 3%, styrene-acrylic emulsion 10%, Water 27%.
Embodiment 4
Any described ecological nano anion inorganic mineral coating of embodiment 1 to 3, its preparation method includes following step Suddenly,
Raw material is weighed according to any raw material proportioning of above-described embodiment 1 to 3,
1) water, dispersant, defoamer, levelling agent, wetting agent are slowly added to successively into high speed dispersor, is mixed After 10min, titanium dioxide, kaolin, negative ion powder, refined mineral powder are sequentially added, high-speed stirred, fineness is controlled at 40 μm;
2) to step 1) obtained by compound in addition nano silicate and emulsion, be sufficiently stirred for being uniformly dispersed, in stirring In the state of add thickener, mix thoroughly.
3) through quality inspection it is qualified after, carry out packaging filtering.
Performance detection experiment is carried out to the ecological nano anion inorganic mineral coating that the present invention is provided, to verify the coating Beneficial effect, it is specific as follows:
(1) use JG/T26-2002 building industry professional standards, to above example provide ecological nano anion without Machine mineral coating carries out the test of following performance indications, test result such as table 1 below.
The ecological nano anion inorganic mineral coating the performance test results that the present invention of table 1 is provided
Project Test result
State in a reservoir Without lump after stirring, in uniform state
Application property Brush twice accessible
Paint film appearance Normally
Drying time/h (25 DEG C, humidity 55%) Surface drying≤2h
Contrast ratio (white and light color) ≥0.96
Thermal storage stability (30d) Without caking, no gel
Abrasion resistance It is 10000 times, not show-through
Stain resistance ≤ 8%
Water resistance (20d)) It is non-foaming, do not fall off, allow slight dry linting
Alkali resistance (10d)) It is non-foaming, do not fall off, allow slight dry linting
Temperature-change resistance (30 times) It is non-foaming, do not fall off, allow slight dry linting
Artificial ageing resistance Efflorescence≤1 grade, changes colour≤2 grades
(2) JC/T1016-2006 is used《The method of testing of material anion-generating capacity》, the ecology that the test present invention is provided Nano-negative ion inorganic mineral coating anion yield, test result is shown in Table 2.
The ecological nano anion inorganic mineral coating anion yield test result that the present invention of table 2 is provided
Project Test data
Anion yield (individual/cm2) 2500
It is ecological nano anion inorganic mineral coating water resistance that the present invention is provided, anti-it can be seen from above-mentioned test result Scratch, stain resistance are significantly improved, have the advantages that to prevent again to bubble, fade, dry linting, environmental protection, high comprehensive performance.

Claims (10)

1. a kind of ecological nano anion inorganic mineral coating, it is characterised in that be made up of the raw material of following mass percent:Point Powder 2-8%, defoamer 1-3%, levelling agent 1-3%, wetting agent 1-4%, titanium dioxide 5-20%, kaolin 5-15%, negative ion powder 1- 5%, refine mineral powder 2-10%, nano silicate 10-30%, thickener 1-5%, styrene-acrylic emulsion 4-20%, water 20-30%.
2. ecological nano anion inorganic mineral coating according to claim 1, it is characterised in that by following quality percentage The raw material composition of ratio:Dispersant 6%, defoamer 1%, levelling agent 3%, wetting agent 1.5%, titanium dioxide 15%, kaolin 10%, anion Powder 1.5%, refines mineral powder 5%, nano silicate 15%, thickener 3%, styrene-acrylic emulsion 14%, water 25%.
3. ecological nano anion inorganic mineral coating according to claim 1, it is characterised in that by following quality percentage The raw material composition of ratio:Dispersant 6%, defoamer 2%, levelling agent 1%, wetting agent 1.5%, titanium dioxide 20%, kaolin 5%, anion Powder 2%, refines mineral powder 3%, nano silicate 20%, thickener 2%, styrene-acrylic emulsion 7.5%, water 30%.
4. ecological nano anion inorganic mineral coating according to claim 1, it is characterised in that by following quality percentage The raw material composition of ratio:Dispersant 4%, defoamer 2%, levelling agent 2%, wetting agent 2%, titanium dioxide 15%, kaolin 10%, negative ion powder 1%, refine mineral powder 5%, nano silicate 19%, thickener 3%, styrene-acrylic emulsion 10%, water 27%.
5. ecological nano anion inorganic mineral coating according to claim 1, it is characterised in that the type of the dispersant Number be 731a, the model of the defoamer is XHD.
6. ecological nano anion inorganic mineral coating according to claim 1, it is characterised in that the type of the levelling agent Number it is BYK306, the model of the wetting agent is X405.
7. ecological nano anion inorganic mineral coating according to claim 1, it is characterised in that the type of the titanium dioxide Number it is R706, the model of the thickener is ASE60.
8. ecological nano anion inorganic mineral coating according to claim 1, it is characterised in that the negative ion powder is Ultra-fine level negative ion powder.
9. the preparation method of the ecological nano anion inorganic mineral coating described in claim 1-4, it is characterised in that including with Lower step,
Raw material is weighed according to any described mass percents of claim 1-4,
1)High speed dispersor is opened, water, dispersant, defoamer, levelling agent, wetting agent are slowly added to successively, is mixed 10min;
2)To step 1)Titanium dioxide, kaolin, negative ion powder, refined mineral powder, high-speed stirring are sequentially added in the compound of gained Mix, until the fineness of compound reaches 40 μm;
3)To step 2)Nano silicate and emulsion are added in the compound of gained, is sufficiently stirred for being uniformly dispersed;
4)In the state of stirring, to step 3)Thickener is added in gained compound, is mixed thoroughly;
5)Quality inspection is qualified, packaging filtering.
10. the preparation method of ecological nano anion inorganic mineral coating according to claim 9, it is characterised in that institute The model 731a of dispersant is stated, the model of the defoamer is XHD, the model of the levelling agent is BYK306, the wetting The model of agent is X405, and the model of the titanium dioxide is R706, and the model of the thickener is ASE60, and the negative ion powder is Ultra-fine level negative ion powder.
CN201710561760.3A 2017-07-11 2017-07-11 A kind of ecological nano anion inorganic mineral coating and preparation method thereof Pending CN107163631A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710561760.3A CN107163631A (en) 2017-07-11 2017-07-11 A kind of ecological nano anion inorganic mineral coating and preparation method thereof

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Application Number Priority Date Filing Date Title
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CN107163631A true CN107163631A (en) 2017-09-15

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135358A (en) * 2018-07-26 2019-01-04 河南华彩无机涂料有限公司 A kind of aqueous inorganic mildew resistant paint and preparation method thereof
CN110628262A (en) * 2019-10-17 2019-12-31 杭州美多乐环保新材料有限公司 Ecological nano-ion inorganic mineral coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648178A (en) * 2004-01-19 2005-08-03 范存玉 Long action negative ion antiseptic function paint
CN1687261A (en) * 2005-04-28 2005-10-26 上海交通大学 Antibacterial, anti electromagnetic radiant interior wall coating with formaldehyde being removed
CN1760289A (en) * 2004-10-14 2006-04-19 大连振邦氟涂料股份有限公司 Negative ion emulsion paint and preparation method thereof
CN101486867A (en) * 2009-02-12 2009-07-22 张文磊 Photo-catalytic coating
CN103642328A (en) * 2013-12-04 2014-03-19 青岛益群漆业集团有限公司 New-generation nanometer oxygen bar interior wall coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648178A (en) * 2004-01-19 2005-08-03 范存玉 Long action negative ion antiseptic function paint
CN1760289A (en) * 2004-10-14 2006-04-19 大连振邦氟涂料股份有限公司 Negative ion emulsion paint and preparation method thereof
CN1687261A (en) * 2005-04-28 2005-10-26 上海交通大学 Antibacterial, anti electromagnetic radiant interior wall coating with formaldehyde being removed
CN101486867A (en) * 2009-02-12 2009-07-22 张文磊 Photo-catalytic coating
CN103642328A (en) * 2013-12-04 2014-03-19 青岛益群漆业集团有限公司 New-generation nanometer oxygen bar interior wall coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
林宣益: "《乳胶漆》", 31 July 2004, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135358A (en) * 2018-07-26 2019-01-04 河南华彩无机涂料有限公司 A kind of aqueous inorganic mildew resistant paint and preparation method thereof
CN110628262A (en) * 2019-10-17 2019-12-31 杭州美多乐环保新材料有限公司 Ecological nano-ion inorganic mineral coating and preparation method thereof

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Application publication date: 20170915